This study investigates the shelf life of nitrile butadiene rubber (NBR) based on age and temperature factors. Natural aging of nitrile butadiene rubber samples is performed under laboratory conditions for 2 years, followed by thermogravimetric analysis to evaluate Arrhenius parameters. Toop’s equation is used to predict shelf life at 5% conversion rate. Model-free kinetic methods, including Ozawa-Flynn-Wall (OFW), Kissinger-Akahira-Sunose (KAS), and Kissinger, estimate shelf life at different temperatures for both virgin and naturally aged nitrile butadiene rubber. Results show close correlation between KAS and Kissinger methods, with slight variations in activation energy impacting shelf life. Fourier-transform infrared spectroscopy (FTIR) tests assess functional group changes with age. Virgin nitrile butadiene rubber activation energy: OFW-73.33 kJ/mol, KAS-68.43 kJ/mol. Aged nitrile butadiene rubber activation energy: OFW-72.57 kJ/mol, KAS-67.88 kJ/mol. Shelf life at 40°C: Virgin nitrile butadiene rubber - OFW-111.29 years, KAS-26.31 years. Aged nitrile butadiene rubber - OFW-89.01 years, KAS-22.37 years. These findings provide valuable insights for predicting and assessing nitrile butadiene rubber viscoelastic damper performance in engineering applications.
{"title":"Estimating shelf life and degradation mechanisms of nitrile butadiene rubber for viscoelastic dampers","authors":"Syam Prasad Ammineni, Dumpala Lingaraju, Cherukuri Nagaraju","doi":"10.1177/00952443241243378","DOIUrl":"https://doi.org/10.1177/00952443241243378","url":null,"abstract":"This study investigates the shelf life of nitrile butadiene rubber (NBR) based on age and temperature factors. Natural aging of nitrile butadiene rubber samples is performed under laboratory conditions for 2 years, followed by thermogravimetric analysis to evaluate Arrhenius parameters. Toop’s equation is used to predict shelf life at 5% conversion rate. Model-free kinetic methods, including Ozawa-Flynn-Wall (OFW), Kissinger-Akahira-Sunose (KAS), and Kissinger, estimate shelf life at different temperatures for both virgin and naturally aged nitrile butadiene rubber. Results show close correlation between KAS and Kissinger methods, with slight variations in activation energy impacting shelf life. Fourier-transform infrared spectroscopy (FTIR) tests assess functional group changes with age. Virgin nitrile butadiene rubber activation energy: OFW-73.33 kJ/mol, KAS-68.43 kJ/mol. Aged nitrile butadiene rubber activation energy: OFW-72.57 kJ/mol, KAS-67.88 kJ/mol. Shelf life at 40°C: Virgin nitrile butadiene rubber - OFW-111.29 years, KAS-26.31 years. Aged nitrile butadiene rubber - OFW-89.01 years, KAS-22.37 years. These findings provide valuable insights for predicting and assessing nitrile butadiene rubber viscoelastic damper performance in engineering applications.","PeriodicalId":15613,"journal":{"name":"Journal of Elastomers & Plastics","volume":"106 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140312686","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-18DOI: 10.1177/00952443241238451
Latifa Alimi, Kamel Chaoui
High Density Polyethylene (HDPE) is one attractive technical option for the transportation and distribution of natural gas and hydrocarbons given the advantages in long-term mechanical strength, lifespan, maintenance costs and resistance to chemical aging. This study investigates the compatibility of extruded pipe material from copolymerized HDPE-80 with DOT 3 brake fluid. Machined standard specimens from inner (IL) and outer (OL) pipe layers are aged in commercial synthetic polyglycol-based oil for 7 days at laboratory conditions. The percent mass changes are +2.2% and +1.9% respectively for IL and OL pipe surfaces. These results are in the same range of published sorption data for other oils and fuels. Stress-strain parameters (E, σ y, σ CD, σ f, ε y, Δ ε CD, ε f) and fracture work are established and thoroughly discussed for both pipe sides. For IL, the reduction of E, σ y and ε f are respectively 28.0%, 13.9% and 22.7%, while for OL they are 22.6%, 7.7% and 25.1%. Globally, it is concluded that strength properties degradation in DOT 3 oil is more important for IL compared to OL. There is an important loss of ductility for both pipe sides. Ageing caused IL crystallinity ( Xc) to increase while OL showed inverse results probably because of frozen anti-oxidants in the outer surface layers following water quenching during extrusion. Before and after ageing, the as-received OL is found to be more resilient to oxidation than corresponding IL, as higher OIT parameters are also shown in the case of crude oil compatibility investigations. DOT 3 brake oil seem to accelerate the degradation of HDPE-80 thermal stability with a higher intensity for IL.
