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Volumetry of Hydrogen Micro-bubbles Dispersed in Water 水中分散氢微泡的体积测定
Pub Date : 2018-02-28 DOI: 10.17265/2161-6221/2018.1-2.003
K. Aoki, Shin Yamaguchi, Jingyuan Chen
: When hydrogen gas is bubbled in water until saturation, micro-bubbles with ca. 0.5  m in diameter have been detected in water by the dynamic light scattering, reportedly. A part of saturated hydrogen may take gas form, whereas it may take hydrated form. A question is how much molar ratio of the two forms. If hydrogen molecule is oxidized to hydronium ion, the volume of the solution including bubbles should decrease by the amount of gas form more predominantly than that of the hydronium one. Herein we oxidized the saturated hydrogen gas with potassium permanganate in the presence of platinum wire as catalyst. The decrease in the volume of the gas was compensated for addition of water so that the pressure of the hydrogen gas was able to be kept to the atmospheric pressure. From the decrease in the volume under the steady state, concentrations of H 2 in the gaseous form were evaluated at several temperatures to be ca. 0.4 mM, which is a half the saturated concentration of H 2 . They were almost independent of the temperature of
据报道,当氢气在水中起泡至饱和时,通过动态光散射在水中发现了直径约为0.5m的微气泡。一部分饱和氢可能以气体形式存在,而一部分则可能以水合形式存在。问题是这两种形式的摩尔比是多少。如果氢分子被氧化为水合氢离子,则含气泡的溶液的体积应比含水合氢离子的体积减少。本文用高锰酸钾在铂丝催化下氧化饱和氢气。气体体积的减少被水的加入所补偿,这样氢气的压力就能保持在大气压力的水平上。根据稳态下体积的减小,在几个温度下,气态h2的浓度约为0.4 mM,这是h2饱和浓度的一半。它们几乎与温度无关
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引用次数: 0
Stain Materials’ Role in Biological Research: A Tool in Heath Care 染色材料在生物学研究中的作用:一种医疗保健工具
Pub Date : 2018-02-28 DOI: 10.17265/2161-6213/2018.1-2.002
E. A. Hassan
Stains and staining methods significantly assist in diagnoses in medical research and health care. Certain color of a dye can identify the location of a tumor within a specimen. Applying histochemical-staining enabled morphological identification of fibrin in the lymphoid tissue during cancer progression. Staining methods in combination with the LSFM (light-sheet fluorescence microscopy) allowed tracing the drug penetration, development and spread of tumors. The Curcumin dye is in use for labelling and imaging of Aβ plaques in post-mortem brain tissue. Immunofluorescent staining methods are employed in detection of some important proteins in early diagnostic changes relevant to heart damage. The methods are developed in medical research to include stem cells and tissue engineering, cell cultures` properties and capabilities, connective tissues and extracellular matrix , nervous system , musculoskeletal system; respiratory system, liver and gastrointestinal tract, and male and female reproductive systems.
染色和染色方法在医学研究和卫生保健的诊断中有重要的帮助。染料的特定颜色可以识别标本中肿瘤的位置。应用组织化学染色可以在肿瘤进展过程中对淋巴组织中的纤维蛋白进行形态学鉴定。染色方法与LSFM(光片荧光显微镜)相结合,可以追踪药物的渗透,肿瘤的发展和扩散。姜黄素染料用于死后脑组织中β斑块的标记和成像。免疫荧光染色方法用于检测与心脏损伤相关的早期诊断改变的一些重要蛋白质。这些方法是在医学研究中发展起来的,包括干细胞和组织工程、细胞培养的特性和能力、结缔组织和细胞外基质、神经系统、肌肉骨骼系统;呼吸系统,肝脏和胃肠道,以及男性和女性生殖系统。
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引用次数: 0
Formation of Faceted Excess Carbides in Damascus Steels Ledeburite Class 大马士革钢Ledeburite类中多面碳化物的形成
Pub Date : 2018-02-28 DOI: 10.17265/2161-6221/2018.1-2.006
D. Sukhanov, N. Plotnikova
In this research was developed stages of formation troostite-carbide structure into pure Damascus steel ledeburite class type BU22А obtained by vacuum melting. In the first stage of the technological process, continuous carbides sheath was formed along the boundaries of austenitic grains, which morphologically resembles the inclusion of ledeburite. In the second stage of the process, there is a seal and faceted large carbide formations of eutectic type. In the third stage of the technological process, troostite matrix is formed with a faceted eutectic carbide non-uniformly distributed in the direction of the deformation with size from 5.0 μm to 20 μm. It found that the stoichiometric composition of faceted eutectic carbides is in the range of 34 < C < 36 (atom %), which corresponds to -carbide type Fe2C with hexagonal close-packed lattice. Considering stages of transformation of metastable ledeburite in the faceted eutectic -carbides type Fe2C, it revealed that the duration of isothermal exposure during heating to the eutectic temperature, is an integral part of the process of formation of new excess carbides type Fe2C with a hexagonal close-packed lattice. It is shown that troostite-carbide structure Damascus steel ledeburite class (BU22А), with volume fraction of excess -carbide more than 20%, is fully consistent with the highest grades of Indian steels type Wootz. Modern Damascus steel type BU22А (Russia) can be described as carbon steel ledeburite class, with similar structural and morphological characteristics of die steel type X12 (Russia) or Cr12 (China) and high-speed steel type P6M5 (Russia) or W6Mo5Cr4V2 (China), differing from them only in the nature of excess carbide phase.
