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Proceedings of 1994 IEEE International Symposium on Applications of Ferroelectrics最新文献

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Quantum size effects and nonlinear optical properties of ZnS and CdS semiconductor-doped silica glasses prepared by sol-gel process 溶胶-凝胶法制备ZnS和CdS半导体掺杂二氧化硅玻璃的量子尺寸效应和非线性光学性质
Zhao Qingchun, L. Chunliang, L. Hongling, Zhang Liangying, Y. Xi
Preparation of silica glasses doped with CdS and ZnS microcrystals is presented. The optical absorption spectra and the photoluminescence spectra show that the optical absorption edges and the photoluminescence peaks shift to the higher energy side with decreasing the size of the microcrystals, which exhibit the quantum size effect. The third order optical susceptibilities are measured by degenerate four wave mixing (DFWM) method. The third order optical nonlinearity of the nanocomposites prepared by the sol-gel process is largely enhanced.
介绍了掺杂CdS和ZnS微晶的二氧化硅玻璃的制备方法。光吸收光谱和光致发光光谱表明,随着微晶体尺寸的减小,光吸收边和光致发光峰向高能侧移动,表现出量子尺寸效应。采用简并四波混频(DFWM)法测量了三阶光学磁化率。溶胶-凝胶法制备的纳米复合材料的三阶光学非线性大大增强。
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引用次数: 1
Nonlinear dynamics and ferroelectric materials 非线性动力学与铁电材料
S. Blochwitz, R. Habel, M. Diestelhorst, H. Beige
The aim of the presented paper is to show that the application of analysis methods of dissipative chaotic systems is a useful tool for the study of structural phase transitions and the large signal behaviour of ferroelectric materials. The series resonance circuit with a ferroelectric capacitor is a practical realization of a nonlinear dynamical system which exhibits period-doubling behaviour and chaos if the amplitude and the frequency of the driving voltage have suitable values. The response function of the nonlinear dynamical system is used for the determination of the nonlinear coefficients of the sample.
本文的目的是表明耗散混沌系统分析方法的应用是研究铁电材料的结构相变和大信号行为的有用工具。铁电电容串联谐振电路是非线性动力系统的实际实现,当驱动电压的幅值和频率合适时,该非线性动力系统表现出周期倍性和混沌性。非线性动力系统的响应函数用于确定样本的非线性系数。
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引用次数: 0
Frequency response of MgO:LiNbO/sub 3/ crystals MgO:LiNbO/ sub3 /晶体的频率响应
B. Jin, N. Bhalla, I. Kim, B. C. Park
MgO-doped congruent LiNbO/sub 3/ were grown by the Czochralski method. All MgO-doped LiNbO/sub 3/ crystals have a higher growing temperature than that of pure crystals. The frequency dependent dielectric spectra was measured to study the relaxational and conduction mechanism. Strong low frequency dispersion indicated that the main conduction mechanism of MgO-doped LiNbO/sub 3/ is by charge carrier hopping which may be caused by defects or Mg-ions. Impedance spectra measurement show that this system does not satisfy a Debye law but Jonscher's "universal law".
用Czochralski法生长了掺mgo的同位LiNbO/ sub3 /。所有掺mgo的LiNbO/ sub3 /晶体的生长温度都高于纯晶体。测量了频率相关的介电谱,研究了弛豫和传导机理。强低频色散表明掺mgo的LiNbO/sub 3/的主要导电机制是载流子跳变,这种跳变可能是由缺陷或mg离子引起的。阻抗谱测量结果表明,该系统不满足德拜定律,而满足琼舍尔“普遍定律”。
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引用次数: 0
Degradation behavior of Ca-doped barium titanate ceramic capacitors 掺钙钛酸钡陶瓷电容器的降解行为
M. Huh, K. Cho, H. Nam, H. Lee
Electrical degradation of calcium-containing MLCCs having nickel internal electrode was studied using a highly accelerated life test set-up. Both extrinsic and intrinsic failures were identified in commercial MLCCs. From the estimated values of degradation parameters such as voltage exponent factor and pseudo-activation energy, it was found that the intrinsic failure took place by thermal runaway. Although, the degradation pattern for nickel electrode MLCCs was similar to that for common palladium electrode MLCCs, the maximum rated lifetime of the former was in the range of 5 to 30 years and was, in general, shorter than that of the latter. This difference was ascribed to the difference in oxygen vacancy concentrations. Thus, possible degradation mechanisms should be related to oxygen vacancy movement. Among them are reduction model, grain boundary barrier model and de-mixing model.
