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Image analysis of titanium carbonitrides 碳氮化钛的图像分析
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3515
P. Martínek, P. Podaný
A manufacturer of crankshafts uses steel stock purchased from several vendors. The steels differ in their behaviour during the manufacture of the crankshaft, although they are the same grade. Some steel stock batches were repeatedly associated with much faster wear of grinding wheels than others. What is more, the crankshafts also suffered damage in production. As a result, the cost of production increased to unacceptable levels. Titanium precipitates were suspected to be the cause of the grinding wheels going dull. Therefore, an investigation was carried out to determine in which phases the titanium addition is present. The quantities, sizes, distributions and morphologies of particles containing titanium were measured using image analysis. Finally, the data were correlated to the method of steel production, the vendor and the titanium content.
一家曲轴制造商使用从几个供应商那里购买的钢库存。这些钢在制造曲轴时的性能不同,尽管它们是同一等级的。一些钢材库存批次的砂轮磨损速度比其他批次快得多。更重要的是,曲轴在生产中也遭受了损坏。结果,生产成本增加到不可接受的水平。钛析出物被怀疑是导致砂轮变钝的原因。因此,进行了一项调查,以确定在哪些相中添加钛。利用图像分析技术测量了含钛颗粒的数量、大小、分布和形态。最后,将数据与钢的生产方式、供应商和钛含量进行了相关性分析。
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引用次数: 1
Comparing two suppliers of aluminium alloys for foundry 比较两家铸造用铝合金供应商
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3593
M. Hugo, Milan Luňák, Jana Vítková, Š. Michna
In this time many suppliers are existed with raw material for foundry and the same as a minimum number has difficult task of choosing the most suitable one. How we can search the best of them for us? It is hard question. This article shows what can be checking around the raw material. The basic test is spectral analysis, what is indispensable every foundry in this time. Chemical composition absolutely does not show an important information about properties of alloy. A little bit more tests were made for compare 2 suppliers. There were used measuring as Dichte Index, Thermal analysis and metallographic cuts as necessary evidence for proper evaluation.
在这种情况下,为铸造提供原材料的供应商众多,同样是数量最少,选择最合适的供应商是一项艰巨的任务。我们怎样才能找到最好的呢?这是个很难回答的问题。这篇文章展示了什么可以检查周围的原材料。最基本的测试是光谱分析,这是每个铸造厂在这个时候必不可少的。化学成分绝对不能显示合金性能的重要信息。对比较2的供应商进行了更多的测试。采用硬度指数测量、热分析和金相切割作为评价的必要依据。
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引用次数: 0
Influence the NON-METALLIC INCLUSIONS on BENDING FATIGUE STRENGTH OF medium-carbon STRUCTURAL STEEL melted in an electric furnace 非金属夹杂物对电炉熔炼中碳结构钢弯曲疲劳强度的影响
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3459
T. Lipiński, Anna Wach, D. Karpisz
Non-metallic inclusions are one of the factors that influence the fatigue strength of steel. Although steel has a relatively small number of non-metallic inclusions, those impurities have a considerable impact on the material's technological and strength parameters, in particular fatigue strength and life. The study was performed on 7 heats produced in an industrial plant. Fourteen heats were produced in 140 ton electric furnaces. The experimental variants were compared in view of the applied melting technology and heat treatment options. The results were presented to account for the correlations between the fatigue strength coefficient during rotary bending, the diameter of and spacing between submicroscopic impurities. Equations for calculating the fatigue strength coefficient at each tempering temperature and a general equation for all tempering temperatures were proposed. Equations for estimating the fatigue strength coefficient based on the relative volume of submicroscopic non-metallic inclusions were also presented. The relationship between the fatigue strength and hardness of high-grade steel vs. the quotient of the diameter of impurities and the spacing between impurities were determined. The analyzed material was one grade of medium-carbon structural steel. The proposed linear regression equations supported the determination of fatigue strength coefficient and bending fatigue strength as a function of hardness taking into account impurities. The proposed equations contributes to the existing knowledge base of practices impact of impurities with various diameters and spacing between non-metalic inclusion on fatigue strength.
