María Teresa Sánchez-Vieyra, Miguel Ojeda-Martínez, Eden Oceguera-Contreras, Sergio Yair Rodríguez-Preciado, Mariana Díaz-Zaragoza, Brenda Esmeralda Martínez-Zérega, José Luis González-Solís, David Omar Oseguera-Galindo
A high rate of silver nanoparticle formation, effective against the Escherichia coli (E. coli) bacterium, was obtained for the first time by means of a simple, eco-friendly, and low-cost green method in a solution of agave inulin. The study was carried out using the traditional method, in which the effects of the concentration of agave inulin, AgNO3, temperature, and pH on the synthesis were analyzed by UV-Vis spectroscopy and transmission electron microscopy (TEM). Most of the nanoparticles produced were spherical with a size less than 10 nm. In a sample with 20 mg/mL of agave inulin, 1 mM of AgNO3, T = 23°C, and pH = 12, the highest percentage of Ag+ ions available in the solution were reduced for the formation of nanoparticles in less than 40 min, whereas a sample prepared with 60 mg/mL of agave inulin, 10 mM of AgNO3, T = 23°C, pH = 12, and a storage time of 40 min showed a significant bactericidal effect on the E. coli strain. Agave inulin is a good biological compound for the formation of small, spherical silver nanoparticles. A pH of 12 favors a higher production speed of the silver nanoparticles and better use of the available Ag+ ions. In addition to this, the concentration of AgNO3 is a determining factor for increased formation of the nanoparticles necessary to bactericidal effect.
{"title":"Eco-friendly high-rate formation of silver nanoparticles in agave inulin and its bactericidal effect against Escherichia coli","authors":"María Teresa Sánchez-Vieyra, Miguel Ojeda-Martínez, Eden Oceguera-Contreras, Sergio Yair Rodríguez-Preciado, Mariana Díaz-Zaragoza, Brenda Esmeralda Martínez-Zérega, José Luis González-Solís, David Omar Oseguera-Galindo","doi":"10.2478/msp-2023-0034","DOIUrl":"https://doi.org/10.2478/msp-2023-0034","url":null,"abstract":"A high rate of silver nanoparticle formation, effective against the <jats:italic>Escherichia coli</jats:italic> (<jats:italic>E. coli</jats:italic>) bacterium, was obtained for the first time by means of a simple, eco-friendly, and low-cost green method in a solution of agave inulin. The study was carried out using the traditional method, in which the effects of the concentration of agave inulin, AgNO<jats:sub>3</jats:sub>, temperature, and pH on the synthesis were analyzed by UV-Vis spectroscopy and transmission electron microscopy (TEM). Most of the nanoparticles produced were spherical with a size less than 10 nm. In a sample with 20 mg/mL of agave inulin, 1 mM of AgNO<jats:sub>3</jats:sub>, T = 23°C, and pH = 12, the highest percentage of Ag<jats:sup>+</jats:sup> ions available in the solution were reduced for the formation of nanoparticles in less than 40 min, whereas a sample prepared with 60 mg/mL of agave inulin, 10 mM of AgNO<jats:sub>3</jats:sub>, T = 23°C, pH = 12, and a storage time of 40 min showed a significant bactericidal effect on the <jats:italic>E. coli</jats:italic> strain. Agave inulin is a good biological compound for the formation of small, spherical silver nanoparticles. A pH of 12 favors a higher production speed of the silver nanoparticles and better use of the available Ag<jats:sup>+</jats:sup> ions. In addition to this, the concentration of AgNO<jats:sub>3</jats:sub> is a determining factor for increased formation of the nanoparticles necessary to bactericidal effect.","PeriodicalId":18269,"journal":{"name":"Materials Science-Poland","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2024-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139411193","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Magnetic treatment technology for concrete mixing water is a cost-effective and environmentally friendly approach that can enhance the performance and durability of cement-based materials. This technology aligns with the principles of sustainable development. In their studies, researchers have utilized static magnetic fields (SMF) of varying intensities to treat regular water and produce magnetically treated mixing water (MTMW) for a specific duration. Various research laboratories have successfully employed MTMW in the production of cement-based materials such as cement paste, mortar, ordinary concrete, foam concrete, self-compacting concrete, and rubber concrete. The main objective of this investigation is to review previous research that evaluated the impact of MTMW produced using different methods on the fresh, hardened, durability, and microstructure properties of cement-based materials. Most studies revealed that magnetic treatment technology improves physical and chemical properties of regular water, including solubility, surface tension, and conductivity. Regarding cement-based materials produced with MTMW, most investigations have demonstrated a significant enhancement in mechanical strength, durability, and microstructure. However, it seems that some researchers may have exaggerated their findings regarding the effect of MTMW on mechanical properties. Consequently, further research is needed to validate these results. I recommend considering the utilization of the MTMW technique for all cement-based materials to enhance their mechanical strength and durability performance.
