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Plant-Mediated Biosynthesis and Photocatalysis Activities of Zinc Oxide Nanoparticles: A Prospect towards Dyes Mineralization 植物介导氧化锌纳米颗粒的生物合成和光催化活性:染料矿化的展望
IF 4.2 Q2 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2021-03-11 DOI: 10.1155/2021/6629180
M. A. Fagier
In recent years, nanoparticles synthesis by green synthesis has gained extensive attention as a facile, inexpensive, and environmentally friendly method compared with chemical and physical synthesis methods. This review covered the biosynthesis of zinc oxide nanoparticles (ZnO NPs), including the procedure and mechanism. Factors affecting the formation of ZnO NPs are discussed. The presence of active bioorganic molecules in plant extract played a vital role in the formation of ZnO NPs as a natural green medium in the metallic ion reduction processes. ZnO NPs exhibit attractive photocatalysis properties due to electrochemical stability, high electron mobility, and large surface area. In this review, the procedure and mechanism of the ZnO photocatalysis process are studied. The effects of dyes amount, catalysts, and light on photodegradation efficiency are also considered. This review provides useful information for researchers who are dealing with green synthesis of ZnO NPs. Moreover, it can provide investigators with different perceptions towards the efficiency of biosynthesized ZnO NPs on dyes degradation and its restrictions.
近年来,纳米颗粒的绿色合成与化学和物理合成方法相比,具有简单、廉价、环保的优点,受到了广泛的关注。本文综述了氧化锌纳米颗粒的生物合成,包括合成过程和机理。讨论了影响ZnO NPs形成的因素。在金属离子还原过程中,植物提取物中活性生物有机分子的存在对ZnO NPs的形成起着至关重要的作用。由于电化学稳定性、高电子迁移率和大表面积,ZnO纳米粒子表现出吸引人的光催化性能。本文综述了氧化锌光催化的过程和机理。考察了染料用量、催化剂用量、光照对光降解效率的影响。本文综述为绿色合成ZnO纳米粒子的研究人员提供了有益的信息。此外,它可以为研究人员提供对生物合成ZnO NPs对染料降解的效率及其限制的不同认识。
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引用次数: 48
Adsorption of lead and iron present in the waters of the Santa River using titanium dioxide nanoparticles (TiO2) [Adsorción de plomo y hierro presentes en aguas del río Santa utilizando nanopartículas de dióxido de titanio (TiO2)] 利用二氧化钛纳米颗粒(TiO2)吸附圣河水中铅和铁[利用二氧化钛纳米颗粒吸附圣河水中铅和铁]
IF 4.2 Q2 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2020-12-26 DOI: 10.32829/nanoj.v4i2.199
Lenin Inquil Ayquipa, Jhonny Valverde Flores
The objective of the investigation was to determine adsorption of lead and iron in waters coming from the Santa River, Recuay jurisdiction, Ancash. Then the synthesis of titanium dioxide nanoparticles (TiO2) was carried out by means of ultrasound, and finally the adsorption of the metal ions present in these waters by means of the titanium dioxide nanoparticles. The results indicate that the iron was adsorbed by 92.69% (from 31.86 mg/L to 2.33 mg/L) and the lead was adsorbed by 79.58% (from 2.361 mg/L to 0.482 mg/L) using 600mg of titanium dioxide nanoparticles (TiO2) and a treatment time of 60 minutes of treatment.
