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Gelation of an Organically Crosslinked PHPA Polymer Gel System: An Experimental Study 有机交联PHPA聚合物凝胶体系凝胶化的实验研究
Pub Date : 2023-01-01 DOI: 10.3329/jsr.v15i1.60039
M. Vaishnav, N. Verma
Excessive water production in the oil field is the major difficulty in production for the petroleum industry. Remedial techniques need to be applied to control this excess water production considering the health, safety, and environmental issues and improve the reservoir's economic and productive life. In this study polymer gel system comprising the polymer partially hydrolyzed polyacrylamide (PHPA) and organic cross-linkers (Hydroquinone and Hexamethylene tetramine) were prepared as a water shut-off system to control the excessive production of water in the oil field. The effect of various parameters such as temperature, pH, cross-linker concentration, degree of hydrolysis, and divalent cations on gelation time was investigated using the bottle testing method. The importance of retarders at high temperatures was also evaluated. The gelation temperature was varied from 90 °C to 120 °C to study the effect of different parameters on the gelation time and gel behavior. This study suggests that Partially Hydrolyzed Polyacrylamide (PHPA) with organic cross-linkers can be an effective polymer gel system for water shut-off operations, and with the addition of retarders at high temperature to control gelation time, the performance of the gel can be improved.
油田含水过多是困扰石油工业生产的一大难题。考虑到健康、安全和环境问题,需要采用补救技术来控制这种过剩的水量,并提高油藏的经济和生产寿命。采用聚合物部分水解聚丙烯酰胺(PHPA)和有机交联剂(对苯二酚和六亚甲基四胺)组成的聚合物凝胶体系作为堵水体系,控制油田的过量产水。采用瓶试法考察了温度、pH、交联剂浓度、水解程度、二价阳离子等参数对凝胶时间的影响。还评价了缓速剂在高温下的重要性。凝胶温度在90 ~ 120℃范围内变化,研究不同参数对凝胶时间和凝胶行为的影响。本研究表明,含有机交联剂的部分水解聚丙烯酰胺(PHPA)可以作为一种有效的堵水聚合物凝胶体系,在高温下加入缓凝剂控制凝胶形成时间,可以提高凝胶的性能。
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引用次数: 0
Effects of Nationwide Lockdown due to COVID-19 on Ambient Air Quality in the State of West Bengal, India 新冠肺炎对印度西孟加拉邦环境空气质量的影响
Pub Date : 2023-01-01 DOI: 10.3329/jsr.v15i1.59249
B. Ghosh, S. Nayek, P. Padhy
The present study assessed the nationwide lockdown impacts on the air pollution situation across West Bengal, India. Air pollution data was collected from the online monitoring stations of the Central Pollution Control Board across West Bengal. The gradual declining pattern of overall pollution status was observed during the lockdown phase from the pre-lockdown phase. The early unlocking stage found slow and gradual increasing air pollution levels. Siliguri’s pre-lockdown ‘poor’ Air Quality Index (AQI) improved in the lockdown phase to ‘satisfactory’ level. ‘Moderate’ level AQI in Asansol of the pre-lockdown stage improved to ‘satisfactory’ level during the lockdown phase. Pre-lockdown AQI of both Kolkata and Howrah changed from ‘moderate’ to ‘good’ level during the lockdown phase. Unlike other pollutants, the ozone level increased in Kolkata, Howrah, and Siliguri in the lockdown phase. The early monsoonal washout possibly caused the changes in the pattern of pollution status of specified periods in the 2019 and 2020. Thus, in the study period of lockdown in 2020, the decrease in pollution level may not only caused by the stoppage of vehicles or industry but also have a possible natural influence.