{"title":"Effect of magnetic treatment of mixing water on the behavior of cement-based materials: A review","authors":"Layachi Guelmine","doi":"10.2478/msp-2023-0029","DOIUrl":"https://doi.org/10.2478/msp-2023-0029","url":null,"abstract":"Magnetic treatment technology for concrete mixing water is a cost-effective and environmentally friendly approach that can enhance the performance and durability of cement-based materials. This technology aligns with the principles of sustainable development. In their studies, researchers have utilized static magnetic fields (SMF) of varying intensities to treat regular water and produce magnetically treated mixing water (MTMW) for a specific duration. Various research laboratories have successfully employed MTMW in the production of cement-based materials such as cement paste, mortar, ordinary concrete, foam concrete, self-compacting concrete, and rubber concrete. The main objective of this investigation is to review previous research that evaluated the impact of MTMW produced using different methods on the fresh, hardened, durability, and microstructure properties of cement-based materials. Most studies revealed that magnetic treatment technology improves physical and chemical properties of regular water, including solubility, surface tension, and conductivity. Regarding cement-based materials produced with MTMW, most investigations have demonstrated a significant enhancement in mechanical strength, durability, and microstructure. However, it seems that some researchers may have exaggerated their findings regarding the effect of MTMW on mechanical properties. Consequently, further research is needed to validate these results. I recommend considering the utilization of the MTMW technique for all cement-based materials to enhance their mechanical strength and durability performance.","PeriodicalId":18269,"journal":{"name":"Materials Science-Poland","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139054491","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shilin Yang, Kateryna Krayushkina, Oleksandra Akmaldinova, Junwen Ji, Andrii Bieliatynskyi
The use of crushed, granulated slag is now a rational direction in the use of phosphorus waste in various areas of construction. The modern state of science and technology and the accumulated experience allow to use almost all types of metallurgical slag for the production of road-building materials. The use of slag from other industries will expand the raw material base and improve its geographical location, increase material production and quality, reduce the distance of material transportation and reduce the road construction cost. The use of slag is an environmental task that will have a social impact. The study theoretically proved and experimentally established the feasibility of laying asphalt concrete coatings with phosphorus slag on roadways. The technology of asphalt–concrete mixture preparations and compaction is developed, which ensures high operational properties of road surfaces. It was established that it is possible to produce homogeneous asphalt concrete with phosphorus slag, gravel, mineral powder, and sand, unlike traditional mineral materials of natural origin, such as limestone.
{"title":"Determination of the possibility of using phosphorus slag in the road industry","authors":"Shilin Yang, Kateryna Krayushkina, Oleksandra Akmaldinova, Junwen Ji, Andrii Bieliatynskyi","doi":"10.2478/msp-2023-0030","DOIUrl":"https://doi.org/10.2478/msp-2023-0030","url":null,"abstract":"The use of crushed, granulated slag is now a rational direction in the use of phosphorus waste in various areas of construction. The modern state of science and technology and the accumulated experience allow to use almost all types of metallurgical slag for the production of road-building materials. The use of slag from other industries will expand the raw material base and improve its geographical location, increase material production and quality, reduce the distance of material transportation and reduce the road construction cost. The use of slag is an environmental task that will have a social impact. The study theoretically proved and experimentally established the feasibility of laying asphalt concrete coatings with phosphorus slag on roadways. The technology of asphalt–concrete mixture preparations and compaction is developed, which ensures high operational properties of road surfaces. It was established that it is possible to produce homogeneous asphalt concrete with phosphorus slag, gravel, mineral powder, and sand, unlike traditional mineral materials of natural origin, such as limestone.","PeriodicalId":18269,"journal":{"name":"Materials Science-Poland","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139054756","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Maciej Robert Roszak, Adam Kurzawa, Tetiana Roik, Oleg Gavrysh, Iulia Vitsiuk, Narcis Barsan, Dariusz Pyka, Mirosław Bocian, Krzysztof Jamroziak
