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Solid-State Characterization of Heteropolyacid-Phyllosilicate Complexes: Structural, Morphological and Thermal Properties 杂多酸-层状硅酸盐配合物的固态表征:结构、形态和热性能
Pub Date : 2023-05-23 DOI: 10.5539/jmsr.v12n1p36
P. Vuillaume, A. Mokrini, L. Robitaille, P. Bébin, Lori Leblond
We have previously described the complex formation from a synthetic smectite clay, Sumecton SA (SSA), and the heteropolyacid (HPA), 12-phosphotungstic acid (PTA). Three new synthetic layered aluminosilicate clays of the smectite- [Lucentite SWN (SWN)] and (fluoro)mica-type [Tetrasilicic mica (TSM); Somasif ME100, (SME)] have been self-assembled with PTA, at a specific PTA-clay weight ratio of 5. New protogenic inorganic complexes have been prepared for the future fabrication of proton exchange membrane for fuel cell devices (PEMFC). Complex formation, thermal and structural properties of PTA-phyllosilicate complexes have been investigated using EDX, XRD, SEM, and DRIFT. EDX indicates that complexes incorporate a substantial amount of PTA (50-60% w/w) and that a moderate depletion of Mg2+ ions from octahedral layers of micas clays occurs during the process compared to smectite ones. In contrast, a significant amount of F is removed from the octahedral framework of the mica clays. DRIFT experiments indicate that the Keggin structure is preserved within all complexes and that complex formation predominantly involves the external oxygen (W-Od) of PTA. According to Patterson functions, coherence lengths - which reflect for the virgin clays the extent of the longitudinal platelet stacking (Lc) - of the two smectite clays (Lc ~25 Å) are significantly lower than for their analogous of the mica type (Lc = 180-225 Å). Clays in complexes are characterized by the loss of in-plane organization but are still partially ordered. The nature of the order is still speculative but could be related to the formation of a new inorganic PTA species formed during the complex formation. Compared to the virgin clays, the order of smectite complexes is maintained in the same range (Lc = 27-42 Å) while for mica complexes, coherence lengths are dramatically reduced to ~ 60 Å. All PTA-activated complexes contain a substantial amount of amorphous silica, which tends to increase when heated at temperatures above 280 oC. However, the Keggin structure within the complexes is at least stable up to 280 oC and even, for the most robust TSM complex, up to 450 oC.
我们之前已经描述了由合成蒙脱石粘土Sumecton SA (SSA)和杂多酸(HPA) - 12-磷钨酸(PTA)形成的络合物。三种新合成的蒙脱石- [Lucentite SWN (SWN)]和(氟)云母型[四硅云母(TSM)]层状铝硅酸盐粘土Somasif ME100, (SME)]与PTA自组装,特定PTA-粘土质量比为5。为制备燃料电池质子交换膜(PEMFC)制备了新的原生无机配合物。采用EDX、XRD、SEM和DRIFT等方法研究了PTA-phyllosilicate配合物的形成、热性能和结构性能。EDX表明,配合物包含了大量的PTA (50-60% w/w),并且在此过程中,与蒙脱石相比,云母粘土八面体层中的Mg2+离子发生了适度的损耗。相反,大量的F从云母粘土的八面体框架中被去除。DRIFT实验表明,所有配合物都保留了Keggin结构,配合物的形成主要涉及PTA的外氧(W-Od)。根据Patterson函数,反映两种蒙脱石粘土(Lc ~25 Å)纵向血小板堆积(Lc)程度的相干长度明显低于类似的云母粘土(Lc = 180-225 Å)。粘土在配合物中的特点是失去了面内组织,但仍然部分有序。该顺序的性质仍是推测性的,但可能与在复杂形成过程中形成的新的无机PTA物种的形成有关。与原始粘土相比,蒙脱石配合物的阶数保持在相同的范围内(Lc = 27-42 Å),而云母配合物的相干长度则大幅降低至~ 60 Å。所有pta激活的配合物都含有大量的无定形二氧化硅,当温度高于280℃时,无定形二氧化硅倾向于增加。然而,配合物中的Keggin结构在280℃下至少是稳定的,对于最稳定的TSM配合物,甚至可以达到450℃。
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引用次数: 0
Mechanical Performance of Hybrid Graphene Nanoplates, Fly-Ash, Cement, Silica, and Sand Particles Filled Cross-Ply Carbon Fibre Woven Fabric Reinforced Epoxy Polymer Composites Beam and Column 混合石墨烯纳米板、粉煤灰、水泥、二氧化硅和沙子颗粒填充交叉层碳纤维编织织物增强环氧聚合物复合材料梁和柱的力学性能
Pub Date : 2023-04-10 DOI: 10.5539/jmsr.v12n1p22
