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Influence of Enriched Urease Producing Bacteria from Leachate and Restaurant Wastewater on Heavy Metal Removal 垃圾渗滤液和餐饮废水中富含的尿素酶产生菌对重金属去除的影响
IF 0.6 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-12-04 DOI: 10.11113/mjfas.v19n6.3130
H. F. Basri, A. Omoregie, M. A. Mokhter
The escalation of heavy metal pollution in natural ecosystems due to industrialization presents a critical environmental concern, endangering the well-being of living organisms. Microbially Induced Carbonate Precipitation (MICP) technology, an emerging innovation, has gained attention from the scientific community for its potential in biocementation and bioremediation applications. However, a substantial gap in understanding exists regarding the utilization of ureolytic microbial strains from waste sources capable of effectively immobilizing high concentrations of heavy metals. This study endeavors to explore the latent potential of indigenous ureolytic bacteria derived from leachate and restaurant wastewater, possessing bioremediation capabilities for heavy metal immobilization. The investigation includes microbial screening, physiological characterization of ureolytic bacteria, assessment of their tolerance levels, and evaluation of heavy metal removal efficacy through Atomic Absorption Spectrophotometry (AAS) analysis. Notably, the results reveal that ureolytic bacteria from restaurant wastewater are more tolerant to Cd2+ concentrations compared to their leachate counterparts, manifesting optimum conductivity, pH, and optical density (OD). More so, AAS analysis demonstrates the restaurant wastewater-derived sample's remarkable proficiency in Cd2+ removal, achieving a substantial 95% removal rate, significantly outperforming the leachate wastewater sample's removal rate of 53%.
由于工业化,自然生态系统中重金属污染的升级引起了严重的环境问题,危及生物的福祉。微生物诱导碳酸盐沉淀(MICP)技术是一项新兴的创新技术,因其在生物胶结和生物修复方面的应用潜力而受到科学界的关注。然而,关于利用废物来源中的溶尿微生物菌株有效固定高浓度重金属的认识存在很大差距。本研究旨在探索从渗滤液和餐饮废水中提取的具有生物修复重金属固定能力的原生解尿菌的潜力。研究内容包括微生物筛选、溶尿细菌的生理特性、耐受性评估、原子吸收分光光度法(AAS)分析对重金属去除效果的评价。值得注意的是,研究结果表明,与渗滤液相比,餐饮废水中的尿溶菌对Cd2+浓度的耐受性更强,表现出最佳的电导率、pH和光密度(OD)。更重要的是,原子吸收光谱分析表明,餐厅废水来源的样品对Cd2+的去除率非常高,达到95%的去除率,显著优于渗滤液样品的53%的去除率。
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引用次数: 0
Application of Imputation Method for Compositional Data with Missing Values based on Adaptive LASSO Model: the Composition of Employment Industry in Taiyuan, China 基于自适应 LASSO 模型的缺失值构成数据估算方法的应用:中国太原市的就业行业构成
IF 0.6 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-12-04 DOI: 10.11113/mjfas.v20n1.3034
Ying Tian, Majid Khan Majahar Ali, Fam Pei Shan, Lili Wu, Siti Zulaikha Mohd Jamaludin
The tripartite industry classification, which divides all economic activities into three parts, is a classification method to reflect the dynamic process of economic development and the historical trend of the change of resource allocation structure.The fact shows that the proportion of each industry has become an important symbol of the level of national economic development. The proportion of each industry is compositional data,which is a kind of complex multidimensional data used in many fields. All components in the compositional data are non-negative and carry only relative information. In practice, there could be missing values in compositional data. However, general statistical analysis methods cannot be firstly used for compositional data with missing values. The complexity of the missing value of compositional data makes traditional imputation methods no longer suitable. Thus, how to carry out effective statistical inference for compositional data with missing values attracts the attention of many scholars, recently. In this paper, we focus on the imputation problem in compositional data containing missing values, and propose an Adaptive Least Absolute Shrinkage and Selection Operator (ALASSO) imputation method to obtain a complete datasets through variable selection and parameter estimation. Then, the new method is simulated and empirically analyzed, and a comparative study with mean imputation, k-nearest neighbor imputation, and iterative regression imputation is conducted. The results show that the ALASSO imputation method has the highest accuracy for different missing rates, dimensions and correlation coefficients.
