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Advanced magnetocaloric microwires: What does the future hold? 先进的磁性微丝:未来会怎样?
Pub Date : 2023-12-14 DOI: 10.31276/VJSTE.65(4).14-24
Hong-Xian Shen, N.T.M. Duc, H. Belliveau, Lin Luo, Yunfei Wang, Jian-Fei Sun, Faxiang Qin, M. Phan
Magnetic refrigeration (MR) based on the magnetocaloric effect (MCE) is a promising alternative to conventional vapor compression refrigeration techniques. The cooling efficiency of a magnetic refrigerator depends on its refrigeration capacity and operation frequency. Existing refrigerators possess limited cooling efficiency due to the low operating frequency (around tens of Hz). Theory predicts that reducing geometrical effects can increase the operation frequency by reducing the relaxation time of a magnetic material. As compared to other shapes, magnetocaloric wires transfer heat most effectively to a surrounding environment, due to their enhanced surface area. The wire shape also yields a good mechanical response, reducing the relaxation time and consequently increasing the operation frequency of the cooling device. Experiments have validated the theoretical predictions. By assembling microwires with different magnetocaloric properties and Curie temperatures into a laminate structure, a table-like magnetocaloric bed can be created and used as an active cooling device for micro-electro-mechanical system (MEMS) and nano-electro-mechanical system (NEMS). This paper assesses recent progress in the development of magnetocaloric microwires and sheds light on the important factors affecting the magnetocaloric behavior and cooling efficiency in microwire systems. Challenges, opportunities, and strategies regarding the development of advanced magnetocaloric microwires are also discussed.
基于磁致效应(MCE)的磁制冷(MR)是传统蒸汽压缩制冷技术的一种很有前途的替代技术。磁制冷器的制冷效率取决于其制冷能力和运行频率。由于工作频率较低(约几十赫兹),现有冰箱的冷却效率有限。理论预测,减少几何效应可以通过缩短磁性材料的弛豫时间来提高工作频率。与其他形状相比,磁致导线的表面积更大,因此能最有效地将热量传递到周围环境中。此外,磁致导线的形状还能产生良好的机械响应,缩短弛豫时间,从而提高冷却装置的工作频率。实验验证了理论预测。通过将具有不同磁致性能和居里温度的微线组装成层压结构,可以创建一个类似桌子的磁致床,并将其用作微机电系统(MEMS)和纳米机电系统(NEMS)的主动冷却装置。本文评估了磁致微线开发的最新进展,并揭示了影响微线系统磁致行为和冷却效率的重要因素。本文还讨论了开发先进磁致伸缩微线所面临的挑战、机遇和策略。
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引用次数: 0
One-dimensional numerical model of landslide over high-steep slopes: Theory and verification to the analytical solution 高陡边坡滑坡的一维数值模型:理论和对解析解的验证
Pub Date : 2023-11-25 DOI: 10.31276/vjst.65(11).42-46
Van Khoi Pham, V. N. Vu
At the steep slope areas, landslide events may suddenly occur due to prolonged heavy rain and seriously affect humans’ lives and their properties. Numerical models simulating landslides help us to predict the real landslide phenomenon effectively because they are not only time-saving compared to physical models but also acceptable accuracy. In this paper, the one-dimensional nonlinear shallow water equations using the global coordinate system are established as the proposed model governing equations. The hybrid finite difference-finite volume method, the implicit method and the automatical time step controlling technique are employed to stably simulate the landslide events over the high-steep slopes. To validate the proposed numerical model to the analytical solution, authors continuously derive the non-dimensional governing equations in one dimension as well as using the global coordinate system. The numerical results are in good agreement with the analytical solution. The proposed numerical model can be used to simulate the landslides and the landslide-induced tsunami events, especially for simulating the high-steep slope conditions.
