Journal of Supercritical Fluids最新文献

{"title":"Optimization of Supercritical CO2 Extraction of Juglone from Waste Walnut Green Husk via Response Surface Methodology","authors":"Yuwei Yang, Peisen Zhao, Lingxue Yu, Jinping Jia, Dandan Zhu","doi":"10.1016/j.supflu.2026.106886","DOIUrl":"https://doi.org/10.1016/j.supflu.2026.106886","url":null,"abstract":"","PeriodicalId":17078,"journal":{"name":"Journal of Supercritical Fluids","volume":"24 1","pages":""},"PeriodicalIF":3.9,"publicationDate":"2026-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145995413","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Valorization of Eucalyptus grandis × Eucalyptus urophylla leaves using supercritical fluid extraction: Yield optimization, chemical composition, and bioactivities","authors":"See Cheng Yip ,&nbsp;Lai Yee Ho ,&nbsp;Yee Ho Chai ,&nbsp;Nam Weng Sit","doi":"10.1016/j.supflu.2026.106892","DOIUrl":"10.1016/j.supflu.2026.106892","url":null,"abstract":"<div><div><em>Eucalyptus grandis</em> × <em>Eucalyptus urophylla</em> has been cultivated on a large scale in Malaysia for its timber values. Its leftover leaves are considered agricultural waste. This study aimed to optimize extraction yields and evaluate the chemical composition and bioactivities of leaf extracts from <em>Eucalyptus</em> hybrid produced using supercritical fluid extraction (SFE) with carbon dioxide. Leaves were collected from <em>Eucalyptus</em> hybrid trees aged 17 months to 31 months (group A) and 40 months to 50 months (group B). Optimization using response surface methodology (RSM) identified optimal extraction conditions (pressure, temperature, and time) as 29.7 MPa, 79.8 °C, and 116.2 min for A, and 30.0 MPa, 79.6 °C, and 108.6 min for B. Gas chromatography-mass spectrometry (GC-MS) showed that eucalyptol (18.82 %) and eucalyptin (16.46 %) were the dominant compounds in A and B, respectively. Incorporation of 10 % ethanol as co-solvent increased the SFE yield by approximately 10-fold from 0.475 % (w/w) (A) to 4.650 % (w/w) (A10) and 0.255 % (w/w) (B) to 2.640 % (w/w) (B10). All extracts demonstrated antimicrobial activity, with minimum inhibitory concentrations ranging from 0.02 mg/mL to 2.50 mg/mL against 10 bacterial strains, and 0.02 mg/mL to 1.25 mg/mL against seven fungal strains. The extracts were generally more effective against Gram-positive bacteria and exhibited variable antifungal activity depending on the fungal species. Notably, the ethanol-assisted SFE extract from B showed the strongest larvicidal activity against <em>Aedes aegypti</em> (LC₅₀: 187.02 µg/mL) and <em>Aedes albopictus</em> (LC₅₀: 294.48 µg/mL) after 48-hour exposure. These findings suggest that <em>Eucalyptus</em> hybrid leaves are a promising source of bioactive compounds with potential applications as disinfectants and mosquito larvicides.</div></div>","PeriodicalId":17078,"journal":{"name":"Journal of Supercritical Fluids","volume":"231 ","pages":"Article 106892"},"PeriodicalIF":4.4,"publicationDate":"2026-01-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145956900","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Investigating thermodynamic and kinetic behaviors of industrial contaminated lean monoethylene glycol in methane gas hydrate inhibition","authors":"Mahmood Riyadh Atta ,&nbsp;Bhajan Lal ,&nbsp;Khor Siak Foo","doi":"10.1016/j.supflu.2026.106891","DOIUrl":"10.1016/j.supflu.2026.106891","url":null,"abstract":"<div><div>Regenerated lean monoethylene glycol (LMEG) is widely reused as a thermodynamic hydrate inhibitor in offshore gas production; however, contaminant accumulation during regeneration cycles alters its inhibition performance. This study presents a combined thermodynamic and kinetic evaluation of industrially regenerated LMEG in a methane hydrate system. Hydrate–liquid–vapor equilibrium (HLVE), suppression temperature, induction time, gas uptake, and hydrate conversion were experimentally quantified using a high-pressure sapphire cell for (5−15) wt% LMEG solutions. Thermodynamic measurements show that regenerated LMEG produces average suppression temperatures of approximately (1.4, 2.6, and 4.2) °C for (5, 10, and 15) wt%, respectively, accompanied by a systematic rightward shift of HLVE curves relative to fresh MEG models. Kinetic analysis