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Assessment of Blast Furnace Slags as a Potential Catalyst in Ozonation to Degrade Bezafibrate: Degradation Study and Kinetic Study via Non-Parametric Modeling 评估高炉渣作为臭氧降解贝扎贝特的潜在催化剂:通过非参数模型进行降解研究和动力学研究
IF 3.5 4区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-17 DOI: 10.3390/pr12091998
Alexandra Galina-Licea, Mariel Alfaro-Ponce, Isaac Chairez, Elizabeth Reyes, Arizbeth Perez-Martínez
This study investigates the effectiveness of blast furnace slags (BFSs) as catalysts in the ozonation process to degrade complex contaminants such as bezafibrate (BFZ) at different pH levels. The findings reveal that the presence of BFS enhances degradation efficiency, achieving a 10% improvement at pH 10 and a 30% improvement at pH 5.5 compared to simple ozonation. The highest degradation efficiency was observed in the Ozonation–BFS system at pH 10, with 90% decomposition of BFZ. These results were corroborated through ozone consumption analysis, BOD5 measurements, and the identification of oxalic acid as the final decomposition product. Due to the complexity of the reaction system, kinetic characterization was performed using non-parametric modeling based on differential neural networks. The model indicated that the observed reaction rate for BFZ degradation in the presence of ozone and BFS was 4.12 times higher at pH 5.0 and 1.08 times higher at pH 10.0 compared to simple ozonation. These results underscore the potential of using BFS in catalytic ozonation processes for the effective treatment of recalcitrant contaminants in wastewater.
本研究调查了高炉矿渣(BFSs)作为臭氧处理过程中的催化剂,在不同 pH 值下降解复杂污染物(如棉子纤酸(BFZ))的效果。研究结果表明,BFS 的存在提高了降解效率,与简单的臭氧处理相比,在 pH 值为 10 时,降解效率提高了 10%,在 pH 值为 5.5 时,降解效率提高了 30%。臭氧-BFS 系统在 pH 值为 10 时的降解效率最高,BFZ 的分解率达到 90%。臭氧消耗分析、BOD5 测量以及草酸作为最终分解产物的鉴定结果都证实了这些结果。由于反应系统的复杂性,使用基于微分神经网络的非参数模型对其进行了动力学表征。该模型表明,与简单的臭氧处理相比,在有臭氧和 BFS 存在的情况下,观察到的 BFZ 降解反应速率在 pH 值为 5.0 时要高出 4.12 倍,在 pH 值为 10.0 时要高出 1.08 倍。这些结果凸显了在催化臭氧过程中使用 BFS 有效处理废水中难降解污染物的潜力。
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引用次数: 0
A Numerical Simulation Study of the Dynamic Instability of Gas Swirling Flows in Cyclones 旋风中气体漩涡流的动态不稳定性数值模拟研究
IF 3.5 4区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-17 DOI: 10.3390/pr12092002
Liqiang Sun, Jiangfei Li, Ming Xie, Maoli Man, Jianqiang Zhao, Jianfei Song
The gas–phase flow field within a cyclone plays a critical role in the particle separation process. While previous research has primarily focused on the steady–state, time–averaged characteristics of this flow field, there has been limited investigation into its dynamic instability. This study seeks to address this gap by examining the dynamic instability of gas swirling flows in cyclones, offering new insights into their spatial and temporal dimensions. Numerical simulations were performed via large eddy simulation (LES) for the gas swirling flow in a reverse cyclone and tangential velocity was measured with a hot–wire anemometer (HWA). The model’s accuracy was validated against experimental data. The results demonstrate that the distributions of instantaneous tangential velocity and pressure exhibit spatial asymmetry and temporal instability across different sections of the cyclone. The dynamic instability of the gas swirling flow in the cyclone is the superposition of the spatial asymmetry and the temporal instability. These instabilities are more pronounced in the internal regions than the outer regions. Dynamic instability arises from the combined effects of rotational dynamics and wall curvature, leading to an eccentric rotation of the swirling center, particularly evident in the lower sections of the cyclone cone. This instability increases fluctuations in the instantaneous parameters, enhancing turbulence intensity and fine particle diffusion, and ultimately impairing both separation efficiency and particle size efficiency.
