Min Liang, Jingya Gong, Jianfeng Xu, Ru Liu, Ling Long
Abstract Formaldehyde-free adhesives are gaining attention due to their compatibility with green production methods. Decorative base paper (DBP) is known for its physical strength and printability and has a high ability for absorbing aldehyde-free adhesives for impregnation. In this paper, DBP was prepared with TiO 2 and SiO 2 combined with polyvinyl alcohol (PVA), where the amount of TiO 2 was reduced in the pulp process. The prepared DBP was impregnated by aldehyde-free adhesive and hot-pressed on wood-based panels. The results showed that upon SiO 2 coating, the surface smoothness of base paper increased by 132.3 %, whereas the tensile strength increased by 33.6 %. Furthermore, the colour density of cyan, magenta, yellow and black colours increased by 75.4 %, 99.2 %, 51.9 % and 90.5 %, respectively. The surface properties like surface bonding strength and wear resistance of the covered wood-based panels were found to satisfy the standard requirements, which indicates the products can be used for furniture products.
{"title":"Preparation and properties of a novel decorative base paper for formaldehyde-free adhesive impregnation","authors":"Min Liang, Jingya Gong, Jianfeng Xu, Ru Liu, Ling Long","doi":"10.1515/npprj-2023-0027","DOIUrl":"https://doi.org/10.1515/npprj-2023-0027","url":null,"abstract":"Abstract Formaldehyde-free adhesives are gaining attention due to their compatibility with green production methods. Decorative base paper (DBP) is known for its physical strength and printability and has a high ability for absorbing aldehyde-free adhesives for impregnation. In this paper, DBP was prepared with TiO 2 and SiO 2 combined with polyvinyl alcohol (PVA), where the amount of TiO 2 was reduced in the pulp process. The prepared DBP was impregnated by aldehyde-free adhesive and hot-pressed on wood-based panels. The results showed that upon SiO 2 coating, the surface smoothness of base paper increased by 132.3 %, whereas the tensile strength increased by 33.6 %. Furthermore, the colour density of cyan, magenta, yellow and black colours increased by 75.4 %, 99.2 %, 51.9 % and 90.5 %, respectively. The surface properties like surface bonding strength and wear resistance of the covered wood-based panels were found to satisfy the standard requirements, which indicates the products can be used for furniture products.","PeriodicalId":19315,"journal":{"name":"Nordic Pulp & Paper Research Journal","volume":"15 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135995964","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nelson Rubens Nascimento Del’Antonio, Mariele Fioreze, Márcio Caliari, João Pedro Amaral, Claudio Mudadu Silva
Abstract Routinely, the mills perform programmed maintenance shutdowns (PMS) that can affect the characteristics of the effluents and the performance of the effluent treatment plant (ETP). A careful planning of the PMS, along with the use of industrial process sectorial spill control and the use of the emergency spill lagoon have considerably minimized these effects. The Suzano pulp mill located in Aracruz (Brazil) has three production lines and carry out, on average, PMS of each production line separately, every 15 months of operation. The purpose of the study was to evaluate the effects of the PMS on the effluent characteristics and performance of the ETP compared to the periods of normal operation. The results showed that during the PMS, the physicochemical characteristics of the raw and treated effluents were like those found during normal operation. The lower organic loads found in the effluents during the PMS periods were associated with the decrease of the flow rates and the increase of the hydraulic retention time of the ETP, causing a better performance of COD, BOD, TSS and AOX removal. A proper planning of the PMS improved the performance of the ETP and the treated effluent quality remained similar to those during the normal operating period.
