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Variability of fallout radionuclides (FRNs) in river channels: implications for sediment tracing 河道中沉降放射性核素(FRNs)的变化:对沉积物追踪的影响
IF 3.6 3区 农林科学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-08-07 DOI: 10.1007/s11368-024-03881-z
Enrique Muñoz-Arcos, Geoffrey E. Millward, Caroline C. Clason, Richard Hartley, Claudio Bravo-Linares, William H. Blake

Purpose

The aims of this research were to assess the sources of variability of particulate FRNs (7Be, 210Pbex and 137Cs) in river channels, the influence of sediment properties such as particle size distribution (PSD) and organic matter (OM) on FRN distributions, and to discuss the implications for sediment tracing in rivers.

Methods

Suspended and channel bed sediment samples were collected in the River Avon (Devon, UK) during five strategic surveys involving a wide variation of river flows, including flood conditions. Particulate matter was analysed for 7Be, 210Pbex and 137Cs by gamma spectrometry, PSD by laser diffraction, and organic constituents, total organic carbon (TOC) and total nitrogen (TN) by elemental analysis.

Results

FRNs activity concentrations vary significantly both spatially, characterised by changes in activity concentrations within and between locations, and temporally, with changes during the storm hydrograph and between seasons. Variability was attributed to changes in sediment sources and, on some occasions, to significant correlation of activity concentrations with sediment properties. The results also highlighted the influence of changes in channel characteristics and the magnitude and frequency of floods on FRN distributions.

Conclusion

In the context of sediment tracing, attention should be given to seasonal changes in riverine conditions that have the potential to affect 7Be and 137Cs conservativeness. Application of FRNs in sediment fingerprinting studies should be accompanied by appropriate temporal characterisation of potential sediment sources. Finally, potential contribution of 7Be-depleted sediment from channel resuspension to the suspended load should also be considered.

本研究旨在评估河道中颗粒 FRNs(7Be、210Pbex 和 137Cs)的变化来源、沉积物特性(如粒度分布 (PSD) 和有机物 (OM) )对 FRN 分布的影响,并讨论其对河流沉积物追踪的意义。通过伽马能谱仪分析了颗粒物质中的 7Be、210Pbex 和 137Cs,通过激光衍射分析了 PSD,通过元素分析分析了有机成分、总有机碳 (TOC) 和总氮 (TN)。这种变化可归因于沉积物来源的变化,在某些情况下,还可归因于活性浓度与沉积物特性之间的显著相关性。结果还强调了河道特征的变化以及洪水的规模和频率对 FRN 分布的影响。在沉积物指纹研究中应用 FRNs 的同时,还应对潜在的沉积物来源进行适当的时间特征描述。最后,还应考虑河道再悬浮对悬浮负荷可能造成的 7Be 贫化沉积物的影响。
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引用次数: 0
Distributions and controlling factors of soil total nitrogen and nitrogen fractions along an altitude gradient in Qinghai-Tibet Plateau 青藏高原土壤全氮和氮组分沿海拔梯度的分布及其控制因素
IF 3.6 3区 农林科学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-08-06 DOI: 10.1007/s11368-024-03882-y
Da Meng, Xinyu Wang, Jiayi Tang, Ning Zong, Jinjing Zhang, Nianpeng He

Purpose

Understanding spatial variations in soil nutrients and its drivers is essential for sustainable nutrient management and related environmental assessment in terrestrial ecosystems. Here, we investigated the distribution characteristics and controlling factors of soil total nitrogen (N) and N fractions along an altitude gradient in an alpine meadow of the Qinghai-Tibet Plateau.

Materials and methods

Six experimental sites at altitudes 4400, 4500, 4650, 4800, 4950, and 5200 m were established on southern slope of Nyainqentanglha Mountain since 2005. Total N and N fractions were quantified and their relationships with climate, vegetation, and edaphic factors were analyzed by Pearson correlation, redundancy analysis, and structural equation modeling.

Results and discussion

With increasing altitude, the contents of total N, alkali-hydrolyzable N, inorganic N fractions (ammonium N and nitrate N), and organic N fractions (acid-hydrolyzable and acid-insoluble organic N) gradually increased, reached their maximums at altitude 4800 or 4950 m, and then decreased. Soil organic carbon explained 90.5% of the variations in TN and N fractions, and soil moisture, pH, mineralogy, texture, and N hydrolyzing enzyme activity explained 8.80% of the variations in TN and N fractions. Mean annual temperature and precipitation exhibited direct and positive impact on soil organic carbon, which had positive effect on inorganic N fractions and plant aboveground biomass in sequence.