调查的目的是确定铅和铁的吸附来自圣河,雷索韦辖区,安卡什的水。然后通过超声波合成二氧化钛纳米粒子(TiO2),最后通过二氧化钛纳米粒子吸附这些水中存在的金属离子。结果表明:当TiO2浓度为600mg,处理时间为60 min时,铁的吸附率为92.69%(从31.86 mg/L增加到2.33 mg/L),铅的吸附率为79.58%(从2.361 mg/L增加到0.482 mg/L);
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引用次数: 1
Shear Thickening Fluids Comparative Analysis Composed of Silica Nanoparticles in Polyethylene Glycol and Starch in Water 二氧化硅纳米颗粒在聚乙二醇中与淀粉在水中组成的剪切增稠流体的对比分析
IF 4.2 Q2 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2020-12-07 DOI: 10.1155/2020/8839185
R. Mankarious, M. Radwan
Shear thickening fluid (STF) occurs in dispersions of highly condensed colloid particles and is categorized as a non-Newtonian fluid whose viscosity increases under shear loading which makes them beneficial in protective and impact resistance applications. The aim of this study is to synthesis two different STFs and characterize their microstructural properties to provide a data base for comparing the final macrobehavior of the two fluids under mechanical testing. Therefore, fumed silica and polyethylene glycol STF and starch with water STF-based dispersions were prepared. The particle size, zeta potential, SEM micrographs, and rheological analysis were performed for each type of STF. The effect of filler concentration was observed by using 10–30 weight% filling material. The rheological properties of STFs show higher viscosity measurements at same shear rates for starch/water STF than silica/PEG with maximum viscosity reaching 523.6 Pa s and 178.9 Pa s, respectively. Larger starch particle size over silica recorded as 303.7 nm and 16.49 nm, respectively, and zeta potential analysis recorded particle electrostatic charges as 22.6 mV and 12.8 mV, respectively, leading to more dispersion stability and obvious thickening effect at higher particle concentration leading to greater jump in viscosity at sudden shear rate. The results indicate the capability of trying more protective applications with more flexibility and less thickness when STF is implemented and a good database for the fluids to choose from according to their behavior.
剪切增稠流体(STF)发生在高度凝聚的胶体颗粒的分散体中,被分类为非牛顿流体,其粘度在剪切载荷下增加,这使得它们有利于保护和抗冲击应用。本研究的目的是合成两种不同的STFs并表征其微观结构特性,为比较两种流体在力学测试中的最终宏观行为提供数据基础。因此,制备了气相二氧化硅和聚乙二醇STF以及淀粉与水STF基分散体。对每种STF进行粒径、zeta电位、SEM显微照片和流变学分析。采用10 ~ 30 %重量的填料,观察填料浓度的影响。在相同剪切速率下,淀粉/水STF的粘度测量值高于二氧化硅/聚乙二醇STF,最大粘度分别达到523.6 Pa s和178.9 Pa s。相比于二氧化硅,淀粉粒径更大,分别为303.7 nm和16.49 nm, zeta电位分析记录的颗粒静电荷分别为22.6 mV和12.8 mV,在高颗粒浓度下分散稳定性更好,增稠效果明显,在突然剪切速率下粘度跳变更大。结果表明,当采用STF时,可以尝试更多具有更大灵活性和更小厚度的保护应用,并且可以根据流体的行为选择良好的数据库。
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引用次数: 8
Corrigendum to “Antibacterial Screening of Gunnera perpensa-Mediated Silver Nanoparticles” 对 "Gunnera perpensa 介导的银纳米粒子的抗菌筛选 "的更正
IF 4.2 Q2 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2020-12-01 DOI: 10.1155/2020/7916862
N. Patel, K. Kasumbwe, V. Mohanlall, L. Mbatha
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引用次数: 0
Fungus- (Alternaria sp.) Mediated Silver Nanoparticles Synthesis, Characterization, and Screening of Antifungal Activity against Some Phytopathogens 真菌- (Alternaria sp.)介导的银纳米颗粒的合成、表征和抗植物病原体活性的筛选
IF 4.2 Q2 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2020-11-28 DOI: 10.1155/2020/8828878
T. Win, Sikandar Khan, Pengcheng Fu
The scientific consensus is now on developing a biocontrol agent that can cause cellular metabolic reprogramming against agricultural pathogens. Biosynthesis of silver nanoparticles was performed by using phytopathogenic fungi (Alternaria sp.) isolated from banana cultivated soil. Alternaria sp. can grow very fast and produce high enough bioactive compounds. This study aims to biosynthesize silver nanoparticles (AgNPs) using fungal Alternaria sp.’s metabolites as a safe antifungal agent against plant pathogenic fungi (Fusarium spp. and Alternaria sp.). To visualize the formation of AgNPs, analytical instruments were used, such as ultraviolet-visible (UV-Vis) spectroscopy, Fourier-transform infrared (FTIR) spectroscopy, scanning transmission electron microscopy (STEM), energy dispersive X-ray (EDX), and elemental mapping. The UV-visible spectra showed a peak at 435 nm. Analysis of scanning transmission electron microscopy (STEM) micrographs evidenced that the size of synthesized silver nanoparticles ranged between 3 and 10 nm. The resulting AgNPs showed distinct antifungal activity against selected plant pathogenic fungi. Synthesized AgNPs have demonstrated remarkable potential for the use of antifungal compounds to combat plant diseases.
