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Properties of gypsum particleboard with added mineral dolomite 添加矿物白云石的石膏刨花板性能
IF 1.5 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2022-05-01 DOI: 10.4067/s0718-221x2022000100428
O. Yalcin, A. Kaya
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引用次数: 0
Colorimetría y densitometría en madera de Guazuma crinita Guazuma crinita木材的比色法和密度法
IF 1.5 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2022-05-01 DOI: 10.4067/s0718-221x2022000100432
Manuel Chavesta, R. Montenegro, J. Romero, Mario Tomazello-Filho, M. Carneiro, Silvana Nisgoski
In the present work, the colorimetric parameters were determined using the CIELAB system and the apparent density by X-ray densitometry in Guazuma crinita Mart. wood to obtain information of its quality in use as solid or transformed wood. The evaluation was carried out in three levels of the axial axis (base, medium, apical) of one plantation of 5 and 8 years old, in Puerto Inca, department of Huánuco, Peru. It was found that in both ages, according to CIElab system, the wood is of homogeneous coloration and is classified as greyish pink. The apparent density measured by X ray densitometry in the pith – bark direction was found to be 520 kg/m 3 and 560 kg/m 3 for 5 and 8 years, respectively; with higher values at the basal level (5 years old: 650 kg/m 3 ; 8 years old: 680 kg/m 3 ) and lower towards the apical part (5 years old: 430 kg/m 3 ; 8 years old: 470 kg/ m 3 ). The densitometric profiles showed, in general, that there is an increase in apparent density radially in the pith-bark direction. The 5-year-old wood density was more uniform than the 8-year-old one with a uniformity index of 149,7 and 170,3, respectively.
本文用CIELAB系统测定了瓜麻的比色参数,并用x射线密度法测定了瓜麻的表观密度。木材,以获得其在实木或变形木材中使用的质量信息。在秘鲁Huánuco省的印加港一个5岁和8岁的种植园的三个轴向水平(基部、中端、顶端)进行了评价。根据CIElab系统,在这两个时代,木材的颜色都是均匀的,被归类为灰粉色。X射线密度测定仪测得5年和8年的树髓-树皮方向表观密度分别为520 kg/ m3和560 kg/ m3;基础水平较高(5岁:650 kg/ m3;8岁:680公斤/平方米3)和更低的顶部部分(5岁:430公斤/平方米3;8岁:470公斤/米3)。密度剖面总体上显示,在髓皮方向上,表观密度呈径向增加。5年生木密度比8年生木密度均匀,均匀指数分别为149、7和170、3。
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引用次数: 0
Formaldehyde free tannin-based adhesive with epoxy as hardener for plywood 以环氧树脂为胶合板硬化剂的无甲醛单宁基胶粘剂
IF 1.5 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2022-05-01 DOI: 10.4067/s0718-221x2022000100433
Bowen Liu, Yunxia Zhou, H. Essawy, Qian Chen, Jiankun Liang, Xiaojian Zhou, Jun Zhang, G. Du
A renewable tannin-based resin adhesive with enhanced bonding strength, good water resistance and long storage life has been prepared based on tannin, furfural and furfuryl alcohol coming from forest and agricultural products. Fourier transform infrared spectroscopy (FT-IR), Electrospray ionization mass spectroscopy (ESI-MS) and Differential scanning calorimetry (DSC) indicated that furfuryl alcohol and furfural can react with tannin under acidic conditions, with the involvement of -CH 2 -O- groups in the cross-linking of tannin-furfuryl alcohol-furfural resin (TFF) adhesive. The gel time of TFF was longer than that of tannin-fur-fural resin (TF), while the shear strength of TFF-bonded plywood suggested that the cured TFF adhesive acquired a performance superior to that of tannin
以林产和农产品中的单宁、糠醛和糠醇为原料,制备了一种粘接强度高、耐水性好、贮存寿命长的可再生单宁基树脂胶粘剂。傅里叶变换红外光谱(FT-IR)、电喷雾电离质谱(ESI-MS)和差示扫描量热法(DSC)表明,在酸性条件下,糠醇和糠醛与单宁发生反应,- ch 2 - o -基团参与了单宁-糠醇-糠醛树脂(TFF)胶粘剂的交联反应。TFF的凝胶时间比单宁-糠醛树脂(TF)的凝胶时间长,而TFF与胶合板的剪切强度表明,固化后的TFF胶粘剂的性能优于单宁树脂
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引用次数: 1
