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Proceedings of 1994 IEEE International Symposium on Applications of Ferroelectrics最新文献

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PTCR characteristics in undoped barium titanate ceramics with core-shell type duplex microstructures 核壳型双相钛酸钡陶瓷的PTCR特性
M. Kuwabara, E. Matsuyama, S. Takahashi, H. Shimooka, Y. Urakawa
Undoped barium titanate ceramics exhibiting a distinct positive temperature coefficient of resistivity (PTCR) effect have been produced by sintering high-purity barium titanate powder compacts in the temperature range 1300-1400/spl deg/C in air. The formation of core-shell type duplex microstructures in the materials covered with a nearly full dense layer is responsible for this phenomenon, where undoped barium titanate ceramics (which are normally insulating) were converted to semiconductors and, moreover, exhibited distinct PTCR effects. The core-shell grain structure is described as a duplex microstructure consisting of a large-grained (/spl ap/50 /spl mu/m) semiconducting phase inside and a small-grained (<10 /spl mu/m) insulating phase outside.
在空气中,在1300 ~ 1400℃的温度范围内烧结高纯度钛酸钡粉末,制备出具有明显正电阻率效应的未掺杂钛酸钡陶瓷。这种现象的原因是在覆盖了几乎全致密层的材料中形成了核壳型双相微结构,其中未掺杂的钛酸钡陶瓷(通常是绝缘的)被转化为半导体,而且表现出明显的PTCR效应。核壳晶粒结构是由内部大晶粒(/spl ap/50 /spl mu/m)的半导体相和外部小晶粒(<10 /spl mu/m)的绝缘相组成的双相组织。
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引用次数: 5
Pyrotransistor-GaAs FET with a "pyroelectric wafer" gate 具有“热释电晶圆”栅极的热释晶体管-砷化镓场效应晶体管
Y. Poplavko, V. Moskalyuk, A.I. Timofeyev, Y. Prokopenko
The multifunction properties of GaAs and other III-V semi-insulating crystals can be expanded by the artificial decreasing of their electric response symmetry that could be transformed from piezo- into a pyroelectric class. An artificial pyroelectricity of III-V type semiconductors can form a basis for one-crystal pyroelectric sensors. The voltage sensitivity of GaAs (111)-cut corresponds to one of PZT pyroelectric ceramics so the GaAs wafer could be used as a thermal-to-electric transducer in a new microelectronic device named "pyrotransistor" that is uncooled far infrared detector based on MESFET technology.
通过人为降低GaAs和其他III-V型半绝缘晶体的电响应对称性,可以将其从压电型转变为热释电型,从而扩大其多功能特性。III-V型半导体的人工热释电可以作为单晶热释电传感器的基础。GaAs(111)晶片的电压灵敏度与PZT热释电陶瓷的电压灵敏度相当,因此GaAs晶片可以作为热电转换器用于新型微电子器件“热释电晶体管”中,该器件是基于MESFET技术的非冷却远红外探测器。
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引用次数: 1
Antiferroelectric to ferroelectric phase switching thin films in the lead zirconate stannate titanate solid solution system 锆酸铅-锡酸钛酸铅固溶体系中反铁电-铁电相开关薄膜
C. J. Gaskey, K. Udayakumar, H.D. Chen, L. Cross
Thin films of lead zirconate stannate titanate (PSZT) with slight additions of niobium and lanthanum have been prepared by the sol-gel, spin coat process. Antiferroelectric tetragonal and orthorhombic compositions have been evaluated on the criteria of P-E loop squareness, maximum polarization and field induced strain for the applications of energy storage and conversion in integrated devices. The orthorhombic compositions in both the niobium and lanthanum doped systems have shown square loop hysteretic behavior with large switchable polarizations (30-40 /spl mu/C/cm/sup 2/), and field-induced strains of 0.33% have been measured in the niobium doped system, thus both systems provide attractive possibilities for practical use.