采用高加速寿命试验装置研究了镍内电极含钙mlcc的电降解。在商业mlcc中发现了外在和内在的故障。从电压指数因子和伪活化能等退化参数的估计值可以看出,材料的内在破坏是由热失控引起的。虽然镍电极mlcc的降解模式与普通钯电极mlcc相似,但前者的最大额定寿命在5 ~ 30年之间,总体上短于后者。这种差异归因于氧空位浓度的差异。因此,可能的降解机制应该与氧空位运动有关。其中包括还原模型、晶界障碍模型和脱混模型。
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引用次数: 0
Microwave dielectric properties of BaO-TiO/sub 2/-WO/sub 3/ ceramics sintered with glasses 玻璃烧结BaO-TiO/sub - 2/-WO/sub - 3陶瓷的微波介电性能
T. Takada, Sea-Fue Wang, S. Yoshikawa, S. Jang, R. Newnham
The microwave dielectric properties and the sintering behavior of commercial BaO-TiO/sub 2/-WO/sub 3/ dielectrics, N-35, with addition of various glasses; (1) simple glass formers, (2) ZnO-B/sub 2/O/sub 3/ based, (3) B/sub 2/O/sub 3/-SiO/sub 2/ based and (4) Al/sub 2/O/sub 3/-SiO/sub 2/ based glasses were studied. The Q of N-35 sintered with a ZnO-B/sub 2/O/sub 3/ glass system showed a sudden drop in the sintering temperature to around 1000/spl deg/C. Results of XRD, thermal analysis and scanning electron microscopy suggest that the chemical reaction between N-35 and the glass had a larger effect on Q than density. A 5wt% addition of B/sub 2/O/sub 3/ to N-35, when sintered at 1200/spl deg/C, had the best dielectric properties, Q=8300 and K=34.1 at 8.5 GHz, among the glasses Q, K and density increased with sintering temperature from 1000 to 1200/spl deg/C. The effects of the amount of glass added and the mixing method on the density and the dielectric properties will be discussed.
添加各种玻璃后,商品BaO-TiO/sub - 2/-WO/sub -3 / N-35的微波介电性能和烧结性能(1)研究了简单玻璃成品剂,(2)ZnO-B/sub - 2/O/sub - 3/基玻璃,(3)B/sub - 2/O/sub - 3/-SiO/sub - 2/基玻璃和(4)Al/sub - 2/O/sub - 3/-SiO/sub - 2/基玻璃。在ZnO-B/sub - 2/O/sub -3 /玻璃体系中烧结的N-35的Q值突然下降到1000/spl℃左右。XRD、热分析和扫描电镜结果表明,N-35与玻璃的化学反应对Q的影响大于密度对Q的影响。当烧结温度为1200/spl℃时,在N-35中添加5wt%的B/sub 2/O/sub 3/时,在8.5 GHz时的介电性能最佳,Q=8300, K=34.1,其中Q、K和密度随烧结温度的升高而增大。讨论了玻璃的加入量和混合方式对密度和介电性能的影响。
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引用次数: 1
Electric properties and domain structures in Ba(Ti,Sn)O/sub 3/ ceramics Ba(Ti,Sn)O/sub - 3/陶瓷的电性质和畴结构
K. Oh, K. Uchino, L. Cross
The Ba(Ti,Sn)O/sub 3/ ceramics are known as relaxor materials and they show very small hysteresis of field induced strains and field induced polarizations. An optical study was attempted to explain these dielectric properties. Domain structures and motions in Ba(Ti/sub 1-x/Sn/sub x/)O/sub 3/ (x=0, 0.05, 0.1, 0.13) ceramics were observed under an electric field at various temperatures using a high resolution CCD microscope system. Electrical properties such as field induced strains, dielectric properties and field induced polarization characteristics were also measured. The Ba(Ti/sub 1-x/ Sn/sub x/)O/sub 3/ ceramics showed a significant difference in domain structures and motions with changing composition. The domain structure became tiny and complex with increasing x. Changes of domain structures due to the phase transitions were also observed with varying temperature. The domain reorientation was easily induced with rising and falling electric field. The results of domain observations can explain the electrical properties well.