科学界现在的共识是开发一种生物防治剂,可以引起细胞代谢重编程,以对抗农业病原体。利用从香蕉栽培土壤中分离的植物致病真菌(Alternaria sp.)进行了纳米银的生物合成。交替孢可以生长得非常快,并产生足够高的生物活性化合物。本研究旨在利用真菌Alternaria sp.的代谢物合成银纳米粒子(AgNPs),作为一种安全的抗植物病原真菌(镰刀菌和Alternaria sp.)的抗真菌剂。为了可视化AgNPs的形成,使用了分析仪器,如紫外-可见(UV-Vis)光谱,傅里叶变换红外(FTIR)光谱,扫描透射电子显微镜(STEM),能量色散x射线(EDX)和元素映射。紫外可见光谱在435 nm处有一个峰值。扫描透射电子显微镜(STEM)显微图分析表明,合成的银纳米颗粒的尺寸在3 ~ 10 nm之间。所得AgNPs对选定的植物病原真菌具有明显的抗真菌活性。合成的AgNPs已显示出利用抗真菌化合物对抗植物病害的巨大潜力。
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引用次数: 33
Synthesis of Copper Oxide Nanoparticles Using Plant Leaf Extract of Catha edulis and Its Antibacterial Activity 毛竹叶提取物合成氧化铜纳米颗粒及其抑菌活性研究
IF 4.2 Q2 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2020-11-22 DOI: 10.1155/2020/2932434
Worku Wubet Andualem, F. K. Sabir, E. T. Mohammed, H. Belay, B. Gonfa
Development of green technology is generating interest of researchers towards ecofriendly and low-cost methods for biosynthesis of nanoparticles (NPs). In this study, copper oxide (CuO) NPs were synthesized using a copper nitrate trihydrate precursor and Catha edulis leaves extract as a reducing and capping agent during the synthesis. The biosynthesized CuO NPs were characterized using an X-ray diffractometer (XRD), scanning electron microscopy-energy-dispersive X-ray spectroscopy (SEM-EDS), transmission electron microscope (TEM), Ultraviolet visible spectroscopy (UV-Vis), and Fourier transform infrared (FTIR) spectroscopy. XRD characterization confirmed that the biosynthesized CuO NPs possessed a good crystalline nature which perfectly matched the monoclinic structure of bulk CuO. Furthermore, the results obtained from SEM and TEM showed that the biosynthesized CuO NPs were spherical in shape. EDS characterization of the biosynthesized NPs also indicated that the reaction product was composed of highly pure CuO NPs. Moreover, the antimicrobial activities of different concentrations of CuO NPs synthesized using Catha edulis extract were also tested. Accordingly, the result showed that the highest zone of inhibitions measured were for CuO NPs synthesized using 1 : 2 ratios at 40 mg/ml solution concentration and observed to be 22 ± 0.01 mm, 24 ± 0.02 mm, 32 ± 0.02 mm, and 29 ± 0.03 mm for S. aureus, S. pyogenes, E. coli, and K. pneumonia, respectively.
