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Adsorption kinetics, isotherms, and selectivity of trihalomethanes and haloacetonitriles by granular activated carbon. 颗粒活性炭对三卤甲烷和卤代乙腈的吸附动力学、等温线和选择性。
Pub Date : 2024-09-13 DOI: 10.1080/10934529.2024.2399453
Juthamas Jaichuedee,Charongpun Musikavong
The performance capability of granular activated carbon (GAC) adsorption in terms of disinfection by-product (DBPs) removal was investigated with synthetic water containing 1) trihalomethanes (THMs), 2) haloacetronitriles (HANs), and 3) Mix-THMs & HANs. The initial 20 min of adsorption resulted in the maximum adsorption rate, with the total THMs, total HANs, and total Mix-THMs & HANs being 4.972, 2.071, and 6.460 µg/gGAC-min, respectively. GAC dosage affects the adsorption selectivity of THMs and HANs. Under a low GAC dosage, the selectivity of GAC adsorbs more bromo-THMs than chloro-THMs. The adsorption selectivity of THMs on GAC following bromoform > dibromochloromethane > bromodichloromethane > chloroform was investigated. As the GAC concentration increased, the selectivity of THM adsorption by GAC became comparable. Chloro-HAN, in contrast to THMs, has a higher adsorption selectivity than bromo-HAN. Trichloroacetonitrile was removed by GAC more rapidly than the other HAN species when the GAC dose was increased. The toxin of bromoform was primarily eliminated through GAC adsorption, caused by a greater removal rate than that of the other THMs. As an implemented measure, GAC is introduced to reduce THMs and HANs and the toxic contents associated with THMs and HANs.
用含有 1)三卤甲烷(THMs)、2)卤代乙腈(HANs)和 3)混合三卤甲烷和卤代乙腈的合成水研究了颗粒活性炭(GAC)吸附去除消毒副产物(DBPs)的性能。最初 20 分钟的吸附率最高,THMs 总量、HANs 总量和混合-THMs & HANs 总量分别为 4.972、2.071 和 6.460 µg/gGAC-min。GAC 的用量会影响对 THMs 和 HANs 的吸附选择性。在较低的 GAC 用量下,GAC 的选择性吸附溴-THMs 多于氯-THMs。研究了三卤甲烷在 GAC 上的吸附选择性:溴甲烷 > 二溴氯甲烷 > 溴二氯甲烷 > 氯仿。随着 GAC 浓度的增加,GAC 对 THM 的吸附选择性变得相当。与三卤甲烷相比,氯-氢的吸附选择性高于溴-氢。当 GAC 的剂量增加时,GAC 去除三氯乙腈的速度比去除其他 HAN 种类的速度更快。溴甲烷毒素主要通过 GAC 吸附去除,其去除率高于其他三卤甲烷。作为一项实施措施,采用 GAC 可以减少三卤甲烷和 HANs 以及与三卤甲烷和 HANs 相关的有毒物质。
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引用次数: 0
Immobilization of HRP enzyme on polymeric microspheres and its use in decolourisation of organic dyes. 在聚合物微球上固定 HRP 酶及其在有机染料脱色中的应用。
Pub Date : 2024-09-11 DOI: 10.1080/10934529.2024.2403279
Nurdan Kurnaz Yetim,Elvan Hasanoğlu Özkan,Nurşen Sarı
In this study, horseradish peroxidase (HRP) enzyme was immobilized on Pd(II) containing polymeric microspheres by adsorption method and used for the decolourisation of Methyl Orange (MO) and Rhodamine B (RB) dyes. The synthesized microspheres were characterized by Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy-Energy Dispersive X-ray (SEM/EDX), Thermal Gravimetric Analysis (TGA). The effects of pH, dye concentration, temperature, and H2O2 concentration on the decolourisation of MO and RB were determined. According to the results of various parameters studied, when 2-AEPS-napht-HRP support was used, MO and RB were biodegraded to 69.72% and 80.65%, respectively, within 60 min. When 2-AEPS-napht-Pd-HRP support was used, MO and RB were biodegraded to 58.35% and 90.81%, respectively, under optimum conditions. When the reproducibility results of the immobilized supports were examined, it was observed that they remained efficient during the first five reusability cycles and even reached 65% decolourisation efficiency after the 9th reuse. The immobilized enzyme (2AEPS-npht-HRP and 2AEPS-npht-Pd-HRP) showed remarkable resistance to higher temperatures compared to the free enzyme.