旋风分离器内的气相流场在颗粒分离过程中起着至关重要的作用。以往的研究主要集中在该流场的稳态、时间平均特性上,而对其动态不稳定性的研究却十分有限。本研究试图通过研究旋风中气体漩涡流的动态不稳定性来填补这一空白,从而对其空间和时间维度提出新的见解。通过大涡流模拟(LES)对反向气旋中的气体漩涡流进行了数值模拟,并用热线风速计(HWA)测量了切向速度。模型的准确性通过实验数据进行了验证。结果表明,瞬时切向速度和压力的分布在气旋的不同部分表现出空间不对称和时间不稳定性。气旋中气体漩涡流的动态不稳定性是空间不对称和时间不稳定性的叠加。这些不稳定性在内部区域比外部区域更为明显。动态不稳定性产生于旋转动力学和壁面曲率的共同作用,导致漩涡中心偏心旋转,这在气旋锥体的下部尤为明显。这种不稳定性增加了瞬时参数的波动,加剧了湍流强度和细颗粒扩散,最终损害了分离效率和粒度效率。
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引用次数: 0
Synergistically Enhanced Enzymatic Hydrolysis of Sugarcane Bagasse Mediated by a Recombinant Endo-Xylanase from Streptomyces ipomoeae 由异穗链霉菌重组内切木聚糖酶介导的甘蔗渣协同强化水解作用
IF 3.5 4区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-16 DOI: 10.3390/pr12091997
Zhong Li, Youqing Dong, Junli Liu, Liang Xian, Aixing Tang, Qingyun Li, Qunliang Li, Youyan Liu
Xylanase is commonly thought to effectively cooperate with cellulase to promote the bioconversion of lignocellulose. In this study, a novel xylanase, SipoEnXyn10A (Xyn10A), previously identified from Streptomyces ipomoeae, was employed to investigate its synergetic effects on sugarcane bagasse (SCB) transformation. It was shown that the relative increase in reducing sugars reached up to 65%, with enhanced yields of glucose and xylose by 78% and 50%, respectively, in the case of the replacement of cellulase with an equivalent amount of Xyn10A at an enzyme loading of 12.5%. The highest degrees of synergy (DS) for glucose and xylose could reach 2.57 and 1.84. Moreover, the hydrolysis rate increased evidently, and the reaction time to reach the same yield of glucose and xylose was shortened by 72 h and 96 h, respectively. This study on synergistic mechanisms demonstrated that the addition of Xyn10A could cause the destruction of substrates’ morphology and the dissolution of lignin components but could not change the accessibility and crystallinity of substrate cellulose. The joint effect of cellulase and xylanase during the hydrolysis process was thought to result in a synergistic mechanism.
一般认为,木聚糖酶能与纤维素酶有效合作,促进木质纤维素的生物转化。在本研究中,采用了一种新型木聚糖酶--SipoEnXyn10A(Xyn10A),研究其对甘蔗渣(SCB)转化的协同作用。结果表明,在酶载量为 12.5%、用等量 Xyn10A 替代纤维素酶的情况下,还原糖的相对增加率高达 65%,葡萄糖和木糖的产量分别提高了 78% 和 50%。葡萄糖和木糖的最高协同度(DS)分别达到 2.57 和 1.84。此外,水解速率明显提高,达到相同葡萄糖和木糖产量的反应时间分别缩短了 72 小时和 96 小时。这项关于协同作用机理的研究表明,Xyn10A 的加入会导致底物形态的破坏和木质素成分的溶解,但不会改变底物纤维素的可及性和结晶度。水解过程中纤维素酶和木聚糖酶的共同作用被认为是一种协同机制。
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引用次数: 0
Coordination of Renewable Energy Integration and Peak Shaving through Evolutionary Game Theory 通过进化博弈论协调可再生能源整合和削峰措施
IF 3.5 4区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-16 DOI: 10.3390/pr12091995
Jian Sun, Fan Wu, Mingming Shi, Xiaodong Yuan
This paper presents a novel approach to optimizing the coordination between renewable energy generation enterprises and power grid companies using evolutionary game theory. The research focuses on resolving conflicts and distributing benefits between these key stakeholders in the context of large-scale renewable energy integration. A theoretical model based on replicator dynamics is developed to simulate and analyze the evolutionary stable strategies of power generation enterprises and grid companies with particular emphasis on peak shaving services and electricity bidding. These simulations are based on theoretical models and do not incorporate real-world data directly, but they aim to replicate scenarios that reflect realistic behaviors within the electricity market. The model is validated through dynamic simulation under various scenarios, demonstrating that the final strategic choices of both thermal power and renewable energy enterprises tend to evolve towards either high-price or low-price bidding strategies, significantly influenced by initial system parameters. Additionally, this study explores how the introduction of peak shaving compensation affects the coordination process and stability of renewable energy integration, providing insights into improving grid efficiency and enhancing renewable energy adoption. Although the results are simulation-based, they are designed to offer practical recommendations for grid management and policy development, particularly for the integration of renewable energies such as wind power in competitive electricity markets. The findings suggest that effective government regulation, alongside well-designed compensation mechanisms, can help establish a balanced interest distribution between stakeholders. By offering a clear framework for analyzing the dynamics of renewable energy integration, this work provides valuable policy recommendations to promote cooperation and stability in electricity markets. This study contributes to the understanding of the complex interactions in the electricity market and offers practical solutions for enhancing the integration of renewable energy into the grid.
