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2013 13th IEEE International Conference on Nanotechnology (IEEE-NANO 2013)最新文献

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Magnetic manipulation for spatially patternel alginate hydrogel microfibers 空间模式海藻酸盐水凝胶微纤维的磁操纵
Pub Date : 2013-08-01 DOI: 10.1109/NANO.2013.6721032
Chengzhi Hu, M. Nakajima, Huaping Wang, Tao Yue, Yajing Shen, Masaru Takeuchi, Qiang Huang, M. Seki, T. Fukuda
Alginate hydrogel finds widespread applications in tissue engineering, cancer therapy, wound management and drug/cell/growth factor delivery due to its biocompatibility, hydrated environment and desirable viscoelastic properties. However Lack of controllability is still an obstacle for utilizing it in the fabrication of 3D tissue constructs and accurate targeting in mass delivery. Here, we proposed a new method for achieving magnetic alginate hydrogel microfiber by encapsulating magnetic nanoparticles inside alginate solution and solidifying the magnetic alginate into hydrogel fiber inside microfluidic chips and micro syringe system. The fabrication method for 3 layered microfluidic channel was given. In the experiments, the magnetic nanoparticles and alginate solution present to be a uniform suspension, no aggregation of magnetic nanoparticles was found, which is crucial for flow control inside microfluidic chips. By regulating the flow rate of different solutions inside the chip, magnetic hydrogel fiber and pure hydrogel fiber are achieved with controllable diameters. Patterning device and magnetic pillar were employed as a magnetic guidance to pattern and align the magnetic fibers. The proposed method for fabricating magnetic hydrogel fiber holds great potentials to engineer 3D tissue constructs with complex architectures and hierarchical vascular networks to mimic the native tissue microenvironment.
海藻酸盐水凝胶由于其生物相容性、水合环境和理想的粘弹性特性,在组织工程、癌症治疗、伤口管理和药物/细胞/生长因子输送方面有着广泛的应用。然而,缺乏可控性仍然是利用它制造三维组织结构和精确定位的障碍。本文提出了一种磁性藻酸盐水凝胶微纤维的制备方法,将磁性纳米颗粒包埋在藻酸盐溶液中,并将磁性藻酸盐固化在微流控芯片和微注射器系统中的水凝胶纤维中。给出了三层微流控通道的制备方法。在实验中,磁性纳米颗粒与海藻酸盐溶液呈均匀悬浮,没有发现磁性纳米颗粒的聚集,这对微流控芯片内部的流动控制至关重要。通过调节芯片内不同溶液的流速,实现磁性水凝胶纤维和纯水凝胶纤维的直径可控。采用图纹装置和磁柱作为磁导,对磁性纤维进行图纹和排列。所提出的制备磁性水凝胶纤维的方法在设计具有复杂结构和分层血管网络的3D组织结构以模拟天然组织微环境方面具有很大的潜力。
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引用次数: 1
Investigation of TiO2-SiO2-Fe3O4 core-shell nanoparticle properties with different functional layer thickness 不同功能层厚度TiO2-SiO2-Fe3O4核壳纳米颗粒性能研究
Pub Date : 2013-08-01 DOI: 10.1109/NANO.2013.6720937
Junyang Li, C. Xue, Qiang Zhang, Libo Gao, Zhenyin Hai, Hongyan Xu, Dong Sun
This paper investigates different properties of the TiO2-SiO2-Fe3O4 core-shell nanoparticles encapsulated for 1 times, 2 times, 3 times (which are named as TSF1, TSF2 and TSF3 in this paper). The TSF nanoparticles were obtained through carbon reduction method and sol-gel method. The properties of the TSF1, TSF2 and TSF3 were characterized by Transmission Electron Microscope (TEM), X-ray Diffraction (XRD), Vibratory Sample Magnetometer (VSM) and BET surface areas. The results show that the TSF2 exhibited better property than the others. The relationships between the irradiation time and decoloration rate of the TSF1, TSF2 and TSF3 indicate that the TSF2 has significant efficiency in decolorating the methyl orange under ultraviolet light.