T. Quadflieg, V. Srivastava, T. Gries, Shantanu Bhatt
The main goal of this study is to reduce the brittleness of a fibre-reinforced cement base structure when exposed to the effects of graphene nanoplates, fly ash, silica, sand, and cement fillers to better understand the effect of hybrid nano/micro particle fillers on the mechanical performance of cross-ply carbon fibre reinforced epoxy resin composites. A three-point bending test through the width was used to measure flexural strength. The impact tests Izod at low impact velocity and Charpy through the thickness were used to determine the dynamic fracture strengths of pre-cracked and non-cracked composite samples. Also, the compressive test method was used to measure the compressive strength of hybrid particles and short glass fibre-reinforced epoxy resin composite square and circular columns. The results show compressive strength and flexural strength. Izod impact energy, Charpy impact energy, and dynamic fracture toughness of hybrid nano/microparticle-filled fibre composites have higher values than virgin fibre composites due to the influence of graphene nanoparticles and perfect interface bonding between two dissimilar molecules of nano and microparticles, which improve the fracture toughness and absorb impact energy. Overall, the results indicate that molecules of nano/microparticle-filled carbon fibre and glass fibre-reinforced epoxy resin composites can be used in aggressive environments because of the improved mechanical properties in comparison to the virgin fibre composites. In addition, SEM micrographs clearly indicate that nano- and microparticles are resistant crack propagation and deboned of matrix fibres.
本研究的主要目的是降低石墨烯纳米板、粉煤灰、二氧化硅、沙子和水泥填料对纤维增强水泥基结构脆性的影响,从而更好地了解纳米/微颗粒混合填料对交叉层碳纤维增强环氧树脂复合材料力学性能的影响。通过宽度的三点弯曲试验来测量弯曲强度。采用低冲击速度Izod试验和厚度Charpy试验测定了预裂和未裂复合材料试样的动态断裂强度。采用抗压试验方法对混杂颗粒与短玻璃纤维增强环氧树脂复合材料方柱和圆柱的抗压强度进行了测试。结果显示了抗压强度和抗折强度。由于石墨烯纳米粒子的影响以及纳米和微颗粒两种不同分子之间完美的界面键合,提高了断裂韧性,吸收了冲击能,纳米/微颗粒混合填充纤维复合材料的Izod冲击能、Charpy冲击能和动态断裂韧性均高于原始纤维复合材料。总的来说,研究结果表明,纳米/微粒填充的碳纤维和玻璃纤维增强环氧树脂复合材料可以在恶劣环境中使用,因为与原始纤维复合材料相比,它们的机械性能得到了改善。此外,SEM显微图清楚地表明,纳米颗粒和微颗粒对基体纤维的裂纹扩展和去骨有抵抗作用。
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引用次数: 0
A Short Literature Review on Turning and Milling of Cobalt Alloys 钴合金车削和铣削的简要文献综述
Pub Date : 2023-04-06 DOI: 10.5539/jmsr.v12n1p9
Edinan Casagrande, Diógenes Barbosa Teles, M. Policena
Among the existing machining processes, turning and milling are characterized as the most used and consequently are considered the most important. Machining moves a market estimated at around 10% of gross national production. Many industrial components and parts are subjected to severe operating conditions, in corrosive environments, high temperatures what causes wear. With the development of industries, there is a need for steel alloys with different properties, to meet different purposes. Cobalt alloys, as well as others, arose from the need to develop metals that would meet the growing demand in applications with high temperatures and high working stress in gas turbine components. Due to their high mechanical and thermal resistance, these alloys are difficult to machining, a situation that requires in-depth studies to reduce process costs and improve the surface quality of machined parts. Machined surfaces may have different textures depending on the process. Turning and milling generate grooved profiles due to tool/part interaction. In many cases, roughness is used as an output parameter to control the