本文提出了一种利用进化博弈论优化可再生能源发电企业与电网公司之间协调的新方法。研究重点是在大规模可再生能源整合的背景下,解决这些关键利益相关者之间的冲突并分配利益。研究开发了一个基于复制器动力学的理论模型,用于模拟和分析发电企业和电网公司的进化稳定策略,尤其侧重于削峰服务和电力竞价。这些模拟基于理论模型,并不直接结合现实世界的数据,但旨在复制反映电力市场真实行为的情景。该模型通过各种情景下的动态模拟进行了验证,表明火电和可再生能源企业的最终战略选择都倾向于向高价或低价竞标战略演进,这在很大程度上受到初始系统参数的影响。此外,本研究还探讨了削峰补偿的引入如何影响可再生能源整合的协调过程和稳定性,为提高电网效率和促进可再生能源的采用提供了启示。虽然研究结果是基于仿真的,但其目的是为电网管理和政策制定提供实用建议,特别是针对竞争性电力市场中风电等可再生能源的整合。研究结果表明,有效的政府监管和精心设计的补偿机制有助于在利益相关者之间建立平衡的利益分配。通过提供分析可再生能源整合动态的清晰框架,这项研究为促进电力市场的合作与稳定提供了宝贵的政策建议。这项研究有助于人们理解电力市场中复杂的互动关系,并为加强可再生能源与电网的融合提供了切实可行的解决方案。
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引用次数: 0
Promoting Gas Extraction Technology with Screen Pipe for Long Borehole Protection in Soft Seam 在软煤层长钻孔保护中使用屏蔽管推广天然气开采技术
IF 3.5 4区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-16 DOI: 10.3390/pr12091996
Lin Wang, Dezhang Wang, Xiangjun Chen, Rui Min
The inherent properties of soft coal seams and their mechanical environment make long boreholes susceptible to issues like collapse, deformation, and blockages. These problems shorten the service life of the boreholes and hinder extraction efficiency. This paper tackles these challenges by analyzing the deformation and damage patterns of long boreholes in soft coal seams. It examines the stress distribution and deformation characteristics around both protected and unprotected boreholes at different burial depths. Additionally, it recommends using screen pipe protection technology to improve gas extraction and mining operations, as demonstrated in Changping Coal Mine. The results show that screen pipe protection substantially improves the stress distribution and deformation stability of coal seam boreholes. The flow attenuation coefficients of two boreholes equipped with protection technology decreased by 48% and 61%. After 50 days of extraction from boreholes with a protection rate exceeding 90%, gas concentration remained above 50%, which is 2.59 times higher than that of unprotected boreholes. This technology effectively addresses the frequent accidents, poor extraction performance, and inefficiency of long boreholes in soft coal seams, ensuring the mine’s safe and efficient production.
