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Advancements in CIGS/ZnS heterojunction solar cells: Experimental and numerical analysis CIGS/ZnS 异质结太阳能电池的进展:实验和数值分析
IF 3.1 3区 物理与天体物理 Q2 Engineering Pub Date : 2024-08-23 DOI: 10.1016/j.ijleo.2024.172008
Taoufik Chargui , Fatima Lmai , Khalid Rahmani

This study presents a comprehensive experimental investigation conducted on a CIGS-based solar cell incorporating a ZnS buffer layer. The primary objective was to determine key parameters of the CIGS/ZnS heterojunction, including parasitic resistances (Rs and Rsh), ideality factor (n), and barrier height (ϕB), using experimental current-voltage (I-V) characteristics over a temperature range of 150 K to 300 K under dark conditions. The heterojunction was modelled using a single-diode electrical circuit that accounted for parasitic resistances. Two methods were employed for parameter determination: direct analysis of the (I-V) curves and Cheung's method. Additionally, the charge transport mechanism within the heterojunction is investigated and discussed. Furthermore, the performance of the Al:ZnO/i:ZnO/ZnS/CIGS/Mo solar cell was assessed using the SCAPS-1D simulator, demonstrating an initial solar energy conversion efficiency of 15.01 %. To enhance this efficiency, a hole transport layer (HTL) was integrated between the back electrode and the absorber layer. Extensive studies were conducted to optimize the thickness and doping density of the HTL, including a comparative analysis of different materials used as HTLs. These optimizations resulted in a significant increase in conversion efficiency, reaching up to 28.68 %.

本研究介绍了对含有 ZnS 缓冲层的铜铟镓硒太阳能电池进行的全面实验研究。主要目的是利用黑暗条件下 150 K 至 300 K 温度范围内的实验电流-电压(I-V)特性,确定 CIGS/ZnS 异质结的关键参数,包括寄生电阻(Rs 和 Rsh)、ideality 因子(n)和势垒高度(jB)。异质结采用单二极管电路建模,其中考虑了寄生电阻。参数确定采用了两种方法:直接分析 (I-V) 曲线和张氏方法。此外,还对异质结内的电荷传输机制进行了研究和讨论。此外,还使用 SCAPS-1D 模拟器评估了 Al:ZnO/i:ZnO/ZnS/CIGS/Mo 太阳能电池的性能,结果显示其初始太阳能转换效率为 15.01%。为了提高这一效率,在背电极和吸收层之间集成了空穴传输层(HTL)。对 HTL 的厚度和掺杂密度进行了广泛的优化研究,包括对用作 HTL 的不同材料进行比较分析。这些优化措施显著提高了转换效率,最高可达 28.68%。
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引用次数: 0
Structural, electronic, optical, and thermoelectric features of Rb2XSbX’6 (X= Ag, Cu; X’= Cl, Br): Ab-initio calculations Rb2XSbX'6 (X= Ag, Cu; X'= Cl, Br) 的结构、电子、光学和热电特性:Ab-initio 计算
IF 3.1 3区 物理与天体物理 Q2 Engineering Pub Date : 2024-08-23 DOI: 10.1016/j.ijleo.2024.172009
M. Bouzidi , M. Ziati , K. Belasfar , A. El Bachiri , M.M. El Hammoumi , A. Rmili , A. Louardi , A. El Kenz , H. Ez-Zahraouy , A. Benyoussef

This study investigates the electronic, optical, and thermoelectric properties of lead-free double halide perovskite materials, Rb2XSbX'6, through first-principles calculations employing Density Functional Theory (DFT) and the Wien2k code, complemented by Boltzmann transport theory. By substituting X with Ag or Cu and X’ with Cl or Br in Rb2XSbX’6, we uncover interesting properties. Rb2AgSbBr6, Rb2AgSbCl6, Rb2CuSbCl6, and Rb2CuSbBr6 exhibit low indirect band gaps of 1.18 eV, 2.17 eV, 1.22 eV, and 0.87 eV, respectively, alongside high absorption in the visible region. The studied compounds sustained a high level of structural and thermodynamic stability, which was confirmed by their high bulk modulus and negative formation energy. Furthermore, extensive values were observed for the figure of merit in the thermoelectric study. Given the strong agreement with previous research, these findings position the investigated materials as promising candidates for visible-light solar cell device applications.

