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A workflow to create geometallurgical clusters without looking directly at geometallurgical variables 创建地质冶金集群的工作流程,无需直接查看地质冶金变量
IF 4.9 2区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2025-01-08 DOI: 10.1016/j.mineng.2024.109171
F.G.F. Niquini , I.A. Andrade , J.F.C.L. Costa , V.M. Silva , R.S. Marcelino
Cluster analysis is frequently used to help in individualizing stationary domains. Its application in creating geometallurgical clusters can follow two approaches. The first utilizes geometallurgical test variables in cluster analysis to define domains based on the geometallurgical database. This approach, common in mining, often lacks sufficient data for accurate 3D modelling. The second approach uses the secondary information widely available in the deposit, such as the chemical, lithological and mineralogical variables, present in the core samples, and correlating them with the metallurgical variables presented in the smaller geometallurgical database. This indirect solution chooses the highly correlated variables with the geometallurgical response using only them as inputs in the cluster analysis. This approach permits defining the geometallurgical clusters using only drillhole samples, without directly looking at the geometallurgical information. Once the drillhole samples outnumber geometallurgical samples in the case study (4862 against 40), the spatial modeling of the geometallurgical clusters using secondary information is more accurate. The workflow proposed starts using recursive feature elimination to define the main explanatory variables affecting the target geometallurgical response. Next, clustering construction using k-means and other techniques is made, followed by building a decision tree to assign each drillhole sample to a geometallurgical cluster. Finally, it concludes with the 3D modeling to classify each block according to its geometallurgical domain. All analyses were made in the Viga mine, an iron ore deposit located at the iron quadrangle in Minas Gerais state, Brazil. The workflow and results proved to be adequate and promising to be implemented at industrial scale.
聚类分析经常用于帮助个性化的平稳域。它在创建地质冶金集群中的应用可以遵循两种方法。第一种方法是利用聚类分析中的地质测试变量来定义基于地质数据库的域。这种方法在采矿中很常见,通常缺乏足够的数据来进行准确的3D建模。第二种方法利用矿床中广泛存在的次要信息,如岩心样品中存在的化学、岩性和矿物学变量,并将它们与较小的地质冶金数据库中提供的冶金变量相关联。这种间接的解决方案选择高度相关的变量与地质冶金的响应只使用他们作为输入在聚类分析。这种方法允许仅使用钻孔样本来定义地质冶金簇,而无需直接查看地质冶金信息。在案例研究中,一旦钻孔样本数量超过了地质样本数量(4862对40),利用二次信息对地质集群的空间建模就会更加准确。提出的工作流程首先使用递归特征消去来定义影响目标地质响应的主要解释变量。接下来,使用k-means等技术进行聚类构建,然后构建决策树将每个钻孔样本分配到一个地质冶金聚类中。最后进行三维建模,根据每块块的地矿学域对每块块进行分类。所有的分析都是在维加矿进行的,维加矿是位于巴西米纳斯吉拉斯州铁四边形的铁矿石矿床。工作流程和结果证明是充分的,并有望在工业规模上实施。
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引用次数: 0
SAG mill ball diameter semi-theory based on pebble fracture strength and DEM validation 基于卵石断裂强度和DEM验证的SAG磨球直径半理论
IF 4.9 2区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2025-01-06 DOI: 10.1016/j.mineng.2024.109169
Yunxiao Li , Qingfei Xiao , Guobin Wang , Boyuan Sun , Chao Zheng , Saizhen Jin , Qingkai Wang
The semi-autogenous grinding (SAG) mill, widely used in large mineral processing plants, is known for its high throughput and production efficiency. However, an accumulation of pebbles can lead to a reduction in throughput and an increase in power consumption during the grinding process. This study investigates the strength of pebbles in conjunction with Davis’ theory of ball movement, considering parameters such as pebble size, mill diameter, rotational speed, filling rate, and grinding concentration. Based on these factors, a semi-theoretical formula is developed to determine the optimal diameter of SAG mill balls. The validity of this formula was verified using discrete element numerical simulations and the Tavares breakage model. The results show that for a SAG mill with dimensions of Φ6.7 × 3.4 m at a tin mine, the steel ball gradation calculated by the semi-theoretical formula is n (Φ140mm): n (Φ110mm) = 1:2. According to the Tavares breakage model simulation, the total crushed mass for the 140–110 scheme was 75.87 kg, which represents a 6.59 % increase compared to the 71.18 kg from the on-site 120–100 scheme. In addition, the cumulative impact power of the steel balls on the rock in the 140–110 scheme was 0.23 % higher than in the on-site 120–100 scheme, while the cumulative impact power of the rock on itself increased by 3.36 %. These findings suggest that the proposed formula has the potential to reduce pebble accumulation and improve grinding efficiency.
