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Occurrence and Removal of Microplastic in Sewage Treatment Facilities in Chungcheongbuk-do 忠清北道污水处理设施中微塑料的发生和去除
Pub Date : 2023-03-31 DOI: 10.36278/jeaht.26.1.25
Hye‐Sung Kim, Joon-Sik Moon, Jun-Young Jo, Chan-Geun Lee, Young‐Cheol Cho, S. Hong
Microplastics from sewage and wastewater treatment facilities can be discharged into rivers and oceans, and the treatment facilities themselves can be a point source of microplastic pollution. The microplastic detection status and methods were compared in Miwon, Cheongju, Jecheon, and Chungju sewage treatment facilities in Chungcheongbuk-do. Samples were collected from the inlet, filtration facility, and discharge of Miwon Sewage Treatment Facility, a Porous Substrate Bioreactor (PSBR) construction corporation. Additionally, the inlet, first settling tank, final settling tank and outlet samples were taken from three sewage treatment facilities (Cheongju, Jecheon, and Chungju), which use bioreactor transformation processes. In the results, raw water showed a range of 232-1,510 pieces/L, and effluent water showed a range of 0.7-6.7 pieces/L. All four sewage treatment facilities showed high treatment efficiency of 98.5-99.9%. The treatment processes showed high removal efficiency in the order of CNR (97.0%) > PSBR (95.9%) > NPR (91.5%) > SMART3 (70.3%). As a study was conducted on only one sewage treatment facility for each process, additional research is necessary.
来自污水和废水处理设施的微塑料可以排放到河流和海洋中,而处理设施本身可能是微塑料污染的一个点源。比较了忠清北道密院、清州、堤川、忠州污水处理设施的微塑料检测现状和方法。在多孔基质生物反应器(PSBR)建设公司美原污水处理设施的入口、过滤设施和排放口采集了样本。此外,还从使用生物反应器转化过程的3个污水处理设施(清州、堤川、忠州)的入口、第一沉淀池、最终沉淀池和出口取样。结果显示,原水为232 ~ 1510片/L,出水为0.7 ~ 6.7片/L。4个污水处理设施的处理效率均达到98.5 ~ 99.9%。各处理工艺去除率依次为CNR (97.0%) > PSBR (95.9%) > NPR (91.5%) > SMART3(70.3%)。由于每个过程只对一个污水处理设施进行了研究,因此需要进行进一步的研究。
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引用次数: 0
A Short Review on Recent Advanced Oxidation Technologies for Microplastics Degradation 微塑料高级氧化降解技术研究进展
Pub Date : 2023-03-31 DOI: 10.36278/jeaht.26.1.1
Microplastics comprise plastic particles that are less than 5 mm in size. Owing to a significant increase in plastic production, micro plastics have become ubiquitous pollutants worldwide. Several studies have reported that microplastics are harmful to living organisms because they can adsorb contaminants from the environment due to their unique physicochemical properties. The adsorbed contaminants on microplastics can be released and accumulated in living organisms, thereby adversely affecting the health of humans and animals. Since existing water treatment technologies as stand-alone processes cannot achieve complete removal of microplastics, reliable methods must be developed. Advanced oxidation processes (AOPs) are a promising approach for the chemical treatment of contaminants such as microplastics. These processes utilize highly reactive oxygen species (e.g., hydroxyl radicals, sulfate radicals, superoxide anions, and singlet oxygen) to decompose microplastics completely. However, at this stage, AOPs can partially degrade and/or alter surface chemistry of microplastics. Therefore, extensive effort must be made to further study AOPs for complete decomposition of microplastics.