鉴于高密度聚乙烯（HDPE）在长期机械强度、使用寿命、维护成本和耐化学老化方面的优势，它是运输和分配天然气和碳氢化合物的一种极具吸引力的技术选择。本研究调查了共聚 HDPE-80 挤压管材料与 DOT 3 制动液的兼容性。在实验室条件下，将管材内层（IL）和外层（OL）的机加工标准试样在商用合成聚乙二醇基油中老化 7 天。内层（IL）和外层（OL）管道表面的质量变化百分比分别为 +2.2% 和 +1.9%。这些结果与已公布的其他油类和燃料的吸附数据范围相同。建立了应力应变参数（E、σ y、σ CD、σ f、ε y、Δ ε CD、ε f）和断裂功，并对两侧管道进行了深入讨论。对于 IL，E、σ y 和 ε f 分别减少 28.0%、13.9% 和 22.7%，而对于 OL，则分别减少 22.6%、7.7% 和 25.1%。总的来说，DOT 3 油品中的强度性能退化对 IL 而言比对 OL 更为重要。两种管材的延展性都有显著下降。老化导致 IL 结晶度（Xc）增加，而 OL 则显示出相反的结果，这可能是因为挤压过程中水淬火后，外表层的抗氧化剂被冻结。在老化之前和之后，我们发现收到的 OL 比相应的 IL 更能抵抗氧化，因为在原油兼容性调查中也显示了更高的 OIT 参数。DOT 3 制动油似乎加速了 HDPE-80 热稳定性的降解，而 IL 的降解强度更高。
{"title":"Compatibility study of high density polyethylene grade 80 gas pipe with synthetic polyglycol-based brake oil","authors":"Latifa Alimi, Kamel Chaoui","doi":"10.1177/00952443241238451","DOIUrl":"https://doi.org/10.1177/00952443241238451","url":null,"abstract":"High Density Polyethylene (HDPE) is one attractive technical option for the transportation and distribution of natural gas and hydrocarbons given the advantages in long-term mechanical strength, lifespan, maintenance costs and resistance to chemical aging. This study investigates the compatibility of extruded pipe material from copolymerized HDPE-80 with DOT 3 brake fluid. Machined standard specimens from inner (IL) and outer (OL) pipe layers are aged in commercial synthetic polyglycol-based oil for 7 days at laboratory conditions. The percent mass changes are +2.2% and +1.9% respectively for IL and OL pipe surfaces. These results are in the same range of published sorption data for other oils and fuels. Stress-strain parameters (E, σ<jats:sub> y</jats:sub>, σ<jats:sub> CD</jats:sub>, σ<jats:sub> f</jats:sub>, ε<jats:sub> y</jats:sub>, Δ ε<jats:sub> CD</jats:sub>, ε<jats:sub> f</jats:sub>) and fracture work are established and thoroughly discussed for both pipe sides. For IL, the reduction of E, σ<jats:sub> y</jats:sub> and ε<jats:sub> f</jats:sub> are respectively 28.0%, 13.9% and 22.7%, while for OL they are 22.6%, 7.7% and 25.1%. Globally, it is concluded that strength properties degradation in DOT 3 oil is more important for IL compared to OL. There is an important loss of ductility for both pipe sides. Ageing caused IL crystallinity ( X<jats:sub>c</jats:sub>) to increase while OL showed inverse results probably because of frozen anti-oxidants in the outer surface layers following water quenching during extrusion. Before and after ageing, the as-received OL is found to be more resilient to oxidation than corresponding IL, as higher OIT parameters are also shown in the case of crude oil compatibility investigations. DOT 3 brake oil seem to accelerate the degradation of HDPE-80 thermal stability with a higher intensity for IL.","PeriodicalId":15613,"journal":{"name":"Journal of Elastomers & Plastics","volume":"2014 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140170532","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The increasing advancements in science and technology have led to a growing demand for wearable products. In this paper, copper sulfide/melamine foam composites were prepared by chemical deposition of copper sulfide on the melamine foam skeleton. The effects of different deposition amount of copper sulfide on its microstructure, and electrical conductivity were studied. The results showed that the composite had good electrical conductivity and flexibility when the reaction solution concentration was 1 wt.%. The material can be used as an electric heater, the surface of the material can be heated to 145°C under the low voltage of 4 V, and the material can also be used as a flexible pressure sensor with a high sensitivity of 0.385 kPa−1 and a stability of more than 2000 cycles. Materials based on flexible copper sulfide/melamine foams can be used for electric heaters and flexible pressure sensor, which will make them promising applications in wearable products.
