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Proceedings of 1994 IEEE International Symposium on Applications of Ferroelectrics最新文献

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The effect of high temperature HIPing and annealing on the dielectric properties of modified lead titanate ceramics 高温高温平镀和退火对改性钛酸铅陶瓷介电性能的影响
M. R. Cockburn, D. Hall, C. Millar
Studies on the hot isostatic pressing (HIPing) of Sm, Mn-doped lead titanate ceramics in an argon/oxygen atmosphere have shown that the HIPed materials exhibit a substantially lower dielectric loss than conventionally sintered materials (tan /spl delta/ being reduced from approximately 0.02 to 0.01 at 1 kHz). The present work was carried out in order to identify the processing variables which are most important in effecting this reduction in loss. The materials were prepared by conventional solid state reaction and subjected to a variety of HIPing and annealing conditions. A mechanism involving the re-distribution of Mn ions among the Pb and Ti sites during HIPing is proposed to account for the observed changes in dielectric loss, which show a strong correlation with changes in the electrical conductivity.
对Sm, mn掺杂钛酸铅陶瓷在氩/氧气氛下的热等静压(HIPing)研究表明,HIPed材料的介电损耗明显低于常规烧结材料(tan /spl δ /在1 kHz时从大约0.02降低到0.01)。目前的工作是为了确定在减少损失方面最重要的加工变量。该材料采用常规固相反应制备,并经过多种HIPing和退火条件。在HIPing过程中,Mn离子在Pb和Ti位点之间的重新分配机制被提出,以解释所观察到的介电损耗的变化,这与电导率的变化有很强的相关性。
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引用次数: 0
Degradation behavior of Ca-doped barium titanate ceramic capacitors 掺钙钛酸钡陶瓷电容器的降解行为
M. Huh, K. Cho, H. Nam, H. Lee
Electrical degradation of calcium-containing MLCCs having nickel internal electrode was studied using a highly accelerated life test set-up. Both extrinsic and intrinsic failures were identified in commercial MLCCs. From the estimated values of degradation parameters such as voltage exponent factor and pseudo-activation energy, it was found that the intrinsic failure took place by thermal runaway. Although, the degradation pattern for nickel electrode MLCCs was similar to that for common palladium electrode MLCCs, the maximum rated lifetime of the former was in the range of 5 to 30 years and was, in general, shorter than that of the latter. This difference was ascribed to the difference in oxygen vacancy concentrations. Thus, possible degradation mechanisms should be related to oxygen vacancy movement. Among them are reduction model, grain boundary barrier model and de-mixing model.
采用高加速寿命试验装置研究了镍内电极含钙mlcc的电降解。在商业mlcc中发现了外在和内在的故障。从电压指数因子和伪活化能等退化参数的估计值可以看出,材料的内在破坏是由热失控引起的。虽然镍电极mlcc的降解模式与普通钯电极mlcc相似,但前者的最大额定寿命在5 ~ 30年之间,总体上短于后者。这种差异归因于氧空位浓度的差异。因此,可能的降解机制应该与氧空位运动有关。其中包括还原模型、晶界障碍模型和脱混模型。
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引用次数: 0
PbTiO/sub 3/ thin films for pyroelectric detection 热释电检测用PbTiO/ sub3 /薄膜
A. Bell, Y. Huang, M. Kohli, O. Paul, P. Ryser, M. Forster
Due to its high pyroelectric coefficient, low permittivity and relatively low piezoelectric coefficients, lead titanate is an important candidate for use in pyroelectric detectors. Sol-gel processing of lead titanate thin films, in combination with micro-machining of silicon substrates, is being used for the development of low-cost infra-red detectors with properties equivalent to existing "bulk" or single crystal devices. Here we report on some aspects of the sol-gel chemistry, the optimisation of the pyroelectric figure of merit and the fabrication and characterisation of an infra-red detector, consisting of two pyroelectric elements on a micro-machined SiO/sub 2/-Si/sub 3/N/sub 4/ membrane.
