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A review on gas permeability of polymer matrix composites for cryogenic applications 低温应用聚合物基复合材料气体渗透性综述
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-01-27 DOI: 10.1177/00219983241228550
Shuvam Saha, Rani W. Sullivan
Fiber-reinforced polymer matrix composites are increasingly considered for lightweight cryogenic pressure vessels due to their excellent combination of tailorability, specific mechanical properties, and relatively low coefficients of thermal expansion. However, significant challenges must be overcome to fully utilize PMCs for cryogenic fuel tanks in terms of transverse microcracking and subsequent permeation of cryogenic fuel. Gas permeation and microcrack densities of cryogenically cycled composites are highly influenced by their layup, ply thickness, load case, and manufacturing defects like voids and resin rich zones. There has been a significant amount of research on measuring gas permeation of composites fatigued under pure thermal or uniaxial thermo-mechanical stresses. However, results demonstrate that the gas permeability should be measured under biaxial thermo-mechanical stresses to properly gauge the leakage characteristics of damaged composites. This paper summarizes the results from over a hundred papers on the key parameters that influence the gas permeability of composites, appropriate testing methods to cycle composites for permeability measurement, methods to limit the evolution of transverse microcracks, and materials traditionally used for the fabrication of all-composite cryogenic fuel tanks. Thin plies and nanofiller-toughening of the matrix have been shown to provide significant improvements in transverse microcrack suppression within cryogenically cycled composites.
纤维增强聚合物基复合材料具有良好的可定制性、特定的机械性能和相对较低的热膨胀系数,因此越来越多地被考虑用于轻质低温压力容器。然而,要在低温燃料箱中充分利用 PMC,必须克服横向微裂纹和随后的低温燃料渗透方面的重大挑战。低温循环复合材料的气体渗透和微裂缝密度受其铺层、层厚、负载情况以及空隙和树脂富集区等制造缺陷的影响很大。在测量纯热或单轴热机械应力下疲劳复合材料的气体渗透性方面,已有大量研究。然而,研究结果表明,应在双轴热机械应力下测量气体渗透性,以正确衡量受损复合材料的泄漏特性。本文总结了百余篇论文的研究成果,涉及影响复合材料透气性的关键参数、循环测量复合材料透气性的适当测试方法、限制横向微裂纹演变的方法以及传统上用于制造全复合材料低温燃料箱的材料。研究表明,薄层和纳米填料增韧基体可显著改善低温循环复合材料的横向微裂纹抑制能力。
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引用次数: 0
Effect of peach peel on shape memory properties of polylactic acid 桃皮对聚乳酸形状记忆特性的影响
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2024-01-03 DOI: 10.1177/00219983231226282
Murat Eroğlu
In this study, two different peach peel powders were produced using the sieving process: with fiber (filler-fiber powder) and without fiber (filler powder). To investigate the effects of the prepared powders on the shape memory properties of PLA, PLA/Filler (wt%90 PLA: wt%10 filler) and PLA/Fiber-Filler (wt%90 PLA: wt%10 Fiber-Filler) biocomposite films were prepared by the solvent casting technique. The shape memory properties of the films, such as shape fixity ratio and shape recovery ratio, were determined by the bending test. For the PLA film, the shape fixity ratio is 81 ± 5%. When filler powders are applied, the shape fixity ratio is unaffected. However, when fiber-filler powder is added, the shape fixity ratio drops to 75 ± 1%. The shape recovery ratio for PLA film is 50 ± 7%. The shape recovery ratio increases to 54 ± 4% when filler powder is added. However, the percentage of shape recovery ratio remains the same when filler-fiber powders are added. Shape memory performance can be enhanced by adding peach peel filler powder to the PLA. The peach peel filler can be considered as a cost-effective filler to improve the shape memory properties of PLA-based biocomposites. As a result, peach peel filler reinforced PLA based composite films may be possible low-cost and biodegreadable shape memory material candidates for a variety of industries like aerospace and soft robotics.
