Pub Date : 2022-05-12DOI: 10.1080/10934529.2022.2079339
Shaorong Huang, Suiqiong Sheng, M. Bei, Yangyong Zhao, Ruihong Chen
Abstract Halogenated carbazoles are a new class of persistent organic pollutants with dioxin-like toxicity, and this study focused on the microbial degradation of 1,3,6,8-tetrabromocarbazole. In this study, a novel 1,3,6,8-tetrabromocarbazole (1,3,6,8-TBCZ) degrading strain TB-1 was isolated from contaminated soil and identified as Achromobacter sp. based on its 16S rRNA gene sequence analysis, morphological, physiological, and biochemical characteristics. The soil sample was collected from a pharmaceutical factory in Suzhou, China. The strain was able to effectively degrade 1 mg L−1 1,3,6,8-TBCZ in 7 d at pH 7.0 and 30 °C with 80% degradation rate. During the process, the intermediate metabolites were identified as Tribromocarbazole, dibromocarbazole and bromocarbazole via gas chromatography mass spectrometry (GC-MS). The results indicated that strain TB-1 may contribute to the bioremediation of polyhalogenated carbazoles (PHCs) in contaminated environment.
{"title":"Isolation and identification of 1,3,6,8-tetrabromocarbazole – degrading bacteria","authors":"Shaorong Huang, Suiqiong Sheng, M. Bei, Yangyong Zhao, Ruihong Chen","doi":"10.1080/10934529.2022.2079339","DOIUrl":"https://doi.org/10.1080/10934529.2022.2079339","url":null,"abstract":"Abstract Halogenated carbazoles are a new class of persistent organic pollutants with dioxin-like toxicity, and this study focused on the microbial degradation of 1,3,6,8-tetrabromocarbazole. In this study, a novel 1,3,6,8-tetrabromocarbazole (1,3,6,8-TBCZ) degrading strain TB-1 was isolated from contaminated soil and identified as Achromobacter sp. based on its 16S rRNA gene sequence analysis, morphological, physiological, and biochemical characteristics. The soil sample was collected from a pharmaceutical factory in Suzhou, China. The strain was able to effectively degrade 1 mg L−1 1,3,6,8-TBCZ in 7 d at pH 7.0 and 30 °C with 80% degradation rate. During the process, the intermediate metabolites were identified as Tribromocarbazole, dibromocarbazole and bromocarbazole via gas chromatography mass spectrometry (GC-MS). The results indicated that strain TB-1 may contribute to the bioremediation of polyhalogenated carbazoles (PHCs) in contaminated environment.","PeriodicalId":15733,"journal":{"name":"Journal of Environmental Science and Health, Part A","volume":"23 1","pages":"487 - 493"},"PeriodicalIF":0.0,"publicationDate":"2022-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78095639","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Phosphorus is a nonrenewable resource, and the recovery of phosphorus from wastewater containing high concentrations of phosphorus is of great importance. In this work, a novel method for highly efficient treatment of high-concentration phosphorus-containing wastewater (50 mg/L, 100 mg/L and 150 mg/L) with low energy consumption was developed by using the block waste foam concrete (FC) as a potential phosphorus recovery material. The results showed that acid leaching significantly improved the accumulation efficiency of phosphorus in calcium hydroxyphosphate (HAP) via accelerating the release of calcium in wastewater. The recovery rate of phosphorus could reach 99.0% under the pH value of 9.0 at 25 °C, using 2.0 g FC. It was also found that the microporous structure of the surface of FC provided the adsorption sites for phosphorus, resulting in the adsorption rate in different concentrations of phosphorus-containing wastewater up to 14.5%. It indicated that FC achieved the recovery of phosphorus from high-concentration phosphorus-containing wastewater by coupling HAP crystallization and physical adsorption to polyphosphorus.
