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Optical Techniques in the Determination of Pitch Lengths in the Cholesteric and Chiral Smectic C Phases 测定胆甾相和手性近晶C相中基音长度的光学技术
Pub Date : 2021-01-01 DOI: 10.37421/2169-0022.2021.10.564
H.S.A Golicha, Mohamed H. Omarn, N. Mbithi
There is no denying that the future of liquid crystals is in the display industry. The use of the twisted nematic (TN) and the superwisted nematic (STN) is widespread. The twisting in these devices is achieved either by use of optical components such as polarizers or the use of chiral dopants in a guest-host system. The later has gained much more attention. This is because not only are the accompanying optical components not needed, but any desired colour can be achieved by varying the pitch length of the helix formed by the chiral nematic (cholesteric) compound. In such application, the ability to determine the pitches of the resulting helical superstructure accurately and quickly is essential. Currently there are many methods for measuring the pitch of a helical super structure. These methods mostly employ optical or spectroscopic techniques. In this paper, four such methods namely, Fingerprint, Diffraction, Selective Reflection and Cano-wedge, are discussed in terms of their theoretical foundation, suitability to given situations and the validity of the results obtained. The suitability of the method depends among other things on the type of mesophase and the length of the pitch in relation to the wavelengths of the visible light. While the Fingerprint and Selective reflection may be used for both cholesteric and chiral smectic C (SmC*), Diffraction and Cano techniques are most suitable for the cholesterics.
不可否认,液晶的未来是在显示行业。扭曲向列(TN)和叠加向列(STN)的应用非常广泛。这些器件中的扭转是通过使用光学元件如偏振器或在主客系统中使用手性掺杂剂来实现的。后者获得了更多的关注。这不仅是因为不需要伴随的光学元件,而且任何期望的颜色都可以通过改变手性向列相(胆甾)化合物形成的螺旋的螺距长度来实现。在这种应用中,能够准确、快速地确定螺旋上层结构的螺距是至关重要的。目前测量螺旋超结构节距的方法有很多种。这些方法大多采用光学或光谱技术。本文讨论了指纹法、衍射法、选择性反射法和卡诺楔法这四种方法的理论基础、对特定情况的适用性以及所得结果的有效性。该方法的适用性除其他外取决于中间相位的类型和相对于可见光波长的间距长度。虽然指纹图谱和选择性反射图谱可用于胆固醇型和手性近晶C (SmC*),但衍射和Cano技术最适合用于胆固醇型。
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引用次数: 1
How a Table within Quantum Field Theory Results in Numerous Periodic Tables 量子场论中的一个表是如何产生众多元素周期表的
Pub Date : 2021-01-01 DOI: 10.37421/2169-0022.2021.10.570
J. Roberts
This is a story of elements, electrons, protons, neutrons and quarks together with their cousins, molecules and the zoo of fundamental particles, as we plot a route through the complexity and diversity of the Universe following requests from several editors of journals to produce a review article as a result of publication of “Implications of the link between the Periodic Table and the Standard Model” in 2018.