微塑料包括尺寸小于5毫米的塑料颗粒。由于塑料产量的显著增加,微塑料已成为世界范围内普遍存在的污染物。一些研究报告称,微塑料由于其独特的物理化学性质,可以吸附环境中的污染物,因此对生物有害。微塑料吸附的污染物可以释放并积聚在生物体中,从而对人类和动物的健康产生不利影响。由于现有的水处理技术作为独立的过程不能完全去除微塑料,因此必须开发可靠的方法。高级氧化工艺(AOPs)是一种很有前途的化学处理微塑料等污染物的方法。这些过程利用高活性氧(如羟基自由基、硫酸盐自由基、超氧阴离子和单线态氧)来完全分解微塑料。然而,在这个阶段,AOPs可以部分降解和/或改变微塑料的表面化学性质。因此,必须进一步研究AOPs以完全分解微塑料。
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引用次数: 0
Improving the Method for Measuring Bromine Compounds in Flue Gas 烟气中溴化物测定方法的改进
Pub Date : 2023-03-31 DOI: 10.36278/jeaht.26.1.16
Hyun-Soo Park, Yong-Won Han, Gil-young Oh, Eun-Ha Oh, Min-Young Kim, Hak-Rim Kim, H. Lim, Yong-Moon Jung, Yoon-Gyeong Cha, Duk-An Lee, Gwi-Nim Park, Ui-Joo Lee
The method detection limit (MDL) using UV-VIS spectrometry (UV/VIS) is the primary method to detect bromine compounds in the flue gas. However, the level of bromine compounds in the flue gas is 0.6 ppm, reaching 20% of the emission limit of 3.0 ppm, which limits the analysis of low-concentration samples. As per the United States Environmental Protection Agency and official test standards for water pollution, bromine compound analysis was performed using ion chromatography (IC). Hydrogen chloride was analyzed using IC, referencing official test standards for air pollution. Therefore, 0.1 M NaOH and distilled water (D.W.) were applied to the absorption solution of the IC analysis sample. Validation was conducted for IC (D.W.), IC (0.1 M NaOH), and UV/VIS (0.1 M NaOH) to improve the analysis method for bromine compounds in the flue gas. The linearity (R2) of the calibration curve for IC (D.W.) satisfied the R2 (0.98 or more) value calculated in the UV/VIS of the official test standards for air pollution. However, the R2 of UV/VIS (0.1 M NaOH) and IC (0.1 M NaOH) was not satisfied. In IC (D.W.) analysis results, the average values of MDL, MLQ (minimum level of quantification), accuracy and precision were 0.127 ppm, 0.403 ppm, 3.7%, and 102.9%, respectively. MDL and MLQ showed the lowest concentration compared to the other two methods, and had high accuracy and precision. Regarding the recovery rate by the absorbing liquid, IC (D.W.) was the highest at 93.55%, followed by UV/VIS (0.1 M NaOH) and IC (0.1 M NaOH). This study analyzed bromine compounds in flue gas with higher accuracy and precision using the IC (D.W.) method compared to IC (0.1 M NaOH) and UV/VIS (0.1 M NaOH).
