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AI for Materials Design Workshop explores needed research directions 材料设计人工智能研讨会探讨所需研究方向
IF 5 3区 材料科学 Q1 Physics and Astronomy Pub Date : 2024-04-01 DOI: 10.1557/s43577-024-00711-y
Vineeth Venugopal
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引用次数: 0
Someya leads MRS Board of Directors for 2024 索米亚领导 2024 年 MRS 董事会
IF 5 3区 材料科学 Q1 Physics and Astronomy Pub Date : 2024-04-01 DOI: 10.1557/s43577-024-00709-6
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引用次数: 0
Chemical and architectural intricacy from nanoscale tetrahedra and their analogues 来自纳米级四面体及其类似物的化学和建筑复杂性
IF 5 3区 材料科学 Q1 Physics and Astronomy Pub Date : 2024-03-28 DOI: 10.1557/s43577-024-00688-8
Jeremy Schneider, Yasutaka Nagaoka, Hongyou Fan, Ou Chen

Abstract

The tetrahedron, as the simplest platonic shape, is a profound building block with the potential to create intricate superstructures. Noteworthy designs utilizing tetrahedral building blocks include the Sierpiński tetrahedron (the most fundamental three-dimensional fractal), a one-dimensional helical structure known as the tetrahelix, and various crystalline and quasicrystalline packings. Historically, the practicality of tetrahedral superstructures has been evident, providing stable, well-defined frameworks for various constructions, including truss bridges, tower cranes, and electricity transmission line pylons. In the field of self-assembled nanocrystal superlattices, tetrahedral nanocrystals, as building blocks, occupy a unique place among all the possible nanoscale particles. Mathematical models, simulation work, and experimental studies using nanocrystals in the laboratory have suggested that self-assembled structures derived from nanoscale tetrahedral building blocks are notably intricate, giving rise to new horizons of high-entropy nanocrystal superlattices. An important implication from previous works is that such tetrahedral nanocrystal superlattices form through highly delicate interparticle interactions, emphasizing the importance of the fine features of these nanocrystals. In this article, we summarize the advances in superlattices assembled from tetrahedral nanocrystals. We first define the tetrahedron and tetrahedron analogues based on Conway’s transformation and graph theory, underscoring their relevance to the crystallization process producing tetrahedral nanocrystals. Then, we showcase previous reports on the synthesis of tetrahedral nanocrystals and the resulting nanocrystal superstructures. Finally, we conclude by offering insights and perspective into the chemical and architectural intricacy that could emerge from tetrahedral nanocrystals.

Graphical abstract

摘要四面体作为最简单的柏拉图形状,是一种深奥的构件,具有创造错综复杂的超结构的潜力。利用四面体构件的著名设计包括西尔潘斯基四面体(最基本的三维分形)、被称为四螺旋的一维螺旋结构以及各种晶体和准晶体组合。从历史上看,四面体超结构的实用性是显而易见的,它为各种建筑提供了稳定、定义明确的框架,包括桁架桥、塔式起重机和输电线铁塔。在自组装纳米晶体超晶格领域,四面体纳米晶体作为构件,在所有可能的纳米级粒子中占有独特的地位。数学模型、模拟工作以及在实验室中使用纳米晶体进行的实验研究表明,由纳米级四面体构件衍生的自组装结构错综复杂,开创了高熵纳米晶体超晶格的新局面。以往研究的一个重要意义在于,这种四面体纳米晶体超晶格是通过高度微妙的粒子间相互作用形成的,从而强调了这些纳米晶体精细特征的重要性。在本文中,我们总结了由四面体纳米晶体组装而成的超晶格的研究进展。我们首先根据康威变换和图论定义了四面体和四面体类似物,强调了它们与产生四面体纳米晶体的结晶过程的相关性。然后,我们展示了以往有关合成四面体纳米晶体和由此产生的纳米晶体超结构的报道。最后,我们对四面体纳米晶体可能产生的复杂化学和结构提出了见解和看法。
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引用次数: 0
Driving forces for particle-based crystallization: From experiments to theory and simulations 粒子结晶的驱动力:从实验到理论和模拟
IF 5 3区 材料科学 Q1 Physics and Astronomy Pub Date : 2024-03-28 DOI: 10.1557/s43577-024-00696-8
Maria L. Sushko

The multistep crystallization processes involving the formation of stable building blocks that subsequently assemble into a crystal are ubiquitous in mineral formation and biomineralization and are particularly attractive in materials synthesis. Utilizing these pathways offers the approach to overcoming the restrictions on the expression of various crystal faces imposed by the interfacial energy during monomer-by-monomer growth to unlock the breadth of architectures with unique properties. Controlling particle-based crystallization proved challenging despite its promise due to the complex interdependence of interfacial forces and their nonlinear dependence on synthesis parameters. Here, the status of the development of state-of-the-art approaches to measuring interparticle forces and predictive theoretical models of particle-based crystallization are reviewed.