将所有经济活动分成三部分的产业三段式分类法,是一种反映经济发展动态过程和资源配置结构变化历史趋势的分类方法。事实表明,各行业的比重已成为衡量国民经济发展水平的重要标志。各个行业的比重是组成数据,是一种复杂的多维数据,应用于很多领域。成分数据中的所有分量都是非负的,只携带相对信息。在实践中,组合数据中可能存在缺失值。然而,一般的统计分析方法不能首先用于含有缺失值的成分数据。由于成分数据缺失值的复杂性,传统的成分数据补全方法已不再适用。因此,如何对含有缺失值的成分数据进行有效的统计推断是近年来众多学者关注的问题。本文针对含有缺失值的成分数据的插值问题,提出了一种自适应最小绝对收缩和选择算子(ALASSO)插值方法,通过变量选择和参数估计获得完整的数据集。然后,对新方法进行了仿真和实证分析,并与均值归算、k近邻归算和迭代回归归算进行了比较研究。结果表明,在不同的缺失率、维度和相关系数下,ALASSO估算方法具有最高的精度。
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引用次数: 0
Comparative Analysis of Improved Dirichlet Process Mixture Model 改进的德里赫特过程混合模型比较分析
IF 0.6 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-12-04 DOI: 10.11113/mjfas.v19n6.3062
Lili Wu, P. Fam, Majid Khan Majahar Ali, Ying Tian, Mohd. Tahir Ismail, Siti Zulaikha Mohd Jamaludin
Due to the development of information technology, large amounts of data are generated every day in various industries such as engineering, healthcare, finance, anomaly detection, image recognition, and artificial intelligence. This massive data poses the challenge of analyzing accurately and appropriate classifications. The traditional clustering methods require specifying the number of clusters and are mostly based on distance, which cannot effectively consider the correlations between different indicators of high-dimensional and multi-source data. Moreover, the number of clusters cannot automatically adjust when new data is generated. In order to improve the clustering analysis of high-dimensional and multi-source data in a big data environment, this study utilizes non-parametric mixture models based on distribution clustering, which does not require specifying the number of clusters and can auto update with the data. By combining Principal Component Analysis (PCA), t-Distributed Stochastic Neighbour Embedding (t-SNE), and the non-parametric Bayesian method called Dirichlet Process Mixture Model (DPMM), the Bayesian non-parametric PCA model (PCA-DPMM) and Bayesian non-parametric t-SNE model (TSNE-DPMM) are proposed. The Chinese restaurant process of DPMM is used for sampling by introducing a finite normal mixture distribution. The clustering results on the iris dataset are compared and analyzed. The accuracy of DPMM and TSNE-DPMM reaches 0.97, while PCA-DPMM achieves a maximum accuracy of only 0.94. When different numbers of iterations are set, TSNE-DPMM maintains an accuracy ranging from 0.92 to 0.97, DPMM ranges from 0.66 to 0.97, and PCA-DPMM ranges from 0.73 to 0.94. Therefore, the proposed TSNE-DPMM ensures accuracy and exhibits better model stability in clustering results. Future research can explore the improvement of the model by incorporating deep learning algorithms, among others, to further enhance its performance. Additionally, applying the TSNE-DPMM model to data analysis in other fields is also a future research direction. Through these efforts, we can better tackle the challenges of analyzing high-dimensional and multi-source data in a big data environment and extract valuable information from it.