半自磨(SAG)磨机以其高产能和生产效率高而广泛应用于大型选矿厂。然而,鹅卵石的堆积会导致研磨过程中吞吐量的降低和功耗的增加。本研究结合Davis的球运动理论考察了卵石的强度,考虑了卵石粒度、磨机直径、转速、填充率和磨矿浓度等参数。在此基础上,推导出一种半理论公式来确定SAG磨球的最佳直径。通过离散元数值模拟和Tavares断裂模型验证了该公式的有效性。结果表明:对于某锡矿尺寸为Φ6.7 × 3.4 m的SAG磨机,用半理论公式计算的钢球级配为n (Φ140mm): n (Φ110mm) = 1:2。根据Tavares破碎模型模拟,140-110方案的总破碎质量为75.87 kg,比现场120-100方案的71.18 kg增加了6.59%。与现场120 ~ 100方案相比,140 ~ 110方案中钢球对岩石的累计冲击能力提高了0.23%,而岩石对自身的累计冲击能力提高了3.36%。上述结果表明,该配方具有减少卵石堆积、提高磨矿效率的潜力。
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引用次数: 0
Study of alkaline hydrometallurgical process for stibnite flotation tailings reprocessing: Semi-pilot antimony leaching
IF 4.9 2区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2025-01-04 DOI: 10.1016/j.mineng.2024.109168
Seydou Dembele , Ata Akcil , Sandeep Panda
Nowadays, tailings management and scarcity of raw materials are both topics that are much discussed in the mining sector. Recycling is therefore a sustainable method of extracting metals from secondary resources for tailings management and the supply of critical metals such as antimony. Alkaline leaching was carried out using mixture of sodium sulfide (Na2S) and sodium hydroxide (NaOH). Optimisation tests at laboratory scale allow the optimum parameters to be set at 25 % pulp density, 0.97 M Na2S, 2.5 M NaOH, 70 °C, 300 rpm for 60 min. The antimony dissolution rates were 99.13 % and 97.00 % at bench and semi-pilot scale, respectively. On the other hand, hydrogen peroxide (H2O2) was used to precipitate antimony from the leach solution. About 99 % of Sb precipitation efficiency was achieved under 5/1 Pregnant Leach Solution (PLS)/Hydrogen peroxide (H2O2) ratio, 30 °C, 300 rpm for 90 min.
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引用次数: 0
Resource utilization of phosphate tailings by calcination and leaching with dilute H3PO4 solution 稀H3PO4煅烧浸出磷矿尾矿资源化利用
IF 4.9 2区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2025-01-02 DOI: 10.1016/j.mineng.2024.109172
Shengyang Ding, Lu Yin, Tao Zhang, Li Lv, Wenxiang Tang, Shengwei Tang
Phosphate tailing is a solid waste from the process of phosphate resource utilization. It is rich in phosphorus, calcium, and magnesium. Exploring a profitable comprehensive utilization route of phosphate tailings is crucial for the disposal of phosphate tailings. A utilization route of P, Ca and Mg in phosphate tailings was proposed in this work. Phosphate tailings were first calcinated and leached with dilute H3PO4. The Ca and Mg from dolomite in phosphate tailings were selectively dissolved into leaching liquor, followed by the precipitation of CaHPO4 and MgNH4PO4 from the leaching liquor through pH adjustment. After leaching, the unreacted fluorapatite and silicates became a phosphate concentrate with a P2O5 content of 29.89 wt%. The phosphorus in the tailings was recovered in the form of concentrated phosphate ore with a recovery rate of 99.86 %. Decomposition kinetics of dolomite in the calcination process was studied. The activation energy is 195.82 kJ/mol and the pre-exponential factor is 1.73 × 109 s−1. The results provide an effective route of utilizing phosphate tailings.