紫外-可见光谱法(UV/VIS)的检测限(MDL)是检测烟气中溴化合物的主要方法。然而,烟气中溴化合物的含量为0.6 ppm,达到排放限值3.0 ppm的20%,这限制了对低浓度样品的分析。根据美国环境保护署和官方水污染测试标准,溴化合物分析采用离子色谱法(IC)进行。参照官方空气污染检测标准,采用集成电路对氯化氢进行了分析。因此,在IC分析样品的吸收溶液中加入0.1 M NaOH和蒸馏水(D.W.)。对IC (D.W.)、IC (0.1 M NaOH)和UV/VIS (0.1 M NaOH)进行了验证,以改进烟气中溴化合物的分析方法。IC (D.W.)校准曲线的线性(R2)满足官方空气污染检测标准中UV/VIS计算的R2(0.98或更高)值。然而,UV/VIS (0.1 M NaOH)和IC (0.1 M NaOH)的R2不令人满意。在IC (D.W.)分析结果中,MDL、MLQ(最低定量水平)、准确度和精密度的平均值分别为0.127 ppm、0.403 ppm、3.7%和102.9%。与其他两种方法相比,MDL和MLQ的浓度最低,准确度和精密度较高。吸收液的回收率以IC (D.W.)最高,为93.55%,其次为UV/VIS (0.1 M NaOH)和IC (0.1 M NaOH)。与IC法(0.1 M NaOH)和UV/VIS法(0.1 M NaOH)相比,本研究使用IC (D.W.)法分析烟气中的溴化合物具有更高的准确度和精密度。
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引用次数: 0
Evaluation of Energy Consumption Efficiency of an Air Diffuser in a Sewage Treatment Aeration Tank Under Standard Conditions 标准条件下污水处理曝气池空气扩散器能耗效率评价
Pub Date : 2022-12-31 DOI: 10.36278/jeaht.25.4.150
Kyu-jin Park, Younghee Kim
In 1970s, the Korean government formulated an energy saving plan, and in 1990s, they added items while implementing the efficiency rating and labeling system. According to the data released by the International Energy Agency (IEA), by 2050, energy savings by the equipment and facilities sector would account for 36% of the policy measures for greenhouse gas reduction. As such, the most useful way to reduce greenhouse gas emissions is to increase the original energy efficiency by distributing various energy-saving products through the efficiency management system. High-efficiency energy equipment certification is a system that certifies products that meet a certain standard in order to promote the supply of high-efficiency energy equipment. In the case of aeration devices, the performance and efficiency of air diffusers can be continuously managed to reduce national energy and carbon dioxide emissions. The purpose of this study is to confirm the definitive carbon reduction levels in the relevant field by examining the performance-based appropriate energy efficiency of air diffusers in aeration tanks during sewage treatment.
韩国政府在20世纪70年代制定了能源节约计划,并在90年代实施效率等级和标签制度时增加了项目。根据国际能源署(IEA)发布的数据,到2050年,设备和设施部门的节能将占温室气体减排政策措施的36%。因此,通过效率管理系统分配各种节能产品,提高原有的能源效率,是减少温室气体排放的最有用的方法。高效能源设备认证是为了促进高效能源设备的供应,对达到一定标准的产品进行认证的制度。在曝气装置的情况下,空气扩散器的性能和效率可以持续管理,以减少国家能源和二氧化碳排放。本研究的目的是通过检查曝气池中空气扩散器在污水处理过程中基于性能的适当能源效率,确认相关领域的最终碳减排水平。
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引用次数: 0
Effects of Soil Amendments on Arsenic Uptake by Earthworms(Eisenia fetida) in Arsenic-Polluted Soil 土壤改良剂对砷污染土壤中蚯蚓吸收砷的影响
Pub Date : 2022-12-31 DOI: 10.36278/jeaht.25.4.132
Ji-Hyock Yoo, K. Chon, O. Kwon, Jung Woo, Ji-Hyun Yoon
This study was conducted to evaluate the effects of soil amendments on arsenic (As) bioavailability in As-polluted soils. We determined the subsequent changes in As toxicity toward earthworms (Eisenia fetida) and As uptake by earthworms. We also investigated whether As bioaccumulation could be used as an index to evaluate changes in quality of As-polluted soils. No significant changes in acute toxicity to earthworms were observed, and the observed increases (70-93 mg kg-1) or decreases (27-38 mg kg-1) in bioavailable As in soils at the end of test were not related to the As concentrations in earthworms. The As concentration in earthworms 14 days after exposure was significantly lower in calcium superphosphate (CSP)- and S-treated soils (101.4-112.8 mg kg-1) than in control soil (138.9 mg kg-1), probably owing to reduced earthworm growth due to lower pH in CSP- and S-treated soils (6.3-7.3) relative to control and steel slag-treated soils (7.5-8.4). Comparisons of As toxicity and the effects of soil properties on this toxicity toward various species of earthworms could facilitate the use of earthworms to produce biological indices for evaluating changes in quality of As-polluted soils following amendment treatments.
