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PHASE ANALYSIS AND PHYSICAL PROPERTIES OF B2O3-ADDED ZIRCON CERAMICS SINTERED AT 1300 °C 1300℃烧结b2o3锆英陶瓷的物相分析及物理性能
Pub Date : 2021-12-20 DOI: 10.18860/neu.v14i1.12663
Fikriyatul Azizah Su'ud, S. Pratapa, M. Musyarofah
This study was aimed to know the effect of B2O3(boria) addition on the phase composition and physical properties of zircon ceramics.The raw zircon powder used in the study was a purified natural zircon sand from Kereng Pangi, Central Kalimantan, Indonesia. The zircon ceramics were prepared by a solid state reaction method with variation of B2O3 addition of 3 wt%, 6 wt% and 9 wt% and sintered at 1300 °C for 5h. The phase composition, density and microstructure were characterized using X-ray diffraction (XRD), densimeter and Scanning Electron Microscope (SEM), respectively. Vickers Hardness measurement was perfomed at the polished surface of the ceramics. Results showed that all samples contained pure zircon phase, i.e. there was no effect of B2O3 addition on the phase composition. In general, the density and hardness increased with increasing B2O3 addition, but addition up to 9 wt% is not optimum to achieve ultra-dense zircon ceramics. Furthermore, the SEM image also showed no significant difference in average grain size. The crystallite size has grown nearly eight times (325 nm) of its original powder. The Vickers hardness of the ceramics is not significantly influenced by the addition of boria. It appears that the boria failure to increase densification also results in the extent of contact between grains which then produces relatively large zircon grains.
本研究旨在了解B2O3(硼酸)的添加对锆英陶瓷的物相组成和物理性能的影响。研究中使用的原始锆石粉是来自印度尼西亚加里曼丹中部克伦邦吉的纯化天然锆石砂。采用B2O3添加量分别为3wt %、6wt %和9wt %的固相反应法制备了锆英陶瓷,并在1300℃下烧结5h。采用x射线衍射仪(XRD)、密度计和扫描电镜(SEM)对其相组成、密度和微观结构进行了表征。对抛光后的陶瓷表面进行了维氏硬度测量。结果表明,所有样品均含有纯锆石相,即B2O3的添加对相组成没有影响。总体而言,随着B2O3添加量的增加,锆英石陶瓷的密度和硬度均有所增加,但添加量高达9 wt%并不适合获得超致密的锆英石陶瓷。此外,SEM图像也显示平均晶粒尺寸没有显著差异。晶体尺寸比原来的粉末大了近8倍(325纳米)。硼砂的加入对陶瓷的维氏硬度影响不大。硼砂未能增加致密性也导致颗粒之间的接触程度,从而产生相对较大的锆石颗粒。
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引用次数: 0
CHARACTERIZATION OF CLAY MATERIALS USED FOR POTTERY PURPOSES FROM RENDENG, MALO, BOJONEGORO 仁登、马洛、波永尼哥罗制陶用粘土材料的表征
Pub Date : 2021-12-20 DOI: 10.18860/neu.v14i1.12753
Dyah Setyaningrum, Sujiat Sujiat, Aprilia Nur Azizah
Clay material from Rendeng, Malo, Bojonegoro was studied by mineralogy and physicochemical characterization to evaluate its potential suitability as a raw material in pottery application. X-ray Diffraction (XRD) and Fourier Transform-Infrared (FTIR) spectrometry were used to establish the mineralogy composition. Meanwhile the physical properties were identified by particle size distribution and consistency limits. Chemical composition was carried out by X-ray Fluorescence Spectrometer (XRF).  The results of XRD characterization revealed that clay from Rendeng Village, Malo, Bojonegoro contained  kaolin, quartz, and feldspar. Physical characterization shows that clay material is a less plastic type based on Atterberg method. Based on the chemical compositions indicated that SiO2, Al2O3, CaO, and Fe2O3 were abundance oxides. Therefore, clay from Desa Rendeng was only suitable for the pottery purposes because most of its mineral compositions did not meet the quality requirements for making advanced ceramics.
