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Co-Application of Biochar Compost and Inorganic Nitrogen Fertilizer Affects the Growth and Nitrogen Uptake by Lowland Rice in Northern Ghana 生物炭堆肥与无机氮肥配施对加纳北部低地水稻生长和氮素吸收的影响
Pub Date : 2022-07-06 DOI: 10.3390/nitrogen3030027
D. Aboagye, Wilfred Teejay Adjadeh, E. Nartey, S. Asuming-Brempong
Inherent low soil fertility status limits productivity of rice in the lowland ecologies in Northern Ghana. Combining organic and inorganic nitrogen fertilizers could help to maintain the fertility of lowland soils for rice production. A screen house pot experiment was carried out to investigate the combined effect of biochar compost and inorganic nitrogen fertilizer on the nitrogen uptake and agronomic performance of rice plants grown on an eutric gleysol lowland soil. Inorganic nitrogen fertilizer alone and its combinations with different types of biochar compost (based on the proportions of biochar and compost) were used as treatment. A control (unamended soil) was also included. The incorporation of biochar compost and inorganic nitrogen fertilizer improved the growth parameters and yield components of rice plants. The combination of biochar compost and inorganic nitrogen fertilizer was also found to improve nitrogen uptake in rice plants. This practice could be the most likely viable option for alleviating lowland soil fertility issues and increasing rice productivity in Northern Ghana.
固有的低土壤肥力状况限制了加纳北部低地生态中水稻的生产力。有机氮肥与无机氮肥配合施用有助于保持低地土壤的肥力,有利于水稻生产。通过筛房盆栽试验,研究了生物炭堆肥与无机氮肥复合施用对水稻氮素吸收和农艺性能的影响。采用单施无机氮肥及其与不同类型生物炭堆肥(根据生物炭与堆肥的比例)的组合处理。对照(未改良土壤)也包括在内。生物炭堆肥和无机氮肥的掺入改善了水稻植株的生长参数和产量组成。生物炭堆肥与无机氮肥配施也能提高水稻对氮的吸收。这种做法可能是缓解加纳北部低地土壤肥力问题和提高水稻生产力的最有可能可行的选择。
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引用次数: 0
The First Reaction Steps of Lithium-Mediated Ammonia Synthesis: Ab Initio Simulation 锂介导的氨合成的第一个反应步骤:从头算模拟
Pub Date : 2022-07-04 DOI: 10.3390/nitrogen3030026
Dominykas Maniscalco, D. Rudolph, E. Nadimi, I. Frank
The reaction of molecular nitrogen with molecular hydrogen was simulated using ab initio molecular dynamics. The reaction was catalyzed by the addition of bulk lithium and oxygen. As is known from the experiment, the limiting step is the breaking of the nitrogen–nitrogen triple bond. We observed a mechanism that has not been discussed before: one of the nitrogen atoms of a nitrogen molecule is absorbed by the lithium bulk, whereas the other nitrogen atom reacts with hydrogen. Adding oxygen leads to a dominating reaction of oxygen with the lithium surface. The oxygen molecules break easily into single atoms and are, in part, absorbed by the lithium structure. Part of them remains on the surface and reacts with hydrogen. In this way, hydrogen is activated and can, in turn, react easily with molecular nitrogen. The overall reactivity as observed in the ab initio simulations reflects the extremely low density of lithium. Interstitial sites are readily occupied, leading to oxide and nitride structures.
