首页 > 最新文献

Processes最新文献

英文 中文
Identification of Flow Pressure-Driven Leakage Zones Using Improved EDNN-PP-LCNetV2 with Deep Learning Framework in Water Distribution System 在配水系统中使用带深度学习框架的改进型 EDNN-PP-LCNetV2 识别流量压力驱动的渗漏区
IF 3.5 4区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-15 DOI: 10.3390/pr12091992
Bo Dong, Shihu Shu, Dengxin Li
This study introduces a novel deep learning framework for detecting leakage in water distribution systems (WDSs). The key innovation lies in a two-step process: First, the WDS is partitioned using a K-means clustering algorithm based on pressure sensitivity analysis. Then, an encoder–decoder neural network (EDNN) model is employed to extract and process the pressure and flow sensitivities. The core of the framework is the PP-LCNetV2 architecture that ensures the model’s lightweight, which is optimized for CPU devices. This combination ensures rapid, accurate leakage detection. Three cases are employed to evaluate the method. By applying data augmentation techniques, including the demand and measurement noises, the framework demonstrates robustness across different noise levels. Compared with other methods, the results show this method can efficiently detect over 90% of leakage across different operating conditions while maintaining a higher recognition of the magnitude of leakages. This research offers a significant improvement in computational efficiency and detection accuracy over existing approaches.
本研究介绍了一种新型深度学习框架,用于检测配水系统(WDS)的渗漏情况。其关键创新在于分两步进行:首先,使用基于压力敏感性分析的 K-means 聚类算法对 WDS 进行分区。然后,采用编码器-解码器神经网络(EDNN)模型来提取和处理压力和流量敏感性。该框架的核心是 PP-LCNetV2 架构,它确保了模型的轻量级,并针对 CPU 设备进行了优化。这种组合确保了快速、准确的泄漏检测。我们采用了三种情况来评估该方法。通过应用包括需求噪声和测量噪声在内的数据增强技术,该框架在不同的噪声水平下都表现出了鲁棒性。与其他方法相比,结果表明该方法能在不同运行条件下有效检测出 90% 以上的泄漏,同时对泄漏量保持较高的识别率。与现有方法相比,这项研究在计算效率和检测精度方面都有显著提高。
{"title":"Identification of Flow Pressure-Driven Leakage Zones Using Improved EDNN-PP-LCNetV2 with Deep Learning Framework in Water Distribution System","authors":"Bo Dong, Shihu Shu, Dengxin Li","doi":"10.3390/pr12091992","DOIUrl":"https://doi.org/10.3390/pr12091992","url":null,"abstract":"This study introduces a novel deep learning framework for detecting leakage in water distribution systems (WDSs). The key innovation lies in a two-step process: First, the WDS is partitioned using a K-means clustering algorithm based on pressure sensitivity analysis. Then, an encoder–decoder neural network (EDNN) model is employed to extract and process the pressure and flow sensitivities. The core of the framework is the PP-LCNetV2 architecture that ensures the model’s lightweight, which is optimized for CPU devices. This combination ensures rapid, accurate leakage detection. Three cases are employed to evaluate the method. By applying data augmentation techniques, including the demand and measurement noises, the framework demonstrates robustness across different noise levels. Compared with other methods, the results show this method can efficiently detect over 90% of leakage across different operating conditions while maintaining a higher recognition of the magnitude of leakages. This research offers a significant improvement in computational efficiency and detection accuracy over existing approaches.","PeriodicalId":20597,"journal":{"name":"Processes","volume":"15 1","pages":""},"PeriodicalIF":3.5,"publicationDate":"2024-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142254303","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Influence of Pre-Lift Gate Opening on the Internal and External Flow Characteristics During the Startup Process of an Axial Flow Pump 轴流泵启动过程中预提升闸门开度对内外流量特性的影响
IF 3.5 4区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-14 DOI: 10.3390/pr12091984
You Fu, Lingling Deng
This paper focuses on a vertical axial flow pump and employs a 1D-3D coupling method to investigate the effects of different gate pre-opening angles on the internal and external flow characteristics of the axial flow pump during startup. Through comparative analysis, the following conclusions are drawn: In the study, a fully open gate is defined as 1, while a fully closed gate is defined as 0. When starting the axial flow pump with different valve pre-opening degrees, backflow occurs within the first 20 s of startup, and the backflow rate inside the pump gradually increases with the increase in the valve pre-opening degree. At a valve pre-opening degree of 0.6, the maximum backflow rate inside the pump reaches 5.89% of the rated flow rate. When starting the pump with the valve fully open, the maximum backflow rate reaches 10.98% of the rated flow rate, and the efficiency is affected by the backflow rate. The valve pre-opening degree has little impact on the axial force acting on the impeller during startup. When starting with a valve pre-opening degree of 0.6, the internal pressure difference in the pump is minimized. Within the first 20 s of startup, the internal pressure difference in the impeller is 28.96% higher and the flow velocity is 14.62% higher with valve pre-opening degrees of 0.8 and 1.0 compared to a 0.6 degree opening. During the initial stage of pump startup, with valve pre-opening degrees of 0.8 and 1.0, the pressure fluctuation amplitude inside the pump is minimal, with maximum relative amplitudes of only 0.621 and 0.525, which are 41.00% and 28.51% lower than the maximum amplitudes at 0 and 0.2 degrees, respectively. In summary, the peak pressure inside the pump is minimized when the valve pre-opening degree is around 0.8, while the pressure difference and flow velocity are relatively lower at a pre-opening degree of 0.6. It is recommended to start the pump with a valve pre-opening degree of around 0.6 to 0.8.