{"title":"Effects of programmed maintenance shutdowns on effluent quality of a bleached kraft pulp mill","authors":"Nelson Rubens Nascimento Del’Antonio, Mariele Fioreze, Márcio Caliari, João Pedro Amaral, Claudio Mudadu Silva","doi":"10.1515/npprj-2023-0043","DOIUrl":"https://doi.org/10.1515/npprj-2023-0043","url":null,"abstract":"Abstract Routinely, the mills perform programmed maintenance shutdowns (PMS) that can affect the characteristics of the effluents and the performance of the effluent treatment plant (ETP). A careful planning of the PMS, along with the use of industrial process sectorial spill control and the use of the emergency spill lagoon have considerably minimized these effects. The Suzano pulp mill located in Aracruz (Brazil) has three production lines and carry out, on average, PMS of each production line separately, every 15 months of operation. The purpose of the study was to evaluate the effects of the PMS on the effluent characteristics and performance of the ETP compared to the periods of normal operation. The results showed that during the PMS, the physicochemical characteristics of the raw and treated effluents were like those found during normal operation. The lower organic loads found in the effluents during the PMS periods were associated with the decrease of the flow rates and the increase of the hydraulic retention time of the ETP, causing a better performance of COD, BOD, TSS and AOX removal. A proper planning of the PMS improved the performance of the ETP and the treated effluent quality remained similar to those during the normal operating period.","PeriodicalId":19315,"journal":{"name":"Nordic Pulp & Paper Research Journal","volume":"12 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135944352","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Lignin, as a widely distributed, renewable and environmentally friendly source of carbon, could been utilized for carbon nanofibers to not only maximize the usage of resources, but also expand the energy-related opportunities. In this research, flexible lignin-based carbon nanofibers are prepared by electrospinning lignin nanofibers in a new green aqueous solution of lignin and polyvinyl alcohol (PVA), which is then characterized by physical and chemical characterizations. The results reveal that optimal carbonization temperature of 800 °C shows great improvements on the structural properties of lignin-based carbon nanofibers, which can be applied as binder-free electric double layer capacitor (EDLC) electrodes with good flexibility. The 2032 type button battery has a superior electrochemical performance with a large specific capacitance of 217.2 F g −1 at a 0.2 A g −1 current density, and remarkable cyclic stability of 94.9 % capacitance retention even after 10,000 charge and discharge cycles, due to the abundance of mesoporous volume and large microporous surface area of lignin-based carbon nanofiber electrodes carbonized in 800 °C.
摘要木质素作为一种分布广泛、可再生、环境友好的碳源，可以用于纳米碳纤维的制备，不仅可以最大限度地利用资源，还可以扩大与能源相关的机会。在新型绿色木质素-聚乙烯醇水溶液中，采用静电纺丝法制备了柔性木质素基碳纳米纤维，并对其进行了理化表征。结果表明，最佳碳化温度为800℃时，木质素基碳纳米纤维的结构性能有较大改善，可作为无粘结剂双电层电容器(EDLC)电极，具有良好的柔韧性。2032型纽扣电池具有优异的电化学性能，在0.2 a g−1电流密度下，其比电容高达217.2 F g−1，在800℃下炭化的木质素基纳米碳纤维电极具有丰富的介孔体积和较大的微孔表面积，在10000次充放电循环后仍保持94.9%的电容稳定性。
{"title":"Preparation of flexible and binder-free lignin-based carbon nanofiber electrode materials by electrospinning in aqueous system","authors":"Yunxia Wang, Pengfei Hao, Lirong Lei, Yi Hou","doi":"10.1515/npprj-2023-0026","DOIUrl":"https://doi.org/10.1515/npprj-2023-0026","url":null,"abstract":"Abstract Lignin, as a widely distributed, renewable and environmentally friendly source of carbon, could been utilized for carbon nanofibers to not only maximize the usage of resources, but also expand the energy-related opportunities. In this research, flexible lignin-based carbon nanofibers are prepared by electrospinning lignin nanofibers in a new green aqueous solution of lignin and polyvinyl alcohol (PVA), which is then characterized by physical and chemical characterizations. The results reveal that optimal carbonization temperature of 800 °C shows great improvements on the structural properties of lignin-based carbon nanofibers, which can be applied as binder-free electric double layer capacitor (EDLC) electrodes with good flexibility. The 2032 type button battery has a superior electrochemical performance with a large specific capacitance of 217.2 F g −1 at a 0.2 A g −1 current density, and remarkable cyclic stability of 94.9 % capacitance retention even after 10,000 charge and discharge cycles, due to the abundance of mesoporous volume and large microporous surface area of lignin-based carbon nanofiber electrodes carbonized in 800 °C.","PeriodicalId":19315,"journal":{"name":"Nordic Pulp & Paper Research Journal","volume":"2015 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135132376","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fernando Alves, Michel De Oliveira Picanço, Jair Rogerio Colares Neto, Tatiana de Fátima Martins Pires, Pedro Ygor Correia, Danillo Wisky Silva, Jordão Cabral Moulin