绿色技术的发展引起了研究人员对生态友好和低成本的纳米颗粒生物合成方法的兴趣。本研究以三水合硝酸铜为前驱体,以Catha edulis叶提取物为还原封盖剂,合成了氧化铜(CuO) NPs。采用x射线衍射仪(XRD)、扫描电镜-能量色散x射线能谱仪(SEM-EDS)、透射电镜(TEM)、紫外可见光谱(UV-Vis)和傅里叶变换红外光谱(FTIR)对生物合成的CuO NPs进行了表征。XRD表征证实了生物合成的CuO纳米粒子具有良好的晶体性质,完全符合大块CuO的单斜结构。SEM和TEM分析结果表明,合成的CuO纳米粒子呈球形。生物合成NPs的EDS表征也表明反应产物由高纯度的CuO NPs组成。此外,还测试了以Catha edulis提取物合成的不同浓度CuO NPs的抑菌活性。结果表明,以1:2比例合成的CuO NPs在40 mg/ml溶液浓度下,对金黄色葡萄球菌、化脓性葡萄球菌、大肠杆菌和肺炎克氏杆菌的抑制区分别为22±0.01 mm、24±0.02 mm、32±0.02 mm和29±0.03 mm。
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引用次数: 60
Adsorption Behaviour and Kinetics of Zearalenone on Hydroxyl-Fe-Al-Intercalated Montmorillonite 玉米赤霉烯酮在羟基铁铝插层蒙脱土上的吸附行为及动力学研究
IF 4.2 Q2 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2020-08-13 DOI: 10.1155/2020/7680738
Shengqiong Fang, Yu Xiao, Huiqiang Wang
Pristine montmorillonite (Mont) was used as raw materials to prepare hydroxyl-Fe-pillared Mont, hydroxyl-Al-pillared Mont, and hydroxyl-Fe-Al-pillared Mont composites. By varying the OH/Fe and Fe/Al molar ratios during the preparation of the pillared Mont, the adsorption capacity of zearalenone (ZEA) and the kinetics were elucidated. The characterization of X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy reveals the adsorption mechanism of pristine and modified Mont. The results indicated that the ZEA adsorption capacity is Mont (0.05 mg/g) << 1.5OH/Fe-Mont (0.28 mg/g) << OH/Al-Mont (0.51 mg/g) < 0.5Fe/Al-Mont (0.56 mg/g) in the condition of pH = 8 and 37°C, in which both 0.5Fe/Al-Mont and OH/Al-Mont reached maximum adsorption capacity and 1.5OH/Fe-Mont attained 5 times the capacity of Mont. Adsorption isotherm studies revealed that Freundlich adsorption isotherms best represented the experimental data. The kinetic data for ZEA adsorption revealed that the Mont adsorption capacity for ZEA equilibrates in 1 hour and is best described using the pseudo-second-order rate equation. The XRD analysis indicated that the amplification of Fe-dominant pillared Mont interlayer spacing is the main reason for the observed increases in the adsorption capacity of ZEA, while Al-dominant pillared Mont has a relatively stable Keggin structure; therefore, interlayer spacing is not the primary mechanism for changes in the adsorption capacity of both OH/Al-Mont and Al-dominant pillared Mont. An FT-IR analysis demonstrated that cationic exchange was the dominant mechanism that allowed ZEA and hydroxyl-Al ions to enter the Mont interlayers, while this cationic exchange mechanism was not the dominant mechanism used by hydroxyl-Fe entering the Mont layers.
以原始蒙脱土为原料,制备了羟基铁柱蒙脱土、羟基铝柱蒙脱土和羟基铁铝柱蒙脱土复合材料。通过改变OH/Fe和Fe/Al的摩尔比,研究了柱状Mont对玉米赤霉烯酮(ZEA)的吸附能力和动力学。x射线衍射(XRD)和傅里叶变换红外光谱(FT-IR)表征揭示了原始和改性Mont的吸附机理。结果表明:在pH = 8和37℃条件下,ZEA吸附量为Mont (0.05 mg/g) << 1.5OH/Fe-Mont (0.28 mg/g) << OH/Al-Mont (0.51 mg/g) < 0.5Fe/Al-Mont (0.56 mg/g),其中0.5Fe/Al-Mont和OH/Al-Mont均达到最大吸附量,1.5OH/Fe-Mont达到Mont的5倍。吸附等温线研究表明Freundlich吸附等温线最能代表实验数据。ZEA吸附的动力学数据表明,ZEA对Mont的吸附量在1 h内达到平衡,用拟二级速率方程最能描述吸附量。XRD分析表明,Fe-dominant柱状Mont层间间距的扩大是ZEA吸附量增加的主要原因,而Al-dominant柱状Mont具有相对稳定的Keggin结构;因此,层间间距不是OH/Al-Mont和Al-dominant柱状Mont吸附能力变化的主要机制。FT-IR分析表明,阳离子交换是ZEA和羟基al离子进入Mont层的主要机制,而这种阳离子交换机制不是羟基fe进入Mont层的主要机制。
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引用次数: 1
Nanoparticle Therapy Is a Promising Approach in the Management and Prevention of Many Diseases: Does It Help in Curing Alzheimer Disease? 纳米粒子治疗在许多疾病的管理和预防中是一种很有前途的方法:它是否有助于治疗阿尔茨海默病?