这是一个关于元素、电子、质子、中子和夸克以及它们的表兄弟、分子和基本粒子动物园的故事,我们在2018年发表《元素周期表与标准模型之间的联系的含义》后,应几位期刊编辑的要求,撰写了一篇评论文章,绘制了一条穿越宇宙复杂性和多样性的路线。
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引用次数: 0
Editorial Note for Journal of Material Sciences and Engineering 材料科学与工程学报编辑说明
Pub Date : 2021-01-01 DOI: 10.37421/2169-0022.2021.10.556
Riny Yol, ha Parapat
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引用次数: 0
Thermodynamic Modeling of oxyhydrogen fueled combined cycle power plant 氢氧联合循环电厂热力模拟
Pub Date : 2021-01-01 DOI: 10.37421/2169-0022.2021.10.569
J. Partheepan, Emily Hunt
Renewable power generation can reduce the dependence on fossil fuels while minimizing greenhouse gas emissions from electric power generation. However, most renewable energy sources are naturally occurring which makes them seasonal and generally unpredictable over time. With more countries trending toward renewable power by 2050, it is imperative that technologies are developed which can utilize and optimize the storage and distribution of this type of power. Hydrogen energy storage is becoming increasingly popular due to its versatility. It is considered an energy carrier like electricity and can be generated and stored in large quantities and for long periods of time. Hydrogen can be derived from water, biomass, and other technologies and can generate electric power using fuel cells and through combustion. This study investigates a novel combined cycle configuration which is thermodynamically analyzed to identify its potential to adapt steam from a hydrogen oxygen steam generator. A thermodynamic analysis on the system is performed using Engineering Equation Solver from F Chart Software. Results show that the oxygen hydrogen fueled combined cycle excels in the specific power ratio, as this cycle was able to achieve the lowest pressure values at the highest points for both thermal loading and pressure loading. This is a major advantage since the thermal loading on some of the power cycles are much higher that what is currently in use, thus reducing it even by a smaller percentage is significant. The oxygen hydrogen fueled combine cycle reduced the specific power by 78%, pressure at the most thermal loaded point by 157%, and pressure at the most pressure loaded element by 10% when compared to other common cycles.
可再生能源发电可以减少对化石燃料的依赖,同时最大限度地减少发电产生的温室气体排放。然而,大多数可再生能源是自然产生的,这使得它们具有季节性,并且随着时间的推移通常是不可预测的。到2050年,随着越来越多的国家转向可再生能源,开发利用和优化这类电力的储存和分配的技术势在必行。氢储能由于其多功能性而越来越受欢迎。它被认为是像电一样的能量载体,可以大量产生和长时间储存。氢可以从水、生物质和其他技术中提取,并可以通过燃料电池和燃烧产生电力。本研究研究了一种新的联合循环结构,并对其进行了热力学分析,以确定其适应氢氧蒸汽发生器蒸汽的潜力。利用F Chart软件中的工程方程求解器对系统进行了热力学分析。结果表明,氢氧燃料联合循环在比功率比方面表现优异,该循环在热负荷和压力负荷的最高点均能达到最低压力值。这是一个主要的优势,因为在一些电源循环上的热负荷比目前使用的要高得多,因此即使减少很小的百分比也很重要。与其他常见循环相比,氢氧燃料联合循环降低了78%的比功率,最大热负荷点的压力降低了157%,最大压力负荷元件的压力降低了10%。
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引用次数: 1
Cupola Furnace Design and Fabrication 冲天炉设计与制造
Pub Date : 2021-01-01 DOI: 10.37421/2169-0022.2021.10.560
Zinabie Degu
The Cupola Furnace Capacity of 450 kilograms per hour was designed and fabricated using locally sourced raw materials which include pig irons, crop ends and foundry shop returns, and ferroalloys for the production of quality cast iron which depends on the customer's demand. Metallurgical coke is the main fuel source employed for the production processes. The design parameters were analyzed and the metallic shells were then fabricated into four sections to allow proper lining. A mild 5 mm thick steel sheet was collected, marked out according to the required specification. slit and formed into cylindrical shapes. The sections were coupled and joined together through a welding process. Sodium silicate was used as a binder to make them bondable to the interior sections; the internal configurations were first lined with asbestos sheets measured 5 mm thick. With a less dense insulating refractory material. Fireclay refractory bricks were used for furnishing as they directly interfaced with the molten metal, while the flame blower was connected, assembled, and erected in the different segments. Financial analysis was performed to give a general overview of the cost of manufacturing and building a cupola furnace produced locally at N1, 467,266.00, which is relatively cheap compared to the imported ones. The technical details were given for the production processes. The raw materials used were sourced locally as they are readily available in quantum and are essential to the government policies on adding values to the production processes by using these materials to promote the addition of these materials for the creation of local content.
