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Ultrafast self-powered solar blind UV photodetectors based on amorphous Ga2O3 thin films in crossbar geometry 基于横杆非晶Ga2O3薄膜的超快自供电太阳盲紫外光电探测器
IF 9.7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-01 DOI: 10.1016/j.mtphys.2025.102007
Amit K. Das , Vikas Kumar Sahu , R.S. Ajimsha , Sunil Verma , Pankaj Misra
Amorphous gallium oxide (a-Ga2O3) based UV photodetectors combine the benefits of low growth temperature, large-area processibility and use of flexible, inexpensive substrates with performance comparable to their crystalline counterparts. Despite these advantages, their photoresponse time is notably slower. To mitigate this, ultrafast vertical Schottky type Au/a-Ga2O3/ITO solar blind ultraviolet photodetectors have been developed in crossbar geometry, wherein the a-Ga2O3 thin film, deposited by RF magnetron sputtering, is sandwiched between the bottom ITO and orthogonal top semi-transparent Au Schottky electrodes. The device sizes vary from ∼8 to 12 mm2. The temporal UV photoresponse measurement of the devices at zero bias shows ultrafast response with both rise and fall times of ∼2 μs, which is the fastest reported till date for a-Ga2O3 based UV photodetectors. The zero bias spectral responsivity measurement reveals that the responsivity peaks at 250 nm with the cut-off at 273 nm. The maximum self-powered spectral responsivity of ∼14 mA/W obtained in these crossbar devices is comparable to that of a-Ga2O3 based devices reported in literature. These crossbar Au/a-Ga2O3/ITO devices showing ultrafast self-powered solar blind UV photoresponse are promising for applications requiring fast solar blind UV detectors such as UV communication, imaging, missile plume detection etc.
基于非晶氧化镓(a-Ga2O3)的紫外光电探测器结合了低生长温度、大面积可加工性和使用柔性、廉价衬底的优点,其性能可与晶体相媲美。尽管有这些优点,它们的光响应时间明显较慢。为了减轻这一问题,在横杆几何结构中开发了超快垂直肖特基型Au/a-Ga2O3/ITO太阳盲紫外光电探测器,其中,通过射频磁控溅射沉积的a-Ga2O3薄膜夹在底部ITO和正交顶部半透明Au - Schottky电极之间。器件尺寸从~ 8到12mm2不等。器件在零偏置下的时间紫外光响应测量显示出超快的响应,上升和下降时间均为~ 2 μs,这是迄今为止报道的基于a-Ga2O3的紫外光电探测器中最快的。零偏光谱响应率测量表明,响应率在250 nm处达到峰值,截止点为273 nm。在这些交叉棒器件中获得的最大自供电光谱响应率为~ 14 mA/W,与文献中报道的基于a-Ga2O3的器件相当。这些横条Au/a-Ga2O3/ITO器件显示了超快的自供电太阳盲紫外光响应,对于需要快速太阳盲紫外探测器的应用,如紫外通信、成像、导弹羽流探测等,具有很大的前景。
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引用次数: 0
IF 9.7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-01
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引用次数: 0
IF 9.7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-01
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引用次数: 0
IF 9.7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-01
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引用次数: 0
IF 9.7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-01
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引用次数: 0
IF 9.7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-01
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引用次数: 0
IF 9.7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-01
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引用次数: 0
IF 9.7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-01
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引用次数: 0
IF 9.7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-01
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引用次数: 0
Realizing overall trade-off of giant caloric effect, wide working temperature range and ultrahigh cyclic stability in Ni-Co-Mn-Ti-B multiferroic phase transformation alloy 实现了Ni-Co-Mn-Ti-B多铁相变合金巨热效应、宽工作温度范围和超高循环稳定性的综合权衡
IF 9.7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-01-01 DOI: 10.1016/j.mtphys.2025.102001
Ziqi Guan , Haoxuan Liu , Hongyuan Tang , Yanze Wu , Xiaowen Hao , Zhenzhuang Li , Jing Bai , Yafei Kuang , Xing Lu , Liang Zuo
Solid-state refrigeration materials have attracted considerable attention due to their promising applications in low-carbon refrigeration technology. Given that the refrigeration performances of solid-state refrigeration materials are intrinsically correlated or even inversely related, an overall trade-off is necessitated. Here, we present a directionally solidified (Ni37Co13Mn33.8Ti16.2)98.7B1.3 alloy that exhibits outstanding comprehensive properties. Its fracture compressive strain and strength are 19.0 % and 2454 MPa at room temperature, respectively. Under external field excitation, the alloy demonstrates a giant elastocaloric adiabatic temperature change of 30.1 K and can also yield a large magnetic entropy change of 33.7 J kg−1 K−1. More importantly, the combination of multiple caloric effects extends the working temperature range of the present alloy over 240 K. Furthermore, a large elastocaloric adiabatic temperature change between loading and unloading during fatigue is about 11 K and can be maintained for more than 73,000 cycles. Experimental and first-principles calculations reveal that the outstanding comprehensive properties of the present alloy are primarily attributed to the synergistic interaction of large lattice vibration entropy, strong preferred orientation, second phase strengthening, and grain boundary strengthening. Such a combination renders the present alloy state-of-the-art refrigeration functional behavior and is expected to benefit the practical applications of solid-state refrigeration.
固态制冷材料因其在低碳制冷技术中的应用前景而备受关注。鉴于固态制冷材料的制冷性能是内在相关的,甚至是负相关的,因此需要一个整体的权衡。本文制备了一种具有优异综合性能的定向凝固(Ni37Co13Mn33.8Ti16.2)98.7B1.3合金。室温下,其断裂抗压应变和强度分别为19.0%和2454 MPa。在外场激励下,合金表现出30.1 K的巨大热弹性绝热温度变化和33.7 J kg−1 K−1的大磁熵变化。更重要的是,多种热效应的结合将合金的工作温度范围扩大到240 K以上。此外,在疲劳期间,加载和卸载之间的大弹性热绝热温度变化约为11 K,可以保持超过73,000次循环。实验和第一性原理计算表明,大晶格振动熵、强择优取向、第二相强化和晶界强化的协同作用是合金优异的综合性能的主要原因。这样的组合使目前的合金具有最先进的制冷功能行为,并有望有利于固态制冷的实际应用。
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引用次数: 0
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Materials Today Physics
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