Conclusions

Soil organic carbon is the most dominant factors driving the variations in TN and N fractions along the altitude gradient. Climate change can impact alpine grassland productivity by regulating soil inorganic N distribution.

目的 了解土壤养分的空间变化及其驱动因素对于陆地生态系统的可持续养分管理和相关环境评估至关重要。材料与方法 2005 年以来,我们在念青唐古拉山南坡建立了海拔 4400 米、4500 米、4650 米、4800 米、4950 米和 5200 米的六个实验点。结果与讨论随着海拔的升高,总氮、碱解氮、无机氮组分(铵氮和硝酸氮)和有机氮组分(酸解有机氮和酸不溶有机氮)的含量逐渐增加,在海拔 4800 或 4950 米处达到最大值,然后逐渐减少。土壤有机碳解释了 TN 和 N 分量变化的 90.5%,土壤水分、pH 值、矿物学、质地和氮水解酶活性解释了 TN 和 N 分量变化的 8.80%。年平均气温和降水量对土壤有机碳有直接的正向影响,而土壤有机碳对无机氮组分和植物地上生物量依次有正向影响。气候变化可通过调节土壤无机氮的分布影响高寒草地的生产力。
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引用次数: 0
Impact of Rare Earth Elements in sediments on the growth and photosynthetic efficiency of the benthic plant Myriophyllum aquaticum 沉积物中的稀土元素对底栖植物水生藻类的生长和光合作用效率的影响
IF 3.6 3区 农林科学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-08-02 DOI: 10.1007/s11368-024-03867-x
Isidora Gjata, Chantal K. E. van Drimmelen, Franca Tommasi, Costantino Paciolla, Susanne Heise

Purpose

Rare Earth Elements (REEs) are becoming more present in our everyday life. With this work, we aimed to study and compare the toxic responses of the REEs lanthanum (La), cerium (Ce), neodymium (Nd), and gadolinium (Gd) to the macrophyte Myriophyllum aquaticum. The scope was to evaluate if these elements trigger a response on the photosynthetic system (PSII), which causes inhibition of the growth rate of the plant.

Methods

We measured the fluorescence yield by pulse-amplitude-modulated chlorophyll fluorometer (PAM) which enabled simultaneous high-resolution fluorescence measurements of the whorls daily for the whole duration of the test (10 days) and fresh weight change (FWC) at the end of the test.

Results

Our findings suggest that La significantly decreased FWC at the highest concentration (500 mg kg−1) but did not cause any significant effects on the fluorescence yield. Ce and Nd significantly decreased the chlorophyll fluorescence between days 2 and 4, and after that the yield was not significantly different with respect to the control. Of all the REEs tested in this study, Gd showed the most negative effect as the whorls exhibited chlorosis/necrosis and the fresh weight at the end of the test decreased significantly compared to the same plant at day 0. The yield of M. aquaticum showed time-dependent effects for Gd at the highest concentration.

Conclusion

Gd was the most toxic REE, strongly affecting both the yield and FWC. The measurement of the fluorescence yield of the PSII is a useful effect observation and of high environmental importance. The difference in sensitivity between the functional and growth endpoints may give hints about the mode of action of contaminants to aquatic plants.

目的稀土元素(REEs)越来越多地出现在我们的日常生活中。通过这项工作,我们旨在研究和比较稀土元素镧(La)、铈(Ce)、钕(Nd)和钆(Gd)对大型水生叶绿藻的毒性反应。方法我们使用脉冲幅度调制叶绿素荧光仪(PAM)测量了荧光产量,该仪器可在整个试验期间(10 天)每天同时对轮叶进行高分辨率荧光测量,并在试验结束时测量鲜重变化(FWC)。结果我们的研究结果表明,在最高浓度(500 毫克/千克)下,La 能显著降低 FWC,但对荧光产量没有明显影响。铈和钕在第 2 至 4 天明显降低了叶绿素荧光,之后的产量与对照组相比没有明显差异。在本研究测试的所有稀土元素中,钆的负面影响最大,因为轮叶出现萎黄/坏死,测试结束时的鲜重与第 0 天的相同植株相比明显下降。结论 Gd 是毒性最强的稀土元素,对产量和 FWC 都有强烈影响。对 PSII 的荧光产量进行测量是一种有用的效应观测,对环境具有重要意义。功能终点和生长终点之间灵敏度的差异可提示污染物对水生植物的作用模式。
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引用次数: 0
Can inoculation of native arbuscular mycorrhizal fungi from a mining area attenuate stress of Acacia mangium Willd. to excess manganese? 接种矿区原生的丛枝菌根真菌能否减轻芒果相思树对过量锰的压力?
IF 3.6 3区 农林科学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-08-01 DOI: 10.1007/s11368-024-03874-y
Kaio Gráculo Vieira Garcia, José de Souza Oliveira Filho, Arthur Prudêncio de Araújo Pereira, Paulo Furtado Mendes Filho