冲天炉的设计和制造能力为每小时450公斤,使用当地采购的原材料,包括生铁、作物末端和铸造车间的废料,以及根据客户需求生产高质量铸铁的铁合金。冶金焦是生产过程中使用的主要燃料来源。对设计参数进行了分析,然后将金属壳制作成四段,以允许适当的衬里。收集了一块5毫米厚的软钢板,并按要求的规格标注出来。切开并形成圆柱形。这些部分通过焊接过程耦合并连接在一起。硅酸钠被用作粘合剂,使其与内部部分粘合;内部结构首先衬以5毫米厚的石棉板。采用密度较小的绝缘耐火材料。使用耐火砖作为装饰,因为它直接与熔融金属接触,而火焰鼓风机在不同的部分进行连接、组装和安装。进行了财务分析,对当地生产的冲天炉的制造和建造费用作了全面的概述,价格为467 266美元,与进口的冲天炉相比相对便宜。给出了生产工艺的技术细节。所使用的原材料来自当地,因为它们在数量上很容易获得,并且对于政府通过使用这些材料来增加生产过程价值的政策至关重要,以促进这些材料的添加以创造本地内容。
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引用次数: 0
Zinc-Based Additives for Biofouling and MIC Protection: Fabrication Method for Long-Term Efficacy 锌基生物污垢和MIC防护添加剂:长效制备方法
Pub Date : 2021-01-01 DOI: 10.37421/2169-0022.2021.10.562
P. Dodge, Emily Hunt
Microbiologically influenced corrosion (MIC) and biofouling both begin with an initial layer of bacteria accumulating on a hard surface exposed to the natural environment. These bacteria quickly form a biofilm which becomes the feeding source for marine life fouling and the root of both of these highly damaging, expensive types of corrosion. Preventative methods for biofilm development is an ongoing field of study due to critical necessity in many industries including healthcare, aerospace, and oil and gas. Today, biofilm inhibitors for the oil and gas industry may include regular cleaning or scraping of the affected surface, electrochemical processes, or biocide injections which have a negative impact on the environment and provide only temporary relief from MIC. This constant need for MIC and fouling remediation creates a great demand and thus market potential for long-term, more environmentally conscious methods to mitigate and control biofilm development. This study investigates the incorporation of well-known biocidal materials as well as one commercial additive into the fabrication process of underwater structures and surfaces. High Density Polyethylene (HDPE) and Fiber Reinforced Plastic (FRP) with antimicrobial additive were processed. Experiments were conducted per ASTM E2149-13a and F895 to evaluate antibacterial efficacy in the laboratory. Field tests were constructed per ASTM D3623 - 78a for material evaluation in offshore fouling conditions. The manufactured materials were tested against gram-positive and gram-negative bacteria and fouling microorganisms to analyze the effectiveness of biofilm prevention. Results showed positive efficacy of biocidal additives incorporated through the fabrication process in all cases including copper, multiple forms of zinc, and titanium dioxide. The commercially available additive produced the largest zone of inhibition and highest reduction of colony forming units in dynamic flow conditions. Fouling tests show that the incorporation of the additive into HDPE and FRP provides a surface protection and thus serves as an agent for material preservation. Results from this study demonstrate innovative and effective methods for surface protection from MIC and biofouling by incorporating antimicrobial additives into the structural matrix during the manufacturing process.