在陡坡地区,由于长时间的暴雨,可能会突然发生山体滑坡事件,严重影响人类的生命和财产安全。与物理模型相比,模拟滑坡的数值模型不仅省时省力,而且精度也可以接受,因此可以帮助我们有效地预测真实的滑坡现象。本文利用全局坐标系建立了一维非线性浅水方程,作为拟建模型的控制方程。采用有限差分-有限体积混合方法、隐式方法和自动时间步长控制技术,稳定地模拟了高陡边坡上的滑坡事件。为了验证所提出的数值模型与解析解的一致性,作者在一维坐标系和全局坐标系下连续推导了非一维控制方程。数值结果与分析解法十分吻合。所提出的数值模型可用于模拟滑坡和滑坡引发的海啸事件,特别是模拟高陡坡条件。
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引用次数: 0
Graphene thermally modified with polyvinyl alcohol applied as conductive water-based paints based on polyurethane 聚乙烯醇热修饰石墨烯用作基于聚氨酯的导电水基涂料
Pub Date : 2023-11-25 DOI: 10.31276/vjst.65(11).37-41
Ngoc Diep Le, Thi Kim Oanh Nguyen, Ho Phuong Thao Le, Duy Linh Nguyen, M. Dang, D. Doan
This paper presents the fabrication of thermally reduced graphene modified with polyvinyl alcohol (PVA), which can be used as a conductive water-based paint based on polyurethane (PU). Graphite oxide (GO) was oxidised from graphite by the Hummer method, and then graphene was formed by the thermal-reducing GO method. The graphene was modified by dispersing it into a PVA solution with various concentrations and mass ratios to optimise the modification process. The graphene modified with PVA could be easily dispersed in water. Water-borne PU film-forming polymer was prepared by polymerisation reaction between isophorone diisocyanate with poly(tetramethylene glycol) and dimethylolpropionic acid. The carboxylate functional groups on the surface of the polymer particles make the polymer particles dispersed well and stable in water, so this polymerisation process does not use any surfactants. The characterisation methods included field emission scanning electron microscope with energy-dispersive X-ray spectroscopy (FESEM-EDX), specific surface area measurement, Raman microspectroscopy, resistance measurement... The graphene-based conductive paint has good adhesion, conductivity of the dry paint film was from 0.1-4 mS/cm with graphene content in the dry paint film was about 5-10 wt%.
本文介绍了用聚乙烯醇(PVA)修饰的热还原石墨烯的制备方法,这种石墨烯可用作基于聚氨酯(PU)的导电水性涂料。采用 Hummer 法从石墨中氧化出氧化石墨(GO),然后用热还原 GO 法形成石墨烯。将石墨烯分散到不同浓度和质量比的 PVA 溶液中对其进行改性,以优化改性过程。用 PVA 修饰的石墨烯很容易分散在水中。异佛尔酮二异氰酸酯与聚(四甘醇)和二羟甲基丙酸发生聚合反应,制备出水性聚氨酯成膜聚合物。聚合物颗粒表面的羧酸官能团使聚合物颗粒在水中分散良好且稳定,因此这种聚合工艺不使用任何表面活性剂。表征方法包括场发射扫描电子显微镜与能量色散 X 射线光谱(FESEM-EDX)、比表面积测量、拉曼微光谱、电阻测量...石墨烯基导电涂料具有良好的附着力,干漆膜的导电率为 0.1-4 mS/cm,干漆膜中的石墨烯含量约为 5-10 wt%。
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引用次数: 0
Characteristics of iron-manganese nodules containing nickel and cobalt in chromite deposits in Co Dinh, Thanh Hoa province 清化省高定铬铁矿床中含镍和钴的铁锰结核的特征
Pub Date : 2023-11-25 DOI: 10.31276/vjst.65(11).23-31
Tien Dung Le, Van Duc Tran, Huu Trong Nguyen, Khac Giang Nguyen, Xuan Ban To, Thi Ly Ly Nguyen
Along with the chromite ore bodies, very early on, geologists recorded the presence of cobalt (Co) and nickel (Ni) metal. The resource of cobalt and nickel is forecasted with over 3 million tons of Ni and over 260 thousand tons of Co metals. Until now, however, knowledge about the existence form and distribution of Ni and Co in chromite ore bodies is very limited. Researching the sludge in the chromite mines and in comparison with manganese nodules found in the ocean floor helps to detect the presence of particles of iron and manganese (Fe-Mn nodules) in granular sewage sludges and in primary chromite ore bodies. Fe-Mn hydroxides, including todorokite mineral, are believed to be the adsorption medium and forming of Ni and Co in the Co Dinh placer chromite. Determining the existence form and distribution of Ni and Co in chromite placer deposits has scientific and practical significance in sampling orientation, sample processing, geological exploration, and reserve and resource estimations, sorting and recovering technology of Co and Ni metals.