本研究采用吸附法将辣根过氧化物酶 (HRP) 固定在含 Pd(II) 的聚合物微球上,并将其用于甲基橙 (MO) 和罗丹明 B (RB) 染料的脱色。傅立叶变换红外光谱(FTIR)、扫描电子显微镜-能量色散 X 射线(SEM/EDX)和热重力分析(TGA)对合成的微球进行了表征。测定了 pH 值、染料浓度、温度和 H2O2 浓度对 MO 和 RB 脱色的影响。根据各种参数的研究结果,当使用 2-AEPS-napht-HRP 载体时,MO 和 RB 在 60 分钟内的生物降解率分别为 69.72% 和 80.65%。当使用 2-AEPS-napht-Pd-HRP 载体时,在最佳条件下,MO 和 RB 的生物降解率分别为 58.35% 和 90.81%。在对固定化支持物的重现性结果进行研究时,发现它们在前五个重复使用周期中都保持高效,甚至在第 9 次重复使用后达到了 65% 的脱色效率。与游离酶相比,固定化酶(2AEPS-npht-HRP 和 2AEPS-npht-Pd-HRP)具有显著的耐高温性。
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引用次数: 0
Integration of down-flow hanging sponge reactor to oreochromis niloticus - Brassica oleracea aquaponics system. 将下流式悬挂海绵反应器集成到黑线鲈-甘蓝鱼菜共生系统中。
Pub Date : 2024-09-11 DOI: 10.1080/10934529.2024.2399444
Wilasinee Kotcharoen,Zen Nagai,Takahiro Watari,Nur Adlin,Masashi Hatamoto,Yuki Murakami,Namita Maharjan,Yutaka Takeuchi,Shinichi Yamazaki,Takashi Yamaguchi
Aquaponics is a promising solution for addressing food security concerns. Nonetheless, an effective water-purification system is necessary to achieve high and stable yields of fish and vegetables. This study aimed to evaluate the nitrification and oxygen transfer performance of a laboratory-scale down-flow hanging sponge (DHS) reactor with a Brassica oleracea aquaponics system to treat water in an Oreochromis niloticus closed-aquaculture system. The DHS reactor showed a higher oxygen transfer coefficient (KLa) than the conventional aerator and provided an adequate dissolved oxygen (DO) concentration of approximately 5.5 mg/L essential for O. niloticus growth throughout the experimental period. The evaluated DHS-based aquaponic system maintained high water quality in an aquaculture tank, with a survival rate of 97%. The O. niloticusgrew at a low feed conversion ratio of 1.5-2.1 and a low feeding rate of 0.5% at high stocking densities of 17.5-22.2 kg-fish-weight/m3. 16S rRNA gene sequencing indicated that the DHS sponge carrier effectively retained nitrifying bacteria such as Nitrosomonas and Nitrospira. This study demonstrated that the DHS reactor provided a high DO concentration and that a simultaneous DHS reactor with a hydroponic tank provided a low-cost aquaponic system that could be applied for food production in the aquaculture industry.
鱼菜共生是解决粮食安全问题的一个前景广阔的解决方案。然而,要实现鱼类和蔬菜的高产稳产,必须有一个有效的水净化系统。本研究旨在评估实验室规模的下流式悬挂海绵(DHS)反应器与大头菜鱼菜共生系统的硝化和氧传递性能,以处理黑线鲈封闭式水产养殖系统中的水。与传统曝气器相比,DHS 反应器显示出更高的氧传递系数(KLa),并在整个实验期间为黑线鲈的生长提供了约 5.5 毫克/升的充足溶解氧(DO)浓度。经过评估的基于 DHS 的水产养殖系统在水产养殖池中保持了较高的水质,存活率达到 97%。在 17.5-22.2 公斤鱼重/立方米的高密度养殖条件下,黑线鲈的饲料转化率为 1.5-2.1,投喂率为 0.5%。16S rRNA 基因测序表明,DHS 海绵载体能有效保留硝化细菌,如亚硝化单胞菌和硝化细菌。这项研究表明,DHS 反应器可提供较高的溶解氧浓度,同时使用 DHS 反应器和水培池可提供一种低成本的水生植物栽培系统,可用于水产养殖业的食品生产。
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引用次数: 0
Photocatalytic degradation process of antibiotic sulfamethoxazole by ZnO in aquatic systems: a dynamic kinetic model based on contributions of OH radical, oxygenated radical intermediates and dissolved oxygen 氧化锌在水生系统中光催化降解抗生素磺胺甲噁唑的过程:基于OH自由基、含氧自由基中间体和溶解氧贡献的动态动力学模型
Pub Date : 2024-04-15 DOI: 10.1080/10934529.2024.2339171
Yuka Takahashi, Maki Kobayashi, Yoshinori Kawase
The photocatalytic degradation process of sulfamethoxazole (SMX) using ZnO in aquatic systems has been systematically studied by varying initial SMX concentration from 0 to 15 mgL−1, ZnO dosage fro...