摘要磷是一种不可再生资源，从高浓度磷废水中回收磷具有重要意义。本研究以块状废泡沫混凝土(FC)为潜在的磷回收材料，开发了一种低能耗高效处理高浓度含磷废水(50 mg/L、100 mg/L和150 mg/L)的新方法。结果表明，酸浸通过加速废水中钙的释放，显著提高了羟基磷酸钙(HAP)中磷的富集效率。25℃，pH = 9.0，使用2.0 g FC，磷的回收率可达99.0%。研究还发现，FC表面的微孔结构为磷提供了吸附位点，在不同浓度含磷废水中的吸附率可达14.5%。结果表明，FC通过HAP结晶与物理吸附相结合，实现了高浓度含磷废水中磷的回收。
{"title":"Treatment of high-concentration phosphorus wastewater based on foamed concrete","authors":"Yuecheng He, Yue Jian, Qixing Huang, Y. Tao, Liurui Peng, Chuan Huang, Wenlai Xu","doi":"10.1080/10934529.2022.2078622","DOIUrl":"https://doi.org/10.1080/10934529.2022.2078622","url":null,"abstract":"Abstract Phosphorus is a nonrenewable resource, and the recovery of phosphorus from wastewater containing high concentrations of phosphorus is of great importance. In this work, a novel method for highly efficient treatment of high-concentration phosphorus-containing wastewater (50 mg/L, 100 mg/L and 150 mg/L) with low energy consumption was developed by using the block waste foam concrete (FC) as a potential phosphorus recovery material. The results showed that acid leaching significantly improved the accumulation efficiency of phosphorus in calcium hydroxyphosphate (HAP) via accelerating the release of calcium in wastewater. The recovery rate of phosphorus could reach 99.0% under the pH value of 9.0 at 25 °C, using 2.0 g FC. It was also found that the microporous structure of the surface of FC provided the adsorption sites for phosphorus, resulting in the adsorption rate in different concentrations of phosphorus-containing wastewater up to 14.5%. It indicated that FC achieved the recovery of phosphorus from high-concentration phosphorus-containing wastewater by coupling HAP crystallization and physical adsorption to polyphosphorus.","PeriodicalId":15733,"journal":{"name":"Journal of Environmental Science and Health, Part A","volume":"132 1","pages":"479 - 486"},"PeriodicalIF":0.0,"publicationDate":"2022-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74693075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-05-10DOI: 10.1080/10934529.2022.2072152
Francisco Sílvio Maia, M. Marques, A. C. Macedo, Carlos C. Matos, M. V. P. Rocha
Abstract This study’s aim was to determine the presence, as well as to evaluate the health and environmental impacts, of chemical elements from firearm shots during shooter practice at outdoor shooting ranges, both in the environment and on the shooters’ hands. Two high-precision devices were used for measuring suspended particles that are released during discharge of Taurus PT 100 .40 caliber pistols. The analysis of collected data allowed the identification of specific distribution patterns of samples that were adsorbed. Moreover, samples were collected from the opisthenar area of the hand to investigate both the occurrence and deposition of particles and chemical elements through scanning electron microscopy coupled with energy dispersive spectroscopy (SEM-EDS). The results indicate that copper, lead, and zinc concentration profiles will be able to delimit and reveal more precise details regarding shots made with nontoxic ammunition (NTA). In particular, the residual graphic analysis indicated that the majority of metal deposited in the shooter's hand is zinc. Further, the metals barium and lead also were detected. Due to the exposure to these elements, it could be concluded that engineering controls and administrative management should be sought in order to avoid human overexposure and environmental release of these airborne toxic metals.