This article analyzes the composition and distribution of chemical elements in friction films and their effect on the tribological properties of the self-lubricating, high-temperature antifriction composite based on EP975 powder nickel alloy with CaF2 solid lubricant. Analysis of the chemical elements by energy-dispersive spectroscopy (EDS) showed their uniform distribution, on both the composite’s surface and the counterface’s surface. The alloying elements’ uniform distribution leads to a uniform distribution of the corresponding phases and structural elements in the antifriction film. This ensures high tribological properties at high temperatures. Analysis of the material’s tribological properties, by means of metallographic and micro-X-ray research confirmed the correctness of the technology for producing the composite. Solid lubricant CaF2, alloying elements, and their corresponding phases form the continuous antiscoring film. The film influences the antifriction properties formation during the friction process and provides a self-lubricating mode under the action of high temperature and oxygen. Antiscoring, self-lubricating CaF2 films minimize wear of the friction pairs and defend the contact surfaces against intensive wear. The dense antifriction films have smooth microtopography, which stabilizes the high-temperature friction unit operation. Thus, the self-lubrication mode is realized for a long exploitation time. Tribological properties analysis allowed us to determine the ranges of rational exploitation modes for the material being studied: a load up to 5.0 MPa, a slide speed from 0.3 to 1.0 m/s, a temperature up to 800°C, in the air. The results obtained opened the opportunity to control the antifriction film formation and the composite’s tribological properties by the choice of the initial ingredients while taking into account the operating conditions.
{"title":"Friction films analysis and tribological properties of composite antifriction self-lubricating material based on nickel alloy","authors":"Maciej Robert Roszak, Adam Kurzawa, Tetiana Roik, Oleg Gavrysh, Iulia Vitsiuk, Narcis Barsan, Dariusz Pyka, Mirosław Bocian, Krzysztof Jamroziak","doi":"10.2478/msp-2023-0031","DOIUrl":"https://doi.org/10.2478/msp-2023-0031","url":null,"abstract":"This article analyzes the composition and distribution of chemical elements in friction films and their effect on the tribological properties of the self-lubricating, high-temperature antifriction composite based on EP975 powder nickel alloy with CaF<jats:sub>2</jats:sub> solid lubricant. Analysis of the chemical elements by energy-dispersive spectroscopy (EDS) showed their uniform distribution, on both the composite’s surface and the counterface’s surface. The alloying elements’ uniform distribution leads to a uniform distribution of the corresponding phases and structural elements in the antifriction film. This ensures high tribological properties at high temperatures. Analysis of the material’s tribological properties, by means of metallographic and micro-X-ray research confirmed the correctness of the technology for producing the composite. Solid lubricant CaF<jats:sub>2</jats:sub>, alloying elements, and their corresponding phases form the continuous antiscoring film. The film influences the antifriction properties formation during the friction process and provides a self-lubricating mode under the action of high temperature and oxygen. Antiscoring, self-lubricating CaF<jats:sub>2</jats:sub> films minimize wear of the friction pairs and defend the contact surfaces against intensive wear. The dense antifriction films have smooth microtopography, which stabilizes the high-temperature friction unit operation. Thus, the self-lubrication mode is realized for a long exploitation time. Tribological properties analysis allowed us to determine the ranges of rational exploitation modes for the material being studied: a load up to 5.0 MPa, a slide speed from 0.3 to 1.0 m/s, a temperature up to 800°C, in the air. The results obtained opened the opportunity to control the antifriction film formation and the composite’s tribological properties by the choice of the initial ingredients while taking into account the operating conditions.","PeriodicalId":18269,"journal":{"name":"Materials Science-Poland","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139054753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The mechanical properties of materials can be analysed under deformation conditions by various laboratory tests. However, such experimental investigations become extremely complicated and often even impossible at the lower length scales where the arrangement of the atomic planes is considered. In this case, computational materials science is a robust alternative to extend the capabilities of laboratory tests. Therefore, the molecular dynamics technique was selected in the current work to evaluate the role of the local grain crystallographic orientation during nanoindentation testing. A pure aluminium sample was selected as a case study. For the sake of clarity, two distinctively different crystallographic orientations cube {100}<001> and hard {110}<011> were investigated in a set of arrangements: monocrystalline, bicrystalline, and polycrystalline. The influence of the substrate and the neighbouring grains on the material response to local deformation was evaluated. The research used two types of indenters: spherical and sharp-tipped. Results obtained were analysed with respect to the arrangement of atoms and load-displacement curves. This research proved that the role of crystallographic orientation in material behaviour under nanoindentation should not be neglected during the interpretation of data from this test.
