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Biosorbent from Industrial Hemp Hurds for Copper Ions Removal 工业大麻中去除铜离子的生物吸附剂
Pub Date : 2019-12-01 DOI: 10.17706/ijmse.2018.6.4.114-125
L. Rozumová, Barbora Legátová
Screening a new biosorbent with low-cost and high efficiency from a biological waste material is a key to the adsorption of heavy metal ions from wastewater. The biosorbent from industrial hemp hurds was prepared from waste materials. In this study, the potential of this biosorbent has been investigated in removing of Cu(II) ions from the aqueous solution under optimized conditions. Waste material biosorbent was activated by hydrochloric acid in room temperature. The synthesized biosorbent was characterized by SEM, EDX, specific surface area and pore size distribution. The impact of pH, contact time and initial concentration on the pollutant removal efficiency was observed. The sorption kinetics were evaluated with pseudo-first and pseudo-second order kinetic models. Adsorption process has been modeled by the Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherms using linear regression. The results of this study indicated that the application of hemp hurds of Cannabis sativa waste material as a biosorbent is highly effective for the removal copper ions from wastewater.
从生物废弃物中筛选低成本、高效的新型生物吸附剂是吸附废水中重金属离子的关键。以工业大麻秸秆为原料制备生物吸附剂。在本研究中,研究了该生物吸附剂在优化条件下去除水溶液中Cu(II)离子的潜力。在室温条件下,用盐酸对垃圾生物吸附剂进行活化。对合成的生物吸附剂进行了SEM、EDX、比表面积和孔径分布等表征。考察了pH、接触时间和初始浓度对污染物去除率的影响。采用拟一级和拟二级动力学模型对吸附动力学进行了评价。吸附过程采用Langmuir, Freundlich, Temkin和Dubinin-Radushkevich等温线进行线性回归。本研究结果表明,利用大麻废渣作为生物吸附剂对废水中的铜离子有较好的去除效果。
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引用次数: 4
Effect of Alloy Composition on Microstructure and Martensitic Transformation Temperature of a Zr-Cu Shape Memory Alloy 合金成分对Zr-Cu形状记忆合金组织和马氏体相变温度的影响
Pub Date : 2019-12-01 DOI: 10.17706/ijmse.2018.6.4.93-98
Hitoo Tokunaga
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引用次数: 0
Evaluating the Performance of a Combined SHS-LHS System SHS-LHS组合系统的性能评估
Pub Date : 2019-12-01 DOI: 10.17706/ijmse.2018.6.4.106-113
Khan Habeeb Ur Rahman, M. M. Rahman
In the present work, a combined sensible heat storage-latent heat storage (SHS-LHS) system has been evaluated with Aragonite, which belongs to the category of Limestone, as the sensible heat storage material and Potassium Hydroxide (KOH) as the latent heat storage material. The performance of the combined sensible-latent heat storage system is analyzed and compared with a sensible only heat storage system by evaluating key parameters such as Heat Transfer Fluid (HTF) exit temperature, average temperature of the heat storage system and the amount of energy stored and retrieved during charging and discharging respectively. It was found that a combined sensible-latent heat storage system stabilizes the HTF exit temperature to around the temperature of the phase change material (PCM) during the discharge cycle. This has also been corroborated by other researchers in their experimental work. It was also found for both the systems (sensible and combined) that the larger the pellet diameter, the longer is the time taken by the Thermal Energy Storage System (TESS) to reach the maximum operating temperature. For both the systems, the temperatures remain at the maximum operating temperature for a longer duration at lower HTF flow rates. This helps in maintaining the stability of the temperatures in a TESS for a longer duration, which in turn, to a limited extent, offsets the losses caused due to a rapid reduction in the outlet temperature in a sensible TESS. The amount of energy retrieved from the combined system is larger than the energy that is retrieved from a sensible only TESS. All these findings point to the fact that using a combined sensible-latent TESS is highly advantageous as compared to a sensible only TESS.