Effect of the thermal treatment on the chemical components, sorption, and shrinkage properties of Tectona grandis juvenile wood 热处理对大构造木幼木化学成分、吸附和收缩性能的影响
IF 1.5 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2022-04-01 DOI: 10.4067/s0718-221x2022000100418
Juliana de Oliveira Lopes, Rosilei A. Garcia, C. B. Cáceres, R. Hernández
The effect of thermal treatment on the chemical components, equilibrium moisture content (EMC), and shrinkage of teak juvenile wood was studied. Heartwood and sapwood samples were thermally-treated at 180 º C and 200 º C. Extractive, Klason lignin, holocellulose, and α -cellulose contents, as well as pH on untreated and thermally-treated woods, were determined. The EMC was reached at five relative humidity (RH) levels using saturated salt solutions: 86 % (KCl), 76 % (NaCl), 58 % (NaBr), 33 % (MgCl 2 ), and 0 % (P 2 O 5 ). Linear and volumetric shrinkages were calculated for all EMCs. The ratio of sorption (S), coefficient of shrinkage ( h ), and fiber saturation point (FSP) were also determined. Thermally-treated wood exhibited lower holocellulose and α -cellulose contents than untreated wood and increased acidity due to degradation of the hemicelluloses. The thermal treatment reduced the EMC of heartwood and sapwood. However, sapwood was more sensitive to RH variations than heartwood regardless of the treatment. Thermally-treated woods had higher hygroscopic and dimensional stabilities, and lower FSP than untreated wood. The thermal treatment did not affect radial shrinkage of the heartwood between 33 % and 86 % RH. Heartwood was more sensitive to the effect of the thermal treatment on shrinkage and degradation of cell wall polymers compared to sapwood.
研究了热处理对柚木幼木化学成分、平衡含水率和收缩率的影响。心材和边材样品分别在180℃和200℃下进行热处理,测定未处理和热处理木材的萃取物、木质素、纤维素和α -纤维素含量以及pH值。用饱和盐溶液在相对湿度(RH)为86% (KCl)、76% (NaCl)、58% (NaBr)、33% (MgCl 2)和0% (p2o 5)的条件下达到电磁兼容。计算了所有EMCs的线性和体积收缩。测定了吸附比(S)、收缩系数(h)和纤维饱和点(FSP)。热处理木材的纤维素和α -纤维素含量低于未经处理的木材,由于半纤维素的降解,木材的酸度增加。热处理降低了心材和边材的电磁兼容系数。但无论处理方式如何,边材对RH变化的敏感性均高于心材。热处理木材具有较高的吸湿性和尺寸稳定性,FSP低于未经处理的木材。在相对湿度为33% ~ 86%之间,热处理对心材的径向收缩率没有影响。与边材相比,心材对热处理对细胞壁聚合物收缩和降解的影响更为敏感。
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引用次数: 2
Evolución del color y de la aparición de defectos en la madera de Eucalyptus globulus expuesta a intemperismo natural 蓝桉木材在自然风化条件下的颜色演变和缺陷的出现
IF 1.5 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2022-04-01 DOI: 10.4067/s0718-221x2022000100426
Karen Gabriela Moreno, E. Spavento, S. Monteoliva
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引用次数: 1
The effects of bioincising by Physisporinus vitreus on cuo retention and copper element leaching in oriental spruce wood 玻璃体物理孢子菌生物切割对东方云杉木材铜潴留和铜元素浸出的影响
IF 1.5 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2022-04-01 DOI: 10.4067/s0718-221x2022000100427
Davut Bakir, S. Kartal, E. Terzi, A. Doğu
Since the treatability of Oriental spruce wood (Picea orientalis) with preservative solutions is difficult and considered as a refractory wood species, this study was intended to bring its treatability class by a bioincising process to the level of sapwood of Scots pine (Pinus sylvestris), a desirable wood species for the forest products industry. Bioincising process by Physisporinus vitreus fungus was applied to wood samples from sapwood and heartwood portions of spruce wood. The samples with two different weight loss groups (5-10 % and 10-15 %) in the bioincising process were used to detect changes in treatability with wood preservative solutions caused by the fungus. The bioincised and unincised control samples were treated with either micronized