除了铬铁矿体,地质学家很早就发现了钴(Co)和镍(Ni)金属。据预测,钴和镍的资源量分别为 300 多万吨镍金属和 26 万多吨钴金属。然而,迄今为止,有关铬铁矿体中镍和钴的存在形式和分布的知识非常有限。对铬铁矿矿井中的污泥进行研究,并与海底发现的锰结核进行比较,有助于发现颗粒状污水污泥和原生铬铁矿矿体中存在铁和锰颗粒(铁锰结核)。铁锰氢氧化物,包括沱沱矿,被认为是科定块状铬铁矿中镍(Ni)和钴(Co)的吸附介质和形成物。确定铬铁矿块矿床中 Ni 和 Co 的存在形式和分布,对取样定位、样品处理、地质勘探、储量和资源估算、Co 和 Ni 金属的分选和回收技术具有科学和现实意义。
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引用次数: 0
Effect of the Ce3+ concentration on the crystallite structure and optical properties of ZnO nanomaterials synthesised by sol-gel method Ce3+ 浓度对溶胶-凝胶法合成的氧化锌纳米材料晶粒结构和光学特性的影响
Pub Date : 2023-11-25 DOI: 10.31276/vjst.65(11).63-68
Thi Bich Hop Dang, Van Cuong Nguyen, Quoc Thuan Hoang, Tien Ha Le, Van Quang Nguyen, Thi Lan Huong Pham
In this study, Ce3+-doped ZnO nanomaterials (Zn1-xO:xCe3+ NPs) were synthesised using the sol-gel method. X-ray diffraction (XRD) pattern and Raman spectra analysis showed that at 1% doping concentration, Zn2+ ions were replaced with Ce3+ ions in the ZnO lattice. However, at higher concentrations (3 and 5%), the CeO2 phase was formed, preventing the diffusion process of Ce3+ ions into the lattice. Field emission scanning electron microscopy (FESEM) images showed that the obtained material had a particle size of several tens of nanometers. X-ray energy dispersive (EDS) spectroscopy and EDS mapping spectra revealed that the synthesised Zn1-xO:xCe3+ NPs had high purity and the Ce element was uniformly distributed in the sample. UV-Vis spectroscopy confirmed the strong interaction between Ce3+ ions and ZnO lattice, leading to increased light absorption in the visible region. The photoluminescence (PL) spectrum of ZnO showed two emission regions peaking at 389 and 650 nm, attributed to band to band recombination and defect types of ZnO such as oxygen vacancy (Vo) and/or oxygen interstitial (Oi), respectively. In comparison with ZnO, the PL spectrum of Zn1-xOx:Ce3+ (x=1-5) samples showed that the visible region emission appeared at new peak at 580 nm originating to the 3d → 4f transition of Ce3+ ions. As the doping concentration increased gradually from 1 to 5%, the 580 nm peak intensity increased, and the 389 peak intensity decreased significantly, indicating that Ce3+ ions inhibited the NBE recombination process of ZnO. This study suggested that Ce3+ doped ZnO NPs have a great potential for application in visible-light photocatalysis.
