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An examination of the heat treatment effect on mechanical properties of twin-roll cast followed by cold rolling sheets made of aluminium and its alloys 热处理对铝及其合金双辊铸轧后冷轧薄板力学性能影响的研究
Pub Date : 2014-11-18 DOI: 10.7494/MAFE.2014.40.2.93
W. Ściężor, A. Mamala, P. Kwaśniewski
Modern aluminium alloys are more commonly used in various industries. Often the products of such materials operate at elevated temperatures. In addition to standard requirements in terms of mechanical and technological properties, one of the key performance properties becomes the increased resistance to annealing. This paper examines the heat treatment effect on the mechanical properties of sheets made of aluminium with grain refiner additions (Ti + B), Fe, Si and Mn. Tested materials were obtained by cold-rolling strips, manufactured by twin-roll casting – TRC method. TRC method is increasingly being used in the manufacture of flat-rolled products. This technology eliminates the hot rolling operations and the strip obtained by TRC method can be subjected to direct cold rolling.
现代铝合金更普遍地用于各种工业。这种材料的产物通常在高温下工作。除了机械和技术性能方面的标准要求外,其中一个关键的性能性能成为增加的退火性能。本文研究了晶粒细化剂(Ti + B)、Fe、Si和Mn对铝薄板力学性能的影响。试验材料采用冷轧带材,采用双辊铸造- TRC法制备。TRC法越来越多地应用于平轧产品的制造。该工艺省去了热轧工序,可直接进行冷轧。
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引用次数: 0
ELECTROCHEMICAL BEHAVIOR OF TELLURIUM IN ACIDIC NITRATE SOLUTIONS 碲在酸性硝酸盐溶液中的电化学行为
Pub Date : 2014-10-14 DOI: 10.7494/MAFE.2014.40.1.15
E. Rudnik, P. Biskup
Electrochemistry of tellurium stationary electrode was studied in acidic nitrate solutions with pH 1.5 – 3.0. Cyclic voltammetry indicated that two products were formed at potentials above 300 mV (SCE): soluble HTeO 2 + (500 mV) and sparingly soluble H 2 TeO 3 (650 mV), but the former seemed to be an intermediate product for TeO 2 precipitation on the electrode surface. Formation of the solid products as porous layers was almost undisturbed and no electrode passivation was observed. H 2 TeO 3 and TeO 2 dissolved to HTeO 2 + under acidic electrolyte, but this process was hindered by pH increase. Cathodic polarization of tellurium electrode below -800 mV was accompanied by evolution of H 2 Te, which was then oxidized at the potentials approx. -700 mV. H 2 Te generated in the electrochemical reaction decomposed to elemental tellurium as black powdery precipitates in the bulk of the solution and a bright film drifting on the electrolyte surface.
研究了碲固定电极在pH为1.5 ~ 3.0的酸性硝酸溶液中的电化学反应。循环伏安法表明,在300 mV (SCE)以上的电位下,形成了两种产物:可溶的hteo2 + (500 mV)和少量可溶的hteo2 + (650 mV),但前者似乎是在电极表面沉淀teo2的中间产物。作为多孔层的固体产物的形成几乎没有受到干扰,也没有观察到电极钝化。在酸性电解液下,h2teo3和teo2溶解为hteo2 +,但pH的增加阻碍了这一过程。在-800 mV以下,碲电极的阴极极化伴随着h2te的析出,h2te在约电位下被氧化。-700 mV。在电化学反应中产生的h2te分解为单质碲,在大部分溶液中形成黑色粉末沉淀,并在电解质表面形成一层明亮的薄膜。
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引用次数: 10
BIODEGRADATION OF A NEW POLYMER BINDER BASED ON MODIFIED STARCH IN A WATER ENVIRONMENT 一种基于变性淀粉的新型聚合物粘合剂在水环境中的生物降解
Pub Date : 2014-10-14 DOI: 10.7494/MAFE.2014.40.1.7
K. Kaczmarska, B. Grabowska
In this study, the results of biodegradability of new polymeric binder consist of modified starch - Polvitex Z (by Xenon) in water solution are presented. Biodegradation tests were conducted in accordance with Zahn-Wellens method, which is intended to denote the susceptibility to biodegradation by microorganisms (in high concentrations during the static test) of the non-volatile, watersoluble organic compounds. Observations of the decomposition process was carried out through regular, daily or at certain time intervals by measurement the Chemical Oxygen Demand (COD) and level of biodegradability (R T )  in the prepared samples during the test. The study showed that the starch binder is fully biodegradable material in an aqueous medium.