Purpose

Manganese (Mn) is crucial in low concentrations but can become toxic in soils and sediments, affecting plants and animals. Understanding how plants inoculated with arbuscular mycorrhizal fungi (AMF) tolerate Mn is crucial for the application of these microorganisms in the remediation of contaminated soils. Despite recognized benefits in various plant species, assessing plant-AMF interaction effectiveness in mitigating Mn toxicity is crucial for undocumented plants.

Methods

Acacia mangium Willd. plants were inoculated with an AMF native to a Mn mining area and grown in soil with increasing Mn levels (0, 200, and 400 mg kg−1) to evaluate the effects of inoculation on plant growth and plant-AMF association strategies to reduce Mn toxicity.

Results

Inoculation with AMF resulted in beneficial effects, minimizing Mn toxicity and enhancing plant growth, despite reduced mycorrhizal colonization and AMF spore levels in the soil. Non-inoculated plants exposed to 400 mg kg−1 of Mn exhibited significant reductions in shoot dry mass (64.9%), number of leaves (25%), and root length (24%) compared to AMF-inoculated plants. Mn concentration was higher in the roots of AMF-inoculated plants at all Mn levels, indicating a restriction in Mn transport to the shoot, thus minimizing damage and promoting plant growth. Energy-dispersive spectroscopy identified Mn, potassium, phosphorus, iron and calcium in AMF spores, suggesting their protective role against Mn phytotoxicity and adaptability of this species of microorganism under stress conditions.

Conclusion

The native AMF inoculation reduces toxicity and improves the growth of A. mangium Willd. under high levels of Mn in the soil.

目的 锰(Mn)在低浓度时非常重要,但在土壤和沉积物中会产生毒性,影响植物和动物。了解接种了丛枝菌根真菌(AMF)的植物是如何耐受锰的,对于应用这些微生物修复受污染的土壤至关重要。尽管各种植物物种的益处已得到公认,但评估植物与 AMF 相互作用在减轻锰毒性方面的有效性对于未记录的植物至关重要。结果尽管土壤中的菌根定殖和 AMF 孢子水平降低,但接种 AMF 产生了有益的影响,最大程度地降低了锰的毒性并促进了植物的生长。与接种了 AMF 的植物相比,未接种 400 毫克/千克锰的植物在嫩枝干重(64.9%)、叶片数量(25%)和根长(24%)方面都有显著下降。在所有锰含量水平下,AMF 接种植物根部的锰浓度都较高,这表明锰向嫩枝的运输受到了限制,从而最大限度地减少了损害,促进了植物生长。能量色散光谱法确定了 AMF 孢子中的锰、钾、磷、铁和钙,表明它们对锰的植物毒性具有保护作用,而且这种微生物在胁迫条件下具有很强的适应性。
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引用次数: 0
Historical and contemporary cemeteries in the urban area. The modern development of the city vs. human remnants in the soil 城市地区的历史和现代墓地。城市的现代发展与土壤中的人类遗迹
IF 3.6 3区 农林科学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-08-01 DOI: 10.1007/s11368-024-03870-2
Andrzej Greinert, Jakub Kostecki

Purpose

Death is inextricably linked to the functioning of the biosphere, including the presence of humans on Earth. The remains of 117 billion people who have ever lived on Earth are mostly hidden in the soil. Hence, the organization, use and subsequent fate of cemeteries and their surroundings should also be considered from the perspective of pedeogenesis. The soils of such areas are subject to multifactorial human pressure, as reflected in their often complex soil profiles.

Materials and methods

The situation of a Central European city of medieval origin, Zielona Gora (Poland), characterized by the presence of 39 cemeteries within its current boundaries, is presented. The location of these cemeteries was shown in light of other factors of human pressure on soil, including relation to buildings construction and a land use. The analysis of the current form of use of burial sites and their immediate surroundings used the technique of field research and a city's documentation query. In order to reflect the specific impact of the form of use of post-burial grounds on soil properties, selected soil characteristics of exemplary historical cemeteries are presented. The main soil characteristics were evaluated using standard methods of laboratory analysis.