reveals that induction time increases from 33.8 min (5 wt%) to 58.0 min (15 wt%) at 80 bar, indicating a concentration-dependent delay in hydrate nucleation. Despite delayed nucleation, higher LMEG concentrations sustain elevated post-induction gas uptake, with methane gas-to-hydrate conversion exceeding 95 % at 15 wt% after 300 min. These results demonstrate a contamination-driven dual inhibition behavior in which reduced thermodynamic efficiency is partially offset by enhanced kinetic retardation. The findings highlight the need for combined thermodynamic–kinetic performance metrics when assessing regenerated MEG for industrial hydrate management.</div></div>","PeriodicalId":17078,"journal":{"name":"Journal of Supercritical Fluids","volume":"231 ","pages":"Article 106891"},"PeriodicalIF":4.4,"publicationDate":"2026-01-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145956800","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Performance evaluation and optimization of a coupled system integrating compressed carbon dioxide energy storage with double reheat thermal power unit","authors":"Guang Yan,&nbsp;Du Wang,&nbsp;Mujie Xue,&nbsp;Jian Lu,&nbsp;Rongyao Jia","doi":"10.1016/j.supflu.2026.106890","DOIUrl":"10.1016/j.supflu.2026.106890","url":null,"abstract":"<div><div>To enhance the peak load regulation capacity of thermal power units and improve the flexibility of power systems, this paper investigates the integration of a compressed carbon dioxide energy storage system with a 1000 MW double reheat thermal power unit. A thermodynamic model is developed for the power plant as well as for supercritical, transcritical, and liquid compressed carbon dioxide energy storage systems, and the effects of various coupling methods on the plant's performance are analyzed. Three types of compressed carbon dioxide energy storage systems and a double reheat thermal power plant coupling system are selected with the aim of minimizing heat consumption. The paper thoroughly examines the influence of key parameters on the thermal efficiency of the system and employs genetic algorithms for optimization. The results indicate that liquid compressed carbon dioxide energy storage is more suitable for coupling with double reheat thermal power units compared to supercritical or transcritical carbon dioxideenergy storage systems. The coupling process is as follows: during the energy storage phase, steam from the medium-pressure cylinder’s final stage is extracted to drive a small steam turbine for compression work, with the generated heat being absorbed by the power unit’s condensation water and returned to the low-pressure inlet of No.7. During the energy release phase, steam from the low-pressure cylinder’s first stage is extracted to heat the CO₂ entering the turbine, which is then returned to the low-pressure heater drain outlet of No.7. Among the key parameters, the inlet temperature of the second-stage compressor, the system expansion ratio, and the inlet temperatures of the first- and second-stage turbines have the greatest impact on system performance. Under the design conditions, the energy storage efficiency of the liquid carbon dioxide system is 56.97 %, the overall system efficiency is 46.27 %, the levelized cost of electricity is 0.118528 $/kWh, the energy storage density reaches 14.343 kWh/m³ , and the coal consumption rate is 256.61 g/kWh. After optimization, the coupled system efficiency can be improved by 1.23 %, and the LCOE can be reduced by 7.64 %. The coupling of liquid carbon dioxide energy storage with double reheat thermal power units can significantly enhance system flexibility and peak load regulation capabilities. This study offers valuable insights for engineering applications.