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Performance evaluation of mercerization and acetylation on hardness of raffia palm fibre 丝光和乙酰化对棕榈纤维硬度的影响
Pub Date : 2023-05-31 DOI: 10.4314/sa.v22i1.12
N. Obinichi, I. Uchegbulam
As the demand for environmentally friendly products rises and global awareness on reducing toxicities in manufacturing increases, the exploitation of  plant-based raw materials like raffia palm fiber requires closer attention. In this study, the effect of sodium hydroxide and acetic anhydride concentration  on the hardness of raffia palm fiber at varying drying temperature and fiber length were investigated. The treatments were carried out using 10% sodium  hydroxide solution and 5% acetic anhydride at oven drying temperatures of 70oC for mercerized fiber and 50oC for acetylated fiber with varying  fiber length of 50mm, 60mm, 70mm and 80mm. Findings show hardness values of 257HR and 370HR for 10% NaOH at 70oC and 5% acetic anhydride at  50oC respectively showing a 30.38% rise in Rockwell Hardness value in the acetylated fibers over the mercerized cohorts. Remarkably, these results were  obtained at ideal fiber lengths of 60mm in both treatments. Hence, acetylation treatment at 5% acetic anhydride concentration and 50oC oven-drying  temperature using 60mm fiber length offered optimal hardness value for raffia palm fiber. This is highly recommended for industrial commercialization  for composites in the automobile, construction, manufacturing, medical, sports, oil and gas industries. In addition, the results from this study will open  new economic values for Nigerian Raffia Palm fiber as potential reinforcement material for both domestic and international markets and applications. 
随着对环保产品需求的增加以及全球对减少制造过程中毒性的意识的提高,需要更加密切地关注以植物为基础的原材料(如拉菲亚棕榈纤维)的开发。研究了在不同干燥温度和纤维长度下,氢氧化钠和乙酸酐浓度对棕榈纤维硬度的影响。以10%的氢氧化钠溶液和5%的乙酸酐为原料,丝光纤维干燥温度为70℃,乙酰化纤维干燥温度为50℃,纤维长度为50mm、60mm、70mm和80mm。结果表明,在10% NaOH(70℃)和5%乙酸酐(50℃)条件下,乙酰化纤维的硬度值分别为257HR和370HR,与丝光纤维相比,乙酰化纤维的洛氏硬度值提高了30.38%。值得注意的是,在理想纤维长度为60mm时,两种处理均获得了这些结果。因此,在5%的乙酸酐浓度和50℃的烘箱干燥温度下,以60mm的纤维长度进行乙酰化处理,可获得最佳的棕榈纤维硬度值。强烈建议在汽车、建筑、制造、医疗、体育、石油和天然气行业的复合材料工业商业化中使用。此外,本研究结果将为尼日利亚拉菲亚棕榈纤维作为潜在的增强材料在国内和国际市场和应用中开辟新的经济价值。
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引用次数: 0
Petrophysical properties and volume estimation of hydrocarbon resources in x field, onshore niger delta: A reservoir characterization study 尼日尔三角洲x油田油气资源物性及体积估算:储层表征研究
Pub Date : 2023-05-31 DOI: 10.4314/sa.v22i1.14
E.G. Maju-Oyovwikowhe, E. Ighodaro
A reservoir characterization study was conducted on three wells located in X Field, situated in the Onshore region of the Niger Delta. A suite of  conventional digital well logs was utilized to identify hydrocarbon-bearing reservoirs, determine reservoir petrophysical parameters, and infer the depositional environment. The study delineated four hydrocarbon-bearing reservoirs, labeled A, B, C, and D, with porosity estimates ranging from 25% to  27%, and permeability values varying from 1863.22md to 2759.78md. These results suggest that the reservoirs have good storage capacity and permit  free flow of fluids, consistent with prior research in the Niger Delta. The water saturation values, ranging from 43% to 70% for Well X and 53% to 94% for  Well Y, indicate the presence of significant hydrocarbon in reservoir C, while Well Z did not contain any hydrocarbon. The estimation of oil and gas  resources indicated that Well X contains 1.11 X 105 barrels/acre of oil and 5.16 X 107 cubic feet/acre of gas, while Well Y contains 4.43 X 106 cubic feet of  gas. The analysis of the volume of shale (0.15-0.19) revealed that the reservoirs range from slightly shaly sand to shaly sand. Based on the log motifs, the  study suggests that the reservoirs are mainly fluvial channel deposits, and the rapid alternation of thin beds of sand and shale indicates deposits of delta  progradation and river floodplain deposits.