本文以立式轴流泵为研究对象,采用一维三维耦合方法研究了不同闸门预开角度对轴流泵启动时内外流量特性的影响。通过对比分析,得出以下结论:在研究中,全开的闸门定义为 1,全闭的闸门定义为 0。当启动不同阀门预开度的轴流泵时,在启动的前 20 秒内会出现回流,并且泵内的回流率随着阀门预开度的增加而逐渐增大。当阀门预开度为 0.6 时,泵内的最大回流率达到额定流量的 5.89%。在阀门全开的情况下启动泵,最大回流率达到额定流量的 10.98%,效率受到回流率的影响。阀门预开度对启动时作用在叶轮上的轴向力影响很小。当阀门预开度为 0.6 时,泵内压差最小。在启动的最初 20 秒内,阀门预开度为 0.8 和 1.0 时,叶轮的内部压差比 0.6 开度时高出 28.96%,流速高出 14.62%。在泵启动的初始阶段,阀门预开度为 0.8 度和 1.0 度时,泵内压力波动振幅很小,最大相对振幅仅为 0.621 和 0.525,分别比 0 度和 0.2 度时的最大振幅低 41.00% 和 28.51%。总之,当阀门预开度在 0.8 左右时,泵内的峰值压力最小,而当阀门预开度为 0.6 时,压差和流速相对较低。建议在阀门预开度约为 0.6 至 0.8 时启动泵。
{"title":"The Influence of Pre-Lift Gate Opening on the Internal and External Flow Characteristics During the Startup Process of an Axial Flow Pump","authors":"You Fu, Lingling Deng","doi":"10.3390/pr12091984","DOIUrl":"https://doi.org/10.3390/pr12091984","url":null,"abstract":"This paper focuses on a vertical axial flow pump and employs a 1D-3D coupling method to investigate the effects of different gate pre-opening angles on the internal and external flow characteristics of the axial flow pump during startup. Through comparative analysis, the following conclusions are drawn: In the study, a fully open gate is defined as 1, while a fully closed gate is defined as 0. When starting the axial flow pump with different valve pre-opening degrees, backflow occurs within the first 20 s of startup, and the backflow rate inside the pump gradually increases with the increase in the valve pre-opening degree. At a valve pre-opening degree of 0.6, the maximum backflow rate inside the pump reaches 5.89% of the rated flow rate. When starting the pump with the valve fully open, the maximum backflow rate reaches 10.98% of the rated flow rate, and the efficiency is affected by the backflow rate. The valve pre-opening degree has little impact on the axial force acting on the impeller during startup. When starting with a valve pre-opening degree of 0.6, the internal pressure difference in the pump is minimized. Within the first 20 s of startup, the internal pressure difference in the impeller is 28.96% higher and the flow velocity is 14.62% higher with valve pre-opening degrees of 0.8 and 1.0 compared to a 0.6 degree opening. During the initial stage of pump startup, with valve pre-opening degrees of 0.8 and 1.0, the pressure fluctuation amplitude inside the pump is minimal, with maximum relative amplitudes of only 0.621 and 0.525, which are 41.00% and 28.51% lower than the maximum amplitudes at 0 and 0.2 degrees, respectively. In summary, the peak pressure inside the pump is minimized when the valve pre-opening degree is around 0.8, while the pressure difference and flow velocity are relatively lower at a pre-opening degree of 0.6. It is recommended to start the pump with a valve pre-opening degree of around 0.6 to 0.8.","PeriodicalId":20597,"journal":{"name":"Processes","volume":"10 1","pages":""},"PeriodicalIF":3.5,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142254306","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Novel Nonsingular Fast Terminal Sliding Mode Control with Sliding Mode Disturbance Observer for Permanent Magnet Synchronous Motor Servo Control 用于永磁同步电机伺服控制的新型非奇异快速终端滑模控制与滑模扰动观测器
IF 3.5 4区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-14 DOI: 10.3390/pr12091986
Difen Shi, Kai Bodemann, Yao Wang, Changliang Xu, Lulu Liu, Chungui Feng
This article proposes a novel nonsingular fast terminal sliding mode control (N-NFTSMC) with a sliding mode disturbance observer (SDOB) for permanent magnet synchronous motor (PMSM) servo control. Firstly, to reduce the chattering issue, a new sliding mode reaching law (NSRL) is proposed for the N-NFTSMC. Secondly, to further improve the dynamic tracking accuracy, we introduce a sliding disturbance observer to estimate unknown disturbances for feedforward compensation. Comparative simulations via Matlab/Simulink 2018 are conducted using the traditional NFTSMC and N-NFTSMC; the step simulation results show that the chattering phenomenon was suppressed well via the N-NFTSMC scheme. The sine wave tracking simulation proves that the N-NFTSMC has better dynamic tracking performance when compared with traditional NFTSMC. Finally, we carry out experiments to validate that the N-NFTSMC adequately suppresses the chattering issue and possesses better anti-disturbance performance.
