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Use of hand-held gamma-ray spectrometry to assess decay of granite ashlars in historical buildings of NW Spain (Barbanza, Galicia) 使用手持伽马射线光谱仪评估西班牙西北部(加利西亚,巴班萨)历史建筑中花岗岩灰岩的衰变情况
IF 3.5 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2024-11-15 DOI: 10.1016/j.culher.2024.10.019
Ana C. Hernández Santomé , Jorge Sanjurjo-Sánchez , Carlos Alves
Non-destructive methods are widely demanded in research on Cultural Heritage. In the last years, several techniques have been proposed, attempted and even routinely tried on research on assessing the deterioration of stone of Cultural Heritage buildings and monuments. We test here the use of hand-held gamma-ray spectrometry (GRS) to assess the decay of stone in two Heritage buildings. GRS is a non-destructive technique widely used in mineral exploration that provides an estimate of the environmental gamma radiation dose but also of the content of some radioisotopes of uranium, thorium and potassium in rocks and minerals. Such radioisotopes are present in very variable contents depending on the rock type. They have a different behavior when a stone overcome weathering processes, being usually the K and U leaching, while Th tends to be considered as an immobile element. We have tested GRS on two historical buildings built with granite blocks of the Peninsula of Barbanza (Galicia, NW, Spain): Santiago de Lampón and San Cristovo de Abaqueiro. The studied buildings show a mild deterioration in some façades, being an interesting study case. Measurements were carried out on the four façades of both buildings at on ashlars located at heights of 0.5, 1.5 and 2 m, above the ground, for comparing the possible effect of capillary water from underground on the weathering degree of the ashlars. The comparison of the content in K, U, and Th provides interesting results, that seems to be useful to assess the degree of decay of ashlars in buildings that shows slight differences in decay, being a non-destructive tool.
非破坏性方法在文化遗产研究中被广泛采用。在过去的几年里,已经提出、尝试甚至常规试用了多种技术来评估文化遗产建筑和古迹石材的老化情况。我们在这里测试使用手持伽马射线光谱仪(GRS)来评估两座文物建筑的石材老化情况。伽马射线光谱仪是一种广泛应用于矿产勘探的非破坏性技术,不仅可以估算环境伽马辐射剂量,还可以估算岩石和矿物中铀、钍和钾等放射性同位素的含量。这些放射性同位素的含量因岩石类型而异。当岩石经历风化过程时,它们会有不同的表现,通常是钾和铀的沥滤,而钍往往被认为是一种不可移动的元素。我们在巴班萨半岛(加利西亚,西班牙西北部)两座用花岗岩砌块建造的历史建筑上测试了 GRS:圣地亚哥-德-兰蓬(Santiago de Lampón)和圣克里斯托沃-德-阿巴凯罗(San Cristovo de Abaqueiro)。这两座建筑的部分外墙出现了轻微的老化现象,是一个有趣的研究案例。为了比较地下毛细管水对灰岩风化程度可能产生的影响,对两座建筑的四个外墙离地面 0.5 米、1.5 米和 2 米高处的灰岩进行了测量。对 K、U 和 Th 含量的比较提供了有趣的结果,这似乎有助于评估建筑物中灰岩的风化程度,因为这些灰岩的风化程度略有不同,是一种非破坏性工具。
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引用次数: 0
Technical examination of Wat Sisowath Ratanaram panel painting Wat Sisowath Ratanaram 壁画的技术检测
IF 3.5 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2024-11-14 DOI: 10.1016/j.culher.2024.10.018
Sokheng La , Jihyeon Yun , Kyeongmin Lee , Radchada Buntem
The technical examination on the early 20th century panel painting of Wat Sisowath Ratanaram was performed using optical microscopy (OM), scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDS), X-ray diffraction (XRD), Micro-Raman spectroscopy (μ-RAMAN), attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR), and pyrolysis gas chromatography-mass spectrometry (Py-GC/MS). The investigation shows the mixture of minium, cinnabar and baryte in red preparation layer, quartz from the natural earth pigment in the underpaint layer and the pigments mixed with the additives in the paint layer. There are various pigments found in the paint layer ranging from emerald green, chalk, baryte, chrome yellow, ultramarine blue, carbon black and zinc white. Zinc white was widely utilized as the additive of green, yellow and blue paint layer. In addition, minium and carbon black were used to draw fine lines for image details. The degradation products of gypsum in the paint layer were evidenced by SEM-EDS and XRD. While the darkening of red lead in the red preparation layer was observed by OM. The trace of natural plant resin as a binding meium was found in S_Wood and S_Black samples evidencing by ATR-FTIR and Py-GC/MS. The 7 steps of painting technique were proposed by implementing all detailed scientific information.