Graphical abstract

在矿物形成和生物矿化过程中,涉及形成稳定构件并随后组装成晶体的多步结晶过程无处不在,在材料合成中尤其具有吸引力。利用这些途径可以克服单体生长过程中界面能对各种晶面表达的限制,从而获得具有独特性质的广泛结构。由于界面力之间复杂的相互依存关系及其与合成参数之间的非线性依赖关系,尽管基于颗粒的结晶技术前景广阔,但控制这种结晶技术仍具有挑战性。本文回顾了测量粒子间作用力的最先进方法和粒子结晶预测理论模型的发展状况。
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引用次数: 0
Journal Highlights 期刊要闻
IF 5 3区 材料科学 Q1 Physics and Astronomy Pub Date : 2024-03-28 DOI: 10.1557/s43577-024-00701-0
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引用次数: 0
Photoluminescent Bi-doped CsPbX3 (X: Br, I) perovskite quantum dots for optoelectronic devices 用于光电设备的光致发光双掺杂 CsPbX3(X:Br,I)包晶量子点
IF 5 3区 材料科学 Q1 Physics and Astronomy Pub Date : 2024-03-19 DOI: 10.1557/s43577-024-00675-z
Mabel Rodríguez-Fernández, Saray Gragera, José Carlos Piñero, Rodrigo Alcántara, Javier Navas

Abstract

Perovskite quantum dots (PQDs) became a hot spot in recent years due to their amazing properties, such as the high photoluminescence quantum yield, tunable emission, and narrow bandwidth being important for their application in different optoelectronic devices. In this work, Bi-doped CsPbBr3 and Bi-doped CsPbI3 PQDs were synthesized through the hot-injection method and compared with pristine CsPbBr3 and CsPbI3 to analyze the effect of Bi and the halogen on their properties. In addition, all the samples were synthesized at 130°C, 150°C, and 170°C with the aim of analyzing the effect of the temperature. The results showed a wide range of the emission wavelength from around 500 nm (Bi-doped CsPbBr3) to 630 nm (Bi-doped CsPbI3) as a consequence of the effect of the halogen in “X” position and a slight blueshift in the main photoluminescence emission band after doping the pristine quantum dots with Bi.

Graphical abstract

Impact statement

We believe that the work in this article represents an important advance in the application of perovskite quantum dots in optoelectronics applications, such as in LEDs or lasers. We report here the synthesis and characterization of Bi-doped CsPbX3 perovskite quantum dots (PQDs), being X: Br and I. These Bi-doped PQDs show a wide range of the emission wavelength from around 500 nm (Bi-doped CsPbBr3) to 630 nm (Bi-doped CsPbI3) as a consequence of the effect of the halogen in “X” position and a slight blueshift in the main photoluminescence emission band after doping the pristine quantum dots with Bi. Therefore, they are good candidates to fabricate optoelectronic devices such as LEDs and lasers thanks to their high photoluminescence emission and their tunable emission.

摘要由于具有高光致发光量子产率、可调谐发射和窄带宽等惊人特性,棱镜量子点(PQDs)成为近年来的热点,这对其在不同光电器件中的应用具有重要意义。本研究采用热注入法合成了掺铒 CsPbBr3 和掺铒 CsPbI3 PQDs,并将其与原始 CsPbBr3 和 CsPbI3 进行了比较,以分析 Bi 和卤素对其性能的影响。此外,所有样品都是在 130°C、150°C 和 170°C 下合成的,目的是分析温度的影响。结果表明,由于卤素在 "X "位的影响,发射波长的范围很宽,从500 nm左右(掺Bi的CsPbBr3)到630 nm(掺Bi的CsPbI3),并且在原始量子点中掺入Bi后,主光致发光发射带发生了轻微的蓝移。图解摘要影响声明我们相信,本文的研究工作代表了包晶量子点在光电应用领域(如 LED 或激光器)的重要进展。我们在此报告了双掺杂 CsPbX3 包晶量子点(PQDs)的合成和表征,X:Br 和 I。由于卤素在 "X "位置的影响,这些掺毕的 PQDs 的发射波长范围很宽,从大约 500 纳米(掺毕 CsPbBr3)到 630 纳米(掺毕 CsPbI3)。因此,由于它们的高光致发光发射和可调谐发射,它们是制造 LED 和激光等光电器件的良好候选材料。
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引用次数: 0
Eliminating paper is a mixed bag 纸张的淘汰喜忧参半
IF 5 3区 材料科学 Q1 Physics and Astronomy Pub Date : 2024-03-19 DOI: 10.1557/s43577-024-00694-w
Steve Moss
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引用次数: 0
Patchy nanoparticles with surface complexity for directed self-assembly 具有表面复杂性的斑状纳米粒子,可进行定向自组装
IF 5 3区 材料科学 Q1 Physics and Astronomy Pub Date : 2024-03-15 DOI: 10.1557/s43577-024-00687-9

Abstract

Patchy nanoparticles (PNPs) possess anisotropic surfaces that produce emergent directionalities in interactions. Manipulation of such surface complexities offers a powerful handle for control over interparticle spatial and orientational orderings, making PNPs an ideal class of nanoscale synthons for self-assembly. However, realization of PNPs with defined patch positions and geometries faces technical challenges related to the level of precision chemistry required to achieve the desired surface patterning. Here, we provide an in-depth review of state-of-the-art strategies available for PNP synthesis. We examine the experimental efforts made to synthesize PNPs, classifying advances based on different material types spanning organic and inorganic systems. We conclude by presenting barriers in PNP synthesis and highlighting ongoing theoretical efforts aimed at guiding experimental design and parameter selection for creating novel surface patterning on NPs.

