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Bicomponent melt spinning of polyamide 6/carbon nanotube/carbon black filaments: Investigation of effect of melt mass-flow rate on electrical conductivity 聚酰胺6/碳纳米管/炭黑双组分熔体纺丝:熔体质量流率对电导率影响的研究
IF 3.2 4区 工程技术 Q1 MATERIALS SCIENCE, TEXTILES Pub Date : 2023-01-01 DOI: 10.1177/15280837231186174
Müslüm Kaplan, J. Ortega, Felix Krooß, T. Gries
Combining the several mixed phase structures and property profiles with a conductive, high aspect ratios nanofiller such as carbon nanotubes, graphene, and carbon black, specific morphological structures in melt spinning can be reached that offer much more potential for developing new functional fibers. Thus, understanding and controlling filler localization inside the developing phase morphology during melt spinning are the keys to the necessary structures. This work aimed to offer the possibility of producing fibers from electrically conductive polymer composites with a high filler concentration. First, the influence of different commercially available nanofillers, such as multi-wall carbon nanotubes (MWCNTs), graphene and carbon black on Polyamide 6 (PA6)-based nanocomposite melt-spun fibers were examined. Following the lab-scale melt spinning experiments, PA6/MWCNT-CB nanocomposite filaments containing 10 wt% nanofiller (each 5 wt%), were chosen for a pilot-scale bicomponent melt spinning process to investigate the influence of the nanocomposite core material feeding parameters on the properties of melt-spun fibers. The electrical conductivity decreased by half (from 3.13E-02 to 6.72E-03) when melt flow rate was increased from 3 g/min to 6 g/min. Scanning electron microscopy micrographs and thermal gravimetric analysis thermograms showed that the change in MFR values significantly affected the nanocomposite filaments’ surface properties.
将几种混合相结构和性能特征与导电、高纵横比的纳米填料(如碳纳米管、石墨烯和炭黑)相结合,可以在熔融纺丝中获得特定的形态结构,为开发新的功能纤维提供了更大的潜力。因此,了解和控制熔体纺丝过程中发展相形态中的填料定位是必要结构的关键。这项工作旨在提供从具有高填充浓度的导电聚合物复合材料中生产纤维的可能性。首先,研究了不同的市售纳米填料,如多壁碳纳米管(MWCNTs)、石墨烯和炭黑对聚酰胺6 (PA6)基纳米复合熔融纺丝纤维的影响。在实验室规模的熔融纺丝实验之后,选择含有10 wt%纳米填料(各5 wt%)的PA6/MWCNT-CB纳米复合长丝进行中试规模的双组分熔融纺丝工艺,研究纳米复合芯材进料参数对熔融纺丝纤维性能的影响。当熔体流动速率从3 g/min增加到6 g/min时,电导率下降了一半(从3.13E-02降至6.72E-03)。扫描电镜显微图和热重分析热图显示,MFR值的变化对纳米复合材料的表面性能有显著影响。
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引用次数: 0
Fabrication of multifunctional cotton textile with battery waste- derived graphene oxide for enhanced joule heating and electromagnetic interference shielding 用电池废料衍生的氧化石墨烯制备多功能棉织物,增强焦耳加热和电磁干扰屏蔽
IF 3.2 4区 工程技术 Q1 MATERIALS SCIENCE, TEXTILES Pub Date : 2023-01-01 DOI: 10.1177/15280837231178945
T. Suryaprabha, Seungkyu Park
Nowadays, the research on wearable electronics have received tremendous attraction because of their potential applications in personalized health monitoring and treatment, energy conversion and storage, and human-machine interface system. Herein, we report a facile route for the fabrication of electrically conductive cotton fabric with excellent joule heating and high electromagnetic shielding performances using graphene oxide (GO) and silver nitrate (AgNO3). The GO used in this study is exclusively synthesized from spent batteries in order to minimize the environmental pollution. The surface morphology, elemental analysis, electrical conductivity, thermo-heating behavior and electromagnetic shielding performance have been studied systematically. Due to the high electrical conductivity, the GO-Ag coated cotton with 5 wt% of GO reached high surface temperature of 117.8°C within 35 s, and also it exhibits high electromagnetic interference shielding efficiency value of 79.08 dB. The high flexibility, excellent conductivity, electromagnetic shielding efficiency and joule heating performance of GO-Ag coated cotton fabric suggesting that the GO synthesized from spent batteries will be a potential and valuable resource for the new generation of wearable electronics.