对位于尼日尔三角洲陆上区域X油田的三口井进行了储层表征研究。利用一套常规数字测井资料识别含油气储层,确定储层岩石物性参数,推断沉积环境。该研究圈定了4个含油气储层,分别为A、B、C和D,孔隙度估计范围为25% ~ 27%,渗透率范围为1863.22md ~ 2759.78md。这些结果表明,储层具有良好的储存能力,允许流体自由流动,这与尼日尔三角洲先前的研究结果一致。X井的含水饱和度在43% ~ 70%之间,Y井的含水饱和度在53% ~ 94%之间,这表明C储层中存在大量的油气,而Z井则不含任何油气。对油气资源的估算表明,X井的产油量为1.11 X 105桶/英亩,天然气储量为5.16 X 107立方英尺/英亩,而Y井的天然气储量为4.43 X 106立方英尺。页岩体积(0.15 ~ 0.19)分析表明,储层范围为微泥质砂-泥质砂。基于测井母图,研究认为储层以河道沉积为主,砂泥薄层的快速交替表明储层为三角洲沉积和河漫滩沉积。
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引用次数: 0
Environmental and ethical negative implications of AI in agriculture and proposed mitigation measures 人工智能对农业的环境和伦理负面影响以及拟议的缓解措施
Pub Date : 2023-05-31 DOI: 10.4314/sa.v22i1.13
U. Okengwu, L. Onyejegbu, L. U. Oghenekaro, M. Musa, A. O. Ugbari
Numerous ethical and environmental questions are raised by the use of Artificial Intelligence (AI) in agriculture or precision farming. This study examines  strategies that can solve environmental and ethical concerns as well as the negative effects artificial intelligence in agriculture may have on the environment and society. It employed a thorough literature study to determine the adverse effects of AI on the environment and ethics in Africa, as well  as the suggested counter measures. The rate of carbon emissions is rising as a result of AI models, and constant power supply in our farms. Additionally, the ethical issues around data ownership rights, privacy and security, data bias, and the belief that AI in agriculture will someday entirely replace  occupations designated for farmers were explored, along with suggestions for mitigating each of these issues. African academics, policymakers, and  innovators are crucial for ensuring that AI solutions are in line with African priorities and requirements. 
人工智能(AI)在农业或精准农业中的应用引发了许多伦理和环境问题。本研究探讨了可以解决环境和伦理问题的策略,以及农业人工智能可能对环境和社会产生的负面影响。它进行了全面的文献研究,以确定人工智能对非洲环境和道德的不利影响,以及建议的应对措施。由于人工智能模型和我们农场的持续电力供应,碳排放量正在上升。此外,还探讨了有关数据所有权、隐私和安全、数据偏见的道德问题,以及人工智能在农业中有朝一日将完全取代指定给农民的职业的信念,以及减轻这些问题的建议。非洲学者、政策制定者和创新者对于确保人工智能解决方案符合非洲的优先事项和要求至关重要。
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引用次数: 0
Application of modified cellulose for Pb2+ and Cu2+ removal from aqueous solutions: Kinetic and isotherms studies 改性纤维素在水中去除Pb2+和Cu2+中的应用:动力学和等温线研究
Pub Date : 2023-05-31 DOI: 10.4314/sa.v22i1.11
A. Ibikunle, A. Ogunneye, N. Sanyaolu, K.A. Olutayo, S. Ogundare, A. Ogunmoye, O. ATEWOLARA-ODULE, S. Yussuf, K. Moberuagba
In this work, acrylamide grafted Kolanut Pod Husk cellulose adsorbents were successfully prepared via chemical modification of Kola nut pod husk  cellulose with acrylamide and N, N’- methylenebisacrylamide. The modified adsorbents were successfully applied for the adsorptive removal of Pb2+ and  Cu2+ ions from aqueous solutions at different parameters, such as pH of the solution, adsorbent dosage, contact time, and initial metal ion  concentrations were optimized. Qualitative analysis of the modified adsorbents was performed by