研究了土壤改良剂对砷污染土壤中砷(As)生物有效性的影响。我们测定了砷对蚯蚓(Eisenia fetida)毒性的变化和蚯蚓对砷的吸收。我们还研究了砷的生物积累是否可以作为评价砷污染土壤质量变化的指标。对蚯蚓的急性毒性没有显著变化,试验结束时土壤中生物可利用性砷的增加(70 ~ 93 mg kg-1)或减少(27 ~ 38 mg kg-1)与蚯蚓体内的砷浓度无关。暴露14天后,过磷酸钙(CSP)和硫处理土壤中蚯蚓的砷浓度(101.4 ~ 112.8 mg kg-1)显著低于对照土壤(138.9 mg kg-1),这可能是由于CSP和硫处理土壤的pH值(6.3 ~ 7.3)低于对照和钢渣处理土壤(7.5 ~ 8.4),从而降低了蚯蚓的生长。比较砷对不同种类蚯蚓的毒性及土壤性质对其毒性的影响,有助于利用蚯蚓建立评价砷污染土壤改良后质量变化的生物学指标。
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引用次数: 0
A Study on the Distribution Characteristics of Formaldehyde, Volatile Organic Compounds, Particulate Matter, and Airborne Bacteria in Indoor Play Centers 室内游乐场所甲醛、挥发性有机物、颗粒物及空气细菌分布特征研究
Pub Date : 2022-12-31 DOI: 10.36278/jeaht.25.4.117
Tae-young Kim, Mija Kim, Min-kyung Baek, Su-Hyun Kim, Jae-pil Moon, Jin-kyung Jo, Yu-kyung Choi, Jong-wan Park, Bo-yeon Kweon
This study aimed to evaluate the indoor air quality differences at 19 indoor play centers of cafés and play areas in Gyeonggi-do where were 430 m2 or larger. We examined concentrations of formaldehyde (HCHO), volatile organic compounds (VOC), particulate matter, and total airborne bacteria, and how their distributions varied with the number of visitors at the places. On weekdays, there were no statistically significant differences in mean indoor air pollutant concentrations between the cafés and play areas at 95% confidence intervals. However, significant differences were observed on weekends when the number of visitors increased. HCHO concentrations increased up to 159%, and VOC concentrations increased up to 210%. A higher increase rate of HCHO occurred at the cafés compared to the play areas since cooking operations were performed under natural ventilation. The PM10 concentration increased by approximately 33.2%, with an increase of 49.2% in the play areas and a 18.3% increase in the cafés on weekends. PM2.5 concentration particularly increased during weekends in the cafés and play areas by 113% and 63.6%, respectively. During cooking operations, the concentration of gaseous and particulate pollution increased more in the air pollutant concentration of cafés, and the overall bacterial concentration increased during weekends due to higher numbers of visitors. Therefore, indoor play centers with cooking operations require adequate air quality management to mitigate the indoor pollution.