研究了真空熔炼得到的纯大马士革钢莱氏体级BU22А的蠕形碳化物组织的形成阶段。在工艺过程的第一阶段,沿奥氏体晶粒边界形成连续的碳化物鞘,其形态类似于莱氏体包裹体。在该过程的第二阶段,存在一个密封和切面的共晶型大碳化物地层。第三阶段形成蠕变体基体,晶粒尺寸为5.0 μm ~ 20 μm,在变形方向上不均匀分布。结果表明,多面共晶碳化物的化学组成在34 < C < 36(原子数%)范围内,属于六边形密排晶格的片状碳化物型Fe2C。考虑到Fe2C多面共晶型碳化物中亚稳ledeburite的转变阶段,发现等温暴露时间在加热至共晶温度的过程中,是形成具有六方密排晶格的Fe2C型新过量碳化物的重要组成部分。结果表明:蠕变体-碳化物结构大马士革钢ledeburite级(BU22А),过量碳化物体积分数大于20%,与印度钢Wootz型的最高牌号完全一致。现代大马士革钢BU22А(俄罗斯)可被描述为碳素钢莱氏体类,具有与模具钢X12(俄罗斯)或Cr12(中国)和高速钢P6M5(俄罗斯)或W6Mo5Cr4V2(中国)相似的组织和形态特征,不同之处在于过量碳化物相的性质。
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引用次数: 2
Effect of 3 GPa Pressure Treatment on the Solid-State Phase Transformation of Cu-11.76Al Alloy during Heating Process 3gpa压力处理对cu -11.76铝合金加热过程中固相转变的影响
Pub Date : 2018-02-28 DOI: 10.17265/2161-6221/2018.1-2.002
X. Hong
Cu-11.76Al alloy was treated at 3 GPa and 700 °C for 15minutes, the solid-state phase transformation temperature and time of Cu-11.76Al alloy before and after 3 GPa pressure treatment during heating process were measured by DSC (differential scanning calorimeter), its activation energy was also calculated, and the microstructures of Cu-11.76Al alloy before and after 3 GPa pressure treatment were analyzed by metallurgical microscope and transmission electron microscopy. Based on the experimental results, the effect of 3 GPa pressure treatment on the solid-state phase transformation of Cu-11.76Al alloy during heating process was investigated. The results show that 3 GPa pressure treatment can decrease the temperature and activation energy of α + γ2→ß transformation of Cu-11.76Al alloy, shorten the phase transformation time, which is helpful for the phase transformation. The main reason is that 3 GPa pressure treatment can refine the grains and increase dislocation density of Cu-11.76Al alloy.