本文研究了1次、2次、3次包封的TiO2-SiO2-Fe3O4核壳纳米粒子(本文分别命名为TSF1、TSF2和TSF3)的不同性质。通过碳还原法和溶胶-凝胶法制备了TSF纳米颗粒。采用透射电镜(TEM)、x射线衍射(XRD)、振动样品磁强计(VSM)和BET表面积对TSF1、TSF2和TSF3的性能进行了表征。结果表明,TSF2具有较好的性能。TSF1、TSF2和TSF3的辐照时间与脱色率的关系表明,TSF2在紫外光下对甲基橙的脱色效果显著。
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引用次数: 1
Resistive random access memories with nanodiamond dielectric films 纳米金刚石介电薄膜的电阻随机存取存储器
Pub Date : 2013-08-01 DOI: 10.1109/NANO.2013.6720929
Chichun Lu, Y. Chu, Y. Tzeng
We report the application of nanodiamond prepared by microwave plasma chemical deposition system as the dielectric film with copper as top electrodes and a tungsten counter electrode for the fabrication of resistive random access memory (RRAM). The RRAM is switched between the high-resistivity state and a low-resistivity state of nanodiamond film. The high or low resistance state can be probed by applying a low voltage across two counter electrodes on two sides of the nanodiamond film and measuring its conduction current. We observed that the Cu/Nanodiamond/W structure shows good performance with ON/OFF current ratio >105 and retention time >104 s. Nanodiamond is known to be chemically inert, good for heat dissipation, and has very low solid solubility in copper. It is, therefore, a suitable dielectric material for RRAM for harsh environments.
本文报道了用微波等离子体化学沉积法制备的纳米金刚石作为介质膜,以铜为顶电极,钨为对电极,用于制作电阻式随机存取存储器(RRAM)。RRAM在纳米金刚石薄膜的高电阻率状态和低电阻率状态之间切换。通过在纳米金刚石薄膜两侧的两个对电极上施加低电压并测量其传导电流,可以探测到高电阻或低电阻状态。我们观察到Cu/Nanodiamond/W结构具有良好的性能,开关电流比>105,保持时间>104 s。众所周知,纳米金刚石具有化学惰性,散热性好,在铜中的固体溶解度很低。因此,它是用于恶劣环境的RRAM的合适介电材料。
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引用次数: 0
Pd modified ZnO nanorod based high dynamic range Hydrogen sensor 基于Pd修饰ZnO纳米棒的高动态范围氢传感器
Pub Date : 2013-08-01 DOI: 10.1109/NANO.2013.6720845
N. Banerjee, S. Roy, C. Sarkar, P. Bhattacharyya
In this paper we report on a high dynamic range Hydrogen sensor based on surface modified aligned ZnO hexagonal nanorods. ZnO nanorods were deposited by Chemical Bath Deposition (CBD) technique on SiO2 coated <;100> p-Si substrate. The nanorods having average diameter of 250-300 nm and average length of 400-500 nm is then surface sensitized by Palladium (Pd) nanoparticles. After structural and electrical characterization, both unmodified and surface modified nanorod based sensors were tested for Hydrogen (H2) detection in the resistive mode with Pd-Ag catalytic electrode. Both types of sensors offered appreciably high dynamic range (100ppm-20000ppm) at their respective operating temperature of 200°C and 150°C with corresponding response magnitude of ~76% and ~88%. Apart from improvement in response magnitude and reduction in the optimum operating temperature, the surface modification of nanorod also offered significant improvement (faster) in response time and recovery time. The high dynamic range of sensing (H2) makes this sensor useful for wide range of applications starting from domestic to commercial appliances.