Fourier Transformed Infra-Red Spectroscopy and  Scanning Electron Microscopy. Characterization analyses portrayed the surface of adsorbents as being short elongated shaped with dispersed pores and  composed of hydroxyl and carbonyl groups as the main binding sites. The optimum conditions for adsorption of Pb2+ and Cu2+ were found to be: pH; 5,  adsorbent dosage; 3.5 and 4 g L-1 , concentration; 60 mg L-1 and contact time; 160 min. Adsorption data were fully fitted with the Freundlich, Langmuir  isotherm model, and a pseudo-second order, Elovich kinetic model. The adsorption of metal ion was heterogenous in nature with qmax of 55.14 mg g-1 and 62.09 mg g-1 for Pb2+, 54.82 mg g-1 , and 60.43 mg gfor Cu2+ respectively. These results showed that the modified adsorbents were able to  efficiently remove Pb2+ and Cu2+ from aqueous solutions. 
本研究通过丙烯酰胺和N, N′-亚甲基双丙烯酰胺对可乐果壳纤维素进行化学改性,制备了丙烯酰胺接枝的可乐果壳纤维素吸附剂。对改性吸附剂在不同溶液pH、吸附剂用量、接触时间和初始金属离子浓度条件下对Pb2+和Cu2+的吸附去除效果进行了优化。采用傅里叶变换红外光谱和扫描电镜对改性吸附剂进行定性分析。表征分析表明,吸附剂表面呈细长状,孔隙分散,以羟基和羰基为主要结合位点。发现吸附Pb2+和Cu2+的最佳条件为:pH;5、吸附剂用量;3.5和4 g L-1,浓度;60 mg L-1及接触时间;吸附数据完全符合Freundlich, Langmuir等温模型和拟二级Elovich动力学模型。对金属离子的吸附是多相的,Pb2+的qmax分别为55.14 mg g-1和62.09 mg g-1, Cu2+的qmax分别为54.82 mg g-1和60.43 mg g-1。结果表明,改性吸附剂能有效去除水中的Pb2+和Cu2+。
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引用次数: 0
Pneumonia disease detection and classification system using naive Bayesian technique 基于朴素贝叶斯技术的肺炎疾病检测与分类系统
Pub Date : 2023-05-31 DOI: 10.4314/sa.v22i1.10
T. Ojetunmibi, P. O. Asagba, U. Okengwu
Pneumonia is a chronic inflammation illness that affects both children and adults and is spread by various bacteria, viruses, and fungi. Since there are not  enough specialists and facilities to interpret the findings of lab-based diagnosis, resulting to several cases of Pneumonia-related deaths. When the  disease is discovered at an early stage as opposed to a later stage, it can be easily managed or controlled. The aim of the study is to create an effective  pneumonia disease detection and classification system that uses Naive Bayesian and random forest Algorithms. The hash-based function was applied to  train the model on X-ray chest samples from patients with pneumonia in order to improve detection accuracy and decrease classification errors. The  hashing-based function was employed to compute and convert X-ray image features to a corresponding numerical code or label stored in a relative  address and used as an array of reference given the associated values. The system was implemented using a future scaling technique that required the  use of a hash encoding algorithm for the categorical labels of the target variable, and it improved model performance. We validated and compared the  techniques in terms of accuracy and RMSE across different fine-tuned hyper-parameter values. The RF produced 97% with 3.33 error rate while NB  recorded 99.08% accuracy rate as the best with 0.020 RMSE value.