采用溶胶-凝胶、旋涂法制备了少量添加铌和镧的锆锡钛酸铅(PSZT)薄膜。以P-E环的平方度、最大极化和场致应变为标准,评价了反铁电四方和正交组合物在集成器件中储能和转换应用的性能。铌和镧掺杂体系的正交组成均表现出方回线迟滞行为,具有较大的可切换极化(30-40 /spl mu/C/cm/sup 2/),并且在铌掺杂体系中测量到0.33%的场致应变,因此两种体系都具有实际应用的可能性。
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引用次数: 4
The domain mechanism of aging and degeneration of ferroelectric material 铁电材料时效与退化的畴机制
A. Sidorkin
The mechanism of interactions of domain boundaries in ferroelectric-ferroelastic crystals with different (uncharge, charge and elastic types) defects are investigated. The diffusion of defects to boundaries and the processes of the domain walls interacting with defects are studied. The values of domain contribution in dielectric permeability and the coercive field determined by the storage time and the number of switching cycles for the material with initial random defect distribution are calculated.
研究了具有不同缺陷(非荷、荷、弹性)的铁电-铁弹性晶体中畴边界相互作用的机理。研究了缺陷向边界扩散的过程以及畴壁与缺陷相互作用的过程。计算了初始缺陷随机分布材料的介电导率和矫顽力场的畴贡献值由存储时间和开关周期数决定。
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引用次数: 2
Ferroelectric properties of the mixed Aurivillius phase Bi/sub 7/Ti/sub 4/NbO/sub 21/ 混合Aurivillius相Bi/sub 7/Ti/sub 4/NbO/sub 21/的铁电性质
R. Maalal, M. Manier, J. Mercurio, B. Frit
Room and high temperature X-ray diffraction, DSC, dilatometric and dielectric measurements have shown that the mixed Aurivillius phase Bi/sub 7/Ti/sub 4/NbO/sub 21/ presents two characteristic temperatures. The first one-close to 675/spl deg/C-seems to be attributed to a ferroelectric-paraelectric transition connected with a structural change from orthorhombic to tetragonal. The second one, strongly observed by dielectric measurements concerns a possible ferroelastic-paraelastic phase transition.
室温和高温x射线衍射、DSC、膨胀和介电测量表明,混合Aurivillius相Bi/sub 7/Ti/sub 4/NbO/sub 21/呈现两个特征温度。第一个接近675/spl度/ c,似乎归因于铁电-准电转变,并伴有从正交向四方的结构变化。第二个是通过介电测量强烈观察到的,涉及可能的铁弹性-准弹性相变。
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引用次数: 1
Ferroelectric ceramics in the Na/sub 0.5/Bi/sub 0.5/TiO/sub 3/-K/sub 0.5/Bi/sub 0.5/TiO/sub 3/, Na/sub 0.5/Bi/sub 0.5/TiO/sub 3/-PbTiO/sub 3/ and K/sub 0.5/Bi/sub 0.5/TiO/sub 3/-PbTiO/sub 3/ systems
O. Elkechai, J. P. Mercurio
The study of the Na/sub 0.5/Bi/sub 0.5/TiO/sub 3/-K/sub 0.5/Bi/sub 0.5/TiO/sub 3/, Na/sub 0.5/Bi/sub 0.5/TiO/sub 3/-PbTiO/sub 3/ and K/sub 0.5/Bi/sub 0.5/TiO/sub 3/-PbTiO/sub 3/ systems was carried our using X-ray diffraction, DSC and dielectric measurements. The limits of the rhombohedral (Na/sub 0.5/Bi/sub 0.5/TiO/sub 3/-rich side) and orthorhombic (K/sub 0.5/Bi/sub 0.5/TiO/sub 3/, and PbTiO/sub 3/-rich side) solid solutions were determined, as well as the evolutions of their lattice parameters as a function of composition. Ceramic materials have been prepared by natural sintering (1090-1220/spl deg/C/0.5 h) of powders obtained by solid state reaction (900-1000/spl deg/C/20 h) of the corresponding oxides and carbonates. The dielectric permittivities of these materials have been measured in a wide frequency range between 20 and 800/spl deg/C. The results showed that they all are ferroelectric at room temperature and some of them exhibit a relaxer-type behaviour. Several specular compositions showed the best piezoelectric characteristics for this type of ceramic materials.