{"title":"Flexible highly conductive melamine foam/copper sulfide has both electrical heating and pressure sensing properties","authors":"Jiarui Zhao, Wei Pan, Mingli Jiao, Chaohua Su, Jintao Zhang, Yu Qi","doi":"10.1177/00952443241240076","DOIUrl":"https://doi.org/10.1177/00952443241240076","url":null,"abstract":"The increasing advancements in science and technology have led to a growing demand for wearable products. In this paper, copper sulfide/melamine foam composites were prepared by chemical deposition of copper sulfide on the melamine foam skeleton. The effects of different deposition amount of copper sulfide on its microstructure, and electrical conductivity were studied. The results showed that the composite had good electrical conductivity and flexibility when the reaction solution concentration was 1 wt.%. The material can be used as an electric heater, the surface of the material can be heated to 145°C under the low voltage of 4 V, and the material can also be used as a flexible pressure sensor with a high sensitivity of 0.385 kPa<jats:sup>−1</jats:sup> and a stability of more than 2000 cycles. Materials based on flexible copper sulfide/melamine foams can be used for electric heaters and flexible pressure sensor, which will make them promising applications in wearable products.","PeriodicalId":15613,"journal":{"name":"Journal of Elastomers & Plastics","volume":"6 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140148318","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-03-06DOI: 10.1177/00952443241238235
İbrahim Şen, Murat Eroğlu, Olcay Severgün, Demet Kızıl
This study aims to develop sustainable, renewable and biodegradable biocomposite films from environmentally friendly materials. For this purpose, completely biodegradable polymer composites were prepared by mixing polylactic acid (PLA) with a new source, quince peel (QP), by solvent casting method, and their structural, mechanical and thermal properties were examined. The tensile strengths of the composites prepared using QP in proportions varying between 5% (P5Q) and 30% (P30Q) by weight vary between 21.13 ± 0.80 and 12.01 ± 0.10 MPa, and their elongations at break vary between 11.33 ± 0.38 and 4.08 ± 1.06 %. As the QP contribution increased, the tensile strength and breaking elongation of these composites generally decreased, while the elastic modulus also increased. Among these composites, whose elastic modulus varies between 1040.00 ± 140.01 and 811.33 ± 13.31 MPa, it was determined that the elastic modulus (1040.00 ± 140.01 MPa) of the 20% QP added composite (P20Q) was higher than the others. When the thermal analysis of PLA/QP films were examined, it was observed that the glass transition temperatures (Tg) were between 58.54 and 51.45°C and the melting temperatures (Tm) were between 167.71 and 164.28°C, and these temperatures generally decreased with increasing QP doping. When the T50 values, which represent the temperature at which 50% of the composite materials decompose, were examined, it was found that the QP-added ones were higher than the pure composites. While this value was 317.96°C in pure PLA composite, T50 values varied between 327.92 and 340.80°C depending on the varying QP ratios. According to the XRD results performed to evaluate the crystalline properties of PLA composites containing quince bark, the crystallinity of pure PLA was determined as 19.5% and the crystallinity of composites containing 5, 10, 20 and 30 wt % QP additives was determined as 19.3, 18.3, 16.4 and 14.6%, respectively.
