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Effects of physicochemical characteristics on natural durability of eucalypts woods to wood-decaying fungi 理化特性对桉树木材对木材腐朽真菌的天然耐久性的影响
IF 2 4区 农林科学 Q2 Chemistry Pub Date : 2024-01-19 DOI: 10.1080/02773813.2024.2303405
Pedro Nicó de Medeiros Neto, Juarez Benigno Paes, Fabricio Gomes Gonçalves, Yonny Martínez López, Nédia Pereira Correia Mendes Correia, Renato Nogueira Antas
This study aimed to relate the biological resistance of seven eucalypt woods to wood-decaying fungi with physicochemical characteristics of wood. Two 12-year-old trees per species were randomly sam...
本研究旨在将七种桉树木材对木材腐朽真菌的生物抗性与木材的物理化学特征联系起来。每个树种随机抽样两棵树龄为 12 年的树。
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引用次数: 0
A zero-waste one step method to produce carboxy nanocellulose from the untreated barley and wheat straws 从未经处理的大麦和小麦秸秆中一步生产羧基纳米纤维素的零废弃方法
IF 2 4区 农林科学 Q2 Chemistry Pub Date : 2024-01-12 DOI: 10.1080/02773813.2024.2303038
Sanmitra Barman, Sambhunath Bera
A zero-waste simple method was developed to produce carboxy nanocellulose directly from the untreated barley and wheat straw by treating with nitric acid (55%) and sodium nitrite at 40 °C for 12 h....
通过使用硝酸(55%)和亚硝酸钠在 40 °C 下处理 12 h,开发出了一种零废弃的简单方法,可直接从未经处理的大麦和小麦秸秆中生产羧基纳米纤维素....。
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引用次数: 0
Acid-catalyzed Kraft lignin liquefaction for producing polyols and polyurethane foams 用于生产多元醇和聚氨酯泡沫的酸催化牛皮纸木质素液化技术
IF 2 4区 农林科学 Q2 Chemistry Pub Date : 2024-01-12 DOI: 10.1080/02773813.2024.2303036
K. T. Barbosa, Silvia Helena Fuentes Da Silva, Washington Luiz Esteves Magalhães, Sandro Campos Amico, Rafael de Avila Delucis
This study investigates the use of acid-catalyzed lignin liquefaction for the production of polyols and polyurethane foams. The liquefaction process was carried out using a kraft lignin powder foll...
本研究调查了利用酸催化木质素液化生产多元醇和聚氨酯泡沫的情况。液化过程使用的是牛皮纸木质素粉末。
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引用次数: 0
Micro-mechanism analysis of the influence of sawdust with different replacement ratio on concrete performances 不同替代率的锯末对混凝土性能影响的微观力学分析
IF 2 4区 农林科学 Q2 Chemistry Pub Date : 2024-01-08 DOI: 10.1080/02773813.2023.2299807
Te Li, Laire Tier
As a waste of wood processing, a large accumulation of sawdust will have an impact on the environment. In this paper, sawdust is added to concrete to explore the influence of sawdust on the perform...
锯末是木材加工过程中产生的废弃物,大量堆积会对环境造成影响。本文在混凝土中加入锯末,以探讨锯末对混凝土性能的影响。
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引用次数: 0
Anti-inflammatory, antioxidant, and antitermite valorization of extractable substances from the heartwood of four major species of the Gabonese forest-timber sectors 从加蓬森林木材部门四种主要树种的心材中提取的可提取物质的抗炎、抗氧化和防白蚁功效
IF 2 4区 农林科学 Q2 Chemistry Pub Date : 2023-12-22 DOI: 10.1080/02773813.2023.2293704
C. S. A. Bopenga Bopenga, L. Mengome, M.-A. N’negue ép Mezui-Mbeng, Hervise Harmand Ndinga, Edou Engonga Prosper
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引用次数: 0
Optimization of delignification depth of wood surfaces for skin polymer impregnation 皮肤聚合物浸渍木材表面脱木质素深度的优化
IF 2 4区 农林科学 Q2 Chemistry Pub Date : 2023-12-01 DOI: 10.1080/02773813.2023.2284157
Kyoung-Chan Park, Byeongho Kim, Hanna Park, Yesun Kim, Nam-Hun Kim, Se-Yeong Park
We controlled the degree of surface delignification of a wood specimen to impart functionality to its surface and injected a polymer into the porous structure to investigate using it as a functiona...
我们控制木材样品的表面脱木质素程度,以赋予其表面功能,并将聚合物注入多孔结构中,以研究将其用作功能材料。
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引用次数: 0
Development of wood preservatives to prevent biodeterioration 防止木材生物变质防腐剂的研制
IF 2 4区 农林科学 Q2 Chemistry Pub Date : 2023-11-25 DOI: 10.1080/02773813.2023.2284161
Himadri Rajput, Preethi Rajan, Shujun Li, Glenn W. Stratton, Gordon Murray, Quan (Sophia) He
Wood is a widely available material that has long been used in various applications. Protection of wood products from degradation due to biotic and abiotic factors is crucial. Traditional wood pres...
