Pub Date : 2022-02-01DOI: 10.1177/20412479221107486
Afaf A Abdel Hakiem, Yasser K. Abdel Moneam, H. M. Said, Magdy MH Senna
A series of polymer blends based on plasticized starch (PLST), poly(vinyl alcohol), alginic acid (AG), and chitosan (CS) were prepared by solution casting. The different blends were exposed to electron beam irradiation to different doses to form hydrogels. The blends before and after electron beam irradiation were characterized in terms of gel fraction (%), swelling in water (%), FTIR spectroscopic analysis, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and rheological measurements. As a practical application in the field agriculture, the hydrogels were used as growth promotion of corn plants. The results showed that the gel fraction was increases by increasing the ratio of PVA in the blends and was decreased by the addition of AG or CS due to the occurrence of degradation. On the other hand, opposite results was found in swelling in water. The corn plant growth indicated an improvement in corn plant height in presence of CS or AG polymers in starch (PLST), poly(vinyl alcohol) blends also, more improvement in corn plant heights in case of blends modified with MgSO4.
{"title":"Radiation induced biodegradable polymer blends for growth promotion of corn plants","authors":"Afaf A Abdel Hakiem, Yasser K. Abdel Moneam, H. M. Said, Magdy MH Senna","doi":"10.1177/20412479221107486","DOIUrl":"https://doi.org/10.1177/20412479221107486","url":null,"abstract":"A series of polymer blends based on plasticized starch (PLST), poly(vinyl alcohol), alginic acid (AG), and chitosan (CS) were prepared by solution casting. The different blends were exposed to electron beam irradiation to different doses to form hydrogels. The blends before and after electron beam irradiation were characterized in terms of gel fraction (%), swelling in water (%), FTIR spectroscopic analysis, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and rheological measurements. As a practical application in the field agriculture, the hydrogels were used as growth promotion of corn plants. The results showed that the gel fraction was increases by increasing the ratio of PVA in the blends and was decreased by the addition of AG or CS due to the occurrence of degradation. On the other hand, opposite results was found in swelling in water. The corn plant growth indicated an improvement in corn plant height in presence of CS or AG polymers in starch (PLST), poly(vinyl alcohol) blends also, more improvement in corn plant heights in case of blends modified with MgSO4.","PeriodicalId":20353,"journal":{"name":"Polymers from Renewable Resources","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47421111","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-08-24DOI: 10.1177/20412479221109912
T. Gumede, K. Shingange, P. Mbule, B. Motloung
Biodegradable polymers are gaining attention for applications in drug delivery, tissue engineering, and wound management. Methods for enhancing their potential in these applications include blending biodegradable aliphatic polyester with other biodegradable aliphatic polyester and/or blending aliphatic polyesters with aromatic polyesters to form blends with unique properties. Herein, we report on the effect of a non-biodegradable aromatic polycarbonate (PC) on the physical, mechanical, and thermal properties of biodegradable aliphatic polybutylene succinate (PBS). The PBS/PC blends contained 3, 13, and 27 wt% PC and were prepared by melt extrusion. The FTIR results revealed apparent compatibility between the two polymers. Even though the blends are compatible, the extent of miscibility depends on thermodynamics terms such as enthalpy, entropy, and Gibbs free energy. According to the SEM micrographs, adding 3 wt% PC resulted in a miscible polymer blend. Above this content, phase dispersion was observed. XRD results revealed peak shifts to higher angles and new peaks forming between 25 and 30°. This is related to the interaction between the components in the blends. The crystallinity was also improved at 3 wt% PC and this is consistent with the DSC results. TGA analysis indicated no improvement in the thermal stability of the blends. DMA revealed that at low PC content (3 wt%), there is a marked improvement in the elastic modulus. This study will benefit the field of Polymer Science because if one wants to prepare PBS/PC they will know that they perform optimally at low PC content.