{"title":"Ecofriendly quince peel powder incorporated Polylactic acid biocomposite film","authors":"İbrahim Şen, Murat Eroğlu, Olcay Severgün, Demet Kızıl","doi":"10.1177/00952443241238235","DOIUrl":"https://doi.org/10.1177/00952443241238235","url":null,"abstract":"This study aims to develop sustainable, renewable and biodegradable biocomposite films from environmentally friendly materials. For this purpose, completely biodegradable polymer composites were prepared by mixing polylactic acid (PLA) with a new source, quince peel (QP), by solvent casting method, and their structural, mechanical and thermal properties were examined. The tensile strengths of the composites prepared using QP in proportions varying between 5% (P5Q) and 30% (P30Q) by weight vary between 21.13 ± 0.80 and 12.01 ± 0.10 MPa, and their elongations at break vary between 11.33 ± 0.38 and 4.08 ± 1.06 %. As the QP contribution increased, the tensile strength and breaking elongation of these composites generally decreased, while the elastic modulus also increased. Among these composites, whose elastic modulus varies between 1040.00 ± 140.01 and 811.33 ± 13.31 MPa, it was determined that the elastic modulus (1040.00 ± 140.01 MPa) of the 20% QP added composite (P20Q) was higher than the others. When the thermal analysis of PLA/QP films were examined, it was observed that the glass transition temperatures (Tg) were between 58.54 and 51.45°C and the melting temperatures (Tm) were between 167.71 and 164.28°C, and these temperatures generally decreased with increasing QP doping. When the T50 values, which represent the temperature at which 50% of the composite materials decompose, were examined, it was found that the QP-added ones were higher than the pure composites. While this value was 317.96°C in pure PLA composite, T50 values varied between 327.92 and 340.80°C depending on the varying QP ratios. According to the XRD results performed to evaluate the crystalline properties of PLA composites containing quince bark, the crystallinity of pure PLA was determined as 19.5% and the crystallinity of composites containing 5, 10, 20 and 30 wt % QP additives was determined as 19.3, 18.3, 16.4 and 14.6%, respectively.","PeriodicalId":15613,"journal":{"name":"Journal of Elastomers & Plastics","volume":"2 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140055805","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-02-27DOI: 10.1177/00952443241235377
Lijun Chen, Shusen Cao
The metal cross-linking fluorinated polyacrylate colloid has a high cross-linking density, high transparency, high heat resistance and hydrophobicity. In this paper, the metal cross-linking fluorinated polyacrylate colloid is synthesized via the semi-continuous seeded emulsion polymerization technology, which uses the self-made magnesium acrylate, calcium acrylate and zinc acrylate as metal crosslinker and dodecafluoroheptyl methacrylate as a fluorine monomer. In this study, the ablation effect of the metal ions is weakened by the increased amount of environmentally friendly and polymerizable anion emulsifier DNS-86. The demulsification phenomenon of emulsion is successfully overcome through destroying the double layer structure of micelles or colloid particles by polyvalent metal ions. The colloidal particle size is smaller and the particle size distribution of the colloid is more uniform. Colloidal film has a good hydrophobicity and the glass transition temperature and the thermal decomposition temperature are high.
