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The Utilization of Magnetized Water for the Improvement of Crude Oil Quality 利用磁化水提高原油品质
Pub Date : 2022-09-11 DOI: 10.52716/jprs.v12i3.545
Samer N. Shatub
The crude oil binds from the oil fields to the refinery with water. This water contains dissolved salts, mostly chloride salts (CaCl2, NaCl, MgCl2), which are one of the components of the water emulsion in crude oil leading to the contamination of the crude oil. This pollution has a serious negative impact on the refinery units if left untreated, causing many Problems such as (corrosion, sedimentation, blockage of exchanger tubes and furnaces, and other problems). As a result, it is necessary to treat the crude oil salts and remove the effect of the salts by desalinating the oil at different stages during production at the wells and then in the refinery unit. Desalination is the main equipment used in the process of washing crude oil from salts using ordinary freshwater         This work aims to use magnetized water as a substitute for normal water in the stage of washing crude oil salts by installing a water magnetization device with strength of (4500) gauss, at the site of the washing water injection line before the mixing valve at the desalination remover. The results showed that the magnetized water increased the efficiency and energy of the water used, reduced the deposition of salts and corrosion in the tubes of the distillation unit, as well as helped to crack the salt ions and transform its molecules into smaller particles and reduce their concentration in the crude oil.
原油随水从油田流入炼油厂。这些水中含有溶解的盐,主要是氯化物盐(CaCl2, NaCl, MgCl2),它们是原油中水乳状液的组成成分之一,导致原油被污染。这种污染如果不加以处理,会对炼油厂装置产生严重的负面影响,造成许多问题,如(腐蚀、沉积、交换管和炉堵塞等问题)。因此,有必要在油井和炼油装置的生产过程中,分阶段对原油进行脱盐处理,以消除原油盐的影响。海水淡化是普通淡水洗涤原油脱盐过程中使用的主要设备,本工作的目的是在脱盐机混合阀前的洗涤注水管线处安装(4500)高斯强度的水磁化装置,以磁化水代替普通水进行原油脱盐阶段的洗涤。结果表明,磁化水提高了水的使用效率和能量,减少了盐在蒸馏装置管内的沉积和腐蚀,有助于盐离子的裂解,使其分子转化为更小的颗粒,降低了其在原油中的浓度。
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引用次数: 1
Comparison between Conventional and Metakaolin bi-functional Catalyst in the Hydrodesulfurization Operation 常规与偏高岭土双功能催化剂加氢脱硫性能的比较
Pub Date : 2022-06-21 DOI: 10.52716/jprs.v12i2.658
Khlood S. AlKhafaji, B. Al-Zaidi, Zaidoon M. Shakor, S. Hussein
The present study investigates hydrodesulfurization (HDS) of gas oil with 9300 ppm (0.93 wt%) sulfur supplied from Al-Dura Refinery by using an economic catalyst prepared from raw mineral (kaolin clay) cemented by alumina as composite support alumina meta-kaolin (AMK). Characterization of the prepared catalyst was achieved by using Energy Dispersive X-Ray Analysis  (EDAX), scanning electron microscopy (SEM), BET surface area, pore volume , Bulk density, X-ray diffraction analysis (XRD) and Fourier-transform infrared spectroscopy (FTIR). AMK was modified as a bifunctional catalyst with active metal (Co and Mo). The hydrodesulfurization (HDS) efficiency was evaluated and compared with the traditional catalyst (CoMo-Al2O3) in a hydrotreating reaction carried out in one stage reactor at temperature 375 oC, pressure 40 bar, LHSV 1hr-1, and H2/HC ratio 200 vol. ratio.  62.2% and 90% of hydrodesulfurization efficiency were achieved for prepared catalyst (CoMo-AMK) and commercial CoMo-Al2O3 respectively at the same operating conditions.