IF 4.2 Q2 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2020-08-07 DOI: 10.1155/2020/8147080
L. Kassem, N. Ibrahim, S. Farhana
Treatment of brain diseases is always limited by the physiological nature of the highly selective blood-brain barrier (BBB) and the electrostatic charge of the nanoporous extracellular matrix. Nanomedical application provides a promising drug delivery revolution for the treatment of neurodegenerative diseases (NDDs). It depends on improving the pharmacokinetic distribution of drugs through the central nervous system. Nanotechnology offers various forms of nanoparticles, and these nanoparticles have brain-targeted and long-acting properties with minimal systemic adverse effects and motor complications. Gene delivery vehicles and nanocarriers including neurotrophic factors are promising therapeutics for many NDDs, and they can modulate neuronal survival and synaptic connectivity. Neurotrophic factors when integrated with the nanotechnological approaches can pass the BBB merely, representing a significant challenging track. Clinical trials proved that levodopa nanoparticles cause little motor complications which is a considerable drawback in treating Parkinson’s disease with levodopa. Recently, nanotechnology had patented new formulations and achieved various advanced procedures for management, and even prevention, of NDDs. Nanotechnology can be integrated into neuroscience to fight against neurodegenerative diseases. Primary research studies in using nanoparticles to cure Alzheimer disease (AD) are promising but are still in need for more investigations. The present paper aims to review, outline, and summarize various efforts done in the field of using nanoparticles in the management of Alzheimer.
脑部疾病的治疗一直受到高选择性血脑屏障(BBB)的生理性质和纳米多孔细胞外基质的静电电荷的限制。纳米医学的应用为神经退行性疾病(ndd)的治疗提供了一场有希望的药物传递革命。它依赖于改善药物在中枢神经系统中的药代动力学分布。纳米技术提供了各种形式的纳米颗粒,这些纳米颗粒具有针对大脑的长效特性,并且具有最小的全身不良反应和运动并发症。包括神经营养因子在内的基因传递载体和纳米载体是许多ndd的治疗方法,它们可以调节神经元存活和突触连通性。当神经营养因子与纳米技术相结合时,仅能通过血脑屏障,这是一个具有重大挑战性的途径。临床试验证明,左旋多巴纳米颗粒引起的运动并发症很少,这是左旋多巴治疗帕金森病的一个相当大的缺点。最近,纳米技术获得了新配方的专利,并实现了管理甚至预防ndd的各种先进方法。纳米技术可以与神经科学相结合,以对抗神经退行性疾病。利用纳米颗粒治疗阿尔茨海默病(AD)的初步研究是有希望的,但仍需要更多的研究。本文旨在回顾、概述和总结在使用纳米颗粒管理阿尔茨海默病领域所做的各种努力。
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引用次数: 11
Effect of Silver Nanoparticles on the Morphology of Toxoplasma gondii and Salmonella braenderup 纳米银对刚地弓形虫和牛痘沙门氏菌形态的影响
IF 4.2 Q2 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2020-07-13 DOI: 10.1155/2020/9483428
Diego Vergara-Duque, Liliana Cifuentes-Yepes, Tatiana Hincapie-Riaño, Felipe Clavijo-Acosta, Graciela Juez-Castillo, Brayan Valencia-Vidal
The study of silver nanoparticles (AgNPs) has recently increased due to the different antimicrobial properties that have been evaluated. Studies have shown that AgNPs decrease the cell viability of some parasitic species and inhibit bacterial growth and biofilm formation. Toxoplasma gondii is a parasite with different stages of development including the oocyst, and it can survive in the environment for a long time generating contamination of vegetables and water. This parasite has the ability to generate congenital toxoplasmosis and chorioretinitis in humans. Another human pathogen present in water is Salmonella braenderup, this bacterium, when consumed, causes gastroenteritis and typhoid fever. We evaluate the affectation that causes the AgNPs in oocysts of T. gondii and S. braenderup using fluorescence microscopy and scanning electron microscopy techniques. The results showed that at different ratios of AgNPs and microorganisms, as well as at different exposure time during the treatments, morphological alteration of the cell structure of oocysts of T. gondii and S. braenderup was evidenced, suggesting a potential treatment method for the inhibition of the viability of these microorganisms.