微生物影响腐蚀(MIC)和生物污垢都始于暴露在自然环境中的坚硬表面上的初始细菌层。这些细菌很快形成一层生物膜,成为海洋生物污染的来源,也是这两种高破坏性、高成本腐蚀的根源。由于医疗保健、航空航天、石油和天然气等许多行业的迫切需要,生物膜形成的预防方法是一个正在进行的研究领域。目前,油气行业的生物膜抑制剂可能包括定期清洁或刮擦受影响的表面、电化学处理或注入杀菌剂,这些措施对环境有负面影响,只能暂时缓解MIC。这种对MIC和污染修复的持续需求创造了巨大的需求,从而创造了长期、更环保的方法来缓解和控制生物膜的发展的市场潜力。本研究探讨了将已知的生物杀灭材料和一种商业添加剂结合到水下结构和表面的制造过程中。采用抗微生物添加剂对高密度聚乙烯(HDPE)和纤维增强塑料(FRP)进行加工。实验依据ASTM E2149-13a和F895进行实验室抗菌效果评价。根据ASTM D3623 - 78a进行了现场测试,以评估海上污染条件下的材料。对制备的生物膜进行革兰氏阳性菌、革兰氏阴性菌和污染微生物的检测,分析生物膜的防治效果。结果表明,在制造过程中加入的杀菌剂添加剂,包括铜、多种形式的锌和二氧化钛,都具有积极的效果。在动态流动条件下,市售添加剂产生了最大的抑制区和最大的集落形成单位减少。污垢试验表明,将添加剂掺入HDPE和FRP中可以提供表面保护,从而作为材料保存剂。本研究的结果表明,在制造过程中,将抗菌添加剂加入结构基质中,可以有效地保护表面免受MIC和生物污染。
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引用次数: 0
Design and Operation of Low Energy Consumption Passive Human Comfort Solutions 低能耗被动式人体舒适解决方案的设计与运行
Pub Date : 2020-05-12 DOI: 10.5958/0976-478X.2020.00004.X
A. Omer
Globally, buildings are responsible for approximately 40% of the total world annual energy consumption. Most of this energy is for the provision of lighting, heating, cooling, and air conditioning. Increasing awareness of the environmental impact of CO2, NOx and CFCs emissions triggered a renewed interest in environmentally friendly cooling, and heating technologies. Under the 1997 Montreal Protocol, governments agreed to phase out chemicals used as refrigerants that have the potential to destroy stratospheric ozone. It was therefore considered desirable to reduce energy consumption and decrease the rate of depletion of world energy reserves and pollution of the environment. This article discusses a comprehensive review of energy sources, environment and sustainable development. This includes all the renewable energy technologies, energy efficiency systems, energy conservation scenarios, energy savings and other mitigation measures necessary to reduce climate change. There is strong scientific evidence that the average temperature of the earth’s surface is rising. This was a result of the increased concentration of carbon dioxide and other GHGs in the atmosphere as released by burning fossil fuels. This global warming will eventually lead to substantial changes in the world’s climate, which will, in turn, have a major impact on human life and the built environment. Therefore, effort has to be made to reduce fossil energy use and to promote green energies, particularly in the building sector. Energy use reductions can be achieved by minimising the energy demand, by rational energy use, by recovering heat and the use of more green energies. Low energy design of urban environment and buildings in densely populated areas requires consideration of wide range of factors, including urban setting, transport planning, energy system design and architectural and engineering details. The focus of the world’s attention on environmental issues in recent years has stimulated response in many countries, which have led to a closer examination of energy conservation strategies for conventional fossil fuels. One way of reducing building energy consumption is to design buildings, which are more economical in their use of energy for heating, lighting, cooling, ventilation and hot water supply.