Ba(Ti,Sn)O/sub 3/陶瓷被称为弛豫材料,它们表现出非常小的场致应变和场致极化的滞后。一种光学研究试图解释这些介电性质。利用高分辨率CCD显微镜系统,观察了Ba(Ti/sub - 1-x/Sn/sub -x/)O/sub - 3/ (x= 0,0.05, 0.1, 0.13)陶瓷在不同温度电场作用下的畴结构和运动。测量了材料的场致应变、介电特性和场致极化特性等电学性能。Ba(Ti/sub - 1-x/ Sn/sub -x/)O/sub - 3/陶瓷的畴结构和运动随成分的变化有显著差异。随着x的增加,畴结构变得微小而复杂。随着温度的变化,畴结构也因相变而发生变化。电场的上升和下降容易引起畴重定向。畴观测结果可以很好地解释其电学性质。
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引用次数: 0
The design, processing, evaluation and characterization of pyroelectric PVDF copolymer/silicon MOSFET detector arrays 热释电PVDF共聚物/硅MOSFET探测器阵列的设计、加工、评价和表征
P. Bloomfield, F. Castro, R. M. Goeller
We have developed a 64 element linear array of pyroelectric elements fully integrated on silicon wafers with MOS readout devices. The ferroelectric polymer film sensor deposited and polarized on the extended gate of the MOSFET results in a hybrid circuit, the pyroelectric-oxide-semiconductor field effect transistor (POSFET). The fabrication of the wafers included the design of the various masks required to produce the layers which made up the transistor array: stopper layer, active layer, poly-silicon layer, contacts layer, and bottom electrode layer. A thin film of the ferroelectric copolymer P(VDF/TrFE) was spin coated onto the wafer. Patterned gold electrodes were sputtered as the top electrode layer. The ferroelectric copolymer was hysteresis poled in situ. Tests performed included the array's response to a CO/sub 2/ laser operating in the CW and single pulse modes at 10.6 /spl mu/m. We present details of the design, processing, and testing of the fabricated devices.
我们开发了一种64元热释电元件线性阵列,完全集成在带有MOS读出器件的硅片上。将铁电聚合物薄膜传感器沉积并极化在MOSFET的扩展栅极上,形成热释电-氧化物-半导体场效应晶体管(POSFET)的混合电路。晶圆的制造包括设计各种掩模,以生产构成晶体管阵列的层:阻流层、有源层、多晶硅层、触点层和底电极层。将铁电共聚物P(VDF/TrFE)薄膜自旋涂覆在晶圆上。溅射图案金电极作为顶层电极层。铁电共聚物在原位进行磁滞极化。所进行的测试包括在连续波和10.6 /spl μ m单脉冲模式下工作的CO/sub 2/激光器对阵列的响应。我们详细介绍了制造器件的设计、加工和测试。
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引用次数: 2
Liquid delivery CVD of PLZT thick films for electro-optic applications 用于电光应用的PLZT厚膜的液体输送CVD
J. Roeder, S. Bilodeau, P. Van Buskirk, V. Ozguz, J. Ma, S. Lee
PLZT films in the composition range 7/0/100-32/0/100 have been deposited by CVD from a single source reagent using a liquid delivery/flash vaporization approach. Single phase perovskite films ranging in thickness from 1-5 /spl mu/m were deposited on fused silica substrates at 535/spl deg/C. The films had very strong crystallographic texture with [100] normal to the plane of the film. Optical loss per unit thickness was lower for thicker films suggesting that interfacial effects dominated losses. Very large electro-optic effects were observed in a number of the films. Birefringent shifts were measured by phase retardation in transmission mode with an electric field applied in the plane of the film using interdigitated electrodes. Birefringent shift varied quadratically with applied field and showed little hysteresis with R coefficients as high as 5/spl times/10/sup -16/ (m/V)/sup 2/. The strength of the electro-optic effect is attributed to the high degree of crystallinity of the films and the a-axis orientation.
