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Study on properties of paper coated with Stachys floridana Shuttlew.ex Benth hemicellulose – chitosan composite solution 半纤维素-壳聚糖复合溶液涂布纸的性能研究
IF 1.2 4区 农林科学 Q3 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-08-09 DOI: 10.1515/npprj-2023-0019
Jie Li, Haitang Liu, Qian Wang, Yefan Wang, Lin Chen, Xin Jin, Zhihua Guo, Tingting Wang, Xinyuan Zhang
Abstract The hemicellulose was extracted from the Stachys floridana Shuttlew.ex Benth by ultrasonic-assisted, fractional alcohol precipitation method, mixed with chitosan solution, and coated on the surface of the paper with three layers, to explore the effect of its morphology, thermal stability, barrier, mechanical properties of coated paper. The results showed that the gas barrier property of the paper coated with hemicellulose – chitosan mixed solution decreased from 180 mL/min to 0.265 mL/min, the water barrier property increased from 0 to 84.8°, and the oil barrier property increased from 0 to Kit nº11. The tearing degree of paper increased by 9.2 %, the folding resistance increased by 1296.6 %, dry and wet tensile strength and dry and wet rupture resistance were also significantly improved. The thermal stability mixed solution coated paper is slightly lower than the base paper, but higher than the pure chitosan coated paper. The prepared S. floridana Shuttlew.ex Benth hemicellulose – chitosan blend coating has good barrier property and mechanical properties, and has a wide application prospect.
摘要采用超声波辅助、分级醇沉法从花木中提取半纤维素,与壳聚糖溶液混合,在纸表面三层涂布,探讨其形态、热稳定性、阻隔性、力学性能对涂布纸性能的影响。结果表明,半纤维素-壳聚糖混合溶液涂布纸的阻气性能从180 mL/min至0.265 mL/min,隔水性能从0°增加到84.8°,隔油性能从0增加到Kit nº11。纸张撕裂度提高9.2 %, 折叠阻力增加了1296.6 %, 干、湿拉伸强度和耐干、湿断裂性能也显著提高。混合溶液涂布纸的热稳定性略低于原纸,但高于纯壳聚糖涂布纸。制备的S.floridana Shuttle.ex Benth半纤维素-壳聚糖共混涂料具有良好的阻隔性能和力学性能,具有广阔的应用前景。
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引用次数: 0
Preparation and application of epoxy cyclohexane/chitosan/methyl methacrylate composite material 环氧环己烷/壳聚糖/甲基丙烯酸甲酯复合材料的制备及应用
IF 1.2 4区 农林科学 Q3 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-08-08 DOI: 10.1515/npprj-2023-0018
Xuxing Li, Xuemei Wang, Jun Gao, Yingping Qi, Hua Li
Abstract As a cultural carrier of historical inheritance, paper has high cultural, historical and scientific research value. But with the passage of time and the change of the environment, many paper are aging and damaged. In order to protect the paper, epoxy cyclohexane/chitosan/methyl methacrylate composite material for paper protection was synthesized by radical grafting polymerization with potassium persulfate (KPS) as initiator and disodium hydrogen phosphate (DSP) as buffer reagent. Through single factor experiment, the synthetic condition was obtained as follows: 3 g of monomer dosage, 7.5 mL of initiator, 80 °C of reaction temperature, 3 h of reaction time. The aging test showed that the coating material could obviously improve the mechanical properties and anti-aging properties of paper. The reversibility experiment shows that the composite material has certain reversibility. The acid and alkali salt resistance experiment shows that the coating material could effectively resist external acid and alkali corrosion and protect paper. This study provides some theoretical guidance for the protection of paper cultural relics.