copper quat (MCQ) or alkaline copper quat type D (ACQ-D) wood preservative solutions by either dipping or vacuum methods. Following impregnation with the preservative solutions, the effects of the bioincising process on CuO (copper oxide) retention, and the leaching of Cu (copper) element were determined. The results showed that CuO retention levels increased after the bioincising process. Moreover, there was greater CuO retention in the spruce heartwood samples compared to the spruce and Scots pine sapwood samples. Amount of Cu element released from the Scots pine sapwood samples was found to be lower than that from the spruce sapwood and heartwood samples after the bioincising. process. The results suggest that the bioincising process by P. vitreus in refractory wood species might improve the treatability of wood by Cu-based wood preservatives.
由于东方云杉木材(Picea orientalis)很难用防腐剂处理,并且被认为是一种耐火木材,因此本研究旨在通过生物切割工艺将其处理等级提高到苏格兰松(Pinus sylvestris)的水平,苏格兰松是林产品工业所需的木材物种。采用玻璃体物理孢子菌对云杉边材和心材进行了生物切割。在生物切割过程中,两个不同失重组(5- 10%和10- 15%)的样品被用来检测真菌引起的木材防腐溶液的可加工性变化。将生物切割和未切割的对照样品分别用微粉铜quat (MCQ)或碱性铜quat D型(ACQ-D)木材防腐剂溶液浸泡或真空处理。在防腐液浸渍后,测定了生物切割工艺对CuO(氧化铜)保留和Cu(铜)元素浸出的影响。结果表明,经过生物刻蚀处理后,CuO滞留量增加。此外,与云杉和苏格兰松边材样品相比,云杉心材样品中的CuO滞留量更大。经生物切割处理后,杉松边材样品中Cu元素的释放量低于云杉边材和心材样品。的过程。结果表明,玻璃体假单胞菌在耐火木材中的生物切割过程可能会提高铜基木材防腐剂对木材的处理能力。
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引用次数: 1
Changes in the content and composition of the extractives in thermally modified tropical hardwoods 热改性热带硬木中提取物含量和成分的变化
IF 1.5 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2022-04-01 DOI: 10.4067/s0718-221x2022000100422
B. Esteves, Umit Ayata, L. Cruz-Lopes, I. Brás, J. Ferreira, I. Domingos
Chemical composition of wood is known to change during thermal treatments. Two species grown in Turkey, afrormosia ( Pericopsis elata ) and duka ( Tapirira guianensis ) were heat treated according to Thermowood® method. Lignin, cellulose, hemicelluloses and extractives in dichloromethane, ethanol and water were determined. Wood extracts were analysed by gas chromatography with mass detection and existing compounds were identified by NIST17 database. Results show that hemicelluloses and cellulose content decreased for both heat-treated woods along the treatment while lignin percentage increased. The analysis of extractives has shown several compounds normally associated to lignin thermal degradation that increased along the treatment. At the same time several compounds associated to carbohydrate thermal degradation were found in all the extracts for both heat-treated woods. These founding have allowed the understanding of the degradation pattern of wood during thermal modification. There was not much difference between afrormosia and duka woods structural compounds behaviour along thermal modification. However, the variation of the amount of extractives along the treatment depended on the species. due to water and ethanol extractives. While the extractives increased along the treatment for afrormosia, in duka wood there was an initial increase followed by a decrease with the increase of heating time, which was probably due to the high amount of initial ethanol extractives in duka wood that are degraded along the treatment. The new formed compounds that increased along the thermal modification found in dichloromethane extract are vanillin, syringaldehyde, vanilic acid and syringic acid. For the most severe treatment (2 h), coniferaldehyde, sinapaldehyde and acetovanillone were also detected. All these compounds have been associated to lignin heat degradation showing