Results and discussion

Some cemeteries are reflected in the city's planning documents – there are all contemporary cemeteries and a few historical ones. The vast majority of historical burial sites are not reflected in the plans. This makes modern urban development directly adjacent to them and even encroaches on their territories. Soil analysis has shown that human remains are still present in soils of these areas, even hundreds of years after cemetery closure. In addition to these, the soils are characterized by elevated C and P content relative to the bedrock. The arrangement of the necrosol profile is disturbed by the significant presence of construction and municipal waste. The most soil characteristics, including grain-size composition, pH, EC, sorption properties, organic and inorganic carbon content, as well as macronutrients and heavy metals, are strong influenced by the land use form and urban pressure on cemetery areas.

Conclusions

It is common practice around the world to bury human bodies or ashes in soil, hence their remains contribute to soil profiles. Proper identification of cemetery soil profiles, with a clear indication of necric features, is difficult due to the different uses of cemetery land. The soils of former cemeteries, by reason of their relationship to buildings and urban parks, take on the characteristics typical of such urban land use forms.

目的死亡与生物圈的运作密不可分,包括人类在地球上的存在。地球上曾经生活过的 1 170 亿人的遗骸大多藏在土壤中。因此,公墓及其周围环境的组织、使用和随后的命运也应从植被生成的角度加以考虑。这些地区的土壤承受着多因素的人为压力,其复杂的土壤剖面就反映了这一点。材料和方法本文介绍了中欧中世纪城市 Zielona Gora(波兰)的情况,其特点是在其现有边界内有 39 个墓地。这些墓地的位置是根据人类对土壤造成压力的其他因素(包括与建筑物建造和土地使用的关系)确定的。对墓地及其周边环境的当前使用形式的分析采用了实地研究和城市文献查询的技术。为了反映墓葬后场地的使用形式对土壤特性的具体影响,本文介绍了一些典型历史墓地的土壤特性。主要土壤特性采用标准的实验室分析方法进行评估。绝大多数历史墓地都没有反映在规划中。这使得现代城市发展直接毗邻它们,甚至侵占了它们的领地。土壤分析表明,即使在墓地关闭数百年后,这些地区的土壤中仍然存在人类遗骸。除此之外,相对于基岩而言,这些土壤还具有 C 和 P 含量高的特点。建筑垃圾和城市垃圾的大量存在扰乱了尸溶剖面的排列。大多数土壤特性,包括粒度组成、pH 值、导电率、吸附特性、有机碳和无机碳含量,以及常量营养元素和重金属,都受到墓地地区土地利用形式和城市压力的强烈影响。由于墓地土地的用途各不相同,因此很难正确识别墓地土壤剖面,并清楚地显示其钙质特征。旧墓地的土壤由于与建筑物和城市公园的关系,具有此类城市土地利用形式的典型特征。
{"title":"Historical and contemporary cemeteries in the urban area. The modern development of the city vs. human remnants in the soil","authors":"Andrzej Greinert, Jakub Kostecki","doi":"10.1007/s11368-024-03870-2","DOIUrl":"https://doi.org/10.1007/s11368-024-03870-2","url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Purpose</h3><p>Death is inextricably linked to the functioning of the biosphere, including the presence of humans on Earth. The remains of 117 billion people who have ever lived on Earth are mostly hidden in the soil. Hence, the organization, use and subsequent fate of cemeteries and their surroundings should also be considered from the perspective of pedeogenesis. The soils of such areas are subject to multifactorial human pressure, as reflected in their often complex soil profiles.</p><h3 data-test=\"abstract-sub-heading\">Materials and methods</h3><p>The situation of a Central European city of medieval origin, Zielona Gora (Poland), characterized by the presence of 39 cemeteries within its current boundaries, is presented. The location of these cemeteries was shown in light of other factors of human pressure on soil, including relation to buildings construction and a land use. The analysis of the current form of use of burial sites and their immediate surroundings used the technique of field research and a city's documentation query. In order to reflect the specific impact of the form of use of post-burial grounds on soil properties, selected soil characteristics of exemplary historical cemeteries are presented. The main soil characteristics were evaluated using standard methods of laboratory analysis.</p><h3 data-test=\"abstract-sub-heading\">Results and discussion</h3><p>Some cemeteries are reflected in the city's planning documents – there are all contemporary cemeteries and a few historical ones. The vast majority of historical burial sites are not reflected in the plans. This makes modern urban development directly adjacent to them and even encroaches on their territories. Soil analysis has shown that human remains are still present in soils of these areas, even hundreds of years after cemetery closure. In addition to these, the soils are characterized by elevated C and P content relative to the bedrock. The arrangement of the necrosol profile is disturbed by the significant presence of construction and municipal waste. The most soil characteristics, including grain-size composition, pH, EC, sorption properties, organic and inorganic carbon content, as well as macronutrients and heavy metals, are strong influenced by the land use form and urban pressure on cemetery areas.</p><h3 data-test=\"abstract-sub-heading\">Conclusions</h3><p>It is common practice around the world to bury human bodies or ashes in soil, hence their remains contribute to soil profiles. Proper identification of cemetery soil profiles, with a clear indication of necric features, is difficult due to the different uses of cemetery land. The soils of former cemeteries, by reason of their relationship to buildings and urban parks, take on the characteristics typical of such urban land use forms.</p>","PeriodicalId":17139,"journal":{"name":"Journal of Soils and Sediments","volume":null,"pages":null},"PeriodicalIF":3.6,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141866416","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
25 years of SUITMAs: Urban soils - a new research field in soil science. What makes these soils and the interest in these soils so special? 25 年的 SUITMAs:城市土壤--土壤科学的新研究领域。是什么让这些土壤和对这些土壤的兴趣变得如此特别?
IF 3.6 3区 农林科学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-08-01 DOI: 10.1007/s11368-024-03826-6
Wolfgang Burghardt

