Emulsion explosives have become a hot topic in various studies due to their explosive combustion characteristics and detonation performance under different environmental pressures. The thermal safety of an emulsified matrix was studied with ignition energy as the characterization. A minimum ignition energy test experimental system for emulsion matrices was established in this research. The system simulated the occurrence of hot spots inside emulsion matrices using an electric heating wire. The effect of bubbles on the thermal safety of the emulsified matrix was studied by adding expanded perlite additive to the emulsified matrix. This study investigated the variation trend in the minimum ignition energy of the emulsion matrix under the coupled effect of bubbles and ambient pressure using the orthogonal experimental method. The impacts of two factors on the thermal safety of the emulsion matrix were studied at different hot-spot temperatures. Coupled analysis experiments were conducted on emulsion matrices containing 0%, 1.5%, and 3% expanded perlite under pressure environments of 1 atm, 2 atm, and 3 atm. The critical hot-spot temperature of the emulsion matrix significantly decreases with increasing bubble content at 1 atm and 2 atm pressures, as revealed by intuitive analysis and analysis of variance. However, at 3 atm of pressure, the bubble content in the emulsion matrix has no significant effect on its critical hot-spot temperature. The results show that the thermal safety of the emulsified matrix decreases with the increase in the content of expanded perlite and environmental pressure, and the influence of environmental pressure is more significant than that of the bubble content. This paper’s research content serves as a reference for a safe emulsified matrix and as an experimental basis for establishing a production line for developing new equipment.
{"title":"Thermal Safety Study of Emulsion Explosive Matrix under the Coupled Effects of Environmental Pressure and Bubble Content with Internal Heat Source","authors":"Yi-Bo Zhang, Qian Liu, Xiao-Cen Shi","doi":"10.3390/pr12081677","DOIUrl":"https://doi.org/10.3390/pr12081677","url":null,"abstract":"Emulsion explosives have become a hot topic in various studies due to their explosive combustion characteristics and detonation performance under different environmental pressures. The thermal safety of an emulsified matrix was studied with ignition energy as the characterization. A minimum ignition energy test experimental system for emulsion matrices was established in this research. The system simulated the occurrence of hot spots inside emulsion matrices using an electric heating wire. The effect of bubbles on the thermal safety of the emulsified matrix was studied by adding expanded perlite additive to the emulsified matrix. This study investigated the variation trend in the minimum ignition energy of the emulsion matrix under the coupled effect of bubbles and ambient pressure using the orthogonal experimental method. The impacts of two factors on the thermal safety of the emulsion matrix were studied at different hot-spot temperatures. Coupled analysis experiments were conducted on emulsion matrices containing 0%, 1.5%, and 3% expanded perlite under pressure environments of 1 atm, 2 atm, and 3 atm. The critical hot-spot temperature of the emulsion matrix significantly decreases with increasing bubble content at 1 atm and 2 atm pressures, as revealed by intuitive analysis and analysis of variance. However, at 3 atm of pressure, the bubble content in the emulsion matrix has no significant effect on its critical hot-spot temperature. The results show that the thermal safety of the emulsified matrix decreases with the increase in the content of expanded perlite and environmental pressure, and the influence of environmental pressure is more significant than that of the bubble content. This paper’s research content serves as a reference for a safe emulsified matrix and as an experimental basis for establishing a production line for developing new equipment.","PeriodicalId":20597,"journal":{"name":"Processes","volume":null,"pages":null},"PeriodicalIF":3.5,"publicationDate":"2024-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141932499","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shale formations present significant challenges to traditional drilling fluids due to fluid infiltration, cuttings dispersion, and shale swelling, which can destabilize the wellbore. While oil-based drilling fluids (OBM) effectively address these concerns about their environmental impact, their cost limits their widespread use. Recently, nanomaterials (NPs) have emerged as a promising approach in drilling fluid technology, offering an innovative solution to improve the efficiency of water-based drilling fluids (WBDFs) in shale operations. This study evaluates the potential of utilizing modified silica nanocomposite and graphene nanopowder to formulate a nanoparticle-enhanced water-based drilling fluid (NP-WBDF). The main objective is to investigate the impact of these nanoparticle additives on the flow characteristics, filtration efficiency, and inhibition properties of the NP-WBDF. In this research, a silica nanocomposite was successfully synthesized using emulsion polymerization and analyzed using FTIR, PSD, and TEM techniques. Results showed that the silica nanocomposite exhibited a unimodal particle size distribution ranging from 38 nm to 164 nm, with an average particle size of approximately 72 nm. Shale samples before and after interaction with the graphene nanopowder WBDF and the silica nanocomposite WBDF were analyzed using scanning electron microscopy (SEM). The NP-WBM underwent evaluation through API filtration tests (LTLP), high-temperature/high-pressure (HTHP) filtration tests, and rheological measurements conducted with a conventional viscometer. Experimental results showed that the silica nanocomposite and the graphene nanopowder effectively bridged and sealed shale pore throats, demonstrating superior inhibition performance compared to conventional WBDF. Post adsorption, the shale surface exhibited increased hydrophobicity, contributing to enhanced stability. Overall, the silica nanocomposite and the graphene nanopowder positively impacted rheological performance and provided favorable filtration control in water-based drilling fluids.