本研究评估了全国范围内的封锁对印度西孟加拉邦空气污染状况的影响。空气污染数据是从西孟加拉邦中央污染控制委员会的在线监测站收集的。总体污染状况在封城阶段由封城前阶段逐渐下降。在早期解锁阶段,空气污染水平缓慢而逐渐上升。西里古里在封城前的“差”空气质量指数(AQI)在封城阶段改善至“满意”水平。在封锁阶段,Asansol的AQI从封锁前的“中等”水平改善到“满意”水平。在封锁阶段,加尔各答和豪拉的AQI都从“中等”变为“良好”。与其他污染物不同,在封锁阶段,加尔各答、豪拉和西里古里的臭氧水平有所上升。早期的季风冲刷可能导致2019年和2020年特定时期污染状况格局的变化。因此,在2020年的封锁研究期内,污染水平的下降不仅可能是车辆或工业停工造成的,也可能是自然影响。
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引用次数: 2
Copper Doped PPy/MWCNT Nanocomposite Materials for Supercapacitor Applications 超级电容器用掺杂铜的PPy/MWCNT纳米复合材料
Pub Date : 2023-01-01 DOI: 10.3329/jsr.v15i1.59397
M. Priyadarsini, M. Adhikary, P. Jena, R. M. Pujahari
We report the structural, morphological, and electrochemical properties of polypyrrole (PPy), copper doped PPy (Cu/PPy), and copper doped polypyrrole multi-walled carbon nanotubes (Cu/PPy/MWCTs) prepared by oxidative polymerization technique. The incorporation of Cu in the form of nanoparticles in the composites was confirmed from XRD data. The granular morphology of PPy was observed from the FESEM micrograph. However, the size of the grains was decreased with Cu nanoparticle insertion in the matrix. The uniform distribution of Cu nanoparticles in the Cu/PPy and Cu/PPy/MWCTs nanocomposites has been evidenced from TEM images. The highest specific capacitance of 311 F/g at a scan rate of 10 mV/s is achieved in the case of Cu/PPy/MWCTs composite. It is found that the cyclic stability of these nanocomposites is enhanced due to the integration of MWCNTS and Cu nanoparticles with PPy polymer. The Cu/PPy/MWCNTs nanocomposites retained 91% of their specific capacitance even after 1000 cycles. The maximum energy density of 19.89 Wh/kg and maximum power density of 4479.71 W/kg at the scan rate of 200 mV/s were also measured for the Cu/PPy/MWCNTs nanocomposite. Our study thus indicates that the prepared Cu/PPy/MWCTs nanocomposite could be a potential candidate for application in supercapacitor and hybrid type storing devices.
本文报道了用氧化聚合技术制备聚吡咯(PPy)、铜掺杂聚吡咯(Cu/PPy)和铜掺杂聚吡咯多壁碳纳米管(Cu/PPy/MWCTs)的结构、形态和电化学性能。XRD数据证实了Cu以纳米颗粒形式掺入复合材料中。在FESEM显微镜下观察到PPy的颗粒形态。然而,随着Cu纳米颗粒在基体中的插入,晶粒尺寸减小。TEM图像证实Cu纳米粒子在Cu/PPy和Cu/PPy/ mwct纳米复合材料中的均匀分布。在Cu/PPy/ mwct复合材料中,在扫描速率为10 mV/s的情况下实现了最高的311 F/g比电容。结果表明,MWCNTS和Cu纳米颗粒与PPy聚合物的结合提高了复合材料的循环稳定性。Cu/PPy/MWCNTs纳米复合材料在1000次循环后仍保持91%的比电容。在扫描速率为200 mV/s时,Cu/PPy/MWCNTs纳米复合材料的最大能量密度为19.89 Wh/kg,最大功率密度为4479.71 W/kg。因此,我们的研究表明,所制备的Cu/PPy/MWCTs纳米复合材料在超级电容器和混合型存储器件中具有潜在的应用前景。
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引用次数: 0
Dielectric Spectroscopy of Ferroelectric Crossbred PVDF–TiO2 Polymer Composite Thin Films 铁电交联PVDF-TiO2聚合物复合薄膜的介电光谱
Pub Date : 2023-01-01 DOI: 10.3329/jsr.v15i1.60132
A. Arshad, S. Dani, S. S. Kulkarni, U. V. Khadke
Polyvinylidene fluoride (PVDF) ferroelectric polymer blend with titanium dioxide (TiO2) is synthesized in the form of thin films by solution casting method. The synthesized PVDF-TiO2 composite films with a different wt% of TiO2 (2, 4, 6, 8, and 10) as fillers in the PVDF matrix were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and Fourier Transform Infrared (FTIR) spectroscopy. The XRD patterns of PVDF-TiO2 composite films confirmed the existence of a β-phase PVDF, uniform distribution of TiO2 particles in the polymer matrix and the crystallinity of the polymer composites was found to be enhanced. The SEM micrograph depicts the augmentation in the structural density due to the addition of TiO2 particles in the PVDF matrix. The dielectric constant of the PVDF-TiO2films is found to be an anomaly at lower frequencies and decreases with an increase in frequency agreeing with the Maxwell–Wagner type of interfacial polarization. The enhancement in the dielectric constant of PVDF-TiO2 composites at lower frequencies suggests that the prepared polymer composite thin films are useful as separator membranes in energy storage devices.
