B. Samantaray, M. K. Praharaj, B. R. Das, S. P. Das
Ultrasonic velocity measurements, density measurements, and viscometric studies were conducted for the ternary mixture of pyridine and toluene separately with N, N-dimethylformamide (DMF) in butanol, at different temperatures and for different concentrations of component liquids. Using these basic experimental data, various acoustic and thermodynamic parameters, such as adiabatic compressibility (β), free length (Lf,), free volume (Vf), etc. were calculated. Also, Excess thermo-acoustical parameters were calculated from the experimentally measured data. The outcomes were expressed in terms of the molecular interactions and the variations in parameters under varying solute concentrations. A comparative study is discussed. Variation in the above parameters for the different mixtures is indicative of the nature of the interactions between the components in the liquid mixture. Concluding remarks regarding intermolecular interactions are provided.
{"title":"Comparative Study of Molecular Interaction in Ternary Liquid Mixtures of Polar and Non-Polar Solvents","authors":"B. Samantaray, M. K. Praharaj, B. R. Das, S. P. Das","doi":"10.3329/jsr.v14i3.57587","DOIUrl":"https://doi.org/10.3329/jsr.v14i3.57587","url":null,"abstract":"Ultrasonic velocity measurements, density measurements, and viscometric studies were conducted for the ternary mixture of pyridine and toluene separately with N, N-dimethylformamide (DMF) in butanol, at different temperatures and for different concentrations of component liquids. Using these basic experimental data, various acoustic and thermodynamic parameters, such as adiabatic compressibility (β), free length (Lf,), free volume (Vf), etc. were calculated. Also, Excess thermo-acoustical parameters were calculated from the experimentally measured data. The outcomes were expressed in terms of the molecular interactions and the variations in parameters under varying solute concentrations. A comparative study is discussed. Variation in the above parameters for the different mixtures is indicative of the nature of the interactions between the components in the liquid mixture. Concluding remarks regarding intermolecular interactions are provided.","PeriodicalId":16984,"journal":{"name":"JOURNAL OF SCIENTIFIC RESEARCH","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74619415","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The primary goal of this study was to determine the risk due to radon concentration in drinking water. Water is essential for most of the life on the Earth, and the quality of drinking water is a key criterion for one's health. Radon (222Rn) and radium (226Ra) are the radioactive elements that can be found in water. Thirty samples of drinking water were collected in Haliyal, Joida, and Mundgod taluks of Uttara Kannada district. Emanometry technique was used to determine the concentration of 222Rn activity. The activity concentration of 222Rn in water varies between 3.78 ± 0.38 Bq l-1. and 135.96 ± 1.72 Bq l-1 with a mean value of 26.23 ± 0.65 Bq l-1. The cumulative average annual effective doses for all of the samples under investigation are well below the safe limit of 100 µSv y-1 suggested by WHO.
{"title":"Study on Estimation of Inhalation and Ingestion Dose due to 222Rn Concentration in Different Types of Ground Water of Some Taluks of Uttara Kannada District, Karnataka, India","authors":"S. Suresh, E. Srinivasa","doi":"10.3329/jsr.v14i3.57163","DOIUrl":"https://doi.org/10.3329/jsr.v14i3.57163","url":null,"abstract":"The primary goal of this study was to determine the risk due to radon concentration in drinking water. Water is essential for most of the life on the Earth, and the quality of drinking water is a key criterion for one's health. Radon (222Rn) and radium (226Ra) are the radioactive elements that can be found in water. Thirty samples of drinking water were collected in Haliyal, Joida, and Mundgod taluks of Uttara Kannada district. Emanometry technique was used to determine the concentration of 222Rn activity. The activity concentration of 222Rn in water varies between 3.78 ± 0.38 Bq l-1. and 135.96 ± 1.72 Bq l-1 with a mean value of 26.23 ± 0.65 Bq l-1. The cumulative average annual effective doses for all of the samples under investigation are well below the safe limit of 100 µSv y-1 suggested by WHO.","PeriodicalId":16984,"journal":{"name":"JOURNAL OF SCIENTIFIC RESEARCH","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88403607","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Coating technology is widely recognized as the most cost-effective and efficient method of preventing metal corrosion. Polymers have been regarded as a powerful coating material owing to their excellent barrier qualities, simplicity of modification, and large-scale production. Nanomaterials differ significantly from their physical and chemical properties, and have been hailed as highly promising functional materials in a wide range of applications, affecting nearly every aspect of science and technology. The addition of organic or inorganic nanofiller particles to polymer nanocomposite coatings may improve corrosion protection and lower the possibility of blistering or delamination. High hardness for polymer coatings, on the other hand, could be achieved by forming hard nanocrystalline phases inside the matrix. This article provides an overview of recent developments in polymer nanocomposite coatings in terms of their history, coating methods, properties, features, and drawbacks.