摘要论文作为历史传承的文化载体,具有较高的文化、历史和科学研究价值。但随着时间的推移和环境的变化,许多纸张都在老化和损坏。为了保护纸张,以过硫酸钾(KPS)为引发剂,磷酸氢二钠(DSP)为缓冲剂,通过自由基接枝聚合,合成了环氧环己烷/壳聚糖/甲基丙烯酸甲酯纸张保护复合材料。通过单因素实验,得到了合成条件如下: g单体用量,7.5 mL引发剂,80 反应温度°C,3 h的反应时间。老化试验表明,该涂料能明显改善纸张的力学性能和抗老化性能。可逆性实验表明,该复合材料具有一定的可逆性。耐酸碱耐盐实验表明,该涂料能有效地抵抗外界酸碱腐蚀,保护纸张。本研究为纸质文物的保护提供了一定的理论指导。
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引用次数: 0
Analyses of the effects of fiber diameter, fiber fibrillation, and fines content on the pore structure and capillary flow using laboratory sheets of regenerated fibers 使用实验室再生纤维片分析纤维直径、纤维原纤化和细粒含量对孔结构和毛细管流动的影响
IF 1.2 4区 农林科学 Q3 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-07-19 DOI: 10.1515/npprj-2022-0077
C. Helbrecht, M. Langhans, T. Meckel, M. Biesalski, S. Schabel
Abstract The aim of this work is to investigate the influence of fiber fibrillation and fines on the pore structure of well-defined regenerated fiber sheets as well as the water flow through the sheet. For this purpose, sheets were produced with refined, fibrillated fibers only, with unfibrillated fibers and fines, as well as with fibrillated fibers and fines. Next, the samples were analyzed by brightfield and fluorescence microscopy, mercury porosimetry, and an ascending test. Both the fibrils and the added fines reach into the pores between the fibers or are deposited there. As a result, pore size decreases and capillary flow slows down. The two effects overlap when the fiber surface is fibrillated and fines are present. Sheets with thicker fibers form a pore structure with larger pores in between the fibers. However, such a change in pore size has no significant influence on the flow of water through the sheet in the performed ascending tests. It is shown that a statistical model with the parameters fibrillation and fines content can be used to describe the ascending rate nearly as well as the Lucas–Washburn equation. Consequently, the equation could be improved by the addition of further fiber and sheet properties.
摘要本工作的目的是研究纤维原纤化和细颗粒对定义明确的再生纤维片材的孔结构以及通过片材的水流的影响。为此,片材仅用精制的原纤化纤维、未原纤化的纤维和细料以及原纤化光纤和细料生产。接下来,通过明场和荧光显微镜、汞孔隙率测定法和上升试验对样品进行分析。原纤维和添加的细料都进入纤维之间的孔隙或沉积在那里。结果,孔径减小,毛细管流动减慢。当纤维表面原纤化并且存在细颗粒时,这两种效应重叠。具有较厚纤维的片材形成在纤维之间具有较大孔隙的孔隙结构。然而,在进行的上升测试中,孔径的这种变化对通过片材的水流没有显著影响。结果表明,具有纤颤和细粒含量参数的统计模型可以用来描述上升速率,几乎与Lucas–Washburn方程一样好。因此,可以通过添加进一步的纤维和片材特性来改进该方程。
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引用次数: 0
Caustic and enzymatic effects on dissolving pulp and its performance as specialty fiber 碱和酶对溶解纸浆及其特种纤维性能的影响
IF 1.2 4区 农林科学 Q3 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-07-07 DOI: 10.1515/npprj-2023-0004
Chen Gong, Shujie Fan, Bin Yang, Yu Zhang, Jianping Ni, Zhen-hua Su
Abstract The aim of this study was to investigate an effective approach for improving the dissolving pulp properties for making specialty fiber. The caustic and enzymatic treatment of the properties of dissolving pulp was conducted by analyzing the macromolecular structure and chemical composition. The results showed that the enzymatic treatment was more effective on influencing the macromolecular properties, while the caustic treatment had more influence on structural changing, mainly cellulose crystal structure and crystallinity. Meanwhile, to maintain a higher purity and higher brightness, caustic treatment would be beneficial in comparison with enzymatic treatment. The performance of caustic treated sample was evaluated in regarding to chemical composition and acetylation reaction performance, using commercial pulp as reference. The competitive feature of treated sample suggested its potential in future application.
摘要:本研究旨在探讨改善特种纤维溶解浆性能的有效途径。通过分析溶解浆的大分子结构和化学成分,对溶解浆的性质进行了烧碱和酶处理。结果表明,酶处理对纤维素大分子性质的影响更大,而碱处理对纤维素结构变化的影响更大,主要是对纤维素晶体结构和结晶度的影响。同时,为了保持更高的纯度和更高的亮度,碱处理比酶处理更有利。以工业纸浆为参照,从化学成分和乙酰化反应性能两方面评价了碱处理后样品的性能。处理后样品的竞争性表明其在未来的应用潜力。
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引用次数: 0
Effect of cellulose micro/nanofibrils and carboxylated styrene butadiene rubber coating on sack kraft paper 纤维素微/纳米原纤维与羧化丁苯橡胶涂布对袋装牛皮纸的影响
IF 1.2 4区 农林科学 Q3 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-07-07 DOI: 10.1515/npprj-2023-0016
L. N. Hugen, Eduardo Miranda, Allan de Amorim dos Santos, R. C. Lago, L. Silva, G. Tonoli, S. Ferreira
Abstract The main objective of this research is to evaluate the influence of coating based on cellulose micro/nanofibrils (CMF) and carboxylated styrene butadiene rubber (XSBR) on sack kraft paper, for possible use in packaging. Filmogenic solutions were applied manually as a coating on sack kraft paper. These solutions were prepared by suspensions of CMF 1.5 % w/v with the addition of different content of XSBR (0, 2, 10, and 20 % about the total mass of CMF). Uncoated sack kraft paper was used as control. Films were obtained by casting and characterized physically, morphologically, and mechanically. The results demonstrated that XSBR and CMF composite suspension showed good performance as a coating on sack kraft paper. The formation of homogeneous structures well distributed on paper can be observed on scanning electron microscope images. Coatings containing XSBR presented a smoother surface, less porosity and hydrophilicity, and a greater coalescence, with good properties of air resistance and water vapor permeability. However, regarding mechanical properties, there were no improvements in coated papers. Therefore, the present study contributed information on the development of more flexible and hydrophobic cellulosic papers for possible applications in the industrial packaging sector.