采用从头算分子动力学方法模拟了分子氮与分子氢的反应。该反应通过添加大块锂和氧来催化。从实验可知,氮-氮三键的断裂是极限步骤。我们观察到一个以前没有讨论过的机制:氮分子的一个氮原子被锂体吸收,而另一个氮原子与氢反应。加入氧气导致氧与锂表面的主要反应。氧分子很容易分解成单个原子,部分被锂结构吸收。它们的一部分留在表面并与氢反应。通过这种方式,氢被激活,反过来,可以很容易地与分子氮反应。从头算模拟中观察到的总体反应性反映了锂的极低密度。间隙位置很容易被占据,导致氧化物和氮化物结构。
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引用次数: 1
Potential Impact of Learning Management Zones for Site-Specific N Fertilisation: A Case Study for Wheat Crops 学习管理区对特定地点氮肥的潜在影响:以小麦作物为例
Pub Date : 2022-06-13 DOI: 10.3390/nitrogen3020025
Camilo Franco, Nicolás Mejía, S. M. Pedersen, R. Gislum
This paper proposes an automatic, machine learning methodology for precision agriculture, aiming at learning management zones that allow a more efficient and sustainable use of fertiliser. In particular, the methodology consists of clustering remote sensing data and estimating the impact of decision-making based on the extracted knowledge. A case study is developed on experimental data coming from winter wheat (Triticum aestivum) crops receiving site-specific fertilisation. A first approximation to the data allows measuring the effects of the fertilisation treatments on the yield and quality of the crops. After verifying the significance of such effects, clustering analysis is applied on sensor readings on vegetation and soil electric conductivity in order to automatically learn the best configuration of zones for differentiated treatment. The complete methodology for identifying management zones from vegetation and soil sensing is validated for two experimental sites in Denmark, estimating its potential impact for decision-making on site-specific N fertilisation.
本文提出了一种用于精准农业的自动机器学习方法,旨在学习管理区域,以便更有效和可持续地使用肥料。具体而言,该方法包括遥感数据聚类和基于提取的知识估计决策影响。对冬小麦(Triticum aestivum)作物接受特定地点施肥的实验数据进行了案例研究。对数据的第一个近似可以测量施肥处理对作物产量和质量的影响。在验证了这些效应的显著性后,对植被和土壤电导率的传感器读数进行聚类分析,自动学习分区的最佳配置进行差异化处理。通过植被和土壤传感确定管理区域的完整方法在丹麦的两个试验点得到了验证,估计了其对特定地点氮肥决策的潜在影响。
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引用次数: 0
Using the Haney Soil Test to Predict Nitrogen Requirements in Winter Wheat (Triticum aestivum L.) 利用哈尼土壤试验预测冬小麦需氮量
Pub Date : 2022-06-09 DOI: 10.3390/nitrogen3020024
Debankur Sanyal, C. Graham
Managing nitrogen (N) is one of the of the biggest challenges in achieving environmental and economic sustainability in the agroecosystem. As N fertilizer prices have increased significantly, farmers are considering a revised N recommendation to optimize crop production, while addressing negative environmental impacts of excess N in water bodies. This study analyzes the accuracy of using the Haney Soil Test (HST) to predict the N requirement (HSTNR) of winter wheat (Triticum aestivum L.) in a semi-arid climate. The accuracy of the HST to predict the economically optimum N rate (EONR) was dependent on in-season precipitation. In drought conditions, the HSTNR was 33 kg N ha−1 lower on average than the EONR. Conversely, in wetter years, the HSTNR was 35 kg N ha−1 higher than the EONR. Net return was approximately USD 19 ha−1 lower than that with the EONR under both precipitation scenarios. Similar differences were found for protein content. There was a strong correlation between soil respiration and the soil health calculation, within the HST, and the difference between the net return on yield from the HSTNR and the EONR yield. These indicators may serve as useful metrics for formulating soil health-based N recommendations in winter wheat. However, in drought-prone areas, the HSTNR may significantly underpredict the EONR in many years due to an overestimation of N mineralization.