{"title":"Role of crystallographic orientation in material behaviour under nanoindentation: Molecular Dynamics study","authors":"Aneta Kurgan, Lukasz Madej","doi":"10.2478/msp-2023-0032","DOIUrl":"https://doi.org/10.2478/msp-2023-0032","url":null,"abstract":"The mechanical properties of materials can be analysed under deformation conditions by various laboratory tests. However, such experimental investigations become extremely complicated and often even impossible at the lower length scales where the arrangement of the atomic planes is considered. In this case, computational materials science is a robust alternative to extend the capabilities of laboratory tests. Therefore, the molecular dynamics technique was selected in the current work to evaluate the role of the local grain crystallographic orientation during nanoindentation testing. A pure aluminium sample was selected as a case study. For the sake of clarity, two distinctively different crystallographic orientations cube {100}<001> and hard {110}<011> were investigated in a set of arrangements: monocrystalline, bicrystalline, and polycrystalline. The influence of the substrate and the neighbouring grains on the material response to local deformation was evaluated. The research used two types of indenters: spherical and sharp-tipped. Results obtained were analysed with respect to the arrangement of atoms and load-displacement curves. This research proved that the role of crystallographic orientation in material behaviour under nanoindentation should not be neglected during the interpretation of data from this test.","PeriodicalId":18269,"journal":{"name":"Materials Science-Poland","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139054755","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mustafa Moussaoui, Abdelkhader Bendriss, Antar Tahiri, Ahmed Kellai, Souad Zergod, Hamza Djeloud, Brahim Kalil Hachi
This work investigates the effect of the notch on fatigue behavior by combining two methods: the extended finite element method (XFEM) and the averaged strain energy density (ASED) method, which considers the combined action of bending and shear loading. The ASED method has already been proven accurate for assessing the failure of components in the presence of sharp and blunt notches, and several results are available in the literature for different materials. These results were compared with those obtained from the experimental tests reported here. The main purpose of this study was twofold: The first part is an experimental study of fatigue in rotary bending of specimens weakened by U and V notches made of polymethyl-methacrylate (PMMA) material. Two values for the radius were used for the U-notches (0.2 and 2 mm) and two angles for the V-notches (20° and 140°). The second part of the study consisted of performing several simulation tests using the Cast3m software for different angles and radii. The local approach based on the mean value of the ASED acted over a finite-sized volume surrounding the highly stressed regions. The maximum principal stress located at the notch edge defined the center of the control volume. If the notch is blunt, the control volume assumes a crescent shape with its width measured along the notch bisector line. When the notch is considered pointed (V-notched) or is a crack, the control volume becomes a circle with its center at the notch tip. The presence of geometric discontinuities in structures affects their lifetime by reducing it, producing a high concentration of local energy around the notch tip. Good convergence was obtained between the numerical simulation and experimental results for the ASED in a finished zone surrounding the notch tip.
{"title":"Numerical and experimental analysis of the notch effect on fatigue behavior of polymethylmethacrylate metal based on strain energy density method and the extended finite element method","authors":"Mustafa Moussaoui, Abdelkhader Bendriss, Antar Tahiri, Ahmed Kellai, Souad Zergod, Hamza Djeloud, Brahim Kalil Hachi","doi":"10.2478/msp-2023-0027","DOIUrl":"https://doi.org/10.2478/msp-2023-0027","url":null,"abstract":"This work investigates the effect of the notch on fatigue behavior by combining two methods: the extended finite element method (XFEM) and the averaged strain energy density (ASED) method, which considers the combined action of bending and shear loading. The ASED method has already been proven accurate for assessing the failure of components in the presence of sharp and blunt notches, and several results are available in the literature for different materials. These results were compared with those obtained from the experimental tests reported here. The main purpose of this study was twofold: The first part is an experimental study of fatigue in rotary bending of specimens weakened by U and V notches made of polymethyl-methacrylate (PMMA) material. Two values for the radius were used for the U-notches (0.2 and 2 mm) and two angles for the V-notches (20° and 140°). The second part of the study consisted of performing several simulation tests using the Cast3m software for different angles and radii. The local approach based on the mean value of the ASED acted over a finite-sized volume surrounding the highly stressed regions. The maximum principal stress located at the notch edge defined the center of the control volume. If the notch is blunt, the