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Synthesis, Antibacterial, and Antifungal Activities of 3-(4,5-Diphenyl-1H-Imidazol-2-yl)-1H-Indole Derivatives 3-(4,5-二苯基- 1h -咪唑-2-基)- 1h -吲哚衍生物的合成、抗菌及抑菌活性研究
Pub Date : 2023-01-01 DOI: 10.3329/jsr.v15i1.59004
N. Nirwan, C. Pareek, A. Chohadia, K. Verma
Indolylimidazole ring-containing natural and synthesized compounds have shown vast biological activities. These indolylimidazole compounds contain both indole and imidazole rings. The indolylimidazole structure resembling compounds 1a-1d and 2a-2d were synthesized by a green and efficient one-pot four components condensation of indole-3-carbaldehyde, benzil, ammonium-acetate, and substituted amines under microwave irradiation using Amberlyst A-15 as a recyclable catalyst. The structures of synthesized compounds were characterized by FTIR, 1H NMR, and Mass spectrometric studies. These compounds' antibacterial and antifungal activities were screened and compared with the standard drug. The compound 1c was found to be the most active derivative in these compounds, with a minimum inhibitory concentration in the range of 09.9 to 12.5 μg/mL. Compound 1d also showed potent activity against Candida albicans. The sensitivity order of compounds was found 1a<1b<1c>1d against Staphylococcus aureus, Staphylococcus epidermidis, and Escherichia coli and 1a<1b<1c<1d for C. albicans. Compound 2a showed good antimicrobial activity against E. coli and C. albicans.
含吲哚咪唑环的天然和合成化合物已显示出广泛的生物活性。这些吲哚咪唑化合物含有吲哚环和咪唑环。以Amberlyst a- 15为可回收催化剂,在微波照射下,以吲哚-3-甲醛、苯、乙酸铵和取代胺为原料,采用绿色高效的一锅四组分缩合法合成了结构类似于化合物1a-1d和2a-2d的吲哚-咪唑。合成的化合物通过FTIR、1H NMR和质谱进行了结构表征。筛选了这些化合物的抗菌和抗真菌活性,并与标准药物进行了比较。化合物1c是这些化合物中活性最强的衍生物,其最低抑制浓度在09.9 ~ 12.5 μg/mL范围内。化合物1d对白色念珠菌也有较强的抑制作用。化合物对金黄色葡萄球菌、表皮葡萄球菌、大肠杆菌的敏感性依次为1a<1b<1c<1d;对白色念珠菌的敏感性依次为1a<1b<1c<1d。化合物2a对大肠杆菌和白色念珠菌具有良好的抑菌活性。
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引用次数: 0
Transforming Conventional Switching Systems to Cost-Effective, Adaptable, Energy-Efficient Smart Switching Systems 将传统交换系统转变为具有成本效益、适应性强、节能的智能交换系统
Pub Date : 2023-01-01 DOI: 10.3329/jsr.v15i1.60070
Ritu Mishra, T. Gupta, A. Patel, R. Kumar, I. Kaur, V. Batra
Reducing energy consumption in the household and commercial sectors is a major global concern. Our objective is to develop a low-cost automation solution that will help improve adoption and reduce energy consumption. Proposed system has functionality that will help typical Indian households reduce electricity consumption in areas of infrequent usage such as stairs, and parking areas where manual switching of the electricity is difficult. In our proposed model, a manual switching system is replaced with a low-cost and adaptable smart automated switching system. Our design is based on the Passive/Pyroelectric Infrared Rays (PIR) motion-sensing mechanism where motion is used as a trigger to turn on/off electrical appliances. Detailed comparative analysis of daily energy usage of traditional switching with intelligent switching showed reduced electricity consumption by 33 %. Lower cost of equipment will increase the adoption of automated systems, leading to a reduction in electricity consumption. Further, a drop in energy consumption means reduced energy costs and less burden on the grid which leads to a clean environment.