{"title":"Miscibility effect of biodegradable aliphatic poly(butylene succinate)/aromatic polycarbonate blends","authors":"T. Gumede, K. Shingange, P. Mbule, B. Motloung","doi":"10.1177/20412479221109912","DOIUrl":"https://doi.org/10.1177/20412479221109912","url":null,"abstract":"Biodegradable polymers are gaining attention for applications in drug delivery, tissue engineering, and wound management. Methods for enhancing their potential in these applications include blending biodegradable aliphatic polyester with other biodegradable aliphatic polyester and/or blending aliphatic polyesters with aromatic polyesters to form blends with unique properties. Herein, we report on the effect of a non-biodegradable aromatic polycarbonate (PC) on the physical, mechanical, and thermal properties of biodegradable aliphatic polybutylene succinate (PBS). The PBS/PC blends contained 3, 13, and 27 wt% PC and were prepared by melt extrusion. The FTIR results revealed apparent compatibility between the two polymers. Even though the blends are compatible, the extent of miscibility depends on thermodynamics terms such as enthalpy, entropy, and Gibbs free energy. According to the SEM micrographs, adding 3 wt% PC resulted in a miscible polymer blend. Above this content, phase dispersion was observed. XRD results revealed peak shifts to higher angles and new peaks forming between 25 and 30°. This is related to the interaction between the components in the blends. The crystallinity was also improved at 3 wt% PC and this is consistent with the DSC results. TGA analysis indicated no improvement in the thermal stability of the blends. DMA revealed that at low PC content (3 wt%), there is a marked improvement in the elastic modulus. This study will benefit the field of Polymer Science because if one wants to prepare PBS/PC they will know that they perform optimally at low PC content.","PeriodicalId":20353,"journal":{"name":"Polymers from Renewable Resources","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45983862","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-08-01DOI: 10.1177/20412479211008761
M. Usman, I. Momohjimoh, A. Usman
Natural fibers are becoming the right candidate material as a substitute for glass fibers in the reinforcement of plastic polymers for various applications. The ease of their processing with minimal energy consumption and the quest to produce biodegradable plastics with lightweight has given natural fibers comparative advantages over synthetic fibers. In this study, groundnut shell powder (GSP) in different forms (untreated, sodium hydroxide treated and ash) were characterized using X-ray diffraction (XRD), Fourier transform infrared (FTIR), X-ray fluorescence (XRF), Nuclear magnetic resonance (NMR), Differential scanning calorimetry (DSC) and Scanning electron microscopy (SEM) to evaluate their possible utilization as reinforcement in polymers. GSP was treated with sodium hydroxide for 5 hrs and dried in vacuum for 24 hrs to obtain treated GSP while ash GSP was formed by heating GSP in the furnace at 600 °C for about 3 hrs. The results reveal that sodium hydroxide treatment was very effective in the breaking down of the hydrogen bond with a consequent reduction in the hydrophilicity of the GSP. This would promote GSP bonding with the hydrophobic polymer matrix in the development of natural fiber reinforced plastic polymer composite materials. Ash GSP was found to have the highest crystallinity among the three forms of GSP based on XRD results. Therefore, the result achieved in this work confirmed that treated and ash GSP fibers are good reinforcement material in the production of polymer composites, with the actual choice depending on end-use property requirements of the composite.