本研究以Al-Dura炼油厂提供的9300 ppm (0.93 wt%)硫为原料,用氧化铝胶结原矿(高岭土)作为复合载体氧化铝间高岭土(AMK)制备经济催化剂,研究了高岭土加氢脱硫(HDS)。利用能量色散x射线分析(EDAX)、扫描电镜(SEM)、BET比表面积、孔隙体积、堆积密度、x射线衍射分析(XRD)和傅里叶变换红外光谱(FTIR)对制备的催化剂进行表征。将AMK改性为具有活性金属(Co和Mo)的双功能催化剂。在温度375℃、压力40 bar、LHSV 1hr-1、H2/HC体积比200的单级反应器中,对CoMo-Al2O3加氢脱硫(HDS)效果进行了评价,并与传统催化剂(CoMo-Al2O3)进行了比较。在相同的操作条件下,CoMo-AMK催化剂加氢脱硫效率为62.2%,CoMo-Al2O3催化剂加氢脱硫效率为90%。
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引用次数: 2
Effectiveness Enhancement of the Double Tube Heat Exchanger Using ZnO Nanofluid ZnO纳米流体增强双管换热器效能
Pub Date : 2022-06-21 DOI: 10.52716/jprs.v12i2.660
H. Kadhim
In this study, the effect of adding zinc oxide nanoparticles to the reversible effect double tube heat exchanger with a length of 1.5 meters, an outer diameter of 19.0 mm, is made of copper material that is used by Nano water as a cold liquid. Zinc solid nanoparticles with a volume concentration of 3% were used with water as the base liquid. The cold nanoscale water flows into the real tube with a volume of 4 L/min which enters into the heat exchanger at 16°C, where the hot water flows into the separator of the heat exchanger representing a blank volume of 6 L/min. The Reynolds number range and flowrate ranges are 10000 to 20000 and 5 to 15 respectively. The heat exchanger was introduced at a temperature of 65°C. An improvement in the performance of the exchanger was shown in the case of using water with the addition of nanoparticles
在本研究中,将氧化锌纳米颗粒添加到长度为1.5米,外径为19.0 mm的可逆效应双管换热器中,该换热器由纳米水作为冷液使用的铜材料制成。采用体积浓度为3%的锌固体纳米颗粒,以水为基液。冷纳米级水以4l /min的体积流入实管,实管在16℃时进入热交换器,其中热水以6l /min的空白体积流入热交换器分离器。雷诺数范围为10000 ~ 20000,流量范围为5 ~ 15。在65℃的温度下引入热交换器。在加入纳米粒子的情况下,交换器的性能得到了改善
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引用次数: 1
Iron Ionic Imprinted Polymers IIps for Separation and Preconcentration of Iron from Crude and Fuel Oil 铁离子印迹聚合物用于原油和燃料油中铁的分离和预富集
Pub Date : 2022-06-21 DOI: 10.52716/jprs.v12i2.656
H. Mohsen, Y. K. Al-bayati, R. Jalil
A novel Iron ion-imprinted polymers (IIPs) was synthesized by bulk polymerization using different types of monomers such as 1-vinyl imidazole and Styrene, respectively. Molar ratios of monomer, template and cross-linking agent for polymerization, various monomers and solvents were studied to obtain the largest adsorption capacity for Iron. The prepared Iron-IIPs were characterized using energy dispersive X-ray spectroscopy (EDX), Fourier - transform infrared spectroscopy (FTIR) and Scanning electron microscopy (SEM).     The three-dimensional network structure surfaces of Iron-IIPs are unaffected by the elution procedure. Iron ions were successfully eluted from IIPs using a mixed solution from ethanol and acetic acid. The maximum adsorption capacity of Iron-IIPs was is (514.5)µmol/g for Iron-IIP1(using styrene as a monomer) and (429.1) µmol/g for Iron-IIP2(using 1-vinyl imidazole as a monomer). The adsorption by Iron-IIPs followed a Langmuir isotherm models. Solid-phase extraction (SPE) syringe packed with ionic imprinted polymers (IIPs) were used to selective separation for Iron ion from Crude or fuel oil and digest the polymer to determination the Iron by flame atomic absorption spectroscopy (FAAS) Abbreviation IIP-SPE-FAAS.