本研究采用密度泛函理论(DFT)和 Wien2k 代码,辅以玻尔兹曼输运理论,通过第一原理计算研究了无铅双卤化物包晶材料 Rb2XSbX'6 的电子、光学和热电特性。通过将 Rb2XSbX'6 中的 X 替换为 Ag 或 Cu,X'替换为 Cl 或 Br,我们发现了一些有趣的性质。Rb2AgSbBr6、Rb2AgSbCl6、Rb2CuSbCl6 和 Rb2CuSbBr6 分别显示出 1.18 eV、2.17 eV、1.22 eV 和 0.87 eV 的低间接带隙,以及在可见光区域的高吸收。所研究的化合物具有很高的结构稳定性和热力学稳定性,这可以从它们的高体积模量和负形成能得到证实。此外,在热电研究中还观察到了广泛的优点值。这些研究结果与之前的研究结果非常吻合,因此将所研究的材料定位为有望应用于可见光太阳能电池装置的候选材料。
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引用次数: 0
Prediction of multi-layer metasurface design using conditional deep convolutional generative adversarial networks 利用条件深度卷积生成对抗网络预测多层元表面设计
IF 3.1 3区 物理与天体物理 Q2 Engineering Pub Date : 2024-08-22 DOI: 10.1016/j.ijleo.2024.172005
Ali Nezaratizadeh , Seyed Mohammad Hashemi , Mohammad Bod

Designing metasurfaces is a challenging task. Traditional methodologies, which primarily depend on iterative procedures, are both time-intensive and require specialized expertise. The proposed algorithm uses conditional deep convolutional generative adversarial networks (cDCGAN) to design metasurfaces. This method instantly create a 2D image of a multi-layer metasurface using the scattering parameter S11 as the input vector. The algorithm significantly reduces the size of the training dataset by applying pre-training and post-generating steps. The pre-training step involves aliasing and modifying images using a limited color palette. The post-generating step consists of separating the color channels, converting the pixels to vector based images, and fine-tuning the borders. The algorithm is evaluated for three metasurfaces that have unique features compared to the training dataset samples: a single-band metasurface unitcell, a dual-band metasurface unitcell, and a partially trained sample improved by magnetic field analysis. The results show that the proposed algorithm can accurately predict the images of these metasurface unitcells, demonstrating its potential for fast and efficient metasurface design.

设计元曲面是一项具有挑战性的任务。传统方法主要依赖于迭代程序,既耗时又需要专业知识。本文提出的算法使用条件深度卷积生成对抗网络(cDCGAN)来设计元曲面。该方法使用散射参数 S11 作为输入向量,即时创建多层元曲面的二维图像。该算法通过应用预训练和后生成步骤,大大减少了训练数据集的大小。预训练步骤包括使用有限的调色板对图像进行别离和修改。后生成步骤包括分离颜色通道、将像素转换为基于向量的图像以及微调边界。该算法针对三个元表面进行了评估,这些元表面与训练数据集样本相比具有独特的特征:单波段元表面单元单元、双波段元表面单元单元以及通过磁场分析改进的部分训练样本。结果表明,所提出的算法可以准确预测这些元表面单元单元的图像,证明了其在快速高效的元表面设计方面的潜力。
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引用次数: 0
High Resolution Terahertz (THz) Imaging 高分辨率太赫兹(THz)成像
IF 3.1 3区 物理与天体物理 Q2 Engineering Pub Date : 2024-08-22 DOI: 10.1016/j.ijleo.2024.172002
Uzair Aalam , Khushboo Singh , Aparajita Bandyopadhyay , Amartya Sengupta