Purpose

Since the occurrence of humans, soil has been affected by them. Thus, rural areas have been modified. Currently, urban areas are increasing extensively. They are locations with a high population density that are impacted by settlements and industrial technologies. This paper shows how soils are further discriminated by urbanization.

Material and methods

A collection of observations and conclusions about the characteristics of natural and urban soils and the discrimination by interpretation of the particularities of discovered soils are presented. This view is enlarged by the specific features of the mode of human action and their effects on soil formation.

Results and discussion

The effects of humans on soils in rural areas are numerous. They concern effects from soil use, evolving soil fertility and raw material supply by mining. Changes in soil formation occur due to natural factors in the landscapes. Discussions about the nature of soils in urban areas stress the situation of a low soil age, that they become relicts, are highly disturbed, contain artifacts, and are mostly byproducts of human decisions. Based on the specific urban climate, there are zonal soils. Perceptions about what qualifies these soils to be separately designated as urban soils are presented. The new view of the differentiation of artifacts by their origin from heat-treated products allows a more precise definition of soils in urban areas. Soil formation can occur quickly.

Conclusion

Urban soil research is a wide field for discovering new modes of soil formation and the relationship between humans and soils.

目的自从有了人类,土壤就受到了影响。因此,农村地区发生了变化。目前,城市地区正在大量增加。它们是人口密度较高的地区,受到定居点和工业技术的影响。本文介绍了如何通过城市化进一步区分土壤。材料和方法本文收集了有关天然土壤和城市土壤特征的观察结果和结论,并通过对已发现土壤特殊性的解释进行了区分。结果与讨论人类对农村地区土壤的影响是多方面的。人类对农村地区土壤的影响是多方面的,包括对土壤的使用、土壤肥力的演变和采矿提供的原材料。土壤形成的变化是由于地貌中的自然因素造成的。关于城市地区土壤性质的讨论强调了土壤年龄较低的情况,即土壤成为遗迹,受到严重干扰,含有人工痕迹,并且大多是人类决策的副产品。根据特定的城市气候,土壤也有分区。本文介绍了对这些土壤被单独指定为城市土壤的认识。根据热处理产品的来源对人工制品进行区分的新观点可以更精确地定义城市地区的土壤。结论城市土壤研究是一个发现新的土壤形成模式以及人类与土壤关系的广阔领域。
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引用次数: 0
Prediction of soil moisture content using genetic algorithm-optimized backpropagation algorithm from spectral data 利用遗传算法优化的反向传播算法从光谱数据中预测土壤含水量
IF 3.6 3区 农林科学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-07-31 DOI: 10.1007/s11368-024-03868-w
Jiawei Wang, Dong Zhang, Yulu Zhang, Hu Liu, Linkang Zhou, Hua Jin

Purpose

Accurately assessing soil moisture content (SMC) is essential for applications in agriculture and ecological sustainability. However, the dynamic monitoring and assessment of SMC presents considerable challenges due to the intricate traditional methods and the ever-evolving environmental variables. Relevant research has indicated that visible and near-infrared (vis–NIR) spectra are a practical and cost-effective alternative for accurate and convenient estimation of SMC. Advances in technology and computer hardware have enabled spectral characteristics and computer vision algorithms to show enormous potential for rapid and non-destructive characterization of soil properties. The objective of this study was to evaluate the predicted ability of SMC using vis–NIR spectral data.