钛酸铅具有高热释电系数、低介电常数和相对较低的压电系数,是热释电探测器的重要候选材料。钛酸铅薄膜的溶胶-凝胶加工与硅衬底的微加工相结合,正被用于开发低成本的红外探测器,其性能相当于现有的“大块”或单晶器件。本文报道了溶胶-凝胶化学的一些方面,热释电性能图的优化以及红外探测器的制造和表征,该探测器由两个热释电元件组成,位于微机械SiO/sub 2/-Si/sub 3/N/sub 4/膜上。
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引用次数: 4
Liquid delivery CVD of PLZT thick films for electro-optic applications 用于电光应用的PLZT厚膜的液体输送CVD
J. Roeder, S. Bilodeau, P. Van Buskirk, V. Ozguz, J. Ma, S. Lee
PLZT films in the composition range 7/0/100-32/0/100 have been deposited by CVD from a single source reagent using a liquid delivery/flash vaporization approach. Single phase perovskite films ranging in thickness from 1-5 /spl mu/m were deposited on fused silica substrates at 535/spl deg/C. The films had very strong crystallographic texture with [100] normal to the plane of the film. Optical loss per unit thickness was lower for thicker films suggesting that interfacial effects dominated losses. Very large electro-optic effects were observed in a number of the films. Birefringent shifts were measured by phase retardation in transmission mode with an electric field applied in the plane of the film using interdigitated electrodes. Birefringent shift varied quadratically with applied field and showed little hysteresis with R coefficients as high as 5/spl times/10/sup -16/ (m/V)/sup 2/. The strength of the electro-optic effect is attributed to the high degree of crystallinity of the films and the a-axis orientation.
PLZT薄膜的组成范围为7/0/100-32/0/100,通过CVD从单一源试剂使用液体输送/闪蒸方法沉积。在535℃/spl℃的温度下,在熔融石英衬底上沉积了厚度为1-5 /spl mu/m的单相钙钛矿薄膜。薄膜具有很强的晶体结构,[100]垂直于薄膜平面。单位厚度的光损耗在较厚的薄膜中较低,表明界面效应主导了损耗。在许多薄膜中观察到非常大的电光效应。双折射位移的测量是在传输模式下,用交叉指状电极在薄膜平面上施加电场,通过相位延迟测量。双折射位移随外加磁场的变化呈二次变化,表现出较小的滞后,R系数高达5/ sp1倍/10/sup -16/ (m/V)/sup 2/。电光效应的强度归因于薄膜的高结晶度和a轴取向。
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引用次数: 4
Dielectric properties and D.C. resistivity of magnesium-substituted lithium ferrites 镁取代锂铁氧体的介电性能和直流电阻率
S. Phanjoubam, D. Kothari, C. Prakash, P. Kishan
The paper reports the influence of magnesium substitution on structural and electrical properties of lithium ferrites. The samples with compositional formula Li/sub (1-x//2)Mg/sub x/Fe/sub (5-x//2)O/sub 4/ with x ranging from 0.1 to 0.9 were prepared by standard dry ceramic method. XRD shows all the samples to be single phase spinel and the value of lattice constant was found to increase with increasing substitution level x. The room temperature d.c. resistivity increases with x. The variation has been explained in terms of hopping mechanism and the cation distribution. The resistivity with temperature shows a change in slope which does not correspond to Curie temperature. The activation energy determined from the slopes in two temperature regions shows a large difference. It has been interpreted in terms of two conduction mechanisms i.e. ionic and electronic. The dielectric measurements were carried out at room temperature in the frequency range 10 kHz to 10 MHz. Dielectric constant shows a dispersion with frequency for all the samples. The dielectric loss decreases with frequency and does not show any peak with frequency for any of the samples.