Terahertz (THz) imaging is essential for non-contact and non-destructive testing due to its ability to penetrate numerous materials. Typically, the sample is raster-scanned through the beam waist of a confocal optical setup to generate an image in a single-pixel detection scheme. However, the spatial resolution achieved using such imaging configurations remains no less than millimeters, restricting the application of THz imaging. Here in this work, a simple hollow-core metal waveguide (HCMWG) based terahertz imaging setup has been designed and implemented in transmission configuration to record THz hyperspectral images of a sample. The sample is kept in the near-field range of the HCMWG to exploit the THz electric field confinement of the guided mode toward attaining high-resolution imaging. The THz images are acquired by raster scanning the sample in front of the HCMWG output aperture using a single-pixel detection setup. Additionally, spectroscopic sensing using the same setup has been shown by extracting the absorption spectrum of a chemical compound. Further, a plant leaf is used as a sample to demonstrate the applicability of this technique, where the highly resolved transmitted THz image is acquired using the proposed setup. This image is compared with the image recorded using a conventional confocal lens-based THz optical setup. The results show that the technique can resolve subwavelength features (approx. 0.8λ) of the sample under study while preserving spectroscopic information.

太赫兹(THz)成像能够穿透多种材料,因此对于非接触和无损检测至关重要。通常情况下,通过共焦光学装置的束腰对样品进行光栅扫描,以单像素检测方案生成图像。然而,使用这种成像配置实现的空间分辨率仍然不低于毫米,限制了太赫兹成像的应用。在这项工作中,我们设计并实现了一种基于传输配置的简单空芯金属波导(HCMWG)太赫兹成像装置,用于记录样品的太赫兹高光谱图像。样品保持在 HCMWG 的近场范围内,以利用导波模式的太赫兹电场约束实现高分辨率成像。太赫兹图像是通过使用单像素检测装置在 HCMWG 输出光圈前对样品进行光栅扫描获得的。此外,通过提取化合物的吸收光谱,使用相同的装置实现了光谱传感。此外,还使用植物叶片作为样本来演示该技术的适用性,并使用所建议的装置获取高分辨率透射太赫兹图像。该图像与使用基于共焦透镜的传统太赫兹光学装置记录的图像进行了比较。结果表明,该技术可以解析所研究样本的亚波长特征(约 0.8λ),同时保留光谱信息。
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引用次数: 0
Impact of dispersion-shifted fiber on optical communications link through orthogonal channels 色散位移光纤对正交信道光通信链路的影响
IF 3.1 3区 物理与天体物理 Q2 Engineering Pub Date : 2024-08-22 DOI: 10.1016/j.ijleo.2024.172004
Haider J. Abd , Heyam A. Marzog , Muthana Al-Amidie , Riyadh Mansoor , Mustafa R. Ismael , Raad Z. Homod , Hayder I. Mohammed

Dispersion-Shifted Fiber (DSF) is essential for reducing chromatic dispersion in high-speed optical communication systems. This study investigates the influence of Four Wave Mixing (FWM) on the quality of signals in orthogonal channels. We examine the advantages of DSF technology and analyze the impact of modulation formats such as On-Off Keying with Return-to-Zero (OOK-RZ) and Duo Binary Modulation class-1 (DBM-1) on transmission performance at different distances. This research assesses the efficacy of orthogonal channels in mitigating four-wave mixing (FWM) effects and improving the overall performance of eight-channel systems at distances of 100 km and 200 km through computer simulations. The results of our study show notable enhancements, namely in optimizing the Q-factor (a metric for signal quality) and reducing bit error rates when employing orthogonal channels compared to previous work. By integrating orthogonal channels with OOK-RZ modulation, we achieved higher performance and reduced nonlinear impairments in a simulated eight-channel system with 50 GHz spacing and 80 Gb/s data rates. This effect was particularly pronounced at high input power levels. At an input power of 20 dBm and a distance of 200 km, this particular combination yielded a maximum Q-factor of 27.25 and a minimum FWM power of −54 dBm. In comparison, under the same conditions, the use of OOK-RZ alone resulted in an FWM power of −24 dBm and a Q-factor of only 1.63. This research provides vital insights into enhancing the efficiency and dependability of optical communication systems, hence facilitating breakthroughs in high-speed data transfer and network scalability.