磷酸尾矿是磷矿资源化利用过程中产生的固体废物。它富含磷、钙和镁。探索一条效益良好的磷矿尾矿综合利用路线对磷矿尾矿的处置至关重要。提出了磷、钙、镁在磷酸尾矿中的利用途径。首先对磷酸尾矿进行煅烧,用稀H3PO4浸出。将磷酸盐尾矿中白云石中的Ca和Mg选择性溶解到浸出液中,通过pH调节,浸出液中沉淀出CaHPO4和MgNH4PO4。浸出后,未反应的氟磷灰石和硅酸盐成为P2O5含量为29.89 wt%的磷酸盐精矿。尾矿中的磷以磷精矿的形式回收,回收率达99.86%。研究了白云石在煅烧过程中的分解动力学。活化能为195.82 kJ/mol,指前因子为1.73 × 109 s−1。为磷矿尾矿的资源化利用提供了一条有效途径。
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引用次数: 0
Challenges associated with the recovery of Co– and As-bearing minerals from aged mine tailings 从老矿尾矿中回收含钴和含砷矿物的挑战
IF 4.9 2区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-12-31 DOI: 10.1016/j.mineng.2024.109167
Samuel Teillaud , Lucie Coudert , Yassine Ait-Khouia , Mostafa Benzaazoua , Marie Guittonny , Baptiste Laubie , Marie-Odile Simonnot
The global demand for cobalt (Co), essential for “clean” energy technologies, has raised interest in identifying secondary sources, including mine tailings. This study evaluates the potential of historic silver (Ag) mine tailings in Ontario, Canada, as a secondary Co source and for arsenic (As) mitigation, offering economic and environmental benefits. Physico–chemical and mineralogical characterization revealed promising Co (1 310 mg/kg) and As (5 245 mg/kg) contents in fine silty tailings (D80 = 55 μm), with key Co-As-bearing minerals (e.g., safflorite, skutterudite, cobaltite, erythrite) exhibiting significant alteration and association with silicates (i.e., albite, quartz, chlorite). The complex mineralogy and fine particle size are challenging for conventional processing methods.
Tests using gravity separation achieved limited Co and As recoveries (4.2% and 7.3%, respectively), despite effective preconcentration (x24.8 and x38, respectively). Flotation experiments, performed in Denver cell with xanthate and hydroxamic acid collectors, achieved concentration factors of 2.5 for Co (70% recovery) and 3.0 for As (80% recovery). Pre-treatment with sonication further enhanced flotation efficiency. Analysis of entrainment index and particle size distribution emphasized the role of hydroxamate in particle recovery.
The study highlights the need for innovative processing strategies to overcome challenges posed by fine particle size, mineral alteration, and complex associations. However, Co grades comparable to global smelter concentrates were achieved, suggesting the potential for sustainable reprocessing of aged mine tailings. Future research should focus on optimizing reprocessing techniques to enhance resource efficiency and sustainability.