采用DSC(差示扫描量热计)测定Cu-11.76Al合金在加热过程中3gpa压力处理前后的固相转变温度和时间,计算其活化能,并通过金相显微镜和透射电镜分析3gpa压力处理前后Cu-11.76Al合金的显微组织。基于实验结果,研究了3gpa压力处理对cu -11.76铝合金加热过程中固相转变的影响。结果表明:3gpa压力处理能降低cu -11.76铝合金α + γ2→β相变的温度和活化能,缩短相变时间,有利于cu -11.76铝合金的相变;主要原因是3gpa压力处理使cu -11.76铝合金晶粒细化,位错密度增大。
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引用次数: 1
Influence of Medium Used during Ferritic Nitro-Carburizing of AISI H-13 Hot Work Tool Steel AISI H-13热加工工具钢铁素体氮化渗碳介质的影响
Pub Date : 2018-02-28 DOI: 10.17265/2161-6213/2018.1-2.003
Valmik Bhavar, Prakash Kattire, Jagdish Sherkar, Digvijay Sheed, R. Singh
Ferritic nitro-carburizing is one of the most popular surface hardening methods used to improve lifespan of hot work tool steels. Different types of mediums like gas, liquid, plasma and fluidized bed are generally used during ferritic nitro-carburizing process. In this paper, various ferritic nitro-carburizing methods were compared where gas, salt bath and fluidized are used as mediums. AISI H-13 hot work tool steel specimens were treated by using these different methods of nitro-carburizing and their performance was evaluated by using micro-structural and mechanical analysis. Optical microscopy, micro-hardness testing and X-ray stress analyzer were used for specimen characterization. Moreover, pin on disk dry sliding wear tests were performed to compare wear performance of specimens treated with different nitro-carburizing methods. It is perceived that, medium used during nitro-carburizing has significant influence on the final surface properties that can be achieved by ferritic nitro-carburizing.
铁素体氮化渗碳是提高热加工工具钢使用寿命的最常用的表面硬化方法之一。铁素体氮渗碳工艺一般采用气体、液体、等离子体和流化床等不同类型的介质。本文比较了以气体、盐浴和流态化为介质的各种铁素体氮化渗碳方法。采用不同的渗氮方法对AISI H-13热作工具钢试样进行了渗氮处理,并通过显微组织和力学分析对其性能进行了评价。采用光学显微镜、显微硬度测试和x射线应力分析仪对试样进行表征。通过销盘式干滑动磨损试验,比较了不同渗氮方式下试样的磨损性能。可以看出,氮化渗碳过程中使用的介质对铁素体氮化渗碳所能达到的最终表面性能有显著影响。
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引用次数: 0
Influence of Coke and Graphite on the Decomposition and Melting Behavior of a Mold Flux 焦炭和石墨对助熔剂分解和熔化行为的影响
Pub Date : 2018-02-28 DOI: 10.17265/2161-6221/2018.1-2.001
E. Benavidez, L. Santini, Alejandro Martín, E. Brandaleze
The melting kinetics of mold fluxes used in steel continuous casting represents a fundamental factor to be considered in order to obtain a quality product without superficial defects and also to avoid production problems. This melting stage is controlled mainly by the type and amount of carbonaceous material added to the powder. In this work, structure, particle size and morphology of two carbonaceous materials: petroleum coke and synthetic graphite were analyzed. Both carbonaceous materials were separately added to a decarburized commercial mold flux. The melting behavior was monitored by HSM (hot stage microscopy) and a melting interval was identified using critical temperatures. A higher fusion rate, as inverse of melting interval, was observed in powder with coke addition. This fact was associated to a lower crystalline degree and a finer PSD (particle size distribution) presented by petroleum coke. Different values of the activation energy of decomposition were related to fusion rate of both mold fluxes. Higher rate of changes in activation energy during the progress of the reaction was observed in the sample with coke. This fact is associated to a faster change in the surface area of coke particles.
连铸中使用的助熔剂的熔化动力学是获得无表面缺陷的优质产品和避免生产问题的一个基本因素。这一熔化阶段主要由添加到粉末中的碳质材料的种类和数量控制。本文对石油焦和合成石墨两种含碳材料的结构、粒度和形貌进行了分析。将两种含碳材料分别添加到脱碳的商业模具助焊剂中。用热段显微镜监测熔炼行为,用临界温度确定熔炼区间。添加焦炭的粉末熔合速率与熔合间隔成反比。这一事实与石油焦的结晶度较低和PSD(粒度分布)较细有关。不同的分解活化能值与两种助熔剂的熔合速率有关。在反应过程中,在有焦炭的样品中观察到较高的活化能变化率。这一事实与焦炭颗粒表面积变化较快有关。
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引用次数: 1
Surface Modification of Di-electric Material Using Photo Pretreatment for Fan-Out Wafer Level Package 扇出晶圆级封装双电材料的光预处理表面改性
Pub Date : 2018-02-28 DOI: 10.17265/2161-6221/2018.1-2.005
Jong-Young Park, Young-jae Kim, J. Noh, H. Honma
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引用次数: 0
One Approach to Eddy Current Testing of Carburized Parts 渗碳件涡流检测的一种方法
Pub Date : 2018-02-28 DOI: 10.17265/2161-6213/2018.1-2.001
J. Ivanov
Through DOE (design of experiment), ЕТ (eddy current testing) is included and proven as a quality indicator of carburizing, quenching and tempering of hydraulic motor parts. A method is suggested for calibrating NDT (non-destructive testing) by means of combined representation of regression models in the field of the technological factors of heat treatment and contour control charts. A method is presented here for choosing the working frequency for ET. It is also suggested that experimental design be considered a basic building element in the methodology of carburized parts ET. This article also presents a methodology for conducting eddy current testing in industrial settings.