that although the percentage increases, there is still some lignin thermal degradation. The compounds identified as resulting from lignin degradation in dichloromethane extracts still represent a significant amount in ethanol extracts of both heat-treated woods. Additionally, several other compounds like hydroxy acids, deoxy-pentonic acids, deoxy-hexonic acids γ-lactone and levoglucosan were found in ethanol extract. On heat-treated duka some carbohydrates were also found. All these compounds have been associated to C5 and C6 carbohydrate thermal decomposition. The results have contributed to the understanding of the chemical degradation path of modified wood by monitoring extractive content transfor mations and have shown the importance of optimizing the treatment for each wood species in order to make the best utilization of this material.
众所周知,木材的化学成分在热处理过程中会发生变化。根据Thermowood®方法,对生长在土耳其的两种植物,afrormosia (periopsis elata)和duka (Tapirira guianensis)进行热处理。测定了木质素、纤维素、半纤维素和萃取物在二氯甲烷、乙醇和水中的含量。采用气相色谱质谱法对木材提取物进行分析,通过NIST17数据库对化合物进行鉴定。结果表明,两种热处理木材的半纤维素和纤维素含量随处理时间的增加而降低,木质素含量随处理时间的增加而增加。对萃取物的分析表明,几种通常与木质素热降解有关的化合物随着处理而增加。同时,在两种热处理木材的所有提取物中都发现了与碳水化合物热降解有关的几种化合物。这些发现使我们能够理解木材在热改性过程中的降解模式。在热改性过程中,非洲木和杜卡木结构化合物的性能没有太大差异。然而,随着处理的进行,提取物的量的变化取决于物种。由于水和乙醇的萃取。随着黑霉处理的进行,提取物的含量逐渐增加,但随着加热时间的增加,杜卡木材的提取物含量先增加后减少,这可能是由于杜卡木材中大量的初始乙醇提取物在处理过程中降解所致。在二氯甲烷萃取物中发现了随着热改性而增加的新形成的化合物有香兰素、丁香醛、香草酸和丁香酸。在最严重处理(2 h)时,还检测到松柏醛、sinap醛和乙酰香草酮。所有这些化合物都与木质素热降解有关,表明尽管百分比增加,但仍有一些木质素热降解。经鉴定为由二氯甲烷提取物中木质素降解产生的化合物在两种热处理木材的乙醇提取物中仍然具有显著的量。此外,在乙醇提取物中还发现了其他几种化合物,如羟基酸、脱氧戊酸、脱氧己酸γ-内酯和左旋葡聚糖。在热处理过的杜卡上也发现了一些碳水化合物。所有这些化合物都与C5和C6碳水化合物的热分解有关。这些结果有助于通过监测提取物含量的变化来了解改性木材的化学降解途径,并表明了优化每种木材的处理以最大限度地利用这种材料的重要性。
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引用次数: 6
Evaluation and comparison of control and heat treated L-shape furniture joints produced from Scotch pine and ash wood under static bending and cyclic fatigue bending loadings 静态弯曲和循环疲劳弯曲载荷下苏格兰松和灰木控制和热处理l形家具接头的评价和比较
IF 1.5 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2022-04-01 DOI: 10.4067/s0718-221x2022000100420
Samet Demirel, Ruveyda Sen Er
This study investigated how the mechanical properties of L-shape joints produced from heat treated Scotch pine or ash wood behaved under cyclic fatigue loading and compared this with the mechanical properties of non-heat treated wood materials. Additionally, static bending performances of the L-shape of joints were investigated and compared to fatigue bending performance of same type of joints. Results indicated that increasing number of staple from 6 to 8 and density generally increased static bending of L-shape joints. Static bending resistance of L-shape joints produced from control Ash wood significantly higher than those of L-shape joints produced from heat treated Ash wood while no significant difference were observed between static bending resistance L-shape joints produced from control Scotch pine and L-shape joints produced from heat treated Scotch pine wood. The fatigue bending resistances of L-shape joints produced from heat treated samples generally passed and failed the same loading steps with those produced from control samples which means both L-shape joints could be used in same service area. L-shape joints under static and fatigue loadings mostly indicated staple leg shear mode. The one under fatigue loading was more than the one under static loading. Additionally, some joints under fatigue loading indicated staple rupture. The overall ratio of static bending loading to cyclic fatigue bending loading for L-shape joints was obtained as 2.85.