非金属夹杂物是影响钢疲劳强度的因素之一。虽然钢中含有相对较少的非金属夹杂物,但这些杂质对材料的工艺和强度参数,特别是疲劳强度和寿命有相当大的影响。这项研究是在一个工业工厂产生的7种热量上进行的。140吨重的电炉产生了14次热量。针对不同的熔炼工艺和热处理方案,对不同的实验变体进行了比较。结果说明了旋转弯曲时的疲劳强度系数与亚微观杂质的直径和间距之间的相关性。提出了各回火温度下疲劳强度系数的计算公式和各回火温度下的一般公式。提出了基于亚微观非金属夹杂物相对体积的疲劳强度系数估算公式。确定了高档钢的疲劳强度和硬度与杂质直径商和杂质间距的关系。分析的材料为一种中碳结构钢。提出的线性回归方程支持将杂质考虑在内的疲劳强度系数和弯曲疲劳强度作为硬度函数的确定。提出的方程有助于现有的实践知识基础,即不同直径的杂质和非金属夹杂物之间的间距对疲劳强度的影响。
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引用次数: 3
Reaction sintering of metal-ceramic AlSi-Al2O3 composites manufactured by binder jetting additive manufacturing process 粘结剂喷射增材制造工艺制备AlSi-Al2O3金属陶瓷复合材料的反应烧结研究
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3618
V. Sufiiarov, Artem Kantyukov, I. Polozov
Metal-ceramic composites are attractive materials for various applications due to their high specific strength, wear resistance, thermal stability, and good high-temperature mechanical properties. Binder jetting additive manufacturing is a promising way of manufacturing metal-ceramic composite parts with complex geometry. In this work, Al 2 O 3 - Si powder blend was used to produce metal-ceramic green-parts by binder jetting process. The green-parts were then subjected to reaction sintering and subsequent liquid metal infiltration with aluminum alloy at 1200 ºC. The microstructure and phase composition of the obtained samples were studied using scanning electron microscopy and X-Ray diffraction analysis. Mechanical properties were evaluated using microhardness measurements and compressive tests.
金属陶瓷复合材料由于其高比强度、耐磨性、热稳定性和良好的高温机械性能,在各种应用中都是有吸引力的材料。粘结剂喷射增材制造是一种很有前途的制造复杂几何形状金属陶瓷复合材料零件的方法。本文采用粘结剂喷射法制备了Al - 2o3 - Si共混粉末的金属陶瓷绿件。然后对绿色部分进行反应烧结,随后用铝合金在1200℃下渗透液态金属。采用扫描电子显微镜和x射线衍射分析研究了样品的显微组织和相组成。通过显微硬度测量和压缩测试来评估机械性能。
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引用次数: 5
Comparison of the Leachability of a silica-rich quartzite conglomerates containing a layer of pyrite Using CIP and CIL 用CIP和CIL比较含一层黄铁矿的富硅石英岩砾岩的浸出性
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3632
M. Kalenga, J. Ntuli
South Africa is amongst the influential producers of gold worldwide. Many results have been published on its ores and different parameters defined. Although the carbon-in-pulp (CIP) and carbon-in-leach (CIL) have been largely investigated, optimum parameters change with the chemical composition of the ore based on the geological origins. The ore used in the present work was silica-rich quartzite conglomerates containing a layer of pyrite. The optimization of the gold recovery from the ore used and the better processing route between CIP and CIL were investigated and adopted. Alternating variations were conducted and most suitable leaching parameters were identified. Mineralogical test work conducted in the present investigation led to a better understanding of the ore mineralogy and assisted efficiently in resolving the reasons of impeding cyanidation with this ore. Also, the mineralogical results were compared with the ore, which is treated conventionally and identification of the problematic minerals was possible. XRD, XRF and AAS were used for characterization.