通过矿物学和物化学研究,对波戎涅戈罗地区仁登、马洛的粘土材料进行了研究,以评价其作为制陶原料的潜在适用性。采用x射线衍射(XRD)和傅里叶变换-红外(FTIR)光谱法确定了矿物组成。同时,通过粒径分布和稠度极限对其物理性质进行了表征。用x射线荧光光谱仪(XRF)测定了其化学成分。XRD表征结果表明,来自Malo, Bojonegoro的Rendeng Village粘土中含有高岭土、石英和长石。基于Atterberg方法的物性表征表明,粘土材料属于低塑性类型。化学成分分析表明,SiO2、Al2O3、CaO和Fe2O3为丰度氧化物。因此,德萨人登的粘土只适用于制陶,因为它的大部分矿物成分不符合制作高级陶瓷的质量要求。
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引用次数: 1
COMPARISON OF EFFICIENCY AND CARBON EMISSIONS OF FILAMENT ELECTRIC STOVES AND INDUCTION ELECTRIC STOVES 长丝电炉与感应电炉效率及碳排放比较
Pub Date : 2021-12-20 DOI: 10.18860/neu.v14i1.13008
Y. Tiandho, F. Afriani
Issues related to energy sustainability and carbon emission reduction are continuously being concerned by the Government of the Republic of Indonesia. Various efforts and programs have been launched to achieve targets of the related issues. As known that energy use for cooking by the household is continuously increasing in relation to population growth that will of course increase in energy need which relates to the sustainability of presence energy and carbon emission. Accordingly, the LPG stove conversion program to an electric stove was introduced in order to achieve the target to solve such issues. This paper compared of efficiency and carbon emissions of both electric filament stoves and induction stoves. The result indicated that the induction stove has better efficiency compared with the electric stove. The study also was proved that the carbon emissions for both types of stoves were relatively low in comparison with LPG stoves. However, the enormous operational power of the induction stove is still a challenge that must be resolved to achieve the target of energy sustainability in Indonesia.
印度尼西亚共和国政府继续关注与能源可持续性和减少碳排放有关的问题。为实现相关目标,开展了各种努力和方案。众所周知,家庭烹饪的能源使用量随着人口增长而不断增加,这当然会增加能源需求,这与能源和碳排放的可持续性有关。因此,为了实现解决上述问题的目标,引进了LPG炉转换为电炉的方案。本文对电丝炉和电磁炉的效率和碳排放进行了比较。结果表明,与电炉相比,感应炉具有更好的效率。研究还证明,与LPG炉相比,这两种炉的碳排放量都相对较低。然而,感应炉的巨大运行功率仍然是印度尼西亚实现能源可持续性目标必须解决的挑战。
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引用次数: 1
SOC (STATE of CHARGE) THREE-CELL LEAD DYNAMIC BATTERY MODEL SOC(充电状态)三芯铅动态电池模型
Pub Date : 2021-06-16 DOI: 10.18860/NEU.V13I2.11835
K. B. Pranata, Freygion Ogiek Rizal Sukma, M. Ghufron, Masruroh Masruroh
Three-cells dynamic lead-acid battery has been widely manufactured as the latest secondary battery technology. It is being carried out by 10 cycles of charge-discharge treatment with a various types of SoC, such as 100% (Full charge 5100 mAh), 50% (2550 mAh), 25% (1275 mAh) and discharge current of 0.8A. This experiment aims to analyze the treatment of SOC conditions on the performance of the lead-acid battery. The cyclicality test has performed using a Battery Management System (BMS) by applying an electric current at charging 1 A and discharging 0.8A. The results of the SOC charging conditions at 100%, 50%, 25% respectively gave a difference in the value of voltage efficiency of 84%, 87%, 88%, capacity efficiency values of 84%, 80%, 69%, energy efficiency values of 70%, 70%, 62%. The 100% and 50% SOC treatments showed better performance and battery energy the 25% SOC treatment. This research can be a recommendation to predict the performance of the lead-acid battery model during the charging and discharging process.