钴对“清洁”能源技术至关重要,全球对钴的需求提高了人们对确定二次来源(包括矿山尾矿)的兴趣。本研究评估了加拿大安大略省历史悠久的银(银)矿尾矿作为二级Co来源和砷(as)缓解的潜力,提供经济和环境效益。细粉质尾矿(D80 = 55 μm)中Co (1 310 mg/kg)和As (5 245 mg/kg)含量较高,主要含Co-As矿物(红铁矿、角闪石、钴矿、赤铜矿)蚀变明显,与硅酸盐(钠长石、石英、绿泥石)伴生。复杂的矿物学和细粒度对传统的处理方法提出了挑战。
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引用次数: 0
Amidoxime collectors: Lead-free flotation performance and adsorption mechanism in the separation of wolframite, quartz and calcite 偕胺肟捕收剂:黑钨矿、石英和方解石的无铅浮选性能及吸附机理
IF 4.9 2区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-12-31 DOI: 10.1016/j.mineng.2024.109170
Guangsheng Zeng , Wei Weng , Shuiping Zhong , Xiaopeng Chi , Jiaozhong Cai , Wen Tan , Junnan Chen
The novel amidoxime-based collectors, 4-pyridylamidoxime (PA), 3-ethyl-4-pyridylamidoxime (EPA), and 3-methyl-5-tert-butyl-4-pyridylamidoxime (MBPA), were introduced in the lead-free flotation separation of wolframite from quartz and calcite. Compared with PA, EPA, and the traditional collector benzohydroxamic acid (BHA), MBPA exhibited a better separation and recovery capacity to wolframite ore. 4.0 × 10-4 mol/L MBPA recovered more than 80 % wolframite, ∼24 % calcite, and ∼ 26 % quartz at pH 8.0 without Pb2+ ions. Under the same conditions, BHA only floated out less than 35 % wolframite. The adsorption amount results exhibited a stronger adsorption ability of MBPA than BHA on wolframite surface. Further, the results of zeta-potential, FTIR, XPS and density functional theory (DFT) calculation revealed that MBPA could chemisorb on wolframite surface to form −N-Fe and −O-Fe bonds. MBPA had stronger electron-donating ability and weaker electron-accepting ability than BHA, which exhibited higher reaction activity. It was clear that MBPA was an excellent collector in the lead-free flotation separation of wolframite from calcite and quartz.
采用新型偕胺肟类捕收剂4-吡啶酰胺肟(PA)、3-乙基-4-吡啶酰胺肟(EPA)和3-甲基-5-叔丁基-4-吡啶酰胺肟(MBPA)进行了黑锰矿与石英、方解石的无铅浮选分离。与PA、EPA和传统捕收剂苯甲羟肟酸(BHA)相比,MBPA对黑钨矿具有更好的分离和回收能力,在pH 8.0条件下,4.0 × 10-4 mol/L MBPA在不含Pb2+离子的情况下,可回收80%以上的黑钨矿、~ 24%的方解石和~ 26%的石英。在相同的条件下,底部钻具组合只浮出不到35%的黑钨矿。结果表明,MBPA在黑钨矿表面的吸附能力强于BHA。此外,zeta电位、FTIR、XPS和密度泛函理论(DFT)计算结果表明,MBPA可以在黑钨矿表面化学吸附形成−N-Fe和−O-Fe键。与BHA相比,MBPA给电子能力更强,接受电子能力更弱,反应活性更高。表明MBPA是一种优良的捕收剂,可用于黑钨矿与方解石、石英的无铅浮选分离。
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引用次数: 0
Correlation between the kinematic properties of carrier particle bubbles and their particle entrainment phenomena 载流子气泡的运动特性与其粒子夹带现象之间的关系
IF 4.9 2区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-12-28 DOI: 10.1016/j.mineng.2024.109162
Xiaofeng Li, Xuan Wu, Junbiao Wang, Hui Dong, Zhengyang Wang
During froth flotation, minerals enter the concentrate either through true flotation or mechanical entrainment. These two processes occur simultaneously and they determine the efficiency and selectivity of the process. This study proposes use of a bubble surface load value to quantitatively characterize the level of particle adhesion on bubbles. A visual experimental platform was constructed using a high-speed camera system and poly (methyl methacrylate) (PMMA) particles as the base material for the particle bed. Variations in the bubble surface load values and particle entrainment phenomena were evaluated under different particle sizes and superficial gas velocities. The morphological changes in particle-laden bubbles, including bubble size, vertical ascending velocity, and horizontal motion velocity, were evaluated. The correlation between the ascending behavior of particle-laden bubbles and the particle entrainment phenomenon was also explored. The results indicated that, under a particle size of 300 μm, increasing the superficial gas velocity reduced particle adhesion on bubbles, resulting in a lower bubble surface load value. However, using a smaller particle size (300 μm) effectively mitigated the impact of increased superficial gas velocity on the bubble surface load value. Bubbles with a surface load value exceeding 40 % exhibited more significant particle entrainment in the vortex beneath them, whereas those with a surface load value below 40 % showed less entrainment. The results demonstrated that the degree of particle entrainment was correlated with the vortex shedding and the motion characteristics of the bubbles. These findings provide valuable insights for developing advanced mineral flotation strategies.