采用光学显微镜 (OM)、扫描电子显微镜-能量色散 X 射线光谱 (SEM-EDS)、X 射线衍射 (XRD)、微拉曼光谱 (μ-RAMAN)、衰减全反射-傅立叶变换红外光谱 (ATR-FTIR) 和热解气相色谱-质谱 (Py-GC/MS) 对 20 世纪早期的 Wat Sisowath Ratanaram 壁画进行了技术检测。调查显示,红色准备层中含有矿石、朱砂和重晶石的混合物,底漆层中含有来自天然土颜料的石英,油漆层中含有与添加剂混合的颜料。涂料层中的颜料种类繁多,包括翡翠绿、白垩、重晶石、铬黄、群青蓝、碳黑和锌白。锌白被广泛用作绿色、黄色和蓝色漆层的添加剂。此外,矿物质和碳黑还被用于绘制图像细节的细线。涂料层中石膏的降解产物通过 SEM-EDS 和 XRD 得到了证明。OM 观察到红色制备层中的红铅变暗。通过 ATR-FTIR 和 Py-GC/MS,在 S_Wood 和 S_Black 样品中发现了天然植物树脂作为粘合剂的痕迹。通过实施所有详细的科学信息,提出了 7 个步骤的绘画技术。
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引用次数: 0
Methodology for measures of twist and crimp in canvas paintings supports and historical textiles 测量帆布绘画支撑物和历史纺织品扭曲和卷曲的方法
IF 3.5 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2024-11-12 DOI: 10.1016/j.culher.2024.10.016
Antonio Iaccarino Idelson, Otto Bergsma, Roger Groves
Twist and crimp values are of paramount importance to the textile industry in understanding the properties and performance of a textile, and their quantification has been a subject of study since the early 20th century. Twist and crimp are the result of how the fibers have been modified from the original bundle to shape the textile, so the industrial methods used to measure them are based on mechanically reversing such deformations. The same information is needed to study the mechanics of historical fabrics such as canvas paintings supports and historical textiles, but they are more difficult to obtain because these are often brittle and impregnated with foreign materials, less homogeneous and very limited in availability for sampling. Therefore, such fundamental parameters are usually unavailable for conservation studies.
This paper examines the protocols used in the textile industry and proposes new methods, developed from previous research, for the reliable measurement of twist and crimp in historical textiles. The twist measurement method is non-destructive as it is based on observing the textile and the fibers on the surface of the yarn. Crimp is the undulation of the interlaced yarns and its measurement is an invasive examination of the internal structure of the textile, as it requires the observation of individual yarns. Both methods, applied here to a group of historical textiles, provide data in accordance with the current parameters of the textile industry, and their use is relatively simple and inexpensive.