三芯动态铅酸电池作为一种最新的二次电池技术已得到广泛的应用。采用100%(充满5100毫安时)、50%(2550毫安时)、25%(1275毫安时)、放电电流为0.8A等不同类型的SoC进行10次循环充放电处理。本实验旨在分析处理荷电状态对铅酸电池性能的影响。循环性测试是使用电池管理系统(BMS)进行的,在充电1 a和放电0.8A时施加电流。结果表明,在100%、50%、25%充电条件下,电池的电压效率值分别为84%、87%、88%,容量效率值分别为84%、80%、69%,能量效率值分别为70%、70%、62%。100%和50%有机碳处理的性能和电池能量均优于25%有机碳处理。本研究可为预测铅酸电池模型在充放电过程中的性能提供参考。
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引用次数: 0
THE USE OF (Mg0.9Zn0.1)TiO3+2wt.% Bi2O3 CERAMICS AS A DIELECTRIC RESONATOR OSCILLATOR MATERIAL AND CHARACTERISATION OF STRUCTURE, MICROSTRUCTURE, AND DENSITY (Mg0.9Zn0.1)TiO3+2wt的使用。作为介电谐振振荡器材料的Bi2O3陶瓷及其结构、微观结构和密度的表征
Pub Date : 2021-06-16 DOI: 10.18860/NEU.V13I2.11720
Afandy Kadarosman, F. U. Ermawati
Magnesium titanate (MgTiO3)-based ceramics have the potential for use in the telecommunications industry at microwave frequencies, including as a resonator in dielectric resonator oscillator (DRO) circuit. This research is intended to study the application of (Mg0.9Z0.1)TiO3+2wt.% Bi2O3 (abbreviated MZT01-2) ceramics as DRO material and characterize the structure, microstructure, and bulk density. Fabrication was carried out by ball milling between (Mg0.9Z0.1)TiO3 crystalline powder and 2wt.% Bi2O3 powder. The milled powder was compacted at certain pressure using a die press to become pellets. All pellets were sintered at 1000, 1100, 1200C for 4 h to obtain ceramics. The structural characterization using XRD showed that the three ceramics contained the main MgTiO3 phase, each 93.63, 93.83, and 90.78% molar, the rest was the MgTi2O5 phase. The increase in sinter temperature causes the lattice parameter and the unit cell volume to decrease. The Archimedes bulk density was 2.928; 2.832 and 2.736 g/cm. The microstructure is solid surfaces with a grain diameter of 1.9-2.3 μm accompanied by pores. As DRO materials, the three ceramics exhibited a resonant frequency at 5.11, 5.08, and 5.12 GHz which shows that the ceramics can be applied as DRO materials at microwave frequencies. The sinter temperature variation tends not to affect the resonant frequency position.