Materials and methods

A total of 60 topsoil samples (0–5 cm) from the maize test field at the Shanxi Central Irrigation Test station were used as the study object. A set of four spectral parameters was derived and filtered from spectral data, and C-W and W-W models were developed using Genetic Algorithm algorithm-optimized backpropagation (GA-BP) neural networks to predict SMC based on outdoor measurements.

Results and discussion

The results showed that: (1) SMC can be successfully predicted using the spectral data through the C-W and W-W models; (2) the C-W model outperformed the W-W model, particularly in the context of deep soil, with R2 ranging from 0.919 to 0.991 and corresponding RMSE values from 0.619% to 0.982%.

Conclusions

This study introduces two effective methodologies for accurate estimation of SMC at different depths using multispectral remote sensing, which showed a high degree of prediction accuracy. It further proves that GA-BP algorithm is still effective for predicting SMC in outdoor. The research result might be helpful for the further study of SMC measurement.

目的准确评估土壤含水量(SMC)对于农业应用和生态可持续性至关重要。然而,由于传统方法的复杂性和环境变量的不断变化,土壤含水量的动态监测和评估面临着相当大的挑战。相关研究表明,可见光和近红外(vis-NIR)光谱是准确、方便地估算 SMC 的一种实用且具有成本效益的替代方法。技术和计算机硬件的进步使得光谱特性和计算机视觉算法在快速、无损地表征土壤特性方面显示出巨大的潜力。本研究的目的是利用可见近红外光谱数据评估 SMC 的预测能力。利用遗传算法-优化反向传播(GA-BP)神经网络建立 C-W 和 W-W 模型,根据室外测量结果预测 SMC:(1) 通过 C-W 和 W-W 模型,可以利用光谱数据成功预测 SMC;(2) C-W 模型的性能优于 W-W 模型,尤其是在深层土壤方面,R2 为 0.919 至 0.991,相应的 RMSE 值为 0.619% 至 0.982%。它进一步证明了 GA-BP 算法在预测室外 SMC 方面仍然有效。该研究成果可能有助于对 SMC 测量的进一步研究。
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引用次数: 0
Variations in iron-bound organic carbon in soils along an altitude gradient and influencing factors in a subtropical mountain ecosystem of southern China 中国南方亚热带山地生态系统土壤中铁结合有机碳沿海拔梯度的变化及其影响因素
IF 3.6 3区 农林科学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-07-30 DOI: 10.1007/s11368-024-03873-z
Kai Xiong, Xinyu Jiang, Shaoqiang Huang, Jinshun Guan, Xiangbo Zou, Chuangting Chen, Tiancheng Zhou, Cao Kuang, Ji Ye, Shiqin Yu, Heng Jiang, Bin Huang

Purpose

The main factors governing iron-bound organic carbon (Fe-bound OC) formation under different environmental conditions have been less well identified. In this study, we investigated the distribution of Fe-bound OC and the influencing factors in soils of a typical subtropical mountain ecosystem.

Materials and methods

Soil samples at different altitudes (402–1653 m) and depths (0–20 cm, 20–40 cm, and 40–60 cm) in the Nanling Mountains of southern China were collected. The influence of soil property indicators and microbial diversity characteristics on the formation of Fe-bound OC was explored.

Results

The Fe-bound OC content in the soils ranged from 1.40 ± 1.32 g/kg to 15.09 ± 3.57 g/kg, accounting for an average of 23.49 ± 13.03% of the total organic carbon (TOC), and generally increased with altitude and exhibited significantly higher values at the soil depth of 0–20 cm, while its proportion to TOC (fFe-OC) gradually increased as soil depth increased. The more significant indicators in explaining the variation of Fe-bound OC include TOC, particulate organic carbon (POC), free iron oxides (Fed), amorphous iron oxides (Feo), complexed iron oxides (Fep), Feo/Fed, pH, Ca, sand and silt. Feo/Fed was strongly linearly correlated with Fe-bound OC, thus can be a good predictor of Fe-bound OC content. RDA analysis showed that Fe-bound OC/fFe-OC had a relatively closer correlation with bacterial phyla including Proteobacteria, Actinobacteriota, Chloroflexi and Firmicutes.

Conclusions

The attitude gradient and soil depth significantly influence the content of Fe-bound OC. The distribution of Fe-bound OC exhibited a certain correlation with both biotic and abiotic factors.