</div></div>","PeriodicalId":17078,"journal":{"name":"Journal of Supercritical Fluids","volume":"232 ","pages":"Article 106890"},"PeriodicalIF":4.4,"publicationDate":"2026-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145956802","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"3-aminopropyltriethoxysilane (APTES) coating of glass surface using supercritical CO2: A solvent-free approach","authors":"Asifa Awan ,&nbsp;Peter Fojan ,&nbsp;Rudi P. Nielsen ,&nbsp;Morten E. Simonsen","doi":"10.1016/j.supflu.2026.106887","DOIUrl":"10.1016/j.supflu.2026.106887","url":null,"abstract":"<div><div>A sustainable alternative to conventional silanization techniques has been investigated with supercritical carbon dioxide (scCO₂) as a solvent for 3-aminopropyltriethoxysilane (APTES) deposition on glass surfaces. APTES deposition behavior was systematically evaluated under varying operational parameters, including pressure (90 and 150 bar), temperature (100–140°C), and reaction time (3 and 5 hr). FTIR spectroscopy, atomic force microscopy (AFM), and drop shape analysis (DSA) were employed to assess the chemical modifications, surface morphology, and wettability of the coated glass. Results demonstrated that temperature and pressure significantly govern the coating process, with increased pressure positively correlating with APTES deposition while elevated temperatures (100°C to 140°C) reduced deposition efficiency. AFM analysis revealed that surface roughness (Ra) increased progressively with higher pressure and longer reaction times, ranging from approximately 0.7 nm for lightly treated surfaces to over 10 nm for heavily coated samples. This confirmed the transition from uniform coatings to agglomerated surface structures at higher operating conditions. Surface energy determination demonstrated that the dispersive component of the surface energy consistently dominated, while the polar component varied with temperature, indicating a temperature-dependent modification of the surface functionalities. The density of scCO₂ emerged as a critical factor affecting surface deposition, with maximum deposition occurring within the 281–333 kg/m³ density range. Notably, complete silanization reactions and homogeneous surfaces were achieved primarily at lower scCO₂ densities.</div></div>","PeriodicalId":17078,"journal":{"name":"Journal of Supercritical Fluids","volume":"232 ","pages":"Article 106887"},"PeriodicalIF":4.4,"publicationDate":"2026-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145956820","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Green extraction of β-carotene-rich oil from tucumã (Astrocaryum vulgare Mart.) pulp using compressed propane","authors":"Lucas Cantão Freitas ,&nbsp;Vanessa Souza Carvalho ,&nbsp;Rogério Willian Silva dos Santos ,&nbsp;Manoel Benedito Sousa Cantão ,&nbsp;Eduardo Gama Ortiz Menezes ,&nbsp;Marcos Lúcio Corazza ,&nbsp;Maria Lucia Masson","doi":"10.1016/j.supflu.2026.106889","DOIUrl":"10.1016/j.supflu.2026.106889","url":null,"abstract":"<div><div>Tucumã pulp oil was obtained for the first time using compressed propane extraction (CPE) and compared with the conventional Soxhlet method. The overall extraction yield was determined, and the Spline model was employed to fit the kinetic parameters, including temperature and solvent flow rate. The oils were characterized by their fatty acid composition, β-carotene content, antioxidant capacity, total phenolics content (TPC), total flavonoids (TF), and thermal behavior. CPE extraction provided the highest extraction yield (33.9 wt%) with an efficiency of up to 91.4 %. The extraction condition that resulted in the highest yield was 80 °C and 3 mL/min, with solvent flow rate showing a significant effect (p &lt; 0.05) on the oil extraction yield. The Spline model provided a suitable fit, with a correlation coefficient of R² = 0.99. Tucumã pulp oil obtained via CPE proved to be an excellent source of β-carotene (21 times more than oils obtained by Soxhlet) and oleic acid, both of which are bioactive compounds of great interest in various industrial sectors, with potential applications in cosmetics, foods, and pharmaceuticals. Such applications enhance the production chain of this species, contributing to the Amazonian bioeconomy development.