本文针对永磁同步电机(PMSM)的伺服控制,提出了一种带有滑动模态扰动观测器(SDOB)的新型非正弦快速终端滑动模态控制(N-NFTSMC)。首先,为了减少颤振问题,为 N-NFTSMC 提出了一种新的滑动模态达到律(NSRL)。其次,为了进一步提高动态跟踪精度,我们引入了滑动干扰观测器来估计未知干扰,以便进行前馈补偿。通过 Matlab/Simulink 2018 进行了传统 NFTSMC 和 N-NFTSMC 的比较仿真;阶跃仿真结果表明,N-NFTSMC 方案很好地抑制了颤振现象。正弦波跟踪仿真证明,与传统的 NFTSMC 相比,N-NFTSMC 具有更好的动态跟踪性能。最后,我们通过实验验证了 N-NFTSMC 能够充分抑制颤振问题,并具有更好的抗干扰性能。
{"title":"A Novel Nonsingular Fast Terminal Sliding Mode Control with Sliding Mode Disturbance Observer for Permanent Magnet Synchronous Motor Servo Control","authors":"Difen Shi, Kai Bodemann, Yao Wang, Changliang Xu, Lulu Liu, Chungui Feng","doi":"10.3390/pr12091986","DOIUrl":"https://doi.org/10.3390/pr12091986","url":null,"abstract":"This article proposes a novel nonsingular fast terminal sliding mode control (N-NFTSMC) with a sliding mode disturbance observer (SDOB) for permanent magnet synchronous motor (PMSM) servo control. Firstly, to reduce the chattering issue, a new sliding mode reaching law (NSRL) is proposed for the N-NFTSMC. Secondly, to further improve the dynamic tracking accuracy, we introduce a sliding disturbance observer to estimate unknown disturbances for feedforward compensation. Comparative simulations via Matlab/Simulink 2018 are conducted using the traditional NFTSMC and N-NFTSMC; the step simulation results show that the chattering phenomenon was suppressed well via the N-NFTSMC scheme. The sine wave tracking simulation proves that the N-NFTSMC has better dynamic tracking performance when compared with traditional NFTSMC. Finally, we carry out experiments to validate that the N-NFTSMC adequately suppresses the chattering issue and possesses better anti-disturbance performance.","PeriodicalId":20597,"journal":{"name":"Processes","volume":"101 1","pages":""},"PeriodicalIF":3.5,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142254308","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Design Optimization and Experimentation of Triple-Head Gradually Reducing Spiral Precision Fertilizer Apparatus 三头渐减螺旋精密施肥器的优化设计与实验
IF 3.5 4区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-14 DOI: 10.3390/pr12091988
Guoqiang Dun, Quanbao Sheng, Haitian Sun, Xinxin Ji, Zhenzhen Yu, Hongxuan Wang, Xingpeng Wu, Yuhan Wei, Chaoxia Zhang, Shang Gao, Hailiang Li
In order to solve the problems of existing spiral fertilizer apparatuses, such as the variation in cavity filling rate with rotational speed, fluctuation of fertilizer discharge flow, and inability to discharge fertilizer precisely, a triple-head gradually reducing spiral fertilizer apparatus is designed, which gradually compresses fertilizer particles through the triple-head reducing fertilizer spiral structure to achieve complete cavity filling and uniform fertilizer discharge. The main factors that affect the particle motion state and the structural size of the spiral fertilizer through theoretical analysis are determined, and its theoretical fertilizer discharge amount and rotational speed are calculated. Using EDEM (Discrete Element Method Software 2022) to establish a simulation model of a single-head gradually reducing fertilizer apparatus, the spiral lead reduction percentage x1, spiral diameter reduction percentage x2, and rotational speed x3 are determined as experimental factors, and the filling rate μ and spiral torque Yaverage are used as experimental indicators to conduct a simulation study on the secondary universal rotation combination design experiment. The results show that when the rotational speed is 95 r/min, the spiral lead reduction percentage is 60.00~73.21%, the spiral diameter reduction percentage is 86.55~97.05%, the filling rate μ is greater than 95%, and the spiral torque Yaverage is less than 16 N·m. In order to further improve the uniformity of fertilizer discharge and ensure the controllable accuracy of fertilizer discharge, comparative verification experiments are conducted on single-, double-, and triple-head gradually reducing spiral fertilizer discharge devices and ordinary spiral fertilizer discharge devices. The results show that the precision of the gradually reducing spiral fertilizer apparatus is better than that of the ordinary spiral fertilizer apparatus. Moreover, it is determined that the three-head style performed best. The triple-head gradually reducing spiral fertilizer apparatus is also validated by randomly adjusting six rotational speeds. The experiment results show that the average deviation of the fertilizer discharge flow rate of the fertilizer apparatus from the preset value is 3.16%. The two have a minor deviation, and the fertilizer precision is high. Precise control of the amount of fertilizer discharged can be achieved by adjusting the rotational speed, and the research can provide a specific reference for the improved design and precise control of the spiral fertilizer apparatus.
为解决现有螺旋施肥机存在的空腔填充率随转速变化、排肥流量波动大、无法精确排肥等问题,设计了一种三头渐减螺旋施肥机,通过三头渐减施肥螺旋结构将肥料颗粒逐渐压缩,实现空腔完全填充和均匀排肥。通过理论分析确定了影响螺旋肥料颗粒运动状态和结构尺寸的主要因素,并计算了其理论排肥量和转速。利用 EDEM(离散元法软件 2022)建立单头渐减肥装置的仿真模型,确定螺旋导程减少百分比 x1、螺旋直径减少百分比 x2、转速 x3 作为实验因子,以填充率 μ 和螺旋扭矩 Yaverage 作为实验指标,对二次万向旋转组合设计实验进行仿真研究。结果表明,当转速为 95 r/min 时,螺旋导程减小率为 60.00%~73.21%,螺旋直径减小率为 86.55%~97.05%,填充率 μ 大于 95%,螺旋扭矩 Yaverage 小于 16 N-m。为进一步提高排肥均匀度,确保排肥精度可控,对单头、双头、三头渐减螺旋排肥装置和普通螺旋排肥装置进行了对比验证实验。结果表明,渐减式螺旋排肥器的排肥精度优于普通螺旋排肥器。此外,还确定三头式的性能最好。还通过随机调整六种转速对三头渐减式螺旋施肥装置进行了验证。实验结果表明,肥料装置的排肥流量与预设值的平均偏差为 3.16%。二者偏差较小,施肥精度较高。通过调节转速可实现排肥量的精确控制,该研究可为螺旋施肥器的改进设计和精确控制提供具体参考。
{"title":"Design Optimization and Experimentation of Triple-Head Gradually Reducing Spiral Precision Fertilizer Apparatus","authors":"Guoqiang Dun, Quanbao Sheng, Haitian Sun, Xinxin Ji, Zhenzhen Yu, Hongxuan Wang, Xingpeng Wu, Yuhan Wei, Chaoxia Zhang, Shang Gao, Hailiang Li","doi":"10.3390/pr12091988","DOIUrl":"https://doi.org/10.3390/pr12091988","url":null,"abstract":"In order to solve the problems of existing spiral fertilizer apparatuses, such as the variation in cavity filling rate with rotational speed, fluctuation of fertilizer discharge flow, and inability to discharge fertilizer precisely, a triple-head gradually reducing spiral fertilizer apparatus is designed, which gradually compresses fertilizer particles through the triple-head reducing fertilizer spiral structure to achieve complete cavity filling and uniform fertilizer discharge. The main factors that affect the particle motion state and the structural size of the spiral fertilizer through theoretical analysis are determined, and its theoretical fertilizer discharge amount and rotational speed are calculated. Using EDEM (Discrete Element Method Software 2022) to establish a simulation model of a single-head gradually reducing fertilizer apparatus, the spiral lead reduction percentage x1, spiral diameter reduction percentage x2, and rotational speed x3 are determined as experimental factors, and the filling rate μ and spiral torque Yaverage are used as experimental indicators to conduct a simulation study on the secondary universal rotation combination design experiment. The results show that when the rotational speed is 95 r/min, the spiral lead reduction percentage is 60.00~73.21%, the spiral diameter reduction percentage is 86.55~97.05%, the filling rate μ is greater than 95%, and the spiral torque Yaverage is less than 16 N·m. In order to further improve the uniformity of fertilizer discharge and ensure the controllable accuracy of fertilizer discharge, comparative verification experiments are conducted on single-, double-, and triple-head gradually reducing spiral fertilizer discharge devices