本研究采用筛分工艺制备了两种不同的桃皮粉末:含纤维粉末(填料-纤维粉末)和不含纤维粉末(填料粉末)。为了研究制备的粉末对聚乳酸形状记忆特性的影响,采用溶剂浇铸技术制备了聚乳酸/填料(wt%90 聚乳酸:wt%10 填料)和聚乳酸/纤维-填料(wt%90 聚乳酸:wt%10 纤维-填料)生物复合薄膜。通过弯曲试验测定了薄膜的形状记忆特性,如形状固定比和形状恢复比。聚乳酸薄膜的形状固定率为 81 ± 5%。当使用填充粉末时,形状固定率不受影响。然而,当加入纤维填充粉末时,形状固定率会下降到 75 ± 1%。聚乳酸薄膜的形状复原率为 50 ± 7%。添加填料粉末后,形状恢复率增至 54 ± 4%。然而,添加填料-纤维粉末时,形状复原率的百分比保持不变。在聚乳酸中添加桃皮填料粉末可提高形状记忆性能。桃皮填料可作为一种具有成本效益的填料,用于改善聚乳酸基生物复合材料的形状记忆性能。因此,桃皮填料增强的聚乳酸基复合薄膜可能成为低成本、可生物分解的形状记忆材料,适用于航空航天和软机器人等多种行业。
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引用次数: 0
A comparison of damping-based methods to identify damage to carbon-fiber-reinforced polymers laminates subjected to low-velocity impact 比较基于阻尼的方法,以确定碳纤维增强聚合物层压板在受到低速冲击时的损坏情况
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-12-29 DOI: 10.1177/00219983231225451
Mohammad Rouhi Moghanlou, Ali Mahmoudi, M. Khonsari, G. Li
A method for detecting low-velocity impact damage in carbon fiber reinforced polymer (CFRP) is presented. It involves the use of the Impulse Excitation Technique (IET) and hysteresis loops to calculate the damping parameter of T700/NCT304-1 carbon/epoxy samples subjected to various low-velocity impact energies. The value of the coefficient of restitution (COR) is determined for each impact, ranging between 0.62 for the lowest impact energy to 0.48 for the highest one. The results reveal that a three-step increase in the damping parameter exists in all cases as the impact energy on the specimen increases. An abrupt jump in the damping parameter value is observed for impact energies exceeding ∼0.9 of the material's maximum capacity. Overall, at the highest impact energy equal to 3.65 J, the damping parameter increased by 43.3% compared to the pristine specimen. Additionally, two cases of cyclic tension-tension loading were applied to the specimens, with maximum stresses set at 150 MPa and 200 MPa. The measured values of plastic and elastic strain energy were used to determine the damping ratios. For both cases, the damping of the specimen subjected to the highest impact energy was ∼1.2 times greater than that of an intact specimen, with an increase pattern similar to the findings of the IET method. Optical microscope images of the specimens are provided to illustrate various damage modes observed in the composite materials.