{"title":"Characterization of groundnut shell powder as a potential reinforcement for biocomposites","authors":"M. Usman, I. Momohjimoh, A. Usman","doi":"10.1177/20412479211008761","DOIUrl":"https://doi.org/10.1177/20412479211008761","url":null,"abstract":"Natural fibers are becoming the right candidate material as a substitute for glass fibers in the reinforcement of plastic polymers for various applications. The ease of their processing with minimal energy consumption and the quest to produce biodegradable plastics with lightweight has given natural fibers comparative advantages over synthetic fibers. In this study, groundnut shell powder (GSP) in different forms (untreated, sodium hydroxide treated and ash) were characterized using X-ray diffraction (XRD), Fourier transform infrared (FTIR), X-ray fluorescence (XRF), Nuclear magnetic resonance (NMR), Differential scanning calorimetry (DSC) and Scanning electron microscopy (SEM) to evaluate their possible utilization as reinforcement in polymers. GSP was treated with sodium hydroxide for 5 hrs and dried in vacuum for 24 hrs to obtain treated GSP while ash GSP was formed by heating GSP in the furnace at 600 °C for about 3 hrs. The results reveal that sodium hydroxide treatment was very effective in the breaking down of the hydrogen bond with a consequent reduction in the hydrophilicity of the GSP. This would promote GSP bonding with the hydrophobic polymer matrix in the development of natural fiber reinforced plastic polymer composite materials. Ash GSP was found to have the highest crystallinity among the three forms of GSP based on XRD results. Therefore, the result achieved in this work confirmed that treated and ash GSP fibers are good reinforcement material in the production of polymer composites, with the actual choice depending on end-use property requirements of the composite.","PeriodicalId":20353,"journal":{"name":"Polymers from Renewable Resources","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45716950","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-04-19DOI: 10.1177/20412479211008746
T. McGauran, N. Dunne, B. Smyth, E. Cunningham, M. Harris
With oil supplies, needed for plastic production, decreasing dramatically, there is a clear driver for alterative polymers from sustainable resources. Poultry feathers, containing ∼90% keratin, are one source of natural polymer with huge potential for biopolymer production. However, the presence of crosslinks, known as disulphide bonds, hinders processability. This paper reviews techniques to enable breakage of disulphide bonds through use of reduction agents (sodium sulphite and sodium sulphate) and hydrolysis. Samples were analysed using FTIR and DSC to quantify achievable bond breakage, effect on thermal properties and changes in protein concentration. A review on the effect of particle size on disulphide bond breakage was also conducted, along with quantifying the reformation of bonds post-processing. Finally, a bicinchoninic acid (BCA) protein assay was used to quantify changes to soluble protein content, key to predicting if biopolymer formation can occur. The results showed a final disulphide bond breakage of between 48% and 67% was achievable using these techniques. It was also shown that disulphide bond content exhibited up to 60% bond reformation post treatment. These reductions in disulphide bonds increased the thermoplastic nature and apparent protein content. Despite achieving the highest bond breakage percentage, hydrolysis caused degradation of useful proteins, rendering the material unsuitable for biopolymer production. Results suggested that treatment with sodium sulphite (4.3% wt. of feathers) and use of a small particle size (0–100 µm), sufficiently altered the properties of raw feathers to enable feather biopolymer production.
{"title":"Poultry feather disulphide bond breakdown to enable bio-based polymer production","authors":"T. McGauran, N. Dunne, B. Smyth, E. Cunningham, M. Harris","doi":"10.1177/20412479211008746","DOIUrl":"https://doi.org/10.1177/20412479211008746","url":null,"abstract":"With oil supplies, needed for plastic production, decreasing dramatically, there is a clear driver for alterative polymers from sustainable resources. Poultry feathers, containing ∼90% keratin, are one source of natural polymer with huge potential for biopolymer production. However, the presence of crosslinks, known as disulphide bonds, hinders processability. This paper reviews techniques to enable breakage of disulphide bonds through use of reduction agents (sodium sulphite and sodium sulphate) and hydrolysis. Samples were analysed using FTIR and DSC to quantify achievable bond breakage, effect on thermal properties and changes in protein concentration. A review on the effect of particle size on disulphide bond breakage was also conducted, along with quantifying the reformation of bonds post-processing. Finally, a bicinchoninic acid (BCA) protein assay was used to quantify changes to soluble protein content, key to predicting if biopolymer formation can occur. The results showed a final disulphide bond breakage of between 48% and 67% was achievable using these techniques. It was also shown that disulphide bond content exhibited up to 60% bond reformation post treatment. These reductions in disulphide bonds increased the thermoplastic nature and apparent protein content. Despite achieving the highest bond breakage percentage, hydrolysis caused degradation of useful proteins, rendering the material unsuitable for biopolymer production. Results suggested that treatment with sodium sulphite (4.3% wt. of feathers) and use of a small particle size (0–100 µm), sufficiently altered the properties of raw feathers to enable feather biopolymer production.","PeriodicalId":20353,"journal":{"name":"Polymers from Renewable Resources","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/20412479211008746","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49406752","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-03-17DOI: 10.1177/20412479221122298