and ordinary spiral fertilizer discharge devices. The results show that the precision of the gradually reducing spiral fertilizer apparatus is better than that of the ordinary spiral fertilizer apparatus. Moreover, it is determined that the three-head style performed best. The triple-head gradually reducing spiral fertilizer apparatus is also validated by randomly adjusting six rotational speeds. The experiment results show that the average deviation of the fertilizer discharge flow rate of the fertilizer apparatus from the preset value is 3.16%. The two have a minor deviation, and the fertilizer precision is high. Precise control of the amount of fertilizer discharged can be achieved by adjusting the rotational speed, and the research can provide a specific reference for the improved design and precise control of the spiral fertilizer apparatus.","PeriodicalId":20597,"journal":{"name":"Processes","volume":"15 1","pages":""},"PeriodicalIF":3.5,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142254309","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Robots for the Energy Transition: A Review 能源转型中的机器人:回顾
IF 3.5 4区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-14 DOI: 10.3390/pr12091982
Sergio Taraglio, Stefano Chiesa, Saverio De Vito, Marco Paoloni, Gabriele Piantadosi, Andrea Zanela, Girolamo Di Francia
The energy transition relies on an increasingly massive and pervasive use of renewable energy sources, mainly photovoltaic and wind, characterized by an intrinsic degree of production uncertainty, mostly due to meteorological conditions variability that, even if accurately estimated, can hardly be kept under control. Because of this limit, continuously monitoring the operative status of each renewable energy-based power plant becomes relevant in order to timely face any other uncertainty source such as those related to the plant operation and maintenance (O&M), whose effect may become relevant in terms of the levelized cost of energy. In this frame, the use of robots, which incorporate fully automatic platforms capable of monitoring each plant and also allow effective and efficient process operation, can be considered a feasible solution. This paper carries out a review on the use of robots for the O&M of photovoltaic, wind, hydroelectric, and concentrated solar power, including robot applications for controlling power lines, whose role can in fact be considered a key complementary issue within the energy transition. It is shown that various robotic solutions have so far been proposed both by the academy and by industries and that implementing their use should be considered mandatory for the energy transition scenario.
能源转型依赖于对可再生能源(主要是光伏和风能)日益大规模和普遍的使用,其特点是生产具有一定程度的内在不确定性,这主要是由于气象条件的多变性造成的,而气象条件的多变性即使估计准确,也很难得到控制。由于这种限制,持续监测每个可再生能源发电厂的运行状况就变得非常重要,以便及时应对任何其他不确定因素,如与发电厂运行和维护(O&M)相关的因素,这些因素的影响可能与能源的平准化成本有关。在这种情况下,机器人的使用被认为是一种可行的解决方案,因为机器人结合了全自动平台,能够监控每个工厂,并实现有效和高效的流程操作。本文综述了机器人在光伏发电、风力发电、水力发电和聚光太阳能发电的运行和维护方面的应用,包括机器人在控制电力线方面的应用,事实上,电力线的作用可被视为能源转型中的一个关键补充问题。研究表明,迄今为止,学术界和工业界已经提出了各种机器人解决方案,在能源转型方案中,使用机器人应被视为强制性的。
{"title":"Robots for the Energy Transition: A Review","authors":"Sergio Taraglio, Stefano Chiesa, Saverio De Vito, Marco Paoloni, Gabriele Piantadosi, Andrea Zanela, Girolamo Di Francia","doi":"10.3390/pr12091982","DOIUrl":"https://doi.org/10.3390/pr12091982","url":null,"abstract":"The energy transition relies on an increasingly massive and pervasive use of renewable energy sources, mainly photovoltaic and wind, characterized by an intrinsic degree of production uncertainty, mostly due to meteorological conditions variability that, even if accurately estimated, can hardly be kept under control. Because of this limit, continuously monitoring the operative status of each renewable energy-based power plant becomes relevant in order to timely face any other uncertainty source such as those related to the plant operation and maintenance (O&M), whose effect may become relevant in terms of the levelized cost of energy. In this frame, the use of robots, which incorporate fully automatic platforms capable of monitoring each plant and also allow effective and efficient process operation, can be considered a feasible solution. This paper carries out a review on the use of robots for the O&M of photovoltaic, wind, hydroelectric, and concentrated solar power, including robot applications for controlling power lines, whose role can in fact be considered a key complementary issue within the energy transition. It is shown that various robotic solutions have so far been proposed both by the academy and by industries and that implementing their use should be considered mandatory for the energy transition scenario.","PeriodicalId":20597,"journal":{"name":"Processes","volume":"21 1","pages":""},"PeriodicalIF":3.5,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142268950","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impacts of Polyvinyl Alcohol and Chitosan-Modified Biochar on the Anaerobic Digestion of Sewage Sludge and Valuable Resource Recovery 聚乙烯醇和壳聚糖改性生物炭对污水污泥厌氧消化和宝贵资源回收的影响
IF 3.5 4区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-14 DOI: 10.3390/pr12091987
Ping Fa Chiang, Teng Ling Zhang, Ndungutse Jean Maurice, Mugabekazi Joie Claire, Bigirimana Gentil, Abdul Ghaffar Memon, Abdulmoseen Segun Giwa
The accumulation of organic dyes and heavy metals (HMs) in sewage sludge (SS) after wastewater treatment is a significant problem due to the non-degradable nature of these pollutants. Moreover, the simultaneous removal of HMs and dyes in the complex process of SS treatment, such as anaerobic digestion (AD), has become attractive. HMs and dyes present in SS can have a detrimental effect on anaerobic digesters. These pollutants not only inhibit the production of methane, which is crucial for biogas generation, but also affect the stability of AD treatment, which can result in failure or inadequate performance of the AD process. This review highlights a novel method of removing HMs and dyes from the AD process of SS through the use of biochar modified with polyvinyl alcohol (PVA) and chitosan (CTS). The applications of conventional biochar have been limited due to poor adsorption capacity. However, modification using PVA/CTS composites enhances properties such as surface functional groups, adsorption capacity, porosity, surface area selectivity, and stability. Furthermore, this modified version can function as an additive in AD of SS treatment to boost biogas production, which is a viable source for heat generation or electricity supply. In addition, the digestates can be further processed through plasma pyrolysis for the removal of HMs and dyes bound to the modified biochar. Plasma pyrolysis generates two major products: syngas and slag. The syngas produced can then be used as a source of hydrogen, heat, and electricity, while the slag can potentially be reused as an AD additive or as a biofertilizer in the agricultural sector. Additionally, this study addresses the challenges associated with this integration and biochar modifications, and offers an outlook on understanding the interactions between the modified biochar properties, microbial dynamics, and the presence of micropollutants to ensure the economic viability and scalability of this technology. This comprehensive review provides insights into the potential of PVA/CTS-modified biochar as an effective additive in AD systems, offering a sustainable approach to SS treatment and valuable resource recovery.