由于信息技术的发展,工程、医疗、金融、异常检测、图像识别、人工智能等各行各业每天都会产生大量的数据。如此庞大的数据对准确和适当的分类进行分析提出了挑战。传统的聚类方法需要指定聚类个数,且多基于距离,不能有效考虑高维多源数据不同指标之间的相关性。而且,当有新数据产生时,集群的数量不能自动调整。为了提高大数据环境下高维多源数据的聚类分析能力,本研究采用基于分布聚类的非参数混合模型,该模型不需要指定聚类个数,并且可以随数据自动更新。将主成分分析(PCA)、t分布随机邻居嵌入(t-SNE)和非参数贝叶斯方法Dirichlet过程混合模型(DPMM)相结合,提出了贝叶斯非参数PCA模型(PCA-DPMM)和贝叶斯非参数t-SNE模型(TSNE-DPMM)。通过引入有限正态混合分布,采用DPMM中餐馆过程进行抽样。对虹膜数据集的聚类结果进行了比较和分析。DPMM和tsn -DPMM的精度达到0.97,而PCA-DPMM的最大精度仅为0.94。设置不同迭代次数时,tsn -DPMM的精度范围为0.92 ~ 0.97,DPMM的精度范围为0.66 ~ 0.97,PCA-DPMM的精度范围为0.73 ~ 0.94。因此,本文提出的TSNE-DPMM在聚类结果中保证了准确性和更好的模型稳定性。未来的研究可以通过结合深度学习算法等探索模型的改进,进一步提高其性能。此外,将tsn - dpmm模型应用于其他领域的数据分析也是未来的研究方向。通过这些努力,我们可以更好地应对大数据环境下高维、多源数据分析的挑战,并从中提取有价值的信息。
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引用次数: 0
Impact of Missing Data on Correlation Coefficient Values: Deletion and Imputation Methods for Data Preparation 缺失数据对相关系数值的影响:数据准备中的删除和估算方法
IF 0.6 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-12-04 DOI: 10.11113/mjfas.v19n6.3098
Mohamed Shantal, Z. Othman, Azuraliza Abu Bakar
The correlation coefficient is one of the essential statistical techniques used to discover relationships among variables. Various techniques can quantify correlation, such as Pearson's, Spearman's, and Kendall's correlation coefficients, depending on the data type. As with any use of data, missing data will impact the availability of data, reducing it and potentially affecting the results. Furthermore, the removal of missing-value data from the study when using complete case analysis or available case analysis may result in selection biases. In this paper, we investigate the impact of missing data on the correlation coefficient value by calculating the difference between the correlation coefficient of the original complete dataset and that of a dataset with missing data. Two deletion strategies (Listwise and Pairwise) and three imputation strategies (Mean, k-Nearest Neighbors (k-NN), and Expectation-Maximization) were used to prepare the data before calculating the correlation coefficient. Unique correlation coefficient values were created by converting unique values to a one-dimensional array, and RMSE metrics were used to evaluate the experiments. Eight UCI and Kaggle datasets with different sizes and numbers of attributes were used in this study. The experiment results demonstrate that the Pairwise strategy and k-NN give good results on the correlation coefficient, respectively, when the missing rate is moderate or less. Pairwise uses all the available values and discards only the missing values of the related attribute, while k-NN fills the missing values with new values that produce correlation coefficient values close to the actual values.
相关系数是用来发现变量之间关系的基本统计技术之一。根据数据类型,各种技术可以量化相关性,例如Pearson的、Spearman的和Kendall的相关系数。与任何数据的使用一样,缺少数据将影响数据的可用性,减少数据的可用性,并可能影响结果。此外,当使用完整的案例分析或可用的案例分析时,从研究中删除缺失值数据可能会导致选择偏差。本文通过计算原始完整数据集的相关系数与缺失数据集的相关系数之差来研究缺失数据对相关系数值的影响。在计算相关系数之前,使用了两种删除策略(Listwise和Pairwise)和三种imputation策略(Mean, k-Nearest Neighbors (k-NN)和Expectation-Maximization)来准备数据。将唯一的相关系数值转换为一维数组,得到唯一的相关系数值,并使用RMSE指标对实验进行评价。本研究使用了8个不同大小和属性数量的UCI和Kaggle数据集。实验结果表明,当缺失率中等或较小时,配对策略和k-NN分别在相关系数上取得了较好的效果。两两使用所有可用的值,只丢弃相关属性的缺失值,而k-NN用新值填充缺失值,产生接近实际值的相关系数值。
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引用次数: 0
Phytochemical Screening and Antioxidant Activities of Geniotrigona thoracica Propolis Extracts Derived from Different Locations in Malaysia 从马来西亚不同地点提取的Geniotrigona thoracica蜂胶提取物的植物化学筛选和抗氧化活性
IF 0.6 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-12-04 DOI: 10.11113/mjfas.v19n6.3128
Lini Idris, Muhammad Amirul Adli, Nurul Najihah Yaacop, Rozaini MOHD ZOHDI