{"title":"Chemical, thermal and film properties of metal cross-linking fluorinated polyacrylate colloid prepared via semi-continuous seeded emulsion polymerization","authors":"Lijun Chen, Shusen Cao","doi":"10.1177/00952443241235377","DOIUrl":"https://doi.org/10.1177/00952443241235377","url":null,"abstract":"The metal cross-linking fluorinated polyacrylate colloid has a high cross-linking density, high transparency, high heat resistance and hydrophobicity. In this paper, the metal cross-linking fluorinated polyacrylate colloid is synthesized via the semi-continuous seeded emulsion polymerization technology, which uses the self-made magnesium acrylate, calcium acrylate and zinc acrylate as metal crosslinker and dodecafluoroheptyl methacrylate as a fluorine monomer. In this study, the ablation effect of the metal ions is weakened by the increased amount of environmentally friendly and polymerizable anion emulsifier DNS-86. The demulsification phenomenon of emulsion is successfully overcome through destroying the double layer structure of micelles or colloid particles by polyvalent metal ions. The colloidal particle size is smaller and the particle size distribution of the colloid is more uniform. Colloidal film has a good hydrophobicity and the glass transition temperature and the thermal decomposition temperature are high.","PeriodicalId":15613,"journal":{"name":"Journal of Elastomers & Plastics","volume":"68 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140010874","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Okra hessian cloth-reinforced high-density polyethylene (HDPE) thermoplastic composites were prepared and characterized with both raw and alkali-treated fibers. The fiber contents were optimized for both the raw Okra thermoplastic composites and the alkali-treated Okra thermoplastic composites, and the optimum value of fiber content was 55 wt%. Samples that were alkali-treated and had 55 wt% fibers were subsequently exposed to gamma radiation at doses of 2.5, 5, and 7.5 kGy. Only the sample subjected to 5 kGy showed improved performance. Treated composites exhibited higher crystallinities than the untreated samples as observed by X-Ray diffraction analysis. The rupture surface micrographs of the composites exposed to 5 kGy gamma radiation revealed more compact than others. By using Fourier transform infrared spectroscopy analysis of composites, it was found that 5 kGy dose sample showed enhanced cross-linking between Okra fibers and HDPE matrix. The irradiated composite showed less water intake than the alkali-treated samples. Composites subjected to 5 kGy gamma rays showed improved tensile strength and Young’s modulus of values 66 MPa and 1925 MPa, respectively. Compared to raw and treated composites, the irradiated composites with a radiation dose of 5 kGy showed improved structural, mechanical, and thermal properties.
{"title":"The impact of chemical treatment and gamma-ray irradiation on the okra hessian cloth reinforced high-density polyethylene composites","authors":"Mohammed Hossan Shahid Shohrawardy, Md Forhad Mina, AKM Moshiul Alam, Ruhul Amin Khan","doi":"10.1177/00952443241236913","DOIUrl":"https://doi.org/10.1177/00952443241236913","url":null,"abstract":"Okra hessian cloth-reinforced high-density polyethylene (HDPE) thermoplastic composites were prepared and characterized with both raw and alkali-treated fibers. The fiber contents were optimized for both the raw Okra thermoplastic composites and the alkali-treated Okra thermoplastic composites, and the optimum value of fiber content was 55 wt%. Samples that were alkali-treated and had 55 wt% fibers were subsequently exposed to gamma radiation at doses of 2.5, 5, and 7.5 kGy. Only the sample subjected to 5 kGy showed improved performance. Treated composites exhibited higher crystallinities than the untreated samples as observed by X-Ray diffraction analysis. The rupture surface micrographs of the composites exposed to 5 kGy gamma radiation revealed more compact than others. By using Fourier transform infrared spectroscopy analysis of composites, it was found that 5 kGy dose sample showed enhanced cross-linking between Okra fibers and HDPE matrix. The irradiated composite showed less water intake than the alkali-treated samples. Composites subjected to 5 kGy gamma rays showed improved tensile strength and Young’s modulus of values 66 MPa and 1925 MPa, respectively. Compared to raw and treated composites, the irradiated composites with a radiation dose of 5 kGy showed improved structural, mechanical, and thermal properties.","PeriodicalId":15613,"journal":{"name":"Journal of Elastomers & Plastics","volume":"137 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139977679","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-02-23DOI: 10.1177/00952443241236912
Fernanda Menezes, Fabio Roberto Passador, Sandra Aparecida Coelho de Mello
Nitrile rubber (NBR) is widely used in the automotive, aerospace, and chemical sectors due to its resistance to fuels, oil, thermal aging, and fatigue. A typical NBR compound is prepared with several components that are added to obtain a product to meet specific industry requirements. Plasticizer is one of the main components used in NBR compounds. Typically, phthalates like DBP (dibutyl phthalate) or DOP (dioctyl phthalate) are used for NBR plasticization. However, these phthalates-based plasticizers are associated with toxicity and often prohibited by international regulatory standards. In this way, in the pursuit of a non-toxic NBR compound, the use of phthalate-free plasticizer, namely dioctyl terephthalate (DOTP), has been proposed. In this work, NBR compounds with DOTP, DBP, or DOP were processed in an open mill and vulcanized in hydraulic press. The unvulcanized samples were tested in a moving die rheometer (MDR). Subsequently, thermal, mechanical, and aging analyses were conducted for the vulcanized samples. The lowest torque observed in the rheometric curve, the displacement value of glass transition temperature (Tg), the smaller Shore A hardness, and the high elongation at break indicate that the addition of DOTP results in higher plasticization. The better-aging properties indicate lower migration of the DOTP plasticizer. Thus, the use of DOTP as a plasticizer holds promise as a viable alternative to replace the phthalates-based plasticizer in NBR compounds.