A. M. Abdel-Ghaffar, H. Ali
Blend films of polyvinyl alcohol (PVA) with starch (St) were obtained by casting method. The effect of different contents of glycerol (Glyc) and citric acid (CA) was investigated. The successful preparations of different compositions were shown by FTIR analysis. The bioblend film of PVA/St/CA/Glyc with a composition of (2:1:1/10 vol %) was selected due to its water resistance, higher mechanical properties, and good thermal stability than other prepared bioblend films. Further improvements were obtained by irradiation with gamma rays at a dose of 10 kGy, where the water resistance was highly reduced and the tensile strength strongly improved. The thermal stability increased with the increasing of irradiation doses up to 30 kGy. The modified thermal and mechanical properties of the selected film either non-irradiated or irradiated were compared with widely used commercially packaging films such as LDPE and PP films. Compared to commercially packaging films, the selected PVA/St bioblend film has higher tensile properties, good and closely thermal properties either non-irradiated or irradiated one. Hence, the study showed the development of modified PVA/St bioblend film, which can be used in many fields such as the packaging industry.
{"title":"Radiation modification and characterization of polyvinyl alcohol/starch/citric acid/glycerol bioblend film","authors":"A. M. Abdel-Ghaffar, H. Ali","doi":"10.1177/20412479221122298","DOIUrl":"https://doi.org/10.1177/20412479221122298","url":null,"abstract":"Blend films of polyvinyl alcohol (PVA) with starch (St) were obtained by casting method. The effect of different contents of glycerol (Glyc) and citric acid (CA) was investigated. The successful preparations of different compositions were shown by FTIR analysis. The bioblend film of PVA/St/CA/Glyc with a composition of (2:1:1/10 vol %) was selected due to its water resistance, higher mechanical properties, and good thermal stability than other prepared bioblend films. Further improvements were obtained by irradiation with gamma rays at a dose of 10 kGy, where the water resistance was highly reduced and the tensile strength strongly improved. The thermal stability increased with the increasing of irradiation doses up to 30 kGy. The modified thermal and mechanical properties of the selected film either non-irradiated or irradiated were compared with widely used commercially packaging films such as LDPE and PP films. Compared to commercially packaging films, the selected PVA/St bioblend film has higher tensile properties, good and closely thermal properties either non-irradiated or irradiated one. Hence, the study showed the development of modified PVA/St bioblend film, which can be used in many fields such as the packaging industry.","PeriodicalId":20353,"journal":{"name":"Polymers from Renewable Resources","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48626520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-02-01DOI: 10.1177/20412479211008747
DG Braga, Pgf Bezerra, Abfd Lima, HA Pinheiro, LG Gomes, AS Fonseca, L. Bufalino
The use of local raw materials for the production of biodegradable films can simultaneously contribute to the development of the Amazon and global sustainability. This work aimed to evaluate the physical and mechanical performance of chitosan-based bionanocomposite films reinforced with different loads of cellulose nanofibrils obtained from açaí (Euterpe oleraceae Mart.) under two nanofibrillation degrees. Nanofibrils were obtained by 3 and 21 passages in a grinder defibrillator. The films were produced by casting with nanofibril reinforcement at 5 wt.%, 10 wt.%, 15 wt.%, and 20 wt.%. The increase in the nanofibril level and nanofibrillation degree reduced water vapor absorption (75.20% to 51.93%), water solubility (28.33% to 17.91%), and density (0.87 g.cm−3 to 0.61 g.cm−3). The water vapor permeability decreased with higher nanofibril loads for both 3-pass (47.30% to 43.61%) and 21-pass (49.82% to 44.48%) reinforced films, but not with nanofibrillation degree. The increase in 3-pass nanofibril level decreased tensile strength (8.18 MPa to 7.88 MPa), modulus of elasticity (867.62 MPa to 670.02 MPa) and elongation at break (0.02 mm.mm−1 to 0.01 mm.mm−1). However, the opposite effect happened to 21-pass nanofibrils, with increases from 9.16 MPa to 9.73 MPa and from 502.00 MPa to 1119.62 MPa for tensile strength and modulus of elasticity, respectively. Meanwhile, the maximum elongation at rupture did not vary. It was concluded that chitosan-based bionanocomposite films reinforced with 20 wt.% of 21-pass nanofibril were more resistant, except for water vapor permeability. Adding coarser nanofibrils enhanced this property. The 3-pass nanofibrils reinforcement enables water solubility, which benefits other packaging applications.