本文介绍了一种检测碳纤维增强聚合物(CFRP)低速冲击损伤的方法。该方法采用脉冲激励技术(IET)和滞后环来计算受到各种低速冲击能量的 T700/NCT304-1 碳/环氧样品的阻尼参数。确定了每次冲击的恢复系数 (COR) 值,最低冲击能量为 0.62,最高冲击能量为 0.48。结果表明,随着试样受到的冲击能量的增加,阻尼参数在所有情况下都呈三段式增长。当冲击能量超过材料最大承载能力的 0.9 时,阻尼参数值会突然跃升。总体而言,在最高冲击能量为 3.65 J 时,阻尼参数比原始试样增加了 43.3%。此外,还对试样施加了两种循环拉伸负载,最大应力分别为 150 兆帕和 200 兆帕。塑性应变能和弹性应变能的测量值用于确定阻尼比。在这两种情况下,受到最高冲击能量的试样的阻尼都是完好试样的 1.2 倍,其增加模式与 IET 方法的结果类似。试样的光学显微镜图像说明了在复合材料中观察到的各种损坏模式。
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引用次数: 0
Ultimate bearing capacity analysis and bio-inspired optimization design of marine composite T-joint 海洋复合材料 T 型接头的极限承载能力分析和生物启发优化设计
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-12-28 DOI: 10.1177/00219983231224046
Wei Shen, Yuqiang Wang, Junliu Yang, Shuangxi Xu, Qin Dong
Sandwich composites are widely used in aviation, aerospace and marine engineering fields because of their excellent comprehensive properties. However, it is difficult to accurately predict the ultimate performance of sandwich composite structures because of their complex failure modes and uncoordinated damage processes. In this paper, the ultimate load, progressive failure process and failure mode of sandwich composite T-joints under three-point bending and lateral bending loads are predicted and verified by using an improved progressive damage analysis program. Moreover, the bio-inspired optimization of the composite T-joint is carried out, and the corner shape and material combination of the T-joint are designed and optimized based on the contour of the flange bone of the bird. The main factors affecting the bearing capacity of T-joint are further discussed, and a reasonable and feasible bio-inspired optimization scheme is obtained, which provides some reference for the design of marine composite T-joint.
三明治复合材料因其优异的综合性能而被广泛应用于航空、航天和海洋工程领域。然而,由于三明治复合材料结构的失效模式复杂,破坏过程不协调,因此很难准确预测其极限性能。本文利用改进的渐进破坏分析程序,预测并验证了夹层复合材料 T 型接头在三点弯曲和横向弯曲载荷作用下的极限载荷、渐进破坏过程和破坏模式。此外,还对复合材料 T 型接头进行了生物启发优化,根据鸟类翼缘骨的轮廓设计并优化了 T 型接头的角形和材料组合。进一步讨论了影响 T 型接头承载能力的主要因素,得到了合理可行的生物启发优化方案,为海洋复合材料 T 型接头的设计提供了一定的参考。
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引用次数: 0
Reducing delamination risk with response surface methodology-supported drilling analysis for Nomex® aramid fiber composites 利用响应面方法支持的钻孔分析降低 Nomex® 芳纶纤维复合材料的分层风险
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-12-26 DOI: 10.1177/00219983231224113
Eser Yarar
This article presents a comprehensive experimental investigation into the drilling behavior of Nomex®, a type of aramid fiber. The study specifically examines the impact of various cutting parameters and drill bit types on drilling outcomes. While Nomex® offers many advantages, difficult chip evacuation during drilling of aramid fiber composites can lead to surface defects and delamination. The research aims to explore how drilling parameters—such as spindle speed, feed rate—and four distinct drill bit types affect drilling performance. The analysis encompasses factors such as thrust force, torque, and surface roughness, studied under different drilling conditions and with various drill bit types. Moreover, the research assesses peeling and push-out delamination factors to gain insights into drill bit and coating characteristics. An examination of burr and chipping further enhances the comprehension of drilling performance. To determine the most effective drilling conditions, the study employs multi-response optimization. The optimal drilling performance is achieved with a combination of a 0.1 mm/rev feed rate, 1402.82 r/min spindle speed, and HSS-TiN drill type. This configuration successfully integrates responses, resulting in a composite desirability value of 0.95.