捻度和卷曲值对于纺织业了解纺织品的特性和性能至关重要,自 20 世纪初以来,量化捻度和卷曲值一直是一个研究课题。捻度和卷曲度是纤维如何从原始纤维束变形为纺织品的结果,因此用于测量它们的工业方法是基于机械地逆转这种变形。要研究历史织物(如帆布画支架和历史纺织品)的力学,也需要同样的信息,但这些信息更难获得,因为这些织物通常比较脆,浸渍了外来材料,不太均匀,而且取样非常有限。因此,这些基本参数通常无法用于保存研究。本文研究了纺织行业使用的规程,并提出了根据以往研究开发的新方法,用于可靠测量历史纺织品的捻度和卷曲度。捻度测量方法是非破坏性的,因为它基于对纺织品和纱线表面纤维的观察。卷曲是纱线交错的起伏,其测量需要观察单根纱线,因此是对纺织品内部结构的侵入性检查。这两种方法都适用于一组历史悠久的纺织品,提供的数据符合当前纺织业的参数,而且使用起来相对简单、成本低廉。
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引用次数: 0
On a newly developed transport method for sensitive cradled panel paintings 关于一种新开发的敏感挂板画运输方法
IF 3.5 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2024-11-01 DOI: 10.1016/j.culher.2024.10.015
Eva Hartlieb , Pascal Ziegler , Andreas Baumann , Peter Schöler , Peter Eberhard , Stefan Velte , Manuela Wiesend , Daniela Karl
This publication describes the successful development and application of an unusual new transport frame. The object to be transported is a highly sensitive medieval panel painting with a cradle. Unique clamping mechanisms are developed. These mechanisms secure the panel painting by clamping the cradle battens without direct immission on the original wooden panel. Preliminary studies and the development of this frame system include creating a simulation model using the finite element method for the computer-assisted computation and prediction of the behaviour. The design and realization of the transport of this wooden panel painting combines expertise from the scientific fields of art technology, conservation, mechanics and dynamics with the professional experience of a specialized transport company.
本出版物介绍了一种不同寻常的新型运输框架的成功开发和应用。需要运输的物品是高度敏感的中世纪板画,带有一个支架。我们开发了独特的夹紧装置。这些机械装置通过夹紧支架板条来固定板画,而不会直接接触到原始木板。该框架系统的初步研究和开发包括使用有限元法创建一个模拟模型,用于计算机辅助计算和行为预测。这幅木板画的运输设计和实现结合了艺术技术、保护、机械和动力学等科学领域的专业知识以及专业运输公司的专业经验。
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引用次数: 0
How do water and acid in marine archaeological wood affect its mechanical properties? 海洋考古木材中的水和酸如何影响其机械性能?
IF 3.5 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2024-11-01 DOI: 10.1016/j.culher.2024.10.017
Xunming Gao , Jian Zhao , Jiahui Liu , Lihua Fei , Dong Zhao
The prolonged burial of marine archaeological wood in seawater mudflats results in the internal saturation of the wood with water, acidification, and salt deposition. Despite the application of desalination, deacidification, and drainage treatments to archaeological wood following excavation, the effects of such environments on wood are irreversible. To understand the effects of moisture content, acidic environments, and insoluble salts (Fe2S) on the mechanical properties of marine archaeological wood, this study employed molecular dynamics simulations to analyze the tensile performance of wood cell walls under various conditions. The results indicate that, compared to completely dry wood, water molecules can significantly enhance the tensile strength of wood cell walls. However, in systems with a 12 % moisture content, the tensile strength is lower than in systems with a 4 % moisture content. The worst tensile performance of wood cell walls occurs in acidic and salt-deposition conditions. This is mainly due to the fact that an appropriate amount of moisture enhances the interconnections between wood fibers, whereas acidic and salt deposition conditions disrupt these connections. Additionally, the impact of varying quantities of moisture molecules on the mechanical properties of wood also varies. Further exploring the optimal moisture content for the preservation of waterlogged wooden artifacts, using archaeological fir wood as an example, we constructed models of amorphous wood fibers and matrices with moisture content varying from 0 % to 36 %. The results indicate that the system with 8 % moisture content exhibits optimal mechanical performance. Specifically, the shear modulus and chain-direction elastic modulus reach 4.52 GPa and 12.93 GPa, respectively, representing an increase of 25.2 % and 45.1 % compared to completely dry systems. The molecular mechanism by which moisture content influence the mechanical properties of wood was analyzed through parameters such as mean square displacement, diffusion coefficient, and free volume. It is hypothesised that an appropriate amount of water molecules can fill the gaps between fibers, enhancing the inter-fiber bonding and stiffness, and thereby improving the mechanical properties of wood. However, as water molecules continue to be added, this positive effect diminishes. The objective of our study is to gain insight into the mechanical behavior of archaeological wood cell walls from a molecular perspective. This paves the way for multiscale studies to determine the optimal moisture content for preserving wooden artifacts and to identify environmental conditions that can maximize the mechanical performance of archaeological wooden objects.