本研究采用溶胶-凝胶法合成了掺杂 Ce3+ 的氧化锌纳米材料(Zn1-xO:xCe3+ NPs)。X 射线衍射(XRD)图和拉曼光谱分析表明,当掺杂浓度为 1%时,ZnO 晶格中的 Zn2+ 离子被 Ce3+ 离子取代。然而,当浓度较高(3% 和 5%)时,CeO2 相形成,阻止了 Ce3+ 离子向晶格的扩散过程。场发射扫描电子显微镜(FESEM)图像显示,所得材料的粒度为几十纳米。X 射线能量色散(EDS)光谱和 EDS 图谱显示,合成的 Zn1-xO:xCe3+ NPs 纯度很高,Ce 元素均匀地分布在样品中。紫外可见光谱证实了 Ce3+ 离子与 ZnO 晶格之间的强烈相互作用,从而增加了可见光区的光吸收。氧化锌的光致发光(PL)光谱显示出两个发射区,峰值分别为 389 纳米和 650 纳米,这分别归因于带间重组和氧化锌的缺陷类型,如氧空位(Vo)和/或氧间隙(Oi)。与氧化锌相比,Zn1-xOx:Ce3+(x=1-5)样品的聚光光谱显示,可见光区的发射在 580 nm 处出现了新的峰值,这源于 Ce3+ 离子的 3d → 4f 转变。随着掺杂浓度从 1%逐渐增加到 5%,580 nm 峰强度增加,389 峰强度显著下降,表明 Ce3+ 离子抑制了 ZnO 的 NBE 重组过程。该研究表明,掺杂 Ce3+ 的 ZnO NPs 在可见光光催化中具有很大的应用潜力。
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引用次数: 0
Study on the influence of some factors on the high burning rate of energy-carrying materials based on acrylonitrile butadiene rubber with end-chain carboxyl group 研究某些因素对带有端链羧基的丙烯腈丁二烯橡胶载能材料高燃烧率的影响
Pub Date : 2023-11-25 DOI: 10.31276/vjst.65(11).06-10
Duc-Long Nguyen, Van Hung Nguyen, Huu-Thanh Tran, Van Diep Doan, Van Hung Hoang
Heterogeneous energy-carrying materials possess outstanding advantages compared to other energy-carrying materials, therefore, research and development of this type of material to create propulsion for flying objects is an inevitable trend in the field of military science and space. This paper presents the results of research on the influence of a number of factors on the technological properties and combustion rate of heterogeneous energy-carrying materials based on acrylonitrile butadiene rubber CKH-10KTP and ammonium perchlorate (AP).The research results show that the combustion law depends on the pressure of heterogeneous energy-carrying materials based on CKH-10KTP and ultra-fine AP (specific surface area 2.61÷3.85 m2/g), using a combustion catalyst ferrocene derivative. The study also determined the optimal content of combustion catalyst - plasticiser to be 3.5÷3.8%. The research results are a solid scientific basis for optimally determining the parameters of radioactivity, energy of energy-carrying materials, supplementing the national data source in the design of aircraft engines, meeting requirements in the new context.
与其他载能材料相比,异质载能材料具有突出的优势,因此,研究和开发这类材料以制造飞行物推进器是军事科学和航天领域的必然趋势。本文介绍了以丙烯腈-丁二烯橡胶 CKH-10KTP 和高氯酸铵(AP)为基础的异质载能材料的技术性能和燃烧速率受多种因素影响的研究成果。研究结果表明,以 CKH-10KTP 和超细 AP(比表面积为 2.61÷3.85 m2/g)为基础的异质载能材料,使用二茂铁衍生物燃烧催化剂,其燃烧规律取决于压力。研究还确定了燃烧催化剂-增塑剂的最佳含量为 3.5%÷3.8%。研究成果为优化确定载能材料的放射性、能量参数提供了坚实的科学依据,补充了飞机发动机设计中的国家数据来源,满足了新形势下的要求。
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引用次数: 0
Fabrication and properties of Fe3O4/C composite materials Fe3O4/C 复合材料的制作与性能
Pub Date : 2023-11-25 DOI: 10.31276/vjst.65(11).52-56
T. Bui, Ha Thang Doan
Climate change is currently one of the most serious problems facing the world. In this study, Fe3O4 powder was used as electrode active material, nanocarbon was used as an additive to fabricate Fe3O4/C composites applying for energy storage systems. The size and morphology of iron oxide and nanocarbon were investigated by scanning electron microscopy. The effects of the additive, the content of the electrode components on the electrochemical properties of the Fe3O4/C composite electrode have been studied by cyclic voltammetry. The results showed that the content of the electrode components strongly affects the electrochemical characteristics of the electrode. The important role of the carbon additive in the Fe3O4/C composite electrode was confirmed: Nanocarbon increases the electrical conductivity of the electrode thereby enhancing the redox reaction rate of iron. The positive effect of the K2S additive in electrolyte was demonstrated by increased redox reaction rate of iron, improved cyclability of Fe3O4, reduced hydrogen evolution, and thus increased the discharge capacity of Fe3O4/C.