软煤层的固有特性及其机械环境使得长钻孔容易出现坍塌、变形和堵塞等问题。这些问题缩短了钻孔的使用寿命,阻碍了开采效率。本文通过分析软煤层中长钻孔的变形和破坏模式来应对这些挑战。本文研究了不同埋深的有保护和无保护钻孔周围的应力分布和变形特征。此外,它还建议使用筛管保护技术来改进瓦斯抽采和采矿作业,并在长坪煤矿进行了演示。结果表明,筛管保护技术大大改善了煤层钻孔的应力分布和变形稳定性。采用保护技术的两个钻孔的流量衰减系数分别降低了 48% 和 61%。保护率超过 90% 的钻孔抽采 50 天后,瓦斯浓度仍保持在 50% 以上,是未保护钻孔的 2.59 倍。该技术有效解决了软煤层长钻孔事故频发、抽采效果差、效率低等问题,确保了矿井的安全高效生产。
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引用次数: 0
Computational Fluid Dynamics (CFD) Investigation of NREL Phase VI Wind Turbine Performance Using Various Turbulence Models 使用各种湍流模型对 NREL 第六阶段风力涡轮机性能进行计算流体动力学 (CFD) 研究
IF 3.5 4区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-16 DOI: 10.3390/pr12091994
Abobakr Al-Ttowi, Akmal Nizam Mohammed, Sami Al-Alimi, Wenbin Zhou, Yazid Saif, Iman Fitri Ismail
This study presents a detailed computational fluid dynamics (CFD) investigation into the aerodynamic performance of the NREL Phase VI wind turbine, focusing on torque and power generation under different turbulence models. The primary objective was to analyse the effect of various turbulence models and their responses in wind turbine torque generation. Furthermore, it also investigates the distance effect on wind velocity deficit. The research utilizes 2D and 3D simulations of the S809 airfoil and the full rotor, examining the predictive capabilities of the k-epsilon, k-omega, and k-omega SST turbulence models. The study incorporates both experimental validation and wake analysis using the Gaussian wake model to assess wind velocity deficits. Simulations were conducted for a wind speed range of (6–10 m/s), with results indicating that the k-epsilon model provided the closest match to experimental data, particularly at higher wind speeds within the targeted range. Even though k-epsilon results had better agreement when validated with experimental data, theoretically k-omega (SST) should perform better as it combines k-epsilon and k-omega advantages in predicting the flow regardless of its farness from the wall. However, in simulations using the k-omega (SST), the separation of flow and the shear stress transients were only visible at wind speeds of 10 m/s or higher. Wake effects, on the other hand, were found to cause significant velocity deficits behind the turbine, following an exponential decay pattern. The findings offer valuable insights into improving wind turbine performance through turbulence model selection and wake impact analysis, providing practical guidelines for future wind energy optimizations.
本研究对 NREL 第六阶段风力涡轮机的空气动力性能进行了详细的计算流体动力学 (CFD) 调查,重点是不同湍流模型下的扭矩和发电量。主要目的是分析各种湍流模型及其对风力涡轮机扭矩产生的影响。此外,它还研究了距离对风速不足的影响。研究利用 S809 机翼和全转子的二维和三维模拟,检验了 k-epsilon、k-omega 和 k-omega SST 湍流模型的预测能力。研究结合了实验验证和使用高斯尾流模型进行的尾流分析,以评估风速缺陷。模拟的风速范围为(6-10 米/秒),结果表明 k-epsilon 模型与实验数据的匹配度最高,尤其是在目标范围内的较高风速下。尽管 k-epsilon 的结果与实验数据的一致性更好,但从理论上讲,k-omega(SST)的性能应该更好,因为它结合了 k-epsilon 和 k-omega 的优势,可以预测无论距离墙壁多远的气流。然而,在使用 k-omega(SST)的模拟中,只有在风速达到或超过 10 米/秒时,才能看到气流分离和剪应力瞬变。另一方面,研究发现,风浪效应会在涡轮机后方造成显著的速度损失,并呈现指数衰减模式。研究结果为通过湍流模型选择和尾流影响分析提高风力涡轮机性能提供了宝贵的见解,为未来风能优化提供了实用指南。
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引用次数: 0
Optimization of Recovery of Nutrients from Pig Manure Slurry through Combined Microbial Fuel Cell and Microalgae Treatment 通过微生物燃料电池和微藻联合处理优化猪粪泥浆中营养物质的回收
IF 3.5 4区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-15 DOI: 10.3390/pr12091989
Adrián Hernández-Fernández, Eduardo Iniesta-López, Ana Isabel Hernández Baños, Yolanda Garrido, Ana Sánchez Zurano, Francisco J. Hernández-Fernández, Antonia Pérez De los Ríos
Microbial fuel cells (MFCs) and microalgae–bacteria consortia represent two renewable and promising technologies of growing interest that enable wastewater treatment while obtaining high-value-added products. This study integrates MFCs and microalgae production systems to treat animal slurry, aiming to remove and recover organic and inorganic components while generating energy and producing biomass. The MFCs effectively eliminated Chemical Oxygen Demand (COD), organic nitrogen, and a portion of the suspended solids, achieving a maximum voltage of 195 mV and a power density of 87.03 mW·m−2. After pre-treatment with MFCs, the slurry was diluted to concentrations of 10%, 50%, and 100% and treated with microalgae–bacteria consortia. The results showed a biomass production of 0.51 g·L−1 and a productivity of 0.04 g·L−1·day−1 in the culture fed with 10% slurry, with significant removal efficiencies: 40.71% for COD, 97.76% for N-NH4+, 39.66% for N-NO2−, 47.37% for N-NO3−, and 94.37% for P-PO4−3. The combination of both technologies allowed for obtaining a properly purified slurry and the recovery of nutrients in the form of bioelectricity and high-value biomass. Increasing the concentration of animal slurry to be treated is essential to optimize and scale both technologies.