本文报道了一种基于表面修饰排列ZnO六方纳米棒的高动态范围氢传感器。采用化学浴沉积(CBD)技术在SiO2包覆的p-Si衬底上制备了ZnO纳米棒。平均直径为250 ~ 300 nm,平均长度为400 ~ 500 nm的纳米棒用钯纳米粒子表面增敏。在完成结构和电学表征后,采用Pd-Ag催化电极对未修饰和表面修饰的纳米棒传感器进行了电阻模式下的氢气(H2)检测。在200°C和150°C的工作温度下,两种类型的传感器都提供了相当高的动态范围(100ppm-20000ppm),相应的响应幅度为~76%和~88%。纳米棒的表面改性除了提高响应幅度和降低最佳工作温度外,在响应时间和恢复时间方面也有显著改善(更快)。传感(H2)的高动态范围使该传感器适用于从家用到商用电器的广泛应用。
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引用次数: 6
MEMS based microfluidic system for HIV detection 基于MEMS的HIV检测微流控系统
Pub Date : 2013-08-01 DOI: 10.1109/NANO.2013.6721005
A. Ganesan, D. Kishore Kumar, Anomitra Banerjee, S. Swaminathan
ART guidelines of World Health Organization recommend a series of tests for HIV diagnostics (HIV antibody test, CD4 cell count and HIV viral load count). There are several modern technologies that are available to ensure reliable HIV diagnosis employing various principles. However, there is a need for point-of-care system that will eliminate the requirement of the patient to visit a hospital for initial diagnosis. In this paper, a novel design and analysis of MEMS based microfluidic chip facilitating point-of-care diagnostics is presented. The chip is based on the CD4 T+ cell count in blood. The device involves an array of silicon micro-needles each of length 250 microns, that would remove blood directly from the veins and feed it to a silicon micro-channel with alternating constrictions. These constrictions are coated with anti-CD4 Ab molecules to selectively adsorb CD4 T+ cells. An alternating current (AC) impedometric method is then used for discrimination and enumeration of these immobilized cells. The results strongly indicate the reliability of low-cost point of care diagnostics for HIV diagnosis.
世界卫生组织的抗逆转录病毒治疗指南建议进行一系列艾滋病毒诊断测试(艾滋病毒抗体测试、CD4细胞计数和艾滋病毒载量计数)。有几种现代技术可确保采用各种原则进行可靠的艾滋病毒诊断。然而,需要一种即时护理系统,这将消除患者前往医院进行初步诊断的要求。本文提出了一种新的基于MEMS的微流控芯片的设计和分析,以促进即时诊断。该芯片基于血液中的CD4 T+细胞计数。该装置包括一组长度为250微米的硅微针,可以直接从静脉中抽出血液,并将其输送到交替收缩的硅微通道中。这些收缩包被抗CD4 Ab分子,选择性吸附CD4 T+细胞。然后使用交流阻抗法对这些固定细胞进行鉴别和计数。结果强烈表明低成本的护理点诊断对HIV诊断的可靠性。
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引用次数: 3
Silver nanowires transparent conductive films: Fabrication using different sintering techniques 银纳米线透明导电薄膜:采用不同烧结技术制备
Pub Date : 2013-08-01 DOI: 10.1109/NANO.2013.6720806
J. Jiu, T. Sugahara, M. Nogi, S. Nagao, K. Suganuma
Large-scale synthesis of silver nanowires (AgNWs) is achieved by an improved facile polyol method, with the diameter about 70 nm and the length exceeding 20 μm. The synthesized AgNWs can be processed to form a highly transparent thin film, making nanowire networks to realize high electrical conductivity. Simple oven heating and fast light sintering methods have been examined for curing the films, and achieved high transparency and excellent conductivity in both the cases. The obtained conductive transparent films of AgNW are expected to have a wide variety of applications such as solar cells, flat displays, and touch panel sensors in future.