本文介绍了一种由改性淀粉- Polvitex Z(氙)组成的新型高分子粘合剂在水溶液中的生物降解性。生物降解试验按照Zahn-Wellens方法进行,该方法旨在表明非挥发性水溶性有机化合物(在静态试验期间高浓度)对微生物生物降解的敏感性。在测试过程中,通过测量制备样品的化学需氧量(COD)和生物降解性(R T)水平,通过定期、每日或一定时间间隔观察分解过程。研究表明,淀粉粘合剂在水介质中是完全可生物降解的材料。
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引用次数: 3
AMORHIZATION AND LIQUID STATE SEPARATION IN Ni80-2xCuxFexP20 ALLOYS Ni80-2xCuxFexP20合金的非晶化和液相分离
Pub Date : 2014-10-14 DOI: 10.7494/MAFE.2014.40.1.45
K. Ziewiec, K. Prusik, M. Różycka
The aim of the work is to study the ability and potential of glass formation in Ni-Fe-Cu-P alloys. A series of alloys were produced in arc furnace (i.e. Ni 70 Fe 5 Cu 5 P 20 , Ni 60 Fe 10 Cu 10 P 20 , Ni 50 Fe 15 Cu 15 P 20 , Ni 40 Fe 20 Cu 20 P 20 , Ni 30 Fe 25 Cu 25 P 20 , Ni 20 Fe 30 Cu 30 P 20 ). The primary microstructure of the ingots was studied. The ribbons  in as-melt-spun state were characterized by X-ray diffraction (XRD). The Ni 70 Fe 5 Cu 5 P 20 , Ni 60 Fe 10 Cu 10 P 20 melt-spun alloys were found to be amorphous. For higher copper and iron concentrations crystalline structure was obtained after melt spinning. This correlated with the tendency for the formation of  the Fe-based phases enriched in P and Cu-based poorly alloyed phases which resulted in formation of crystalline microstructure in melt-spun ribbons. For higher concentration of Fe and Cu, microstructures of the alloys contained constituents resultant from tendency for separation in the liquid state. It is observed that formation of the crystalline melt-spun ribbons is caused by attraction of phosphorus by iron and formation of copper-based fcc phase.
本工作的目的是研究Ni-Fe-Cu-P合金玻璃化的能力和潜力。在电弧炉中制备了Ni 70 Fe 5 Cu 5 p20、Ni 60 Fe 10 Cu 10 p20、Ni 50 Fe 15 Cu 15 p20、Ni 40 Fe 20 Cu 20 p20、Ni 30 Fe 25 Cu 25 p20、Ni 20 Fe 30 Cu 30 p20等系列合金。对铸锭的初次组织进行了研究。用x射线衍射(XRD)对熔融纺丝状态下的条带进行了表征。Ni 70 Fe 5 Cu 5 p20、Ni 60 Fe 10 Cu 10 p20熔纺合金均为非晶态。当铜和铁浓度较高时,熔体纺丝后得到结晶结构。这与熔纺带中富P的fe基相和cu基低合金化相的形成趋势有关,导致了结晶组织的形成。当Fe和Cu浓度较高时,合金的显微组织中含有液相分离倾向的成分。观察到结晶熔融纺带的形成是由铁对磷的吸引和铜基fcc相的形成引起的。
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引用次数: 0
INFLUENCE OF ANNEALING CONDITIONS ON THE PROPERTIES AND MICROSTRUCTURE OF STEEL COMPOSITES 退火条件对钢复合材料性能和组织的影响
Pub Date : 2014-10-14 DOI: 10.7494/MAFE.2014.40.1.33
I. Sulima, P. Hyjek, T. Tokarski
Samples made of AISI 316L stainless steel reinforced with 8 vol.% TiB 2 particles were prepared using high pressure-high temperature (HP-HT) method. Next, the composites were annealed at temperature of 1200°C for different holding times.  The influence of annealing temperature and time on the properties and microstructure of AISI316L+8% vol.TiB 2 composites was investigated. The structural studies showed formation of phases containing chromium, molybdenum and boron.