银纳米颗粒(AgNPs)的研究最近有所增加,因为已经评估了不同的抗菌性能。研究表明,AgNPs降低了一些寄生物种的细胞活力,抑制了细菌的生长和生物膜的形成。刚地弓形虫是一种包括卵囊在内的不同发育阶段的寄生虫,它可以在环境中长时间生存,对蔬菜和水产生污染。这种寄生虫有能力在人类中产生先天性弓形虫病和绒毛膜视网膜炎。另一种存在于水中的人类病原体是牛痘沙门氏菌,这种细菌被食用后会引起肠胃炎和伤寒。我们利用荧光显微镜和扫描电子显微镜技术评估了导致弓形虫和布氏绦虫卵囊中AgNPs的影响。结果表明,在AgNPs与微生物的不同比例、不同处理时间下,弓形虫和S. braenderup卵囊的细胞结构发生了形态学改变,提示了抑制这两种微生物活力的潜在处理方法。
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引用次数: 3
Synthesis of Specific ZnF Based Nanoparticles (ZnFe2O4): Antimicrobial Properties, Surface Characteristics, and Adsorption Activity for AB 29 Textile Dye ZnF基纳米颗粒(ZnFe2O4)的合成:抗菌性能、表面特性及对AB - 29纺织染料的吸附活性
IF 4.2 Q2 NANOSCIENCE & NANOTECHNOLOGY Pub Date : 2020-07-02 DOI: 10.1155/2020/3139701
Ferda Gönen, Gökhan Tekinerdoğan
In this investigation, the color removal from synthetic wastewaters containing Acid Blue 29 (AB 29) dye was investigated by ZnF-based nanomaterials (ZnFe2O4) synthesized by the coprecipitation method in a batch system. SEM, FT–IR, and XRD analysis were used for the characterization of the nanoparticles (before and after adsorption), and the analysis results were compared with each other. The parameters such as pH, temperature, dye concentration, and nanoparticle dosage affecting color removal were examined systematically, and favorable color removal conditions were determined by the classical approach. From the experimental results, the favorable conditions with high removal efficiency for the adsorption were determined: removal temperature 35°C and the removal pH 2.0. At these experimental conditions, the adsorbed dye amount per unit mass of adsorbent and the percentage dye removal were determined as 1489.79 mg·g−1 and 98.83%, respectively. In the other part of the research, three different isotherm models (Langmuir, Freundlich, and Temkin) were used to examine the adsorption equilibrium data. Langmuir and especially Freundlich linear isotherm models provided the highest R2 regression coefficients, successfully. The kinetic data was evaluated by pseudo-first-order and pseudo-second-order kinetic model approach. It was observed that pseudo-second-order kinetic model best represented AB 29-ZnF adsorption kinetic data. The determined thermodynamic parameters such as ΔH, ΔS, and ΔG were proved that the AB 29-ZnF adsorption system was an exothermic (ΔH < 0), spontaneous, thermodynamically favorable (ΔG < 0), and stabilized system without any structural changes in sorbate and sorbents (ΔS<0).
采用共沉淀法合成的ZnFe2O4纳米材料对含酸性蓝29 (AB 29)染料的合成废水进行了脱色研究。采用SEM、FT-IR、XRD等分析方法对纳米颗粒(吸附前后)进行表征,并对分析结果进行对比。系统考察了pH、温度、染料浓度、纳米颗粒用量等对去色的影响,并通过经典方法确定了最佳去色条件。从实验结果中确定了吸附效率高的有利条件:去除温度35℃,去除pH 2.0。在此实验条件下,单位质量吸附剂对染料的吸附量和去除率分别为1489.79 mg·g−1和98.83%。在研究的另一部分,使用了三种不同的等温线模型(Langmuir, Freundlich和Temkin)来检查吸附平衡数据。Langmuir,特别是Freundlich线性等温线模型成功地提供了最高的R2回归系数。采用拟一阶和拟二阶动力学模型方法对动力学数据进行了评价。结果表明,准二级动力学模型最能反映AB - 29-ZnF吸附动力学数据。测定的热力学参数ΔH、ΔS和ΔG证明了AB 29-ZnF吸附体系是一个放热(ΔH <0)、自发、热力学有利(ΔG <0)、稳定的体系,山梨酸盐和吸附剂(ΔS<0)没有任何结构变化。
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引用次数: 3
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Journal of Nanotechnology
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