在泡沫浮选过程中,矿物通过真正的浮选或机械夹带进入精矿。这两个过程同时发生,它们决定了过程的效率和选择性。本研究建议使用气泡表面负载值来定量表征气泡上颗粒粘附的水平。采用高速摄像系统,以聚甲基丙烯酸甲酯(PMMA)颗粒为基材,搭建了可视化实验平台。研究了不同粒径和表面气速下气泡表面载荷值和颗粒夹带现象的变化。研究了载颗粒气泡的形态变化,包括气泡大小、垂直上升速度和水平运动速度。探讨了载粒子气泡的上升行为与粒子夹带现象之间的关系。结果表明,在粒径为300 μm时,增大表面气速可降低颗粒在气泡上的附着,从而降低气泡表面负载值;然而,使用较小的粒径(300 μm)可以有效地减轻表面气速增加对气泡表面负载值的影响。气泡表面载荷值大于40%时,其下方漩涡中的颗粒夹带更明显,而表面载荷值小于40%时,其下方漩涡中的颗粒夹带较少。结果表明,颗粒的夹带程度与气泡的涡脱落和运动特性有关。这些发现为开发先进的矿物浮选策略提供了有价值的见解。
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引用次数: 0
Microencapsulation of Acidithiobacillus thiooxidans in a biopolymeric matrix of gum arabic and whey protein using complex coacervation and freeze drying 在阿拉伯树胶和乳清蛋白的生物聚合物基质中使用复合凝聚和冷冻干燥的酸性硫氧化硫硫杆菌微胶囊化
IF 4.9 2区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-12-25 DOI: 10.1016/j.mineng.2024.109164
Angel Manuel Cabrales-González , Diola Marina Núñez-Ramírez , María Adriana Martínez-Prado , Luis Medina-Torres , Walfred Rosas-Flores , Octavio Manero
Acidithiobacillus thiooxidans is a microorganism of great interest in biohydrometallurgical processes, as it is potentially capable of treating complex, low-grade sulfur minerals. However, there are concerns in the metallurgical industry regarding microbial manipulation due to problems related to cellular integrity, metabolic activities, genetic stability, and long-term maintenance of microbial cultures. In this study, the microencapsulation of Acidithiobacillus thiooxidans in a biopolymeric matrix composed of whey protein isolate (WPI) and gum arabic (GA) was carried out by complex coacervation and freeze-drying, with the goal to improve the above-mentioned factors. Results revealed that the highest level and quality of microencapsulation was obtained at a pH of 4.0 with a WPI: GA ratio of 2:1. The physicochemical properties of the powders (freeze-dried cells encapsulated in the WPI-GA matrix) revealed water activity (aw) of 0.089 ± 0.001, encapsulation efficiency (EE) of 88.88 ± 3.75 %, coacervation yield (YC) of 37.71 ± 0.063 %, and moisture content (MC) of 4.0 ± 0.14 %. Additionally, scanning electron microscopy (SEM) showed that the morphology corresponds to amorphous particles like crystals, with a polydisperse size distribution. Fourier transform infrared spectroscopy (FTIR) analysis confirmed the presence of electrostatic interactions between WPI and GA. Finally, growth kinetics and the bacteria metabolic activity remained intact after a freeze-drying process, reaching a growth of 1.64 x 109 cells/mL in 16 days. This microencapsulation process of the Acidithiobacillus thiooxidans may be an innovative method with applications in the mining and metallurgical industry regarding the storage, handling, and use of this microorganism in bioleaching processes.