本文以石灰石属文石为显热储热材料,氢氧化钾为潜热储热材料,对显热-潜热组合式储热系统进行了评价。通过对传热液出口温度、蓄热系统平均温度、充放电过程中蓄能量和回能量等关键参数的评价,分析了显潜热联合蓄热系统的性能,并与单纯显潜热系统进行了比较。研究发现,显潜热组合蓄热系统在放电周期内将HTF出口温度稳定在相变材料(PCM)温度附近。其他研究人员在实验工作中也证实了这一点。对于两种系统(敏感和组合),球团直径越大,储热系统(TESS)达到最高工作温度所需的时间越长。对于这两种系统,在较低HTF流量下,温度保持在最高工作温度的时间更长。这有助于在较长时间内保持TESS温度的稳定性,这反过来又在有限程度上抵消了由于敏感TESS出口温度迅速降低而造成的损失。从联合系统中获取的能量比从一个敏感的单独的TESS中获取的能量要大。所有这些发现都表明,与仅使用感隐TESS相比,使用联合感隐TESS具有很高的优势。
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引用次数: 0
Microstructural and Mechanical Properties of Bassar Forged Steel Bassar锻钢的显微组织和力学性能
Pub Date : 2019-04-19 DOI: 10.12691/AJMSE-7-1-2
Pali Kpelou, Ayi Djifa Hounsi, D. Kongnine, T. Aboki, Essowè Mouzou, G. Djeteli, K. Napo
The Bassar iron industry has produced large quantities of steel ingots exceeding local needs and opening up a vast sub regional iron trade network. Bassar blacksmiths of Bitchabe and those of neighboring peoples such as kabiye have transformed these ingots into finished products to feed this trade network. The present work studied the microstructural and mechanical properties of traditional Bassar Steel (BS) forged by Kabiye blacksmiths. The forging process of Kabiye blacksmiths was described. Optical Microscopy (OM), Scanning electron microscopy (SEM), X-ray diffraction (XRD), Vickers microhardness and tensile tests were used to investigate the microstructural and mechanical properties of the forged samples. Optical micrographs indicate a ferritic matrix containing many non-metallic inclusions. Micro-hardness measurement values ranging from 130 to 185 Hv0.3 are measured from the heart to the surface of the Bassar Forged Steel (BFS). This field covers the microhardness values of ferritic steel or very low carbon steel. The tensile strength of the studied forged steel is 148 GPa with a low total strain of 14 %. EDS analysis indicate the presence of Phosphorus in a low proportion.
巴萨尔铁工业生产的大量钢锭超过了当地的需求,并开辟了一个庞大的次区域铁贸易网络。Bitchabe的Bassar铁匠和kabiye等邻近民族的铁匠将这些铸锭转化为成品,以满足这个贸易网络。本文研究了卡比耶铁匠锻造的传统Bassar钢(BS)的显微组织和力学性能。介绍了卡比耶铁匠的锻造工艺。采用光学显微镜(OM)、扫描电镜(SEM)、x射线衍射仪(XRD)、维氏显微硬度和拉伸试验研究了锻造样品的显微组织和力学性能。光学显微照片显示铁素体基体含有许多非金属夹杂物。从basar锻钢(BFS)的中心到表面的显微硬度测量值范围为130至185 Hv0.3。这一领域包括铁素体钢或极低碳钢的显微硬度值。所研究的锻造钢的抗拉强度为148 GPa,总应变为14%。能谱分析表明,磷的存在比例较低。
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引用次数: 0
Physico-Chemical Behavior of Glycerol-Coated Cassava Starch Gels Incorporating Kaolin and Metakaolin 含高岭土和偏高岭土的木薯淀粉凝胶甘油包被的物理化学行为
Pub Date : 2019-03-14 DOI: 10.12691/AJMSE-7-1-1
N. Méité, L. Konan, Bi Irié Hervé Gouré Doubi, D. Soro, I. Lazar, S. Oyetola
This study aims at analyzing the physico-chemical interactions in glycerol-coated cassava starch gels incorporating clay as mineral filler during heating. The physico-chemical and structural characterization of the clay used is composed of 75% kaolinite, 14% quartz and 11% illite. A thermal treatment at 700°C for 1 hour of this kaolinitic clay has allowed strong destructuring of the crystalline structure. The suspensions of glycerol plasticized cassava starch without charge or containing 5% by weight of clay were prepared and then heated at various temperatures between 30°C and 100°C. The suspensions viscosity increases according to the temperature up to a maximum following the penetration of the water molecules inside the starch grains. This phase is followed immediately by a sharp drop in the viscosity, resulting in a granular destructuring and solubilization of the starch grains. The suspensions incorporating metakaolin have a higher viscosity than those incorporating kaolin. The gels incorporating metakaolin have a hight ability to downgrade. The infrared spectroscopy of gels taken at different temperatures show the formation of the inter and intra molecular bonds within the starch granules.