采用溶液浇铸法制备了聚偏氟乙烯(PVDF)与二氧化钛(TiO2)共混铁电聚合物薄膜。采用x射线衍射(XRD)、扫描电镜(SEM)和傅里叶变换红外光谱(FTIR)对合成的PVDF-TiO2复合膜进行了表征,并在PVDF基体中加入不同wt%的TiO2(2,4,6,8和10)作为填料。PVDF-TiO2复合膜的XRD谱图证实了β相PVDF的存在,聚合物基体中TiO2颗粒分布均匀,聚合物复合材料的结晶度增强。SEM显微图显示了由于在PVDF基体中加入TiO2颗粒而导致的结构密度的增加。pvdf - tio2薄膜的介电常数在较低频率处存在异常,随着频率的增加而减小,符合麦克斯韦-瓦格纳型界面极化。PVDF-TiO2复合材料的介电常数在较低频率下的增强表明所制备的聚合物复合薄膜可作为储能装置的隔膜膜。
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引用次数: 0
Solution of Linear Volterra Integral Equation of Second Kind via Rishi Transform 利用Rishi变换求解第二类线性Volterra积分方程
Pub Date : 2023-01-01 DOI: 10.3329/jsr.v15i1.60337
S. Aggarwal, R. Kumar, J. Chandel
The solution of various problems of engineering and science can easily determined by representing these problems in integral equations. There are numerous analytical and numerical methods which can be used for solving different kinds of integral equations. In this paper, authors used recently developed integral transform “Rishi Transform” for obtaining the analytical solution of linear Volterra integral equation of second kind (LVIESK). For this, the kernel of LVIESK has assumed a convolution type kernel. Five numerical examples are considered for demonstrating the complete procedure of determining the solution. Results of these problems suggest that Rishi transform provides the exact analytical solution of LVIESK without doing complicated calculation work.
用积分方程表示各种工程和科学问题,可以很容易地确定这些问题的解。有许多解析和数值方法可用于求解不同类型的积分方程。本文利用近年来发展起来的积分变换“Rishi变换”,得到了第二类线性Volterra积分方程(LVIESK)的解析解。为此,LVIESK的内核假定为卷积型内核。为了演示确定解的完整过程,考虑了五个数值算例。这些问题的结果表明,Rishi变换无需复杂的计算工作,就能提供LVIESK的精确解析解。
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引用次数: 0
Optimization of M/M/2 Queueing Model with Working Vacations 带工作假期的M/M/2排队模型优化
Pub Date : 2023-01-01 DOI: 10.3329/jsr.v15i1.59348
S. Gupta, P. Joshi, K. Rajeshwari
The paper deals with an M/M/2 Queueing Model with working vacations and reneging of customers due to impatience. The matrix geometric method is used to find the distribution of the number of customers in the system. A cost function is constructed to obtain the optimal value of the service rate to optimize (minimize) the cost function using the Quadratic Fit Search Method (QFSM). Further, the effects on the system's performance measures using numerical analysis and graphical representation are studied.