酸性硫氧化硫硫杆菌是生物湿法冶金过程中非常感兴趣的微生物,因为它有可能处理复杂的低品位硫矿物。然而,在冶金工业中,由于与细胞完整性、代谢活动、遗传稳定性和微生物培养的长期维持有关的问题,人们对微生物操作存在担忧。本研究以乳清分离蛋白(WPI)和阿拉伯胶(GA)组成的生物聚合物为基质,采用复合凝聚和冷冻干燥的方法对酸性硫氧化硫杆菌进行微胶囊化,以改善上述因素。结果表明,在pH为4.0、WPI: GA比为2:1的条件下,微胶囊化水平和质量最高。经冻干细胞包封在WPI-GA基质中的粉末理化性质表明,其水活度(aw)为0.089±0.001,包封效率(EE)为88.88±3.75%,凝聚率(YC)为37.71±0.063%,含水量(MC)为4.0±0.14%。此外,扫描电镜(SEM)显示,形貌符合非晶颗粒状晶体,具有多分散的尺寸分布。傅里叶红外光谱(FTIR)分析证实了WPI和GA之间存在静电相互作用。最后,在冷冻干燥过程中,细菌的生长动力学和代谢活性保持不变,在16天内达到1.64 x 109个细胞/mL的生长。这种酸化硫氧化硫硫杆菌的微胶囊化工艺可能是一种创新方法,可用于采矿和冶金工业中对该微生物的储存、处理和在生物浸出过程中的使用。
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引用次数: 0
Surface electron transfer promoted by Peroxymonosulfate oxidant enhances bioleaching of arsenic-containing gold ore 过氧单硫酸盐氧化剂促进表面电子转移对含砷金矿生物浸出有促进作用
IF 4.9 2区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-12-24 DOI: 10.1016/j.mineng.2024.109166
Jiayu Xin , Jiahong Li , Xi Zhao , Changliu He , Lei Zheng , Aijun Zhang , Ranting Tao , Xu Zhang
Improving the efficiency of leaching arsenic from arsenic-containing gold ores is still a problem that needs to be solved urgently by traditional biological oxidation method. In this work, the effect of oxidant on mineral leaching and the change of arsenic ion valence during biological oxidation were investigated in detail. The results showed that when 5 g/L Peroxymonosulfate(PMS) was added on the second day of bioleaching, the concentration of arsenic ion in the solution was 0.682 g/L on the 14th day of the reaction, and the leaching rate of arsenic reached 71.06 %. Compared with the mixed microbial leaching system, the leaching rate of arsenic was increased by 8.95 %, while the content of As (Ⅲ) was decreased by 12.82 %. The results of electrochemical experiments show that PMS plays a cathode strengthening role in mineral oxidation and the passivation phenomenon in the process of microbial leaching is reduced by improving the oxidation capacity of the system. And the dissolved charge transfer resistance of the mineral is reduced from 44.17 Ω to 32.29 Ω. This study provides a new research perspective for improving the arsenic leaching rate of arsenic-containing gold ores, and our strategy also provides guidance for the research mechanism of increasing the arsenic leaching rate.