本研究的目的是评价京畿道市内19个咖啡厅室内游戏场和430平方米以上游戏场的室内空气质量差异。我们检测了甲醛(HCHO)、挥发性有机化合物(VOC)、颗粒物和空气中细菌的浓度,以及它们的分布如何随游客人数的变化而变化。在工作日,在95%的置信区间内,咖啡馆和游乐区的平均室内空气污染物浓度没有统计学上的显著差异。然而,在周末,当游客人数增加时,观察到显著的差异。HCHO浓度增加了159%,VOC浓度增加了210%。由于烹饪作业是在自然通风的情况下进行的,因此与玩耍区相比,咖啡工区的HCHO增加率更高。PM10浓度增加了约33.2%,其中在游乐区增加了49.2%,周末在咖啡厅增加了18.3%。周末期间,咖啡馆和游乐场的PM2.5浓度分别上升了113%和63.6%。在烹饪过程中,咖啡馆空气污染物浓度中气态和颗粒物污染浓度增加较多,周末游客较多,细菌总体浓度增加。因此,有烹饪操作的室内游戏中心需要适当的空气质量管理来减轻室内污染。
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引用次数: 0
A Study on the Adsorption Capture-Thermal Desorption Gas Chromatography Mass Spectrometry Analysis of Biogenic Volatile Organic Compounds in Forests 吸附捕获-热解吸气相色谱-质谱法分析森林生物源性挥发性有机物的研究
Pub Date : 2022-12-31 DOI: 10.36278/jeaht.25.4.141
Hyo-Jung Lee, Kyoung-Min Lee, Hyeon-Yeong Kim, Seong-Min Choi, B. Park
Phytoncide, a forest healing indicator, is known to help suppress depression, anxiety, and stress of human. Furthermore, it has positive effects on blood pressures, pulses, and mood fluctuations. Previous studies mostly focused on phytoncide emission trends and its concentration prediction in forest. Moreover, a direct comparison of phytoncide concentrations between existing studies is often challenging owing to the use of differingunits, target analytes, analysis conditions, as well as unreported concentrations per type of the compound. Therefore, this study evaluated the overall performance of adsorption sampling and thermal desorption coupled with gas chromatography to evaluatethe phytoncide concentration in a forest atmosphere. To this end, the analysis quality management and analysis accuracy were evaluated for on-site samples in two different laboratories. The phytoncide analysis results obtained from each laboratory can serve as reference data for the adsorption capture-thermal desorption method applied to biogenic volatile organic compounds.
植物杀菌剂是一种森林治疗指示剂,可以抑制人类的抑郁、焦虑和压力。此外,它对血压、脉搏和情绪波动有积极影响。以往的研究主要集中在森林植物杀菌剂排放趋势及其浓度预测上。此外,由于使用不同的单位、目标分析物、分析条件以及每种化合物未报告的浓度,在现有研究之间直接比较植物杀素浓度往往具有挑战性。因此,本研究评估了吸附取样和热解吸结合气相色谱法评估森林大气中植物杀虫剂浓度的总体性能。为此,对两个不同实验室现场样品的分析质量管理和分析准确性进行了评价。各实验室的植物杀素分析结果可作为生物源性挥发性有机物吸附捕获-热解吸法的参考数据。
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引用次数: 0
Evaluation of Urban Air Quality Monitoring Stations in Ulsan using Geographic Information System 基于地理信息系统的蔚山城市空气质量监测站评价
Pub Date : 2022-09-30 DOI: 10.36278/jeaht.25.3.99
Sung-Deuk Choi
To manage particulate matter (PM2.5) in Ulsan, this study evaluated the current status of the emissions and concentrations of PM2.5 and the number and spatial distribution of urban air quality monitoring stations (AQMSs). The major emission sources of PM2.5 in Ulsan are industrial activities (production process, manufacturing combustion, and ships), and the annual mean concentration of PM 2.5 in Ulsan is not higher than those in other large megacities. However, the toxicity of PM2.5 in Ulsan seems to be high owing to the presence of hazardous air pollutants. Although the AQMSs in Ulsan have been well operated, and the number of stations is sufficient, further evaluation of the roles and spatial distribution of some of these stations is required. This study proposed the priority areas for installing new AQMSs using Geographic Information System (GIS) tools based on the population distribution and PM2.5 pollution levels. The method developed in this study can be used for other cities, as well as for expanding urban areas and new downtown areas in Ulsan to assess the existing monitoring network and suggest the optimum locations of new stations.