减少家庭和商业部门的能源消耗是全球关注的一个主要问题。我们的目标是开发一种低成本的自动化解决方案,以帮助提高采用率并降低能耗。拟议中的系统具有功能,将帮助典型的印度家庭减少不经常使用的区域的电力消耗,例如楼梯和停车区域,这些区域的手动切换电力很困难。在我们提出的模型中,人工交换系统被低成本、适应性强的智能自动交换系统所取代。我们的设计基于被动/热释电红外线(PIR)运动感应机制,其中运动被用作打开/关闭电器的触发器。对传统开关与智能开关的日常能源使用情况进行了详细的对比分析,结果显示,智能开关的用电量减少了33%。较低的设备成本将增加自动化系统的采用,从而减少电力消耗。此外,能源消耗的下降意味着能源成本的降低和电网负担的减轻,从而带来一个清洁的环境。
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引用次数: 0
Electrochemical Activity of Pure and Sn-Doped CeO2 Nanoparticles using Simple Chemical Precipitation Method 用简单化学沉淀法研究纯和掺锡CeO2纳米颗粒的电化学活性
Pub Date : 2023-01-01 DOI: 10.3329/jsr.v15i1.56206
K. Anandalakshmi, P. Venkatachalam, J. Venugobal
In the present work, pure and Sn-doped CeO2 nanoparticles (NPs) were synthesized by the chemical precipitation method calcined at 400 ºC for 4 h. Characterization of NPs was done through X-ray diffraction (XRD), UV-visible, photoluminescence (PL), Fourier transform infrared (FTIR) spectroscopy and high-resolution electron microscope (HRTEM) techniques. The XRD study revealed the crystalline nature, size, and structure of the prepared NPs. The HRTEM results illustrated cubic structure. The UV–visible and PL studies were used to measure the optical behaviors of CeO2 NPs. The UV-visible showed that the bandgap value of CeO2 NPs increased from 3.61 to 3.65 eV for different doping concentrations. The XRD study exhibited that the size of the CeO2 NPs reduced from 11.03 to 7.91 nm. From the TEM analysis, the average size of undoped and 10% Sn-doped CeO2 NPs was calculated as 9.3 and 7 nm, respectively. A cyclic voltammetric study confirmed that Sn-doped CeO2 exhibited a higher specific capacitance value than the pure CeO2. The chemical precipitation method observed excellent redox and oxidation behavior were observed for Sn-CeO2 NPs by the cyclic voltammetric study. The significant enhancement in the specific capacitance suggested that Sn-doped CeO2 is a promising material for supercapacitor applications.
本文采用化学沉淀法在400℃下煅烧4 h,合成了纯锡掺杂的CeO2纳米颗粒(NPs)。通过x射线衍射(XRD)、紫外可见、光致发光(PL)、傅里叶变换红外(FTIR)光谱和高分辨率电子显微镜(HRTEM)技术对NPs进行了表征。XRD研究揭示了所制备的纳米粒子的晶体性质、尺寸和结构。HRTEM结果显示为立方结构。利用紫外可见光谱和PL光谱研究了CeO2纳米粒子的光学行为。紫外可见光谱表明,不同掺杂浓度下CeO2 NPs的带隙值从3.61 eV增加到3.65 eV。XRD研究表明,CeO2纳米粒子的尺寸从11.03 nm减小到7.91 nm。TEM分析显示,未掺杂和10% sn掺杂的CeO2 NPs的平均尺寸分别为9.3 nm和7 nm。循环伏安研究证实,掺杂sn的CeO2比纯CeO2具有更高的比电容值。化学沉淀法观察到Sn-CeO2 NPs具有良好的氧化还原和氧化行为。比电容的显著增强表明,锡掺杂CeO2是一种很有前途的超级电容器材料。
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引用次数: 0
Impact of Zn-doped Manganese Oxide Nanoparticles on Structural and Optical Properties 掺杂锌的氧化锰纳米颗粒对结构和光学性质的影响
Pub Date : 2022-09-01 DOI: 10.3329/jsr.v14i3.58542
V. Yadav, R. Shukla, K. Sharma
In the present work, the structural and optical properties of pure and zinc-doped manganese oxide nanoparticles prepared by the sol-gel method have been studied for doping concentrations of 5, 10, and 15 %. The XRD patterns reveal that the cubic phase of pure manganese oxide nanoparticles is changed to tetragonal on doping with Zn. The surface morphology of pure and Zn doped manganese oxide nanoparticles has been studied by Scanning Electron Microscopy (SEM), which reveals appreciable changes in size and shape of the nanoparticles as the doping level of Zn is increased. The optical properties studied by UV-Visible spectroscopy further reveal that the energy band gap increases with a decrease in the size of nanoparticles.
在本工作中,研究了溶胶-凝胶法制备的纯和掺杂锌的氧化锰纳米颗粒在掺杂浓度为5%、10%和15%时的结构和光学性质。XRD谱图表明,掺杂Zn后,纯氧化锰纳米颗粒的立方相变为四方相。利用扫描电子显微镜(SEM)研究了纯氧化锰纳米粒子和掺杂Zn的氧化锰纳米粒子的表面形貌,发现随着Zn掺杂水平的增加,纳米粒子的尺寸和形状发生了明显的变化。紫外可见光谱的光学性质进一步表明,能带隙随着纳米颗粒尺寸的减小而增大。
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引用次数: 2
Quantum Dialogue Protocols: A Review 量子对话协议:综述
Pub Date : 2022-09-01 DOI: 10.3329/jsr.v14i3.53280
S. Chauhan, G. Ahmed, N. Gupta
In recent years, quantum cryptography (QC) has received much attention in academic and commercial fields. It has proved to be a promising technology for ensuring the security of future data transmission. In this paper, we review the development of a remarkable area of quantum cryptography, i.e., Quantum dialogue (QD), which is currently in the theoretical stage but is of great interest to academics. We will discuss the quantum dialogue protocols in two categories, single photon-based protocols, and entanglement-based protocols, depending on the quantum resource employed. Finally, experimental implementation, comparison and analysis, security and practical feasibility, and future work for the above-mentioned branch will also be discussed.