采用x射线衍射、DSC和介电测量对Na/sub 0.5/Bi/sub 0.5/TiO/sub 3/-K/sub 0.5/Bi/sub 0.5/TiO/sub 3/、Na/sub 0.5/Bi/sub 0.5/TiO/sub 3/-PbTiO/sub 3/和K/sub 0.5/Bi/sub 0.5/TiO/sub 3/-PbTiO/sub 3/体系进行了研究。确定了菱形固溶体(Na/sub 0.5/Bi/sub 0.5/TiO/sub 3/富侧)和正交体(K/sub 0.5/Bi/sub 0.5/TiO/sub 3/和PbTiO/sub 3/富侧)的极限,以及它们的晶格参数随组成的变化规律。将相应的氧化物和碳酸盐固相反应(900 ~ 1000/spl℃/20 h)得到的粉末自然烧结(1090 ~ 1220/spl℃/0.5 h)制备陶瓷材料。这些材料的介电常数已在20至800/spl度/C的宽频率范围内测量。结果表明,它们在室温下都是铁电的,其中一些表现出弛豫型行为。几种镜面组合物在这类陶瓷材料中表现出最好的压电特性。
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引用次数: 0
Fabrication of high density, fine-grained PZT ceramics using a post-sinter HIP treatment 采用烧结后HIP处理制备高密度、细粒PZT陶瓷
C. Millar, B. Andersen, E. Ringgard, W. Wolny, J. Ricote, L. Pardo
For many applications, such as medical array transducers, the frequency of use of ceramics is limited by their grain size and porosity content. Here, the microstructure of two commercial soft PZT ceramics (with /spl epsiv//sub r/ of 1800 and 4000) is optimised through a combined sintering and HIP study. The study includes the effect of sintering temperature (T=1100 to 1260/spl deg/C) and HIP conditions (T=1000/spl deg/C, P=50 to 200 MPa and t=1 to 4 h) on the microstructure and dielectric and piezoelectric properties. The properties obtained are compared with those of the conventionally prepared ceramics.
对于许多应用,如医疗阵列换能器,陶瓷的使用频率受到其晶粒尺寸和孔隙率含量的限制。在这里,通过结合烧结和HIP研究,优化了两种商用软PZT陶瓷(/spl epsiv//sub / r/为1800和4000)的微观结构。研究了烧结温度(T=1100 ~ 1260/spl℃)和热压条件(T=1000/spl℃,P=50 ~ 200 MPa, T=1 ~ 4 h)对材料微观结构和介电、压电性能的影响。所得的性能与常规制备的陶瓷进行了比较。
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引用次数: 6
The application of microwave ceramics 微波陶瓷的应用
T. Okawa, H. Utaki, T. Takada
Sumitomo Metal Industries, Ltd. (SMI) has developed and commercialized microwave dielectric ceramics with variable characteristics. We present and discuss the application of microwave ceramics at one of the ceramic components manufacturers. Microwave devices, such as co-axial dielectrics and the high frequency capacitor, are introduced. Further, a multi-layer dielectric resonator and a voltage control oscillator (VCO), which use the developed low firing materials, are also discussed.