{"title":"Analysis of gunshot residues from nontoxic ammunition: a contribution to health and environmental analysis","authors":"Francisco Sílvio Maia, M. Marques, A. C. Macedo, Carlos C. Matos, M. V. P. Rocha","doi":"10.1080/10934529.2022.2072152","DOIUrl":"https://doi.org/10.1080/10934529.2022.2072152","url":null,"abstract":"Abstract This study’s aim was to determine the presence, as well as to evaluate the health and environmental impacts, of chemical elements from firearm shots during shooter practice at outdoor shooting ranges, both in the environment and on the shooters’ hands. Two high-precision devices were used for measuring suspended particles that are released during discharge of Taurus PT 100 .40 caliber pistols. The analysis of collected data allowed the identification of specific distribution patterns of samples that were adsorbed. Moreover, samples were collected from the opisthenar area of the hand to investigate both the occurrence and deposition of particles and chemical elements through scanning electron microscopy coupled with energy dispersive spectroscopy (SEM-EDS). The results indicate that copper, lead, and zinc concentration profiles will be able to delimit and reveal more precise details regarding shots made with nontoxic ammunition (NTA). In particular, the residual graphic analysis indicated that the majority of metal deposited in the shooter's hand is zinc. Further, the metals barium and lead also were detected. Due to the exposure to these elements, it could be concluded that engineering controls and administrative management should be sought in order to avoid human overexposure and environmental release of these airborne toxic metals.","PeriodicalId":15733,"journal":{"name":"Journal of Environmental Science and Health, Part A","volume":"57 1","pages":"427 - 435"},"PeriodicalIF":0.0,"publicationDate":"2022-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73474030","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-05-03DOI: 10.1080/10934529.2022.2060026
S. Soares, G. Costa, L. Brito, Gisele Augusto Rodrigues de Oliveira, P. Scalize
Abstract The data on water pollution is scarce in developing countries, including Brazil. The water quality assessment is important implementing the monitoring and remediation programs to minimize the risk of hazardous substances in freshwaters. Thus, this study evaluated the surface water quality of a stretch of the Bois River (Brazil), based on the physicochemical, microbiological and ecotoxicological analyses conducted in 2017, using Standard Methods and fish embryo acute toxicity (FET) test with zebrafish (Danio rerio). The results indicated that the quality of water samples located close to the discharge of tannery effluents was most impaired. Total phosphorus, BOD, DO, ammoniacal nitrogen, and thermotolerant coliforms parameters in P4 were not in accordance with the standards of current Brazilian legislation. Iron, lead, and copper levels were higher than environmental standards. The physicochemical quality of water samples was lower in the dry season than the rainy season. All samples (P1, P3, and P5) in rainy and dry seasons did not induce significant acute toxicity for zebrafish early-life stage; however other trophic levels (algae and microcrustacean) should be investigated to gain a better understanding of the toxicity during water quality analysis. In conclusion, the physicochemical and microbiological changes in the water of the Bois River can affect aquatic organisms as well as humans when it is used for drinking or in agriculture.
{"title":"Assessment of surface water quality of the bois river (Goiás, Brazil) using an integrated physicochemical, microbiological and ecotoxicological approach","authors":"S. Soares, G. Costa, L. Brito, Gisele Augusto Rodrigues de Oliveira, P. Scalize","doi":"10.1080/10934529.2022.2060026","DOIUrl":"https://doi.org/10.1080/10934529.2022.2060026","url":null,"abstract":"Abstract The data on water pollution is scarce in developing countries, including Brazil. The water quality assessment is important implementing the monitoring and remediation programs to minimize the risk of hazardous substances in freshwaters. Thus, this study evaluated the surface water quality of a stretch of the Bois River (Brazil), based on the physicochemical, microbiological and ecotoxicological analyses conducted in 2017, using Standard Methods and fish embryo acute toxicity (FET) test with zebrafish (Danio rerio). The results indicated that the quality of water samples located close to the discharge of tannery effluents was most impaired. Total phosphorus, BOD, DO, ammoniacal nitrogen, and thermotolerant coliforms parameters in P4 were not in accordance with the standards of current Brazilian legislation. Iron, lead, and copper levels were higher than environmental standards. The physicochemical quality of water samples was lower in the dry season than the rainy season. All samples (P1, P3, and P5) in rainy and dry seasons did not induce significant acute toxicity for zebrafish early-life stage; however other trophic levels (algae and microcrustacean) should be investigated to gain a better understanding of the toxicity during water quality analysis. In conclusion, the physicochemical and microbiological changes in the water of the Bois River can affect aquatic organisms as well as humans when it is used for drinking or in agriculture.","PeriodicalId":15733,"journal":{"name":"Journal of Environmental Science and Health, Part A","volume":"63 1","pages":"242 - 249"},"PeriodicalIF":0.0,"publicationDate":"2022-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74319184","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-04-16DOI: 10.1080/10934529.2022.2073764
Kazuaki Syutsubo, Yuma Miyaoka, Tsuyoshi Danshita, Yasuyuki Takemura, Masataka Aoki, N. Tomioka, Haruhiko Sumino, T. Watari, Takashi Yamaguchi
Abstract In the production of natural rubber, formate or acetate is added to the latex solution to coagulate the rubber; therefore, the wastewater contains high concentrations of organic acids, requiring the application of anaerobic treatment technology. In this study, a two-phase continuous flow experiment using a laboratory-scale upflow anaerobic sludge blanket (UASB) was conducted to investigate the influence of formate inflow on the microbial and physical characteristics of the retained granular sludge. In phase 1, acetate-based wastewater was used as feed, while in phase 2, formate-based wastewater was used as feed. In phase 1, the UASB exhibited high COD removal efficiency (97.2%); in addition, the retained sludge showed increased methane production from acetate and proliferation of acetate-utilizing Methanosaeta species. In phase 2, the UASB performed as well as phase 1, with 98.2% COD removal efficiency. Microbial community structure analysis confirmed that relatives of Methanobacterium formicicum present in the retained sludge were responsible for the degradation of formate in phase 2. However, decreased diameter and slight deterioration of granular sludge settleability were observed. In conclusion, formate inflow has low risk of interference with the process performance of the UASB, but it has negative effects on the physical properties of the granular sludge.