以1-乙烯基咪唑和苯乙烯为单体,采用本体聚合法制备了一种新型铁离子印迹聚合物。研究了单体、模板和交联剂的摩尔比、各种单体和溶剂对铁的最大吸附量。利用能量色散x射线能谱(EDX)、傅里叶红外光谱(FTIR)和扫描电镜(SEM)对制备的铁- iip进行了表征。铁- iip的三维网络结构表面不受洗脱过程的影响。用乙醇和乙酸的混合溶液成功地洗脱了IIPs中的铁离子。铁- iip1(以苯乙烯为单体)和铁- iip2(以1-乙烯基咪唑为单体)的最大吸附量分别为(514.5)µmol/g和(429.1)µmol/g。铁离子的吸附遵循Langmuir等温模型。采用固相萃取(SPE)注射器填充离子印迹聚合物(IIPs),对原油或燃料油中的铁离子进行选择性分离,并对聚合物进行消解,用火焰原子吸收光谱法(FAAS)测定铁的含量。
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引用次数: 0
Adsorption of Some Heavy Elements on Surface of Activated Carbonized Cellulose from Aqueous Solution 水溶液中活性炭纤维素表面对某些重元素的吸附
Pub Date : 2022-06-21 DOI: 10.52716/jprs.v12i2.661
Dr. Ghassan Burhan Yaqoob
      In this study the activated carbonized cellulose in (350 ºC) by citric acid have been used to remove some heavy metals (Hg Cd, Cu, Pb) from its aqueous solution at room temperature. The adsorbed metals data applied on three adsorption isotherm models, Freundlich, Langmuir and Temkin isotherms. The adsorption results were very good fitted with isotherm models by the (R2) meaningful value. The removal metals adsorbed on surface of adsorbent from high to the less remove arranged according to its ability depending on the nature and size of metals. The free energy (ΔG) and constants of the adsorption process (Ɵ, n, kf, kT, b, bT) for copper, lead and cadmium were measured from isotherm curves, infra-red spectrums of the activated carbonized cellulose and cellulose itself were measured by FTIR spectrophotometer.
在室温条件下,用柠檬酸对活性炭纤维素(350℃)水溶液中的重金属(Hg、Cd、Cu、Pb)进行了脱除。吸附金属数据应用于Freundlich、Langmuir和Temkin三种吸附等温线模型。吸附结果与等温线模型拟合良好,R2有意义。吸附在吸附剂表面的金属的去除由高到低,根据金属的性质和大小按其去除能力进行排列。用等温线测定了活性炭对铜、铅和镉的吸附自由能(ΔG)和吸附常数(Ɵ, n, kf, kT, b, bT),用FTIR分光光度计测定了活性炭纤维素和纤维素本身的红外光谱。
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引用次数: 1
Evaluation of Main Pay- Zubair Formation after Operations Re-Injection of Produced Water Directly In Rumaila Oil Field Norths under Matrix Condition 鲁迈拉油田北部主产层祖拜尔地层在基质条件下直接回注采出水后评价
Pub Date : 2022-06-21 DOI: 10.52716/jprs.v12i2.655
A. F. Nader, Rana Muhammad Jassim, W. Saleh, Mahdi S. Abdullah, Ali Qassem Atwan
The water injection program is a key part of Rumaila oilfield long-term development plan to raise pressure levels in reservoirs. This water injection program has involved project of produced water re-injection (PWRI) directly. Although PWRI is most economical method for disposal of produced water and reduces environmental pollution risks but it can causes impairment in formation permeability due to contain it on suspended and dissolved solids that can plug porous media. Therefore, it is essential conduct fluid-rocks compatibility experiments and analysis to evaluation PWRI. The experimental work was carried out in Department of Laboratory and Quality Control in Basra Oil Company, using waterflooding apparatus. The compatibility experiments were applied on five core selected from Main Pay - Zubair formation that has very high permeability with 40 liter produced water at North-Rumaila oilfield. The main purpose of this work is evaluation of PWRI by studying the reduction of permeability(formation damage). The maximum damage degree is 71% and the minimum damage degree is 55% with average value 68.2%. The main causes to impairment permeability are present high concentration from suspended solids in PW.  The damage is start from maximum degree  near wellbore and  gradually decreasing away from injection well and the permeability start jump up. The damage zone is propagate symmetrical around axial wellbore injector and connect together formed roughly circular dish. In this paper we establish table of monitor for help to minimize formation damage.  Based on these results, we can concludes, direct injection of produced water into Zubair formation without surface treatments or  washing of formation or acidizing treatment  or injection under fracture conditions causes formation damage and increases with time.