微生物燃料电池(MFCs)和微藻-细菌联合体是两种可再生且前景广阔的技术,它们在处理废水的同时还能获得高附加值的产品,因此受到越来越多的关注。本研究整合了 MFC 和微藻生产系统来处理动物粪便,旨在去除和回收有机和无机成分,同时产生能量和生物质。MFCs 能有效去除化学需氧量(COD)、有机氮和部分悬浮固体,最大电压为 195 mV,功率密度为 87.03 mW-m-2。在使用 MFC 进行预处理后,将泥浆稀释到 10% 、50% 和 100% 的浓度,并使用微藻-细菌联合体进行处理。结果表明,在以 10%泥浆为原料的培养液中,生物量产量为 0.51 g-L-1,生产率为 0.04 g-L-1-天-1,去除率显著提高:COD 去除率为 40.71%,N-NH4+ 去除率为 97.76%,N-NO2- 去除率为 39.66%,N-NO3- 去除率为 47.37%,P-PO4-3 去除率为 94.37%。将这两种技术结合起来,可以获得适当净化的泥浆,并以生物电和高价值生物质的形式回收养分。提高待处理动物泥浆的浓度对于优化和推广这两种技术至关重要。
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引用次数: 0
Research on Hotspots and Evolutionary Trends in Coal Mine Gas Prevention 煤矿瓦斯防治热点与演化趋势研究
IF 3.5 4区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-15 DOI: 10.3390/pr12091993
Chunguang Zhao, Peng Gao, Jinlin Ruan, Yang Pu, Yuan Sun, Xiaoyang Cheng, Yu Sun
Mine gas accidents have received widespread attention at home and abroad, because mine gas accidents often cause casualties and property losses once they occur. This study was conducted in order to have a more comprehensive understanding of the research status of and research hotspots in coal mine gas management at home and abroad, and to provide references for relevant researchers’ studies and literature searches. Using the Web of Science (WOS) core database as the data source, this paper analyzed the data from the period of 2000–2023 under the headings of “gas governance”, “Gas Control Technology”, “Pre-mining gas methods in coal mines”, “Methods of Gas Mining in Coal Mines”, “Post-mining gas”, and “Post-mining gas methods in coal mines”. “Methods in Coal Mines”, “Methods of Gas Mining in Coal Mines”, and “Post-mining Gas Methods in Coal Mines” were searched, and the CiteSpace tool was utilized to provide a multi-dimensional visual presentation of the literature, including authors, the number of journals issued, countries of issue, keywords, etc., in order to explore the research hotspots in this field. The analysis results show the following: the development process in the field of gas prevention and control is mainly divided into the three stages of initial exploration, steady development, and explosive surge; China, Australia, and the United States are the top three countries in terms of the number of articles published, and they have a greater influence in the field, but there is a closer connection between the regions in Europe; a certain group size has been formed by the researchers and research institutes in this field, the China University of Mining and Technology is more active in this field, ranking as the first in terms of the number of articles issued, and it has a cooperative relationship with many universities; Kai Wang and Enyuan Wang are the core authors in this field, while C. Ozgen Karacan also has a large body of research in the field, and his research results are widely recognized; the main journals issued in this field are Fuel and Energy Policy, while other journals have been frequently cited, and these journals have an important role in the field. In these journals, “Coal mine methane: A review of capture and utilization practices with benefits to mining safety and to greenhouse gas reduction” is one of the most important articles in the field. Thin coal seams, coal mining workings, and coal and gas protrusion are current research hotspots.