Graphical abstract

摘要 补丁状纳米粒子(PNPs)具有各向异性的表面,可在相互作用中产生新的方向性。对这种表面复杂性的操纵为控制粒子间的空间和方向有序性提供了强有力的手段,使 PNPs 成为自组装的一类理想的纳米级合成物。然而,实现具有确定贴片位置和几何形状的 PNPs 面临着技术挑战,这与实现所需的表面图案化所需的精密化学水平有关。在此,我们将对现有的 PNP 合成策略进行深入评述。我们研究了合成 PNP 的实验工作,并根据有机和无机系统的不同材料类型对进展进行了分类。最后,我们介绍了 PNP 合成中的障碍,并重点介绍了正在进行的旨在指导实验设计和参数选择的理论工作,以便在 NPs 上创建新颖的表面图案。 图表摘要
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引用次数: 0
Chiral assembly of nanoparticles in functional inorganic materials 功能性无机材料中纳米粒子的手性组装
IF 5 3区 材料科学 Q1 Physics and Astronomy Pub Date : 2024-03-13 DOI: 10.1557/s43577-024-00673-1

Abstract

Chirality is prevalent in nature, offering unique inspirations for building functional inorganic materials. Within these intricate chiral materials, the assembly of nanoparticles as fundamental building blocks is supposed to contribute to the formation of chiral suprastructures. Herein, by a comprehensive review of various reported chiral materials recently, we systematically document the strategies for precise control of chiral materials synthesis via inorganic nanoparticle assembly, including additive-induced, template-directed, and physical field-mediated approaches. Additionally, we demonstrate the key applications of chiral assembly inorganic materials. In summary, this work likewise advances our understanding the roles of nanoparticle assembly in chiral suprastructures, which could provide important design insights into the fabrication of functional materials in structural applications.

Graphical abstract

摘要 手性在自然界十分普遍,为构建功能性无机材料提供了独特的灵感。在这些错综复杂的手性材料中,纳米粒子作为基本构件的组装应该有助于形成手性超结构。在此,我们全面回顾了最近报道的各种手性材料,系统地记录了通过无机纳米粒子组装精确控制手性材料合成的策略,包括添加剂诱导、模板导向和物理场介导的方法。此外,我们还展示了手性组装无机材料的关键应用。总之,这项工作同样推进了我们对纳米粒子组装在手性超结构中的作用的理解,这将为结构应用中功能材料的制造提供重要的设计见解。 图表摘要
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引用次数: 0
Understanding the complexities of Li metal for solid-state Li-metal batteries 了解固态锂金属电池中锂金属的复杂性
IF 5 3区 材料科学 Q1 Physics and Astronomy Pub Date : 2024-03-12 DOI: 10.1557/s43577-024-00677-x
Andrew S. Westover

Li-metal anodes are a key enabling technology for next-generation high-energy batteries, including Li–S, Li-air, and high-voltage cathodes. While most research enabling Li metal focuses on electrolyte design, especially in the solid state, the nature of the Li metal itself has a significant impact on the performance of both solid- and liquid-based batteries. This has historically been understudied, but recent work has highlighted the importance of tailoring the Li metal to optimize high-performance batteries. This article focuses on the key aspects of Li metal that impact performance, including the method of synthesis, microstructure, surfaces, impurities, mechanics, and alloying strategies to optimize Li anode performance. The article will also briefly look at the impact of long-term cycling on the evolution of Li-metal anodes in solid-state batteries and highlight key areas of needed research.

Graphical abstract

锂金属阳极是下一代高能电池(包括锂太阳能电池、锂空气电池和高压阴极电池)的关键赋能技术。虽然大多数有关锂金属的研究都侧重于电解质设计,尤其是固态电解质设计,但锂金属本身的性质对固态和液态电池的性能都有重大影响。这一点历来没有得到充分研究,但最近的研究突显了定制锂金属以优化高性能电池的重要性。本文重点介绍影响锂金属性能的关键方面,包括合成方法、微观结构、表面、杂质、力学以及优化锂阳极性能的合金策略。文章还将简要介绍固态电池中长期循环对锂金属阳极演化的影响,并强调需要研究的关键领域。
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引用次数: 0
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Mrs Bulletin
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