南非是世界上最有影响力的黄金生产国之一。已经发表了许多关于它的矿石和不同参数的研究结果。虽然对矿浆碳(CIP)和浸出碳(CIL)进行了大量的研究,但根据地质成因,最佳参数随矿石化学成分的变化而变化。本研究使用的矿石为含一层黄铁矿的富硅石英岩砾岩。对所选矿石的金回收率进行了优化研究,并确定了CIP和CIL之间较好的工艺路线。进行了交替变化,确定了最合适的浸出参数。在本次调查中进行的矿物学测试工作使人们对矿石矿物学有了更好的了解,并有效地帮助解决了阻碍该矿石氰化的原因。此外,矿物学结果与常规处理的矿石进行了比较,从而有可能识别出有问题的矿物。采用XRD、XRF、AAS进行表征。
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引用次数: 0
Protection of lead by preservation acrylic coatings in acetic vapors environment 醋酸蒸气环境中丙烯酸防腐涂料对铅的保护作用
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3553
Š. Msallamová, M. Kouřil, F. Mícek, Kateryna Popova, Jessika Yerbe
A lead was used in the past in a variety of applications for example for roofs of churches, garden ornaments, lead seals, and organ pipes. Lead alloys are susceptible to a corrosion attack in an environment containing volatile organic compounds especially acetic acid vapors. The source of acetic acid vapors is mainly wood, glued joints, some varnishes, plastics, and paints. In the acetic acid vapors environment, the corrosion rate of Pb alloys rapidly increases. The study of protective properties of acrylic coatings of lead (Paraloid 72, B48N a B44) in an environment containing acetic acid vapors was the aim of this work. The acrylic coatings were prepared with or without 1,2,3, - Benzotriazole (BTA). Painted lead samples were exposed in an environment containing acetic acid vapors for 8 weeks. The color change of lead surfaces was observed by a spectrophotometer during the exposition. The preservation effect of acrylic coatings were evaluated by the mass gain of lead samples during the exposition. The surface of the lead samples after exposition was observed by optical microscopy, and X-ray diffraction analysis. The research proved that the Paraloid B44 with BTA has the best protective properties of lead in an environment containing acetic acid vapors from all tested coatings.
铅在过去被用于各种用途,例如教堂的屋顶,花园装饰品,铅封和风琴管。铅合金在含有挥发性有机化合物特别是醋酸蒸气的环境中易受腐蚀。醋酸蒸汽的来源主要是木材、胶合接头、一些清漆、塑料和油漆。在醋酸蒸气环境中,Pb合金的腐蚀速度迅速加快。本文研究了含铅丙烯酸涂料(Paraloid 72, B48N和B44)在醋酸蒸汽环境中的防护性能。采用添加或不添加1,2,3,-苯并三唑(BTA)制备丙烯酸涂料。涂铅样品在含有乙酸蒸气的环境中暴露8周。用分光光度计观察了暴露过程中铅表面的颜色变化。通过展览过程中铅样品的质量增益来评价丙烯酸涂料的保存效果。用光学显微镜和x射线衍射仪对暴露后的铅样品表面进行了观察。研究证明,在含乙酸蒸汽的环境中,含BTA的拟合B44对铅的保护性能最好。
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引用次数: 0
Harmonization of technical demands to paint coatings as a component of competitiveness increase on the international market 技术要求的统一是提高涂料在国际市场上竞争力的一个组成部分
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3538
V. Boldyrev, V. Men’Shikov, F. Il’Darkhanova, V. Puchkova, Daria Strapolova
The specific feature of modern Russian paintwork material (PWM) market is an import share rise along with foreign manufactures extensive expansion. Russian market range of PWM contents above 3000 items, considering both PWM being used in household and foreign products. Import products are 25-30% of Russian PWM market volume. High level of rivalry, marketing battle between foreign and domestic manufactures is common for it. Major PWM exporting countries in Russia are: German (14% of total amount), Finland (11%), Belarus (9,7%), Estonian (9%), USA(8,9%), Korea (7,5%), Lithuania (7%). According to «Symbol Marketing» agency data, Tikkurila (Finland), AkzoNobel (Sweden), Meffest AG (German), PPG-Helios (Italy-Slovenia), BASF (German), Jobi (German), Teknos (Finland), Marshall (Turkey), DuPont (USA) lead among the manufacturing companies exporting their PWM in Russia. The main domestic PWM competitiveness rise condition is establishment of common quality, endurance, ecological safety and evaluating methods standards accepted as in Russia so in other countries. This scientific research made for PWM manufacturers and consumers solves International Organization for Standardization (ISO) and Russian National Standart (GOST) interaction problem in order to standardize Russian PWM output and increase its competitiveness at the international market.