本文对芳纶纤维 Nomex® 的钻孔行为进行了全面的实验研究。研究特别考察了各种切削参数和钻头类型对钻孔结果的影响。虽然 Nomex® 具有许多优点,但在芳纶纤维复合材料钻孔过程中,排屑困难会导致表面缺陷和分层。这项研究旨在探索钻孔参数(如主轴转速、进给速度)和四种不同的钻头类型如何影响钻孔性能。分析包括推力、扭矩和表面粗糙度等因素,在不同的钻孔条件下使用不同类型的钻头进行研究。此外,研究还评估了剥离和推出分层因素,以深入了解钻头和涂层的特性。对毛刺和崩角的研究进一步加深了对钻孔性能的理解。为了确定最有效的钻孔条件,研究采用了多响应优化方法。0.1 mm/rev 进给速度、1402.82 r/min 主轴转速和 HSS-TiN 钻头类型的组合实现了最佳钻孔性能。这一配置成功地整合了各种响应,使综合可取值达到 0.95。
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引用次数: 0
Mode Ⅰ–Governed fracture energy and maximum normal traction of a CFRP rod CFRP 杆件的模式Ⅰ控制断裂能和最大法向牵引力
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-12-26 DOI: 10.1177/00219983231224112
Yuta Tobata, K. Naito, Jonathon D. Tanks
This study develops a double cantilever beam test by using a specific fixture for measuring the representative critical energy release rate of rigid composite rods. Carbon fiber reinforced epoxy composite rod was used for the evaluation. Finite element analysis applying Cohesive Zone Model was used to estimate the relationship between load and displacement. In addition, for verifying the effect of specimen width on the measurement, the representative critical energy release rate was estimated and compared with reference to the crack length measured from the center or outer tip of the crack. The numerical results showed close value to that of experiment. This suggests that an effective representative critical energy release rate can be measured by the proposed method.
本研究利用特定的夹具开发了一种双悬臂梁试验,用于测量刚性复合材料杆的代表性临界能量释放率。碳纤维增强环氧树脂复合材料杆被用于评估。采用内聚区模型进行有限元分析,以估算荷载和位移之间的关系。此外,为了验证试样宽度对测量结果的影响,还估算了具有代表性的临界能量释放率,并与从裂纹中心或外端点测量的裂纹长度进行了比较。数值结果显示与实验值接近。这表明,所提出的方法可以测量出有效的代表性临界能量释放率。
{"title":"Mode Ⅰ–Governed fracture energy and maximum normal traction of a CFRP rod","authors":"Yuta Tobata, K. Naito, Jonathon D. Tanks","doi":"10.1177/00219983231224112","DOIUrl":"https://doi.org/10.1177/00219983231224112","url":null,"abstract":"This study develops a double cantilever beam test by using a specific fixture for measuring the representative critical energy release rate of rigid composite rods. Carbon fiber reinforced epoxy composite rod was used for the evaluation. Finite element analysis applying Cohesive Zone Model was used to estimate the relationship between load and displacement. In addition, for verifying the effect of specimen width on the measurement, the representative critical energy release rate was estimated and compared with reference to the crack length measured from the center or outer tip of the crack. The numerical results showed close value to that of experiment. This suggests that an effective representative critical energy release rate can be measured by the proposed method.","PeriodicalId":15489,"journal":{"name":"Journal of Composite Materials","volume":"46 5","pages":""},"PeriodicalIF":2.9,"publicationDate":"2023-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139155087","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Progressive damage analysis for fatigue life prediction in plain weave composites: A multi-scale approach 用于平织复合材料疲劳寿命预测的渐进损伤分析:多尺度方法
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-12-26 DOI: 10.1177/00219983231218783
Amir Mohammad Ghanavaty, R. Mosalmani, Mohammad Shishesaz
This study introduces an analytical micromechanical model considering progressive damage designed to predict the elastic and strength properties of plain weave composites subjected to fatigue loading. The presented model is composed of a multi-scale micromechanical model, wherein a progressive damage mechanism has been incorporated. During the development of this multi-scale micromechanical model, a representative volume element was chosen and homogenized, utilizing assumptions pertaining to identical out-of-plane stresses and in-plane strains. These assumptions satisfy the conditions of equilibrium and displacement continuity in the representative volume element and, through a three-step process, enhance the model’s accuracy in applying the damage model and predicting the elastic properties of plain weave composites under static loading. Subsequently, the damage mechanism was progressively developed by accounting for the crucial role of matrix crack growth. This was achieved by employing the kinetic theory of fracture for polymers and integrating it with the multi-scale micromechanical model. Ultimately, the elastic and strength properties of plain weave composites under fatigue loading were predicted. A comparison of the results derived from the present model with those available in the literature demonstrated a high degree of agreement.