{"title":"Effect of formic acid inflow on microbial properties of the anaerobic granular sludge in a UASB reactor","authors":"Kazuaki Syutsubo, Yuma Miyaoka, Tsuyoshi Danshita, Yasuyuki Takemura, Masataka Aoki, N. Tomioka, Haruhiko Sumino, T. Watari, Takashi Yamaguchi","doi":"10.1080/10934529.2022.2073764","DOIUrl":"https://doi.org/10.1080/10934529.2022.2073764","url":null,"abstract":"Abstract In the production of natural rubber, formate or acetate is added to the latex solution to coagulate the rubber; therefore, the wastewater contains high concentrations of organic acids, requiring the application of anaerobic treatment technology. In this study, a two-phase continuous flow experiment using a laboratory-scale upflow anaerobic sludge blanket (UASB) was conducted to investigate the influence of formate inflow on the microbial and physical characteristics of the retained granular sludge. In phase 1, acetate-based wastewater was used as feed, while in phase 2, formate-based wastewater was used as feed. In phase 1, the UASB exhibited high COD removal efficiency (97.2%); in addition, the retained sludge showed increased methane production from acetate and proliferation of acetate-utilizing Methanosaeta species. In phase 2, the UASB performed as well as phase 1, with 98.2% COD removal efficiency. Microbial community structure analysis confirmed that relatives of Methanobacterium formicicum present in the retained sludge were responsible for the degradation of formate in phase 2. However, decreased diameter and slight deterioration of granular sludge settleability were observed. In conclusion, formate inflow has low risk of interference with the process performance of the UASB, but it has negative effects on the physical properties of the granular sludge.","PeriodicalId":15733,"journal":{"name":"Journal of Environmental Science and Health, Part A","volume":"14 1","pages":"413 - 419"},"PeriodicalIF":0.0,"publicationDate":"2022-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88067184","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-04-16DOI: 10.1080/10934529.2022.2067444
T. Stafilov, R. Šajn, Ružica Blaževska, C. Tănăselia
Abstract The main objective of this study is to present the distribution of different chemical elements in soil samples from the Skopje region, North Macedonia. To determine the level of presence of chemical elements, soil samples are collected from a total of 60 locations. From each location, from an area of 5 × 5 km2 samples of soil are collected: topsoil (0–5 cm) and subsoil (20–30 cm). The soil samples were analyzed for 69 elements by using two instrumental methods: inductively coupled plasma-atomic emission spectrometry (ICP-AES) for macro-elements and inductively coupled plasma-mass spectrometry (ICP-MS) for trace elements. A factor analysis was applied to analyze the factors affecting the linear combination variables grouped at the same factor. Spatial distribution maps of each factor as well as distribution maps for the analyzed elements were prepared by universal kriging interpolation. It was found that the distribution of most elements follows the lithology of the examined area, except for some elements (Cd, Cu, Fe, Hg, Mn, Pb, and Zn) whose higher contents are found in the area of the city of Skopje as a result of urban and industrial activities (traffic, metal processing, fossil fuel combustion for heating).