本研究旨在分析以粘土为矿物填料的甘油包被木薯淀粉凝胶在加热过程中的物理化学相互作用。所用粘土的物理化学和结构表征由75%的高岭石、14%的石英和11%的伊利石组成。在700°C下对这种高岭石粘土进行1小时的热处理,可以使晶体结构发生强烈的破坏。制备无电荷的甘油增塑木薯淀粉悬浮液或含有5%重量粘土的悬浮液,然后在30℃至100℃的不同温度下加热。悬浮液的粘度随着温度的升高而增加,在水分子渗透到淀粉颗粒内部后达到最大值。在这一阶段之后,粘度立即急剧下降,导致淀粉颗粒破裂和增溶。掺偏高岭土的混悬液粘度高于掺高岭土的混悬液。含有偏高岭土的凝胶具有很强的降级能力。凝胶在不同温度下的红外光谱显示了淀粉颗粒内部分子间和分子内键的形成。
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引用次数: 2
Comparative Study of the Influence of Antireflective Coatings and Transparent Oxides on a CdS/CdTe Solar Cell 抗反射涂层与透明氧化物对CdS/CdTe太阳能电池性能影响的比较研究
Pub Date : 2018-12-14 DOI: 10.12691/AJMSE-6-2-4
O. A. Niasse, Alassane Diaw, M. Niane, N. Mbengue, M. A. Tankhari, P. Olivier, B. Ba
In this paper, we have studied the transparent oxide antireflective effects coatings on solar cell transmission at the n-CdS/p-CdTe heterojunction. We start from the results obtained on the determination of the optical constants by the dielectric function model which takes into account the contribution of the intermediate states. Thus, the transmission is studied to function to epitaxial layers thicknesses of cadmium sulphide CdS and transparent oxide ITO. Our results are compared with those of others authors for different calculation models. Thus, the study is extended to other transparent oxides such as Nb2O5 and Ta2O5 and to observe the effective influence on the quantum yield of the CdS/CdTe photocell. A table linking the transmission and the reflectivity of its various oxides as function to the thickness could thus be established.
本文研究了透明氧化物涂层在n-CdS/p-CdTe异质结处对太阳能电池透射的减反射效应。我们从考虑中间态贡献的介电函数模型确定光学常数的结果出发。因此,研究了透射率对硫化镉CdS和透明氧化物ITO外延层厚度的影响。在不同的计算模型下,我们的结果与其他作者的结果进行了比较。因此,本研究扩展到其他透明氧化物如Nb2O5和Ta2O5,观察其对CdS/CdTe光电池量子产率的有效影响。因此,可以建立一个表,将其各种氧化物的透射率和反射率与厚度的关系联系起来。
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引用次数: 2
Investigation of Optical and Electrical Properties of 2-acrylamido-2-methyl Propane Sulfonic Acid/2-Hydroxy Ethyl Methacrylate (AMPS/HEMA) Hydrogel Prepared by Gamma Irradiation γ辐照制备2-丙烯酰胺-2-甲基丙烷磺酸/2-羟甲基丙烯酸乙酯(AMPS/HEMA)水凝胶的光电性能研究
Pub Date : 2018-11-06 DOI: 10.12691/AJMSE-6-2-2
H. Ghulman
Hydrogels from either 2-acrylamido-2-methylpropane sulfonic acid (AMPS) or 2-hydroxyl ethyl methacrylate (HEMA) have been prepared by gamma radiation at irradiation dose of 10 kGy. Different volume ratio (v/v) of the starting materials were used to obtain crosslinked hydrogels of variable compositions and crosslink density. UV-VIS absorption spectra indicated that there is a variation in intensity as well as in optical energy gap with different doping levels. Therefore, values of direct and indirect energy gaps were calculated and discussed. The reflectance and transmittance were collected for the as-prepared hydrogels and analyzed in the incident photon energy range from 0.1 to 1.6 eV at a temperature range 300 to 500 K. The optical investigation revealed that the optical transition is directly allowed.
