Pub Date : 2026-01-01DOI: 10.1016/j.mtphys.2025.102007
Amit K. Das , Vikas Kumar Sahu , R.S. Ajimsha , Sunil Verma , Pankaj Misra
Amorphous gallium oxide (a-Ga2O3) based UV photodetectors combine the benefits of low growth temperature, large-area processibility and use of flexible, inexpensive substrates with performance comparable to their crystalline counterparts. Despite these advantages, their photoresponse time is notably slower. To mitigate this, ultrafast vertical Schottky type Au/a-Ga2O3/ITO solar blind ultraviolet photodetectors have been developed in crossbar geometry, wherein the a-Ga2O3 thin film, deposited by RF magnetron sputtering, is sandwiched between the bottom ITO and orthogonal top semi-transparent Au Schottky electrodes. The device sizes vary from ∼8 to 12 mm2. The temporal UV photoresponse measurement of the devices at zero bias shows ultrafast response with both rise and fall times of ∼2 μs, which is the fastest reported till date for a-Ga2O3 based UV photodetectors. The zero bias spectral responsivity measurement reveals that the responsivity peaks at 250 nm with the cut-off at 273 nm. The maximum self-powered spectral responsivity of ∼14 mA/W obtained in these crossbar devices is comparable to that of a-Ga2O3 based devices reported in literature. These crossbar Au/a-Ga2O3/ITO devices showing ultrafast self-powered solar blind UV photoresponse are promising for applications requiring fast solar blind UV detectors such as UV communication, imaging, missile plume detection etc.
{"title":"Ultrafast self-powered solar blind UV photodetectors based on amorphous Ga2O3 thin films in crossbar geometry","authors":"Amit K. Das , Vikas Kumar Sahu , R.S. Ajimsha , Sunil Verma , Pankaj Misra","doi":"10.1016/j.mtphys.2025.102007","DOIUrl":"10.1016/j.mtphys.2025.102007","url":null,"abstract":"<div><div>Amorphous gallium oxide (<em>a</em>-Ga<sub>2</sub>O<sub>3</sub>) based UV photodetectors combine the benefits of low growth temperature, large-area processibility and use of flexible, inexpensive substrates with performance comparable to their crystalline counterparts. Despite these advantages, their photoresponse time is notably slower. To mitigate this, ultrafast vertical Schottky type Au/<em>a</em>-Ga<sub>2</sub>O<sub>3</sub>/ITO solar blind ultraviolet photodetectors have been developed in crossbar geometry, wherein the <em>a</em>-Ga<sub>2</sub>O<sub>3</sub> thin film, deposited by RF magnetron sputtering, is sandwiched between the bottom ITO and orthogonal top semi-transparent Au Schottky electrodes. The device sizes vary from ∼8 to 12 mm<sup>2</sup>. The temporal UV photoresponse measurement of the devices at zero bias shows ultrafast response with both rise and fall times of ∼2 μs, which is the fastest reported till date for <em>a</em>-Ga<sub>2</sub>O<sub>3</sub> based UV photodetectors. The zero bias spectral responsivity measurement reveals that the responsivity peaks at 250 nm with the cut-off at 273 nm. The maximum self-powered spectral responsivity of ∼14 mA/W obtained in these crossbar devices is comparable to that of <em>a</em>-Ga<sub>2</sub>O<sub>3</sub> based devices reported in literature. These crossbar Au/<em>a</em>-Ga<sub>2</sub>O<sub>3</sub>/ITO devices showing ultrafast self-powered solar blind UV photoresponse are promising for applications requiring fast solar blind UV detectors such as UV communication, imaging, missile plume detection etc.</div></div>","PeriodicalId":18253,"journal":{"name":"Materials Today Physics","volume":"60 ","pages":"Article 102007"},"PeriodicalIF":9.7,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145880635","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
IF 9.7 2区 材料科学Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY
Pub Date : 2026-01-01DOI: 10.1016/j.mtphys.2025.102001
Ziqi Guan , Haoxuan Liu , Hongyuan Tang , Yanze Wu , Xiaowen Hao , Zhenzhuang Li , Jing Bai , Yafei Kuang , Xing Lu , Liang Zuo
Solid-state refrigeration materials have attracted considerable attention due to their promising applications in low-carbon refrigeration technology. Given that the refrigeration performances of solid-state refrigeration materials are intrinsically correlated or even inversely related, an overall trade-off is necessitated. Here, we present a directionally solidified (Ni37Co13Mn33.8Ti16.2)98.7B1.3 alloy that exhibits outstanding comprehensive properties. Its fracture compressive strain and strength are 19.0 % and 2454 MPa at room temperature, respectively. Under external field excitation, the alloy demonstrates a giant elastocaloric adiabatic temperature change of 30.1 K and can also yield a large magnetic entropy change of 33.7 J kg−1 K−1. More importantly, the combination of multiple caloric effects extends the working temperature range of the present alloy over 240 K. Furthermore, a large elastocaloric adiabatic temperature change between loading and unloading during fatigue is about 11 K and can be maintained for more than 73,000 cycles. Experimental and first-principles calculations reveal that the outstanding comprehensive properties of the present alloy are primarily attributed to the synergistic interaction of large lattice vibration entropy, strong preferred orientation, second phase strengthening, and grain boundary strengthening. Such a combination renders the present alloy state-of-the-art refrigeration functional behavior and is expected to benefit the practical applications of solid-state refrigeration.
{"title":"Realizing overall trade-off of giant caloric effect, wide working temperature range and ultrahigh cyclic stability in Ni-Co-Mn-Ti-B multiferroic phase transformation alloy","authors":"Ziqi Guan , Haoxuan Liu , Hongyuan Tang , Yanze Wu , Xiaowen Hao , Zhenzhuang Li , Jing Bai , Yafei Kuang , Xing Lu , Liang Zuo","doi":"10.1016/j.mtphys.2025.102001","DOIUrl":"10.1016/j.mtphys.2025.102001","url":null,"abstract":"<div><div>Solid-state refrigeration materials have attracted considerable attention due to their promising applications in low-carbon refrigeration technology. Given that the refrigeration performances of solid-state refrigeration materials are intrinsically correlated or even inversely related, an overall trade-off is necessitated. Here, we present a directionally solidified (Ni<sub>37</sub>Co<sub>13</sub>Mn<sub>33.8</sub>Ti<sub>16.2</sub>)<sub>98.7</sub>B<sub>1.3</sub> alloy that exhibits outstanding comprehensive properties. Its fracture compressive strain and strength are 19.0 % and 2454 MPa at room temperature, respectively. Under external field excitation, the alloy demonstrates a giant elastocaloric adiabatic temperature change of 30.1 K and can also yield a large magnetic entropy change of 33.7 J kg<sup>−1</sup> K<sup>−1</sup>. More importantly, the combination of multiple caloric effects extends the working temperature range of the present alloy over 240 K. Furthermore, a large elastocaloric adiabatic temperature change between loading and unloading during fatigue is about 11 K and can be maintained for more than 73,000 cycles. Experimental and first-principles calculations reveal that the outstanding comprehensive properties of the present alloy are primarily attributed to the synergistic interaction of large lattice vibration entropy, strong preferred orientation, second phase strengthening, and grain boundary strengthening. Such a combination renders the present alloy state-of-the-art refrigeration functional behavior and is expected to benefit the practical applications of solid-state refrigeration.</div></div>","PeriodicalId":18253,"journal":{"name":"Materials Today Physics","volume":"60 ","pages":"Article 102001"},"PeriodicalIF":9.7,"publicationDate":"2026-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145822858","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}