{"title":"Assessment of natural and anthropogenic factors on the distribution of chemical elements in soil from the Skopje region, North Macedonia","authors":"T. Stafilov, R. Šajn, Ružica Blaževska, C. Tănăselia","doi":"10.1080/10934529.2022.2067444","DOIUrl":"https://doi.org/10.1080/10934529.2022.2067444","url":null,"abstract":"Abstract The main objective of this study is to present the distribution of different chemical elements in soil samples from the Skopje region, North Macedonia. To determine the level of presence of chemical elements, soil samples are collected from a total of 60 locations. From each location, from an area of 5 × 5 km2 samples of soil are collected: topsoil (0–5 cm) and subsoil (20–30 cm). The soil samples were analyzed for 69 elements by using two instrumental methods: inductively coupled plasma-atomic emission spectrometry (ICP-AES) for macro-elements and inductively coupled plasma-mass spectrometry (ICP-MS) for trace elements. A factor analysis was applied to analyze the factors affecting the linear combination variables grouped at the same factor. Spatial distribution maps of each factor as well as distribution maps for the analyzed elements were prepared by universal kriging interpolation. It was found that the distribution of most elements follows the lithology of the examined area, except for some elements (Cd, Cu, Fe, Hg, Mn, Pb, and Zn) whose higher contents are found in the area of the city of Skopje as a result of urban and industrial activities (traffic, metal processing, fossil fuel combustion for heating).","PeriodicalId":15733,"journal":{"name":"Journal of Environmental Science and Health, Part A","volume":"30 1","pages":"357 - 375"},"PeriodicalIF":0.0,"publicationDate":"2022-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89962127","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Oil sludge is a typical hazardous waste in the petrochemical and electric power industry. It has complex components and special properties, and has serious hazards to humans, plants, water, and soil. Therefore, how to realize the effective disposal of oil sludge has become an urgent issue to be solved worldwide. Among the existing oil sludge treatment approaches, combustion has been considered to be a promising technology to realize the large-scale industrial application. In the present work, the characteristics of oil sludge were described in detail. The application and development of oil sludge combustion technology were critically summarized and discussed, including factors affecting combustion, drying process, combustion characteristics, synergistic treatment technology, and formation and control of secondary pollution. Besides, the development of combustion equipment, and integrated thermal treatment technology for oil sludge were prospected. This work can be used for guiding the industrial disposal of oil sludge.
{"title":"A review of application and development of combustion technology for oil sludge","authors":"Zhiqiang Gong, Haoteng Zhang, Yonglong Juan, Lingkai Zhu, W. Zheng, Junqi Ding, Mao-cheng Tian, Xiaoyu Li, Jianqiang Zhang, Yizhi Guo, Guoen Li","doi":"10.1080/10934529.2022.2071067","DOIUrl":"https://doi.org/10.1080/10934529.2022.2071067","url":null,"abstract":"Abstract Oil sludge is a typical hazardous waste in the petrochemical and electric power industry. It has complex components and special properties, and has serious hazards to humans, plants, water, and soil. Therefore, how to realize the effective disposal of oil sludge has become an urgent issue to be solved worldwide. Among the existing oil sludge treatment approaches, combustion has been considered to be a promising technology to realize the large-scale industrial application. In the present work, the characteristics of oil sludge were described in detail. The application and development of oil sludge combustion technology were critically summarized and discussed, including factors affecting combustion, drying process, combustion characteristics, synergistic treatment technology, and formation and control of secondary pollution. Besides, the development of combustion equipment, and integrated thermal treatment technology for oil sludge were prospected. This work can be used for guiding the industrial disposal of oil sludge.","PeriodicalId":15733,"journal":{"name":"Journal of Environmental Science and Health, Part A","volume":"55 1","pages":"396 - 412"},"PeriodicalIF":0.0,"publicationDate":"2022-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75955733","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-04-16DOI: 10.1080/10934529.2022.2069977
Lenwood W. Hall Jr., Ronald D. Anderson
Abstract The objective of this study was to assess annual, seasonal and spatial trends in copper sediment concentrations in an agricultural California stream (Cache Slough) based on sampling 12 sites over two seasons (spring and fall) in 2012, 2013 and 2014. The relationship between copper sediment concentrations and precipitation was also evaluated. The results from this study showed that copper sediment concentrations from Cache Slough ranging from 19 to 63 ug/g dw were similar to concentrations reported in European agricultural streams. Copper sediment concentrations were not reported to increase over time in this agricultural waterbody where copper was used as a fungicide. However, spatial differences in copper sediment concentrations were reported among sites with the highest concentrations in the middle waterbody section. Seasonal analysis showed no significant difference in copper sediment concentrations for both spring and fall for 2012 and 2013 but 2014 spring concentrations were statistically higher than fall concentrations when precipitation was lower than the two previous years. There were no statistically significant relationships between copper sediment concentrations and precipitation for the three-year period based on an analysis by year and season.