如今,可穿戴电子产品的研究因其在个性化健康监测和治疗、能量转换和存储以及人机界面系统中的潜在应用而受到极大的吸引力。在此,我们报道了一种使用氧化石墨烯(GO)和硝酸银(AgNO3)制备具有优异焦耳热和高电磁屏蔽性能的导电棉布的简单方法。本研究中使用的GO完全由废电池合成,以最大限度地减少环境污染。系统地研究了其表面形貌、元素分析、导电性、热行为和电磁屏蔽性能。由于高导电性,含有5wt%GO的GO-Ag涂层棉在35s内达到117.8°C的高表面温度,并且表现出79.08dB的高电磁干扰屏蔽效率值,GO-Ag涂层棉布的电磁屏蔽效率和焦耳热性能表明,用废电池合成的GO将成为新一代可穿戴电子产品的潜在和有价值的资源。
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引用次数: 0
Corresponding measurement-based patternmaking method for customized gloves to support smart wearables 基于相应测量的定制手套图案制作方法,支持智能穿戴设备
IF 3.2 4区 工程技术 Q1 MATERIALS SCIENCE, TEXTILES Pub Date : 2023-01-01 DOI: 10.1177/15280837231188966
H. Kim, Yujin Hong, H. Choi
This study developed a corresponding measurement-based patternmaking (CMP) method for customized gloves applicable to different hand shapes to support the manufacturing of smart wearables. This method can be used directly to implement a 2D block pattern of gloves by hand measuring and 3D scanning alone. Our customized glove prototype was manufactured considering the glove’s functionality and usability and in accordance with the protocol designed, targeting individual participants. The CMP method for customized gloves was verified by checking the function and functional fit of the customized glove prototype through a wear test that compared the prototype with a commercial glove. In the process, the rules of the existing CMP method for customized leggings were adjusted for the protocol to comply with the structural specificity of the hand. Accordingly, a guideline for customized gloves’ patternmaking was proposed to help future developers. The originality of the CMP method lies in the pattern construction of a perfectly matched size, a side panel structure of C-curve fingers, and patterns for a trapezoid hand proximal part structure. Furthermore, the newly devised CMP method for customized gloves can be used as a baseline for smart wearable devices to offer high functionality and usability for individuals with unique hand shapes who need customized gloves.
这项研究开发了一种相应的基于测量的图案制作(CMP)方法,用于定制手套,适用于不同的手形,以支持智能可穿戴设备的制造。该方法可以直接用于通过手动测量和单独的3D扫描来实现手套的2D块图案。我们定制的手套原型是根据手套的功能和可用性,并根据设计的协议,针对个人参与者制造的。通过将定制手套原型与商用手套进行比较的磨损测试,检查定制手套原型的功能和功能配合,验证了定制手套的CMP方法。在此过程中,对现有定制紧身裤CMP方法的规则进行了调整,以符合手部的结构特异性。因此,提出了一个定制手套图案制作指南,以帮助未来的开发人员。CMP方法的独创性在于完美匹配尺寸的图案结构、C形弯曲手指的侧板结构以及梯形手部近端结构的图案。此外,新设计的定制手套CMP方法可以作为智能穿戴设备的基线,为需要定制手套的手形独特的个人提供高功能性和可用性。
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引用次数: 0
Moisture insensitive analysis of polyester/viscose waste textiles using Near-Infrared spectroscopy and Orthogonalization of external parameters algorithm 基于近红外光谱和外参数正交化算法的涤纶/粘胶废纺织品湿不敏感分析
IF 3.2 4区 工程技术 Q1 MATERIALS SCIENCE, TEXTILES Pub Date : 2023-01-01 DOI: 10.1177/15280837231187671
Xun Qiu, Yuanyuan Liu, Xiaoqiang Zhang, Dongzhi Liu, Ran Wang, Chong Wang, Jun Liu, Wei Liu, Yan Gong
Near-Infrared (NIR) spectroscopic analyses can be applied in waste textile recycling as a rapid and non-invasive method to provide both qualitative and quantitative results. However, it has been a challenge to enhance the accuracy rate of NIR-based waste textile sorting due to the major influences from water contexts in the samples. Orthogonalization of External Parameters (EPO) has been introduced to reduce the interference from water absorption in NIR spectral signals for better accuracy and reliability in modeling. Here we explore the feasibility of applying EPO strategy with varieties of algorithms, including partial least squares regression (PLS), artificial neural network (ANN), decision tree (DT), random forest (RF), gradient boosting decision tree (GBDT), extreme random tree (Extra-tree), decision tree model based on AdaBoost algorithm (AdaBoost-tree), support Vector machine (SVM), one-dimensional convolutional neural network (1D-CNN), and one-dimensional convolutional neural network with improved Inception structure (1D-Inception-CNN). 216 waste textiles samples from Xinjiang, China, were studied with different moisture levels. Among them, 80 samples were used to develop the EPO algorithm, 112 were used to establish the prediction models, and 24 were used as test datasets. Then, the samples were scanned using a near-infrared spectrometer at different moisture regain rates. Our results showed that the moisture content of waste textiles had strong absorption peaks near 1150 and 1450 nm, leading to a decrease in the near-infrared reflectance of waste textiles. To verify the effectiveness of the EPO algorithm, the decision coefficients (R2 score) and other indicators of the model without the EPO process and the model with EPO process are systematically compared. Our results show that the EPO algorithm preprocessing improves the accuracy of the NIR model (The average decision coefficient (R2 score) of the models was increased by 0.83), especially when the moisture interference level is significant. Therefore, the EPO integrated modeling method is a reliable approach for better accuracy in NIR-based waste textile sorting.