目的 在不同环境条件下,影响铁结合有机碳(Fe-bound OC)形成的主要因素尚不十分明确。材料与方法在中国南方南岭山区采集了不同海拔(402-1653 m)、不同深度(0-20 cm、20-40 cm、40-60 cm)的土壤样品。结果土壤中铁结合有机碳的含量从1.40±1.32 g/kg到15.09±3.57 g/kg不等,平均占总有机碳(TOC)的23.49±13.03%,且随海拔的升高而升高,在0-20 cm深度的土壤中铁结合有机碳的含量显著升高,其占TOC的比例(fFe-OC)随土壤深度的增加而逐渐升高。解释铁结合有机碳变化的重要指标包括 TOC、颗粒有机碳 (POC)、游离铁氧化物 (Fed)、无定形铁氧化物 (Feo)、络合铁氧化物 (Fep)、Feo/Fed、pH 值、Ca、砂和淤泥。Feo/Fed 与铁结合 OC 呈强线性相关,因此可以很好地预测铁结合 OC 的含量。RDA 分析表明,Fe-bound OC/Fe-OC 与细菌门(包括变形菌、放线菌、绿霉菌和腐生菌)的相关性较近。结合铁的有机碳的分布与生物和非生物因素有一定的相关性。
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引用次数: 0
The occurrence of selected organic pollutants in the soils of the Songnen Plain, China 中国松嫩平原土壤中部分有机污染物的出现
IF 3.6 3区 农林科学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-07-29 DOI: 10.1007/s11368-024-03876-w
Yanan Chen, Yichen Zhang, Jiquan Zhang, Chenyang Wu, Lili, Qiuling Lang, Huanan Liu

Purpose

To protect and improve the soil environment of the Songnen Plain, detailed identification of organic pollutant contamination features in the soil and the degree of contamination is required. The primary goals of this research are to measure the levels of organic pollutants detected in the soil of the Songnen Plain, to correlate the levels of organic pollutants with different land use practices, and to assess the environmental quality of the soil using various pollution indicators.

Material and methods

Contaminated soil was collected at three types of areas: residential (n = 26), agricultural (n = 22), and industrial (n = 12) in the Songnen Plain of Jilin Province, at 0–20 cm and 20–40 cm depths. The concentrations of dichlorodiphenyltrichloroethane, benzene hexachloride, toluene, ethylbenzene, xylene, benzo (a) pyrene (BaP), trichloromethane, tetrachloromethane, hexachlorobenzene, and atrazine in the soil samples were determined using gas chromatography (GC), gas chromatograph-mass spectrometer-mass spectrometer (GC-MS-MS), and high-performance liquid chromatography (HPLC).

Results and discussion

Soil BaP had the highest concentration with a mean value of 20.59 ng/kg, followed by atrazine, hexachlorobenzene, benzene hexachloride, dichlorodiphenyltrichloroethane (DDT), trichloromethane, toluene, ethylbenzene, xylene, and tetrachloromethane with mean concentrations of 0.46, 0.44, 0.34, 0.28, 0.21, 0.14, 0.06, 0.03, and 0.02 ng/kg, respectively. Soil organic pollutants at all sampling sites did not exceed the secondary environmental quality standard values. The most serious soil contamination was found in landfill sites, followed by urban areas, industrial areas and farmland areas.

Conclusions

Soil contamination is more severe in locations where human activity is more prevalent. The subsoil can better reflect the characteristics of soil pollution in the area compared to the upper layer of soil. Although contamination is low in the research region, the presence of these pollutants must be taken seriously in order to maintain the quality and safety of agricultural products and human health.