Propolis, a natural resinous substance secreted by bees, has garnered considerable interest due to its diverse bioactive compounds and potential health benefits. Nevertheless, the phytochemical composition of propolis exhibits significant variation, influenced by multiple factors including geographical region, and botanical origin. These determinants exert profound effects on the distinctive properties and biological diversities of propolis. This study aimed to investigate the phytochemical composition and antioxidant activities of Geniotrigona thoracica propolis extracts collected from three apiary sites, designated as apiary A, apiary B, and apiary C, located in different regions within Selangor. The ethanolic extracts of propolis were prepared using 70% of ethanol and subjected to phytochemical screening to identify the presence of flavonoids, terpenoids, alkaloids, saponins, tannins, steroids, and cardiac glycosides, whilst the total phenolic content (TPC) and total flavonoid content (TFC) were measured using the Folin-Ciocalteu colorimetric and aluminium chloride methods, respectively. Additionally, the antioxidant activities of the propolis extracts were evaluated using 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging and ferric-reducing antioxidant power (FRAP) assays. The phytochemical screening revealed the presence of flavonoids, terpenoids, alkaloids, saponins, tannins, steroids, and cardiac glycosides in all propolis extracts. The propolis from apiary A exhibited significantly higher TPC (302.21 ± 0.11 mg/mL GAE) and TFC values (99.08 ± 0.03 mg/mL QE) compared to apiary B and C. The results also indicated that propolis from apiary A possessed significantly higher antioxidant activities, with IC₅₀ value of DPPH at 25.27 μg/mL and FRAP value of 727.53 ± 0.09 μM Fe²+, in comparison to apiary B and C. A strong correlation was observed between TPC, TFC, and IC₅₀ of DPPH. This study highlights significant variations in the phytochemical compositions and antioxidant activities of propolis samples collected from different geographical and botanical sources. Further investigation is in progress to identify the specific phytochemical constituents responsible for these variations.
蜂胶是一种由蜜蜂分泌的天然树脂物质,由于其多种生物活性化合物和潜在的健康益处而引起了相当大的兴趣。然而,蜂胶的植物化学成分受地理区域和植物来源等多种因素的影响,呈现出显著的差异。这些决定因素对蜂胶的特性和生物多样性有着深远的影响。本研究旨在研究从雪兰莪州3个不同地区的蜂巢A、蜂巢B和蜂巢C采集的金三角蜂蜂胶提取物的植物化学成分和抗氧化活性。以70%乙醇为溶剂制备蜂胶乙醇提取物,通过植物化学筛选鉴定蜂胶中黄酮类、萜类、生物碱类、皂苷类、单宁类、甾体类和心苷类成分,并分别采用Folin-Ciocalteu比色法和氯化铝法测定蜂胶中总酚含量(TPC)和总黄酮含量(TFC)。此外,利用2,2-二苯基-1-苦味酰肼(DPPH)自由基清除和铁还原抗氧化能力(FRAP)测定蜂胶提取物的抗氧化活性。植物化学筛选显示,所有蜂胶提取物中均含有黄酮类、萜类、生物碱、皂苷、单宁、类固醇和心糖苷。与蜂房B和c相比,蜂房A的蜂胶表现出显著更高的TPC(302.21±0.11 mg/mL GAE)和TFC值(99.08±0.03 mg/mL QE)。结果还表明,蜂房A的蜂胶具有显著更高的抗氧化活性,DPPH的IC₅₀值为25.27 μg/mL, FRAP值为727.53±0.09 μM Fe²+,与蜂房B和c相比,TPC, TFC和DPPH的IC₅₀之间存在强相关性。本研究强调了不同地理和植物来源的蜂胶样品在植物化学成分和抗氧化活性方面的显著差异。进一步的调查正在进行中,以确定造成这些变化的特定植物化学成分。
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引用次数: 0
Fuzzy Intuitionistic Alpha-cut Interpolation Rational Bézier Curve Modeling for Shoreline Island Data 针对海岸线岛屿数据的模糊直觉阿尔法切插值有理贝塞尔曲线建模
IF 0.6 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-12-04 DOI: 10.11113/mjfas.v19n6.3126
Siti Nasyitah Jaman, R. Zakaria, I. Ismail
The problem of uncertain data cannot be solved by conventional methods, which results in inaccurate data analysis and prediction. During the data collecting phase, ambiguous data are often collected, but they cannot be used immediately to generate geometric models. In this case, the new approaches to intuitionistic fuzzy sets will be used to determine the alpha cut value for uncertainty data sets. To solve the uncertainty data and build the mathematical model, this study applied fuzzy set theory, intuitionistic fuzzy sets, and rational Bézier curve geometric modelling. There are three main methods in this study. The triangular fuzzy number is used to define the uncertainty data in the first place. The alpha value can then be found using a centre of mass alpha-cut. The intuitionistic alpha-cut can then be applied to both membership and non-membership data. This procedure, also called fuzzification, is defined as fuzzy intuitionistic into alpha-cut values. The data set will then undergo the defuzzification procedure to get single value data. For the purpose of analysis and conclusion-making, the modeling data for each process will be visualised using an interpolation rational Bézier curve. The findings demonstrate that using the intuitionistic fuzzy set for the alpha-cut value was more effective than the previous method without considering both membership and non-membership values.