近红外(NIR)光谱分析可以作为一种快速、无创的方法应用于废纺织品回收,提供定性和定量结果。然而,由于样品中水环境的主要影响,提高基于近红外的废纺织品分拣的准确率一直是一个挑战。引入了外部参数正交化(EPO),以减少近红外光谱信号中吸水的干扰,从而提高建模的准确性和可靠性。在这里,我们探索了将EPO策略与各种算法相结合的可行性,包括偏最小二乘回归(PLS)、人工神经网络(ANN)、决策树(DT)、随机森林(RF)、梯度增强决策树(GBDT)、极端随机树(Extra树)、基于AdaBoost算法的决策树模型(AdaBoost-tree)、支持向量机(SVM),一维卷积神经网络(1D-CNN)和具有改进的Inception结构的一维卷积神经网(1D Inception CNN)。对来自中国新疆的216个不同水分水平的废弃纺织品样品进行了研究。其中,80个样本用于开发EPO算法,112个样本用于建立预测模型,24个样本用作测试数据集。然后,使用近红外光谱仪以不同的回潮率对样品进行扫描。我们的结果表明,废纺织品的水分含量在1150和1450 nm附近具有较强的吸收峰,导致废纺织品的近红外反射率降低。为了验证EPO算法的有效性,系统地比较了无EPO过程和有EPO过程的模型的决策系数(R2得分)和其他指标。我们的结果表明,EPO算法预处理提高了NIR模型的准确性(模型的平均决策系数(R2分数)提高了0.83),尤其是当水分干扰水平显著时。因此,EPO集成建模方法是一种可靠的方法,可以在基于近红外的废纺织品分拣中获得更好的精度。
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引用次数: 0
Dimensionless study of the fiber arrangement on particle filtration characteristics in a multi-fiber filter 多纤维过滤器中纤维排列对颗粒过滤特性的无因次研究
IF 3.2 4区 工程技术 Q1 MATERIALS SCIENCE, TEXTILES Pub Date : 2023-01-01 DOI: 10.1177/15280837231200030
Jianhua Fan, Kun Yang, Liang Zhang, Lu Wang, Zhiwu Han
In this paper, two-dimensional numerical simulations are performed to investigate the particle filtration performance of multi-fiber filters using computational fluid dynamics ( CFD) technology. We combine fluid and particle properties as well as fiber size into single dimensionless numbers to analyze the influence of fiber arrangements on the system pressure drop and capture efficiency during the filtration process. The results indicate that the motion and deposition of aerosol particles significantly depend on the combined effects of Brownian diffusion, interception and inertial impaction mechanisms. The capture of aerosol particles with diameters less than 0.1 [Formula: see text] is strongly determined by the Brownian diffusion mechanism. For the case where interception and inertia impaction mechanisms dominate, particles with diameters in the range of 1–10 [Formula: see text] are more easily captured. In addition, the filter with a staggered fiber array structure exhibits a higher capture efficiency than that of parallel and random cases. From the quality factor standpoint, filters with both the staggered and random fiber arrangements show a better filtration performance. The research results can provide a fundamental understanding of the particle filtration process and the theoretical basis for filter design and optimization.