目的为了保护和改善松嫩平原的土壤环境,需要详细查明土壤中有机污染物的污染特征和污染程度。本研究的主要目标是测定松嫩平原土壤中有机污染物的含量,将有机污染物的含量与不同的土地利用方式相关联,并利用各种污染指标评估土壤的环境质量。采用气相色谱法(GC)、气相色谱-质谱-质谱联用仪(GC-MS-MS)和高效液相色谱法(HPLC)测定了土壤样品中二氯二苯三氯乙烷、六氯化苯、甲苯、乙苯、二甲苯、苯并(a)芘(BaP)、三氯甲烷、四氯甲烷、六氯苯和阿特拉津的浓度。结果与讨论土壤中的苯并[a]芘浓度最高,平均值为 20.59 纳克/千克,其次是阿特拉津、六氯苯、六氯化苯、二氯二苯基三氯乙烷(DDT)、三氯甲烷、甲苯、乙苯、二甲苯和四氯甲烷,平均浓度分别为 0.46、0.44、0.34、0.28、0.21、0.14、0.06、0.03 和 0.02 纳克/千克。所有采样点的土壤有机污染物均未超过二级环境质量标准值。垃圾填埋场的土壤污染最为严重,其次是城市地区、工业区和农田地区。与上层土壤相比,底层土壤更能反映该地区的土壤污染特征。虽然研究区域的污染程度较低,但必须重视这些污染物的存在,以维护农产品的质量安全和人类健康。
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引用次数: 0
Evaluation of hazardous element accumulation in urban soils of Cracow, Lublin and Torun (Poland): pollution and ecological risk indices 克拉科夫、卢布林和托伦(波兰)城市土壤中有害元素积累的评估:污染和生态风险指数
IF 3.6 3区 农林科学 Q3 ENVIRONMENTAL SCIENCES Pub Date : 2024-07-27 DOI: 10.1007/s11368-024-03864-0
Andrzej Plak, Małgorzata Telecka, Przemysław Charzyński, Agnieszka Hanaka

Purpose

This study assesses how urban soil transformation affects pollution levels and ecological risks in Cracow, Lublin, and Torun using specific geochemical indices.

Methods

The surveyed cities, namely Cracow, Lublin and Torun, are among the oldest in Poland, with origins dating back to the Middle Ages. Moreover, they did not experience significant destruction during World War II. A total of 135 sampling points were selected from three cities, and topsoil samples (0–20 cm) were collected from various areas, including industrial, residential, recreational areas, wastelands, traffic routes, allotments, cultivated fields, forests and cemeteries (45 topsoil samples in each city). The concentration of 8 elements (As, Cd, Cu, Cr, Ni, Pb, Sb, Zn) was measured to determine pollution and ecological risk indicators, such as geoaccumulation index (Igeo), pollution load index (PLI), cancer risk (CR), and ecological risk assessment (ERi).

Results

Findings reveal significant differences among the cities, with Cracow showing the highest pollution and ecological risk levels, influenced primarily by industrial activities. Igeo above 3 was found for Sb (4% of the sample population), Cr (33%), Ni (31%), Cd, Pb, Cu, Zn (11%). In the other two cities, high Igeo values occurred sporadically with most values ranging from 0 to 2. The concentrations of Cd, Pb, Sb, Cr and Ni were found to be highest in industrial areas, transportation areas and urban wastelands, and the lowest in the study plots located in forests. In Cracow, almost 58% of the surveyed areas are polluted. Almost the entire area of Torun (87%) shows high values of summed ecological risk assessment (PERk). Lublin is characterized by the lowest ecological risk, almost 32% of the surveyed areas are polluted (PERk—high and very high).

Conclusions

The application of pollution and ecological risk indicators allowed for the identification of elevated heavy metal and metalloid concentrations in the studied soils and evaluation of disease risk in people. The data were strongly correlated with the level of anthropogenic pressure, which varied depending on the different land use.

目的 本研究使用特定的地球化学指数,评估城市土壤的变化如何影响克拉科夫、卢布林和托伦的污染水平和生态风险。方法 被调查的城市,即克拉科夫、卢布林和托伦,是波兰最古老的城市之一,其起源可追溯到中世纪。此外,它们在第二次世界大战期间也没有遭受严重破坏。三个城市共选取了 135 个采样点,并从不同区域采集了表土样本(0-20 厘米),包括工业区、住宅区、娱乐区、荒地、交通线路、分配区、耕地、森林和墓地(每个城市采集 45 个表土样本)。测量了 8 种元素(砷、镉、铜、铬、镍、铅、锑、锌)的浓度,以确定污染和生态风险指标,如地质累积指数 (Igeo)、污染负荷指数 (PLI)、癌症风险 (CR) 和生态风险评估 (ERi)。锑(占样本人口的 4%)、铬(33%)、镍(31%)、镉、铅、铜、锌(11%)的 Igeo 超过 3。镉、铅、锑、铬和镍的浓度在工业区、交通区和城市荒地中最高,而在位于森林中的研究地块中最低。在克拉科夫,近 58% 的调查区域受到污染。托伦几乎整个地区(87%)的生态风险评估总和 (PERk) 值都很高。卢布林的生态风险最低,近 32% 的调查区域受到污染(PERk 高和非常高)。这些数据与人为压力水平密切相关,而人为压力水平因不同的土地用途而异。
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引用次数: 0
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Journal of Soils and Sediments
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