{"title":"Polymer-Based Nanocomposite Coating Methods: A Review","authors":"S. Mathai, P. S. Shaji","doi":"10.3329/jsr.v14i3.58338","DOIUrl":"https://doi.org/10.3329/jsr.v14i3.58338","url":null,"abstract":"Coating technology is widely recognized as the most cost-effective and efficient method of preventing metal corrosion. Polymers have been regarded as a powerful coating material owing to their excellent barrier qualities, simplicity of modification, and large-scale production. Nanomaterials differ significantly from their physical and chemical properties, and have been hailed as highly promising functional materials in a wide range of applications, affecting nearly every aspect of science and technology. The addition of organic or inorganic nanofiller particles to polymer nanocomposite coatings may improve corrosion protection and lower the possibility of blistering or delamination. High hardness for polymer coatings, on the other hand, could be achieved by forming hard nanocrystalline phases inside the matrix. This article provides an overview of recent developments in polymer nanocomposite coatings in terms of their history, coating methods, properties, features, and drawbacks.","PeriodicalId":16984,"journal":{"name":"JOURNAL OF SCIENTIFIC RESEARCH","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90807910","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The synthesis of random copolyesters involves polycondensation of arylidene diol with curcumin and glutaryl chloride in 1:1:2 ratio. For this monomers, 2,6-bis-(4-hydroxy benzylidene) cyclohexanone, 2,6-bis-(4-hydroxy-3-methoxybenzylidene)cyclohexanone, 2,5-bis-(4-hydroxybenzylidene)cyclopentanone and 2,5-bis-(4-hydroxy-3-methoxy benzylidene)cyclopentanone were synthesized using acid catalyzed Claisen-Schmidt reaction. Qualitative solubility tests reveal that prepared copolyesters dissolve well in polar solvents. The successful formation of copolyesters was confirmed by Fourier transform-infrared spectroscopy and proton nuclear magnetic resonance spectroscopic techniques. Glass transition temperature of prepared polymers was calculated using differential scanning calorimetric analysis. Further, the prepared copolyesters were utilized as in vitro anticancer agents against breast cancer MCF7 cells. The experimental results of phototcrosslinking property of the copolyesters was compared with that of computational method by DFT calculations which shows coincidence of both.