本文研究了具有工作假期和顾客因不耐烦而违约的M/M/2排队模型。采用矩阵几何方法求出系统中顾客数量的分布。利用二次拟合搜索法(Quadratic Fit Search Method, QFSM)构造了一个成本函数,以获得服务率的最优值,从而优化(最小化)成本函数。进一步,利用数值分析和图形表示研究了对系统性能指标的影响。
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引用次数: 0
Prevalence and Risk Factors Associated with Chronic Diseases Among Young Adult in Bangladesh 孟加拉国青年慢性疾病的患病率和相关风险因素
Pub Date : 2023-01-01 DOI: 10.3329/jsr.v15i1.60328
M. Hasan
One of the major health challenges of the century is the prevalence of chronic diseases in young adults. The aim of the study was to identify the risk factors for chronic disease and the prevalence of chronic disease in individuals aged 18 to 39. The outcome variable was chronic diseases, and potential predictors included sex, age, education, work status, division, region, smoking status, and respondent's income. Of the 5490 young people, 1782 (32.5 %) had at least one chronic illness. Age, work status, division, geography, and smoking status were significant predictors of chronic illnesses in the multivariate model. Compared to younger young adults, those aged 30-39 had greater odds of developing chronic diseases (OR = 1.57, 95 % CI: 1.16–2.13). Residents in socioeconomically disadvantaged areas are more likely to have chronic illnesses than their more affluent counterparts. Young men are more likely than women to experience chronic illness (OR = 1.06, 95 % CI: 0.92-1.21), although this difference wasn't statistically significant. The highly educated group reports chronic disease more frequently than other groups. These findings, particularly those pertaining to decision-makers, can aid in the justification, direction, and support of programs required to address these altering epidemiological trends.
本世纪主要的健康挑战之一是年轻人中慢性病的流行。该研究的目的是确定慢性疾病的危险因素和18至39岁人群中慢性疾病的流行程度。结果变量为慢性疾病,潜在的预测因素包括性别、年龄、教育程度、工作状况、部门、地区、吸烟状况和被调查者的收入。在5490名年轻人中,1782名(32.5%)患有至少一种慢性疾病。在多变量模型中,年龄、工作状态、部门、地理位置和吸烟状况是慢性疾病的显著预测因子。与年轻的年轻人相比,30-39岁的人患慢性疾病的几率更大(OR = 1.57, 95% CI: 1.16-2.13)。社会经济条件较差地区的居民比富裕地区的居民更容易患慢性病。年轻男性比女性更容易患慢性疾病(OR = 1.06, 95% CI: 0.92-1.21),尽管这种差异没有统计学意义。受过高等教育的群体报告慢性疾病的频率高于其他群体。这些发现,特别是那些与决策者有关的发现,可以帮助证明、指导和支持应对这些不断变化的流行病学趋势所需的规划。
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引用次数: 0
Enhanced Anticarcinogenic and Antimicrobial Response of Synthesized Tungsten Oxide Nanoparticles 合成氧化钨纳米颗粒增强的抗癌和抗菌作用
Pub Date : 2023-01-01 DOI: 10.3329/jsr.v15i1.58211
J. Kumari, P. Mangala
In the present study, we fabricated tungsten trioxide nanoparticles (WO3 NPs) from a tungsten complex [W(C13H10NO)3] of ligand N-salicylideneaniline with tungstic acid as the precursor. Nanoparticles were synthesized using the direct thermal decomposition method. These nanoparticles were evaluated for cytotoxicity influence on human breast cancer MCF7 cell line (adenocarcinoma). The observed results suggested that WO3 can destroy 50 % of viable cells after 24 h of incubation at 37 °C. Based on these results, we concluded that WO3 nanoparticles could be a potential drug carrier candidate against human breast cancer cells based on the amount of the drug. In addition, WO3 nanoparticles exhibited significant antimicrobial and antifungal activity.