{"title":"Assessing annual, seasonal and spatial trends in copper sediment concentrations from a California agricultural waterbody","authors":"Lenwood W. Hall Jr., Ronald D. Anderson","doi":"10.1080/10934529.2022.2069977","DOIUrl":"https://doi.org/10.1080/10934529.2022.2069977","url":null,"abstract":"Abstract The objective of this study was to assess annual, seasonal and spatial trends in copper sediment concentrations in an agricultural California stream (Cache Slough) based on sampling 12 sites over two seasons (spring and fall) in 2012, 2013 and 2014. The relationship between copper sediment concentrations and precipitation was also evaluated. The results from this study showed that copper sediment concentrations from Cache Slough ranging from 19 to 63 ug/g dw were similar to concentrations reported in European agricultural streams. Copper sediment concentrations were not reported to increase over time in this agricultural waterbody where copper was used as a fungicide. However, spatial differences in copper sediment concentrations were reported among sites with the highest concentrations in the middle waterbody section. Seasonal analysis showed no significant difference in copper sediment concentrations for both spring and fall for 2012 and 2013 but 2014 spring concentrations were statistically higher than fall concentrations when precipitation was lower than the two previous years. There were no statistically significant relationships between copper sediment concentrations and precipitation for the three-year period based on an analysis by year and season.","PeriodicalId":15733,"journal":{"name":"Journal of Environmental Science and Health, Part A","volume":"25 1","pages":"386 - 395"},"PeriodicalIF":0.0,"publicationDate":"2022-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73486119","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Oxytetracycline hydrochloride is the most widely used veterinary antibiotic in aquaculture. The presence of large amounts of residual antibiotics in aquaculture wastewater harms the ecological environment. In this study, the ternary composite of Zn0.75Mn0.75Fe1.5O4/ZnFe2O4/ZnO (ZMF-ZF-Z) photocatalyst was prepared by the coprecipitation method for degradation of oxytetracycline hydrochloride in marine aquaculture wastewater. The crystal phase, structure, morphology, elemental composition, element content, and optical properties of photogenerated electron-hole pairs of catalyst were characterized by XRD, SEM, EDS, UV-VIS (DRS), PL spectroscopy, and other test methods. The results showed that ZMF-ZF-Z photocatalyst had a larger response range of visible light than pure ZnO, which can absorb more natural light. During the process of the experiment, the photocatalytic effect of Z ZMF-ZF-Z photocatalyst was almost no weakening after 5 times reuse, which means quite good stability of the photocatalyst. Under the visible light irradiation, the degradation rate of oxytetracycline hydrochloride in seawater was 77.11% with ZMF-ZF-Z photocatalyst, which was about 3 times higher than that of pure ZnO, and the photocatalytic activity was significantly improved. This research provides a scientific and effective method for degrading antibiotics in seawater in actual production and life.