control volume assumes a crescent shape with its width measured along the notch bisector line. When the notch is considered pointed (V-notched) or is a crack, the control volume becomes a circle with its center at the notch tip. The presence of geometric discontinuities in structures affects their lifetime by reducing it, producing a high concentration of local energy around the notch tip. Good convergence was obtained between the numerical simulation and experimental results for the ASED in a finished zone surrounding the notch tip.","PeriodicalId":18269,"journal":{"name":"Materials Science-Poland","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-12-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138552734","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ameer Malik Shaik, Bobbili Veera Siva Reddy, C. Chandrasekhara Sastry, J. Krishnaiah, B. Ramakrishna
This study investigates the blast mitigation capabilities of A286 steel micro-lattice structures produced through additive manufacturing. The research explores the effects of different manufacturing conditions, such as stress relief and heat treatment, on the mechanical properties and blast resistance of honeycomb and gyroid lattice structures in correlation with armour steel structures. Comprehensive evaluations, including surface morphology, corrosion resistance, and compressive residual stress analysis, reveal notable findings for micro-lattice structures. Micro-lattice structures demonstrated 57.23% higher corrosion resistance compared to conventional materials, presently available in the form of rolled homogeneous armour, medium hardness armour, and high-nitrogen steel. Additionally, honeycomb lattice structures exhibit compressive residual stresses of up to 581.90 MPa, providing significant advantages in blast mitigation potential. These results underscore the significance of lattice geometry, material microstructure, and residual stress in enhancing blast resistance. The research offers valuable insights into optimizing additive manufactured structures as an alternative modular solution for defence applications.
{"title":"Investigation of additive manufactured micro-lattice structures for defence applications","authors":"Ameer Malik Shaik, Bobbili Veera Siva Reddy, C. Chandrasekhara Sastry, J. Krishnaiah, B. Ramakrishna","doi":"10.2478/msp-2023-0023","DOIUrl":"https://doi.org/10.2478/msp-2023-0023","url":null,"abstract":"This study investigates the blast mitigation capabilities of A286 steel micro-lattice structures produced through additive manufacturing. The research explores the effects of different manufacturing conditions, such as stress relief and heat treatment, on the mechanical properties and blast resistance of honeycomb and gyroid lattice structures in correlation with armour steel structures. Comprehensive evaluations, including surface morphology, corrosion resistance, and compressive residual stress analysis, reveal notable findings for micro-lattice structures. Micro-lattice structures demonstrated 57.23% higher corrosion resistance compared to conventional materials, presently available in the form of rolled homogeneous armour, medium hardness armour, and high-nitrogen steel. Additionally, honeycomb lattice structures exhibit compressive residual stresses of up to 581.90 MPa, providing significant advantages in blast mitigation potential. These results underscore the significance of lattice geometry, material microstructure, and residual stress in enhancing blast resistance. The research offers valuable insights into optimizing additive manufactured structures as an alternative modular solution for defence applications.","PeriodicalId":18269,"journal":{"name":"Materials Science-Poland","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138515208","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Elhachemi Zehar, Abdallah Ouerdane, Boualem Chetti, Ali Çoruh
Using the ultrasonic spray pyrolysis technique, pure (ZnO) and manganese (4at%)-doped zinc oxide (ZnMnO) thin films were synthesized and treated with Ar+ sputtering in the UHV (ultra-high vacuum) system. In this regard, XRD (X-ray diffraction), XPS (X-ray photoelectron spectroscopy), PL (photoluminescence), and AFM (atomic force microscopy) techniques were applied to investigate the electronic and photonic properties of ZnO. XRD and XPS allowed us to identify the successful incorporation of Mn as a substitute for Zn, while PL and AFM images reveal a high tendency for crystalline grains on theZnMnO surface to aggregate to form small grains. However, bandgap narrowing, a redshift with considerable fluctuations in excitonic emission, and a perfect quenching of visible emission (400–640 nm) were observed. Investigations into defect-related emission in ZnMnO and ZnO compounds were conducted. The PL spectra of the prepared samples were measured and analyzed using Gaussian fitting. The PL of undoped ZnOexhibited an intense broad band with a peak at 550 nm. Two effects were shown to occur as a result of Mn doping: (i) a sharp quenching of self-activated PL with a progressive red-shift of the quenching’s spectral boundary; (ii) the appearance of a new emission band with a peak at 1.64 eV (756 nm), which dominates the PL spectrum and is noted in a band diagram; as well as a slight shift in the main line of ZnO, which is located at energy 3.275 eV (378.57nm).