海洋考古木材长期埋藏在海水泥滩中会导致木材内部水分饱和、酸化和盐分沉积。尽管在发掘后对考古木材进行了脱盐、脱酸和排水处理,但这种环境对木材的影响是不可逆的。为了了解含水量、酸性环境和不溶盐(Fe2S)对海洋考古木材机械性能的影响,本研究采用分子动力学模拟分析了木材细胞壁在各种条件下的拉伸性能。结果表明,与完全干燥的木材相比,水分子能显著增强木材细胞壁的拉伸强度。然而,在含水率为 12% 的体系中,拉伸强度低于含水率为 4% 的体系。在酸性和盐沉积条件下,木材细胞壁的拉伸性能最差。这主要是由于适量的水分会增强木纤维之间的相互连接,而酸性和盐沉积条件则会破坏这些连接。此外,不同数量的水分分子对木材机械性能的影响也各不相同。以考古杉木为例,我们构建了含水量从 0% 到 36% 不等的无定形木纤维和基质模型,进一步探索了保存水渍木质文物的最佳含水量。结果表明,含水率为 8% 的系统具有最佳机械性能。具体来说,剪切模量和链向弹性模量分别达到了 4.52 GPa 和 12.93 GPa,与完全干燥的体系相比,分别增加了 25.2 % 和 45.1 %。通过均方位移、扩散系数和自由体积等参数分析了含水率影响木材机械特性的分子机制。据推测,适量的水分子可以填充纤维之间的空隙,增强纤维间的结合力和刚度,从而改善木材的机械性能。然而,随着水分子的不断加入,这种积极作用会逐渐减弱。我们的研究旨在从分子角度深入了解考古木材细胞壁的机械行为。这为多尺度研究铺平了道路,以确定保存木质文物的最佳含水量,并确定可最大限度提高考古木质文物机械性能的环境条件。
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引用次数: 0
Iron and lead in Notre-Dame de Paris: An interdisciplinary perspective 巴黎圣母院的铁与铅:跨学科视角
IF 3.1 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2024-01-01 DOI: 10.1016/j.culher.2022.09.003
Maxime L'Héritier

The construction of cathedral Notre-Dame de Paris sheds new light on the use of iron and lead in the building. It encourages one to question the evolution of practices related to these metals over the centuries. On the one hand, the restoration work has brought to light various armatures, chains and series of iron staples that were previously unknown, the study of which makes it possible to specify their role in the structure of the building, their chronology, but also their quality and origin. Research is also being carried out into the various uses of lead (roofing, decoration, sealing, etc.) and the practices of craftsmen at different times. The identification of the lead sources is carried out by means of elemental and isotopic analyses, making it possible to highlight recycling practices, as well as to trace the lead possible contribution to the pollution of the environment. An interdisciplinary research group on metal bringing together archaeologists, archaeometers, chemists, art historians and heritage specialists has been set up within Notre-Dame scientific research program to jointly address all these issues.

巴黎圣母院大教堂的建造揭示了建筑中使用铁和铅的新情况。它促使人们质疑几个世纪以来与这些金属有关的做法的演变。一方面,修复工作揭示了以前不为人知的各种衔铁、链条和一系列铁钉,对它们的研究可以明确它们在建筑结构中的作用、年代、质量和来源。此外,还对铅的各种用途(屋顶、装饰、密封等)以及不同时期工匠的做法进行了研究。通过元素分析和同位素分析来确定铅的来源,从而可以突出回收利用的做法,并追踪铅可能对环境造成的污染。为了共同解决所有这些问题,在圣母院科学研究计划内成立了一个跨学科金属研究小组,汇集了考古学家、考古学家、化学家、艺术史学家和遗产专家。
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引用次数: 0
Mediators, users and narratives: The cathedral experience 调解者、使用者和叙述:大教堂体验
IF 3.1 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2024-01-01 DOI: 10.1016/j.culher.2023.06.011
Sylvie Sagnes

The unprecedented emotion aroused by the burning of Notre-Dame de Paris on April 15, 2019 implies an attachment to this building whose foundations anthropology attempts to uncover. Therefore, it is also a case of questioning the way in which a heritage can be as universally shared as is the Parisian cathedral. Moreover, in the present of the restoration, which holds the monument at a distance from its users in an unprecedented way, the current investigation aims to understand what happens to this link, as revealed by the catastrophe.