近年来,量子密码学受到了学术界和商业界的广泛关注。它已被证明是一种很有前途的技术,可以确保未来数据传输的安全性。在本文中,我们回顾了量子密码学中一个引人注目的领域,即量子对话(QD),它目前处于理论阶段,但引起了学术界的极大兴趣。我们将根据所使用的量子资源,将量子对话协议分为两类,基于单光子的协议和基于纠缠的协议。最后,对实验实现、对比分析、安全性和现实可行性进行了探讨,并对该分支机构今后的工作进行了展望。
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引用次数: 0
Unbiased Modified Two-Parameter Estimator for the Linear Regression Model 线性回归模型的无偏修正双参数估计
Pub Date : 2022-09-01 DOI: 10.3329/jsr.v14i3.58234
A. O. Abidoye, I. M. Ajayi, F. L. Adewale, J. O. Ogunjobi
This study centers on estimating parameters in a linear regression model in the presence of multicollinearity. Multicollinearity poses a threat to the efficiency of the Ordinary Least Squares (OLS) estimator. Some alternative estimators have been developed as remedial measures to the earlier mentioned problem. This study introduces a new unbiased modified two-parameter estimator based on prior information. Its properties are also considered; the new estimator was compared with other estimators’ Mean Square Error (MSE). A numerical example and Monte Carlo simulation were used to illustrate the performance of the new estimator.
本文主要研究多重共线性下线性回归模型的参数估计问题。多重共线性对普通最小二乘(OLS)估计的有效性造成了威胁。已经开发了一些替代估算器,作为对前面提到的问题的补救措施。提出了一种新的基于先验信息的无偏修正双参数估计器。它的性质也被考虑;将新估计量与其他估计量的均方误差(MSE)进行比较。通过数值算例和蒙特卡罗仿真验证了该估计器的性能。
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引用次数: 0
Ranking Fuzzy Numbers with Mean Value of Points and Comparative Reviews 模糊数均值排序与比较评价
Pub Date : 2022-09-01 DOI: 10.3329/jsr.v14i3.58133
S. Prasad, A. Sinha
Even though various ranking fuzzy numbers approaches have been presented so far, none of them can always provide satisfactory results in every situation. Some are counterintuitive, and some are inconsistent for the same circumstances. To overcome the issues mentioned above, we present a new technique for ranking fuzzy numbers using the mean value of the two points. The points are taken on the left and the right membership functions (reference functions) such that they divide the respective membership function in the same ratio . The proposed technique determines the order of the fuzzy numbers significantly. To use this technique, the membership functions need not be normal and linear.
尽管目前已经提出了各种模糊数排序方法,但没有一种方法能够在所有情况下都提供满意的结果。有些是违反直觉的,有些在同样的情况下是不一致的。为了克服上述问题,我们提出了一种利用两个点的平均值对模糊数进行排序的新技术。在左边和右边的隶属函数(参考函数)上取点,使它们以相同的比例除以各自的隶属函数。该方法能有效地决定模糊数的排序。要使用这种技术,隶属函数不必是正规和线性的。
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引用次数: 0
Does the Solution to the Non-linear Diophantine Equation 3x+35y=Z2 Exist? 非线性丢番图方程3x+35y=Z2的解存在吗?
Pub Date : 2022-09-01 DOI: 10.3329/jsr.v14i3.58535
D. Biswas
This paper investigates the solutions (if any) of the Diophantine equation 3x + 35y = Z2, where  , x, y, and z are whole numbers. Diophantine equations are drawing the attention of researchers in diversified fields over the years. These are equations that have more unknowns than a number of equations. Diophantine equations are found in cryptography, chemistry, trigonometry, astronomy, and abstract algebra. The absence of any generalized method by which each Diophantine equation can be solved is a challenge for researchers. In the present communication, it is found with the help of congruence theory and Catalan’s conjecture that the Diophantine equation 3x + 35y = Z2 has only two solutions of  (x, y, z) as  (1, 0, 2) and (0, 1, 6) in non-negative integers.