气候变化是当前全球面临的最严重问题之一。在这项研究中,Fe3O4 粉末被用作电极活性材料,纳米碳被用作添加剂,以制造出应用于储能系统的 Fe3O4/C 复合材料。通过扫描电子显微镜研究了氧化铁和纳米碳的尺寸和形态。通过循环伏安法研究了添加剂、电极成分含量对 Fe3O4/C 复合电极电化学性能的影响。结果表明,电极成分的含量对电极的电化学特性有很大影响。碳添加剂在 Fe3O4/C 复合电极中的重要作用得到了证实:纳米碳增加了电极的导电性,从而提高了铁的氧化还原反应速率。K2S 添加剂在电解液中的积极作用体现在提高了铁的氧化还原反应速率,改善了 Fe3O4 的循环性,减少了氢的演化,从而提高了 Fe3O4/C 的放电容量。
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引用次数: 0
Development of a tunable, narrow, and ultraviolet Ce:LiCAF crystal multipass laser amplifier for environmental application 开发用于环境应用的可调谐窄紫外 Ce:LiCAF 晶体多通道激光放大器
Pub Date : 2023-11-25 DOI: 10.31276/vjst.65(11).01-05
Van Diep Nguyen, Xuan Tu Nguyen, Van Duong Pham, Thi Khanh Van Nguyen, Van Minh Nguyen, Van Thu Vu, Hong Minh Pham
In this paper, the authors present results on the development of both an oscillator and a 4-pass amplifier of ultraviolet and narrow linewidth pulses using a Ce:LiCAF crystal. By using a grating at one end of the laser cavity, the output laser wavelength of the laser can be tuned from 285 nm to 296 nm with a maximum output power of 8 mW at 288.5 nm. Moreover, amplification in a 4-pass amplifier of the Ce:LiCAF laser was investigated theoretically and experimentally. From the results, 49.0 mW amplified pulses can be obtained using a 4-pass amplifier with 7.0 mW power and 3.6 ns pulse duration at 288.5 nm injection, corresponding to an amplifier gain of 7. Furthermore, the angular scattering intensity of some common single-particle aerosols such as black carbon, brown carbon, and polluted water has been studied using the Ce:LiCAF laser. This result can serve as the basis for the multipass laser amplifier’s environmental application, particularly in identifying atmospheric particles.