{"title":"Improving Shale Stability through the Utilization of Graphene Nanopowder and Modified Polymer-Based Silica Nanocomposite in Water-Based Drilling Fluids","authors":"Yerlan Kanatovich Ospanov, Gulzhan Abdullaevna Kudaikulova, Murat Smanovich Moldabekov, Moldir Zhumabaevna Zhaksylykova","doi":"10.3390/pr12081676","DOIUrl":"https://doi.org/10.3390/pr12081676","url":null,"abstract":"Shale formations present significant challenges to traditional drilling fluids due to fluid infiltration, cuttings dispersion, and shale swelling, which can destabilize the wellbore. While oil-based drilling fluids (OBM) effectively address these concerns about their environmental impact, their cost limits their widespread use. Recently, nanomaterials (NPs) have emerged as a promising approach in drilling fluid technology, offering an innovative solution to improve the efficiency of water-based drilling fluids (WBDFs) in shale operations. This study evaluates the potential of utilizing modified silica nanocomposite and graphene nanopowder to formulate a nanoparticle-enhanced water-based drilling fluid (NP-WBDF). The main objective is to investigate the impact of these nanoparticle additives on the flow characteristics, filtration efficiency, and inhibition properties of the NP-WBDF. In this research, a silica nanocomposite was successfully synthesized using emulsion polymerization and analyzed using FTIR, PSD, and TEM techniques. Results showed that the silica nanocomposite exhibited a unimodal particle size distribution ranging from 38 nm to 164 nm, with an average particle size of approximately 72 nm. Shale samples before and after interaction with the graphene nanopowder WBDF and the silica nanocomposite WBDF were analyzed using scanning electron microscopy (SEM). The NP-WBM underwent evaluation through API filtration tests (LTLP), high-temperature/high-pressure (HTHP) filtration tests, and rheological measurements conducted with a conventional viscometer. Experimental results showed that the silica nanocomposite and the graphene nanopowder effectively bridged and sealed shale pore throats, demonstrating superior inhibition performance compared to conventional WBDF. Post adsorption, the shale surface exhibited increased hydrophobicity, contributing to enhanced stability. Overall, the silica nanocomposite and the graphene nanopowder positively impacted rheological performance and provided favorable filtration control in water-based drilling fluids.","PeriodicalId":20597,"journal":{"name":"Processes","volume":null,"pages":null},"PeriodicalIF":3.5,"publicationDate":"2024-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141932498","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Heat dissipation significantly limits semiconductor component performance improvement. Thermal management devices are pivotal for electronic chip heat dissipation, with the enhanced thermal conductivity of materials being crucial for their effectiveness. This study focuses on single-crystal diamond, renowned for its exceptional natural thermal conductivity, investigating diamond microchannels using finite element simulations. Initially, a validated mathematical model for microchannel flow heat transfer was established. Subsequently, the heat dissipation performance of typical microchannel materials was analyzed, highlighting the diamond’s impact. This study also explores diamond microchannel topologies under high-power conditions, revealing unmatched advantages in ultra-high heat flux density dissipation. At 800 W/cm2 and inlet flow rates of 0.4–1 m/s, diamond microchannels exhibit lower maximum temperatures compared to pure copper microchannels by 7.0, 7.2, 7.4, and 7.5 °C, respectively. Rectangular cross-section microchannels demonstrate superior heat dissipation, considering diamond processing costs. The exploration of angular structures with varying parameters shows significant temperature reductions with increasing complexity, such as a 2.4 °C drop at i = 4. The analysis of shape parameter ki indicates optimal heat dissipation performance at ki = 1.1. This research offers crucial insights for developing and optimizing diamond microchannel devices under ultra-high-heat-flux-density conditions, guiding future advancements in thermal management technology.