现代俄罗斯油漆材料(PWM)市场的具体特征是随着国外制造商的广泛扩张,进口份额上升。考虑到PWM在家用和国外产品中的应用,俄罗斯市场的PWM内容范围在3000项以上。进口产品占俄罗斯PWM市场总量的25-30%。高水平的竞争,国内外制造商之间的营销战是常见的。俄罗斯主要的PWM出口国为:德国(占总量的14%)、芬兰(11%)、白俄罗斯(9.7%)、爱沙尼亚(9%)、美国(8.9%)、韩国(7.5%)、立陶宛(7%)。根据«Symbol Marketing»机构的数据,Tikkurila(芬兰)、AkzoNobel(瑞典)、Meffest AG(德国)、PPG-Helios(意大利-斯洛文尼亚)、BASF(德国)、Jobi(德国)、Teknos(芬兰)、Marshall(土耳其)、DuPont(美国)在向俄罗斯出口PWM的制造公司中处于领先地位。国内PWM竞争力提高的主要条件是建立了与俄罗斯和其他国家通用的质量、耐久性、生态安全性和评价方法标准。这项针对PWM制造商和消费者的科学研究解决了国际标准化组织(ISO)和俄罗斯国家标准(GOST)的相互作用问题,从而使俄罗斯PWM输出标准化,提高其在国际市场上的竞争力。
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引用次数: 2
Failure analysis of anchoring system of a Circulating Fluidized Bed Boiler 某循环流化床锅炉锚固系统失效分析
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3509
A. Dudek, Jerzy Cugowski
The combustion of fuels plays an important role in the field of industry and power engineering. Circulating fluidized bed combustion (CFBC) is a clean technology and also it is a convenient method of energy production from a wide range of fuels. The present paper reports the results of the authors' investigation focused on the analysis of heat resistant steel samples from one of the Polish circulating fluidized bed boilers. The anchors were degraded during boiler operation and lost their mechanical durability. To determine the reasons for anchors degradation the materials were subjected to microstructural analysis using a light microscope, scanning microscopy Joel JSM 5400 equipped with EDS. In the case of the investigated anchor samples, the formation of a large number of hard and chromium-rich intrusions was determined. The reason for material problems as incorrect positioning of the anchors in the refractory material was determined.
燃料的燃烧在工业和动力工程领域中占有重要的地位。循环流化床燃烧(CFBC)是一种清洁技术,也是一种利用多种燃料生产能源的简便方法。本文报道了作者对波兰某循环流化床锅炉耐热钢试样的分析结果。锚在锅炉运行过程中发生退化,失去了机械耐久性。为了确定锚固降解的原因,采用光学显微镜、配备能谱仪的Joel JSM 5400扫描显微镜对材料进行微观结构分析。在所调查的锚样中,确定了大量硬的富铬侵入物的形成。确定了耐火材料中锚定位不正确等材料问题的原因。
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引用次数: 0
COMPLEX EVALUATION OF STRUCTURE AND MATERIAL PROPERTIES OF SELECTED WELDING JOINTS 选定焊接接头的结构和材料性能的复杂评价
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3520
M. Šmátralová, P. Čížek, L. Kander
The National Action Plan for the Development of Nuclear Energy in the Czech Republic envisages the preparation for the construction of two new blocks of the nuclear power plant in the location of Dukovany and the location of Temelín. Although the final supplier of these units is not clear yet, there are good prospects that some components could be produced by the local producers. The paper presents the principal results of development and verification of production technology of weld joints of pressure vessels components for primary circuits of the nuclear power plants of MIR 1200 type. Attention was focused to the influence of welding technology SAW and SMAW including post weld heat treatment on the final mechanical and fracture properties of welded joints of large forgings. Homogeneous weld joints were made of 10GN2MFA low-alloy steel while heterogeneous weldment was prepared from 10GN2MFA and 08CH18N10T stainless steel. The welded joints were subjected to a comprehensive evaluation of the material properties, especially the evaluation of macro and microstructure, tensile test and impact bending test as well as unconventional mechanical properties such as initial value of the J-integral, the stress intensity factor and low cycle fatigue limit. The effect of welding technology on the transition temperature (Tk0) of the weld joint was evaluated, too.