本文采用计算流体力学(CFD)技术对多纤维过滤器的颗粒过滤性能进行了二维数值模拟。我们将流体和颗粒特性以及纤维尺寸组合成单个无量纲数,以分析过滤过程中纤维排列对系统压降和捕获效率的影响。结果表明,气溶胶粒子的运动和沉积在很大程度上取决于布朗扩散、拦截和惯性撞击机制的综合作用。直径小于0.1的气溶胶颗粒的捕获[公式:见正文]主要由布朗扩散机制决定。对于拦截和惯性冲击机制占主导地位的情况,直径在1-10范围内的颗粒更容易被捕获[公式:见正文]。此外,具有交错光纤阵列结构的滤波器表现出比平行和随机情况更高的捕获效率。从质量因素的角度来看,交错和随机纤维排列的过滤器显示出更好的过滤性能。研究结果可以为颗粒过滤过程提供基本的理解,为过滤器的设计和优化提供理论依据。
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引用次数: 0
Lightweight panels with high delamination resistance made of integrally woven truss-like fabric structures 由整体编织桁架状织物结构制成的轻质板,具有高分层阻力
IF 3.2 4区 工程技术 Q1 MATERIALS SCIENCE, TEXTILES Pub Date : 2023-01-01 DOI: 10.1177/15280837221150202
M. Vorhof, C. Sennewald, P. Schegner, M. Q. Pham, G. Hoffmann, T. Gereke, C. Cherif
Lightweight panels are of high relevance for various applications, such as automotive, aerospace, civil engineering, and achieve high stiffnesses and strengths at low self-weight. The sandwich principle is commonly used to manufacture the panels, although conventional materials and reinforcement structures often limit the design and application of the panels in a wide range of possible applications. The reason for this is that lightweight panels fail either under combined compressive/shear loading or as a result of delamination of the individual layers. In this article, novel fabric structures are presented as a basis for the fabrication of lightweight panels that effectively overcome these deficiencies. These fabrics have a spatial truss-like structure, with the core and top layer being connected by continuously running reinforcing fibers. This results in high panel stability and high delamination resistance, which are evaluated in this article using mechanical tests in compression, flexure and combined tension-shear. The results are related to sample panels with conventional honeycomb core as reference. The high potential and excellent delamination resistance of the new fabric-based lightweight panels is shown in the result of the tests.
轻质面板与各种应用具有高度相关性,如汽车、航空航天、土木工程,并在低自重下实现高刚度和强度。夹层原理通常用于制造面板,尽管传统的材料和加固结构经常限制面板在广泛的可能应用中的设计和应用。原因是轻质面板在组合压缩/剪切载荷下失效,或者是由于单个层的分层而失效。在这篇文章中,新型织物结构被提出作为制造轻质面板的基础,以有效地克服这些缺陷。这些织物具有空间桁架状结构,芯部和顶层通过连续运行的增强纤维连接。这导致了高面板稳定性和高抗分层性,本文使用压缩、弯曲和组合拉伸剪切的机械测试对其进行了评估。该结果与以传统蜂窝芯为参考的样品板有关。测试结果表明,新型织物基轻质面板具有高潜力和优异的抗分层性能。
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引用次数: 0
Influence of fabric permeability on breathing phenomenon of supersonic parachute 织物透气性对超音速降落伞呼吸现象的影响
IF 3.2 4区 工程技术 Q1 MATERIALS SCIENCE, TEXTILES Pub Date : 2023-01-01 DOI: 10.1177/15280837231171733
Shunchen Nie, Li Yu, Yanjun Li, Zhihong Sun, Bowen Qiu
In order to investigate the dynamics and vortex shedding of flexible supersonic canopies, a compressible permeability model combined with fabric structure parameters is proposed, and the periodic oscillation of the supersonic parachute which is referred to as breathing phenomenon is simulated based on the Arbitrary Langrangian Eulerian (ALE) method. The calculated results by new permeability model are consistent with the experimental results. The underlying mechanism of canopy breathing motion is then investigated. Moreover, the influence of canopy permeability on breathing phenomenon of supersonic parachute is analyzed. The results indicate that the periodic growth and shedding of the canopy vortex causes the variation of the pressure differential, which finally lead to the periodic oscillation of the canopy. With the increase of fabric permeability, the vortex rolled up from the canopy skirt move backward and become more slender. The influence of vortex shedding on canopy breathing motion weakened. Those lead to the decrease of the average value of canopy projected area and parachute dynamic load. So are the oscillation amplitude and frequency. The parachute deceleration performance decreases while the parachute swing angle decreases as the canopy permeability increases.