采用高压-高温(HP-HT)法制备了8vol .% tib2颗粒增强的AISI 316L不锈钢试样。然后,在1200℃的温度下,对复合材料进行不同保温时间的退火。研究了退火温度和退火时间对AISI316L+8% vol. tib2复合材料性能和组织的影响。结构研究表明形成了含铬、钼和硼的相。
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引用次数: 4
PRELIMINARY STUDIES OF SEAMLESS FLUX CORED WIRES STORED IN EXTREME CONDITIONS 在极端条件下储存的无缝药芯焊丝的初步研究
Pub Date : 2014-01-01 DOI: 10.7494/MAFE.2014.40.4.211
D. Fydrych, A. Świerczyńska, M. Landowski
In the paper preliminary experimental studies of flux cored wires moisturized under controlled conditions are described. Three seamless wires of different grades have been placed in environmental chamber and moisturized in extremely adverse conditions (temperature T = 60° C, relative humidity H = 90%) for 240 hours. During this time measurements of weight gain and observations of surface of wires have been carried out. Also diffusible hydrogen amount in deposited metal has been determined by mercury method for one of moisturized wire. Significant increase of hydrogen level was observed (from H5 to H10 level). Further research will be aimed on determination of the effect of storage conditions on hydrogenation of deposited metal and quality of flux cored wires.
本文叙述了在受控条件下对药芯焊丝进行润湿的初步实验研究。三根不同等级的无缝丝放置在环境室中,在极端恶劣的条件下(温度T = 60℃,相对湿度H = 90%)保湿240小时。在此期间,进行了增重测量和导线表面观察。同时,用汞法测定了一种湿化金属丝在沉积金属中的扩散氢量。观察到氢含量显著增加(从H5到H10)。进一步的研究将旨在确定储存条件对沉积金属氢化和药芯焊丝质量的影响。
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引用次数: 3
METHODS OF INTRODUCING ALLOYING ELEMENTS INTO LIQUID MAGNESIUM 在液态镁中引入合金元素的方法
Pub Date : 2014-01-01 DOI: 10.7494/MAFE.2014.40.3.141
D. Kapinos, B. Augustyn, M. Szymanek
In recent years, magnesium alloys have gained widespread popularity as construction materials. This is due to their low density, high strength properties, and advances in their production technology. Properties of magnesium alloys depend primarily on the type, quantity, and quality of elements present in their composition. It is therefore necessary to carry out research on the further optimisation of the production technology of these alloys. This article presents the results of studies carried out in order to determine the type, form, and parameters of the process of introducing selected alloying elements to magnesium in a manner which enables the manufacture of alloys with predetermined chemical composition. As part of the work, elements such as Al, Zn, Mn, Zr, Si, Cu, Ca, as well as rare earth elements (RE) were introduced into the liquid magnesium. The alloying elements were introduced into the melt at different temperatures in either a metallic form or as master alloys. While conducting studies, respective solubility graphs were plotted for the alloying elements showing the time taken for each element to dissolve to the required form at a specific temperature and concentration. The studies resulted in the development of several techniques of introducing selected alloying elements, which enabled the manufacture of various types of alloys.
近年来,镁合金作为建筑材料得到了广泛的普及。这是由于它们的低密度、高强度特性和生产技术的进步。镁合金的性能主要取决于其成分中所含元素的种类、数量和质量。因此,有必要对这些合金的生产工艺进行进一步的优化研究。本文介绍了研究的结果,以确定将选定的合金元素引入镁的过程的类型、形式和参数,从而能够制造具有预定化学成分的合金。将Al、Zn、Mn、Zr、Si、Cu、Ca等元素以及稀土元素(RE)引入到液态镁中。合金元素在不同的温度下以金属形式或作为主合金引入熔体。在进行研究时,绘制了合金元素的溶解度图,显示了每种元素在特定温度和浓度下溶解成所需形式所需的时间。这些研究导致了几种引入选定合金元素的技术的发展,这使得制造各种类型的合金成为可能。
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引用次数: 6
MICROSTRUCTURE OF TIG WELDED WITH SELECTED MAGNESIUM ALLOYS 选定镁合金tig焊接的显微组织
Pub Date : 2014-01-01 DOI: 10.7494/MAFE.2014.40.4.231
L. Tuz, K. Pańcikiewicz, Z. Żurek
An evaluation of the macro- and microstructure of magnesium alloy tungsten arc-welded butt joints is presented in this paper. Al-Zn-Mn magnesium alloys are taken into consideration in the research. Their main alloying elements are zinc and aluminum, respectively. The dendritic microstructure of the base metal is obtained. The analysis shows that achieving good-quality butt joints of magnesium alloys is possible.