Abstract The industrial sector is increasingly interested in the production of yarns based on renewable, efficient, innovative, and ecological resources. Among these precursors, cellulose nanofibrils (NFC) have gained attention due to their interesting characteristics for the development of new products. However, their dimensions pose challenges in their use. Therefore, this study aimed to analyze the influence of NFC concentrations and dimensions on the quality of bicomponent yarns. The bicomponent yarns were produced using a coaxial needle and the dry–wet-spinning method. The outer layer was made of guar gum (3 % w/v) and the inner layer of NFC bleached at two different degrees of refining (NFC A and NFC B). Yarn production involved varying concentrations of NFC (4.5 %, 3.5 % and 2.5 % w/v) NFC, which were characterized by real density analyses, tensile strength, water absorption, thermogravimetry, and scanning electron microscopy. Guar gum showed more hydrophilic characteristics, and its delay in hardening caused a less circular section and flaps on the side of the yarn. NFC B exhibited the smallest average diameter, and higher concentrations resulted in yarns with greater mechanical strength, more circular cross-sections, and fewer microstructural defects.
{"title":"Effect of cellulose nanofibril concentration and diameter on the quality of bicomponent yarns","authors":"Fernando Alves, Michel De Oliveira Picanço, Jair Rogerio Colares Neto, Tatiana de Fátima Martins Pires, Pedro Ygor Correia, Danillo Wisky Silva, Jordão Cabral Moulin","doi":"10.1515/npprj-2023-0039","DOIUrl":"https://doi.org/10.1515/npprj-2023-0039","url":null,"abstract":"Abstract The industrial sector is increasingly interested in the production of yarns based on renewable, efficient, innovative, and ecological resources. Among these precursors, cellulose nanofibrils (NFC) have gained attention due to their interesting characteristics for the development of new products. However, their dimensions pose challenges in their use. Therefore, this study aimed to analyze the influence of NFC concentrations and dimensions on the quality of bicomponent yarns. The bicomponent yarns were produced using a coaxial needle and the dry–wet-spinning method. The outer layer was made of guar gum (3 % w/v) and the inner layer of NFC bleached at two different degrees of refining (NFC A and NFC B). Yarn production involved varying concentrations of NFC (4.5 %, 3.5 % and 2.5 % w/v) NFC, which were characterized by real density analyses, tensile strength, water absorption, thermogravimetry, and scanning electron microscopy. Guar gum showed more hydrophilic characteristics, and its delay in hardening caused a less circular section and flaps on the side of the yarn. NFC B exhibited the smallest average diameter, and higher concentrations resulted in yarns with greater mechanical strength, more circular cross-sections, and fewer microstructural defects.","PeriodicalId":19315,"journal":{"name":"Nordic Pulp & Paper Research Journal","volume":"18 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134885162","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Anders Ahlbom, Marco Maschietti, Rudi Nielsen, Merima Hasani, Hans Theliander
Abstract The depolymerisation of softwood kraft lignin was investigated, under hydrothermal conditions at 290 °C and 250 bar, with guaiacol in the reactor feed to evaluate its impact on the formation of char and on the molecular weights of the products. The effect of residence time was investigated in the time span 1–12 min. Lignin is depolymerised during the process and guaiacol is both formed and consumed during the reaction, with clearly noticeable changes as early as in the first minute of reaction. Although the addition of guaiacol in the reactor feed causes a reduction in the weight average molecular weight of the products, the yield of char increases. Longer residence times result in repolymerisation of the reaction products as well as a further increase in the yield of monoaromatic components and char.