煤矿瓦斯事故受到国内外的广泛关注,因为煤矿瓦斯事故一旦发生往往会造成人员伤亡和财产损失。为了更全面地了解国内外煤矿瓦斯治理的研究现状和研究热点,为相关研究人员的研究和文献检索提供参考,特开展本研究。本文以 Web of Science(WOS)核心数据库为数据源,按照 "瓦斯治理"、"瓦斯治理技术"、"煤矿瓦斯开采前方法"、"煤矿瓦斯开采方法"、"瓦斯开采后"、"煤矿瓦斯开采后方法 "等标题,对 2000-2023 年期间的数据进行了分析。"煤矿开采方法"、"煤矿瓦斯开采方法 "和 "煤矿开采后瓦斯方法 "进行了检索,并利用 CiteSpace 工具对文献进行了多维度的直观展示,包括作者、期刊发行数量、期刊发行国家、关键词等,以探索该领域的研究热点。分析结果显示如下:瓦斯防治领域的发展进程主要分为初步探索、稳步发展和爆发式激增三个阶段;中国、澳大利亚和美国是发文量排名前三位的国家,在该领域的影响力较大,但欧洲地区之间的联系较为密切;该领域的研究人员和研究机构已经形成了一定的群体规模,中国矿业大学在该领域较为活跃,发文量排名第一,并与多所高校有合作关系;王凯和王恩远是该领域的核心作者,C.Ozgen Karacan 在该领域也有大量研究,其研究成果得到广泛认可;该领域的主要期刊为《燃料》和《能源政策》,其他期刊也经常被引用,这些期刊在该领域具有重要作用。在这些期刊中,《煤矿甲烷:对采矿安全和温室气体减排有益的捕获和利用实践综述》是该领域最重要的文章之一。薄煤层、采煤工作面、煤与瓦斯突出是当前的研究热点。
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引用次数: 0
The Role of Different Roasting Temperatures on the Physico-Chemical Properties, Phenolic Compounds, Fatty Acid and Mineral Contents of Carob (Ceratonia siliqua L.) Fruit Powder 不同烘焙温度对角豆树(Ceratonia siliqua L.)果粉的理化性质、酚类化合物、脂肪酸和矿物质含量的影响
IF 3.5 4区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-15 DOI: 10.3390/pr12091990
Isam A. Mohamed Ahmed, Fahad Y. AlJuhaimi, Mehmet Musa Özcan, Nurhan Uslu, Emad Karrar
In this study, the role of different roasting temperatures on oil amount, total phenolic contents, total flavonoid quantities, antioxidant capacity, polyphenol, fatty acid and mineral profiles of roasted-carob fruit powders was revealed. The oil and protein amounts of the carob powders were specified to be between 0.40 (90 °C) and 0.85% (control) to 8.40 (120 °C) and 10.27% (control), respectively. Total phenolic and flavonoid quantities of the raw (control—unroasted) and roasted carob powders were defined to be between 781.16 (control) and 903.07 mg GAE/100 g (150 °C) to 663.81 (control) and 1141.90 mg/100 g (150 °C), respectively. In addition, antioxidant activities of the carob powders were measured to be between 9.27 (150 °C) and 10.30 mmoL/kg (control). Gallic acid and 3,4-dihydroxybenzoic acid amounts of the carob powders were specified to be between 45.16 (control) and 120.66 (150 °C) to 7.06 (control) and 20.46 mg/100 g (150 °C), respectively. Palmitic, oleic and linoleic acids were the key fatty acids of carob oils. It is thought that the fatty acid compositions of carob powder oil, which is generally subjected to heat treatment, are negatively affected by high temperatures. Especially, the linoleic and linolenic acid amounts of the oil samples decreased significantly after 90 °C. The highest element was potassium, followed by Ca, P, Mg, S, Fe, Na, Pb, Cu, Zn B and Mn, in descending order.