采用超声波喷雾热解技术合成了纯(ZnO)掺杂锰(4at%)的氧化锌(ZnMnO)薄膜，并在特高压(超高真空)系统中进行了Ar+溅射处理。为此，采用XRD (x射线衍射)、XPS (x射线光电子能谱)、PL(光致发光)和AFM(原子力显微镜)技术研究了ZnO的电子和光子性质。XRD和XPS使我们能够识别Mn作为Zn的替代品的成功掺入，而PL和AFM图像显示znmno表面的晶体颗粒聚集形成小颗粒的趋势很高。然而，观察到带隙缩小，激子发射有相当大的波动红移，可见光发射(400-640 nm)完全猝灭。对ZnO和ZnMnO化合物的缺陷相关发射进行了研究。用高斯拟合对制备的样品进行了PL光谱测量和分析。未掺杂zno的光谱线在550 nm处呈现出较强的宽频带。Mn掺杂导致两种效应:(i)自激活PL急剧猝灭，猝灭光谱边界逐渐红移;(ii)在1.64 eV (756 nm)处出现了一个新的发射带，在PL光谱中占主导地位，并在带图中注明;ZnO的主线线在能量为3.275 eV (378.57nm)处发生了轻微的位移。
{"title":"Improving optical and morphological properties of Mn-doped ZnO via Ar ion sputtering followed by high-temperature UHV annealing","authors":"Elhachemi Zehar, Abdallah Ouerdane, Boualem Chetti, Ali Çoruh","doi":"10.2478/msp-2023-0024","DOIUrl":"https://doi.org/10.2478/msp-2023-0024","url":null,"abstract":"Using the ultrasonic spray pyrolysis technique, pure (ZnO) and manganese (4at%)-doped zinc oxide (ZnMnO) thin films were synthesized and treated with Ar<jats:sup>+</jats:sup> sputtering in the UHV (ultra-high vacuum) system. In this regard, XRD (X-ray diffraction), XPS (X-ray photoelectron spectroscopy), PL (photoluminescence), and AFM (atomic force microscopy) techniques were applied to investigate the electronic and photonic properties of ZnO. XRD and XPS allowed us to identify the successful incorporation of Mn as a substitute for Zn, while PL and AFM images reveal a high tendency for crystalline grains on theZnMnO surface to aggregate to form small grains. However, bandgap narrowing, a redshift with considerable fluctuations in excitonic emission, and a perfect quenching of visible emission (400–640 nm) were observed. Investigations into defect-related emission in ZnMnO and ZnO compounds were conducted. The PL spectra of the prepared samples were measured and analyzed using Gaussian fitting. The PL of undoped ZnOexhibited an intense broad band with a peak at 550 nm. Two effects were shown to occur as a result of Mn doping: (i) a sharp quenching of self-activated PL with a progressive red-shift of the quenching’s spectral boundary; (ii) the appearance of a new emission band with a peak at 1.64 eV (756 nm), which dominates the PL spectrum and is noted in a band diagram; as well as a slight shift in the main line of ZnO, which is located at energy 3.275 eV (378.57nm).","PeriodicalId":18269,"journal":{"name":"Materials Science-Poland","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138515200","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In order to investigate the material properties of maraging steel laser additive manufacturing, the cladding layers with different overlap rates on the surface of 18Ni300 were prepared by laser cladding technology, and the morphology, microstructure, and hardness of the cladding layer with different overlap rates were analyzed by various means. The results show that the macroscopic morphology of the cladding layer mainly presents three states under different overlap rates, and the change of overlap rate has no effect on the microstructure in the same area of the cladding layer, but does have an effect on the size of the cladding layer. In the end, the optimum overlap rate is 50%, the surface is smooth, the inner is free from defects, the bonding effect is good, and the metallographic structure is even with high hardness. Milling experiments were carried out on the material after laser additive manufacturing, and the surface morphology was observed, confirming a smooth and well-flattened surface with a roughness of 0.342 μm had been obtained. The suitable overlap rate can make the coating surface smoother, reduce the subsequent processing loss, and improve the production efficiency and powder utilization rate while ensuring the coating quality.