肺炎是一种影响儿童和成人的慢性炎症疾病,由各种细菌、病毒和真菌传播。由于没有足够的专家和设施来解释实验室诊断的结果,导致几例肺炎相关死亡。如果在早期而不是后期发现疾病,就可以很容易地对其进行管理或控制。该研究的目的是创建一个有效的肺炎疾病检测和分类系统,该系统使用朴素贝叶斯和随机森林算法。为了提高检测精度,减少分类误差,我们利用基于哈希函数的肺炎患者x线胸片样本训练模型。基于散列的函数用于计算x射线图像特征并将其转换为存储在相对地址中的相应数字代码或标签,并作为给定关联值的参考数组使用。该系统是使用未来的缩放技术实现的,该技术需要对目标变量的分类标签使用哈希编码算法,并且它提高了模型性能。我们在不同微调超参数值的准确性和RMSE方面验证并比较了这些技术。RF的准确率为97%,错误率为3.33,NB的准确率为99.08%,RMSE值为0.020。
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引用次数: 1
Determination of groundwater potential using electrical resistivity survey and borehole logging in sites I and III of Delta State University, Abraka Nigeria 利用电阻率测量和钻孔测井在尼日利亚阿布巴卡三角洲州立大学I和III点确定地下水潜力
Pub Date : 2023-01-29 DOI: 10.4314/sa.v21i3.1
J. Okonkwo, J. Egbai
This study examines the aquifer properties and lithological structure of Abraka, Nigeria, specifically the Delta State University Site I and III environs. Ten Schlumberger geoelectric soundings, geophysical well logging and pumping test method were employed using an ABEM Terrameter. A drilled water well and existing borehole data were used for this study. The result of the lithological study revealed that the subsurface formations consist of topsoil, lateritic sand, fine and medium grain sand mixed with clay. The topsoil is brownish with thickness of 2 m, the laterite is reddish with thickness of 4 m, the fine sand is whitish with thickness of 10 m, and the medium sand is also whitish with thickness >12 m. The results of the evaluation of the geoelectric data using curve matching and Win Resist computer iteration was in strong agreement with that of the well record, with a subsurface that is composed of 4 to 6 geo-electric layers. The depth ranges from 13.5m to 97.8m while the resistivity ranges from 1021.2 Ωm to 9092.4 Ωm. A core soil sample collected at an interval of 5m, spontaneous potential and resistivity logs were carried out on the well. The hydraulic conductivity, well's transmissivity, storativity, and specific capacity are 102.7m2/day, 5.14 m/day, 0.00062 and 0.39 m3/m respectively. It is recommended that a drill depth of 30 m and above should be accessed for potable water in the area. From the result of this survey, we infer that this aquifer is confined and capable of supplying the people with adequate and good quality drinking water.
本研究考察了尼日利亚阿布巴卡的含水层性质和岩性结构,特别是三角洲州立大学遗址I和III周边地区。使用ABEM Terrameter进行了斯伦贝谢地电测深、地球物理测井和泵送测试。本研究使用了一口钻探水井和现有钻孔数据。岩性研究结果表明,地下地层由表层土、红土砂、细粒砂和中粒砂混合粘土组成。表层土为褐色,厚度为2 m,红土为红色,厚度为4 m,细砂为白色,厚度为10 m,中砂也为白色,厚度>12 m。利用曲线匹配和Win Resist计算机迭代对地电数据进行评价的结果与井记录的结果非常吻合,地下由4至6个地电层组成。埋深13.5m ~ 97.8m,电阻率1021.2 Ωm ~ 9092.4 Ωm。每隔5m采集岩心土壤样品,对该井进行了自然电位和电阻率测井。水导率为102.7m2/天,井透过率为5.14 m/天,储水量为0.00062 m/天,比容为0.39 m/天。建议该地区饮用水的钻孔深度为30米及以上。根据调查结果,我们推断该含水层是受限制的,能够为人们提供充足、优质的饮用水。
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引用次数: 0
Sequence stratigraphy and tectonic framework of the Gabo Field, Niger Delta, Nigeria 尼日利亚尼日尔三角洲Gabo油田层序地层学与构造格架
Pub Date : 2023-01-29 DOI: 10.4314/sa.v21i3.2
T.C. Iheaturu, R. Ideozu, S. Abrakasa, A. Jones
This research examines the sequence stratigraphic and structural framework of the Gabo Field Niger Delta, Nigeria. Materials used in this research include 3D seismic volume in Seg-Y, ditch cuttings and wells logs. The methods applied are standard methods in addition to using the Frazier and Galloway approach for genetic sequences. The tectonic framework was interpreted in terms of deformational, depositional and post-depositional structures. The deformational structures are faults F1 and F2 – which are closely spaced normal faults and F3 is a