{"title":"Effect of phthalate-free plasticizer addition on thermal, mechanical, and aging properties of nitrile rubber (NBR)","authors":"Fernanda Menezes, Fabio Roberto Passador, Sandra Aparecida Coelho de Mello","doi":"10.1177/00952443241236912","DOIUrl":"https://doi.org/10.1177/00952443241236912","url":null,"abstract":"Nitrile rubber (NBR) is widely used in the automotive, aerospace, and chemical sectors due to its resistance to fuels, oil, thermal aging, and fatigue. A typical NBR compound is prepared with several components that are added to obtain a product to meet specific industry requirements. Plasticizer is one of the main components used in NBR compounds. Typically, phthalates like DBP (dibutyl phthalate) or DOP (dioctyl phthalate) are used for NBR plasticization. However, these phthalates-based plasticizers are associated with toxicity and often prohibited by international regulatory standards. In this way, in the pursuit of a non-toxic NBR compound, the use of phthalate-free plasticizer, namely dioctyl terephthalate (DOTP), has been proposed. In this work, NBR compounds with DOTP, DBP, or DOP were processed in an open mill and vulcanized in hydraulic press. The unvulcanized samples were tested in a moving die rheometer (MDR). Subsequently, thermal, mechanical, and aging analyses were conducted for the vulcanized samples. The lowest torque observed in the rheometric curve, the displacement value of glass transition temperature (T<jats:sub>g</jats:sub>), the smaller Shore A hardness, and the high elongation at break indicate that the addition of DOTP results in higher plasticization. The better-aging properties indicate lower migration of the DOTP plasticizer. Thus, the use of DOTP as a plasticizer holds promise as a viable alternative to replace the phthalates-based plasticizer in NBR compounds.","PeriodicalId":15613,"journal":{"name":"Journal of Elastomers & Plastics","volume":"36 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-02-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139956004","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-02-22DOI: 10.1177/00952443241236915
Sinan Şen, Melek Irmak Cengiz, Emre Tekay
In this study, high impact polystyrene (HIPS) materials was prepared by using a styrenic elastomer (10, 20, 30 wt%) and carbon nanotube (CNT) (3, 5, 7, 10 phr) by melt blending technique as alternative to commercial HIPS including polybutadiene rubber. The poly (styrene- b-isobutylene- b-styrene) (SIBS) was used as thermoplastic elastomer with polystyrene (PS) to improve its poor impact resistance and CNT was added to PS/SIBS blend matrix to maintain its strength and stiffness. The modulus, tensile strength and toughness values of the blends decreased while those of impact resistance increased in comparison to neat PS. The impact strength of PS20SIBS blend containing 20 wt% SIBS was found to be approximately 530% higher than pure PS. The nanocomposites of the PS20SIBS exhibited a decrease in the size of SIBS particles with increasing CNT compared to PS20SIBS. This was ascribed to the increased viscosity of PS matrix via CNT filler, preventing the coalescence of the elastomer domains. Compared to the PS20SIS, its nanocomposites showed higher strength, modulus and toughness, but lower impact strength. The toughness of the nanocomposite containing 5 phr CNT (PS20SIBS-5CNT), increased by 117% while its creep deformation decreased by approximately 40%, in comparison with PS20SIBS blend. Although PS20SIBS-5CNT exhibited lower impact strength than the PS20SIBS blend due to the dispersion of smaller SIBS particles in the PS matrix, it still increased the impact strength of pure PS by 188%. The PS20SIBS-5CNT nanocomposite, which improved impact strength and creep resistance with optimal toughness and tensile modulus can be used as a novel HIPS material that tunes the hardness-toughness/impact balance effectively. Moreover, the same nanocomposite was found to reach the conductivity threshold by exhibiting 106 times lower electrical resistance in comparison with that containing 3 phr CNT, leading to a conductive filer network with 5 phr loading of the nanotubes into the system.