{"title":"Using guaiacol as a capping agent in the hydrothermal depolymerisation of kraft lignin","authors":"Anders Ahlbom, Marco Maschietti, Rudi Nielsen, Merima Hasani, Hans Theliander","doi":"10.1515/npprj-2023-0013","DOIUrl":"https://doi.org/10.1515/npprj-2023-0013","url":null,"abstract":"Abstract The depolymerisation of softwood kraft lignin was investigated, under hydrothermal conditions at 290 °C and 250 bar, with guaiacol in the reactor feed to evaluate its impact on the formation of char and on the molecular weights of the products. The effect of residence time was investigated in the time span 1–12 min. Lignin is depolymerised during the process and guaiacol is both formed and consumed during the reaction, with clearly noticeable changes as early as in the first minute of reaction. Although the addition of guaiacol in the reactor feed causes a reduction in the weight average molecular weight of the products, the yield of char increases. Longer residence times result in repolymerisation of the reaction products as well as a further increase in the yield of monoaromatic components and char.","PeriodicalId":19315,"journal":{"name":"Nordic Pulp & Paper Research Journal","volume":"55 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134886190","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Andrea Christine Pfennich, Elisabeth Anna Schoeffmann, Herfried Lammer, Ulrich Hirn
Abstract Water-dispersible paper is useful for packaging applications as it disintegrates into its fibers after usage, and also is a fully biodegradable material. Here, we first introduce a laboratory testing method for the disintegration performance of different paper grades under low agitation in water. Then a quantitative analysis on the technological and physical mechanisms responsible for dispersibility of paper is performed. We identify lignin content, degree of refining and addition of starch as relevant factors reducing paper dispersibility. Addition of a debonding agent, a non-ionic surfactant, was not found to be effective here. We found a strong correlation of both, wet- and dry tensile strength to dispersibility. From all water absorption related paper properties only ultrasonic liquid penetration measurements were correlated to paper dispersibility. Principal component analysis revealed that paper strength and water penetration speed are not governed by different latent variables but instead are all strongly associated with the first principal component. This suggests that the same mechanisms are responsible for reduction of water penetration speed and wet/dry strength. Hence we suggest to decouple network strength and water penetration, e.g. by identifying suitable additives imparting bonding strength without reducing the access of water which is required to break the fiber–fiber bonds.
{"title":"Water-dispersible paper for packaging applications – balancing material strength and dispersibility","authors":"Andrea Christine Pfennich, Elisabeth Anna Schoeffmann, Herfried Lammer, Ulrich Hirn","doi":"10.1515/npprj-2023-0048","DOIUrl":"https://doi.org/10.1515/npprj-2023-0048","url":null,"abstract":"Abstract Water-dispersible paper is useful for packaging applications as it disintegrates into its fibers after usage, and also is a fully biodegradable material. Here, we first introduce a laboratory testing method for the disintegration performance of different paper grades under low agitation in water. Then a quantitative analysis on the technological and physical mechanisms responsible for dispersibility of paper is performed. We identify lignin content, degree of refining and addition of starch as relevant factors reducing paper dispersibility. Addition of a debonding agent, a non-ionic surfactant, was not found to be effective here. We found a strong correlation of both, wet- and dry tensile strength to dispersibility. From all water absorption related paper properties only ultrasonic liquid penetration measurements were correlated to paper dispersibility. Principal component analysis revealed that paper strength and water penetration speed are not governed by different latent variables but instead are all strongly associated with the first principal component. This suggests that the same mechanisms are responsible for reduction of water penetration speed and wet/dry strength. Hence we suggest to decouple network strength and water penetration, e.g. by identifying suitable additives imparting bonding strength without reducing the access of water which is required to break the fiber–fiber bonds.","PeriodicalId":19315,"journal":{"name":"Nordic Pulp & Paper Research Journal","volume":"20 