注水工程是鲁迈拉油田提高油藏压力水平的长期开发计划的重要组成部分。本次注水项目直接涉及到采出水回注项目。虽然PWRI是最经济的采出水处理方法,降低了环境污染风险,但由于PWRI含有悬浮和溶解固体,会堵塞多孔介质,因此会损害地层渗透率。因此,对PWRI进行评价必须进行流-岩相容性实验和分析。实验工作在巴士拉石油公司实验室和质量控制部进行,采用水驱装置。在北鲁迈拉油田采出水40升、渗透率极高的主Pay - Zubair地层中,选取5个岩心进行了配伍试验。本工作的主要目的是通过研究降低渗透率(地层损害)来评价PWRI。最大损伤程度为71%,最小损伤程度为55%,平均值为68.2%。造成渗透率降低的主要原因是油液中悬浮物浓度过高。损害从近井处最大程度开始,远离注入井处逐渐减小,渗透率开始跳升。损伤区在轴向注入器周围对称扩展,并连接在一起形成大致圆形的盘状。为了最大限度地减少地层损害,本文建立了监测表。基于这些结果,我们可以得出结论,在未进行表面处理、未对地层进行洗井、未进行酸化处理或未在压裂条件下进行注水的情况下,直接将采出水注入Zubair地层,会对地层造成损害,并随着时间的推移而增加。
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引用次数: 1
Study The Effect of The Main Variables on The Objectives of The Natural Gas Dehydration Plant by ASPEN-HYSYS v8.8 应用ASPEN-HYSYS v8.8研究主要变量对天然气脱水装置目标的影响
Pub Date : 2022-06-21 DOI: 10.52716/jprs.v12i2.657
Ali Sameer Ismail Al-Jammali
In the NGD process, TEG dehydration is commonly employed to prevent corrosion and blockage of equipment, valves, and piping systems. TEG is frequently lost in the system during this procedure owing to vaporization and carryover. Therefore, it is necessary to study the affection of variables of the dehydration process the process was simulated with ASPEN-HYSYSV8.8 and the thermodynamic model was glycol-package; the process was validated by comparing the Plant results with the simulation results and demonstrating good acceptance. ASPEN-HYSYS conducted a sensitivity study to investigate the impact of variables on the main objectives. , as this study showed that not all of these variables have a strong effect, some of them have a weak effect, for example (wet gas pressure and same case of solvent pressure) and the rest of the variables have a strong effect on this process, so it must be taken into consideration by the station operators where this The changes were targeted because they are subject to change within the plant, and the highest value and the smallest value were taken according to the factory's parameters. As these variables are taken into account and the requisite improvements are made, the natural gas drying process will improve, and the dry gas requirements needed will improve, resulting in increased benefit.
在NGD工艺中,TEG脱水通常用于防止设备、阀门和管道系统的腐蚀和堵塞。在此过程中,由于蒸发和结转,TEG经常在系统中丢失。采用aspin - hysysv8.8软件对脱水过程进行了模拟,热力学模型为乙二醇包合;通过与仿真结果的对比,验证了该工艺的可行性。ASPEN-HYSYS进行了一项敏感性研究,以调查变量对主要目标的影响。,这项研究表明,并非所有的这些变量有很强的效果,其中一些有弱的影响,例如相同(湿气体压力和溶剂压力)和其他变量对这个过程有强烈的影响,因此必须考虑车站运营商这个改变是有针对性的,因为他们是主体改变植物内,最大值和最小值是根据工厂的参数。由于考虑了这些变量并进行了必要的改进,天然气干燥过程将得到改进,所需的干气要求将得到改善,从而提高效益。
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引用次数: 0
تدقيق نظام ادارة الصحة والسلامة المهنية وفق المواصفة (ISO 19011: 2018)/ دراسة حالة في وزارة النفط/ دائرة الدراسات والتخطيط والمتابعة 在石油部/研究、规划和后续处对职业健康和安全管理系统进行了审查(ISO 19011: 2018)/个案研究
Pub Date : 2022-06-21 DOI: 10.52716/jprs.v12i2.663
فائزة صالح بلكت, د. اريج سعيد خليل