PLZT薄膜的组成范围为7/0/100-32/0/100,通过CVD从单一源试剂使用液体输送/闪蒸方法沉积。在535℃/spl℃的温度下,在熔融石英衬底上沉积了厚度为1-5 /spl mu/m的单相钙钛矿薄膜。薄膜具有很强的晶体结构,[100]垂直于薄膜平面。单位厚度的光损耗在较厚的薄膜中较低,表明界面效应主导了损耗。在许多薄膜中观察到非常大的电光效应。双折射位移的测量是在传输模式下,用交叉指状电极在薄膜平面上施加电场,通过相位延迟测量。双折射位移随外加磁场的变化呈二次变化,表现出较小的滞后,R系数高达5/ sp1倍/10/sup -16/ (m/V)/sup 2/。电光效应的强度归因于薄膜的高结晶度和a轴取向。
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引用次数: 4
Pyrotransistor-GaAs FET with a "pyroelectric wafer" gate 具有“热释电晶圆”栅极的热释晶体管-砷化镓场效应晶体管
Y. Poplavko, V. Moskalyuk, A.I. Timofeyev, Y. Prokopenko
The multifunction properties of GaAs and other III-V semi-insulating crystals can be expanded by the artificial decreasing of their electric response symmetry that could be transformed from piezo- into a pyroelectric class. An artificial pyroelectricity of III-V type semiconductors can form a basis for one-crystal pyroelectric sensors. The voltage sensitivity of GaAs (111)-cut corresponds to one of PZT pyroelectric ceramics so the GaAs wafer could be used as a thermal-to-electric transducer in a new microelectronic device named "pyrotransistor" that is uncooled far infrared detector based on MESFET technology.
通过人为降低GaAs和其他III-V型半绝缘晶体的电响应对称性,可以将其从压电型转变为热释电型,从而扩大其多功能特性。III-V型半导体的人工热释电可以作为单晶热释电传感器的基础。GaAs(111)晶片的电压灵敏度与PZT热释电陶瓷的电压灵敏度相当,因此GaAs晶片可以作为热电转换器用于新型微电子器件“热释电晶体管”中,该器件是基于MESFET技术的非冷却远红外探测器。
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引用次数: 1
Ce:Fe:LiNbO/sub 3/ photorefractive crystal: material properties and applications Ce:Fe:LiNbO/ sub3 /光折变晶体:材料性质及应用
F. Yu, A. Bhalla, S. Yin, F. Zhao, Z. Wu, D. Salerno
A specially doped photorefractive (PR) crystal Ce:Fe:LiNbO/sub 3/, and the effect due to Ce and Fe dopants are reported. We have found that the double-doped crystal exhibits higher PR sensitivity, larger dynamic range, broader spectral bandwidth, and lower scattering noise. It is about 10-times higher in PR sensitivity in the red light region (633 nm), as compared with the reported data. We have also discovered anomalous enhancement of PR effects which occur at 57/spl deg/C, 70/spl deg/C and 110/spl deg/C. The anomalies are primarily due to possible structural phase-transitions of the crystal at these temperatures. Several applications of this specially doped PR (Ce:Fe:LiNbO/sub 3/) crystal (both bulk and fiber) are also provided.
报道了一种特殊掺杂的光折变(PR)晶体Ce:Fe:LiNbO/ sub3 /,以及Ce和Fe掺杂剂对晶体性能的影响。我们发现,双掺杂晶体具有更高的PR灵敏度、更大的动态范围、更宽的光谱带宽和更低的散射噪声。它在红光区(633 nm)的PR灵敏度比报道的数据高10倍左右。我们还发现,在57/spl℃、70/spl℃和110/spl℃时,PR效应异常增强。这些异常主要是由于晶体在这些温度下可能发生的结构相变。本文还介绍了这种特殊掺杂PR (Ce:Fe:LiNbO/sub 3/)晶体(块状和光纤)的几种应用。
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引用次数: 1
期刊
Proceedings of 1994 IEEE International Symposium on Applications of Ferroelectrics
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