通过改变0至15 mgL-1的SMX初始浓度、ZnO用量、ZnO......和ZnO......等参数,系统研究了氧化锌在水生系统中光催化降解磺胺甲噁唑(SMX)的过程。
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引用次数: 0
A novel and efficient voltammetric sensor for the simultaneous determination of alizarin red S and tartrazine by using poly(leucine) functionalized carbon paste electrode 利用聚(亮氨酸)功能化碳糊电极同时测定茜素红 S 和酒石酸的新型高效伏安传感器
Pub Date : 2024-04-13 DOI: 10.1080/10934529.2024.2339160
Karnayana Prasad Moulya, Jamballi G. Manjunatha, Sameh M Osman, Narges Ataollahi
In the current work, a rapid, selective, and sensitive technique was developed for the detection of Alizarin Red S (ARS) by applying poly leucine modified carbon paste electrode (PLMCPE). Electroch...
在当前的工作中,利用聚亮氨酸修饰碳浆电极(PLMCPE)开发了一种快速、选择性和灵敏的茜素红 S(ARS)检测技术。电...
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引用次数: 0
Association of serum five heavy metals level with all-cause and cause-specific mortality: a large population-based cohort study 血清中五种重金属水平与全因和特定原因死亡率的关系:一项大型人群队列研究
Pub Date : 2024-04-12 DOI: 10.1080/10934529.2024.2339776
Shengjue Xiao, Zhenwei Wang, Ronghua Zuo, Yufei Zhou, Zhongkai Wang, Tian Chen, Naifeng Liu
The study aimed to explore the association between five heavy metals exposure (Cadmium, Lead, Mercury, Manganese, and Selenium) and mortality [all-cause, cardiovascular disease (CVD), and cancer-re...
该研究旨在探讨五种重金属(镉、铅、汞、锰和硒)暴露与死亡率(全因、心血管疾病(CVD)和癌症)之间的关系。
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引用次数: 0
Predictive modeling of copper (II) adsorption from aqueous solutions by sawdust: a comparative analysis of adaptive neuro-fuzzy interference system (ANFIS) and artificial neural network (ANN) approaches 锯屑对水溶液中铜 (II) 吸附的预测建模:自适应神经模糊干扰系统 (ANFIS) 和人工神经网络 (ANN) 方法的比较分析
Pub Date : 2024-04-12 DOI: 10.1080/10934529.2024.2339775
Banza Jean Claude, Maurice Stephane Onyango
Heavy metal ions are considered to be the most prevalent and toxic water contaminants. The objective of thois work was to investigate the effectiveness of employing the adsorption technique in a la...
重金属离子被认为是最常见的有毒水污染物。这项工作的目的是研究吸附技术在水处理中的应用效果。
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引用次数: 0
Effects of pyroligneous acid on acute, chronic, and cyto-genotoxicity to earthworms (Eisenia fetida) 焦磷酸对蚯蚓(Eisenia fetida)急性、慢性和细胞遗传毒性的影响
Pub Date : 2024-04-10 DOI: 10.1080/10934529.2024.2339774
Anithadevi Kenday Sivaram, Kannappar Mukunthan, Mallavarapu Megharaj
The pyroligneous acid (PA), or wood vinegar, is a byproduct of wood carbonization during the slow pyrolysis process. PA is recognized globally as a safe compound for agriculture due to its various ...
火成酸(PA)或木醋是木材在缓慢热解过程中碳化的副产品。由于其各种特性,PA 是全球公认的农业安全化合物。
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引用次数: 0
Biofiltration of n-butyl acetate with three packing material mixtures, with and without biochar 用三种填料混合物(含生物炭和不含生物炭)对醋酸正丁酯进行生物过滤
Pub Date : 2024-04-03 DOI: 10.1080/10934529.2024.2332127
Martin Halecký, Jiří Mach, Luboš Zápotocký, Michael Pohořelý, Zdeněk Beňo, Josef Farták, Evguenii Kozliak
Two cost-effective packing materials were used for n-butyl acetate removal in lab-scale biofilters, namely waste spruce root wood chips and biochar obtained as a byproduct from a wood gasifier. Thr...
在实验室规模的生物过滤器中使用了两种具有成本效益的填料来去除醋酸正丁酯,即废弃云杉根木屑和作为木材气化炉副产品获得的生物炭。这些...
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引用次数: 0
To explore the remediation mechanism and effect of biochar and KH2PO4 on soils contaminated with heavy metal ions Hg2+, Cd2+ and Pb2+ 探索生物炭和 KH2PO4 对受重金属离子 Hg2+、Cd2+ 和 Pb2+ 污染的土壤的修复机制和效果
Pub Date : 2023-12-09 DOI: 10.1080/10934529.2023.2290421
Dun Wu, Jianwei Lu, Jian Wu, Bo Li
In this study, wheat straw-derived biochar was prepared by setting a temperature of 400 °C under an oxygen-limited environment using the technique of “programmed temperature increase control”. The ...
本研究采用 "程序升温控制 "技术,在限氧环境下将温度设定为 400 °C,制备了小麦秸秆衍生生物炭。其 ...
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引用次数: 0
期刊
Journal of Environmental Science and Health, Part A
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