常规方法无法解决数据的不确定性问题,导致数据分析和预测不准确。在数据收集阶段,经常会收集到模棱两可的数据,但这些数据不能立即用于生成几何模型。在这种情况下,直觉模糊集的新方法将用于确定不确定性数据集的α切值。为了解决不确定性数据,建立数学模型,本研究应用模糊集理论、直觉模糊集和理性bassazier曲线几何建模。本研究主要采用三种方法。首先用三角模糊数来定义不确定性数据。然后可以使用质量中心的alpha-cut来找到alpha值。直观的alpha-cut可以同时应用于隶属和非隶属数据。这个过程,也被称为模糊化,被定义为对α -切值的模糊直觉。然后对数据集进行去模糊化处理,得到单值数据。为了分析和得出结论,每个过程的建模数据将使用插值有理bsamzier曲线进行可视化。研究结果表明,使用直觉模糊集来确定alpha-cut值比不考虑隶属度和非隶属度的方法更有效。
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引用次数: 0
Effects of Bio-Amendment of Coconut Dust with Empty Fruit Bunch Compost on the Efficacy of Mycorrhizae Under Deficit Fertigation 椰糠与空果束堆肥的生物添加对缺肥条件下菌根功效的影响
IF 0.6 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-12-04 DOI: 10.11113/mjfas.v19n6.3164
M. F. Karim, Mohd Razi Ismail
It has been known that the application of beneficial fungi and compost, has a favourable effect on easing water deficiency stress in plants, hence helping to boost agricultural activities in times of climate uncertainty. In this study, the influence of arbuscular mycorrhizal fungi (AMF) in combination with oil palm empty fruit bunch compost (EFB) on the growth, yield, and physiology of chilli under deficit fertigation was investigated. Throughout the study, five-week-old chilli seedlings were fertigated daily with 100% and 60% of daily evapotranspiration (ET) readings. Three days after transplanting, 10g of sandy soil containing roughly 120-150 mycorrhizal spores was applied to the root zone. Physiological data such as real-time photosynthesis and stomatal conductance were measured at vegetative, early flowering, fruit setting, and maturity or harvesting stages. Meanwhile, yield and morphological measurements were recorded at the end of the study. It was discovered that the addition of EFB to the coconut coir dust media enhanced the beneficial effects of AMF on all parameters including total biomass, chlorophyll fluorescence Fv/Fm, total chlorophylls, photosynthesis rate and stomatal conductance regardless of fertigation levels. The study also revealed that AMF inoculation alone was less effective than non-inoculation + EFB. In conclusion, it is suggested that incorporation of AMF and EFB compost positively affect the yield, growth and physiology of chilli under deficit fertigation.