氮管理是实现农业生态系统环境和经济可持续性的最大挑战之一。随着氮肥价格的大幅上涨,农民们正在考虑修订氮肥建议,以优化作物生产,同时解决水体中过量氮对环境的负面影响。本研究分析了利用哈尼土壤试验(HST)预测半干旱气候条件下冬小麦(Triticum aestivum L.)需氮量(HSTNR)的准确性。HST预测经济最佳氮肥速率(EONR)的准确性依赖于季内降水。在干旱条件下,HSTNR比EONR平均低33 kg N ha - 1。相反,在湿润年份,HSTNR比EONR高35 kg N ha−1。两种降水情景下的净收益均比EONR低约19 ha−1。蛋白质含量也存在类似的差异。土壤呼吸与土壤健康计算之间存在较强的相关性,土壤呼吸与土壤健康计算之间存在较强的相关性,土壤呼吸与土壤健康计算之间存在较强的相关性。这些指标可作为制定冬小麦土壤健康氮素建议用量的有用指标。然而,在干旱易发地区,由于对N矿化的高估,HSTNR可能在多年内显著低估了EONR。
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引用次数: 0
Thawing Permafrost as a Nitrogen Fertiliser: Implications for Climate Feedbacks 解冻永久冻土作为氮肥:对气候反馈的影响
Pub Date : 2022-06-03 DOI: 10.3390/nitrogen3020023
E. Burke, S. Chadburn, C. Huntingford
Studies for the northern high latitudes suggest that, in the near term, increased vegetation uptake may offset permafrost carbon losses, but over longer time periods, permafrost carbon decomposition causes a net loss of carbon. Here, we assess the impact of a coupled carbon and nitrogen cycle on the simulations of these carbon fluxes. We present results from JULES-IMOGEN—a global land surface model coupled to an intermediate complexity climate model with vertically resolved soil biogeochemistry. We quantify the impact of nitrogen fertilisation from thawing permafrost on the carbon cycle and compare it with the loss of permafrost carbon. Projections show that the additional fertilisation reduces the high latitude vegetation nitrogen limitation and causes an overall increase in vegetation carbon uptake. This is a few Petagrams of carbon (Pg C) by year 2100, increasing to up to 40 Pg C by year 2300 for the RCP8.5 concentration scenario and adds around 50% to the projected overall increase in vegetation carbon in that region. This nitrogen fertilisation results in a negative (stabilising) feedback on the global mean temperature, which could be equivalent in magnitude to the positive (destabilising) temperature feedback from the loss of permafrost carbon. This balance depends on the future scenario and initial permafrost carbon. JULES-IMOGEN describes one representation of the changes in Arctic carbon and nitrogen cycling in response to climate change. However there are uncertainties in the modelling framework, model parameterisation and missing processes which, when assessed, will provide a more complete picture of the balance between stabilising and destabilising feedbacks.
对北部高纬度地区的研究表明,在短期内,植被吸收的增加可能抵消永久冻土的碳损失,但在较长时间内,永久冻土的碳分解会导致碳的净损失。在这里,我们评估了碳氮耦合循环对这些碳通量模拟的影响。我们介绍了jules - imogen的结果,jules - imogen是一个全球陆地表面模型,与具有垂直分辨率的土壤生物地球化学的中等复杂气候模型耦合。我们量化了永久冻土融化带来的氮肥对碳循环的影响,并将其与永久冻土碳的损失进行了比较。预估表明,额外的施肥减少了高纬度植被氮的限制,并导致植被碳吸收的总体增加。这是到2100年的几个百格碳(Pg C),在RCP8.5浓度情景下,到2300年将增加到40 Pg C,并使该地区预计的植被碳总增长量增加约50%。这种氮肥对全球平均温度产生负反馈(稳定反馈),其量级可能与永久冻土碳损失产生的正反馈(不稳定反馈)相当。这种平衡取决于未来的情景和最初的永久冻土碳。JULES-IMOGEN描述了北极碳和氮循环变化对气候变化的反应。然而,在建模框架、模型参数化和缺失过程中存在不确定性,当评估时,将提供稳定和不稳定反馈之间平衡的更完整图景。
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引用次数: 4
Role of Tree Species, the Herb Layer and Watershed Characteristics in Nitrate Assimilation in a Central Appalachian Hardwood Forest 树种、草本层和流域特征在阿巴拉契亚中部阔叶林硝酸盐同化中的作用
Pub Date : 2022-06-03 DOI: 10.3390/nitrogen3020022
Sian E. Eisenhut, I. Holásková, K. Stephan
Forest plants that can assimilate nitrate may act as nitrate sink and, consequently, reduce nitrate losses from watershed ecosystems through leaching. This study, conducted at the Fernow Experimental Forest in West Virginia, quantified via nitrogen reductase activity (NRA) the nitrate assimilation of two tree species, red maple and sugar maple, and surrounding common herb-layer species at the tissue (foliage, roots) and plot level. NRA measurements were conducted in summer and spring. Furthermore, NRA was quantified under varying levels of soil nitrate availability due to fertilization, different stages in secondary forest succession, and watershed aspect. This study confirmed that NRA of mature maples does not respond to varying levels of soil nitrate availability. However, some herb-layer species’ NRA did increase with nitrogen fertilization, and it may be greater in spring than in summer. Combined with biomass, the herb layer’s NRA at the plot-level (NRAA) comprised 9 to 41% of the total (tree + herb-layer) foliar NRAA during the growing season. This demonstrates that the herb layer contributes to nitrate assimilation disproportionally to its small biomass in the forest and may provide a vernal dam to nitrate loss not only by its early presence but also by increased spring NRA relative to summer.