本研究以钨酸为前驱体,以n -水杨基苯胺为配体的钨配合物[W(C13H10NO)3]为原料制备了三氧化钨纳米颗粒(wo3nps)。采用直接热分解法制备了纳米颗粒。评估了这些纳米颗粒对人乳腺癌MCF7细胞系(腺癌)的细胞毒性影响。结果表明,37℃孵育24 h后,WO3可破坏50%的活细胞。基于这些结果,我们得出结论,基于药物的量,WO3纳米颗粒可能是对抗人类乳腺癌细胞的潜在药物载体。此外,WO3纳米颗粒表现出显著的抗菌和抗真菌活性。
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引用次数: 0
Samarium(III) Triflate as an Efficient and Reusable Catalyst for the Facile Synthesis of 1,2,4,5-Tetrasubstituted Imidazoles 三氟酸钐作为快速合成1,2,4,5-四取代咪唑的高效可重复使用催化剂
Pub Date : 2023-01-01 DOI: 10.3329/jsr.v15i1.60623
A. Gorepatil, P. Gorepatil, M. Gaikwad, A. Ghumare, J. Mali, V. Ingle
An efficient, simple, and green four-component reaction for synthesizing 1,2,4,5-tetrasubstituted imidazoles is developed. In present work exploring the use of Samarium triflate as a heterogeneous catalyst for the four-component reaction of aldehydes, aromatic amines, benzil, and ammonium acetate. The current approach offers many advantages, such as excellent yields, shortening of reaction time, reusability of catalyst, and use of mild reaction conditions.
提出了一种高效、简单、绿色的四组份合成1,2,4,5-四取代咪唑的方法。本研究探讨了三酸钐作为非均相催化剂在醛、芳胺、苯和乙酸铵四组分反应中的应用。该方法具有收率高、反应时间短、催化剂可重复使用、反应条件温和等优点。
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引用次数: 1
Physicochemical Characteristics and Antimicrobial Efficacy of Soaps Prepared Using Carica papaya Extracts 番木瓜提取物制备肥皂的理化特性及抗菌效果研究
Pub Date : 2023-01-01 DOI: 10.3329/jsr.v15i1.60126
S. Pednekar, K. Mangaonkar
Value-added products harnessing the phytotherapeutic potential of papaya are scarce. There is a paucity of data on the efficacy and safety of such products (if available) from papaya. Thus, the current study attempted to exemplify the utilization of papaya extracts in preparing a value-added product, namely, Toilet Soap. This study is the first of its kind in which the physicochemical characteristics and antimicrobial efficacy of the toilet soaps infused with different papaya extracts were assessed and compared against the market available soaps containing papaya fruit extract. The soap samples had pH values between 8.37 – 9.74 and their moisture content between 2.94 – 11.32 %. Their estimated lather volume ranged between 410 – 780 mL with good foaming power and foam stability. The laboratory-prepared soaps (Samples A to D) had matter insoluble slcohol and total fatty matter contents per Bureau of Indian Standards. They either did not contain or had an insignificant amount of free caustic alkali. The quantitative in vitro assessment findings showed antibacterial efficacy against Streptococcus aureus except for Sample E. The in vivo finger imprint test demonstrated the antibacterial efficacy of the soaps against E. coli and S. aureus.
利用木瓜植物治疗潜力的增值产品很少。关于木瓜制品(如果有的话)的有效性和安全性的数据缺乏。因此,本研究试图举例说明利用木瓜提取物制备一种增值产品,即香皂。本研究首次对含有不同木瓜提取物的香皂的理化特性和抗菌效果进行了评估,并与市场上含有木瓜果实提取物的香皂进行了比较。肥皂样品的pH值为8.37 ~ 9.74,水分含量为2.94 ~ 11.32%。他们的估计泡沫体积范围在410 - 780毫升之间,具有良好的发泡能力和泡沫稳定性。根据印度标准局,实验室制备的肥皂(样品A至D)含有不溶性酒精和总脂肪物质含量。它们要么不含,要么含有少量的游离苛性碱。体外定量评价结果显示,除e样品外,皂液对金黄色链球菌均有抑菌作用。体内指纹实验显示皂液对大肠杆菌和金黄色葡萄球菌均有抑菌作用。
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引用次数: 0
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