由于有机染料和重金属(HMs)具有不可降解的特性,因此在污水处理后,这些污染物在污水污泥(SS)中的积累是一个重大问题。此外,在厌氧消化(AD)等复杂的污水污泥处理工艺中同时去除 HMs 和染料已变得颇具吸引力。SS 中的 HMs 和染料会对厌氧消化器产生不利影响。这些污染物不仅会抑制甲烷的产生(甲烷对沼气的产生至关重要),还会影响厌氧消化处理的稳定性,从而导致厌氧消化工艺失败或性能不佳。本综述重点介绍了一种通过使用聚乙烯醇(PVA)和壳聚糖(CTS)改性的生物炭去除 SS 厌氧消化(AD)过程中的 HMs 和染料的新方法。由于吸附能力差,传统生物炭的应用受到了限制。然而,使用 PVA/CTS 复合材料进行改性,可增强生物炭的特性,如表面官能团、吸附能力、孔隙率、表面积选择性和稳定性。此外,这种改性产品还可作为固态发酵(AD)处理的添加剂,以提高沼气产量,而沼气是一种可行的供热或供电来源。此外,沼渣还可通过等离子体热解进一步处理,以去除与改性生物炭结合在一起的 HMs 和染料。等离子热解产生两种主要产品:合成气和炉渣。产生的合成气可用作氢气、热能和电力来源,而炉渣则有可能作为厌氧消化添加剂或生物肥料重新用于农业领域。此外,本研究还探讨了与这种整合和生物炭改性相关的挑战,并展望了如何理解改性生物炭特性、微生物动力学和微污染物存在之间的相互作用,以确保该技术的经济可行性和可扩展性。本综述深入探讨了 PVA/CTS 改性生物炭作为厌氧消化(AD)系统有效添加剂的潜力,为 SS 处理和宝贵资源回收提供了一种可持续的方法。
{"title":"Impacts of Polyvinyl Alcohol and Chitosan-Modified Biochar on the Anaerobic Digestion of Sewage Sludge and Valuable Resource Recovery","authors":"Ping Fa Chiang, Teng Ling Zhang, Ndungutse Jean Maurice, Mugabekazi Joie Claire, Bigirimana Gentil, Abdul Ghaffar Memon, Abdulmoseen Segun Giwa","doi":"10.3390/pr12091987","DOIUrl":"https://doi.org/10.3390/pr12091987","url":null,"abstract":"The accumulation of organic dyes and heavy metals (HMs) in sewage sludge (SS) after wastewater treatment is a significant problem due to the non-degradable nature of these pollutants. Moreover, the simultaneous removal of HMs and dyes in the complex process of SS treatment, such as anaerobic digestion (AD), has become attractive. HMs and dyes present in SS can have a detrimental effect on anaerobic digesters. These pollutants not only inhibit the production of methane, which is crucial for biogas generation, but also affect the stability of AD treatment, which can result in failure or inadequate performance of the AD process. This review highlights a novel method of removing HMs and dyes from the AD process of SS through the use of biochar modified with polyvinyl alcohol (PVA) and chitosan (CTS). The applications of conventional biochar have been limited due to poor adsorption capacity. However, modification using PVA/CTS composites enhances properties such as surface functional groups, adsorption capacity, porosity, surface area selectivity, and stability. Furthermore, this modified version can function as an additive in AD of SS treatment to boost biogas production, which is a viable source for heat generation or electricity supply. In addition, the digestates can be further processed through plasma pyrolysis for the removal of HMs and dyes bound to the modified biochar. Plasma pyrolysis generates two major products: syngas and slag. The syngas produced can then be used as a source of hydrogen, heat, and electricity, while the slag can potentially be reused as an AD additive or as a biofertilizer in the agricultural sector. Additionally, this study addresses the challenges associated with this integration and biochar modifications, and offers an outlook on understanding the interactions between the modified biochar properties, microbial dynamics, and the presence of micropollutants to ensure the economic viability and scalability of this technology. This comprehensive review provides insights into the potential of PVA/CTS-modified biochar as an effective additive in AD systems, offering a sustainable approach to SS treatment and valuable resource recovery.","PeriodicalId":20597,"journal":{"name":"Processes","volume":"18 1","pages":""},"PeriodicalIF":3.5,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142254310","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electricity Generation at Gas Distribution Stations from Gas Surplus Pressure Energy 配气站利用天然气余压发电
IF 3.5 4区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-14 DOI: 10.3390/pr12091985
Serhii Vanieiev, Jana Mizakova, Dmytro Smolenko, Dmytro Miroshnychenko, Jan Pitel, Vadym Baha, Stanislav Meleychuk
At gas distribution stations (GDSs), the process of throttling (pressure reduction) of natural gas occurs on gas pressure regulators without generating useful energy. If the gas expansion process is created in a turbine, to the shaft where an electric generator is connected, then electricity can be obtained. At the same time, the recycling of secondary energy resources is provided, which is an important component in the efficient use of natural resources. The obtained electric power can be supplied to the external power grid and/or used for the GDS’s own needs. The process of generating electricity at the GDS from gas overpressure energy is an environmentally friendly, energy-saving technology that ensures an uninterrupted, autonomous operation of the GDS in the absence of an external energy supply. The power needs of a GDS with regard to electricity are relatively small (5 ÷ 20 kW). Expansion in throttling devices or turbine flow paths leads to gas cooling with a possible hydrate formation. It is prevented via gas preheating or vortex expansion equipment that keeps the further gas temperature at a necessary level. Turbogenerators can be created on the basis of vortex expansion turbomachines, which have many advantages compared to turbomachines of other types. This article studies how gas pressure (outlet: gas distribution station) and gas preheating (inlet: vortex expansion machine) influence turbogenerator parameters. Nine turbogenerator variants for the power needs of gas distribution stations have been assessed.