采用改进的易溶多元醇法制备了银纳米线(AgNWs),其直径约为70 nm,长度超过20 μm。合成的AgNWs可以加工成高透明的薄膜,形成纳米线网络,实现高导电性。研究了简单的烘箱加热和快速光烧结两种固化方法,均获得了高透明度和优异的导电性。所获得的AgNW导电透明膜有望在未来具有广泛的应用,如太阳能电池,平板显示器和触摸面板传感器。
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引用次数: 4
The investigation of surface roughness of substrate on electrochromic characteristics for PMeT thin film 基板表面粗糙度对PMeT薄膜电致变色特性的影响
Pub Date : 2013-08-01 DOI: 10.1109/NANO.2013.6720844
C. Yang, J. Chou, Yi-Hung Liao, Chia-Yu Liu, Pei-An Ho, C. Huang, Hsueh-Tao Chou
The objective of this study is to investigate the influence of surface roughness on electrochromic characteristics. The rough surface of indium tin oxide/glass (ITO/Glass) was prepared by wet etching. And the poly (3-methylthiophene) (PMeT) has been deposited on ITO/Glass by potentiostatic method. The electrochromic behaviors of the PMeT/ITO/Glass were performed in 0.1 M lithium perchlorate (LiClO4)/propylene carbonate (PC) electrolyte. Compared with the oxalic acid ((COOH)2·H2O) and ferric chloride + hydrochloric acid (FeCl3+HCl) solutions, the ITO/Glass has high surface roughness when the ITO/Glass was etched in (COOH)2·H2O solution. The PMeT/ITO/Glass has the best transmittance variation (ΔT(%)) (25 %) at 450 nm after the ITO/Glass was etched in (COOH)2·H2O solution for 160 sec. And, the PMeT/ITO/Glass has the best transmittance variation (ΔT(%)) (5 %) at 650 nm after the ITO/Glass was etched in FeCl3+HCl solution for 60 sec. Furthermore, the experimental results observed that the color of PMeT/ITO/Glass was changed from blue (oxidation state) to red (reduction state).
本研究的目的是研究表面粗糙度对电致变色特性的影响。采用湿法刻蚀法制备了氧化铟锡玻璃(ITO/ glass)的粗糙表面。用恒电位法在ITO/Glass上沉积了聚(3-甲基噻吩)(PMeT)。在0.1 M高氯酸锂(LiClO4)/碳酸丙烯酯(PC)电解质中,研究了PMeT/ITO/Glass的电致变色行为。与草酸((COOH)2·H2O)和氯化铁+盐酸(FeCl3+HCl)溶液相比,在(COOH)2·H2O溶液中蚀刻ITO/Glass具有较高的表面粗糙度。在(COOH)2·H2O溶液中蚀刻160秒后,PMeT/ITO/Glass在450 nm处透光率变化最大(ΔT(%))(25%),在FeCl3+HCl溶液中蚀刻60秒后,PMeT/ITO/Glass在650 nm处透光率变化最大(ΔT(%))(5%)。实验结果表明,PMeT/ITO/Glass的颜色由蓝色(氧化态)变为红色(还原态)。
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引用次数: 0
Mechanical properties of a novel nano-thermal interface material 一种新型纳米热界面材料的力学性能
Pub Date : 2013-08-01 DOI: 10.1109/NANO.2013.6720990
Wanli Peng, C. Zandén, L. Ye, Xiuzhen Lu, Johan Liu
Continued miniaturization in combination with increased performance in microelectronics has generated an urgent need for improved thermal management techniques in order to maintain reliability in systems and devices. Thermal interface materials play a key role in the development of solutions for thermal management in microelectronics. In this paper, mechanical properties of a nanotechnology enhanced thermal interface material (Nano-TIM) were studied. The material is based on Sn-Ag-Cu based alloy reinforced with nano scale fiber matrix. Tensile tests were used to investigate and compare the elastic modulus at room temperature and mechanical strength between 20 to 100°C. Scanning Electron Microscopy (SEM) analysis techniques were used to investigate the morphology of the fracture section after tensile tests as well as the internal structure of the samples. The results show that the Nano-TIM can have a significantly lower elastic modulus compared to the pure alloy phase of SnAgCu due to its fiber phase. A lower elastic modulus of the solder joint can be important since it will reduce the stress transfer across the interface. This is particular important when the joint substrates have mismatching coefficients of thermal expansion. The findings of this study thus indicate that the Nano-TIM may provide a useful alternative to improve the thermomechanical reliability compared to pure solder joints.