{"title":"Thermal, mechanical, electrical properties of poystyrene/poly (styrene-b-isobutylene-b-styrene/carbon nanotube nanocomposites","authors":"Sinan Şen, Melek Irmak Cengiz, Emre Tekay","doi":"10.1177/00952443241236915","DOIUrl":"https://doi.org/10.1177/00952443241236915","url":null,"abstract":"In this study, high impact polystyrene (HIPS) materials was prepared by using a styrenic elastomer (10, 20, 30 wt%) and carbon nanotube (CNT) (3, 5, 7, 10 phr) by melt blending technique as alternative to commercial HIPS including polybutadiene rubber. The poly (styrene- b-isobutylene- b-styrene) (SIBS) was used as thermoplastic elastomer with polystyrene (PS) to improve its poor impact resistance and CNT was added to PS/SIBS blend matrix to maintain its strength and stiffness. The modulus, tensile strength and toughness values of the blends decreased while those of impact resistance increased in comparison to neat PS. The impact strength of PS20SIBS blend containing 20 wt% SIBS was found to be approximately 530% higher than pure PS. The nanocomposites of the PS20SIBS exhibited a decrease in the size of SIBS particles with increasing CNT compared to PS20SIBS. This was ascribed to the increased viscosity of PS matrix via CNT filler, preventing the coalescence of the elastomer domains. Compared to the PS20SIS, its nanocomposites showed higher strength, modulus and toughness, but lower impact strength. The toughness of the nanocomposite containing 5 phr CNT (PS20SIBS-5CNT), increased by 117% while its creep deformation decreased by approximately 40%, in comparison with PS20SIBS blend. Although PS20SIBS-5CNT exhibited lower impact strength than the PS20SIBS blend due to the dispersion of smaller SIBS particles in the PS matrix, it still increased the impact strength of pure PS by 188%. The PS20SIBS-5CNT nanocomposite, which improved impact strength and creep resistance with optimal toughness and tensile modulus can be used as a novel HIPS material that tunes the hardness-toughness/impact balance effectively. Moreover, the same nanocomposite was found to reach the conductivity threshold by exhibiting 10<jats:sup>6</jats:sup> times lower electrical resistance in comparison with that containing 3 phr CNT, leading to a conductive filer network with 5 phr loading of the nanotubes into the system.","PeriodicalId":15613,"journal":{"name":"Journal of Elastomers & Plastics","volume":"35 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-02-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139955638","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-08-18DOI: 10.1177/00952443231196279
Yuchun Kuang, Peng Fan, Z. Dong, Yiwei Han, Wei Lin
For the totally incompressible Yeoh (i.e., classic Yeoh) model predicts the equibiaxial tension (ET) stress lower, this paper proposes the totally incompressible Yeoh-Revised model to improve the prediction of ET stress. First, the fitting expression of the totally incompressible Yeoh-Revised constitutive model was derived under the presumption that fluororubber (FPM) and hydrogenated nitrile-butadiene rubber (HNBR) are isotropic and entirely incompressible. Meanwhile, the goodness-of-fit (R^2) statistic was used to assess the fitting outcomes of the three tension tests data (e.g., single tension (ST), ET and planar tension (PT)). Additionally, in order to fit the rubber materials tensile test data more accurately, we suggest a novel hyperelastic constitutive fitting method that takes into account the volume microscopic compressibility of rubber materials. The findings demonstrate that the totally incompressible Yeoh-Revised model's prediction of ET stress has marginally improved which neglecting the rubber materials’ volume microcompressibility, while the almost incompressible Yeoh-Revised model fits the ET stress significantly and accurately, and also enhances the forecast accuracy of overall R^2. Finally, the fitting formula of the almost incompressible constitutive model may be reduced to that of the totally incompressible model if the volume microcompressibility is disregarded, which is beneficial to more accurately forecast the experiment tests of rubber materials tension.