{"title":"Photocrosslinking Property of Certain Synthesized Bis(arylidene)cycloalkanone based Random Copolyesters with Computational Support and their Anticancer Study","authors":"B. Kiruba, S. Chidambaravinayagam","doi":"10.3329/jsr.v14i3.57161","DOIUrl":"https://doi.org/10.3329/jsr.v14i3.57161","url":null,"abstract":"The synthesis of random copolyesters involves polycondensation of arylidene diol with curcumin and glutaryl chloride in 1:1:2 ratio. For this monomers, 2,6-bis-(4-hydroxy benzylidene) cyclohexanone, 2,6-bis-(4-hydroxy-3-methoxybenzylidene)cyclohexanone, 2,5-bis-(4-hydroxybenzylidene)cyclopentanone and 2,5-bis-(4-hydroxy-3-methoxy benzylidene)cyclopentanone were synthesized using acid catalyzed Claisen-Schmidt reaction. Qualitative solubility tests reveal that prepared copolyesters dissolve well in polar solvents. The successful formation of copolyesters was confirmed by Fourier transform-infrared spectroscopy and proton nuclear magnetic resonance spectroscopic techniques. Glass transition temperature of prepared polymers was calculated using differential scanning calorimetric analysis. Further, the prepared copolyesters were utilized as in vitro anticancer agents against breast cancer MCF7 cells. The experimental results of phototcrosslinking property of the copolyesters was compared with that of computational method by DFT calculations which shows coincidence of both.","PeriodicalId":16984,"journal":{"name":"JOURNAL OF SCIENTIFIC RESEARCH","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81272905","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this paper, respiratory irregularities of humans are investigated, and a self Adaptive Fuzzy Logic-based Proportional plus Derivative Controller (AFLPDC) is designed to provide a controlled supply of oxygen to the patient, suffering from breathlessness. The Fuzzy Logic-based Proportional plus Derivative Controller (FLPDC) is tuned, by implementing an adaptive scheme, which provides desired control action according to the process parameter variations. The electrical equivalent model of the respiratory system is developed, and the model is validated with the help of a Spirometer and MATLAB System Identification Toolbox. To build up this model, the respiratory tract is well thought out into four sections: the nasal cavity, trachea, bronchi, and finally, the alveolar sacs. Each of these sections is represented as a series of combinations of Resistance, Inductance, and Compliance. The control capability of the proposed AFLPDC is investigated on the derived respiratory model. The supply of the desired level of supplemental oxygen by AFLPDC to the patients suffering from the diseases like Bronchitis and Emphysema during respiratory dysfunction is observed in the MATLAB SIMULINK environment without human intervention. The response revealed by AFLPDC is compared with the responses of the conventional PD controller and the Fuzzy Logic-based PD controller (FLPDC).
{"title":"Self Adaptive Fuzzy Controller for Supplementary Oxygen Supply to the Respiratory Distress Patients","authors":"I. Naskar, A. K. Pal","doi":"10.3329/jsr.v14i3.58391","DOIUrl":"https://doi.org/10.3329/jsr.v14i3.58391","url":null,"abstract":"In this paper, respiratory irregularities of humans are investigated, and a self Adaptive Fuzzy Logic-based Proportional plus Derivative Controller (AFLPDC) is designed to provide a controlled supply of oxygen to the patient, suffering from breathlessness. The Fuzzy Logic-based Proportional plus Derivative Controller (FLPDC) is tuned, by implementing an adaptive scheme, which provides desired control action according to the process parameter variations. The electrical equivalent model of the respiratory system is developed, and the model is validated with the help of a Spirometer and MATLAB System Identification Toolbox. To build up this model, the respiratory tract is well thought out into four sections: the nasal cavity, trachea, bronchi, and finally, the alveolar sacs. Each of these sections is represented as a series of combinations of Resistance, Inductance, and Compliance. The control capability of the proposed AFLPDC is investigated on the derived respiratory model. The supply of the desired level of supplemental oxygen by AFLPDC to the patients suffering from the diseases like Bronchitis and Emphysema during respiratory dysfunction is observed in the MATLAB SIMULINK environment without human intervention. The response revealed by AFLPDC is compared with the responses of the conventional PD controller and the Fuzzy Logic-based PD controller (FLPDC).","PeriodicalId":16984,"journal":{"name":"JOURNAL OF SCIENTIFIC RESEARCH","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75327238","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
K. P. Krishna, P. B. Sandhyasri, K. Anitha, G. R. Babu, K. R. Kumar, R. Raju
The intermolecular hydrogen bond interactions in the dimethyl malonate with some branched alkanols (2-methyl-1-propanol, 2-propanol, and 2-butanol) binary mixture have been studied experimentally and theoretically. The ultrasonic velocities U, densities ρ of binary mixtures of dimethyl malonate with 2-methyl-1-propanol, 2-propanol, 2-butanol from 303.15 K to 318.15 K were measured. Excess molar volume (VE), deviation in adiabatic compressibility (Δβad) and excess intermolecular free length ( LEf) have been calculated from the measured experimental data. It is observed that the order of interactions in dimethyl malonate – branched alkanols mixtures is 2-methyl-1-propanol > 2-propanol > 2-butanol.