报道了镁取代对锂铁氧体结构和电学性能的影响。采用标准干法制备了组分式为Li/sub (1-x//2)Mg/sub x/Fe/sub (5-x//2)O/sub 4/的样品,样品的x值范围为0.1 ~ 0.9。XRD结果表明,样品均为单相尖晶石,晶格常数随取代水平x的增加而增加,室温直流电阻率随取代水平x的增加而增加,这种变化可以从跳变机理和阳离子分布上解释。电阻率随温度变化的斜率与居里温度不一致。由两个温度区域的斜率确定的活化能差异较大。它已被解释为两种传导机制,即离子和电子。介电测量在室温下进行,频率范围为10 kHz至10 MHz。所有样品的介电常数随频率呈色散。介质损耗随频率的增加而减小,且不随频率的增加而出现峰值。
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引用次数: 0
Low-firing Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/-PbTiO/sub 3/-Pb/sub 5/Ge/sub 2/SiO/sub 11/ compositions for thick film capacitor applications 厚膜电容器用低燃烧Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/-PbTiO/sub 3/-Pb/sub 5/Ge/sub 2/SiO/sub 11/组合物
Y.D. Kim, S. M. Landin, I. Cornejo, M. J. Haun
Commercial ferroelectric thick films have been developed with high dielectric constants for capacitor applications. However, these compositions typically do not densify well in thick film form at characteristic firing temperatures (850/spl sim/900/spl deg/C), and thus require encapsulants to provide environmental stability. In this paper, ferroelectric compositions that can be fired at low temperatures with useful dielectric properties for thick film application are presented based on the combination of Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/ (PMN)-PbTiO/sub 3/ (PT) with Pb/sub 5/Ge/sub 2/SiO/sub 11/ (PGS). The PGS melts at /spl ap/724/spl deg/C, and causes liquid phase sintering of the PMN-PT at low temperatures. Thick film samples of PMN-PT with 30 weight percent PGS and 5 weight percent PbO additions densify to closed porosity fired at 850/spl deg/C for 10 minutes with a room temperature 1 KHz dielectric constant greater than 1500 and a dissipation factor less than 6%. Preliminary results indicate that these compositions are compatible with a commercial silver thick film conductor paste (DuPont 6160).
商用铁电厚膜具有高介电常数的电容器应用。然而,这些组合物在特征烧成温度(850/spl /900/spl℃)下通常不能很好地致密成厚膜,因此需要封装剂提供环境稳定性。基于Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/ (PMN)-PbTiO/sub 3/ (PT)与Pb/sub 5/Ge/sub 2/SiO/sub 11/ (PGS)的组合,提出了可在低温下烧制的具有良好介电性能的铁电组合物。PGS在/spl /724/spl℃下熔化,在低温下引起PMN-PT的液相烧结。PMN-PT的厚膜样品,添加30%重量百分比的PGS和5%重量百分比的PbO,在850/spl℃下加热10分钟,室温1 KHz介电常数大于1500,耗散系数小于6%。初步结果表明,这些组合物与商业银厚膜导体浆料(杜邦6160)兼容。
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引用次数: 0
Electric properties and domain structures in Ba(Ti,Sn)O/sub 3/ ceramics Ba(Ti,Sn)O/sub - 3/陶瓷的电性质和畴结构
K. Oh, K. Uchino, L. Cross
The Ba(Ti,Sn)O/sub 3/ ceramics are known as relaxor materials and they show very small hysteresis of field induced strains and field induced polarizations. An optical study was attempted to explain these dielectric properties. Domain structures and motions in Ba(Ti/sub 1-x/Sn/sub x/)O/sub 3/ (x=0, 0.05, 0.1, 0.13) ceramics were observed under an electric field at various temperatures using a high resolution CCD microscope system. Electrical properties such as field induced strains, dielectric properties and field induced polarization characteristics were also measured. The Ba(Ti/sub 1-x/ Sn/sub x/)O/sub 3/ ceramics showed a significant difference in domain structures and motions with changing composition. The domain structure became tiny and complex with increasing x. Changes of domain structures due to the phase transitions were also observed with varying temperature. The domain reorientation was easily induced with rising and falling electric field. The results of domain observations can explain the electrical properties well.