提高含砷金矿浸出砷的效率仍然是传统生物氧化法亟待解决的问题。本文详细研究了氧化剂对矿物浸出的影响以及生物氧化过程中砷离子价态的变化。结果表明:在生物浸出第2天加入5 g/L过氧单硫酸根(PMS),反应第14天溶液中砷离子浓度为0.682 g/L,砷的浸出率达到71.06%;与混合微生物浸出系统相比,砷的浸出率提高了8.95%,砷(Ⅲ)的含量降低了12.82%。电化学实验结果表明,PMS在矿物氧化过程中起到阴极强化作用,通过提高体系的氧化能力,减少了微生物浸出过程中的钝化现象。矿物的溶解电荷转移电阻由44.17 Ω降至32.29 Ω。本研究为提高含砷金矿的砷浸出率提供了新的研究视角,也为提高含砷金矿的砷浸出率的研究机制提供了指导。
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引用次数: 0
Efficient resource utilization of gypsum in the flotation separation of apatite from calcite 石膏在磷灰石与方解石浮选分离中的有效资源利用
IF 4.9 2区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-12-21 DOI: 10.1016/j.mineng.2024.109165
Shengzong Lan , Liuyang Dong , Peilun Shen , Haoran Su , Zhengchang Shen , Dianwen Liu
A large amount of the industrial byproduct gypsum can harm the environment, so developing an innovative approach for the utilization of gypsum is highly important. In this study, gypsum was employed to increase the flotation separation efficiency of apatite from calcite. The micro-flotation test revealed that sodium oleate could not separate the two minerals without a depressant. At pH 9, following the incorporation of gypsum, apatite achieved a recovery of 83.22 %, which was 51.49 % greater than that of calcite. The artificial mixed mineral test yielded a mixed concentrate with a P2O5 recovery of 72.71 % and a grade of 25.88 %. Mineral surface properties were analyzed, revealing that gypsum enhanced the hydrophilicity of the calcite surface and inhibited NaOL adsorption on calcite but had a minimal impact on apatite. Ca2+ in the slurry facilitated SO42– adsorption on the calcite surface. X-ray photoelectron spectroscopy results indicated that phosphate species on the apatite surface could adsorb Ca2+ from the solution, creating active sites for sodium oleate. Additionally, a higher concentration of S was observed on the calcite surface, suggesting that the adsorption capacity of gypsum dissolved in the slurry is greater on the surface of calcite. Surface morphology analysis revealed selective gypsum dissolved components adsorption on calcite rather than apatite, primarily within the 8–30 nm range, exhibiting uniform spot adsorption. These findings demonstrate the potential of gypsum as an inorganic depressant for calcite from various sources, enabling the flotation separation of apatite from calcite and thus providing a theoretical basis for the resource utilization of gypsum solid waste.
大量的工业副产品石膏会对环境造成危害,因此开发一种创新的石膏利用方法非常重要。本研究采用石膏提高磷灰石与方解石的浮选分离效率。微浮选试验表明,油酸钠在没有抑制剂的情况下不能分离这两种矿物。在pH为9时,石膏掺入后磷灰石的回收率为83.22%,比方解石的回收率高51.49%。人工混合矿物试验获得了P2O5回收率为72.71%、品位为25.88%的混合精矿。矿物表面性质分析表明,石膏增强了方解石表面的亲水性,抑制了方解石对NaOL的吸附,但对磷灰石的影响很小。浆液中的Ca2+有利于方解石表面对SO42 -的吸附。x射线光电子能谱结果表明,磷灰石表面的磷酸盐可以吸附溶液中的Ca2+,形成油酸钠的活性位点。此外,方解石表面的S浓度更高,说明石膏在方解石表面的吸附能力更大。表面形貌分析表明,在8 ~ 30 nm范围内,石膏溶解组分在方解石而非磷灰石上有选择性吸附,表现出均匀的斑点吸附。这些发现证明了石膏作为各种来源方解石的无机抑制剂的潜力,实现了磷灰石与方解石的浮选分离,从而为石膏固体废物的资源化利用提供了理论依据。
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Minerals Engineering
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