process. Another important factor is the wear of cutting tools, which must be selected according to the material properties of the workpiece, machine tool and other parameters that influence its wear. Controlling the useful life of the tool is a decisive factor when you want to avoid loss of productivity, with fewer stops for changes, consequently, you have a more effective and economical production. The present study presents a brief review of the literature regarding turning and milling of cobalt alloys, regarding the optimization of machining parameters, tools used and the use of lubri-cooling techniques, with the objective of reducing the roughness of the parts, the tool wear, improve surface integrity and contribute to the sustainability of manufacturing processes when machining difficult-to-cut materials. In this review, a comparative analysis of the results is presented, indicating the gaps in research such as classification and processing of alloys, formation of carbides with non-uniform distribution, which impairs the performance of the tools. Some suggestions for future work indicate the absence of studies on the use of diamond and CBN tools, clarify the interaction medium lubricant-coolant-coating of the tools-alloy chemical composition and cutting parameters, in addition to dynamic analyzes in the cutting of hardened materials.
在现有的加工工艺中,车削和铣削是使用最多的,因此被认为是最重要的。据估计,机械加工市场约占国民生产总值的10%。许多工业零部件都要经受严酷的操作条件,在腐蚀性环境中,高温下会造成什么磨损。随着工业的发展,需要具有不同性能的钢合金,以满足不同的用途。钴合金以及其他合金的出现,是由于需要开发金属,以满足燃气轮机部件在高温和高工作应力应用中日益增长的需求。由于这些合金具有较高的机械和热阻,因此难以加工,这需要深入研究以降低加工成本并提高加工零件的表面质量。根据加工过程的不同,加工表面可能具有不同的纹理。车削和铣削由于刀具/零件的相互作用而产生槽形轮廓。在许多情况下,粗糙度被用作控制过程的输出参数。另一个重要的因素是刀具的磨损,必须根据工件的材料特性、机床和其他影响其磨损的参数来选择。控制刀具的使用寿命是避免生产力损失的决定性因素,减少更换停机时间,从而获得更有效和更经济的生产。本研究简要回顾了关于钴合金车削和铣削的文献,关于加工参数的优化,使用的工具和使用润滑冷却技术,目的是减少零件的粗糙度,刀具磨损,提高表面完整性,并有助于加工难切削材料时制造过程的可持续性。本文对研究结果进行了对比分析,指出了合金的分类和加工、形成分布不均匀的碳化物等方面的研究不足,影响了刀具的使用性能。对未来工作的一些建议指出,缺乏对金刚石和CBN刀具使用的研究,澄清刀具的相互作用介质润滑剂-冷却剂-涂层-合金化学成分和切削参数,以及对淬火材料切削的动态分析。
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引用次数: 0
An Improved Model for Estimation of Mechanical Properties of Polymer-Clay Nano-Composites 聚合物-粘土纳米复合材料力学性能评估的改进模型
Pub Date : 2023-02-27 DOI: 10.5539/jmsr.v12n1p1
A. Al-Abduljabbar
Polymer-clay nanocomposites are more popular in many industries and applications due to improved mechanical and gas barrier properties over pure polymers and classical polymer-based composites. The mechanism by which clay platelets, with thicknesses in the nanometer range, as opposed to the hundred-nanometer range in the other two dimensions, introduce the mechanical and other properties improvement can be attributed to their high efficiency in creating discontinuities to flows through the bulk matrix polymer material. However, the extent of this improvement depends on the success of separation or achieving full exfoliation of the clay platelets through the bulk matrix. Since such full exfoliation is not achievable experimentally, the aspect ratio of the filler particles is not a simple value that mathematical models employ to describe mechanical properties. In this work, a modification is proposed to improve such models by using relationships utilizing different concentrations of varying filler platelets thicknesses. The improvements in elastic tensile modulus are discussed with consideration of the effect of clay platelet inclusions geometry as depicted through the proposed modification to considered models to capture the effect of nano-platelets on the properties of the composite.