{"title":"Chitosan-based films reinforced with cellulose nanofibrils isolated from Euterpe oleraceae MART","authors":"DG Braga, Pgf Bezerra, Abfd Lima, HA Pinheiro, LG Gomes, AS Fonseca, L. Bufalino","doi":"10.1177/20412479211008747","DOIUrl":"https://doi.org/10.1177/20412479211008747","url":null,"abstract":"The use of local raw materials for the production of biodegradable films can simultaneously contribute to the development of the Amazon and global sustainability. This work aimed to evaluate the physical and mechanical performance of chitosan-based bionanocomposite films reinforced with different loads of cellulose nanofibrils obtained from açaí (Euterpe oleraceae Mart.) under two nanofibrillation degrees. Nanofibrils were obtained by 3 and 21 passages in a grinder defibrillator. The films were produced by casting with nanofibril reinforcement at 5 wt.%, 10 wt.%, 15 wt.%, and 20 wt.%. The increase in the nanofibril level and nanofibrillation degree reduced water vapor absorption (75.20% to 51.93%), water solubility (28.33% to 17.91%), and density (0.87 g.cm−3 to 0.61 g.cm−3). The water vapor permeability decreased with higher nanofibril loads for both 3-pass (47.30% to 43.61%) and 21-pass (49.82% to 44.48%) reinforced films, but not with nanofibrillation degree. The increase in 3-pass nanofibril level decreased tensile strength (8.18 MPa to 7.88 MPa), modulus of elasticity (867.62 MPa to 670.02 MPa) and elongation at break (0.02 mm.mm−1 to 0.01 mm.mm−1). However, the opposite effect happened to 21-pass nanofibrils, with increases from 9.16 MPa to 9.73 MPa and from 502.00 MPa to 1119.62 MPa for tensile strength and modulus of elasticity, respectively. Meanwhile, the maximum elongation at rupture did not vary. It was concluded that chitosan-based bionanocomposite films reinforced with 20 wt.% of 21-pass nanofibril were more resistant, except for water vapor permeability. Adding coarser nanofibrils enhanced this property. The 3-pass nanofibrils reinforcement enables water solubility, which benefits other packaging applications.","PeriodicalId":20353,"journal":{"name":"Polymers from Renewable Resources","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/20412479211008747","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45212516","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-02-01DOI: 10.1177/20412479211008773
K. Sreekumar, B. Bindhu, K. Veluraja
The demand for an adoption of renewable resources rather than finitely available non renewable sources for industrial purposes are rising, with the growing environmental constraints. Polymers being one of the crucial part of almost all the industries, pioneer in the list of sources needed for various applications. This makes polymers that can be obtained from renewable sources being studied widely and are anticipated to make a revolution in the field of packaging industry, medical field, and automobile industry. Polylactic acid (PLA) is one among such biopolymers, which is an aliphatic polyester derived from lactic acid (2-hydroxypropionic acid), that find wide applications in food packaging industry, tissue scaffolding, and biomedical devices. This paper focuses on an in-depth review on polylactic acid, its structure, and various properties of PLA. The details of different polymer blends/composites based on PLA are also discussed here. The fields of applications, where PLA is being utilized and the future scopes of the polymer are also studied.