本文研究Diophantine方程3x + 35y = Z2的解(如果有),其中,x, y, z为整数。丢番图方程近年来引起了各领域研究者的广泛关注。这些方程比其他方程有更多的未知数。丢芬图方程存在于密码学、化学、三角学、天文学和抽象代数中。对于研究人员来说,没有一种可以求解丢番图方程的通用方法是一个挑战。本文利用同余理论和Catalan猜想,得到了丢芬图方程3x + 35y = Z2在非负整数中只有两个解(x, y, z)分别为(1,0,2)和(0,1,6)。
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引用次数: 0
A Unified Approach to the Sandor-Smarandache Function Sandor-Smarandache函数的统一方法
Pub Date : 2022-09-01 DOI: 10.3329/jsr.v14i3.56205
S. Islam, A. K. Z. Ahmed, H. Gunarto, A. Majumdar
The Sandor-Smarandache function, SS(n), is a recently introduced Smarandache-type arithmetic function, which involves binomial coefficients. It is known that SS(n) does not possess many of the common properties of the classical arithmetic functions of the theory of numbers. Sandor gave the expression of SS(n) when n ( ³ 3) is an odd integer. It is found that SS(n) has a simple form when n is even and not divisible by 3. In the previous papers, some closed-form expressions of SS(n) have been derived for some particular cases of n. This paper continues to find more forms of SS(n), starting from the function SS(24m). Particular attention is given to finding necessary and sufficient conditions such that SS(n) = n–5 and SS(n) = n–6. Based on the properties of SS(n), some interesting Diophantine equations have been studied. The study reveals that the form of SS(n) depends on the prime factors of the integer n in the natural order of the primes.
Sandor-Smarandache函数SS(n)是最近引入的涉及二项式系数的smarandache型算术函数。众所周知,SS(n)不具备数论中经典算术函数的许多共同性质。Sandor给出了当n(³3)为奇数时SS(n)的表达式。发现当n为偶数且不能被3整除时,SS(n)有一个简单的形式。在前面的文章中,对于n的一些特殊情况,已经推导出了SS(n)的一些闭式表达式。本文从函数SS(24m)开始,继续寻找SS(n)的更多形式。特别注意找到SS(n) = n - 5和SS(n) = n - 6的充分必要条件。基于SS(n)的性质,研究了一些有趣的丢番图方程。研究表明,SS(n)的形式取决于整数n的素数因子的自然阶数。
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引用次数: 0
Laminar Forced Convection MHD Couette-Poiseuille Flow with Viscous and Joule Dissipations 具有粘性和焦耳耗散的层流强迫对流MHD库埃-泊泽维尔流
Pub Date : 2022-09-01 DOI: 10.3329/jsr.v14i3.58945
B. C. Sarkar
The laminar forced convection MHD Couette-Poiseuille flow of a viscous incompressible fluid with the viscous and Joule dissipations has been studied.  Two different orientations of the wall thermal boundary-conditions have been considered, namely: the constant heat-flux at the upper moving plate with the adiabatic stationary lower plate and the constant heat flux at the stationary lower plate with an adiabatic moving upper plate. The governing equations are solved analytically. It is observed that the fluid velocity increases near the stationary plate and it decreases near the moving plate with an increase in magnetic parameter. The temperature field is significantly affected by the modified Brinkman number. The fluid temperature increases when the lower plate is adiabatic and the upper plate is at positive constant heat flux while it decreases in case the lower plate is at negative constant heat flux and the upper plate is adiabatic with an increase in modified Brinkman number for the combined effects of viscous and Joule dissipations. Further, the fluid temperature decreases for positive heat flux case while it increases for negative heat flux case with an increase in either magnetic parameter or velocity parameter when the combined effects of viscous and Joule dissipations are taken into account.
研究了具有粘性耗散和焦耳耗散的粘性不可压缩流体的层流强迫对流MHD库埃-泊泽维尔流动。考虑了两种不同方向的壁面热边界条件,即:上运动板与绝热静止下板的热流密度恒定和静止下板与绝热运动上板的热流密度恒定。对控制方程进行了解析求解。随着磁参数的增大,流体速度在静极板附近增大,在动极板附近减小。修正后的布林克曼数对温度场有显著影响。下板为绝热、上板为正等热流密度时,流体温度升高,下板为负等热流密度、上板为绝热时,由于粘滞耗散和焦耳耗散的共同作用,修正Brinkman数增加,流体温度降低。此外,考虑粘性耗散和焦耳耗散的综合影响,正热流密度情况下流体温度降低,而负热流密度情况下流体温度随磁参数或速度参数的增加而升高。
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引用次数: 2
期刊
JOURNAL OF SCIENTIFIC RESEARCH
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