在配气站(GDS),天然气的节流(减压)过程发生在天然气压力调节器上,不会产生有用的能量。如果气体膨胀过程在涡轮机中产生,并连接到发电机的轴上,则可以获得电力。与此同时,还提供了二次能源的循环利用,这是有效利用自然资源的重要组成部分。获得的电能可以供应给外部电网和/或用于满足 GDS 自身的需要。利用气体超压能在 GDS 上发电是一项环保节能技术,可确保 GDS 在没有外部能源供应的情况下不间断地自主运行。GDS 对电力的需求相对较小(5 ÷ 20 千瓦)。节流装置或涡轮流道中的膨胀会导致气体冷却,并可能形成水合物。可通过气体预热或涡流膨胀设备将气体温度保持在必要的水平。涡轮发电机可以在涡流膨胀透平机械的基础上制造,与其他类型的透平机械相比,涡流膨胀透平机械具有许多优点。本文研究了气体压力(出口:配气站)和气体预热(入口:涡流膨胀机)对涡轮发电机参数的影响。针对配气站的电力需求,对九种涡轮发电机变体进行了评估。
{"title":"Electricity Generation at Gas Distribution Stations from Gas Surplus Pressure Energy","authors":"Serhii Vanieiev, Jana Mizakova, Dmytro Smolenko, Dmytro Miroshnychenko, Jan Pitel, Vadym Baha, Stanislav Meleychuk","doi":"10.3390/pr12091985","DOIUrl":"https://doi.org/10.3390/pr12091985","url":null,"abstract":"At gas distribution stations (GDSs), the process of throttling (pressure reduction) of natural gas occurs on gas pressure regulators without generating useful energy. If the gas expansion process is created in a turbine, to the shaft where an electric generator is connected, then electricity can be obtained. At the same time, the recycling of secondary energy resources is provided, which is an important component in the efficient use of natural resources. The obtained electric power can be supplied to the external power grid and/or used for the GDS’s own needs. The process of generating electricity at the GDS from gas overpressure energy is an environmentally friendly, energy-saving technology that ensures an uninterrupted, autonomous operation of the GDS in the absence of an external energy supply. The power needs of a GDS with regard to electricity are relatively small (5 ÷ 20 kW). Expansion in throttling devices or turbine flow paths leads to gas cooling with a possible hydrate formation. It is prevented via gas preheating or vortex expansion equipment that keeps the further gas temperature at a necessary level. Turbogenerators can be created on the basis of vortex expansion turbomachines, which have many advantages compared to turbomachines of other types. This article studies how gas pressure (outlet: gas distribution station) and gas preheating (inlet: vortex expansion machine) influence turbogenerator parameters. Nine turbogenerator variants for the power needs of gas distribution stations have been assessed.","PeriodicalId":20597,"journal":{"name":"Processes","volume":"78 1","pages":""},"PeriodicalIF":3.5,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142254307","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Analysis of the Impact of Multiple Explosion Source Layouts on the Kinetic Characteristics of Gas Explosions in Blind Roadways 多爆炸源布局对盲道中气体爆炸动力学特性的影响分析
IF 3.5 4区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-14 DOI: 10.3390/pr12091980
Weijian Wang, Qing Ye, Zhenzhen Jia
To investigate the changes in conditions within a blind roadway when multiple gas explosion sources are simultaneously detonated, the fluid dynamics software Fluent14.0 was used to conduct numerical simulation experiments with different numbers (2 and 3) and varying intervals (5 m, 10 m, and 15 m) of explosion sources. The results revealed that multiple explosion sources in gas explosions generate shock waves that propagate in opposite directions, creating pressure overlap zones within the roadway. The pressure waves and shock waves in these overlap zones continuously couple within the roadway. The number of overlap zones decreases incrementally with each encounter of opposing shock waves in the roadway. Unlike single explosion source models, the pressure at various positions within the roadway in multiple explosion source models oscillates due to the coupling of multiple shock waves, with significant peak pressures occurring at the closed end of the roadway and in the pressure overlap zones. Additionally, the propagation patterns of shock waves and flames within the roadway are not associated with the interval distance between explosion sources, whereas the encounter time, speed, and pressure of shock waves increase with the interval distance.