为了研究柔性超声速伞盖的动力学特性和旋涡脱落问题,提出了结合织物结构参数的可压缩透气性模型,并基于任意朗日欧拉(ALE)方法对超声速伞盖的周期性振荡(即呼吸现象)进行了数值模拟。新渗透率模型的计算结果与实验结果吻合较好。研究了冠层呼吸运动的潜在机制。此外,还分析了冠层透气性对超音速降落伞呼吸现象的影响。结果表明,冠层涡的周期性生长和脱落引起了压差的变化,最终导致冠层的周期性振荡。随着织物透气性的增加,从伞裙卷起的旋涡向后移动,变得更细。旋涡脱落对冠层呼吸运动的影响减弱。这导致伞盖投影面积平均值和伞动载荷的减小。振荡振幅和频率也是如此。随着伞盖透气性的增大,降落伞的减速性能降低,降落伞摆角减小。
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引用次数: 0
Recent advances of textile sorbents for oil spills cleanup: A review 纺织吸附剂用于石油泄漏清理的研究进展
IF 3.2 4区 工程技术 Q1 MATERIALS SCIENCE, TEXTILES Pub Date : 2023-01-01 DOI: 10.1177/15280837231186652
B. Zaarour, Wanjun Liu
Oil sorbents play a significant role in the treatment processes of oil spills, therefore, enhancing the oil-water separation capacity of sorbents has been charming the consideration of scientific researchers. To improve the properties of oil sorption and simplify the process of oil recovery, many advanced oil sorbent devices have been projected recently. Different types of materials are used as sorbents for oil-water separation, however, up to now, there is no review paper focused on textile (woven, knitting, and nonwoven) sorbents, and compared with them. In this review paper, the classification of textile fabrics, properties of surface wetting, fabrication methods of textile sorbents for oil spill cleanup, their properties, and recent applications in the field of oil cleanup are studied. We believe this review can serve as an essential reference for the formation of textile sorbents, their properties, and their applications in the field of oil spill cleanup.
吸油剂在溢油处理过程中起着重要的作用,因此,提高吸油剂的油水分离能力一直是科研人员关注的问题。为了提高吸油性能,简化采油过程,近年来研制了许多先进的吸油装置。不同类型的材料被用作油水分离的吸附剂,但到目前为止,还没有针对纺织(梭织、针织和非织造)吸附剂的综述文章,并与它们进行比较。本文综述了纺织织物的分类、表面润湿性能、油污清除用纺织品吸附剂的制备方法、性能及其在油污清除领域的应用现状。本文综述可为纺织吸附剂的形成、性能及其在溢油清理领域的应用提供重要参考。
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引用次数: 1
Development of a hand classification system for smart hand wearables 智能手穿戴设备手部分类系统的开发
IF 3.2 4区 工程技术 Q1 MATERIALS SCIENCE, TEXTILES Pub Date : 2023-01-01 DOI: 10.1177/15280837231188529
Yujin Hong, H. Kim, H. Choi
Research purpose: This study aimed to lay a research foundation for smart hand wearable design by classifying the right-hand data of 4545 adults aged 20 to 69. Further, to increase the practical applicability of the hand classification system, a hand type discrimination method and regression equations for the hand dimensions of each type were presented. Methods: This study statistically analyzed eighth Size Korea data with IBM SPSS Ver.26.0. Cluster analysis was performed to classify both finger length and circumference type. Discriminant analysis was conducted, yielding discriminant functions to aid potential smart hand wearable wearers in self-diagnosing their hand types. Linear regression analysis yielded regression equations for the detailed finger dimensions for the pattern-making of smart hand wearables. Results: The finger length type was categorized into four types: the Uphill type, Downhill type, Mountain type, and Horizon type for both men’s and women’s hands. The finger circumference type was categorized into two types, the Cone and Cylinder types, for both men’s and women’s hands. The discriminant function showed a mean accuracy rate of 89.9% and the regression equations a mean explanatory power of 72.9%. Conclusion: The hand classification system proposed in this study aimed to improve the fingertip fit of smart hand wearable products by analyzing the configuration of motion tracking gloves or haptic gloves. In addition, considering the practical applicability for both wearers and designers of smart hand wearables, a discrimination method of finger types for wearers’ self-diagnosis and regression functions of finger dimensions for designers’ pattern making were provided.