钛酸镁(MgTiO3)基陶瓷具有在微波频率下用于电信工业的潜力,包括作为介电谐振振荡器(DRO)电路中的谐振器。本研究旨在研究(Mg0.9Z0.1)TiO3+2wt的应用。% Bi2O3(简称MZT01-2)陶瓷作为DRO材料,并表征了结构,微观结构和堆积密度。采用球磨法制备(Mg0.9Z0.1)TiO3结晶粉末和2wt。% Bi2O3粉末。研磨后的粉末在一定压力下使用压模机压实成为颗粒。所有球团在1000、1100、1200℃下烧结4 h,得到陶瓷。XRD结构表征表明,三种陶瓷均以MgTiO3相为主,摩尔数分别为93.63、93.83和90.78%,其余为MgTi2O5相。烧结温度的升高使晶格参数和晶胞体积减小。阿基米德容重为2.928;2.832和2.736克/厘米。显微组织为晶粒直径为1.9 ~ 2.3 μm的固体表面,并伴有气孔。作为DRO材料,三种陶瓷的谐振频率分别为5.11、5.08和5.12 GHz,表明陶瓷可以作为微波频率的DRO材料。烧结温度的变化往往不影响谐振频率的位置。
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引用次数: 3
THE EFFECT OF PH AND CALCINATION TEMPERATURE ON THE ZrO2 PHASE FORMATION FROM NATURAL ZIRCON SAND OF KERENG PANGI 研究了PH和煅烧温度对克楞攀基天然锆石砂形成ZrO2相的影响
Pub Date : 2021-06-16 DOI: 10.18860/NEU.V13I2.10507
Mohammad Abdullah, T. Triwikantoro, Chairatul Umamah, H. Andi
In this research ZrO 2 has been synthesized from Kereng Pangi zircon sand in Central Kalimantan through alkali fusion-coprecipitation method. Firstly, zircon sand (ZrSiO 4 ) was purified to reduce impurities by magnetic separation, cleaned using an ultrasonic cleaner, soaked/leached with HCl 2 M for 12 hours and leached with HCl at 60 oC for 3 hours. Secondly, alkali fusion was done with KOH as an alkali. This product was then washed by water and dried before leached with HCl 30% at 90 oC for 30 minutes to precipitate and seperate Silica from Zircon. ZrO 2 filtrate (ZrOCl 2 ) precipitated with NH 4 OH at pH 4, pH 7, and pH 10 forms Zr(OH) 4 gel. Zr(OH) 4 gel was dried and characterized by DTA-TGA, which was then followed by calcination based on DTA TGA results at temperature ranges of 550 oC - 700 oC to produce ZrO 2 . XRD results show that single tetragonal phase of ZrO 2 is formed in all variations of pH precipitation and calcination temperature. An analysis using MAUD software show that crystal size reduces as the increase in precipitation of pH. The crystal size results are 110 nm, 66 nm and 48 nm at pH 4, pH 7 dan pH 10 at 700 oC, respectively. Moreover, XRF results show that ZrO 2  with purity is at around 95.8 % at pH 4 and 96.3 % at pH 7 and pH 10.
本研究以加里曼丹中部克钦邦吉锆石砂为原料,采用碱熔共沉淀法合成了氧化锆。首先对锆英砂(zrsio4)进行磁选提纯,减少杂质,超声波清洗机清洗,HCl 2m浸泡/浸出12小时,HCl 60℃浸出3小时。其次,以KOH为碱进行碱熔。然后用水冲洗干燥,再用30%盐酸在90℃下浸出30分钟,沉淀分离出锆石。ZrO - 2滤液(ZrOCl - 2)在pH 4、pH 7和pH 10下与nh4 OH沉淀形成Zr(OH) 4凝胶。对Zr(OH) 4凝胶进行干燥和DTA-TGA表征,然后根据DTA-TGA结果在550℃~ 700℃范围内进行煅烧,制得ZrO 2。XRD结果表明,在不同的pH沉淀和煅烧温度下,zro2均形成单一的四方相。MAUD软件分析表明,随着pH沉淀的增加,晶体尺寸减小。在700℃下,pH 4、pH 7和pH 10的结晶尺寸分别为110 nm、66 nm和48 nm。XRF结果表明,在ph4和ph7、ph10条件下,氧化锆的纯度分别为95.8%和96.3%。
{"title":"THE EFFECT OF PH AND CALCINATION TEMPERATURE ON THE ZrO2 PHASE FORMATION FROM NATURAL ZIRCON SAND OF KERENG PANGI","authors":"Mohammad Abdullah, T. Triwikantoro, Chairatul Umamah, H. Andi","doi":"10.18860/NEU.V13I2.10507","DOIUrl":"https://doi.org/10.18860/NEU.V13I2.10507","url":null,"abstract":"In this research ZrO 2 has been synthesized from Kereng Pangi zircon sand in Central Kalimantan through alkali fusion-coprecipitation