木材是一种广泛使用的材料,长期以来一直用于各种应用。保护木制品免受生物和非生物因素的降解是至关重要的。传统木压机…
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引用次数: 0
Increasing packaging grade kraft pulp yield by using sodium methyl mercaptide 甲基巯基钠提高包装级硫酸盐纸浆收率
4区 农林科学 Q2 Chemistry Pub Date : 2023-10-31 DOI: 10.1080/02773813.2023.2274091
Ravikant Patil, Adriaan van Heiningen
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引用次数: 0
Structure and property variations of mixed hardwood kraft lignins 混合硬木硫酸盐木质素的结构和性能变化
4区 农林科学 Q2 Chemistry Pub Date : 2023-10-04 DOI: 10.1080/02773813.2023.2262974
Xiao Jiang, Runkun Sun, Matthew Kollman, Hou-min Chang, Hasan Jameel
AbstractKraft lignin as an emerging renewable feedstock can be used to produce fuels, chemicals, and materials. Hardwood kraft lignin bears intrinsic variation due to wood species and the isolation process. The structure and property variation of hardwood kraft lignin could introduce new challenges and opportunities for its application. To better understand such variation, seven kraft lignin samples, originated from southern mixed hardwood (North America), northern mixed hardwood (North America), and Asian mixed hardwood, were isolated from commercial kraft pulping black liquor using both LignoBoost and LignoForce processes. Modern analytical techniques were used to elucidate the characteristics of mixed hardwood kraft lignins, including chemical composition, molecular weight, functional groups, and thermal properties. All lignin samples had a lignin content over 90% (92% to 96%) with one exception, which was northern mixed hardwood kraft lignin with 86% of lignin content and 6% polysaccharides. The elemental and methoxy analyses revealed the expected variation of hardwood kraft lignins with the methoxy content ranging from 0.85 to 1.20 per C9 unit. The weight average molecular weight exhibited a higher variation (from 4800 to 1895 Da) with a descending order of southern mixed hardwood kraft lignins, northern mixed hardwood lignins, and Asian mixed hardwood lignins. The aliphatic hydroxy groups ranged from 14 to 25 per 100 C9 units, and phenolic hydroxy groups ranged from 65 to 112 per 100 C9 units. The catecholic group content ranged from 12 to 34 per 100 C9 units, which is higher than softwood kraft lignin. The lignins isolated from the rapid displacement heating (RDH) pulping process were more condensed than from the regular kraft pulping process. 2D HSQC and quantitative 13C NMR revealed the drastic structure change upon kraft pulp with the low abundance of native lignin linkages and formation of new interunit linkages, such as stilbene, enol ethers, and 1-1’/5’. The S/G ratio was calculated using 2D HSQC spectra correcting for signal shift caused by the catecholic groups.Keywords: Mixed hardwoodkraft ligninchemical structurevariation Authors’ contributionsXiao Jiang and Runkun Sun contributed equally to this work.Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThe authors greatly appreciate the financial support from Domtar and Chung Hua Paper Company for this research project.
摘要硫酸盐木质素是一种新兴的可再生原料,可用于生产燃料、化学品和材料。硬木硫酸盐木质素因木材种类和分离过程的不同而发生内在变化。硬木硫酸盐木质素的结构和性能变化为其应用带来了新的挑战和机遇。为了更好地了解这种变化,使用LignoBoost和LignoForce工艺从商业硫酸盐制浆黑液中分离出7个硫酸盐木质素样品,分别来自南方混合硬木(北美)、北方混合硬木(北美)和亚洲混合硬木。采用现代分析技术对混合硬木硫酸盐木质素的化学组成、分子量、官能团和热性能等进行了研究。所有木质素样品的木质素含量都在90%以上(92% ~ 96%),只有一个例外,即北方混合硬木硫酸盐木质素,木质素含量为86%,多糖含量为6%。元素分析和甲氧基分析表明硬木硫酸盐木质素的预期变化,甲氧基含量为0.85 ~ 1.20 / C9单位。质量平均分子量变化较大(从4800 ~ 1895 Da),南方混合硬木硫酸盐木质素次之,北方混合硬木木质素次之,亚洲混合硬木木质素次之。脂肪羟基为14 ~ 25个/ 100个C9单位,酚羟基为65 ~ 112个/ 100个C9单位。每100 C9单位中儿茶酚群含量在12 ~ 34之间,高于软木硫酸盐木质素。从快速位移加热(RDH)制浆过程中分离的木质素比从常规硫酸盐制浆过程中分离的木质素更浓缩。二维HSQC和定量13C核磁共振显示,硫酸盐浆的结构发生了剧烈变化,天然木质素键丰度较低,并形成了新的单元间键,如苯乙烯、烯醇醚和1-1 ' /5 '。利用二维HSQC光谱校正由儿茶基团引起的信号移位计算S/G比。关键词:混合硬木,硫酸盐,木质素,化学结构变化作者的贡献蒋晓和孙润坤对这项工作也有同样的贡献。披露声明作者未报告潜在的利益冲突。作者非常感谢Domtar和中华纸业公司对本研究项目的资金支持。