在全球范围内,建筑每年消耗的能源约占世界能源消耗总量的40%。大部分能源用于照明、供暖、制冷和空调。人们越来越意识到二氧化碳、氮氧化物和氟氯化碳排放对环境的影响,从而引发了对环保制冷和供暖技术的新兴趣。根据1997年的《蒙特利尔议定书》,各国政府同意逐步淘汰可能破坏平流层臭氧的制冷剂化学品。因此,人们认为最好减少能源消耗,降低世界能源储备的耗竭速度和减少环境污染。本文对能源、环境与可持续发展进行了全面的综述。这包括所有可再生能源技术、能源效率系统、节能方案、能源节约和其他减少气候变化所需的缓解措施。有强有力的科学证据表明,地球表面的平均温度正在上升。这是由于燃烧化石燃料释放的大气中二氧化碳和其他温室气体浓度增加的结果。这种全球变暖最终将导致世界气候的重大变化,这反过来又将对人类生活和建筑环境产生重大影响。因此,必须努力减少化石能源的使用,并推广绿色能源,特别是在建筑领域。减少能源使用可以通过尽量减少能源需求、合理使用能源、回收热能和使用更多的绿色能源来实现。人口密集地区的城市环境和建筑的低能耗设计需要考虑广泛的因素,包括城市环境、交通规划、能源系统设计以及建筑和工程细节。近年来,世界对环境问题的注意引起了许多国家的反应,导致更密切地审查传统矿物燃料的节约能源战略。减少建筑物能源消耗的一种方法是设计建筑物,使其在供暖、照明、制冷、通风和热水供应方面的能源使用更加经济。
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引用次数: 5
The Assembly and Classification of the Elements Using the Roberts-Janet Nuclear Periodic Table 用罗伯特-珍妮特核元素周期表组装和分类元素
Pub Date : 2020-01-01 DOI: 10.37421/2169-0022.2020.9.549
J. Roberts
A framework and surprisingly coherent analysis of the elements is presented using the Roberts-Janet table derived by inverting the Periodic Table coupled with the Quantum Mechanical Table established using the mathematics of the Standard Model and groups U (1) x S U (2) x S U (3). Having already identified in previous articles a one to one mapping between the two tables, this article seeks to consolidate such a framework to include nucleosynthesis by presenting the appearance of the highly stable numbers of neutrons and protons – magic numbers within the Nuclear Shell Model – as a consequence of the framework itself. The article also seeks to illustrate similarities between the electron structure of individual elements in condensed matter (Periodic Table) and the structure of neutrons and protons in plasma during fusion (Nucleosynthesis) and its possible extension to the Standard Model and beyond. Phase changes together with suitable boundary conditions lead to the hypothesis that all elements ultimately become metallic.
通过将元素周期表与使用标准模型和群U (1) x S U (2) x S U(3)的数学建立的量子力学表相结合,使用robert - janet表推导出了元素的框架和令人惊讶的连贯分析。在之前的文章中已经确定了两个表之间的一对一映射,本文试图通过呈现高度稳定的中子和质子数量——核壳模型中的神奇数字——作为框架本身的结果,来巩固这样一个框架,使其包括核合成。本文还试图说明凝聚态物质(元素周期表)中单个元素的电子结构与聚变(核合成)过程中等离子体中中子和质子的结构之间的相似之处,以及它可能扩展到标准模型及以后。相变加上适当的边界条件导致所有元素最终都变成金属的假设。
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引用次数: 1
Comparative Life Cycle Analysis (LCA) Study on Two Wear-Resistant Boron Steels: RAEX450 and 30MnB5 两种耐磨硼钢RAEX450和30MnB5的寿命周期对比分析(LCA)研究
Pub Date : 2020-01-01 DOI: 10.37421/2169-0022.2020.9.551
L. GarcíaSánchez, Growene W Queirós, J. Salazar, A. Criado
The inter-critical annealing and water quenching heat treatment proposed by us is a practical example of environmental sustainability applied to wear-resistant boron steels. In this research we try to compare the LCAs of two wear-resistant steels, a RAEX450 widely used in the industry today and cheaper 30MnB5 boron steel without alloy elements. The 30MnB5 steel has been given an inter-critical annealing and hardening treatment and the RAEX450 a conventional annealing and hardening treatment. The mechanical properties achieved are similar to or better than those of boron steel; but the energy savings with this steel and its environmental impact are notably more positive for the environment. The LCA of the heat treatment applied to 30MnB5 is significantly more positive than that applied to RAEX450, without affecting its mechanical properties as wear-resistant steel.