本研究介绍了一种考虑渐进损伤的微观力学分析模型,旨在预测平纹复合材料在疲劳载荷作用下的弹性和强度特性。该模型由一个多尺度微观力学模型组成,其中纳入了渐进损伤机制。在这一多尺度微观力学模型的开发过程中,利用与相同的面外应力和面内应变有关的假设,选择了具有代表性的体积元素并对其进行了均匀化处理。这些假设满足了代表性体积元素的平衡和位移连续性条件,并通过三步流程提高了模型在应用损伤模型和预测平织复合材料在静态加载下的弹性性能方面的准确性。随后,通过考虑基体裂纹生长的关键作用,逐步建立了损伤机理。为此,采用了聚合物断裂动力学理论,并将其与多尺度微观力学模型相结合。最终,预测了平纹编织复合材料在疲劳加载下的弹性和强度特性。将本模型得出的结果与文献中的结果进行比较,结果显示两者高度一致。
{"title":"Progressive damage analysis for fatigue life prediction in plain weave composites: A multi-scale approach","authors":"Amir Mohammad Ghanavaty, R. Mosalmani, Mohammad Shishesaz","doi":"10.1177/00219983231218783","DOIUrl":"https://doi.org/10.1177/00219983231218783","url":null,"abstract":"This study introduces an analytical micromechanical model considering progressive damage designed to predict the elastic and strength properties of plain weave composites subjected to fatigue loading. The presented model is composed of a multi-scale micromechanical model, wherein a progressive damage mechanism has been incorporated. During the development of this multi-scale micromechanical model, a representative volume element was chosen and homogenized, utilizing assumptions pertaining to identical out-of-plane stresses and in-plane strains. These assumptions satisfy the conditions of equilibrium and displacement continuity in the representative volume element and, through a three-step process, enhance the model’s accuracy in applying the damage model and predicting the elastic properties of plain weave composites under static loading. Subsequently, the damage mechanism was progressively developed by accounting for the crucial role of matrix crack growth. This was achieved by employing the kinetic theory of fracture for polymers and integrating it with the multi-scale micromechanical model. Ultimately, the elastic and strength properties of plain weave composites under fatigue loading were predicted. A comparison of the results derived from the present model with those available in the literature demonstrated a high degree of agreement.","PeriodicalId":15489,"journal":{"name":"Journal of Composite Materials","volume":"73 3","pages":""},"PeriodicalIF":2.9,"publicationDate":"2023-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139157173","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A numerical and experimental identification of crystallinity gradients in carbon fiber reinforced thermoplastic composites obtained by laser assisted filament winding 通过激光辅助绕丝获得的碳纤维增强热塑性复合材料结晶度梯度的数值和实验鉴定
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-12-22 DOI: 10.1177/00219983231223568
Anna Maria El Bayssari, M. Péron, Anaïs Barasinski, F. Jacquemin, Federica Daghia, Damien Guillon
The presence of temperature and crystallinity gradients in carbon fiber–reinforced PolyEtherEtherKetone (PEEK) composite laminates, produced via laser-assisted tape placement, is investigated in this paper. The manufacturing process takes place with high deposition speed and using localized laser source for heating, therefore enhancing the formation of temperature and crystallinity gradients through the laminate thickness. A previously validated thermal model coupled with a non-isothermal crystallinity model and a fusion model are used to simulate the temperature and crystallinity distributions through the laminate thickness. The results from the model are correlated with Dynamic Mechanical Analysis (DMA) tests and Differential Scanning Calorimetry (DSC) tests since a crystallinity gradient is difficult to monitor experimentally. The simulated gradients suggested the presence of an amorphous layer between two consecutive plies and an increase in the crystallinity through the material’s thickness. This observation is correlated with the behavior reported for the semi-crystalline laminates during the DMA test, where the modulus drops abruptly during the glass transition, a typical behavior for an amorphous material.