2019 年 4 月 15 日焚烧巴黎圣母院所引发的空前情绪意味着人们对这座建筑的依恋,人类学试图揭开这座建筑的根基。因此,这也是对巴黎大教堂这样的遗产如何能够得到普遍共享的一种质疑。此外,目前的修复工作以前所未有的方式拉开了纪念碑与其使用者之间的距离,本次调查旨在了解灾难所揭示的这种联系会发生什么变化。
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引用次数: 0
Casting, joining and recycling. Use of lead and plumbers practices in Notre-Dame building yard (12th-19th c.) through historical, archaeological and chemical investigations 铸造、连接、回收。通过历史、考古和化学调查,了解圣母院建筑院子里铅和管道工的使用情况(12 -19世纪)
IF 3.1 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2024-01-01 DOI: 10.1016/j.culher.2023.02.005
Delphine Syvilay , Aurélia Azéma , Guillaume Sarah , Richard Costa , Maxime L'Héritier

An interdisciplinary scientific project composed of different work groups was set up after the fire of Notre-Dame cathedral in 2019 which aims at studying all different aspects of the building and its evolutions from the 12th to the 19th century. One of them is the Metal work group who investigates the use of iron and lead in this monument and try for instance to trace the history of lead uses in the construction and restorations of cathedrals. The present paper focuses on the case of Notre-Dame de Paris, a jewel of French gothic architecture to question the role of this metal in its structure, to determine the quantities used and to investigate issues related to its provisioning and its recycling. Paradoxically, though the fire of 15th April 2019 melted almost the whole lead roof as well as decorative elements on the spire, lost forever for scientific investigations, it also enabled to reveal hidden parts of the cathedral where lead used as sealing became accessible thanks to scaffolding. A methodology combining archaeology, archive record study and archaeometry was implemented to study the remaining lead in the cathedral leading to a textual approach coupled with a material approach. Two case studies are considered in this paper as representative of lead uses at different periods of the cathedral's life: in medieval masonry with cramp's sealings in the tribunes, and on the sacristy's roof dating from the 19th century. For the first case, a chronology of the construction will be suggested and for the second a discussion between chemical analyses and archive records will be opened.

2019 年巴黎圣母院大教堂火灾后,成立了一个由不同工作小组组成的跨学科科学项目,旨在研究这座建筑的各个方面及其从 12 世纪到 19 世纪的演变。其中一个工作小组是金属工作小组,该小组负责调查该纪念碑中铁和铅的使用情况,并试图追溯大教堂建造和修复过程中铅的使用历史。本文以法国哥特式建筑的瑰宝--巴黎圣母院为例,质疑这种金属在其结构中的作用,确定其使用量,并调查与铅的供应和回收相关的问题。令人啼笑皆非的是,尽管 2019 年 4 月 15 日的大火熔化了几乎整个铅制屋顶以及尖塔上的装饰构件,使科学研究永远失去了意义,但这场大火也揭示了大教堂的隐秘部分,由于搭起了脚手架,人们可以接触到用作密封的铅。为了研究大教堂中残存的铅,我们采用了一种结合考古学、档案记录研究和考古计量学的方法,将文字方法与材料方法相结合。本文考虑了两个案例研究,它们代表了大教堂不同时期的铅使用情况:在护民官的中世纪砖石结构中使用的抽筋封条,以及在圣器室屋顶上使用的 19 世纪的铅。对于第一种情况,我们将提出一个建筑年表,对于第二种情况,我们将在化学分析和档案记录之间展开讨论。
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引用次数: 0
Scientific research on stained-glass windows for Notre-Dame de Paris Cathedral 巴黎圣母院彩色玻璃窗的科学研究
IF 3.1 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2024-01-01 DOI: 10.1016/j.culher.2023.07.010
Claudine Loisel

During the fire at Notre-Dame de Paris Cathedral on April 15 th, 2019, the historic stained-glass windows were entirely protected by the action of firefighters and the resistance of the vault, which fulfilled its role as a shield. In this context, a group of art historians, stained glass experts, conservation scientists and university researchers was created to coordinate scientific research concerning the stained-glass windows of the cathedral. This “Glass” working group (GT Verre) defined the following priority research themes: the characterisation of surface deposits on stained glass, understanding the interaction of the former with materials and how to optimise conservation-restoration treatments, and general research to extend our knowledge of the 12 th to 20 th -century stained glass at Notre-Dame.