色散位移光纤(DSF)对于降低高速光通信系统中的色散至关重要。本研究探讨了四波混频(FWM)对正交信道中信号质量的影响。我们研究了 DSF 技术的优势,并分析了开关键控归零(OOK-RZ)和双二进制调制 1 级(DBM-1)等调制格式对不同距离传输性能的影响。这项研究通过计算机模拟,评估了正交信道在减轻四波混合(FWM)效应和提高八信道系统在 100 千米和 200 千米距离上的整体性能方面的功效。我们的研究结果表明,与以前的研究相比,采用正交信道后,在优化 Q 因子(信号质量指标)和降低误码率方面都有显著提高。通过将正交信道与 OOK-RZ 调制相结合,我们在一个间距为 50 GHz、数据速率为 80 Gb/s 的模拟八信道系统中实现了更高的性能,并减少了非线性损伤。这种效果在高输入功率时尤为明显。在输入功率为 20 dBm、距离为 200 千米的条件下,这种特定组合产生的最大 Q 因子为 27.25,最小 FWM 功率为 -54 dBm。相比之下,在相同条件下,单独使用 OOK-RZ 的全频调制功率为 -24 dBm,Q 因子仅为 1.63。这项研究为提高光通信系统的效率和可靠性提供了重要见解,从而促进了高速数据传输和网络可扩展性方面的突破。
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引用次数: 0
Synthesis of tungsten-doped zinc oxide nanoparticles using Aloe vera extracts for perovskite solar cells 利用芦荟提取物合成掺钨氧化锌纳米粒子,用于过氧化物太阳能电池
IF 3.1 3区 物理与天体物理 Q2 Engineering Pub Date : 2024-08-22 DOI: 10.1016/j.ijleo.2024.172006
M. Shahinuzzaman , Mohammad Aminul Islam , Sanjida Afroz , Mosharof Hossain , M.S. Jamal , Abdulaziz M. Alanazi , Shahiduzzaman , Md. Akhtaruzzaman

A green, plant extract-mediated synthesis technique utilizing the Aloe vera stem extract with Zinc acetate (Zn(CH₃CO₂)₂·2H₂O), and Tungsten chloride (WCl2) salt has been employed to grow Zinc Oxide (ZnO) and tungsten doped ZnO (W-ZnO) nanoparticles (NPs). The formation of NPs was confirmed by FESEM with EDX and TEM analysis. The synthesized NPs have been employed for fabricating ZnO and W-ZnO thin films and the electro-optical properties of the films have also been investigated in detail. The thin films have obtained via spin coating and followed by annealing at 350 °C for 3 h in an ambiance atmosphere. The films showed smooth surfaces with a bandgap of 3.20 and 3.25 eV for ZnO and W-ZnO respectively. Finally, a novel structure inverted perovskite solar cells (PSCs) has been numerically analyzed utilizing the films as an electron transporting layer (ETL) for realizing the device performance. The highest PCE of the device for synthesized ZnO and W-ZnO has been found to be 21.16 % and 23.61 %, respectively. All of the findings show that the W-ZnO film is more suitable for the fabrication of PSCs than the ZnO film. In a nutshell, the synthesis of W-ZnO NPs employing green and eco-friendly methods, mediated by Aloe vera extract as the reducing agent, offers in this study a novel approach to enhancing solar cell efficiency with the simple spin coating fabrication technique.