method. Firstly, zircon sand (ZrSiO 4 ) was purified to reduce impurities by magnetic separation, cleaned using an ultrasonic cleaner, soaked/leached with HCl 2 M for 12 hours and leached with HCl at 60 oC for 3 hours. Secondly, alkali fusion was done with KOH as an alkali. This product was then washed by water and dried before leached with HCl 30% at 90 oC for 30 minutes to precipitate and seperate Silica from Zircon. ZrO 2 filtrate (ZrOCl 2 ) precipitated with NH 4 OH at pH 4, pH 7, and pH 10 forms Zr(OH) 4 gel. Zr(OH) 4 gel was dried and characterized by DTA-TGA, which was then followed by calcination based on DTA TGA results at temperature ranges of 550 oC - 700 oC to produce ZrO 2 . XRD results show that single tetragonal phase of ZrO 2 is formed in all variations of pH precipitation and calcination temperature. An analysis using MAUD software show that crystal size reduces as the increase in precipitation of pH. The crystal size results are 110 nm, 66 nm and 48 nm at pH 4, pH 7 dan pH 10 at 700 oC, respectively. Moreover, XRF results show that ZrO 2  with purity is at around 95.8 % at pH 4 and 96.3 % at pH 7 and pH 10.","PeriodicalId":17685,"journal":{"name":"Jurnal Neutrino","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78887972","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Back Matter 回到问题
Pub Date : 2021-06-16 DOI: 10.18860/neu.v13i2.12585
Kusairi S.Si
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引用次数: 0
DESIGN AND BUILD OF AUTOMATIC WASTAFEL USING ULTRASOUND HC-SR04 SENSOR BASED ON ARDUINO 基于arduino的超声波hc-sr04传感器自动废物处理系统的设计与构建
Pub Date : 2021-06-16 DOI: 10.18860/NEU.V13I2.11664
Henry Prasetyo, Mohammad Rofi’i, Septiana Kurniasari, Muhammad Wisnu Pamungkas
The lack of public concern for washing hands during the Covid-19 pandemic, the authors designed an automatic sink using an arduino-based HC-SR04 ultrasound sensor to attract the public's interest. By making automatic sink technology using the HC-SR04 ultrasound sensor based on Arduino for use in hand washing by the community. This study uses experimental research that examines the effect of automatic washbasin with people's behavior in washing hands. By testing the use of water in 20 seconds, 43 people can use it in one day, and soap can be used by 6 people in one day in 5 seconds. The automatic sink using the HC-SR04 ultrasound sensor based arduino can be used with a distance that is made less than 15cm designed to be practical and sterile because it is used that does not touch faucets or soap. The conclusion of the study is that if there is an object that approaches the ultrasound sensor within a distance of less than 15cm, the water pump will be active for 20 seconds or the soap pump for 5 seconds will automatically come out. And it will run out if used for 934 seconds in 1 liter gallon or 46 people a day and the use of soap for 5 seconds will run out approximately 6 people in one day.