{"title":"Excess Thermodynamic Properties of Binary Mixtures of Dimethyl Malonate with some Branched Alkanols","authors":"K. P. Krishna, P. B. Sandhyasri, K. Anitha, G. R. Babu, K. R. Kumar, R. Raju","doi":"10.3329/jsr.v14i3.57976","DOIUrl":"https://doi.org/10.3329/jsr.v14i3.57976","url":null,"abstract":"The intermolecular hydrogen bond interactions in the dimethyl malonate with some branched alkanols (2-methyl-1-propanol, 2-propanol, and 2-butanol) binary mixture have been studied experimentally and theoretically. The ultrasonic velocities U, densities ρ of binary mixtures of dimethyl malonate with 2-methyl-1-propanol, 2-propanol, 2-butanol from 303.15 K to 318.15 K were measured. Excess molar volume (VE), deviation in adiabatic compressibility (Δβad) and excess intermolecular free length ( LEf) have been calculated from the measured experimental data. It is observed that the order of interactions in dimethyl malonate – branched alkanols mixtures is 2-methyl-1-propanol > 2-propanol > 2-butanol.","PeriodicalId":16984,"journal":{"name":"JOURNAL OF SCIENTIFIC RESEARCH","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84037940","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The nonlinear fractional differential equation (FDE) is discussed in this study. First, we will investigate the existence and uniqueness solution of the nonlinear differential equation to the Atangana-Baleanu fractional derivative in the sense of Caputo with the initial periodic condition and integral boundary condition by Krasnoselskii’s and Banach fixed point theorems. Then, we will study the Hyers-Ulam stability of our problem. Finally, we presented an example to demonstrate the use of our main theorems.
{"title":"Existence Solutions of ABC-Fractional Differential Equations with Periodic and Integral Boundary Conditions","authors":"M. Muhammad, A. Rafeeq","doi":"10.3329/jsr.v14i3.58210","DOIUrl":"https://doi.org/10.3329/jsr.v14i3.58210","url":null,"abstract":"The nonlinear fractional differential equation (FDE) is discussed in this study. First, we will investigate the existence and uniqueness solution of the nonlinear differential equation to the Atangana-Baleanu fractional derivative in the sense of Caputo with the initial periodic condition and integral boundary condition by Krasnoselskii’s and Banach fixed point theorems. Then, we will study the Hyers-Ulam stability of our problem. Finally, we presented an example to demonstrate the use of our main theorems.","PeriodicalId":16984,"journal":{"name":"JOURNAL OF SCIENTIFIC RESEARCH","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79451548","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
P. Singh, K. Soni, A. S. Nair, N. Kumar, Ranjan Sharma
Atmospheric Boundary Layer (ABL) height is an important parameter in defining the Ventilation Coefficient (VC) of any area. In this work, SODAR (Sound Detection and Ranging) observed data of different echograms for the year 2020 has been used for structure identification. The interpretation of ecograms is often not straight-forward. In this paper, an interpretation of different echograms along with meteorological parameters over Delhi is described. The ecogram structures were interpreted along with VC analysis. It is observed from the structures that during foggy days, VC values vary from day to day in the winter, with daily maximum values occurring between 13:00 and 15:00 h. The daytime values varied significantly from sunrise to sunset, while the night-time values remained relatively stable (200 m2/s). However, due to fog diurnal variation from 16:00 h to 11:00 h, that is from evening to all night and then the next morning until 12:00 h, the atmospheric condition remained stable. At maximal wind speeds, a maximum VC of 1600 m2/s (at 12:00 h) was observed during extended fumigation. With minimal wind speeds and ABL height, a minimum VC of 100 m2/s (at 20:00 h) was observed. However, both VCs were smaller than the optimal VC for 6000 m2/s safe dispersion.