以2-丙烯酰胺-2-甲基丙烷磺酸(AMPS)和2-羟乙基甲基丙烯酸酯(HEMA)为原料,在10 kGy的辐照剂量下制备了水凝胶。采用不同体积比(v/v)的原料制备不同组成和交联密度的交联水凝胶。紫外-可见吸收光谱表明,不同掺杂水平的材料在光强和光能间隙上都有变化。因此,计算并讨论了直接能隙和间接能隙的取值。在入射光子能量为0.1 ~ 1.6 eV,温度为300 ~ 500 K的条件下,测定了水凝胶的反射率和透射率。光学研究表明,光跃迁是直接允许的。
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引用次数: 0
From Industry 4.0 to Research 4.0. Development of High Performance Fibers in the Light of Digitization 从工业4.0到研究4.0。数字化背景下高性能光纤的发展
Pub Date : 2018-08-28 DOI: 10.17265/2161-6221/2018.7-8.004
Steffen Müller-Probandt
We associate a variety of innovations with the term “Industry 4.0”. The pioneer of many 4.0 modifications forms the basis for the trend towards the integrated digitization of many areas of life. The field of research requires from the pilot plants to develop new pioneering fibers high flexibility of its experimental facilities to allow new insights in the laboratory and prototype facilities at a reasonable cost. Added to this is the desire to closely track all process data and prepare it in a timely manner. Mobile devices now allow the researcher to vary parameters close to the process during observation. In the following lecture the question will be discussed which of the many definitions and varieties of “Industry 4.0” can be meaningfully transferred to the field of research. In doing so, we are guided by the findings that have been gained with modularized spinning systems in recent years. The respective spinning processes require different analysis focuses and different conversion options. The digital world must follow the real demands of the analog world. In addition to the elegance functions, it must be ensured that the control functions of the process meet the requirements of machine safety. Digitization allows intelligent analyzes to be developed independently of the various spinning processes and can be flexibly adapted to the respective process conditions. The variability of spin systems depends on the intelligent modularization of individual functions and the physics that require the spinning conditions. Finally, some examples of modular prototype systems are presented, and the limits of variability are discussed.