本研究研究了由热处理苏格兰松或白蜡木制成的l形接头在循环疲劳载荷下的力学性能,并将其与未经热处理的木材材料的力学性能进行了比较。此外,还研究了l型接头的静态弯曲性能,并与同类型接头的疲劳弯曲性能进行了比较。结果表明,短纤维数量从6根增加到8根,密度增加,l型关节的静态弯曲度普遍增加。对照灰分木生产的l型接头的静态抗弯性能显著高于热处理灰分木生产的l型接头,而对照苏格兰松生产的l型接头与热处理苏格兰松生产的l型接头的静态抗弯性能无显著差异。热处理后的l型接头的疲劳弯曲性能与对照试样的疲劳弯曲性能大体符合或不符合相同的加载步骤,这意味着两种l型接头可以在同一服务区域使用。静态和疲劳载荷作用下的l型节点多表现为短肢剪切模式。疲劳载荷作用下的应力大于静载荷作用下的应力。在疲劳载荷作用下,部分关节出现短钉断裂。l型节点的静态弯曲载荷与循环疲劳弯曲载荷的总比值为2.85。
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引用次数: 2
Application of a strain gauge to assess drying stresses in normal and tension wood of Corymbia citriodora 应用应变计评估柠檬茅正常木材和拉伸木材的干燥应力
IF 1.5 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2022-04-01 DOI: 10.4067/s0718-221x2022000100421
José Yony Cricel Sima Sánchez, José Tarcísio Lima, J. R. Moreira da Silva, B. C. Soares
The quantitative evaluation of longitudinal drying strain can provide relevant information for the processing wood and lumber industry, especially with regard to reaction wood in Corymbia , since little has been published. The objective of this work was to evaluate the effect of the steam conditioning and the cooling on the longitudinal drying strain ( LDS ) obtained from a strain gauge, called extensometer, in boards of both normal and tension wood of Corymbia citriodora . Lumbers 30 mm thick were produced and kiln dried at the initial temperature of 40°C, final temperature of 65°C and drying potential of 2,1. The LDS were measured before and after steam conditioning on hot and cold lumbers. It was observed that the conditioning did not reduce the LDS . Hot lumbers showed higher LDS values than the cold lumbers. The LDS values measured in normal, tension and opposite woods were statistically similar, indicating that the type of wood was not an influential factor in the appearance of longitudinal drying stresses. Extensometer proved to be feasible for measuring LDS , allowing its easy and quick quantification.