{"title":"Interpretation of Acousting Sounding Records with Meterological Parameters and Ventilation Coefficient Over Delhi","authors":"P. Singh, K. Soni, A. S. Nair, N. Kumar, Ranjan Sharma","doi":"10.3329/jsr.v14i3.58317","DOIUrl":"https://doi.org/10.3329/jsr.v14i3.58317","url":null,"abstract":"Atmospheric Boundary Layer (ABL) height is an important parameter in defining the Ventilation Coefficient (VC) of any area. In this work, SODAR (Sound Detection and Ranging) observed data of different echograms for the year 2020 has been used for structure identification. The interpretation of ecograms is often not straight-forward. In this paper, an interpretation of different echograms along with meteorological parameters over Delhi is described. The ecogram structures were interpreted along with VC analysis. It is observed from the structures that during foggy days, VC values vary from day to day in the winter, with daily maximum values occurring between 13:00 and 15:00 h. The daytime values varied significantly from sunrise to sunset, while the night-time values remained relatively stable (200 m2/s). However, due to fog diurnal variation from 16:00 h to 11:00 h, that is from evening to all night and then the next morning until 12:00 h, the atmospheric condition remained stable. At maximal wind speeds, a maximum VC of 1600 m2/s (at 12:00 h) was observed during extended fumigation. With minimal wind speeds and ABL height, a minimum VC of 100 m2/s (at 20:00 h) was observed. However, both VCs were smaller than the optimal VC for 6000 m2/s safe dispersion.","PeriodicalId":16984,"journal":{"name":"JOURNAL OF SCIENTIFIC RESEARCH","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74896339","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. K. Brindha, P. Charkarborthy, S. Chenkual, J. Zohmingthanga, J. Pautu, P. Nath, A. Maitra, N. S. Kumar, L. Hmingliana
Aim of this study is to identify diet and lifestyle patterns that cause microsatellite instability gastric cancer (MSI-GC) using supervised machine learning algorithms. There were 142 genetic variants acquired via targeted resequencing of 60 biomarker genes from gastric tumor samples and tabulated with respect to MSI status, diet and lifestyle characteristics. Four classifiers (logistic regression, random forest, logistic regression, multilayer perceptron) were used to train the data and evaluated based on their classification efficiency. Data analysis revealed features extracted using ridge regression: extra salt, smoked food, smokeless tobacco products (Khaini /sadha), alcohol and betel nut leaf with lime (khuva) were the core factors for causing MSI-GC. The extracted features were exploited using random forest and multilayer perceptron classifiers, which has produced accuracy, precision, recall, F1 score, and Receiver operating characteristics (ROC) curve of 96 %. The brier score was 0.04 and Matthews correlation coefficient (MCC) was +0.91. Linear regression results revealed khuva was main driving factor and extra salt, smoked food, khaini/sadha and alcohol were confounding factors to cause MSI-GC. This is a first-time report that integrates mutation and diet-lifestyle data using machine learning, to precisely identify the driving and confounding factors for causing MSI-GC.