为了研究多个瓦斯爆炸源同时引爆时盲巷内的条件变化,使用流体动力学软件 Fluent14.0 对不同数量(2 个和 3 个)和不同间隔(5 米、10 米和 15 米)的爆炸源进行了数值模拟实验。结果表明,气体爆炸中的多个爆炸源会产生向相反方向传播的冲击波,在巷道内形成压力重叠区。这些重叠区内的压力波和冲击波在巷道内不断耦合。巷道中每遇到一次相反的冲击波,重叠区的数量就会逐渐减少。与单爆炸源模型不同的是,在多爆炸源模型中,巷道内不同位置的压力会因多个冲击波的耦合而摆动,显著的峰值压力出现在巷道的封闭端和压力重叠区。此外,冲击波和火焰在巷道内的传播模式与爆炸源之间的间隔距离无关,而冲击波的相遇时间、速度和压力则随着间隔距离的增加而增加。
{"title":"Analysis of the Impact of Multiple Explosion Source Layouts on the Kinetic Characteristics of Gas Explosions in Blind Roadways","authors":"Weijian Wang, Qing Ye, Zhenzhen Jia","doi":"10.3390/pr12091980","DOIUrl":"https://doi.org/10.3390/pr12091980","url":null,"abstract":"To investigate the changes in conditions within a blind roadway when multiple gas explosion sources are simultaneously detonated, the fluid dynamics software Fluent14.0 was used to conduct numerical simulation experiments with different numbers (2 and 3) and varying intervals (5 m, 10 m, and 15 m) of explosion sources. The results revealed that multiple explosion sources in gas explosions generate shock waves that propagate in opposite directions, creating pressure overlap zones within the roadway. The pressure waves and shock waves in these overlap zones continuously couple within the roadway. The number of overlap zones decreases incrementally with each encounter of opposing shock waves in the roadway. Unlike single explosion source models, the pressure at various positions within the roadway in multiple explosion source models oscillates due to the coupling of multiple shock waves, with significant peak pressures occurring at the closed end of the roadway and in the pressure overlap zones. Additionally, the propagation patterns of shock waves and flames within the roadway are not associated with the interval distance between explosion sources, whereas the encounter time, speed, and pressure of shock waves increase with the interval distance.","PeriodicalId":20597,"journal":{"name":"Processes","volume":"6 1","pages":""},"PeriodicalIF":3.5,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142268866","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research on the Energy-Absorbing and Cushioning Performance of a New Half-Bowl Ball Rubber Body in Tunnel Support 新型半碗球橡胶体在隧道支护中的吸能和缓冲性能研究
IF 3.5 4区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-14 DOI: 10.3390/pr12091981
Jian Ma, Yaomeng Xiao, Bin Ma, Canguang Zheng, Xiangpeng Hu, Dan Tian, Mingchao Du, Kun Zhang
As coal mine underground operating conditions are harsh, strengthening and optimizing the support structure is conducive to the safety of mining work and personnel. Currently, underground support devices face problems such as poor environmental adaptability and unbalanced performance of shockproof and energy absorption. At the same time, the energy absorption mechanism and impact dynamic analysis of the support structure are still imperfect. This paper proposes a simple and effective bionic half-bowl spherical rubber energy-absorbing structure based on the actual production needs of coal mines, with energy-absorbing rubber as the main structural interlayer. A combination of experimental testing and simulation was used to reveal the dynamic response and mechanism of simulated energy absorption of a half-bowl-shaped rubber layer under different working conditions. Abaqus software was used to simulate and analyze the dynamic response of the half-bowl spherical rubber structure under the impact condition, and the simulation data were compared with the experimental results. In addition, the relationship between energy absorption and stress at the rubber structure and the base plate under different impact velocities was investigated. The results show that the simulated and experimental results of the rubber structure have almost the same pressure vs. time trend within 0.1 s at an impact velocity of 64 m/s, and there is no significant wear on the rubber surface after impact. Due to the energy-absorbing effect of the rubber structure, the maximum stress of the bottom member plate-2 of the mechanism is lower than 9 × 104 N. The maximum amount of compression of the half-bowl ball is 37.56 mm at an impact velocity of 64 m/s. The maximum amount of compression of the half-bowl ball is 37.56 mm.
煤矿井下作业条件恶劣,加强和优化支护结构有利于矿井作业和人员安全。目前,井下支护装置面临着环境适应性差、防震吸能性能不均衡等问题。同时,支护结构的吸能机理和冲击动力分析还不完善。本文根据煤矿实际生产需要,以吸能橡胶为主要结构夹层,提出了一种简单有效的仿生半碗球形橡胶吸能结构。采用实验测试和模拟相结合的方法,揭示了半碗形橡胶层在不同工况下的动态响应和模拟吸能机理。利用 Abaqus 软件模拟分析了半碗状球形橡胶结构在冲击条件下的动态响应,并将模拟数据与实验结果进行了对比。此外,还研究了不同冲击速度下橡胶结构和底板的能量吸收和应力之间的关系。结果表明,在 64 米/秒的冲击速度下,橡胶结构的模拟结果和实验结果在 0.1 秒内的压力与时间趋势几乎相同,而且冲击后橡胶表面没有明显磨损。由于橡胶结构的吸能效果,机构底部构件板-2 的最大应力低于 9 × 104 N。半碗球的最大压缩量为 37.56 毫米。
{"title":"Research on the Energy-Absorbing and Cushioning Performance of a New Half-Bowl Ball Rubber Body in Tunnel Support","authors":"Jian Ma, Yaomeng Xiao, Bin Ma, Canguang Zheng, Xiangpeng Hu, Dan Tian, Mingchao Du, Kun Zhang","doi":"10.3390/pr12091981","DOIUrl":"https://doi.org/10.3390/pr12091981","url":null,"abstract":"As coal mine underground operating conditions are harsh, strengthening and optimizing the support structure is conducive to the safety of mining work and personnel. Currently, underground support devices face problems such as poor environmental adaptability and unbalanced performance of shockproof and energy absorption. At the same time, the energy absorption mechanism and impact dynamic analysis of the support structure are still imperfect. This paper proposes a simple and effective bionic half-bowl spherical rubber energy-absorbing structure based on the actual production needs of coal mines, with energy-absorbing rubber as the main structural interlayer. A combination of experimental testing and simulation was used to reveal the dynamic response and mechanism of simulated energy absorption of a half-bowl-shaped rubber layer under different working conditions. Abaqus software was used to simulate and analyze the dynamic response of the half-bowl spherical rubber structure under the impact condition, and the simulation data were compared with the experimental results. In addition, the relationship between energy absorption and stress at the rubber structure and the base plate under different impact velocities was investigated. The results show that the simulated and experimental results of the rubber structure have almost the same pressure vs. time trend within 0.1 s at an impact velocity of 64 m/s, and there is no significant wear on the rubber surface after impact. Due to the energy-absorbing effect of the rubber structure, the maximum stress of the bottom member plate-2 of the mechanism is lower than 9 × 104 N. The maximum amount of compression of the half-bowl ball is 37.56 mm at an impact velocity of 64 m/s. The maximum amount of compression of the half-bowl ball is 37.56 mm.","PeriodicalId":20597,"journal":{"name":"Processes","volume":"7 1","pages":""},"PeriodicalIF":3.5,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142268951","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Key Components Degradation in Proton Exchange Membrane Fuel Cells: Unraveling Mechanisms through Accelerated Durability Testing 质子交换膜燃料电池中的关键部件降解:通过加速耐久性测试揭示机理