يهدف البحث الى تقديم برنامج تدقيق داخلي على متطلبات نظام ادارة الصحة والسلامة المهنية وفق المواصفة الدولية (ISO 45001: 2018) بالاستناد الى ارشادات المواصفة (ISO 19011: 2018) في دائرة الدرسات والتخطيط والمتابعة – وزارة النفط، اذ ينطلق البحث من المشكلة المتمثلة بضعف اجراءات التدقيق الداخلي على نظام ادارة الصحة والسلامة المهنية والذي ادى بدوره الى خلق مجموعة من الثغرات في متطلبات تطبيق نظام ادارة الصحة والسلامة المهنية وفق متطلبات المواصفة (ISO 45001: 2018)، وبقصد الوصول إلى الحقائق العلمية تم اعتماد منهج دراسة الحالة الذي يتضمن الملاحظة المباشرة والزيارات الميدانية والمقابلات الشخصية، كما استعملت قائمة الفحص (Checklist) المعتمدة في البحث والتي تم اعدادها بالاستناد الى متطلبات المواصفة (ISO 45001: 2018)، لذا اظهرت نتائج البحث وجود (3) حالات عدم مطابقة رئيسة و(22) حالة عدم مطابقة ثانوية وتثبيت مجموعة من فرص التحسين التي تساعد الى اكمال كافة جوانب تطبيق نظام ادارة الصحة والسلامة المهنية في دائرة الدراسات والتخطيط والمتابعة.
这项研究的目的是在研究、规划和后续行动处(ISO 45001: 2018年)的规格说明(ISO 1901: 2018年)基础上,向国际标准职业健康和安全管理系统(ISO 45001:为了获取科学事实,采用了案例研究方法,其中包括直接观察、实地访问和个人访谈,并使用了研究中采用的检查清单(ISO 45001: 2018),因此研究结果显示(3)主要的不匹配和(22)次要的不匹配,并确定了一系列改进的机会,以全面研究、规划和后续处职业健康和安全管理系统的应用。
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引用次数: 0
Iraq Crude Oil Exports – January, February and March 2020 伊拉克原油出口- 2020年1月、2月和3月
Pub Date : 2022-06-21 DOI: 10.52716/jprs.v12i2.664
M. O. O. O. M. C. Somo
Table 1. Iraq Crude Oil Exports – January 2020Table 2. Iraq Crude Oil Exports – February 2020Table 3. Iraq Crude Oil Exports – March 2020
表1。伊拉克原油出口- 2020年1月伊拉克原油出口- 2020年2月伊拉克原油出口- 2020年3月
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引用次数: 0
Drag Reduction of AL-Ahdab Crude Oil Using Chemical Additives 化学添加剂对AL-Ahdab原油减阻的影响
Pub Date : 2022-06-21 DOI: 10.52716/jprs.v12i2.659
Talib M. Subkh, H. Hussein
The viscosity of crude oil has a crucial role in drag reduction during pipeline transportation; hence additives are required to enhancing the flow properties of AL-Ahdab crude oil. In this work, the potato starch biopolymer and CTAB surfactant are utilized to achieve the target. The drag reduction experiments were carried out at different crude oil flow rates (20-35-50 liters/min), pipe diameters (0.5-0.75 -1 inch), and different concentrations of potato starch (500-2000 ppm) and CTAB (100-500 ppm). The results showed that these additives had minimized flow resistance in various operating conditions, the drag reduction percent increased with increasing of additives concentration increase. The maximum drag reduction achieved using CTAB and potato starch is 41.6% and 36.3%, respectively, at 50 liters/min and 1-inch pipe diameter.
原油粘度对管道运输减阻起着至关重要的作用;因此,需要添加添加剂来提高AL-Ahdab原油的流动性能。本研究利用马铃薯淀粉生物聚合物和CTAB表面活性剂来实现这一目标。在不同原油流速(20-35-50升/分钟)、管径(0.5-0.75 -1英寸)、马铃薯淀粉(500-2000 ppm)和CTAB (100-500 ppm)浓度下进行减阻实验。结果表明:在不同工况下,添加剂的流动阻力最小,减阻率随添加剂浓度的增加而增加。在50升/分钟、管径为1英寸的情况下,CTAB和马铃薯淀粉的最大减阻效果分别为41.6%和36.3%。
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引用次数: 0
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Journal of Petroleum Research and Studies
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