{"title":"Lifestyle and Dietary Factors Causing Microsatellite Instability Gastric Cancer Detected using Ensemble Modeling","authors":"S. K. Brindha, P. Charkarborthy, S. Chenkual, J. Zohmingthanga, J. Pautu, P. Nath, A. Maitra, N. S. Kumar, L. Hmingliana","doi":"10.3329/jsr.v14i3.58331","DOIUrl":"https://doi.org/10.3329/jsr.v14i3.58331","url":null,"abstract":"Aim of this study is to identify diet and lifestyle patterns that cause microsatellite instability gastric cancer (MSI-GC) using supervised machine learning algorithms. There were 142 genetic variants acquired via targeted resequencing of 60 biomarker genes from gastric tumor samples and tabulated with respect to MSI status, diet and lifestyle characteristics. Four classifiers (logistic regression, random forest, logistic regression, multilayer perceptron) were used to train the data and evaluated based on their classification efficiency. Data analysis revealed features extracted using ridge regression: extra salt, smoked food, smokeless tobacco products (Khaini /sadha), alcohol and betel nut leaf with lime (khuva) were the core factors for causing MSI-GC. The extracted features were exploited using random forest and multilayer perceptron classifiers, which has produced accuracy, precision, recall, F1 score, and Receiver operating characteristics (ROC) curve of 96 %. The brier score was 0.04 and Matthews correlation coefficient (MCC) was +0.91. Linear regression results revealed khuva was main driving factor and extra salt, smoked food, khaini/sadha and alcohol were confounding factors to cause MSI-GC. This is a first-time report that integrates mutation and diet-lifestyle data using machine learning, to precisely identify the driving and confounding factors for causing MSI-GC.","PeriodicalId":16984,"journal":{"name":"JOURNAL OF SCIENTIFIC RESEARCH","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88870595","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Here, we have studied the elastic, ultrasonic, mechanical, and thermal behavior of temperature-dependent hexagonal oxygen-functionalized M2CO2 (M= Ti, Zr, Hf) MXenes. The higher-order linear and nonlinear elastic constants, viz., second-order (SOECs), and third-order (TOECs) have been computed using the Lenard Jones interaction potential model. For mechanical characterization, bulk modulus (B), shear modulus (G), Young's modulus (Y), Pugh's ratio (B / G), Poisson's ratio, and anisotropic index are evaluated using SOECs. Born's stability and Pugh's criteria are used to examine the nature and strength of the MXenes in all the temperatures. For the investigation of anisotropic behavior and its thermophysical properties, temperature-dependent ultrasonic velocities and thermal relaxation time have been calculated along with different orientations from the unique axis of the crystal. The ultrasonic attenuation (UA) of a longitudinal and shear wave due to phonon-phonon (p-p) interaction and thermoelastic relaxation mechanism were investigated for these oxygen-functionalized MXenes. Thermal conductivity is a principal contributor to the behavior of UA due to p-p interactions. Our analysis suggests that semiconductor Ti2CO2 MXenes show superior mechanical properties to other oxygen-functionalized MXenes. Computed elastic, ultrasonic, and thermal properties are correlated to evaluate the microstructural behavior of the materials useful for industrial applications.
{"title":"Temperature-Dependent Ultrasonic Properties of Semiconducting M2CO2 (M= Ti, Zr, Hf) MXenes","authors":"P. Yadawa, N. Chaurasiya, S. Rai, A. Prajapati","doi":"10.3329/jsr.v14i3.56976","DOIUrl":"https://doi.org/10.3329/jsr.v14i3.56976","url":null,"abstract":"Here, we have studied the elastic, ultrasonic, mechanical, and thermal behavior of temperature-dependent hexagonal oxygen-functionalized M2CO2 (M= Ti, Zr, Hf) MXenes. The higher-order linear and nonlinear elastic constants, viz., second-order (SOECs), and third-order (TOECs) have been computed using the Lenard Jones interaction potential model. For mechanical characterization, bulk modulus (B), shear modulus (G), Young's modulus (Y), Pugh's ratio (B / G), Poisson's ratio, and anisotropic index are evaluated using SOECs. Born's stability and Pugh's criteria are used to examine the nature and strength of the MXenes in all the temperatures. For the investigation of anisotropic behavior and its thermophysical properties, temperature-dependent ultrasonic velocities and thermal relaxation time have been calculated along with different orientations from the unique axis of the crystal. The ultrasonic attenuation (UA) of a longitudinal and shear wave due to phonon-phonon (p-p) interaction and thermoelastic relaxation mechanism were investigated for these oxygen-functionalized MXenes. Thermal conductivity is a principal contributor to the behavior of UA due to p-p interactions. Our analysis suggests that semiconductor Ti2CO2 MXenes show superior mechanical properties to other oxygen-functionalized MXenes. Computed elastic, ultrasonic, and thermal properties are correlated to evaluate the microstructural behavior of the materials useful for industrial applications.","PeriodicalId":16984,"journal":{"name":"JOURNAL OF SCIENTIFIC RESEARCH","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90544607","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
京公网安备 11010802042870号
京ICP备2023020795号-1
扫码关注我们
求助内容：
应助结果提醒方式：