IF 3.5 4区 工程技术 Q2 ENGINEERING, CHEMICAL Pub Date : 2024-09-14 DOI: 10.3390/pr12091983
Keguang Yao, Li Wang, Xin Wang, Xiaowu Xue, Shuai Li, Hanwen Zhang, Zhengnan Li, Yanpu Li, Gangping Peng, Min Wang, Haijiang Wang
In the process of promoting the commercialization of proton exchange membrane fuel cells, the long-term durability of the fuel cell has become a key consideration. While existing durability tests are critical for assessing cell performance, they are often time-consuming and do not quickly reflect the impact of actual operating conditions on the cell. In this study, improved testing protocols were utilized to solve this problem, which is designed to shorten the testing cycle and evaluate the degradation of the cell performance under real operating conditions more efficiently. Accelerated durability analysis for evaluating the MEA lifetime and performance decay process was carried out through two testing protocols—open circuit voltage (OCV)-based accelerated durability testing (ADT) and relative humidity (RH) cycling-based ADT. OCV-based ADT revealed that degradation owes to a combined mechanical and chemical process. RH cycling-based ADT shows that degradation comes from a mainly mechanical process. In situ fluoride release rate technology was employed to elucidate the degradation of the proton exchange membrane during the ADT. It was found that the proton exchange membrane suffered more serious damage under OCV-based ADT. The loss of F- after the durability test was up to 3.50 × 10−4 mol/L, which was 4.3 times that of the RH cycling-based ADT. In addition, the RH cycling-based ADT had a significant effect on the catalyst layer, and the electrochemically active surface area decreased by 48.6% at the end of the ADT. Moreover, it was observed that the agglomeration of the catalysts was more obvious than that of OCV-based ADT by transmission electron microscopy. It is worth noting that both testing protocols have no obvious influence on the gas diffusion layer, and the contact angle of gas diffusion layers does not change significantly. These findings contribute to understanding the degradation behavior of proton exchange membrane fuel cells under different working conditions, and also provide a scientific basis for developing more effective testing protocols.
在推动质子交换膜燃料电池商业化的过程中,燃料电池的长期耐久性已成为一个关键的考虑因素。虽然现有的耐久性测试对评估电池性能至关重要,但这些测试往往耗时较长,而且不能快速反映实际运行条件对电池的影响。本研究利用改进的测试协议来解决这一问题,旨在缩短测试周期,更有效地评估实际运行条件下电池性能的退化情况。通过两种测试方案--基于开路电压(OCV)的加速耐久性测试(ADT)和基于相对湿度(RH)循环的加速耐久性测试(ADT)--进行了加速耐久性分析,以评估 MEA 的使用寿命和性能衰减过程。基于开路电压的 ADT 表明,降解是机械和化学过程的综合结果。基于相对湿度循环的 ADT 表明降解主要来自机械过程。我们采用原位氟释放率技术来阐明质子交换膜在 ADT 过程中的降解情况。结果发现,质子交换膜在基于 OCV 的 ADT 条件下受到的破坏更为严重。耐久性测试后的 F- 损失量高达 3.50 × 10-4 mol/L,是基于相对湿度循环的 ADT 的 4.3 倍。此外,基于相对湿度循环的 ADT 对催化剂层有显著影响,在 ADT 结束时,电化学活性表面积减少了 48.6%。此外,透射电子显微镜观察到催化剂的团聚现象比基于 OCV 的 ADT 更为明显。值得注意的是,两种测试方案对气体扩散层均无明显影响,气体扩散层的接触角也无明显变化。这些发现有助于理解质子交换膜燃料电池在不同工作条件下的降解行为,也为制定更有效的测试方案提供了科学依据。
{"title":"Key Components Degradation in Proton Exchange Membrane Fuel Cells: Unraveling Mechanisms through Accelerated Durability Testing","authors":"Keguang Yao, Li Wang, Xin Wang, Xiaowu Xue, Shuai Li, Hanwen Zhang, Zhengnan Li, Yanpu Li, Gangping Peng, Min Wang, Haijiang Wang","doi":"10.3390/pr12091983","DOIUrl":"https://doi.org/10.3390/pr12091983","url":null,"abstract":"In the process of promoting the commercialization of proton exchange membrane fuel cells, the long-term durability of the fuel cell has become a key consideration. While existing durability tests are critical for assessing cell performance, they are often time-consuming and do not quickly reflect the impact of actual operating conditions on the cell. In this study, improved testing protocols were utilized to solve this problem, which is designed to shorten the testing cycle and evaluate the degradation of the cell performance under real operating conditions more efficiently. Accelerated durability analysis for evaluating the MEA lifetime and performance decay process was carried out through two testing protocols—open circuit voltage (OCV)-based accelerated durability testing (ADT) and relative humidity (RH) cycling-based ADT. OCV-based ADT revealed that degradation owes to a combined mechanical and chemical process. RH cycling-based ADT shows that degradation comes from a mainly mechanical process. In situ fluoride release rate technology was employed to elucidate the degradation of the proton exchange membrane during the ADT. It was found that the proton exchange membrane suffered more serious damage under OCV-based ADT. The loss of F- after the durability test was up to 3.50 × 10−4 mol/L, which was 4.3 times that of the RH cycling-based ADT. In addition, the RH cycling-based ADT had a significant effect on the catalyst layer, and the electrochemically active surface area decreased by 48.6% at the end of the ADT. Moreover, it was observed that the agglomeration of the catalysts was more obvious than that of OCV-based ADT by transmission electron microscopy. It is worth noting that both testing protocols have no obvious influence on the gas diffusion layer, and the contact angle of gas diffusion layers does not change significantly. These findings contribute to understanding the degradation behavior of proton exchange membrane fuel cells under different working conditions, and also provide a scientific basis for developing more effective testing protocols.","PeriodicalId":20597,"journal":{"name":"Processes","volume":"38 1","pages":""},"PeriodicalIF":3.5,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142254305","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Processes
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1