摘要本研究的主要目的是评估基于纤维素微/纳米纤维(CMF)和羧化苯乙烯-丁二烯橡胶(XSBR)的涂层对麻袋牛皮纸的影响,以备在包装中使用。成膜溶液作为涂层手动施加在麻袋牛皮纸上。这些溶液是通过CMF1.5的悬浮液制备的 % w/v,添加不同含量的XSBR(0、2、10和20 % 大约CMF的总质量)。使用未涂布的袋装牛皮纸作为对照。通过流延获得薄膜,并对其进行物理、形态和机械表征。结果表明,XSBR和CMF复合悬浮液在麻袋牛皮纸上具有良好的涂层性能。在扫描电子显微镜图像上可以观察到均匀结构在纸上的形成。含有XSBR的涂层表面更光滑,孔隙率和亲水性更小,聚结性更强,具有良好的空气阻力和水蒸气渗透性。然而,在机械性能方面,涂布纸没有任何改进。因此,本研究为开发更具柔性和疏水性的纤维素纸在工业包装领域的可能应用提供了信息。
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引用次数: 0
Waste newspaper activation using sodium salts: a new perspective 利用钠盐活化废报纸:一个新视角
IF 1.2 4区 农林科学 Q3 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-07-04 DOI: 10.1515/npprj-2023-0014
Y. S. Hao, N. Othman, M. A. Ahmad Zaini
Abstract Waste newspaper causes contamination to the environment. Conversion of waste newspaper into activated carbon is a potential strategy due to its high carbon content. This paper aims to summarize recent advances in the production of activated carbons from waste newspaper and their applications in adsorption and wastewater treatment. The physicochemical properties from the use of different chemical activators with special emphasize on sodium salts to facilitate the adsorption of water pollutants were compared. The high BET surface and cost effectiveness allow the waste newspaper-based activated carbon as an economical alternative to be mass-produced for wastewater treatment.
废弃报纸对环境造成污染。由于废报纸含碳量高,将其转化为活性炭是一种潜在的策略。综述了废报纸活性炭的制备及其在吸附和废水处理中的应用研究进展。比较了不同化学活化剂对水污染物的吸附效果,重点介绍了钠盐对水污染物的吸附效果。高BET表面和成本效益使废报纸活性炭作为一种经济的替代方案被大量生产用于废水处理。
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引用次数: 0
Out-of-plane uniaxial loading of paperboard: experimental procedure and evaluation 纸板平面外单轴加载的实验方法与评价
IF 1.2 4区 农林科学 Q3 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-06-14 DOI: 10.1515/npprj-2023-0017
Kristofer Robertsson, J. Engqvist, M. Wallin, M. Ristinmaa, J. Tryding, Eric Borgqvist
Abstract Development of three-dimensional continuum models for paperboard is an active field and the need for reliable measurements to calibrate and validate such models is evident. An experimental device and protocol for cyclic out-of-plane loading is developed. This loading sequence is present during converting operations of paperboard. The experimental tests reveals that the commonly observed soft initial non-linear response during out-of-plane compression is a structural effect that stems from the surface roughness rather than being an inherent material behavior. A gluing procedure, used to perform cyclic out-of-plane loading, is mitigating the effect of the surface roughness. Several novel cyclic loading experiments are performed, alternating between compression and tension which indicates that fiber bonds are not recovered in compression after they have been broken through delamination. Measurements also show that the transition in compression and tension is continuous, hence the use of a switch function present in a number of constitutive continuum models for paperboard is deemed questionable.