{"title":"Preparation and characterization of ternary composite photocatalyst for degradation of oxytetracycline hydrochloride in seawater under visible light","authors":"Jinghua Liu, Yifu Liu, Shini Wu, Yuqi Zhang, Xiaocai Yu","doi":"10.1080/10934529.2022.2075212","DOIUrl":"https://doi.org/10.1080/10934529.2022.2075212","url":null,"abstract":"Abstract Oxytetracycline hydrochloride is the most widely used veterinary antibiotic in aquaculture. The presence of large amounts of residual antibiotics in aquaculture wastewater harms the ecological environment. In this study, the ternary composite of Zn0.75Mn0.75Fe1.5O4/ZnFe2O4/ZnO (ZMF-ZF-Z) photocatalyst was prepared by the coprecipitation method for degradation of oxytetracycline hydrochloride in marine aquaculture wastewater. The crystal phase, structure, morphology, elemental composition, element content, and optical properties of photogenerated electron-hole pairs of catalyst were characterized by XRD, SEM, EDS, UV-VIS (DRS), PL spectroscopy, and other test methods. The results showed that ZMF-ZF-Z photocatalyst had a larger response range of visible light than pure ZnO, which can absorb more natural light. During the process of the experiment, the photocatalytic effect of Z ZMF-ZF-Z photocatalyst was almost no weakening after 5 times reuse, which means quite good stability of the photocatalyst. Under the visible light irradiation, the degradation rate of oxytetracycline hydrochloride in seawater was 77.11% with ZMF-ZF-Z photocatalyst, which was about 3 times higher than that of pure ZnO, and the photocatalytic activity was significantly improved. This research provides a scientific and effective method for degrading antibiotics in seawater in actual production and life.","PeriodicalId":15733,"journal":{"name":"Journal of Environmental Science and Health, Part A","volume":"138 1","pages":"420 - 426"},"PeriodicalIF":0.0,"publicationDate":"2022-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82857277","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-04-16DOI: 10.1080/10934529.2022.2064668
Ying-Hao Xue, Tao Jia, Ning Yang, Zhanxiang Sun, Zhiyuan Xu, Xin-Li Wen, Liang-shan Feng
Abstract Most studies on microplastics (MPs) focused on gut, liver, and brain, and MPs toxicity was size-dependent, but less has been reported on gill. Here, zebrafish were exposed to three sizes of MPs (45-53 μm, 90-106 μm, and 250-300 μm). Next, comparative transcriptome analysis and determination of physiological indices were performed in zebrafish gills to elucidate the size-associated toxicity of MPs to fish gills. Compared with the control, 60, 344, and 802 differentially expressed genes (DEGs) were identified after exposure to 45-53 μm, 90-106 μm, and 250-300 μm MPs for 5 days, respectively. More DEGs in treatment with bigger MPs suggested that bigger MPs might induce more changes in zebrafish gills than smaller ones. These DEGs were significantly enriched in the FoxO signaling, cellular senescence, circadian rhythm and p53 signaling pathways. Besides, 90-106 μm and 250-300 μm MPs treatments inhibited the cell cycle and prevented the apoptosis. The GSH content significantly increased after MPs exposure, suggesting the induction of oxidative stress. AChE and Na+/K+-ATPase activities were significantly lowered in all MPs treatments than in the control, suggesting the inhibition of neurotransmission and ion regulation. These changes might negatively influence the normal functioning of gills, such as osmoregulation, ion regulation, and respiration.
{"title":"Transcriptome alterations in zebrafish gill after exposure to different sizes of microplastics","authors":"Ying-Hao Xue, Tao Jia, Ning Yang, Zhanxiang Sun, Zhiyuan Xu, Xin-Li Wen, Liang-shan Feng","doi":"10.1080/10934529.2022.2064668","DOIUrl":"https://doi.org/10.1080/10934529.2022.2064668","url":null,"abstract":"Abstract Most studies on microplastics (MPs) focused on gut, liver, and brain, and MPs toxicity was size-dependent, but less has been reported on gill. Here, zebrafish were exposed to three sizes of MPs (45-53 μm, 90-106 μm, and 250-300 μm). Next, comparative transcriptome analysis and determination of physiological indices were performed in zebrafish gills to elucidate the size-associated toxicity of MPs to fish gills. Compared with the control, 60, 344, and 802 differentially expressed genes (DEGs) were identified after exposure to 45-53 μm, 90-106 μm, and 250-300 μm MPs for 5 days, respectively. More DEGs in treatment with bigger MPs suggested that bigger MPs might induce more changes in zebrafish gills than smaller ones. These DEGs were significantly enriched in the FoxO signaling, cellular senescence, circadian rhythm and p53 signaling pathways. Besides, 90-106 μm and 250-300 μm MPs treatments inhibited the cell cycle and prevented the apoptosis. The GSH content significantly increased after MPs exposure, suggesting the induction of oxidative stress. AChE and Na+/K+-ATPase activities were significantly lowered in all MPs treatments than in the control, suggesting the inhibition of neurotransmission and ion regulation. These changes might negatively influence the normal functioning of gills, such as osmoregulation, ion regulation, and respiration.","PeriodicalId":15733,"journal":{"name":"Journal of Environmental Science and Health, Part A","volume":"23 1","pages":"347 - 356"},"PeriodicalIF":0.0,"publicationDate":"2022-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86167142","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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