本文研究了碳纤维增强聚醚醚酮(PEEK)复合材料层压板中存在的温度梯度和结晶度梯度,该层压板是通过激光辅助胶带贴装工艺生产的。制造过程采用高速沉积,并使用局部激光源进行加热,因此在层压板厚度上形成的温度梯度和结晶度梯度更大。本文使用先前验证过的热模型、非等温结晶度模型和熔融模型来模拟层压板厚度上的温度和结晶度分布。由于结晶度梯度难以通过实验进行监测,因此该模型的结果与动态机械分析(DMA)测试和差示扫描量热仪(DSC)测试相关联。模拟梯度表明,在两个连续的层之间存在一个无定形层,结晶度随着材料厚度的增加而增加。这一观察结果与 DMA 测试中报告的半结晶层压板的行为相关,即模量在玻璃化转变过程中突然下降,这是无定形材料的典型行为。
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引用次数: 0
Assessment of vegetable fiber-matrix adhesion and durability, in cement-based and polymer-based composite: Principles from literature review 评估水泥基和聚合物基复合材料中植物纤维与基质的粘附性和耐久性:文献综述的原理
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-12-22 DOI: 10.1177/00219983231220729
Ashley Closse, Cristel Onesippe Potiron, M. Arsene, K. Bilba
This paper presents some principles of research done on the assessment of fiber-matrix adhesion and durability in cement-based and polymer-based composites reinforced with vegetable fibers. Natural vegetable fibers are light, biodegradable and low-cost; however, their compatibility with both matrices - which are generally hydrophobic- is poor, because of their hydrophilic character. This review presents the different strategies proposed in literature to improve (1) interfacial bonding between matrix and fibers and (2) sustainability of composite materials reinforced by vegetable fibers. In order to achieve these goals, searchers investigate chemical or/and physical treatments of fibers and/or matrix modification of composites materials. The impacts of these strategies are followed in terms of mechanical properties, thermal properties, morphology and water absorption of the composite materials. Authors proposed to focus on the influence of aging on these characteristics in order to estimate durability.
本文介绍了在用植物纤维增强的水泥基复合材料和聚合物基复合材料中评估纤维与基体的粘附性和耐久性的一些研究原则。天然植物纤维质轻、可生物降解且成本低廉,但由于其亲水性,与这两种基质(通常为疏水性基质)的兼容性较差。本综述介绍了文献中提出的不同策略,以改善(1)基体与纤维之间的界面粘合;(2)植物纤维增强复合材料的可持续性。为了实现这些目标,研究人员对纤维进行了化学或/和物理处理,以及/或对复合材料的基体进行了改性。这些策略对复合材料的机械性能、热性能、形态和吸水性产生了影响。作者建议重点研究老化对这些特性的影响,以评估耐久性。
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引用次数: 0
A comparative study on the influence of fiber enzymatic treatment in thermal, morphological and mechanical properties of PBS matrix reinforced with different date palm fibers: Under accelerated UV radiation exposure 纤维酶解处理对使用不同枣椰纤维增强的 PBS 基质的热性能、形态和机械性能影响的比较研究:加速紫外线辐射条件下
IF 2.9 3区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES Pub Date : 2023-12-21 DOI: 10.1177/00219983231223821
Rania Chaari, M. Khlif, C. Bradai, C. Lacoste, Philippe Dony
The use of natural fiber-reinforced polymer materials has become increasingly common in various applications. However, the performance and durability of these composites in outdoor applications are not fully understood. Therefore, the objective of this study is to investigate the impact of an artificial ultraviolet radiation on the degradation behavior of composites based on a Poly Butylene Succinate (PBS) matrix. The reinforcement materials used in this research were the trunk and palm fibers obtained from date palm trees. Specifically, the effect of modifying the fiber surface with an enzymatic treatment on the interfacial adhesion fiber/matrix as well as on the rate of deterioration of the resulted composites, under accelerated aging, was assessed. Changes in the composite’s thermal stability, surface morphology and mechanical properties were determined after aging. A sharp transition in the behavior of the PBS matrix was observed after UV exposure, shifting from slight ductility following 100 h to brittleness after 700 h. The aging process resulted in a decrease in the thermal stability of all composites. However, the composites containing treated fibers exhibited better thermal stability compared to those with untreated fibers. Additionally, the use of enzyme-treated fibers in the composites promoted greater stability in the mechanical properties even after aging. The reinforcement of the composites with palm fibers yielded better interfacial adhesion compared to the use of trunk fibers, and resulted in better retention in the tensile strength property after aging. The enzymatic treatment facilitated stronger physical attachment between the fibers and the matrix, preventing any fiber or interface degradation.