聚合物-粘土纳米复合材料在许多行业和应用中更受欢迎,因为它比纯聚合物和经典聚合物基复合材料具有更好的机械和气体阻隔性能。与其他两个维度的百纳米厚度相比,厚度在纳米范围内的粘土片的机械性能和其他性能改善的机制可归因于它们在通过大块基质聚合物材料时产生不连续的高效率。然而,这种改善的程度取决于分离的成功与否或粘土血小板通过散装基质的完全剥落。由于这种完全的剥落在实验上是无法实现的,填料颗粒的长径比不是数学模型用来描述机械性能的简单值。在这项工作中,提出了一种修改,以改善这样的模型,利用不同浓度的关系利用不同的填充血小板厚度。讨论了弹性拉伸模量的提高,并考虑了粘土血小板包裹体几何形状的影响,通过提出的修正来描述考虑模型,以捕捉纳米血小板对复合材料性能的影响。
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引用次数: 0
Reviewer acknowledgements for Journal of Materials Science Research, Vol. 11, No. 2 《Journal of Materials Science Research》第11卷第2期审稿人致谢
Pub Date : 2023-01-31 DOI: 10.5539/jmsr.v11n2p33
Jhon Martin
Reviewer acknowledgements for Journal of Materials Science Research, Vol. 11, No. 2, 2022.
《Journal of Materials Science Research》,Vol. 11, No. 2, 2022。
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引用次数: 0
Applying Thermo-Reactive Diffusion Method to Surface Coating of H13 Tool Steel Using Ferrovanadium, Ferrochromium, and Misch Metal 热反应扩散法在钒铁、铬铁和杂金属H13工具钢表面涂层中的应用
Pub Date : 2023-01-30 DOI: 10.5539/jmsr.v11n2p23
Nastran Najafian, A. Moloodi, E. Karimi
The thermo-reactive diffusion (TRD) process is a method for surface hardening that improves the hardness, corrosion resistance, and wear resistance of the materials. In this study, the effect of composition was investigated, by using 8, 12, 16, 20, and 24 wt% of ferrochrome and ferrovanadium with equal amounts, along with 3 wt% aluminum and borax. The TRD process was carried out at 1000°C for 7 hours on AISI H13 hot work tool steel so that a complex coating of chromium-vanadium carbide was formed on the H13 substrate. Optical and scanning electron microscopes were used to evaluate the thickness and microstructure of the samples, respectively. Moreover, the amount of alloying elements and constituent phases on the surface were analyzed by point analysis and X-ray diffraction. The micro-hardness method was used to evaluate the hardness of the samples. The results of this study showed that by increasing the amount of ferroalloy, the hardness and thickness of the coating increase. The optimal composition with 8% ferrochrome and 8% ferrovanadium was found to yield a coating with a thickness of 7.65 μm and a hardness of 2115 HV.