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134886051","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Separator plays a key role in the safety and performances of lithium-ion batteries with the needs of good thermal stability and wettability. Compared with the commercial separator mainly made by polyolefins in organic solvents, the electrospinning of lignin/polyvinyl alcohol in an aqueous solution has been investigated as a green and economically viable method to produce high-performance separators without any other chemical additives. Lignin/polyvinyl alcohol (mass ratio: 3:7) nanofiber separators outperform commercial polypropylene separators in terms of porosity (71 %), liquid absorption (373 %), and outstanding thermal stability at 200 °C. Additionally, Li-ion battery cells that were constructed using different separators were assessed to demonstrate favorable electrochemical performance. The results showed that fabricated Li-ion battery with Lignin/polyvinyl alcohol (mass ratio: 3:7) nanofiber separators possesses a superior capacitance of 154.1 mA h g−1 at 0.5 C, and maintained outstanding cycle stability after 50 times of charging and discharging process at 0.5 C with the capacitance retention rate up to 98.7 %. The facile and sustainable synthesis strategy of lignin-based separator materials for Li-ion batteries developed in this work provides new perspectives for related research, especially based on environmentally friendly aqueous systems.
{"title":"Great potentials of lignin-based separator for Li-ion battery with electrospinning in aqueous system","authors":"Weipan Zhang, Peng-Yuan Hao, Lirong Lei, Yi Hou","doi":"10.1515/npprj-2023-0028","DOIUrl":"https://doi.org/10.1515/npprj-2023-0028","url":null,"abstract":"Abstract Separator plays a key role in the safety and performances of lithium-ion batteries with the needs of good thermal stability and wettability. Compared with the commercial separator mainly made by polyolefins in organic solvents, the electrospinning of lignin/polyvinyl alcohol in an aqueous solution has been investigated as a green and economically viable method to produce high-performance separators without any other chemical additives. Lignin/polyvinyl alcohol (mass ratio: 3:7) nanofiber separators outperform commercial polypropylene separators in terms of porosity (71 %), liquid absorption (373 %), and outstanding thermal stability at 200 °C. Additionally, Li-ion battery cells that were constructed using different separators were assessed to demonstrate favorable electrochemical performance. The results showed that fabricated Li-ion battery with Lignin/polyvinyl alcohol (mass ratio: 3:7) nanofiber separators possesses a superior capacitance of 154.1 mA h g−1 at 0.5 C, and maintained outstanding cycle stability after 50 times of charging and discharging process at 0.5 C with the capacitance retention rate up to 98.7 %. The facile and sustainable synthesis strategy of lignin-based separator materials for Li-ion batteries developed in this work provides new perspectives for related research, especially based on environmentally friendly aqueous systems.","PeriodicalId":19315,"journal":{"name":"Nordic Pulp & Paper Research Journal","volume":" ","pages":""},"PeriodicalIF":1.2,"publicationDate":"2023-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41838876","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Carton board packages with different creases have been manufactured and loaded with point loads to see if there is a difference in point load behavior depending on crease. A carton board was creased in four different ways. The differences of the creases were judged according to appearance and residual moment. Three of the four creases showed divergent appearances. The residual moment was as expected lowest for the hardest creased sample and vice versa. The packages with the different creases were loaded with a point load. The registered force – displacement curves were analyzed according to stiffness and collapse load. No statistically significant difference could be seen in the collapse load of the package or in the stiffness measured, indicating that with a standard point load measurement it was hard to distinguish a difference in packaging behavior due to creasing. In future work it might be interesting to further study the average stiffness, since a trend of higher average stiffness for lower matrix channel depth exists in the measurements, however not statistically ensured. One possibility to discern possibly existing differences in the resistance of packaging to point load due to crease differences could be to study the interaction in more detail.