{"title":"Study on overlap rate and machinability of selected laser melting of maraging steel","authors":"Zeyu Yang, Weimin Li, Shufen Liu, Qi Gao","doi":"10.2478/msp-2023-0028","DOIUrl":"https://doi.org/10.2478/msp-2023-0028","url":null,"abstract":"In order to investigate the material properties of maraging steel laser additive manufacturing, the cladding layers with different overlap rates on the surface of 18Ni300 were prepared by laser cladding technology, and the morphology, microstructure, and hardness of the cladding layer with different overlap rates were analyzed by various means. The results show that the macroscopic morphology of the cladding layer mainly presents three states under different overlap rates, and the change of overlap rate has no effect on the microstructure in the same area of the cladding layer, but does have an effect on the size of the cladding layer. In the end, the optimum overlap rate is 50%, the surface is smooth, the inner is free from defects, the bonding effect is good, and the metallographic structure is even with high hardness. Milling experiments were carried out on the material after laser additive manufacturing, and the surface morphology was observed, confirming a smooth and well-flattened surface with a roughness of 0.342 <jats:italic>μ</jats:italic>m had been obtained. The suitable overlap rate can make the coating surface smoother, reduce the subsequent processing loss, and improve the production efficiency and powder utilization rate while ensuring the coating quality.","PeriodicalId":18269,"journal":{"name":"Materials Science-Poland","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-11-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138515201","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Biyang Tuo, Xiulong Shi, Jinwang Tian, Jianli Wang
To broaden the light response range of TiO2 and improve its photocatalytic activity, BiOCl/TiO2/MMT composite materials (BTMC) with outstanding photocatalytic performance were prepared by the sol-gel method with montmorillonite (MMT) as the supporting material, tetrabutyl titanate as titanium source and, bismuth nitrate pentahydrate as the bismuth source. The properties of the prepared materials were characterized by X-ray diffractometer (XRD), surface and porosity analysis (BET), scanning electron microscopy–energy-dispersive X-ray spectroscopy (SEM-EDS), transmission electron microscopy (TEM), X-ray photoelectron spectrometry (XPS), and ultraviolet-visible diffuse reflection spectroscopy (UV-Vis DRS). When the Bi/Ti molar ratio was 20%, the composite material exhibited a slit mesoporous structure, and its specific surface area was 109.02 m2/g, with optimum photocatalytic activity. TiO2 and BiOCl formed the type-II heterojunction on the surface of MMT, which facilitates the transfer of photogenerated electrons and holes, thus enhancing the photocatalytic activity of BTMC-20. The results of this study indicated that BTMC-20 is a promising photocatalytic composite material and has better photocatalytic properties under visible light.
{"title":"Preparation and characterization of BiOCl/TiO2/MMT composite materials","authors":"Biyang Tuo, Xiulong Shi, Jinwang Tian, Jianli Wang","doi":"10.2478/msp-2023-0025","DOIUrl":"https://doi.org/10.2478/msp-2023-0025","url":null,"abstract":"To broaden the light response range of TiO<jats:sub>2</jats:sub> and improve its photocatalytic activity, BiOCl/TiO<jats:sub>2</jats:sub>/MMT composite materials (BTMC) with outstanding photocatalytic performance were prepared by the sol-gel method with montmorillonite (MMT) as the supporting material, tetrabutyl titanate as titanium source and, bismuth nitrate pentahydrate as the bismuth source. The properties of the prepared materials were characterized by X-ray diffractometer (XRD), surface and porosity analysis (BET), scanning electron microscopy–energy-dispersive X-ray spectroscopy (SEM-EDS), transmission electron microscopy (TEM), X-ray photoelectron spectrometry (XPS), and ultraviolet-visible diffuse reflection spectroscopy (UV-Vis DRS). When the Bi/Ti molar ratio was 20%, the composite material exhibited a slit mesoporous structure, and its specific surface area was 109.02 m<jats:sup>2</jats:sup>/g, with optimum photocatalytic activity. TiO<jats:sub>2</jats:sub> and BiOCl formed the type-II heterojunction on the surface of MMT, which facilitates the transfer of photogenerated electrons and holes, thus enhancing the photocatalytic activity of BTMC-20. The results of this study indicated that BTMC-20 is a promising photocatalytic composite material and has better photocatalytic properties under visible light.","PeriodicalId":18269,"journal":{"name":"Materials Science-Poland","volume":null,"pages":null},"PeriodicalIF":1.1,"publicationDate":"2023-11-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138515194","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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