众所周知,施用有益真菌和堆肥对缓解植物缺水压力有有利作用,因此有助于在气候不确定时期促进农业活动。研究了亏缺施肥条件下丛枝菌根真菌(AMF)与油棕空果串堆肥(EFB)配合施用对辣椒生长、产量和生理的影响。在整个研究过程中,每天对五周大的辣椒幼苗进行施肥,每日蒸散量(ET)分别为100%和60%。移栽3天后,在根区施用含菌根孢子约120-150个的沙土10g。在营养、早花、坐果、成熟或收获阶段测量实时光合作用和气孔导度等生理数据。同时,在研究结束时记录了产量和形态测量。结果表明,无论施肥水平如何,在椰子粉培养基中添加EFB均增强了AMF对总生物量、叶绿素荧光Fv/Fm、总叶绿素、光合速率和气孔导度等参数的有利影响。研究还发现,单独接种AMF的效果不如不接种+ EFB。综上所述,掺入AMF和EFB堆肥对亏缺施肥辣椒的产量、生长和生理均有积极影响。
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引用次数: 0
Type-2 Intuitionistic Interpolation Cubic Fuzzy Bézier Curve Modeling using Shoreline Data 利用海岸线数据进行第 2 类直觉插值立体模糊贝塞尔曲线建模
IF 0.6 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-12-04 DOI: 10.11113/mjfas.v19n6.3076
Nur Batrisyia Ahmad Azmi, R. Zakaria, I. Ismail
The notion of fuzzy sets is fast becoming a key instrument in defining the uncertainty data and has increasingly been recognised by practitioners and researchers across different disciplines in recent decades. The uncertainty data cannot be modeled directly and this causes hindrance in obtaining accurate information for analysis or predictions. Hence, this paper contributes to another approach in which an application of type-2 intuitionistic fuzzy set (T-2IFS) in geometric modeling onto complex uncertainty data where the data are defined using the type-2 fuzzy concept. T-2IFS is the generalized forms of fuzzy sets, intuitionistic fuzzy sets, interval-valued fuzzy sets, and interval-valued intuitionistic fuzzy sets. Based on the concept of T2IFS, type-2 intuitionistic fuzzy point (T-2IFP) is defined in order to generate a type-2 intuitionistic fuzzy control point (T-2IFCP). Following, the T-2IFCP will be blended with the Bernstein blending function through the interpolation method, resulting to a type-2 intuitionistic interpolation cubic fuzzy Bézier curve. Shoreline data is used as the data and further verifies that the model can be conceivably accepted. In conclusion, the proposed methods are reliable and can be expanded to many other areas.
近几十年来,模糊集的概念正迅速成为定义不确定性数据的关键工具,并越来越多地被不同学科的从业者和研究人员所认可。不确定性数据不能直接建模,这对获得准确信息进行分析或预测造成了障碍。因此,本文提出了另一种方法,将2型直觉模糊集(T-2IFS)应用于复杂不确定性数据的几何建模,其中数据是使用2型模糊概念定义的。T-2IFS是模糊集、直觉模糊集、区间值模糊集、区间值直觉模糊集的广义形式。基于T2IFS的概念,定义2型直觉模糊点(T-2IFP),生成2型直觉模糊控制点(T-2IFCP)。接下来,将T-2IFCP通过插值方法与Bernstein混合函数进行混合,得到type-2直观插值三次模糊bsamizier曲线。采用岸线数据作为数据,进一步验证了模型的可接受性。总之,所提出的方法是可靠的,可以推广到许多其他领域。
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引用次数: 0
What is the Effect of a Magnetic Field on Dye Adsorption onto Graphite Carbon? 磁场对石墨碳吸附染料有何影响?
IF 0.6 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-12-04 DOI: 10.11113/mjfas.v19n6.3243
Nursyafreena Attan, Desmilia Putri Ramadhani, Asmi Munadhiroh, Hadi Nur
This research explores the impact of magnetic fields on dye adsorption onto graphite carbon, utilizing electric currents to generate varying magnetic field strengths, as determined by the Biot-Savart law. The study demonstrates that even with small current magnitudes typically used in physics laboratories, the generated magnetic fields significantly influence dye adsorption. Through experiments with currents ranging from 1.5 A to 7.5 A, resulting in magnetic fields from 1.54 µT to 4.63 µT, we observed enhanced adsorption for congo red, methylene blue, and methyl orange. In contrast, phenol red exhibited a unique desorption pattern due to electrostatic repulsion. Temperature variations were noted but were considered to have a negligible effect on the adsorption behavior. The findings highlight the crucial role of magnetic energy density and the charge of dye molecules in the adsorption process, leading to the conclusion that magnetic fields, indeed, play a significant role in influencing dye adsorption onto graphite carbon, with potential applications in environmental conservation and industrial waste management.