我们提出的临界间退火和水淬热处理是环境可持续性应用于耐磨硼钢的一个实际例子。在本研究中,我们试图比较两种耐磨钢的lca,一种是目前工业上广泛使用的RAEX450钢,另一种是不含合金元素的30MnB5硼钢。对30MnB5钢进行了临界间退火硬化处理,对RAEX450钢进行了常规退火硬化处理。所获得的力学性能与硼钢相似或优于硼钢;但是,这种钢材的节能和对环境的影响对环境来说明显更为积极。30MnB5热处理后的LCA明显大于RAEX450热处理后的LCA,且不影响其作为耐磨钢的力学性能。
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引用次数: 0
Recovery of Metals from Dry Shot Blast Waste Generated in the Stainless-Steel Production Process 从不锈钢生产过程中产生的干抛丸废渣中回收金属
Pub Date : 2020-01-01 DOI: 10.37421/JME.2020.9.554
S. Khumkoa, T. akhiaw, N. Ma-ud, P. Khamseetha, P. Hathong, P. Laokhen, C. Kansomket
Dry shot blast generated during stainless steel production contains high content of valued metals such as iron chromium and nickel. These metals are in the form of oxides and it can be used as a raw material in iron and steel. This work aims to study the feasibility of metals recovery from dry shot blast by smelting reduction process. Smelting reduction of dry shot blast by using coking coal as reductant was conducted in an induction furnace. The effect of metallurgical parameters e.g. stoichiometry ratio of reductant per oxygen containing in dry shot blast, CaO/SiO2 of slag forming and CaF2 in slag, on %recovery of metal product was investigated. The results based on this study showed that the weight of metal product increases with increased the amount of coke to about 1.5 of stoichiometric molar ratio. Increasing of coke above this amount leads to decrease %recovery of metal product. Moreover, the weight of metal product is increased when the ratio of CaO/SiO2 in slag decreased from 2 to 1. The chemical composition of the metal product is in the range of commercial grade and it can be used as raw materials to produce steel and cast iron alloy.Dry shot blast generated during stainless steel production contains high content of valued metals such as iron chromium and nickel. These metals are in the form of oxides and it can be used as a raw material in iron and steel. This work aims to study the feasibility of metals recovery from dry shot blast by smelting reduction process. Smelting reduction of dry shot blast by using coking coal as reductant was conducted in an induction furnace. The effect of metallurgical parameters e.g. stoichiometry ratio of reductant per oxygen containing in dry shot blast, CaO/SiO2 of slag forming and CaF2 in slag, on %recovery of metal product was investigated. The results based on this study showed that the weight of metal product increases with increased the amount of coke to about 1.5 of stoichiometric molar ratio. Increasing of coke above this amount leads to decrease %recovery of metal product. Moreover, the weight of metal product is increased when the ratio of CaO/SiO2 in slag decreased from 2 to 1. The chemical composition of the metal product is in the range of commercial grade and it can be used as raw materials to produce steel and cast iron alloy.
不锈钢生产过程中产生的干抛丸含有高含量的贵重金属,如铁、铬和镍。这些金属以氧化物的形式存在,可用作钢铁的原料。本文旨在研究采用熔炼还原法回收干抛丸中金属的可行性。以焦煤为还原剂,在感应炉中对干抛丸进行了冶炼还原。考察了干抛丸中还原剂含氧化学计量比、成渣中CaO/SiO2和渣中CaF2等冶金参数对金属产品回收率的影响。研究结果表明,随着焦炭用量的增加,金属产品的重量增加,焦炭的化学计量摩尔比约为1.5。焦炭添加量超过此量会导致金属产品回收率下降。当渣中CaO/SiO2的比值由2降到1时,金属产品的重量增加。金属制品的化学成分在工业级范围内,可用作生产钢铁和铸铁合金的原料。不锈钢生产过程中产生的干抛丸含有高含量的贵重金属,如铁、铬和镍。这些金属以氧化物的形式存在,可用作钢铁的原料。本文旨在研究采用熔炼还原法回收干抛丸中金属的可行性。以焦煤为还原剂,在感应炉中对干抛丸进行了冶炼还原。考察了干抛丸中还原剂含氧化学计量比、成渣中CaO/SiO2和渣中CaF2等冶金参数对金属产品回收率的影响。研究结果表明,随着焦炭用量的增加,金属产品的重量增加,焦炭的化学计量摩尔比约为1.5。焦炭添加量超过此量会导致金属产品回收率下降。当渣中CaO/SiO2的比值由2降到1时,金属产品的重量增加。金属制品的化学成分在工业级范围内,可用作生产钢铁和铸铁合金的原料。
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引用次数: 0
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Journal of Material Sciences & Engineering
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