我们将各种创新与“工业4.0”一词联系在一起。许多4.0修改的先驱形成了生活中许多领域集成数字化趋势的基础。该领域的研究需要从试点工厂开发新的开创性纤维,其实验设施的高度灵活性,以允许在实验室和原型设施中以合理的成本获得新的见解。除此之外,还需要密切跟踪所有过程数据并及时准备。移动设备现在允许研究人员在观察过程中改变接近过程的参数。在接下来的讲座中,我们将讨论“工业4.0”的众多定义和变体中,哪些可以有意义地转移到研究领域。在这样做的过程中,我们受到近年来模块化纺丝系统所获得的发现的指导。不同的纺丝工艺需要不同的分析重点和不同的转换选项。数字世界必须遵循模拟世界的真实需求。除了优雅的功能外,还必须保证过程的控制功能满足机器安全的要求。数字化使智能分析能够独立于各种纺纱工艺开发,并可以灵活地适应各自的工艺条件。自旋系统的可变性取决于个体功能的智能模块化和需要自旋条件的物理特性。最后,给出了一些模块化原型系统的实例,并讨论了可变性的限制。
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引用次数: 0
Generation and Recombination of a CIGSe Solar Cell under the Influence of the Thickness of a Potassium Fluoride (KF) Layer 氟化钾(KF)层厚度影响下CIGSe太阳能电池的生成和复合
Pub Date : 2018-07-18 DOI: 10.12691/AJMSE-6-2-1
Djimba Niane, O. Diagne, A. Ehemba, M. Socé, M. Dieng
In this paper, we study the phenomena of generations and recombination of a CIGSe solar cell under the influence of the thickness of a potassium fluoride (KF) layer. The different thicknesses taken are respectively 15 nm, 30 nm and 45 nm and the doping rate of the base has been fixed at 1016cm-3. The simulations made with the SCAPS-1D software show, on the one hand, a decrease in the emission rate and an increase in the electron capture rate; on the other hand, an increase in the rate of emission and capture of the holes respectively, as the thickness of the KF layer increases. Furthermore, we note that the rate of recombination of the carriers increases slightly with the thickness of KF at the CIGSe layer caused by a passivation of the defects.
本文研究了氟化钾(KF)层厚度影响下CIGSe太阳能电池的生成和复合现象。所取厚度分别为15nm、30nm和45nm,碱的掺杂率固定为1016cm-3。利用SCAPS-1D软件进行的模拟表明,一方面,发射速率降低,电子捕获速率增加;另一方面,随着KF层厚度的增加,空穴的发射速率和捕获速率分别增加。此外,我们注意到载流子的复合率随着缺陷钝化引起的CIGSe层KF厚度的增加而略有增加。
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引用次数: 3
Optimization of Machining Parameter for Surface Roughness in Turning GFRP Composite Using RSM-GA Approach 基于RSM-GA方法的车削GFRP复合材料表面粗糙度加工参数优化
Pub Date : 2018-06-11 DOI: 10.12691/AJMSE-6-1-4
Md. Rezaul Karim, S. Ahmed, S. Salahuddin
This paper deals with the analysis of surface roughness in turning GFRP composite through experimental investigation and Response surface methodology (RSM) based optimization modeling incorporated with Genetic Algorithm (GA). The investigation has been carried out in dry condition where cutting speed, feed rate and depth of cut has been considered as input parameters to check the desired surface roughness response. This experiment has been designed using RSM central composite design (CCD). Afterwards the response model has been formulated using quadratic RSM model and Genetic algorithm. The correlation coefficient value of 0.9989 suggests the adequacy of the formulated model. Main effect plot and 3D surface plot have been used to evaluate the effect of input parameters followed by Desirability Function Analysis (DFA) through response surface equation of the machining response. Machining parameters were then optimized using GA approach which indicated that to attain advantageous machining response cutting speed and feed rate need to be at 78 m/min and 0.10 mm/rev respectively. These findings are also analogous with the result of DFA which validates both the model. By employing the model, surface roughness of as minimum as 0.056 µm can be achieved.
通过试验研究和基于响应面法的优化建模与遗传算法相结合,对车削玻璃钢复合材料的表面粗糙度进行了分析。研究在干燥条件下进行,将切削速度、进给速度和切削深度作为输入参数,以检查所需的表面粗糙度响应。本实验采用RSM中心复合设计(CCD)进行设计。然后利用二次RSM模型和遗传算法建立了响应模型。相关系数为0.9989,说明所建立的模型是适当的。采用主效应图和三维曲面图对输入参数的影响进行评价,并通过加工响应的响应面方程进行期望函数分析。采用遗传算法对加工参数进行了优化,结果表明,为获得较好的加工响应,切削速度为78 m/min,进给速度为0.10 mm/rev。这些发现也与DFA的结果相似,验证了模型的正确性。采用该模型,表面粗糙度最小可达0.056µm。
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引用次数: 2
期刊
Journal of materials science & engineering
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