热反应扩散(TRD)工艺是一种提高材料硬度、耐腐蚀性和耐磨性的表面硬化方法。在这项研究中,通过使用8、12、16、20和24 wt%的等量铬铁和钒铁,以及3 wt%的铝和硼砂,研究了组成的影响。对aisih13热加工工具钢在1000℃下进行7小时的TRD处理,在H13基体上形成了一层复杂的碳化钒铬涂层。利用光学显微镜和扫描电镜分别对样品的厚度和微观结构进行了评价。利用点分析和x射线衍射分析了合金表面合金元素和组成相的含量。采用显微硬度法对样品进行硬度评定。研究结果表明,随着铁合金用量的增加,涂层的硬度和厚度都有所增加。结果表明,以8%铬铁和8%钒铁为最佳配比,镀层厚度为7.65 μm,硬度为2115 HV。
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引用次数: 0
The Effect of Laser Irradiation on The Properties of Micro to Nanolayer Titanium Alloy 激光辐照对微纳米层钛合金性能的影响
Pub Date : 2023-01-30 DOI: 10.5539/jmsr.v11n2p11
H. Hebatalrahman
In this work, a new technique for Laser irradiation of Ti6Al4VELI was developed, this alloy is an alpha-beta structure, the irradiation was done at room temperature in the normal atmosphere without any external media, the effects of laser irradiation on the Ti6Al4VELI such as the chemical composition of the alloy before and after laser irradiation were recorded by Energy dispersive X-ray “EDX” technique. the affected zone (thickness) of the laser irradiation technique was limited to the surface in micro to the nanoscale. The variation in mechanical properties due to laser irradiation at different wavelengths was measured by the determination of the variation of modulus and hardness at maximum load with a number of pulses. The wear rate was measured for the Ti6Al4VELI before and after laser irradiation at 5000 pulses where the maximum improvement in the hardness occurs at all wavelengths, in the current study, it improves surface mechanical characteristics. The effect of laser irradiation on the structures was studied by SEM, the quantitative analysis was done at all irradiation conditions. Laser treatment is suitable for both field works and industry. The improvement in mechanical properties occurs due to microstructure changes without significant changes in chemical composition. the efficiency and lifetime of the alloys were increased, the work is registered as patent number 24014 in the Egyptian patent office.
本文研究了一种激光辐照Ti6Al4VELI合金的新技术,该合金为α - β结构,在室温正常气氛下进行辐照,无外界介质,用能量色散x射线“EDX”技术记录了激光辐照前后合金的化学成分等对Ti6Al4VELI合金的影响。激光辐照技术的影响区(厚度)仅限于微观到纳米尺度的表面。通过测定不同波长激光照射下的最大载荷下的模量和硬度变化,测量了不同波长激光照射下的力学性能变化。在5000脉冲激光照射前后测量了Ti6Al4VELI的磨损率,在所有波长下硬度都有最大的改善,在目前的研究中,它改善了表面力学特性。采用扫描电镜研究了激光辐照对结构的影响,并对不同辐照条件下的影响进行了定量分析。激光治疗既适用于野外作业,也适用于工业。机械性能的提高是由于微观结构的改变,而化学成分没有显著变化。提高了合金的效率和寿命,该工作已在埃及专利局注册为专利号24014。
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引用次数: 0
Heisenberg-Ivanenko Nonlinear Spinor Field Equation: Spherical Symmetric Soliton-Like Solutions in Gravitational Theory Heisenberg-Ivanenko非线性旋量场方程:引力理论中的球对称类孤子解
Pub Date : 2022-11-07 DOI: 10.5539/jmsr.v11n2p1
A. Essoun, M. A. Konnon, J. Edou, A. Adomou
This research work deals with the concept of soliton as regular localized stable solutions of nonlinear di erential equations. In this context, exact static, spherically symmetric solutions to Heisenberg-Ivanenko nonlinear spinor field equation have been obtained in General Relativity. We opted to the static spherical symmetric metric defined in the pseudoriemannian varieties. It has been shown that the obtained solutions are regular with localized energy density and a finite total energy. In addition, the total charge and the total spin are bounded. Therefore the obtained solutions of Heisenberg-Ivanenko nonlinear spinor field equation are soliton-like configurations. Note that the e ect of gravitational field on the properties of regular localized solutions significantly depends on the symmetry of the system.