天然纤维增强聚合物材料在各种应用中的使用越来越普遍。然而,人们对这些复合材料在户外应用中的性能和耐用性并不完全了解。因此,本研究旨在探讨人工紫外线辐射对基于聚丁二酸丁二醇酯(PBS)基质的复合材料降解行为的影响。本研究使用的增强材料是从椰枣树上获取的树干和棕榈纤维。具体来说,在加速老化条件下,评估了用酶处理方法改变纤维表面对纤维/基质界面粘附力的影响,以及对所得复合材料劣化率的影响。老化后,复合材料的热稳定性、表面形态和机械性能都发生了变化。紫外线照射后,PBS 基质的行为发生了急剧转变,从 100 小时后的轻微延展性转变为 700 小时后的脆性。不过,与含有未处理纤维的复合材料相比,含有经处理纤维的复合材料具有更好的热稳定性。此外,在复合材料中使用经酶处理的纤维,即使在老化后也能提高机械性能的稳定性。与使用树干纤维相比,用棕榈纤维增强复合材料能产生更好的界面粘附性,并能在老化后更好地保持拉伸强度特性。酶处理有助于加强纤维与基体之间的物理附着,防止纤维或界面降解。
{"title":"A comparative study on the influence of fiber enzymatic treatment in thermal, morphological and mechanical properties of PBS matrix reinforced with different date palm fibers: Under accelerated UV radiation exposure","authors":"Rania Chaari, M. Khlif, C. Bradai, C. Lacoste, Philippe Dony","doi":"10.1177/00219983231223821","DOIUrl":"https://doi.org/10.1177/00219983231223821","url":null,"abstract":"The use of natural fiber-reinforced polymer materials has become increasingly common in various applications. However, the performance and durability of these composites in outdoor applications are not fully understood. Therefore, the objective of this study is to investigate the impact of an artificial ultraviolet radiation on the degradation behavior of composites based on a Poly Butylene Succinate (PBS) matrix. The reinforcement materials used in this research were the trunk and palm fibers obtained from date palm trees. Specifically, the effect of modifying the fiber surface with an enzymatic treatment on the interfacial adhesion fiber/matrix as well as on the rate of deterioration of the resulted composites, under accelerated aging, was assessed. Changes in the composite’s thermal stability, surface morphology and mechanical properties were determined after aging. A sharp transition in the behavior of the PBS matrix was observed after UV exposure, shifting from slight ductility following 100 h to brittleness after 700 h. The aging process resulted in a decrease in the thermal stability of all composites. However, the composites containing treated fibers exhibited better thermal stability compared to those with untreated fibers. Additionally, the use of enzyme-treated fibers in the composites promoted greater stability in the mechanical properties even after aging. The reinforcement of the composites with palm fibers yielded better interfacial adhesion compared to the use of trunk fibers, and resulted in better retention in the tensile strength property after aging. The enzymatic treatment facilitated stronger physical attachment between the fibers and the matrix, preventing any fiber or interface degradation.","PeriodicalId":15489,"journal":{"name":"Journal of Composite Materials","volume":"67 5","pages":""},"PeriodicalIF":2.9,"publicationDate":"2023-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138951348","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Journal of Composite Materials
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