在新冠肺炎大流行期间,公众对洗手缺乏关注,作者使用基于arduino的HC-SR04超声传感器设计了一种自动洗手池,以吸引公众的兴趣。通过采用基于Arduino的HC-SR04超声传感器制作自动洗手池技术,供社区使用。本研究采用实验研究的方法,考察自动洗脸盆对人们洗手行为的影响。通过20秒的用水测试,一天可以用43个人,5秒可以用6个人。使用基于arduino的HC-SR04超声波传感器的自动水槽可以在小于15cm的距离内使用,因为它不接触水龙头或肥皂,因此设计实用且无菌。研究的结论是,如果在小于15cm的距离内有物体接近超声波传感器,水泵将活动20秒或肥皂泵将自动出现5秒。1升加仑用934秒就会用完,或者一天46个人用完肥皂用5秒就会用完大约6个人一天用完。
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引用次数: 0
CROSS SECTION OF ELECTRON ANTINEUTRINO INTERACTION WITH 40AR AND 84KR AND ITS RELEVANCE TO GEONEUTRINO DETECTION 电子反中微子与40ar和84kr相互作用的截面及其与地球中微子探测的相关性
Pub Date : 2021-02-02 DOI: 10.18860/NEU.V13I1.10602
Akmal Ferdiyan, U. N. Prabowo
Neutrino can carry information from places that cannot be reached by the usual detection mechanism because it has a very weak interaction with matter. This can be utilized to study the heat flow process inside the earth by using information carried by geoneutrino (electron antineutrino). In this sense, it is important to know the characteristics of neutrino interaction with materials. In this study, the cross-section calculation of the electron antineutrino interaction with Ar-40 and Kr-84 was carried out using computational methods with the help of GENIE software. In the energy range of 0-10 MeV, the dominant interaction between the two materials is the interaction of QES NC and MEC types with an energy threshold of 5,09 MeV. Both Ar-40 and Kr-84 cannot be used as a scintillator material for geoneutrino detection because in the energy range 0-4,4 MeV the cross-sectional value of the CC interaction  is 0.
中微子可以从通常的探测机制无法到达的地方携带信息,因为它与物质的相互作用非常弱。这可以利用地球中微子(电子反中微子)携带的信息来研究地球内部的热流过程。从这个意义上说,了解中微子与材料相互作用的特性是很重要的。本研究在GENIE软件的帮助下,利用计算方法进行了电子反中微子与Ar-40和Kr-84相互作用的截面计算。在0-10 MeV的能量范围内,两种材料之间的主要相互作用是QES NC和MEC类型的相互作用,其能量阈值为5,09 MeV。Ar-40和Kr-84都不能作为地球中微子探测的闪烁体材料,因为在0-4,4 MeV能量范围内,CC相互作用的横截面值为0。
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引用次数: 0
A SIMPLE SYNTHESIS OF NICKEL OXIDE NANOTUBE USING HIGH VOLTAGE ELECTROLYSIS 高压电解法合成氧化镍纳米管
Pub Date : 2021-02-02 DOI: 10.18860/NEU.V13I1.10224
Y. Pramana, B. Setiawan, Prihono Prihono, Yitno Utomo, M. Subandowo, K. Budipramana
Recently, the development of nanoparticle nickel oxide has increased due to their potential application such as biosensors, catalysts, solar cells, supercapacitors, and batteries. In this work, the addition of CTAB for nickel oxide nanoparticle synthesis using electrolysis was investigated.  The nickel plates were used as anode and cathode in the electrolysis process. The process was operated at a constant voltage of 60 V for 30 minutes. The XRD result showed conformity with the Nickel oxide diffraction pattern. Meanwhile, the impurity from nickel hydroxide peaks still appeared. From FTIR characterization also indicates the band of Ni-O stretching vibration. The morphology characterization of nickel oxide using Scanning Electron Microscopy (SEM) showed the nanotube structure, while Transmission Electron Microscopy showed the nanoparticle size from 250.44 to 325.60 nm in length. On the other hand, the transformation of Ni(OH) 2 to NiO has been shown using TGA characterization.
近年来,纳米颗粒氧化镍因其在生物传感器、催化剂、太阳能电池、超级电容器和电池等方面的潜在应用而得到了越来越多的发展。本文研究了在电解条件下添加CTAB合成氧化镍纳米颗粒。在电解过程中,镍板分别作为阳极和阴极。该工艺在60 V恒定电压下运行30分钟。XRD结果与氧化镍的衍射图一致。同时,来自氢氧化镍的杂质峰仍然出现。FTIR表征还表明了Ni-O的伸缩振动带。扫描电镜(SEM)表征氧化镍的形貌为纳米管结构,透射电镜(tem)表征氧化镍的纳米颗粒长度为250.44 ~ 325.60 nm。另一方面,利用热重分析仪表征了Ni(OH) 2向NiO的转变。
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引用次数: 2
期刊
Jurnal Neutrino
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