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引用次数: 0
Preparation and characterization of plywood panels using recycled HDPE as a formaldehyde-free adhesive: A comparative study 利用再生HDPE作为无醛胶粘剂制备胶合板及其性能的比较研究
IF 2 4区 农林科学 Q2 Chemistry Pub Date : 2023-08-27 DOI: 10.1080/02773813.2023.2251463
A. Ashori, V. Heydari, N. Ayrilmiş
Abstract Formaldehyde-based resins such as urea-formaldehyde (UF) are the most widely used adhesives in the plywood industry. However, due to the concerns about formaldehyde toxicity, there is a need to develop formaldehyde-free adhesive materials. Therefore, the present study aimed to minimize or eliminate the harmful effects of UF resin by using recycled high-density polyethylene (HDPE) from post-consumed fruit packing boxes as a nontoxic adhesive. Three-layer plywood panels using poplar veneers and recycled HDPE films were prepared. UF was used as a control adhesive for the comparison. The influence of three variable parameters in terms of HDPE content (from 80 to 320 g/m2), hot-pressing temperature (from 140 to 180 °C), and pressing duration (from 3 to 8 min) on the properties of plywood panels were evaluated. For evaluation, physical properties, namely water absorption (WA), thickness swelling (TS), and mechanical properties, namely modulus of elasticity (MOE), modulus of rupture (MOR), and glue-line shear strength of the samples, were studied. The findings of this work confirmed that HDPE films gave the values of mechanical properties of plywood panels comparable to those obtained with UF adhesive, even though the adhesive content and pressing time were lower than when the UF adhesive was used. The obtained bonding strength values of HDPE-bonded plywood panels ranged from 0.82 to 1.60 MPa and met the requirement for the European Standard EN 314-2. According to FE-SEM micrographs, the fractured surface of plywood panels with 240 g/m2 of HDPE displayed a homogeneous cross-section area, and a large amount of HDPE was attached to the veneer surfaces. It was found that the average mechanical properties tended to increase with an increase in the pressing temperature and time. The type of adhesive had a significant effect on WA and TS. The smallest values of WA and TS were observed in plywood samples using high contents of HDPE films (240 and 320 g/m2). The optimum conditions were an HDPE loading of 240 g/m2, a hot-pressing temperature of 160 °C, and a hot-pressing time of 5 min. The overall results showed that recycled HDPE had enough potential to reuse as a promising adhesive for the environmentally-friendly plywood manufacturing.
摘要脲醛树脂是胶合板工业中应用最广泛的粘合剂。然而,由于对甲醛毒性的担忧,有必要开发无甲醛粘合剂材料。因此,本研究旨在通过使用食用后水果包装盒中回收的高密度聚乙烯(HDPE)作为无毒粘合剂,最大限度地减少或消除UF树脂的有害影响。采用杨木单板和再生HDPE膜制备了三层胶合板。使用UF作为对照粘合剂进行比较。三个可变参数对HDPE含量的影响(从80到320 g/m2),热压温度(从140到180 °C)和按压持续时间(从3到8 min)对胶合板性能的影响。为了评估,研究了样品的物理性能,即吸水性(WA)、厚度膨胀性(TS)和机械性能,即弹性模量(MOE)、断裂模量(MOR)和胶线剪切强度。这项工作的结果证实,HDPE膜的胶合板力学性能值与使用UF粘合剂获得的值相当,尽管粘合剂含量和压制时间低于使用UF胶粘剂时。获得的HDPE粘合胶合板面板的粘合强度值在0.82至1.60之间 MPa,并符合欧洲标准EN 314-2的要求。根据FE-SEM显微照片,240 g/m2的HDPE显示出均匀的横截面面积,并且大量的HDPE附着在单板表面上。研究发现,随着压制温度和压制时间的增加,平均力学性能有增加的趋势。粘合剂的类型对WA和TS有显著影响。在使用高含量HDPE膜(240和320)的胶合板样品中观察到WA和TS的最小值 g/m2)。最佳条件是HDPE负载量为240 g/m2,热压温度160 °C,热压时间为5 min.总体结果表明,再生HDPE具有足够的潜力,可作为一种有前途的粘合剂重新用于环保胶合板生产。
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Journal of Wood Chemistry and Technology
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