捷克共和国发展核能国家行动计划设想在杜科瓦尼地点和Temelín地点筹备建造两座新的核电站。虽然这些装置的最终供应商还不清楚,但一些部件可以由当地生产商生产的前景很好。本文介绍了MIR - 1200型核电站一次回路压力容器部件焊接接头生产工艺开发与验证的主要成果。重点研究了包括焊后热处理在内的焊接工艺SAW和SMAW对大型锻件焊接接头最终力学性能和断裂性能的影响。采用10GN2MFA低合金钢制备均匀焊缝接头,采用10GN2MFA和08CH18N10T不锈钢制备非均匀焊件。对焊接接头的材料性能进行了综合评价,特别是宏观和微观组织评价、拉伸试验和冲击弯曲试验以及j积分初值、应力强度因子和低周疲劳极限等非常规力学性能。还评价了焊接工艺对焊缝转变温度(Tk0)的影响。
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引用次数: 1
electron beam additive manufacturing of Ni-Ti alloy 镍钛合金的电子束增材制造
Pub Date : 2020-01-01 DOI: 10.37904/metal.2020.3619
M. Węglowski, S. Błacha, K. Kwieciński, P. Śliwiński, J. Dutkiewicz, Ł. Rogal
Shape memory alloys (such as Ni-Ti) are a unique class of active materials, which can recover to their original shape after applying stimuli, such as deformation due to stress, heat or magnetic field. These alloys possess attractive characteristics such as ability to provide large recoverable strain during mechanical loading (pseudoelasticity), shape recovery upon heating (shape memory effect), and potent biocompatibility, which make alloys one of the suitable actuators for biomedical applications. In the present paper the results of microstructure, martensitic transformation behaviour and superelastic properties of Ni-Ti alloys fabricated using a EBAM technique, which applies wire as the additive material were presented. It was revealed that the microstructure of the deposit exhibited typical solidification features of columnar grains of austenite, due to epitaxial growth mechanism. Moreover, EBSD investigations revealed that the preferential grain orientation in [001] is a result of the adopted material layer deposition. TEM studies have shown presence of martensitic needles partially twinned within austenitic matrix, and a low dislocation density within austenite confirming ability of the EBAM manufactured sample to pseudoelastic deformation at room temperature.
形状记忆合金(如Ni-Ti)是一类独特的活性材料,在施加刺激(如应力、热或磁场引起的变形)后可以恢复到原来的形状。这些合金具有吸引人的特点,如在机械加载时提供大的可恢复应变(假弹性),加热时形状恢复(形状记忆效应),以及强大的生物相容性,使合金成为生物医学应用的合适执行器之一。本文介绍了以金属丝为添加剂的EBAM工艺制备的Ni-Ti合金的显微组织、马氏体相变行为和超弹性性能。结果表明,由于外延生长机制的作用,镀层的显微组织表现为典型的奥氏体柱状晶粒凝固特征。此外,EBSD研究表明[001]中的晶粒取向优先是采用材料层沉积的结果。透射电镜研究表明,在奥氏体基体中存在部分孪晶的马氏体针状结构,并且在奥氏体中存在较低的位错密度,这证实了EBAM制造的样品在室温下具有假弹性变形的能力。
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引用次数: 0
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METAL 2020 Conference Proeedings
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