对镁合金钨电弧焊对接接头的宏观和显微组织进行了评价。研究中考虑了Al-Zn-Mn镁合金。它们的主要合金元素分别是锌和铝。得到了母材的枝晶组织。分析表明,获得高质量的镁合金对接接头是可能的。
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引用次数: 0
Metallostatic pressure function in the quality of Al-Si alloy castings made in sand moulds 金相压力对铝硅合金砂型铸件质量的影响
Pub Date : 2014-01-01 DOI: 10.7494/MAFE.2014.40.3.191
J. Zych, M. Wójcik, J. Kolczyk, T. Snopkiewicz
The paper presents results of the studies regarding influence of metallostatic pressure of AlSi7Mg alloy on surface roughness of castings prepared in sand moulds as well as on alloy’s density. Castings in a cylindrical shape with a diameter of 15.0; 25.0 or 3.5 mm and height of 700 mm that were cast in a vertical orientation are investigated. The melted alloy was poured into moulds in two ways: bottom up, and top down. Higher pressure and larger diameter of castings favors increase of surface roughness. In the analyzed range of height of a metal column, density increases linearly: for instance, in case of castings with diameter of o25 mm, the density increases from ρ = 2.60 g/cm3 to ρ = 2.68 g/cm3, what is about 0.10 g/cm3. In the roller with larger diameter, the density is slightly smaller, however the range of changes along the longer axis is similar to that in the cylinder with diameter of o25 mm. Additional, ultrasonic studies were performed, which prove that with small changes of the alloy density, velocity of a longitudinal wave changes only slightly. Thus, it is difficult to control small variations (Δρ < 0,10 g/cm3) in density of AlSi7Mg alloy with ultrasonic technique.
本文介绍了AlSi7Mg合金静金压对砂型铸件表面粗糙度和合金密度影响的研究结果。直径为15.0的圆柱形铸件;研究了25.0或3.5 mm,高度为700 mm的垂直方向铸件。熔化的合金以两种方式倒入模具:自下而上和自上而下。较高的压力和较大的铸件直径有利于提高表面粗糙度。在分析的金属柱高度范围内,密度线性增加:例如,对于直径为25 mm的铸件,密度从ρ = 2.60 g/cm3增加到ρ = 2.68 g/cm3,约为0.10 g/cm3。在直径较大的滚筒中,密度略小,但沿较长轴的变化范围与直径为25 mm的滚筒相似。此外,超声波研究表明,当合金密度变化很小时,纵波的速度变化很小。因此,超声波技术难以控制AlSi7Mg合金密度的微小变化(Δρ < 0.10 g/cm3)。
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引用次数: 0
CASTING OF Al-Si ALLOYS IN THE FULL-MOULD TECHNOLOGY. PROCESS CONDITIONS 铝硅合金全模铸造技术。工艺条件
Pub Date : 2014-01-01 DOI: 10.7494/MAFE.2014.40.3.161
J. Mocek, J. Zych, Łukasz Krubnik
A review of various technologies using expendable casting patterns made of expanded polystyrene is given in the paper. The results of our own investigations on implementing this technology at the pilot-plant scale – for the art castings series – were presented. The results of tests of materials and moulds applied in the full-mould technology were shown. Gas evolution tendencies of expanded polystyrenes and protective coatings were estimated. Gas evolutions were described as functions of the polystyrene heating temperature. The tests of protective coatings used in this technology were performed and strength (Rm), permeability (P), and gas evolution tendency of these coatings assessed. New solutions developed by the team of researchers were applied in testing coating strength, permeability, and the gas evolution tendency of expanded polystyrene. A good correlation between the results of coating properties and the obtained casting quality was found. Coatings, which were characterised by higher strengths and better permeability, allowed us to produce castings without surface or inner faults.
本文综述了用膨胀聚苯乙烯制造可消耗铸件的各种工艺。介绍了我们自己在中试工厂规模上对艺术铸件系列实施这项技术的调查结果。介绍了全模工艺中所用材料和模具的试验结果。分析了膨胀聚苯乙烯和保护涂层的气体演化趋势。气体演化被描述为聚苯乙烯加热温度的函数。对该技术中使用的保护涂层进行了测试,并对这些涂层的强度(Rm)、渗透率(P)和气体演化趋势进行了评估。研究小组开发的新解决方案被应用于测试涂层强度、渗透率和膨胀聚苯乙烯的析气倾向。发现涂层性能的结果与获得的铸件质量有很好的相关性。涂层具有更高的强度和更好的渗透性,使我们能够生产没有表面或内部缺陷的铸件。
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引用次数: 2
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Metallurgy and Foundry Engineering
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