syn-depositional growth fault. The depositional structures are pinchouts and interbedded sand/shale sequences whereas the postdepositional structures are compaction and smearing or flexure of the shales. The well correlation shows the sequences are cyclic and the facies analysis of T4 – T9 sands are very fine to medium grained, light to dark brown, texturally mature and moderate to well sorted. The facies associations are fluvial distributary channel, tide dominated fluvial channels, abandoned channel or switching and flood plain deposits. While the depositional environments are upper delta plain, lower delta plain and delta front. Sequence stratigraphic analysis explained the observed increase in shale thickness in the intermediate sections and showed sediment deposition occurred in three (3) systems tracts- Lowstand Systems Tract (LST), the Transgressive Systems Tract (TST) and Highstand Systems Tract (HST). The sedimentological model showed the environments of deposition had a tidal influence and ranged from fluvial to estuarine. The findings of this research may be applied to similar deltaic basins around the world in planning of oilfield development. In addition it may correlate cyclic successions and predict facies distributions of similar depositional patterns. 
本研究考察了尼日利亚尼日尔三角洲Gabo油田的层序地层和构造格架。本研究使用的材料包括segg - y的三维地震体、岩屑和测井资料。除了使用Frazier和Galloway方法进行基因序列外,所应用的方法是标准方法。从变形构造、沉积构造和沉积后构造三个方面对构造格架进行了解释。变形构造为断层F1和断层F2 -,它们是紧密间隔的正断层,而断层F3是同沉积生长断层。沉积构造为针状和层间砂/页岩层序,而沉积后构造为页岩压实、涂抹或弯曲构造。井对比表明,层序为旋回,T4 ~ T9砂相分析为极细至中粒,浅至深褐色,结构成熟,分选适中。相组合为河流分流河道、潮汐控制河道、废弃河道或转换河道和洪泛平原沉积。沉积环境为上三角洲平原、下三角洲平原和三角洲前缘。层序地层学分析解释了中间剖面页岩厚度的增加,表明沉积发生在低水位体系域(LST)、海侵体系域(TST)和高水位体系域(HST) 3个体系域。沉积学模型表明,沉积环境受潮汐影响,从河流到河口不等。研究结果可为世界上类似三角洲盆地的油田开发规划提供参考。此外,它还可以对比旋回序列和预测相似沉积模式的相分布。
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引用次数: 0
Design and analysis of grid-connected energy systems for commercial buildings 商业建筑并网能源系统的设计与分析
Pub Date : 2023-01-29 DOI: 10.4314/sa.v21i3.9
D. Akinyele, O. Olabode, I. Okakwu, J.A. Adeosun, M. Sulaiman, A. Okediji
This paper presents the design of energy generation based on the national grid, solar photovoltaic (PV), and diesel-based supply systems for a commercial building in Obanikoro, Lagos with a total demand and peak load of ~56,000 kWh/yr and 13.5 kW, respectively. The grid is simulated based on the average daily supply of 6 hours being experienced in the study location, indicating that the building is not served for an average of 18 hours/day. The paper considers three design configurations: grid, grid + PV, and grid + PV + generator systems in HOMER Microgrid tool and their performances are compared in terms of the annual generation, load not served, and the emissions. A load demand of ~14,000 kWh/yr meaning that 75 % of total demand is not met. A 35.2 kW PV was added to the grid, with both supplying 49,687 and 13,826 kWh/yr, respectively. However, a 6.98% of the load is not served. A 15 kW generator is then added to form the grid + PV+ diesel generator configuration, and the participating energy sources supply 15,818, 49,723 and 4,834 kWh/yr, respectively. This configuration is able to meet the demand without any deficit. The CO2, CO, unburned hydrocarbons, particulate matter and SO2 and nitrogen oxides emissions for the three configurations are 8.824, 0, 0, 0, 0.0383 and 0.0187 tonnes/yr; 8.192, 0, 0, 0, 0.0355 and 0.0174 tonnes/yr, and 11.833, 0.0259, 0.00113, 0.000157, 0.0435 and 0.0407 tonnes/yr, respectively. The study can help to mitigate the energy shortage in commercial buildings. 