通过DOE(实验设计),引入ЕТ(涡流检测)作为液压马达零件渗碳、淬火、回火的质量指标,并加以验证。提出了一种热处理工艺因素回归模型与轮廓控制图相结合的无损检测标定方法。本文提出了一种选择ET工作频率的方法。还建议将实验设计视为渗碳部件ET方法的基本构建要素。本文还提出了一种在工业环境中进行涡流测试的方法。
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引用次数: 0
Lead-Free Piezoelectric Ceramics as Candidates on the Development of Morphing Winglets in Aircrafts 无铅压电陶瓷作为飞机可变形小翼发展的候选材料
Pub Date : 2018-02-28 DOI: 10.17265/2161-6213/2018.1-2.005
Kevin Jiménez, G. Herrera
In this paper we discussed the development of a morphing wingtip device or winglet for aircraft. The aim of this research is enhancing the aerodynamic of aircrafts, by optimizing the winglet shape, angle and torsion, to reduce wingtip vortices at each flight stage, reduce drag, fuel consumption and increase its endurance. The development of a working physical wingtip device with morphing functionality, is possible by using piezoelectric MFCs (Macro Fiber Composites) as actuators in wing structures. Due to their excellent properties like flexibility, light weight, tolerant to damage and long term stability MFC fit most of the requirements and specifications of morphing structures. Unfortunately, they are based on the toxic compound of PbZrxTi1-xO3 (PZT). Lead-free materials can replace lead based compounds. Also, other aim of this inquiry is the development of piezoelectric lead-free compounds based on the solid solution Ba1-xCaxTi0.9Zr0.1O3 (BCZT) with x = 0.1, 0.125, 0.15. The reason for choosing these compositions is because BZCT compounds could reach a piezoelectricity coefficient d33~400 pC/N. This value is comparable with commercial PZT, therefore it is a great candidate to replace it.
本文讨论了飞机可变形翼尖装置或小翼的研制。本研究的目的是通过优化小翼的形状、角度和扭转来增强飞机的气动性能,从而减少各飞行阶段的翼尖涡,减少阻力,降低油耗,提高飞机的续航能力。通过在机翼结构中使用压电mfc(宏纤维复合材料)作为致动器,开发具有变形功能的工作物理翼尖装置成为可能。由于其优异的性能,如柔韧性,重量轻,耐损伤和长期稳定的MFC适合大多数变形结构的要求和规格。不幸的是,它们是基于PbZrxTi1-xO3 (PZT)的有毒化合物。无铅材料可以代替铅基化合物。此外,本研究的另一个目的是开发基于x = 0.1, 0.125, 0.15的固溶体Ba1-xCaxTi0.9Zr0.1O3 (BCZT)的压电无铅化合物。选择这些成分的原因是BZCT化合物可以达到d33~ 400pc /N的压电系数。该值与商用PZT相当,因此它是取代它的一个很好的候选者。
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引用次数: 3
CARBOCHAIN POLYMER-GLUCOSE HYBRIDS: SYNTHESIS, THERMAL/MECHANICAL PROPERTIES AND BIODEGRADABILITY 碳链聚合物-葡萄糖杂化物:合成、热/机械性能和生物降解性
Pub Date : 2018-02-10 DOI: 10.18642/JMSEAT_7100121905
V. Bershtein, P. Yakushev, Izabela Bukowska-Śluz, M. Sobiesiak, B. Gawdzik
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引用次数: 0
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Journal of materials science & engineering
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