{"title":"The influence of creases on carton board package behavior during point loading","authors":"Camilla Persson, Henry Eriksson, Christer Korin","doi":"10.1515/npprj-2023-0021","DOIUrl":"https://doi.org/10.1515/npprj-2023-0021","url":null,"abstract":"Abstract Carton board packages with different creases have been manufactured and loaded with point loads to see if there is a difference in point load behavior depending on crease. A carton board was creased in four different ways. The differences of the creases were judged according to appearance and residual moment. Three of the four creases showed divergent appearances. The residual moment was as expected lowest for the hardest creased sample and vice versa. The packages with the different creases were loaded with a point load. The registered force – displacement curves were analyzed according to stiffness and collapse load. No statistically significant difference could be seen in the collapse load of the package or in the stiffness measured, indicating that with a standard point load measurement it was hard to distinguish a difference in packaging behavior due to creasing. In future work it might be interesting to further study the average stiffness, since a trend of higher average stiffness for lower matrix channel depth exists in the measurements, however not statistically ensured. One possibility to discern possibly existing differences in the resistance of packaging to point load due to crease differences could be to study the interaction in more detail.","PeriodicalId":19315,"journal":{"name":"Nordic Pulp & Paper Research Journal","volume":" ","pages":""},"PeriodicalIF":1.2,"publicationDate":"2023-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46328497","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-09-01DOI: 10.1515/npprj-2023-frontmatter3
{"title":"Frontmatter","authors":"","doi":"10.1515/npprj-2023-frontmatter3","DOIUrl":"https://doi.org/10.1515/npprj-2023-frontmatter3","url":null,"abstract":"","PeriodicalId":19315,"journal":{"name":"Nordic Pulp & Paper Research Journal","volume":"43 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135298767","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
D. Toprak, Tulay Yilmaz, Kerem Gülpınar, A. Yücel, Yakup Çakmak, D. Ucar
Abstract Trace elements have a significant effect on biochemical reactions and therefore the presence of optimum levels of trace elements is essential for bioreactor performances. In this study, the effects of five trace elements on biomethane production have been investigated. Experimental studies have been carried out with multiple batch reactors at 15 day HRT and mesophilic temperatures. The optimum concentrations for each of the trace elements Fe, Cu, Ni, Co and Mg were found as 5, 0.5, 0.5, 0.5 and 100 mg/L, respectively. Among tested trace elements, Cu was the one which provided the highest biomethane production. Cu addition was resulted in a 46 % increase in biomethane production followed by Co with 24 %. The biomethane production rate for these two trace elements was 191.70 and 110.77 ml CH4/g COD, respectively. Optimum levels for Ni, Fe and Mg increased biomethane production rate by approximately 14.3, 10 and 17 % compared to control groups, respectively. Because the exact amount of trace element requirement for each industry/reactor is different, specific case studies should be performed for each application. These results could be used as initial trace element concentrations for further continuous studies.
微量元素对生物化学反应有重要影响，因此最佳微量元素水平的存在对生物反应器的性能至关重要。本研究研究了5种微量元素对生物甲烷生成的影响。实验研究进行了多批反应器在15 天HRT和中温。Fe、Cu、Ni、Co和Mg微量元素的最佳浓度分别为5、0.5、0.5、0.5和100 Mg /L。在所测微量元素中，Cu是提供最高生物甲烷产量的元素。添加Cu可使生物甲烷产量提高46 %，其次是Co，提高24 %。这两种微量元素的生物甲烷产率分别为191.70和110.77 ml CH4/g COD。与对照组相比，最佳水平的Ni、Fe和Mg分别使生物甲烷产量提高了14.3%、10%和17. %。由于每个工业/反应器对微量元素的确切需求量是不同的，因此应针对每种应用进行具体的案例研究。这些结果可以作为后续研究的初始微量元素浓度。
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