利用芦荟茎提取物与醋酸锌(Zn(CH₃CO₂)₂-2H₂O)和氯化钨(WCl2)盐的绿色植物提取物介导合成技术,生长出氧化锌(ZnO)和掺杂钨的氧化锌(W-ZnO)纳米粒子(NPs)。通过 FESEM 以及 EDX 和 TEM 分析确认了 NPs 的形成。合成的 NPs 被用于制造 ZnO 和 W-ZnO 薄膜,薄膜的电光特性也得到了详细研究。薄膜通过旋涂获得,然后在 350 °C 的环境气氛中退火 3 小时。薄膜表面光滑,ZnO 和 W-ZnO 的带隙分别为 3.20 和 3.25 eV。最后,利用这些薄膜作为电子传输层(ETL),对一种新型结构的倒置型过氧化物太阳能电池(PSCs)进行了数值分析,以实现其器件性能。结果发现,合成 ZnO 和 W-ZnO 器件的最高 PCE 分别为 21.16 % 和 23.61 %。所有研究结果都表明,W-ZnO 薄膜比 ZnO 薄膜更适合用于制造 PSC。总之,本研究以芦荟提取物为还原剂,采用绿色环保的方法合成了 W-ZnO NPs,为利用简单的旋涂制造技术提高太阳能电池效率提供了一种新方法。
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引用次数: 0
Dual-frequency terahertz amplitude modulator based on the coupling effect of cross-shaped structure and U-shaped metal patches 基于十字形结构和 U 形金属贴片耦合效应的双频太赫兹振幅调制器
IF 3.1 3区 物理与天体物理 Q2 Engineering Pub Date : 2024-08-20 DOI: 10.1016/j.ijleo.2024.172003
Zhen Zhang , Linji Yang , Huan Zhou , Kuan Ye , Sen Qiu , Xin Chen , Yong Ma , Renpu Li

This letter presents a dual-frequency terahertz amplitude modulator based on a cross-shaped structure and U-shaped metal patches. Its structural unit is a typical metal-substrate structure. The top metal consists of a cross-shaped structure and U-shaped metal patches, and the bottom substrate layer is made of quartz. Amplitude modulation is achieved by adjusting the temperature of the vanadium dioxide (VO2) patches. The modulation depth can be approximately 75 %. The mechanism of the resonance frequency is explained by the equivalent circuit model. The proposed structure shows good amplitude modulation capability at different incidence and azimuth angles by changing the location of the VO2 patches. The dual-frequency terahertz amplitude modulator can be used in terahertz communication, imaging, etc.

本文介绍了一种基于十字形结构和 U 形金属贴片的双频太赫兹振幅调制器。其结构单元为典型的金属-基底结构。顶部金属由十字形结构和 U 形金属贴片组成,底部基底层由石英制成。振幅调制是通过调节二氧化钒(VO2)贴片的温度来实现的。调制深度约为 75%。等效电路模型解释了共振频率的机理。通过改变二氧化钒贴片的位置,拟议结构在不同入射角和方位角下显示出良好的振幅调制能力。这种双频太赫兹振幅调制器可用于太赫兹通信、成像等领域。
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引用次数: 0
WITHDRAWN: Perfect asymmetric transmission for linear polarization in background reflection-free bilayer dielectric metasurfaces 撤回:无背景反射双层介电元表面中线性偏振的完美非对称传输
IF 3.1 3区 物理与天体物理 Q2 Engineering Pub Date : 2024-08-13 DOI: 10.1016/j.ijleo.2024.171997
Kwang-Hyon Kim, Ui-Hyon An
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引用次数: 0
Improved pH performance of cresol red radiochromic dye for spectroscopic investigations 改善甲酚红放射变色染料的 pH 值性能,用于光谱研究
IF 3.1 3区 物理与天体物理 Q2 Engineering Pub Date : 2024-08-13 DOI: 10.1016/j.ijleo.2024.172000
Hafiz Muhammad Asif Javed , Taqmeem Hussain , Kanwal Younas , Muhammad Fakhar-e-Alam , Tariq Munir , Muhammad Kashif , Safwat A. Mahmoud , Mouna Jeridi