本文介绍了拉各斯Obanikoro一座商业建筑的发电设计,该建筑的总需求和峰值负荷分别为~56,000千瓦时/年和13.5千瓦,基于国家电网、太阳能光伏(PV)和柴油供电系统。网格是根据研究地点平均每天6小时的供电进行模拟的,表明该建筑平均每天18小时没有供电。本文考虑了HOMER微电网工具中电网、电网+光伏、电网+光伏+发电机三种系统的设计配置,并从年发电量、未服务负荷、排放等方面对其性能进行了比较。约14000千瓦时/年的负荷需求意味着总需求的75%没有得到满足。新增35.2千瓦光伏发电装机,年发电量分别为49687千瓦时和13826千瓦时。但是,6.98%的负载没有得到服务。然后再加上一台15kw的发电机,形成电网+光伏+柴油发电机的配置,参与的能源分别供应15,818、49,723和4,834 kWh/年。这种配置能够满足需求,没有任何赤字。三种构型的CO2、CO、未燃碳氢化合物、颗粒物、SO2和氮氧化物排放量分别为8.824、0、0、0、0.0383和0.0187吨/年;分别为8.192、0、0、0、0.0355和0.0174吨/年,11.833、0.0259、0.00113、0.000157、0.0435和0.0407吨/年。该研究有助于缓解商业建筑的能源短缺问题。
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引用次数: 0
Late maastrichtian- early eocene dinoflagellate cyst biostratigraphy and aleoenvironmental study of sediments in Akukwa-1 well in the Anambra Basin 阿南布拉盆地Akukwa-1井晚马氏-早始新世甲藻囊生物地层学及沉积环境研究
Pub Date : 2023-01-29 DOI: 10.4314/sa.v21i3.15
G. Soronnadi-Ononiwu, Y. Yikarebogha, N. Ukpabi
Dinoflagellate cyst biostratigraphy and palaeoenvironment of deposition of sediments penetrated by Akukwa-1 Well was carried out with a total of 253ditch cuttings using the conventional maceration technique for recovering of acid insoluble organic-walled microfossils from sediments. Sedimentological description delineated five (5) lithological units within the well, which included those of Nkporo Shale, Mamu Formation, Ajali Sandstone, Nsukka Formation and Imo Shale. A total of 14 genera and 35 species of dinoflagellate cyst were identified. The recovered dinocysts were used to establish palaeoenvironment which ranged from marginal to shallow marine, the forms were also used to propose four (4) informal dinoflagellate cyst zonations labelled (A-D) based on the first and last occurrences of two or more species. They included Zone A (Apectodinium paniculatum zone), occurring at 7990ft(Maastrichtian), zone B(Paleocystodinium australinium zone) occurring between 7990ft -4000ft (Upper Maastrichtian), zone C(Apectodinium homomorphum zone) occurring between 4000ft -2550ft (Upper Maastrichtian), and zone D(Homotryblum palladium zone) occurring between 5550ft-1520ft(Paleocene- Early Eocene). The erected dinocyst zones were correlated with the existing biozones in tropical areas of Africa and northern South America.