{"title":"Research on Yeoh-Revised hyperelastic constitutive model considering the volume almost incompressible premise for rubber materials","authors":"Yuchun Kuang, Peng Fan, Z. Dong, Yiwei Han, Wei Lin","doi":"10.1177/00952443231196279","DOIUrl":"https://doi.org/10.1177/00952443231196279","url":null,"abstract":"For the totally incompressible Yeoh (i.e., classic Yeoh) model predicts the equibiaxial tension (ET) stress lower, this paper proposes the totally incompressible Yeoh-Revised model to improve the prediction of ET stress. First, the fitting expression of the totally incompressible Yeoh-Revised constitutive model was derived under the presumption that fluororubber (FPM) and hydrogenated nitrile-butadiene rubber (HNBR) are isotropic and entirely incompressible. Meanwhile, the goodness-of-fit (R^2) statistic was used to assess the fitting outcomes of the three tension tests data (e.g., single tension (ST), ET and planar tension (PT)). Additionally, in order to fit the rubber materials tensile test data more accurately, we suggest a novel hyperelastic constitutive fitting method that takes into account the volume microscopic compressibility of rubber materials. The findings demonstrate that the totally incompressible Yeoh-Revised model's prediction of ET stress has marginally improved which neglecting the rubber materials’ volume microcompressibility, while the almost incompressible Yeoh-Revised model fits the ET stress significantly and accurately, and also enhances the forecast accuracy of overall R^2. Finally, the fitting formula of the almost incompressible constitutive model may be reduced to that of the totally incompressible model if the volume microcompressibility is disregarded, which is beneficial to more accurately forecast the experiment tests of rubber materials tension.","PeriodicalId":15613,"journal":{"name":"Journal of Elastomers & Plastics","volume":"20 1","pages":"1123 - 1151"},"PeriodicalIF":0.0,"publicationDate":"2023-08-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89309804","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-08-16DOI: 10.1177/00952443231196278
Mohsin Ali, Emin Istif, M. Bathaei, L. Beker
Micromechanical properties of polymeric materials play a critical role in various biological applications in terms of their biocompatibility and mechanical durability. Apart from material properties such as modulus and density, viscoelastic properties play a crucial role during the design and fabrication of devices. Here, we investigated the viscoelastic properties of poly (glycerol sebacate) (PGS), a widely used bioresorbable elastic material, through the nanoindentation technique, configured by the continuous stiffness measurement (CSM) method at frequencies from 10 Hz to 50 Hz. The results revealed that the storage modulus (E’) depends on the test frequency and cannot be ignored as the results showed significant changes. Additionally, increasing the curing temperature of PGS specimens between 150 to 170°C allows modifying the storage modulus of samples between 0.52 MPa and 1.05 MPa at 10 Hz. The results were also confirmed using the dynamic mechanical measurements to validate the reliability of the CSM nanoindentation technique.
{"title":"Investigation of dynamic micromechanical properties of biodegradable elastic material by continuous stiffness measurement analysis","authors":"Mohsin Ali, Emin Istif, M. Bathaei, L. Beker","doi":"10.1177/00952443231196278","DOIUrl":"https://doi.org/10.1177/00952443231196278","url":null,"abstract":"Micromechanical properties of polymeric materials play a critical role in various biological applications in terms of their biocompatibility and mechanical durability. Apart from material properties such as modulus and density, viscoelastic properties play a crucial role during the design and fabrication of devices. Here, we investigated the viscoelastic properties of poly (glycerol sebacate) (PGS), a widely used bioresorbable elastic material, through the nanoindentation technique, configured by the continuous stiffness measurement (CSM) method at frequencies from 10 Hz to 50 Hz. The results revealed that the storage modulus (E’) depends on the test frequency and cannot be ignored as the results showed significant changes. Additionally, increasing the curing temperature of PGS specimens between 150 to 170°C allows modifying the storage modulus of samples between 0.52 MPa and 1.05 MPa at 10 Hz. The results were also confirmed using the dynamic mechanical measurements to validate the reliability of the CSM nanoindentation technique.","PeriodicalId":15613,"journal":{"name":"Journal of Elastomers & Plastics","volume":"23 1","pages":"1111 - 1122"},"PeriodicalIF":0.0,"publicationDate":"2023-08-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78977888","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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