能够吸收硝酸盐的森林植物可以作为硝酸盐汇,从而通过淋滤减少流域生态系统的硝酸盐损失。本研究在西弗吉尼亚州Fernow试验林进行,通过氮还原酶活性(NRA)定量分析了红枫和糖枫两种树种及其周围常见草本层树种在组织(叶、根)和样地水平上的硝酸盐同化。NRA测量在夏季和春季进行。在不同施肥水平、次生林演替不同阶段和流域格局下,对NRA进行了量化。本研究证实了成熟枫树的NRA不受不同土壤硝态氮有效性的影响。部分草本层植物的NRA随施氮量的增加而增加,且春季高于夏季。结合生物量,草本层在样地水平的NRAA (NRAA)占整个生长季节(树+草本层)叶片NRAA的9 ~ 41%。这表明,草本层对硝酸盐同化的贡献与其在森林中的小生物量不成比例,并且可能通过其早期存在以及相对于夏季增加的春季NRA为硝酸盐损失提供了一个春季屏障。
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引用次数: 4
Increased Arctic NO3− Availability as a Hydrogeomorphic Consequence of Permafrost Degradation and Landscape Drying 北极NO3−可用性的增加是冻土退化和景观干燥的水文地貌后果
Pub Date : 2022-05-21 DOI: 10.3390/nitrogen3020021
C. Arendt, J. M. Heikoop, B. Newman, C. Wilson, H. Wainwright, Jitendra Kumar, Christian G. Andersen, N. Wales, B. Dafflon, J. Cherry, S. Wullschleger
Climate-driven permafrost thaw alters the strongly coupled carbon and nitrogen cycles within the Arctic tundra, influencing the availability of limiting nutrients including nitrate (NO3−). Researchers have identified two primary mechanisms that increase nitrogen and NO3− availability within permafrost soils: (1) the ‘frozen feast’, where previously frozen organic material becomes available as it thaws, and (2) ‘shrubification’, where expansion of nitrogen-fixing shrubs promotes increased soil nitrogen. Through the synthesis of original and previously published observational data, and the application of multiple geospatial approaches, this study investigates and highlights a third mechanism that increases NO3− availability: the hydrogeomorphic evolution of polygonal permafrost landscapes. Permafrost thaw drives changes in microtopography, increasing the drainage of topographic highs, thus increasing oxic conditions that promote NO3− production and accumulation. We extrapolate relationships between NO3− and soil moisture in elevated topographic features within our study area and the broader Alaskan Coastal Plain and investigate potential changes in NO3− availability in response to possible hydrogeomorphic evolution scenarios of permafrost landscapes. These approximations indicate that such changes could increase Arctic tundra NO3− availability by ~250–1000%. Thus, hydrogeomorphic changes that accompany continued permafrost degradation in polygonal permafrost landscapes will substantially increase soil pore water NO3− availability and boost future fertilization and productivity in the Arctic.