Ba(Ti,Sn)O/sub 3/陶瓷被称为弛豫材料,它们表现出非常小的场致应变和场致极化的滞后。一种光学研究试图解释这些介电性质。利用高分辨率CCD显微镜系统,观察了Ba(Ti/sub - 1-x/Sn/sub -x/)O/sub - 3/ (x= 0,0.05, 0.1, 0.13)陶瓷在不同温度电场作用下的畴结构和运动。测量了材料的场致应变、介电特性和场致极化特性等电学性能。Ba(Ti/sub - 1-x/ Sn/sub -x/)O/sub - 3/陶瓷的畴结构和运动随成分的变化有显著差异。随着x的增加,畴结构变得微小而复杂。随着温度的变化,畴结构也因相变而发生变化。电场的上升和下降容易引起畴重定向。畴观测结果可以很好地解释其电学性质。
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引用次数: 0
Field-induced piezoelectric materials for 100 kHz-10 MHz transducer applications 用于100 kHz-10 MHz换能器的场致压电材料
J. Fielding, S. Jang, T. Shrout
Several electrostrictive materials were investigated as candidates for high frequency transducer applications. Families investigated included (1-x)Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/-(x)PbTiO/sub 3/ and PLZT relaxors, and Srand Sn-substituted BaTiO/sub 3/ normal ferroelectrics. The field dependent dielectric, piezoelectric and elastic properties were characterized at frequencies between 100 kHz and 5 MHz. The large magnitude and E-field tunability of the electromechanical and elastic properties observed in several of the materials may present opportunities for several new transducer applications, such as biomedical imaging and non-destructive evaluation.
研究了几种电致伸缩材料作为高频换能器的候选材料。研究的家族包括(1-x)Pb(Mg/sub 1/3/Nb/sub 2/3/)O/sub 3/-(x)PbTiO/sub 3/和PLZT弛豫剂,以及sand sn取代的BaTiO/sub 3/正常铁电体。在100 kHz到5 MHz的频率范围内表征了材料的介电、压电和弹性特性。在几种材料中观察到的机电和弹性特性的大幅度和e场可调性可能为几种新的换能器应用提供机会,例如生物医学成像和非破坏性评估。
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引用次数: 1
High-efficiency ferro-piezoceramic PCR-type materials for various applications 用于各种用途的高效压电陶瓷材料
A. Dantsiger, O.N. Razumovskaja, L.A. Reznitchenko, L. D. Grineva, S. Dudkina, S.V. Gavrilyatchenko, N.V. Bergunova
The piezoceramic materials, possessing a wide variety of properties, have been designed. They may be used effectively in the various fields of science and technology.
已设计出具有多种性能的压电陶瓷材料。它们可以有效地应用于科学技术的各个领域。
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引用次数: 1
The structural phase transition in PZT ferroelectric films PZT铁电薄膜的结构相变
L. A. Sapozhnikov, I. Sem, I. Zakharchenko, E. Sviridov, V. Alyoshin, V. Dudkevich
The Pb(Zr,Ti,W,Cd)O/sub 3/ (PZT) films were deposited by rf-sputtering of stoichiometric targets in an oxygen atmosphere. Epitaxial films had a tetragonal unit cell at room temperature. The unit cell parameter vs temperature curve showed a kink at phase transition temperature characteristic of the bulk material. Polycrystalline films had a pseudocubic unit cell. In spite of the presence of a full set of ferroelectric properties no anomalies in the temperature dependence of the unit cell parameter at phase transition were observed. The only evidence of the presence of the structural phase transition to a cubic phase was the essential decrease of intensity of X-ray reflections with an odd sum of indices as in the epitaxial films. These reflection intensities are most sensitive to the displacement of Zr and Ti cations with respect to Pb on approaching the Curie point temperature.
采用红外溅射法制备了Pb(Zr,Ti,W,Cd)O/sub 3/ (PZT)薄膜。外延薄膜在室温下具有四边形的晶胞。单晶胞参数随温度变化曲线显示了块状材料相变温度特征的扭结。多晶薄膜具有伪晶胞。尽管存在一整套铁电性质,但在相变过程中,没有观察到单元胞参数的温度依赖性异常。结构相变到立方相存在的唯一证据是x射线反射强度的本质下降,在外延薄膜中指数为奇和。在接近居里点温度时,这些反射强度对Zr和Ti离子相对于Pb的位移最为敏感。
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引用次数: 0
期刊
Proceedings of 1994 IEEE International Symposium on Applications of Ferroelectrics
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