本研究探讨了磁场对染料在石墨碳上吸附的影响,利用电流产生不同的磁场强度,由比奥-萨瓦定律确定。研究表明,即使在物理实验室中通常使用的小电流,产生的磁场也会显著影响染料的吸附。通过实验,电流范围为1.5 A至7.5 A,磁场范围为1.54µT至4.63µT,我们观察到对刚果红、亚甲基蓝和甲基橙的吸附增强。相比之下,苯酚红由于静电斥力表现出独特的解吸模式。温度变化被注意到,但被认为对吸附行为的影响可以忽略不计。这些发现强调了磁能密度和染料分子的电荷在吸附过程中的关键作用,从而得出结论,磁场确实在影响染料在石墨碳上的吸附方面起着重要作用,在环境保护和工业废物管理方面具有潜在的应用前景。
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引用次数: 0
Probing the Electronic Properties of Cu and CuO Thin Films via XANES utilizing Powder XRD System 利用粉末 XRD 系统通过 XANES 探测铜和氧化铜薄膜的电子特性
IF 0.6 Q3 MULTIDISCIPLINARY SCIENCES Pub Date : 2023-12-04 DOI: 10.11113/mjfas.v19n6.3143
Siti Sarah Saniman, M. F. Omar
This research introduces an alternative approach on materials characterization by developing an in-house X-ray Absorption Spectroscopy (XAS) system utilizing powder X-ray Diffraction (XRD) machine. The performance of the in-house XAS system was investigated by analysing the position of Cu K-edge and the absorption spectrum shape within the X-ray Absorption Near Edge Structure (XANES) region. Copper (Cu) based samples were used to test the performance of the system where Cu and Copper Oxide (CuO) thin film deposited on polyimide tape and silicon wafer (100) prepared through the deposition process carried out using RF Magnetron Sputtering machine. Phase confirmation analysis were conducted by XRD and the deposited films’ thickness were measured by Scanning Electron Microscope (SEM). The laboratory-based XAS measurement was carried out using Rigaku SmartLab X-ray Diffractometer configured for Bragg-Brentano (BB) measurement mode. Molybdenum (Mo) target was used to produce white X-rays by energizing it near 20 keV ±0.01 keV. XRD measurements on XRD and SEM analysis proves successful deposition of pure Cu and CuO thin films and the film thickness measured is 1.432 μm and 0.680 μm respectively. The conclusive findings of the laboratory-based XAS measurements indicate successful acquisition of XAS data with similar spectrum shape of experimental Cu and CuO XANES in comparison with theoretical data. Next, experimental XANES shows clear observation of Cu K-edge peaks for Cu thin film at 8.9737 keV, while Cu K-edge for CuO thin films is not observable. Lastly, there is also presence of significant XANES broadening and which then effect consequent peak shiftings.
本研究介绍了利用粉末x射线衍射(XRD)机器开发内部x射线吸收光谱(XAS)系统的另一种材料表征方法。通过分析Cu k边的位置和x射线吸收近边结构(XANES)区域内的吸收光谱形状,研究了内部XAS系统的性能。采用射频磁控溅射机沉积工艺制备了聚酰亚胺带和硅片(100),以铜(Cu)为基材,测试了Cu和氧化铜(CuO)薄膜沉积系统的性能。采用x射线衍射(XRD)进行物相分析,并用扫描电镜(SEM)测量了沉积膜的厚度。基于实验室的XAS测量使用配置为Bragg-Brentano (BB)测量模式的Rigaku SmartLab x射线衍射仪进行。利用钼靶在20 keV±0.01 keV附近通电产生白色x射线。XRD和SEM分析表明,制备出了纯Cu和纯CuO薄膜,薄膜厚度分别为1.432 μm和0.680 μm。基于实验室的XAS测量结果表明,与理论数据相比,实验Cu和CuO XANES的XAS数据具有相似的光谱形状。其次,实验XANES显示,Cu薄膜在8.9737 keV处有清晰的Cu K-edge峰,而CuO薄膜的Cu K-edge没有被观察到。最后,还存在显着的XANES拓宽,然后影响随之而来的峰移。
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Malaysian Journal of Fundamental and Applied Sciences
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