采用常规浸渍法从沉积物中回收酸不溶性有机壁微化石,对Akukwa-1井共253块沟岩屑进行了甲藻囊生物地层及沉积古环境研究。通过沉积学描述,圈定了井内5个岩性单元,分别为Nkporo页岩、Mamu组、Ajali砂岩、Nsukka组和Imo页岩。共鉴定出鞭毛藻囊14属35种。利用回收的甲藻囊建立了从边缘到浅海的古环境,并根据两个或两个以上物种的首次和最后出现,提出了四(4)个非正式甲藻囊带(A-D)。它们包括A区(Apectodinium paniculatum带),出现在7990英尺(马斯特拉特),B区(palocystodinium australinium带)出现在7990英尺-4000英尺(上马斯特拉特),C区(Apectodinium homoomorphum带)出现在4000英尺-2550英尺(上马斯特拉特),D区(Homotryblum palladium带)出现在5550英尺-1520英尺(古新世-早始新世)。竖立的恐龙囊带与非洲热带地区和南美洲北部已有的生物带具有相关性。
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引用次数: 0
Preparation, functional and pasting behavior of starch phosphates of red cocoyam (Colocosia esculenta) and white cocoyam (Colocosia antiquorum): a comparative study 红椰和白椰淀粉磷酸酯的制备、功能和糊化行为的比较研究
Pub Date : 2023-01-29 DOI: 10.4314/sa.v21i3.11
S. Yussuf, A. Ibikunle, N. Sanyaolu, S. Ogundare, M. A. Adesanya, C.O. Atewolara- Odule, A. Ogunmoye, A. Adeleke, A. Hashimi, O. Olubomehin
A contemporary strategy in the starch industries is the diversification of raw materials. However, the hydrophilic nature of starch limits its use as a raw material for food and packaging products, resulting in a low level of biodegradation. To address this issue, it is imperative that starch be chemically modified. Starch phosphates are among the most common and commonly used chemically modified starches. In this study, native red cocoyam starch (NRCS) and native white cocoyam starch (NWCS) were chemically modified with di-sodium hydrogen orthophosphate as phosphorylating agent to produce red cocoyam starch phosphate (PRCS) and white cocoyam starch phosphate (PWCS). The functional and pasting properties of the native and starch phosphates of both cocoyam species were evaluated and compared. The starch yield increased from ~ 17% for NRCS to ~ 25% for PRCS and from ~ 12% for NWCS to ~ 20% for PWCS. The water and oil absorption capacities were 97.00 & 143.00% for NRCS and 78.00 & 164.00% for NWCS, whereas for PRCS it was 160.00 & 153.00% and for PWCS it was 127.00 & 173.00% respectively. NRCS and PRCS had a foam capacity of 8.80 and 9.00% while NWCS and PWCS had 8.00 and 10.00% respectively. Phosphorylation had a significant impact on the pasting properties leading to a reduction in the peak, breakdown, set back, and final viscosities of the native cocoyam starches. In conclusion, phosphorylation considerably improved the functional and pasting qualities of red and white cocoyam starch, revealing its tremendous application potential in the formulation of food components, as a stabilizer, tablet binders in pharmaceutical industries, as well as in the packaging industries.
淀粉工业的当代战略是原料的多样化。然而,淀粉的亲水性限制了其作为食品和包装产品原料的使用,导致生物降解水平较低。为了解决这个问题,必须对淀粉进行化学改性。淀粉磷酸酯是最常见和最常用的化学改性淀粉。本研究以正磷酸二氢钠为磷酸化剂,对天然红豆淀粉(NRCS)和天然白豆淀粉(NWCS)进行化学改性,得到红豆淀粉磷酸(PRCS)和白豆淀粉磷酸(PWCS)。对两种薯蓣原生磷酸盐和淀粉磷酸盐的功能和糊化性能进行了评价和比较。淀粉收率由NRCS的~ 17%提高到PRCS的~ 25%,由NWCS的~ 12%提高到PWCS的~ 20%。NRCS和NWCS分别为97.00和143.00%、78.00和164.00%、PRCS分别为160.00和153.00%和PWCS分别为127.00和173.00%。NRCS和PRCS的泡沫容量分别为8.80和9.00%,NWCS和PWCS的泡沫容量分别为8.00和10.00%。磷酸化对糊化特性有显著影响,导致天然椰淀粉的峰值、分解、回退和最终粘度降低。综上所述,磷酸化可显著改善红薯淀粉和白薯淀粉的功能和糊化品质,显示出其在食品成分配方、稳定剂、制药行业片剂粘结剂以及包装行业的巨大应用潜力。
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Scientia Africana
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