气候驱动的永久冻土融化改变了北极冻土带内强耦合的碳和氮循环,影响了包括硝酸盐(NO3−)在内的限制性营养物质的可用性。研究人员已经确定了永久冻土中增加氮和NO3−可用性的两种主要机制:(1)“冰冻盛宴”,以前冻结的有机物质在解冻时变得可用;(2)“灌木化”,固氮灌木的扩张促进了土壤氮的增加。通过综合原始和先前发表的观测数据,以及多种地理空间方法的应用,本研究调查并强调了增加NO3−可用性的第三种机制:多边形永久冻土景观的水文地貌演化。多年冻土融化驱动微地形的变化,增加地形高地的排水,从而增加氧条件,促进NO3−的产生和积累。我们推断了在我们的研究区域和更广泛的阿拉斯加沿海平原的高纬度地形特征中NO3 -和土壤水分之间的关系,并研究了NO3 -有效性的潜在变化,以响应永久冻土景观可能的水文地貌演变情景。这些近似值表明,这种变化可能使北极冻土带NO3−可用性增加~ 250-1000%。因此,在多边形永久冻土景观中,伴随永久冻土持续退化的水文地貌变化将大大增加土壤孔隙水NO3−的可用性,并促进北极未来的施肥和生产力。
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引用次数: 0
Technologies for Biological and Bioelectrochemical Removal of Inorganic Nitrogen from Wastewater: A Review 生物与生物电化学去除废水中无机氮技术研究进展
Pub Date : 2022-05-14 DOI: 10.3390/nitrogen3020020
Diplina Paul, Abhisek Banerjee
Water contamination due to various nitrogenous pollutants generated from wastewater treatment plants is a crucial and ubiquitous environmental problem now-a-days. Nitrogen contaminated water has manifold detrimental effects on human health as well as aquatic life. Consequently, various biological treatment processes are employed to transform the undesirable forms of nitrogen in wastewater to safer ones for subsequent discharge. In this review, an overview of various conventional biological treatment processes (viz. nitrification, denitrification, and anammox) have been presented along with recent novel bioelectrochemical methods (viz. microbial fuel cells and microbial electrolysis cells). Additionally, nitrogen is an indispensable nutrient necessary to produce artificial fertilizers by fixing dinitrogen gas from the atmosphere. Thus, this study also explored the potential capability of various nitrogen recovery processes from wastewater (like microalgae, cyanobacteria, struvite precipitation, stripping, and zeolites) that are used in industries. Further, the trade-offs, challenges posed by these processes have been dwelt on along with other biological processes like CANON, SHARON, OLAND, and others.
由污水处理厂产生的各种含氮污染物引起的水污染是当今普遍存在的重要环境问题。氮污染的水对人类健康和水生生物有多方面的有害影响。因此,采用各种生物处理工艺将废水中不需要的氮形式转化为更安全的氮形式,以供后续排放。在这篇综述中,概述了各种传统的生物处理工艺(即硝化、反硝化和厌氧氨氧化)以及最近的新型生物电化学方法(即微生物燃料电池和微生物电解电池)。此外,氮是一种不可缺少的营养物质,通过固定大气中的二氮气体来生产人工肥料。因此,本研究还探索了工业中使用的各种废水氮回收工艺(如微藻、蓝藻、鸟粪石沉淀、剥离和沸石)的潜在能力。此外,这些过程带来的权衡和挑战已经与其他生物过程(如CANON, SHARON, OLAND等)一起进行了讨论。
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引用次数: 0
Effects of Nitrogen Fertilization on Weed Flora and Productivity of Soybean [Glycine max (L.) Merr.] Crop 施氮对大豆杂草区系及产量的影响[j]稳定。]作物
Pub Date : 2022-05-10 DOI: 10.3390/nitrogen3020019
I. Kakabouki, Antonios Mavroeidis, Varvara Kouneli, Stella Karydogianni, Antigolena Folina, V. Triantafyllidis, Aspasia Efthimiadou, I. Roussis, A. Zotos, C. Kosma, Nikolaos Katsenios
The literature suggests that nitrogen (N) fertilization increases yield in soybean. This study aimed to investigate the effects of N fertilization on: (i) The performance of soybean, and (ii) the weed flora. A two-year field experiment was carried out in Agrinio, Western Greece. The experiment was set up in a randomized complete block design, with four organic fertilizer treatments and six replications. The four treatments included 0 kg N ha−1 (N0/unfertilized control) and the application of 80 kg N ha−1, 100 kg N ha−1, and 120 kg N ha−1. The application of 120 N kg ha−1 resulted in the most notable increment of plant height (22.6–24%), biomass (10–13%), LAI values (14–17%), and yield (10–12%) compared to the N0. Compared to the N0, total weed biomass was increased by 26–32%, 34–49%, and 55–57% in N80, N100, and N120, respectively. The values of the H (Shannon), Dmg (Margalef), and J (Pielou) indices were unaffected by the fertilization, hence they did not affect weed biodiversity. CRI (crop resistance index), on the contrary, was negatively affected by N fertilization and was significantly reduced. Overall, our results indicate that the application of 80 kg N ha−1 is more efficient, can effectively improve the soybean performance, and enhance its yield.