微电子技术的持续小型化和性能的不断提高,迫切需要改进热管理技术,以保持系统和设备的可靠性。热界面材料在开发微电子热管理解决方案中起着关键作用。研究了纳米技术增强热界面材料(Nano-TIM)的力学性能。该材料以Sn-Ag-Cu基合金为基础,以纳米纤维为基体增强。拉伸试验用于研究和比较室温下的弹性模量和20至100°C之间的机械强度。采用扫描电镜(SEM)分析技术对试样拉伸后断口的形貌及内部组织进行了研究。结果表明,与纯合金相SnAgCu相比,纳米tim具有较低的弹性模量。低弹性模量的焊点可以是重要的,因为它将减少在界面上的应力传递。当接头衬底具有不匹配的热膨胀系数时,这一点尤为重要。因此,本研究结果表明,与纯焊点相比,纳米tim可以提供一种有用的替代方法来提高热机械可靠性。
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引用次数: 0
Jet rollable nanoimprint lithography with piezoelectric jetting of resist 采用压电喷射抗蚀剂的喷射可滚压纳米压印技术
Pub Date : 2013-08-01 DOI: 10.1109/NANO.2013.6720909
David Gehlhausen, S. Menezes, Lichuan Chen, Gyu-ho Kim, Hongbing Lu, Jinming Gao, Walter Hu
We report an jet rollable nanoimprint lithography tool as a low cost method to produce micro- and nano-structures rapidly over large areas. We integrated a piezoelectric nozzle to deposit resist in-line in a low-waste, high-precision manner. We demonstrate the capabilities of this system by creating a variety of microstructures in SU8 resist with high pattern transfer fidelity.
我们报告了一种喷射可卷曲纳米压印工具,作为一种低成本的方法,可以在大面积上快速生产微纳米结构。我们集成了一个压电喷嘴,以低浪费、高精度的方式在线沉积抗蚀剂。我们通过在SU8抗蚀剂中创建具有高模式转移保真度的各种微结构来证明该系统的能力。
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引用次数: 0
Harnessing the synergistic cooperation of silver nanowires and graphene for enhanced electrochemical detection of hydrogen peroxide 利用银纳米线和石墨烯的协同合作增强过氧化氢的电化学检测
Pub Date : 2013-08-01 DOI: 10.1109/NANO.2013.6720797
Mei Zhang, Zuankai Wang
A facile one-step strategy to synthesize hybrid Ag NWs-graphene nanostructure for enhanced electrochemical detection of hydrogen peroxide was reported. The simple nature of our process leads to formation of Ag continuous and seamless integrated NWs-graphene hybrids with excellent interfacial electron transfer, avoiding the interface problems associated with the multiple-step process Interestingly, the one-step process also leads to the synergistic cooperation of graphene and Ag NWs: graphene promotes the continuous and preferential growth of long NWs by suppressing the deposition of undesirable Ag nanoparticles and short Ag NWs and facilitates the charge transfer and reactants transport by bridging the random Ag NWs, whereas Ag NWs prevents the aggregation of individual graphene sheet. By harnessing the synergy between individual constituents and their advantages, we show that the hybrid film exhibits enhanced electrochemical activity for the detection of H2O2. We envision that the new nanostructured electrode with enhanced electrocatalytic activity offers great promise for new class of biosensors in environmental and biomedical applications.
报道了一种简单的一步合成混合纳米结构Ag - nws -石墨烯的策略,用于增强过氧化氢的电化学检测。我们的工艺性质简单,形成了银连续无缝集成的NWs-石墨烯杂化体,具有优异的界面电子转移,避免了多步骤工艺带来的界面问题。有趣的是,一步工艺还导致了石墨烯和银NWs的协同合作。石墨烯通过抑制不需要的银纳米粒子和短银NWs的沉积,促进长NWs的连续和优先生长,并通过桥接随机的银NWs促进电荷转移和反应物运输,而银NWs则阻止单个石墨烯片的聚集。通过利用单个成分之间的协同作用及其优势,我们发现混合膜具有增强的检测H2O2的电化学活性。我们设想这种具有增强电催化活性的新型纳米结构电极为环境和生物医学应用中的新型生物传感器提供了巨大的希望。
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引用次数: 0
期刊
2013 13th IEEE International Conference on Nanotechnology (IEEE-NANO 2013)
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