</div></div>","PeriodicalId":17078,"journal":{"name":"Journal of Supercritical Fluids","volume":"231 ","pages":"Article 106889"},"PeriodicalIF":4.4,"publicationDate":"2026-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145956801","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Continuous drying of alginate aerogel particles: Residence time measurement and process optimization under high pressure conditions","authors":"Erik Manke ,&nbsp;Bennet Rastar ,&nbsp;Alberto Bueno ,&nbsp;Baldur Schroeter ,&nbsp;Irina Smirnova","doi":"10.1016/j.supflu.2026.106888","DOIUrl":"10.1016/j.supflu.2026.106888","url":null,"abstract":"<div><div>This study advances continuous supercritical carbon dioxide (scCO₂) drying of aerogel particles by introducing a non-invasive optical method to determine particle residence time in a countercurrent extraction column. In countercurrent operation, scCO₂ flows upward while the particle suspension in ethanol enters from the top. The method enables precise, real-time residence time measurement under high pressure conditions without disturbing the process. The effects of pressure (100–150 bar), temperature (40–80 °C), CO₂ flow rate (30–80 g/min), and suspension flow rate (10–45 g/min) on residence time and drying efficiency were accordingly analyzed. Experiments were performed in a 1.25 m high extraction column, with an internal diameter of 20.5 mm, using highly spherical alginate beads with a diameter of ∼ 400 µm as a model system. Evidence of effective solvent removal throughout the whole operation range was provided by determination of the residual ethanol content in the intact aerogel beads after the drying process (0.0053–0.0341 g_ethanol/g_aerogel). The dried products featured a specific surface area of 363 ± 27 m²/g, a mesopore volume of 3.2 ± 0.7 cm³ /g, consistent with the typical range of alginate aerogels. The combined insights provide a comprehensive picture of the countercurrent column’s operational response and allow the definition of practical operating windows. Elevated temperature and high pressure provide the most favorable trade-off between short residence time and minimized residual ethanol, maximizing the time-specific yield. Overall, the approach establishes a robust, transferable framework for optimizing continuous scCO₂ drying of aerogel particles and supports extension to other particle sizes and formulations.</div></div>","PeriodicalId":17078,"journal":{"name":"Journal of Supercritical Fluids","volume":"231 ","pages":"Article 106888"},"PeriodicalIF":4.4,"publicationDate":"2026-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145956821","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Experimental study on supercritical CO₂ flow and heat transfer in rectangular microchannel PCHE under recompression cycle conditions","authors":"Shishen Cheng ,&nbsp;Yan Ren ,&nbsp;Ruowen Jiang ,&nbsp;Mengjie Song ,&nbsp;Weidong Wu ,&nbsp;Yingying Yang ,&nbsp;Qiguo Yang","doi":"10.1016/j.supflu.2025.106873","DOIUrl":"10.1016/j.supflu.2025.106873","url":null,"abstract":"<div><div>Rectangular microchannel printed circuit heat exchangers (RM-PCHEs) exhibit excellent flow and heat transfer characteristics. However, within the operating range of low-temperature recuperator for the supercritical carbon dioxide (SCO₂) Brayton recompression cycle, their performance data remain scant for hot-side inlet temperatures ranging from 373.8 K to 423.4 K. To address this gap, this study conducted experimental research on the flow and heat transfer characteristics of an RM-PCHE using SCO₂ as the working fluid, based on a comprehensive performance test system for heat exchangers. The results showed that the heat transfer performance of test sample was most significantly influenced by SCO₂ inlet temperature, with a 4.3 % increase in <em>Q</em>_ave and a 1.3 % decrease in <em>UA</em> for every 1 % increase in <em>T</em>_hot,i, and a 3.6 % increase in <em>ε</em> for every 1 % increase in <em>T</em>_cold,i. Besides, the test sample was most greatly influenced by mass flow rate, with a 1.5 % decrease in Δ<em>P</em>_hot for every 1 % decrease in <em>m</em>_hot, and a 1.7 % in Δ<em>P</em>_cold for every 1 % decrease in <em>m</em>_cold. Finally, test sample demonstrated enhanced thermal hydraulic performance, achieving maximum <em>UA</em> and <em>ε</em> values of 414.8 W·K⁻¹ and 0.92, respectively, while the maximum pressure drops on hot- and cold-side were 42.0 kPa and 13.9 kPa, respectively.