本文研究了非线性微分方程的正则定域稳定解孤子的概念。在此背景下,得到了广义相对论中Heisenberg-Ivanenko非线性旋量场方程的精确静态球对称解。我们选择了静态球对称度规定义在伪黎曼变体。结果表明,所得到的解具有局域能量密度和有限总能量的正则性。此外,总电荷和总自旋是有界的。因此得到的非线性旋量场方程解是类孤子构型。注意,引力场对正则局域解性质的影响很大程度上取决于系统的对称性。
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引用次数: 0
Dynamic Fracture Toughness Behaviour of CFRP-Foam-CFRP Sandwich Composite and Particles Filled Hybrid Glass Fiber Cloth, Graphene Nanoplates Coated Glass Fiber Strand Composite Materials under Low Impact Velocity 低冲击速度下cfrp -泡沫- cfrp夹层复合材料及颗粒填充杂化玻璃纤维布、石墨烯纳米片涂覆玻璃纤维股复合材料的动态断裂韧性行为
Pub Date : 2022-05-23 DOI: 10.5539/jmsr.v11n1p70
V. Srivastava
The main objective of the present study is to investigate the dynamic fracture toughness behaviors of CFRP-Foam-CFRP sandwich composite of V-notched through -thickness, surface, and un-notched specimens under Izod, and Charpy impact tests.  The sandwich composite structures are made of cross-plied carbon fiber reinforced plastic (CFRP) composite faces with polyurethane foam core. CFRP composites are used to combine the upper face and the lower face through the core in stitched sandwich structures. Compressive strength of weight drop impact perforated and un-perforated sandwich composite specimens are measured from a universal testing machine. Also, particles (Al2O3, CNTs, and cement) filled glass fiber cloth and graphene nanoplates coated glass fiber strands reinforced polymer hybrid composite are fabricated for V-notched, un-notched Izod impact and Charpy impact tests. The results show that weight drop impact energy is lower than the Izod impact energy but higher than the Charpy impact energy, whereas the dynamic fracture toughness of Izod impact energy is more than the Charpy and weight drop impact energy due to geometry of impactor and sandwich specimen. However energy and dynamic fracture toughness of Al2O3, CNTs, and Cement filled un-notched hybrid composites higher than the notched hybrid composites under Izod Impact. The dynamic fracture toughness and energy of CNTs filled hybrid composites is higher than the sandwich composites, Al2O3, and Cement filled hybrid composites under Charpy Impact.
本研究的主要目的是研究cfrp -泡沫- cfrp夹层复合材料的v形缺口穿透厚度、表面和未缺口试样在Izod和Charpy冲击试验下的动态断裂韧性行为。夹层复合材料结构是由碳纤维增强塑料(CFRP)复合材料面与聚氨酯泡沫芯交叉层合而成。采用CFRP复合材料通过缝芯将上、下表面结合在一起。在万能试验机上测定了有孔和无孔夹层复合材料试样的抗压强度。此外,还制备了填充玻璃纤维布的颗粒(Al2O3、CNTs和水泥)和涂覆石墨烯纳米板的玻璃纤维股增强聚合物杂化复合材料,用于v形缺口、非缺口Izod冲击和Charpy冲击试验。结果表明:由于冲击体和夹层试样的几何特性,失重冲击能低于伊佐德冲击能,但高于查比冲击能,而伊佐德冲击能的动态断裂韧性大于查比冲击能和失重冲击能。而Al2O3、CNTs和水泥填充的非缺口杂化复合材料在Izod冲击下的能量和动态断裂韧性高于缺口杂化复合材料。在Charpy冲击作用下,CNTs填充复合材料的动态断裂韧性和能量均高于夹层复合材料、Al2O3和水泥填充复合材料。
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引用次数: 0
New Interferometric Method and Device for Measuring the X-Ray Train Length 新型干涉测量x射线列阵长度的方法及装置
Pub Date : 2022-05-23 DOI: 10.5539/jmsr.v11n1p85
H. R. Drmeyan, S. Mkhitaryan
A new interferometric method for measuring the length of the X-ray train is proposed, and a special interferometer, a device for measurement of the X-ray train length has been developed, created, and tested. The length of the X-ray train and the duration of coherent radiation are estimated and it has been proven that the interference pattern disappears when the difference of paths between the superimposing waves becomes greater than the length of the coherent X-ray train. The bound of a disappearance of the X-ray interference pattern is determined depending on the magnitude of the path differences. The length of the X-ray train is determined, which is close to the theoretically determined value.
提出了一种新的测量x射线列列长度的干涉仪方法,研制了一种专用的测量x射线列列长度的干涉仪,并进行了试验。估计了x射线序列的长度和相干辐射的持续时间,并证明了当叠加波之间的路径差大于相干x射线序列的长度时,干涉图样消失。x射线干涉图样消失的边界取决于路径差的大小。确定了x射线序列的长度,该长度接近于理论确定的值。
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引用次数: 1
期刊
Journal of Materials Science Research
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