{"title":"Perspectives of polylactic acid from structure to applications","authors":"K. Sreekumar, B. Bindhu, K. Veluraja","doi":"10.1177/20412479211008773","DOIUrl":"https://doi.org/10.1177/20412479211008773","url":null,"abstract":"The demand for an adoption of renewable resources rather than finitely available non renewable sources for industrial purposes are rising, with the growing environmental constraints. Polymers being one of the crucial part of almost all the industries, pioneer in the list of sources needed for various applications. This makes polymers that can be obtained from renewable sources being studied widely and are anticipated to make a revolution in the field of packaging industry, medical field, and automobile industry. Polylactic acid (PLA) is one among such biopolymers, which is an aliphatic polyester derived from lactic acid (2-hydroxypropionic acid), that find wide applications in food packaging industry, tissue scaffolding, and biomedical devices. This paper focuses on an in-depth review on polylactic acid, its structure, and various properties of PLA. The details of different polymer blends/composites based on PLA are also discussed here. The fields of applications, where PLA is being utilized and the future scopes of the polymer are also studied.","PeriodicalId":20353,"journal":{"name":"Polymers from Renewable Resources","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/20412479211008773","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46496215","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-02-01DOI: 10.1177/2041247921989898
A. Amarasekara, Rocio Garcia-Obregon
Renewable resources based hydrovanilloin [1,2-bis(4-hydroxy-3-methoxyphenyl)-1,2-ethanediol] was synthesized in 86% yield by electrochemical dimerization of vanillin in aqueous NaOH. This symmetrical bis-phenol monomer was then used for the preparation of urethane polymers by two different methods. In the first method a 1:2 mole ratio mixture of hydrovanilloin and diisocyanate was polymerized in DMF using 1,4-diazabicyclo[2,2,2]octane as the catalyst at 60°C, for 1 h to give poly(hydrovanilloin–urethane)s. In the second method diisocyanates were first reacted with polyethylene glycol-400 to give pre-polymers. Then prepolymers were reacted with equivalent amount of hydrovanilloin at 60°C for 4 days to produce poly(hydrovanilloin-ethylene glycol-urethane)s. The first method resulted hard poly(hydrovanilloin–urethane)s showing Tg values in the range of 121–172°C. The second method yielded softer poly(hydrovanilloin-ethylene glycol-urethane)s and these polymers failed to show distinct glass transition temperatures in the DSC analysis. However, poly(hydrovanilloin-ethylene glycol-urethane)s showed better thermal stabilities than polymers without polyethylene glycol units.