在 2019 年 4 月 15 日巴黎圣母院大教堂火灾期间,消防员的行动和拱顶的抵抗完全保护了历史悠久的彩色玻璃窗,拱顶发挥了它的保护作用。在这种情况下,一个由艺术史学家、彩色玻璃专家、文物保护科学家和大学研究人员组成的小组应运而生,以协调有关大教堂彩色玻璃窗的科学研究。该 "玻璃 "工作组(GT Verre)确定了以下优先研究课题:彩色玻璃表面沉积物的特征、了解前者与材料的相互作用以及如何优化保护和修复处理,并开展一般性研究,以扩展我们对圣母院 12 至 20 世纪彩色玻璃的了解。
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引用次数: 0
2D/3D data fusion for the comparative analysis of the vaults of Notre-Dame de Paris before and after the fire 巴黎圣母院拱顶火灾前后的2D/3D数据融合对比分析
IF 3.1 2区 综合性期刊 0 ARCHAEOLOGY Pub Date : 2024-01-01 DOI: 10.1016/j.culher.2023.06.012
El Mustapha Mouaddib , Anthony Pamart , Marc Pierrot-Deseilligny , Daniel Girardeau-Montaut

The work presented in this article was carried out following the fire (April 15, 2019) that ravaged Notre-Dame de Paris. The goal was to establish in a short and limited time-span the structural diagnosis of the remaining vaults of the cathedral. The analysis relied on 2D and 3D data acquired before and after the fire, and available at that time. Two complementary methods have been developed to estimate potential displacements from multi-temporal surveys. The first method is mainly based on the processing of image collections obtained with photogrammetric routines right after the fire. The second method, based on the processing of raw 3D data acquired with Terrestrial Laser Scanning, was developed afterward to refine and complete the analysis. Both methods have benefited from essential functionalities offered by two open-source solutions proven to enable “real-based” modeling in Cultural Heritage contexts, namely Micmac and CloudCompare. This paper presents the complementary use of these two software packages whilst detailing some procedural computing approaches to document and support structural diagnosis in an emergency situation. The limits and capabilities of each method are exposed and analyzed, toward the objective to develop 2.5D and 3D based geometrical analysis, respectively from photogrammetric and lasergrammetric sources. The results are presented and discussed regarding their potential usage for a quantitative and accurate diagnosis of vaults.

本文介绍的工作是在大火(2019 年 4 月 15 日)肆虐巴黎圣母院之后开展的。其目的是在短时间内对大教堂剩余拱顶的结构进行诊断。分析工作依赖于火灾前后获得的二维和三维数据,这些数据在当时是可用的。我们开发了两种互补方法来估算多时段勘测的潜在位移。第一种方法主要基于对火灾发生后通过摄影测量程序获得的图像集的处理。第二种方法是在处理地面激光扫描获得的原始三维数据的基础上开发的,用于完善和完成分析工作。这两种方法都得益于两个开源解决方案(即 Micmac 和 CloudCompare)所提供的基本功能,这两个解决方案已被证明能够在文化遗产背景下进行 "基于真实 "的建模。本文介绍了这两个软件包的互补使用,同时详细介绍了在紧急情况下记录和支持结构诊断的一些程序计算方法。本文揭示并分析了每种方法的局限性和能力,目的是分别从摄影测量和激光测距来源开发基于 2.5D 和 3D 的几何分析。结果展示并讨论了这两种方法在对拱顶进行定量和精确诊断方面的潜在用途。
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