纵向干燥应变的定量评价可以为加工木材和木材工业提供相关信息,特别是关于Corymbia的反应木材,因为很少发表。本研究的目的是评估蒸汽调节和冷却对从应变计获得的纵向干燥应变(LDS)的影响,该应变计被称为伸长计,在柠檬木的正常和拉伸板中。生产30mm厚的木材,在初始温度40°C,最终温度65°C,干燥势为2,1的条件下进行干燥。测定了冷热木材蒸汽处理前后的LDS。观察到,条件没有降低LDS。热处理木材的LDS值高于冷处理木材。在正常木材、张力木材和相对木材中测量的LDS值在统计上相似,表明木材类型不是纵向干燥应力出现的影响因素。经证明,延伸仪测量LDS是可行的,可以方便、快速地定量。
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引用次数: 1
Combining artificial neural network and moth-flame optimization algorithm for optimization of ultrasound-assisted and microwave-assisted extraction parameters: Bark of Pinus brutia 结合人工神经网络和蛾焰优化算法优化超声和微波辅助提取参数:棕松皮
IF 1.5 4区 农林科学 Q2 Agricultural and Biological Sciences Pub Date : 2022-04-01 DOI: 10.4067/s0718-221x2022000100424
Ayşenur Gürgen, Başak Atilgan, S. Yıldız, O. Gönültaş, Sami Imamoğlu
In this study, the extraction parameters of Pinus brutia bark were optimized using a hybrid artificial in telligence technique. Firstly, the bark samples were extracted by ultrasound-assisted extraction and micro -wave-assisted extraction which are defined as ‘green’ extraction methods at different conditions. The selected extraction parameters for ultrasound-assisted extraction were 0:100; 20:80; 40:60; 80:20 (%) ethanol: water ratios; 40 ºC, 60 °C extraction temperatures and 5 min, 10 min, 15 min, 20 min extraction times and for mi -crowave-assisted extraction were 90, 180, 360, 600, 900 (W) microwave power, 0:100; 20:80; 40:60; 60:40; 80:20 (%) ethanol: water ratios. Then Stiasny number, condensed tannin content and reducing sugar content of all extracts were determined. Next, the prediction models were developed for each studied parameter using Artificial Neural Network. Finally, the extraction parameters were optimized using Moth-Flame Optimization Algorithm. After that optimization process, while the extraction time was the same (5 min), the ethanol: water ratio and extraction temperature values differed for the optimization of all studied assays of ultrasound-assisted extraction. Also, microwave power and ethanol: water ratio variables were found in different values for each assay of microwave-assisted extraction. The results showed that the Artificial Neural Network and Moth-Flame Optimization could be a novel and powerful hybrid approach to optimize the extraction parameters of Pinus brutia barks with saving time, cost, chemical and effort. Developing prediction model for UAE extraction parameters of Pinus brutia bark using ANN Developing prediction model for MAE extraction parameters of Pinus brutia bark using ANN Optimization of UAE extraction parameters of Pinus brutia bark using MFO algorithm Optimization of MAE extraction parameters of Pinus brutia bark using MFO algorithm
本研究采用混合人工智能技术对粗松皮的提取工艺进行优化。首先,在不同条件下,分别采用超声辅助提取和微波辅助提取两种“绿色”提取方法提取树皮样品。超声辅助提取的提取参数为0∶100;20:80;40:6 0;80:20(%)乙醇:水比;40℃、60℃提取温度下5 min、10 min、15 min、20 min提取次数和微波辅助提取分别为90、180、360、600、900 (W)微波功率,0:100;20:80;40:6 0;比例;80:20(%)乙醇:水的比例。然后测定各提取物的Stiasny数、缩合单宁含量和还原糖含量。其次,利用人工神经网络对各研究参数建立预测模型。最后,采用蛾焰优化算法对提取参数进行优化。优化后,在提取时间相同(5 min)的情况下,不同的乙醇:水比和提取温度对超声辅助提取的各项指标进行优化。此外,微波功率和乙醇:水比变量在微波辅助提取的每个实验中都有不同的值。结果表明,人工神经网络和飞蛾火焰优化是一种新颖而有效的混合方法,可以优化松皮的提取参数,节省时间、成本、化学成分和精力。基于神经网络的油松UAE提取参数预测模型基于神经网络的油松MAE提取参数预测模型基于MFO算法的油松UAE提取参数优化基于MFO算法的油松MAE提取参数优化
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引用次数: 0
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