研究目的:本研究通过对4545名20 - 69岁成年人右手数据进行分类,为智能手穿戴设计奠定研究基础。为了提高手型分类系统的实用性,提出了手型判别方法和各手型尺寸的回归方程。方法:本研究采用IBM SPSS Ver.26.0软件对八级韩国数据进行统计分析。采用聚类分析对手指长度和围度进行分类。进行判别分析,得到判别函数,帮助潜在的智能手穿戴者自我诊断自己的手型。线性回归分析得到了智能手穿戴式制模的详细手指尺寸回归方程。结果:男性和女性手指长度类型均分为上坡型、下坡型、山地型和地平线型4种类型。男性和女性的手指周长类型分为两种类型,锥型和圆柱形。判别函数的平均准确率为89.9%,回归方程的平均解释力为72.9%。结论:本研究提出的手部分类系统,旨在通过分析运动追踪手套或触觉手套的配置,提高智能手穿戴产品的指尖贴合度。此外,考虑到智能手穿戴设备对佩戴者和设计师的实用性,提供了一种用于佩戴者自我诊断的手指类型判别方法和用于设计师图案制作的手指尺寸回归函数。
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引用次数: 1
Fe3O4/SiO2/polymer hybrid biosorbent based on an etch-fill strategy for heavy metal ion adsorption 基于刻蚀填充策略的Fe3O4/SiO2/聚合物杂化生物吸附剂对重金属离子的吸附
IF 3.2 4区 工程技术 Q1 MATERIALS SCIENCE, TEXTILES Pub Date : 2023-01-01 DOI: 10.1177/15280837221146292
Jin Tao, Ying Zhu, Tao Huang, Jishu Zhang, Jianbing Wu, Lei-gen Liu
Heavy metal contamination is a serious concern worldwide. In order to remove heavy metal ions from wastewater efficiently, multifunctinoal biomass-based material have been utilized. Herein, hyperbranched polymer modified cellulose biomass (HBP-CB) derived from textile waste materials ramie fibers was successfully developed by construction of Fe3O4/SiO2/polymer multiple structure through an etch-fill strategy. Specifically, Fe3O4 and SiO2 particles were introduced to the oxidation etching cellulose surface, and subsequently modified by hyperbranched polymer The adsorption behavior of the adsorbent toward two classes of heavy metal ions was investigated. The results indicated that HBP-CB owned excellent adsorption capacities for chromium and Cu(II) with maximum 123.5 mg/g and 149.0 mg/g and magnetic recovery performance in aqueous medium. These are owing to the oxidization etching biomass matrix with a higher BET surface area of 4.61 m2/g and the hybrid multiple structure modified by functional hyperbranched polymer with high dense adsorptive sites on the matrix. The adsorption behavior was well described by pseudo-second-order kinetic model and Langmuir isotherm model, revealing a rapid surface adsorption and monolayer spontaneous chemical adsorption. For recycling, 81% of adsorption capacity could be retained after five recovery cycles. These demonstrate that the hybrid multiple structure based on biomass, nanomaterials and polymer could provide sustainable and high-performance adsorption property for wastewater treatment.
重金属污染是全世界关注的一个严重问题。为了有效地去除废水中的重金属离子,利用了多功能生物质基材料。本文以纺织废料苎麻纤维为原料,通过蚀蚀填充策略构建Fe3O4/SiO2/聚合物复合结构,成功开发了超支化聚合物改性纤维素生物质(HBP-CB)。将Fe3O4和SiO2颗粒引入氧化蚀刻纤维素表面,然后用超支化聚合物对其进行改性,研究了该吸附剂对两类重金属离子的吸附行为。结果表明,HBP-CB对铬和Cu(II)具有优异的吸附能力,在水中的吸附能力分别为123.5 mg/g和149.0 mg/g,并具有磁回收性能。这是由于氧化蚀刻的生物质基质具有较高的BET表面积(4.61 m2/g)和功能超支化聚合物修饰的杂化复合结构在基质上具有高密度的吸附位点。拟二级动力学模型和Langmuir等温线模型很好地描述了吸附行为,表现出快速的表面吸附和单层自发化学吸附。经5次循环后,可保留81%的吸附量。这表明,基于生物质、纳米材料和聚合物的复合复合结构可以为废水处理提供可持续和高性能的吸附性能。
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引用次数: 0
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Journal of Industrial Textiles
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