{"title":"Vanillin based polymers: V. Poly(hydrovanilloin–urethane)","authors":"A. Amarasekara, Rocio Garcia-Obregon","doi":"10.1177/2041247921989898","DOIUrl":"https://doi.org/10.1177/2041247921989898","url":null,"abstract":"Renewable resources based hydrovanilloin [1,2-bis(4-hydroxy-3-methoxyphenyl)-1,2-ethanediol] was synthesized in 86% yield by electrochemical dimerization of vanillin in aqueous NaOH. This symmetrical bis-phenol monomer was then used for the preparation of urethane polymers by two different methods. In the first method a 1:2 mole ratio mixture of hydrovanilloin and diisocyanate was polymerized in DMF using 1,4-diazabicyclo[2,2,2]octane as the catalyst at 60°C, for 1 h to give poly(hydrovanilloin–urethane)s. In the second method diisocyanates were first reacted with polyethylene glycol-400 to give pre-polymers. Then prepolymers were reacted with equivalent amount of hydrovanilloin at 60°C for 4 days to produce poly(hydrovanilloin-ethylene glycol-urethane)s. The first method resulted hard poly(hydrovanilloin–urethane)s showing Tg values in the range of 121–172°C. The second method yielded softer poly(hydrovanilloin-ethylene glycol-urethane)s and these polymers failed to show distinct glass transition temperatures in the DSC analysis. However, poly(hydrovanilloin-ethylene glycol-urethane)s showed better thermal stabilities than polymers without polyethylene glycol units.","PeriodicalId":20353,"journal":{"name":"Polymers from Renewable Resources","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/2041247921989898","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49441681","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-11-15DOI: 10.1177/2041247920968505
N. Goudarzian, M. Esmaeli, S. Mousavi, S. Hashemi, M. Zarei, A. Gholami, K. Yousefi
In this paper, the mechanical and morphological properties of biodegradable SAN/EOC/Nanoclay/Proteins nanocomposite were investigated. The composites were first prepared by a laboratory-scale twin screw extruder. Morphology of the blend was determined by SEM images. Mechanical properties in terms of tensile tests were carried out by Testometric TS2000, stress at break, strain at break, and Young’s modulus was determined. Based on mechanical results, although the young’s modulus increases with increasing protein content but the strain at break of the composite decreases acutely because of the presence of protein. The blend indicated an improvement in mechanical and thermal properties. Today, according to the vast application of plastic in different fields, environmental issues were affected by these kinds of non-degradable materials, so that biodegradability of the plastics is just the remaining route to solve. In this research, biodegradable blends were prepared using whey protein as a biodegradable natural polymer. The results of the biological procedure-test after 3 months indicated sufficient weight loss and biodegradation of these blends.
{"title":"Preparation physical, mechanical properties and biodegradable study of SAN/EOC/nanoclay/proteins nanocomposite","authors":"N. Goudarzian, M. Esmaeli, S. Mousavi, S. Hashemi, M. Zarei, A. Gholami, K. Yousefi","doi":"10.1177/2041247920968505","DOIUrl":"https://doi.org/10.1177/2041247920968505","url":null,"abstract":"In this paper, the mechanical and morphological properties of biodegradable SAN/EOC/Nanoclay/Proteins nanocomposite were investigated. The composites were first prepared by a laboratory-scale twin screw extruder. Morphology of the blend was determined by SEM images. Mechanical properties in terms of tensile tests were carried out by Testometric TS2000, stress at break, strain at break, and Young’s modulus was determined. Based on mechanical results, although the young’s modulus increases with increasing protein content but the strain at break of the composite decreases acutely because of the presence of protein. The blend indicated an improvement in mechanical and thermal properties. Today, according to the vast application of plastic in different fields, environmental issues were affected by these kinds of non-degradable materials, so that biodegradability of the plastics is just the remaining route to solve. In this research, biodegradable blends were prepared using whey protein as a biodegradable natural polymer. The results of the biological procedure-test after 3 months indicated sufficient weight loss and biodegradation of these blends.","PeriodicalId":20353,"journal":{"name":"Polymers from Renewable Resources","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1177/2041247920968505","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43950996","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-11-02DOI: 10.1177/2041247920968498
N. Lardjane, N. Belhaneche-Bensemra
The aim of this paper is the determination of the migration and biodegradation of the PVC additives in the soil. Epoxidized Sunflower Oil (ESO) was used as a thermal organic co-stabilizer for PVC; it was obtained by epoxidation of commercial sunflower oil. Two plasticizers were used: dioctyl phthalate (DOP) and diisononyl adipate (DINA). A natural aging test on site in a garden soil (Tizi Ouzou, Algeria) of the PVC samples was investigated for 6 months. The samples were characterized by Fourier transform infrared (FTIR).The morphological changes were followed by scanning electron microscopy (SEM). The evolution of the bacterial growth, identification using biochemical tests, variation of pH and variation of mass were investigated. The results showed that the nature of the plasticizer and heat stabilizer affects the properties of PVC as well as the phenomena of migration and biodegradation.
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