为了管理蔚山市的PM2.5,本研究评估了蔚山市PM2.5的排放和浓度现状,以及城市空气质量监测站(AQMSs)的数量和空间分布。蔚山PM2.5的主要排放源是工业活动(生产过程、制造业燃烧、船舶),年均PM2.5浓度并不高于其他大城市。但是蔚山的PM2.5的毒性似乎很高,因为存在有害的空气污染物。虽然蔚山的空气质量监测系统运作良好,而且台站数目充足,但需要进一步评价其中一些台站的作用和空间分布。本研究利用地理信息系统(GIS)工具,根据人口分布和PM2.5污染水平,提出了安装新的空气质量监测系统的优先区域。本研究开发的方法可用于其他城市,以及蔚山的扩展市区和新市中心,以评估现有的监测网络并建议新站点的最佳位置。
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引用次数: 0
Characteristics of Atmospheric Compounds based on Regional Multicorrelation Analysis in Honam Area 基于区域多相关分析的湖南地区大气化合物特征
Pub Date : 2022-09-30 DOI: 10.36278/jeaht.25.3.85
Sung-Hyun Oh, Sea-Ho Oh, M. Bae
Particulate Matter (PM) in the atmosphere has serious impacts on human health and the global environmental systems. To reduce anthropogenic PM emissions is of importance to protect public health. In this study, the variation of concentrations in PM2.5, NO2, and O3 of Honam region over the past 6 years (2016-2021) was investigated. A statistical approach (i.e., hierarchical cluster analysis) was performed to present their spatial relationships. As a result, the high concentration of PM2.5 in Iksan-si was found in sources of primary pollutants emitted from industrial complexes and ammonia from large-scale livestock complexes. The high concentration periods of PM2.5 with lower concentrations of NO2 and O3 can be seasonal and secondary PM product contributions. In addition, the concentration of O3 in Buan-gun and Wanju-gun with lower PM levels can be the effect of emission of volatile organic compounds (VOCS) from sources. It is necessary to strengthen management for reducing emissions by sources and to establish a policy to control precursors of the atmospheric contaminants.
大气中的颗粒物(PM)对人类健康和全球环境系统产生严重影响。减少人为颗粒物排放对保护公众健康具有重要意义。本研究以湖南地区近6年(2016-2021年)PM2.5、NO2和O3浓度变化为研究对象。采用统计方法(即层次聚类分析)来呈现它们的空间关系。因此,益山市的PM2.5浓度很高,主要是在工业园区的一级污染物排放源和大型畜牧园区的氨水排放源。NO2和O3浓度较低的PM2.5高浓度期可以作为PM产品的季节性和二次贡献。此外,保安县和万州县的O3浓度较低,可能是污染源挥发性有机物(VOCS)排放的影响。必须加强源头减排管理,制定大气污染物前体控制政策。
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引用次数: 0
Comparison of On-site Assessment of Testing and Inspection Laboratories 检测与检验实验室现场评价的比较
Pub Date : 2022-09-30 DOI: 10.36278/jeaht.25.3.111
Jong-Yeon Hwang, Hye-ri Lee, S. Go, Sooa Jeon, Jeehye Kim, Hyo-Kyeong Kim, Jin-Ju Lee, C. Park, Jeong-ki Yoon, S. Shin
The quality control of testing and inspection laboratories operated in Korea, the United States, and Canada was compared. The basic framework of on-site evaluation operated by each country was similar in terms of evaluation procedure, document evaluation, issuance of verification certificate, and follow-up management. For conducting on-site evaluation and granting the certificate, the preparation materials and evaluation processes are subdivided in Korea, while the dates of granting the certificate are restricted to four times a year in the United States. After receiving accreditation as a testing/inspection laboratories for the first time in Canada, follow-up management is divided into re-evaluation, verification evaluation, and monitoring evaluation.
对比了韩国、美国、加拿大的检验实验室的质量管理情况。各国开展现场评价的基本框架在评价程序、文件评价、核发核查证书、后续管理等方面是相似的。在韩国,现场评价和颁发证书的准备材料和过程被细分,而在美国,颁发证书的时间被限制在每年4次。在加拿大首次获得检测/检验实验室认可后,后续管理分为再评价、验证评价和监测评价。
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引用次数: 0
期刊
Journal of Environmental Analysis, Health and Toxicology
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