摘要纸板三维连续体模型的开发是一个活跃的领域,显然需要可靠的测量来校准和验证这些模型。开发了一种用于平面外循环加载的实验装置和协议。这种装载顺序存在于纸板的转换操作期间。实验测试表明,在平面外压缩过程中常见的软初始非线性响应是一种结构效应,源于表面粗糙度,而不是固有的材料行为。用于执行循环平面外加载的胶合程序可以减轻表面粗糙度的影响。进行了几个新的循环加载实验,在压缩和拉伸之间交替,这表明纤维结合在通过分层后在压缩中没有恢复。测量还表明,压缩和拉伸的转变是连续的,因此在纸板的许多本构连续体模型中使用切换函数被认为是有问题的。
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引用次数: 0
Frontmatter 头版头条
4区 农林科学 Q3 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-06-01 DOI: 10.1515/npprj-2023-frontmatter2
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引用次数: 0
Disintegration of toilet papers used in shopping malls 商场里厕纸的分解
IF 1.2 4区 农林科学 Q3 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-05-26 DOI: 10.1515/npprj-2022-0089
Gulnur Mertoglu Elmas, Beyza Karabulut, Sultan Bekiroglu Ozturk, C. Atik, S. Sonmez
Abstract Paper has been used in the field of hygiene for centuries. Tissue papers have low grammage, creped or non-creped surface, and consisting of one or more layers from virgin papers. Toilet paper, which has an important area of use, comes at the beginning of the tissue papers divided into various product groups. Its use has increased even more with the effect of the coronavirus pandemic. Increasing use of toilet paper causes clogging in sewers as solid waste. Because an important and large part of the sewage is composed of cellulosic structures. Therefore, the disintegration of toilet paper is an important issue. The main properties of toilet paper are characterized by grammage, thickness, polymerization degree, softness and wet tensile strength. This study, it was aimed to determine the relationship between the degree of polymerization, thickness, grammage, softness and wet tension strength of toilet papers, which accumulate in the sewer pipes and cause clogging, and their disintegration in tap water and pure water at environment of different pH levels. A great level and positive linear relationship was found between grammage and in disintegration pH9. It was determined a low level and positive relationship with wet tensile strength in disintegration tap water.
纸在卫生领域已经使用了几个世纪。薄纸重量低,表面起皱或不起皱,由一层或多层原纸组成。卫生纸,其中有一个重要的使用领域,是在卫生纸开始被分成各种产品组。受冠状病毒大流行的影响,其使用量进一步增加。卫生纸的使用越来越多,导致下水道堵塞,成为固体废物。因为污水中有很大一部分是由纤维素结构组成的。因此,卫生纸的分解是一个重要的问题。卫生纸的主要性能有克重、厚度、聚合度、柔软度和湿拉伸强度。本研究旨在研究在不同pH值环境下,在自来水和纯净水中,聚积在下水道管道中造成堵塞的卫生纸的聚合度、厚度、重量、柔软度和湿拉伸强度与分解的关系。重量与崩解ph值呈极显著水平正线性关系。测定其与崩解自来水的湿抗拉强度呈低水平正相关。
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引用次数: 0
Interlaminar shear modulus of cardboard obtained by torsional and flexural vibration tests 通过扭转和弯曲振动试验获得纸板的层间剪切模量
IF 1.2 4区 农林科学 Q3 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-05-16 DOI: 10.1515/npprj-2023-0022
H. Yoshihara, Masahiro Yoshinobu, M. Maruta
Abstract The interlaminar shear modulus of cardboards was measured using torsional vibration (TV) and flexural vibration (FV) methods. In the TV method, the sample widths were decreased during the tests, and the interlaminar and in-plane shear moduli were determined using the data obtained based on the different widths. By contrast, in the FV method, the resonance frequencies from the first to third FV modes were measured using samples of various lengths, and the interlaminar shear modulus and Young’s modulus in the length direction were calculated using Timoshenko’s vibration theory. In addition to the experiment, modal analyses based on the finite element (FE) method were performed, and the sample configurations used to accurately obtain the interlaminar shear modulus were experimentally and numerically investigated. The TV method did not allow the interlaminar shear modulus to be obtained appropriately because the vibration behavior often deviated from that theoretically derived by the TV equation. By contrast, the FV method allowed the interlaminar shear modulus to be obtained appropriately for a wide range of sample lengths.
摘要采用扭转振动(TV)和弯曲振动(FV)两种方法测定了纸板的层间剪切模量。在TV方法中,在测试过程中减小了样品宽度,并使用基于不同宽度获得的数据来确定层间和平面内剪切模量。相反,在FV方法中,使用不同长度的样品测量第一至第三FV模式的共振频率,并使用Timoshenko的振动理论计算长度方向上的层间剪切模量和杨氏模量。除了实验之外,还进行了基于有限元(FE)方法的模态分析,并对用于精确获得层间剪切模量的样品配置进行了实验和数值研究。TV方法不允许适当地获得层间剪切模量,因为振动行为经常偏离TV方程的理论推导。相比之下,FV方法允许对于宽范围的样品长度适当地获得层间剪切模量。
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引用次数: 0
期刊
Nordic Pulp & Paper Research Journal
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