本研究揭示了不同烘焙温度对烘焙角豆树果粉的油量、总酚含量、总黄酮含量、抗氧化能力、多酚、脂肪酸和矿物质含量的影响。角豆树果粉的油分和蛋白质含量分别为 0.40(90 °C)和 0.85%(对照组)到 8.40(120 °C)和 10.27%(对照组)。生(对照组-未焙烧)和焙烧角豆树粉的总酚和类黄酮含量分别为 781.16(对照组)和 903.07 毫克 GAE/100 克(150 °C)至 663.81(对照组)和 1141.90 毫克/100 克(150 °C)。此外,还测出角豆树粉的抗氧化活性介于 9.27 毫摩尔/千克(150 °C)和 10.30 毫摩尔/千克(对照组)之间。角豆树粉中的没食子酸和 3,4-二羟基苯甲酸含量分别为 45.16(对照组)和 120.66(150 °C)至 7.06(对照组)和 20.46 毫克/100 克(150 °C)。棕榈酸、油酸和亚油酸是角豆油的主要脂肪酸。一般认为,经过热处理的角豆树粉油的脂肪酸组成会受到高温的负面影响。特别是在 90 °C 之后,油样中的亚油酸和亚麻酸含量明显下降。元素含量最高的是钾,其次依次是钙、磷、镁、硫、铁、鈉、铅、铜、锌、硼和锰。
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引用次数: 0
Land Suitability Analysis for Green Ammonia Unit Implementation in Morocco Using the Geographical Information System–Analytic Hierarchy Process Approach 利用地理信息系统-层次分析法分析摩洛哥实施绿色氨装置的土地适宜性
IF 3.5 4区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-15 DOI: 10.3390/pr12091991
Abir Dahani, Chouaib Benqlilou, Markus Holz, Cornelia Scott
Morocco contains one of the greatest phosphate deposits and is the second-largest international phosphate fertilizer producer. However, it heavily relies on imported grey ammonia. To reduce this dependency, a paradigm shift is required toward local green ammonia production to strengthen the fertilizer industry. The purpose of the study is to identify the most promising locations in Morocco for hosting a green ammonia unit through a land suitability analysis. This was carried out using multi-criteria decision-making (MCDM) and geographical information systems (GIS). Eight relevant criteria were considered, based on carefully studying the relevant literature and consultation with renewable energy experts and professionals. The land suitability analysis revealed high suitability locations and five sites were selected from the regions of Dakhla, Laayoune, Boujdour, and Tarfaya. These locations were introduced to Hybrid Optimization of Multiple Electric Renewables (HOMER) software 3.16.2 for simulation. The simulation findings showed that the levelized cost of hydrogen (LCOH) ranges from 1.67 USD/kg to 1.82 USD/kg, with the lowest LCOH at Dakhla. The corresponding levelized cost of ammonia (LCOA) ranges from 646 USD/t to 687 USD/t. Dakhla was identified as the location with the lowest LCOA, accounting for 646 USD/t. The outcomes showed a similar trend compared to other studies (Saudi Arabia, Jordan, Iran). Considering improvements in the electrolyzer’s efficiency and cost, a technical and financial sensitivity analysis was conducted, identifying highly promising LCOA in Morocco, reaching 548 USD/t.
摩洛哥是磷酸盐储量最大的国家之一,也是国际第二大磷肥生产国。然而,摩洛哥严重依赖进口灰氨。为了减少这种依赖,需要转变模式,在当地生产绿色合成氨,以加强化肥产业。本研究的目的是通过土地适宜性分析,确定摩洛哥最有希望建立绿色合成氨装置的地点。这项工作是利用多标准决策(MCDM)和地理信息系统(GIS)进行的。在仔细研究相关文献并咨询可再生能源专家和专业人士的基础上,考虑了八项相关标准。土地适宜性分析表明,这些地点的适宜性较高,因此从达赫拉、阿尤恩、布吉杜尔和塔尔法亚地区选出了五个地点。这些地点被引入多种电力可再生能源混合优化(HOMER)软件 3.16.2 进行模拟。模拟结果显示,氢气的平准化成本(LCOH)从 1.67 美元/千克到 1.82 美元/千克不等,达赫拉的 LCOH 最低。相应的氨的平准化成本(LCOA)从 646 美元/吨到 687 美元/吨不等。达赫拉被确定为 LCOA 最低的地点,为 646 美元/吨。与其他研究(沙特阿拉伯、约旦、伊朗)相比,结果显示出相似的趋势。考虑到电解槽效率和成本的提高,进行了技术和财务敏感性分析,确定摩洛哥的 LCOA 极具潜力,达到 548 美元/吨。
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