Optical properties of a synthetic dye cresol red (CR) were investigated at its absorption band maxima (λmax) using double beam scanning UV/VIS spectrophotometer for the sample solutions having initial optimized dye-concentration. Urbach Edge method was utilized for the investigations of absorption edge (AE= 2.35 eV) while Mott and Davis model was utilized for the investigations of band gap energy for direct (Eg,direct= 2.45 eV) and indirect (Eg,indirect= 2.23 eV) allowed transitions. The spectrophotometric-evaluations assisted most-sensitive working pH of sample solutions was optimized for a long spectrum of pH values from 1 to 12 for further investigations. Some spectrophotometric and comercial parameters e.g., molar extinction coefficient ε, stability, reproducibility and fading were figured out. The response efficacy was also observed to enhanc the sensitivity and stability of the CR solutions by incorporating a selected amount (by %vol) of a polar additive ethanol. The invariant aborbance related isosbestic wavelength for both acidic and alkaline samples remained unaffected from pH and firmly stood at 475 nm. The improved and reasonable pH values were found to be pH 4 and pH 9 and hence were opted for CR solutions and may further be applicable to the radiation-induced degradation phenomenon based on radiolytic bleaching.

使用双光束扫描紫外/可见分光光度计研究了具有初始优化染料浓度的样品溶液中合成染料甲酚红(CR)在其吸收带最大值(λmax)处的光学特性。乌尔巴赫边缘法用于研究吸收边缘(AE= 2.35 eV),莫特和戴维斯模型用于研究直接(Eg,direct= 2.45 eV)和间接(Eg,indirect= 2.23 eV)允许跃迁的带隙能。分光光度法评估辅助最灵敏的样品溶液工作 pH 值,优化了 pH 值从 1 到 12 的长光谱,以便进一步研究。一些分光光度和商业参数,如摩尔消光系数ε、稳定性、可重复性和衰减也得到了确定。此外,还观察到通过加入一定量(体积百分比)的极性添加剂乙醇,CR 溶液的灵敏度和稳定性得到了提高。酸性和碱性样品的不变吸光度相关等距波长不受 pH 值的影响,始终保持在 475 nm。经改进的合理 pH 值为 pH 4 和 pH 9,因此被选为 CR 溶液,并可进一步用于基于辐射漂白的辐射诱导降解现象。
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引用次数: 0
Full-field stress-strain analysis of octagonal shape PMMA using reflection photoelasticity 利用反射光弹性对八角形 PMMA 进行全场应力应变分析
IF 3.1 3区 物理与天体物理 Q2 Engineering Pub Date : 2024-08-13 DOI: 10.1016/j.ijleo.2024.172001
Yongyut Manjit , Netnawee Um-In , Apichart Limpichaipanit , Athipong Ngamjarurojana

This research involves stress-strain analysis in poly(methyl methacrylate) (PMMA) octagonal shape compressed by hydraulic system. The observation of uniaxially stressed samples was carried out using reflection photoelasticity technique. The results of fringe order number and principal stress angle were used to determine stress and strain distribution in the samples by shear difference method. It was found that high stress-strain region was close to the contact point where compressive force was applied but it was zero at the edge of the samples. The area of high strain region increased as the magnitude of force was increased but it decreased as the dimension of octagonal shape was increased.

本研究涉及通过液压系统压缩八角形聚甲基丙烯酸甲酯(PMMA)的应力-应变分析。利用反射光弹性技术对单轴受压样品进行了观察。利用条纹阶数和主应力角的结果,通过剪切差法确定样品中的应力和应变分布。结果发现,高应力应变区域靠近施加压缩力的接触点,但在样品边缘则为零。高应变区的面积随着力的增大而增大,但随着八角形尺寸的增大而减小。
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引用次数: 0
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Optik
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