住友金属工业有限公司(SMI)已经开发并商业化了具有可变特性的微波介电陶瓷。本文介绍并讨论了微波陶瓷在某陶瓷元件制造厂的应用。介绍了同轴介质和高频电容等微波器件。此外,还讨论了采用所研制的低燃材料的多层介质谐振器和电压控制振荡器(VCO)。
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引用次数: 2
Development of 1-3 PZT-polymer composite for low frequency acoustical applications 用于低频声学应用的1-3 pzt聚合物复合材料的研制
C. Richard, R. Ting, C. Audoly
Piezoelectric 1.3 composites of PZT-epoxy and PZT-polyurethane compositions were developed for investigations in low-frequency acoustic applications. Samples with different PZT volume fractions and varying PZT rod aspect ratios (from 4/spl times/4/spl times/9 to 1/spl times/1/spl times/9 mm/sup 3/) were fabricated by using the "dice and fill" method. Experimental measurement in the 3.3 mode in air was carried out by using a laser-Doppler vibrometry (LDV) technique. Strain profiles of the composite sample driven by a low-frequency ac electric field excitation was obtained. The result showed that PZT rod aspect ratio has a drastic effect on composite performance. A quasi-static model based on an isolated 1.3 composite unit-cell was developed to account for the stress transfer at the PZT-polymer interface. Analysis result showed that an aspect ratio of 20 or higher is necessary for low frequency sensing or projecting application of 1.3 piezocomposites. For use in the 3.3 mode, a soft polymer was shown to be preferred, since the longitudinal clamping of the PZT rod is greater for hard resins.
研制了pzt -环氧树脂和pzt -聚氨酯组成的压电1.3复合材料,用于低频声学应用研究。采用“切片填充法”制备了不同PZT体积分数和不同PZT棒长径比(从4/spl倍/4/spl倍/9到1/spl倍/1/spl倍/9 mm/sup 3/)的样品。采用激光多普勒测振仪(LDV)技术对空气中3.3模式下的振动进行了实验测量。得到了在低频交流电场激励下复合材料试样的应变曲线。结果表明,PZT棒长径比对复合材料性能有较大影响。建立了基于隔离的1.3复合材料单元格的准静态模型,以解释pzt -聚合物界面的应力传递。分析结果表明,1.3压电复合材料的低频传感或投影应用需要20或更高的宽高比。对于3.3模式的使用,软聚合物被证明是首选的,因为PZT棒的纵向夹紧对硬树脂更大。
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引用次数: 4
Ferroelectric ceramics and thin films for uncooled thermal imaging arrays 非冷却热成像阵列用铁电陶瓷和薄膜
A. Patel, P. Osbond, N. M. Shorrocks, R. Twiney, R. Whatmore, R. Watton
The pyroelectric effect in ferroelectric materials has long been used for the detection and imaging of long wavelength infra-red radiation. Lead scandium tantalate (PST) has been shown to have exceptionally good pyroelectric figures of merit, especially for small detectors of the type involved in the large arrays needed for uncooled solid state thermal imaging. This paper will review the properties of PST in relation to those of other materials which have been considered for use in this role and discuss how the inclusion of dopants can be used to modify the properties of the material in a way which would be beneficial to certain modes of detector operation, particularly with respect to the elimination of the requirement of cooling. Single element detectors and linear and two dimensional arrays have been made using PST. Their properties are compared with those of similar devices made using conventional pyroelectric ceramics. Ferroelectric thin films can now be made using sol-gel techniques whose figure-of-merit are comparable with those of bulk ceramic materials and the properties of these will be reviewed in relation to those of the ceramics discussed above and their potential for device applications discussed.
铁电材料中的热释电效应早已被用于长波红外辐射的探测和成像。钽酸铅钪(PST)已被证明具有非常好的热释电性能,特别是对于非冷却固态热成像所需的大型阵列中涉及的小型探测器。本文将回顾PST的性质,并将其与其他被考虑用于该角色的材料的性质进行比较,并讨论如何使用掺杂剂来改变材料的性质,从而有利于某些检测器操作模式,特别是在消除冷却要求方面。单元素探测器和线性和二维阵列已经使用PST。将其性能与使用传统热释电陶瓷制成的类似器件进行了比较。铁电薄膜现在可以使用溶胶-凝胶技术制作,其性能指标与大块陶瓷材料相当,这些特性将与上面讨论的陶瓷及其在器件应用中的潜力相关。
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引用次数: 3
期刊
Proceedings of 1994 IEEE International Symposium on Applications of Ferroelectrics
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