文献表明,施氮可提高大豆产量。本研究旨在探讨施氮对大豆生产性能和杂草区系的影响。在希腊西部的阿格里尼奥进行了为期两年的实地试验。试验采用完全随机区组设计,4个有机肥处理,6个重复。4个处理分别为0 kg N ha - 1 (N0/未施肥对照)、80 kg N ha - 1、100 kg N ha - 1和120 kg N ha - 1。与氮肥处理相比,施用120 N kg ha−1后,株高(22.6-24%)、生物量(10-13%)、叶面积指数(14-17%)和产量(10-12%)的增加最为显著。与N0相比,N80、N100和N120处理的杂草总生物量分别增加了26-32%、34-49%和55-57%。H (Shannon)、Dmg (Margalef)和J (Pielou)指数不受施肥影响,不影响杂草多样性。CRI(作物抗性指数)则受氮肥的负向影响,显著降低。综上所述,施用80 kg N ha - 1处理效率更高,可有效改善大豆生产性能,提高产量。
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引用次数: 3
Simulating Increased Permafrost Peatland Plant Productivity in Response to Belowground Fertilisation Using the JULES Land Surface Model 利用JULES陆地表面模型模拟冻土泥炭地植物生产力对地下施肥的响应
Pub Date : 2022-05-05 DOI: 10.3390/nitrogen3020018
Rayanne Vitali, S. Chadburn, F. Keuper, A. Harper, E. Burke
Several experimental studies have shown that climate-warming-induced permafrost thaw releases previously unavailable nitrogen which can lower nitrogen limitation, increase plant productivity, and counteract some of the carbon released from thawing permafrost. The net effect of this belowground fertilisation effect remains debated and is yet to be included in Earth System models. Here, we included the impact of thaw-related nitrogen fertilisation on vegetation in the Joint UK Land Environment Simulator (JULES) land surface model for the first time. We evaluated its ability to replicate a three-year belowground fertilisation experiment in which JULES was generally able to simulate belowground fertilisation in accordance with the observations. We also ran simulations under future climate to investigate how belowground nitrogen fertilisation affects the carbon cycle. These simulations indicate an increase in plant-available inorganic nitrogen at the thaw front by the end of the century with only the productivity of deep-rooting plants increasing in response. This suggests that deep-rooting species will have a competitive advantage under future climate warming. Our results also illustrate the capacity to simulate belowground nitrogen fertilisation at the thaw front in a global land surface model, leading towards a more complete representation of coupled carbon and nitrogen dynamics in the northern high latitudes.
一些实验研究表明,气候变暖引起的永久冻土解冻释放出以前无法获得的氮,这可以降低氮的限制,提高植物生产力,并抵消永久冻土融化释放的一些碳。这种地下施肥效应的净效应仍有争议,而且尚未包括在地球系统模型中。在这里,我们首次在联合英国土地环境模拟器(JULES)陆地表面模型中纳入了与融化相关的氮肥对植被的影响。我们评估了它复制一个为期三年的地下施肥实验的能力,在这个实验中,JULES基本上能够根据观察结果模拟地下施肥。我们还在未来气候下进行了模拟,以调查地下氮肥如何影响碳循环。这些模拟表明,到本世纪末,融化前沿的植物可利用无机氮增加,只有深根植物的生产力相应增加。这表明,在未来气候变暖的情况下,深根物种将具有竞争优势。我们的研究结果还说明了在全球陆地表面模型中模拟解冻前沿地下氮肥的能力,从而更完整地描述了北部高纬度地区碳氮耦合动力学。
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引用次数: 2
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Nitrogen
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