</div></div>","PeriodicalId":17078,"journal":{"name":"Journal of Supercritical Fluids","volume":"231 ","pages":"Article 106873"},"PeriodicalIF":4.4,"publicationDate":"2025-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145894252","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Semi-continuous subcritical hydrothermal conversion of lignin-rich defatted olive pomace","authors":"Alex Schulz ,&nbsp;William Santos Fagundes ,&nbsp;Leonardo Ramos Ten Caten ,&nbsp;Francisco Dalcin Vezaro ,&nbsp;Crisleine Perinazzo Draszewski ,&nbsp;Leoni Nogueira Brondani ,&nbsp;Michel Brondani ,&nbsp;João Henrique Cabral Wancura ,&nbsp;Flávio Dias Mayer ,&nbsp;Ederson Rossi Abaide","doi":"10.1016/j.supflu.2025.106874","DOIUrl":"10.1016/j.supflu.2025.106874","url":null,"abstract":"<div><div>Defatted olive pomace (DOP) is an abundant and low-cost agro-industrial residue that can be repurposed as an alternative to conventional uses such as direct combustion, animal feed, and land disposal. DOP has potential for the production of value-added products including biocrude (BC), hydrochar (HC), fermentable sugars (FS), and platform chemicals (PC) through the depolymerization of holocellulose and lignin present in its composition. The objective of this study was to evaluate the influence of temperature (250 and 300 ºC) and water-to-biomass ratio (15, 20, and 25) on the yields of BC, HC, FS, and PC through semi-continuous subcritical hydrothermal liquefaction of DOP. The highest yields were achieved at 300 °C with a water-to-DOP ratio of 25, resulting in values of 38.50 ± 3.13, 5.78 ± 1.07, 6.74 ± 1.67, and 2.84 ± 0.13 g/100 g for BC, HC, FS, and PC, respectively. The higher heating values (HHV) of BC and HC were 29.11 ± 0.05 and 26.01 ± 1.18 MJ/kg, respectively—comparable to values reported in other studies with both similar and different residues.</div></div>","PeriodicalId":17078,"journal":{"name":"Journal of Supercritical Fluids","volume":"231 ","pages":"Article 106874"},"PeriodicalIF":4.4,"publicationDate":"2025-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145882677","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Modeling supercritical water gasification of municipal waste: Machine learning and data augmentation approaches","authors":"A. Cosenza ,&nbsp;B. Cosenza ,&nbsp;S. Lima ,&nbsp;F. Scargiali ,&nbsp;G. Caputo","doi":"10.1016/j.supflu.2025.106872","DOIUrl":"10.1016/j.supflu.2025.106872","url":null,"abstract":"<div><div>This study presents a comprehensive machine learning framework for modeling supercritical water gasification (SCWG) of organic fraction of municipal solid waste (OFMSW) to optimize syngas production. A systematic experimental campaign investigated 16 conditions across 400–450 °C, 10–60 min reaction times, and OFMSW/H₂O ratios of 0.050–0.085, yielding gas compositions with H₂ concentrations of 12–44 %, CO₂ of 24–79 %, CO of 2.8–15.7 %, and CH₄ of 0–22 %. To address limited experimental data challenges, a SCWG-tailored Monte Carlo augmentation with compositional closure, measurement-uncertainty modeling, and leakage-free cross-validation was implemented to address tiny-n multi-output composition prediction, incorporating experimentally characterized uncertainties and generating augmented datasets of 10 × and 100 × the original size while enforcing physical feasibility (non-negativity, unit-sum, and range bounds). Random Forest (RF) and Gradient Boosting (GB) algorithms were employed for multi-output modeling of gas yield and composition. Under physically constrained augmentation and cross-validation, high in-domain accuracy is achieved across the explored operating window with R² values increasing from 0.445 ± 0.327 (RF) and 0.549 ± 0.324 (GB) on original data to &gt; 0.96 for major components on 100 × augmented datasets. Process optimization identified distinct optimal conditions: hydrogen fuel production (450 °C, 16 min, yielding 39.4 % H₂ with 77.6 % gas yield) and Fischer-Tropsch synthesis (450 °C, 10 min, achieving H₂/CO ratio of 2.13 with 63.6 % gas yield). The framework successfully bridges limited experimental data and reliable process optimization, providing validated methodology for advancing SCWG technology toward industrial implementation. Independent validation on new waste batches and configurations will be required to establish broader generalization.</div></div>","PeriodicalId":17078,"journal":{"name":"Journal of Supercritical Fluids","volume":"231 ","pages":"Article 106872"},"PeriodicalIF":4.4,"publicationDate":"2025-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145796136","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}