在本文中,作者介绍了利用 Ce:LiCAF 晶体开发紫外线和窄线宽脉冲振荡器和四通放大器的成果。通过在激光腔的一端使用光栅,激光器的输出波长可以从 285 纳米调谐到 296 纳米,在 288.5 纳米处的最大输出功率为 8 mW。此外,还对 Ce:LiCAF 激光器的 4 路放大器的放大效果进行了理论和实验研究。结果表明,在 288.5 nm 波长注入时,使用功率为 7.0 mW、脉冲持续时间为 3.6 ns 的 4 路放大器可获得 49.0 mW 的放大脉冲,相当于放大器增益为 7。 此外,还使用 Ce:LiCAF 激光器研究了一些常见单粒子气溶胶(如黑碳、褐碳和污染水)的角散射强度。这一结果可以作为多通道激光放大器在环境应用,特别是在识别大气颗粒方面的基础。
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引用次数: 0
Mathematical model for the calculation of life cycle cost of the Kamaz truck 计算卡玛兹卡车生命周期成本的数学模型
Pub Date : 2023-11-25 DOI: 10.31276/vjst.65(11).69-72
Ngoc Tuan Vu, Trung Kien Nguyen, Dinh-Son Le, Van-An Tran, Anh-Tuan Phung, Thanh Duong Nguyen
Currently, research on life cycle and product life cycle management is of interest in many countries, especially for products of high complexity and long service life. One of the issues of product life cycle management is the calculation and determination of product life cycle costs. Calculating the product life cycle costs will allow managers and users to know the cost that needs to be spent on acquiring the product (purchase cost), as well as corrective maintenance cost, preventive maintenance cost, operation cost, disposal cost, and also indicates the economic efficiency of purchasing, operating and using this product.This paper presents the mathematical model allowing a truck’s life cycle cost calculation and performs calculations for a specific Kamaz 43119/43118 truck. The calculation results allow evaluation of the contribution level of the cost components in the product life cycle, thus allowing managers to build financial estimates for the life cycle stages and compare the calculated product life cycle costs with the types of products in suitable circulation.
目前,关于生命周期和产品生命周期管理的研究受到许多国家的关注,特别是对于复杂程度高、使用寿命长的产品。产品生命周期管理的问题之一是计算和确定产品生命周期成本。计算产品生命周期成本可以让管理者和用户了解购买产品所需的成本(购买成本),以及纠正性维护成本、预防性维护成本、运营成本和处置成本,还可以显示购买、运营和使用该产品的经济效益。本文介绍了计算卡车生命周期成本的数学模型,并对特定的 Kamaz 43119/43118 卡车进行了计算。计算结果可以评估产品生命周期中各成本组成部分的贡献水平,从而使管理人员能够对生命周期各阶段进行财务估算,并将计算出的产品生命周期成本与适合流通的产品类型进行比较。
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引用次数: 0
Load-current demand forecasting in substations of urban railway lines 城市铁路变电站的负荷-电流需求预测
Pub Date : 2023-11-25 DOI: 10.31276/vjst.65(11).47-51
Van Khoi Tran
Load-current forecasting is important in the operation and energy management of urban railway lines. It helps control strategies to manage and distribute energy optimally, thereby saving energy and reducing voltage fluctuations. This paper presents a method to predict the traction current at the busbar of a substation using the supervised machine learning algorithm. Because the traction power load is supplied from both adjacent traction power stations, and the energy exchange process between trains also takes place during work, the input data are selected to combine the value history of busbar currents and feeder currents. Besides, the neural network configuration and the number of training cycles in the estimated model can be adjusted to achieve the desired accuracy. The proposed method was tested and adjusted based on the actual operation data at the Lang traction station on 24 June, 2022. The estimated results compared with measurement data from the supervisory control and data acquisition (SCADA) have proven that the largest absolute error is no more than 5 (A). The maximum relative error is not more than 0.005, and the mean squared error does not exceed 0.01 over the whole operating time of a day from 4h45 to 22h45.
负载电流预测对城市铁路线路的运行和能源管理非常重要。它有助于控制策略以最佳方式管理和分配能源,从而节约能源并减少电压波动。本文提出了一种利用监督机器学习算法预测变电站母线上牵引电流的方法。由于牵引电力负荷由相邻两个牵引电站提供,且工作期间列车之间也存在能量交换过程,因此输入数据的选择结合了母线电流和馈线电流的历史值。此外,还可以调整估计模型中的神经网络配置和训练循环次数,以达到所需的精度。根据 2022 年 6 月 24 日朗牵引站的实际运行数据,对所提出的方法进行了测试和调整。估算结果与监控和数据采集(SCADA)的测量数据相比,证明最大绝对误差不超过 5 (A)。最大相对误差不超过 0.005,从 4 时 45 分至 22 时 45 分的全天运行时间内,平均平方误差不超过 0.01。
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引用次数: 0
期刊
Ministry of Science and Technology, Vietnam
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