散热极大地限制了半导体元件性能的提高。热管理装置对于电子芯片散热至关重要，而增强材料的导热性则是其有效性的关键。本研究以天然导热性能优异的单晶金刚石为研究对象，通过有限元模拟研究金刚石微通道。首先，建立了一个经过验证的微通道流动传热数学模型。随后，分析了典型微通道材料的散热性能，突出了金刚石的影响。这项研究还探讨了高功率条件下的金刚石微通道拓扑结构，揭示了其在超高热流密度散热方面无与伦比的优势。在 800 W/cm2 和 0.4-1 m/s 的入口流速条件下，金刚石微通道的最高温度分别比纯铜微通道低 7.0、7.2、7.4 和 7.5 °C。考虑到金刚石的加工成本，矩形截面微通道具有更优越的散热性能。对不同参数的角度结构的研究表明，随着复杂程度的增加，温度显著降低，例如 i = 4 时温度降低了 2.4 °C。对形状参数 ki 的分析表明，ki = 1.1 时散热性能最佳。这项研究为开发和优化超高热流密度条件下的金刚石微通道器件提供了重要启示，为热管理技术的未来发展提供了指导。
{"title":"Numerical Study on the Heat Dissipation Performance of Diamond Microchannels under High Heat Flux Density","authors":"Jiwen Zhao, Kunlong Zhao, Xiaobin Hao, Yicun Li, Sen Zhang, Benjian Liu, Bing Dai, Wenxin Cao, Jiaqi Zhu","doi":"10.3390/pr12081675","DOIUrl":"https://doi.org/10.3390/pr12081675","url":null,"abstract":"Heat dissipation significantly limits semiconductor component performance improvement. Thermal management devices are pivotal for electronic chip heat dissipation, with the enhanced thermal conductivity of materials being crucial for their effectiveness. This study focuses on single-crystal diamond, renowned for its exceptional natural thermal conductivity, investigating diamond microchannels using finite element simulations. Initially, a validated mathematical model for microchannel flow heat transfer was established. Subsequently, the heat dissipation performance of typical microchannel materials was analyzed, highlighting the diamond’s impact. This study also explores diamond microchannel topologies under high-power conditions, revealing unmatched advantages in ultra-high heat flux density dissipation. At 800 W/cm2 and inlet flow rates of 0.4–1 m/s, diamond microchannels exhibit lower maximum temperatures compared to pure copper microchannels by 7.0, 7.2, 7.4, and 7.5 °C, respectively. Rectangular cross-section microchannels demonstrate superior heat dissipation, considering diamond processing costs. The exploration of angular structures with varying parameters shows significant temperature reductions with increasing complexity, such as a 2.4 °C drop at i = 4. The analysis of shape parameter ki indicates optimal heat dissipation performance at ki = 1.1. This research offers crucial insights for developing and optimizing diamond microchannel devices under ultra-high-heat-flux-density conditions, guiding future advancements in thermal management technology.","PeriodicalId":20597,"journal":{"name":"Processes","volume":null,"pages":null},"PeriodicalIF":3.5,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141932500","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Carmine De Francesco, Thomas Gasperini, Daniele Duca, Giuseppe Toscano, Alessio Ilari
Hydrothermal carbonization (HTC) is a promising method for the conversion of agricultural and agro-industrial residues into valuable products. HTC processes biomass through chemical reactions that produce hydrochar, a carbon-rich solid similar to lignite. Unlike other thermochemical processes, HTC can handle high-moisture biomass without pre-drying. This article evaluates the efficiency of HTC on wood chips, wheat straw, and grape pomace, examining their chemical and structural characteristics and critical operational parameters such as the temperature, pressure, biomass/water ratio, and reaction time. The obtained results highlight that the two key process parameters are the temperature and the ratio between the solid biomass and liquid phase. Increasing the first parameter increases the energy content by 20% and increases the carbon concentration by up to 50%, while reducing the oxygen content by 30% in the hydrochar. Varying the second parameter leads to the alternating reduction of the ash content but simultaneously reduces the energy content. The reaction time seems to have a limited influence on the quality parameters of the biochar produced. Lastly, HTC appears to successfully enhance the overall quality of widely available agricultural wastes, such as grape pomace.
{"title":"Hydrothermal Carbonization of Residual Biomass from Agricultural and Agro-Industrial Sector","authors":"Carmine De Francesco, Thomas Gasperini, Daniele Duca, Giuseppe Toscano, Alessio Ilari","doi":"10.3390/pr12081673","DOIUrl":"https://doi.org/10.3390/pr12081673","url":null,"abstract":"Hydrothermal carbonization (HTC) is a promising method for the conversion of agricultural and agro-industrial residues into valuable products. HTC processes biomass through chemical reactions that produce hydrochar, a carbon-rich solid similar to lignite. Unlike other thermochemical processes, HTC can handle high-moisture biomass without pre-drying. This article evaluates the efficiency of HTC on wood chips, wheat straw, and grape pomace, examining their chemical and structural characteristics and critical operational parameters such as the temperature, pressure, biomass/water ratio, and reaction time. The obtained results highlight that the two key process parameters are the temperature and the ratio between the solid biomass and liquid phase. Increasing the first parameter increases the energy content by 20% and increases the carbon concentration by up to 50%, while reducing the oxygen content by 30% in the hydrochar. Varying the second parameter leads to the alternating reduction of the ash content but simultaneously reduces the energy content. The reaction time seems to have a limited influence on the quality parameters of the biochar produced. Lastly, HTC appears to successfully enhance the overall quality of widely available agricultural wastes, such as grape pomace.","PeriodicalId":20597,"journal":{"name":"Processes","volume":null,"pages":null},"PeriodicalIF":3.5,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141932497","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Gen Zhang, Yun Yu, Chunyu Yao, Lang Zhou, Guangyao Zhu, Yushu Lai, Po Niu
To clarify the effects of far-infrared drying technology on the drying kinetics and quality of broccoli rhizomes, broccoli rhizomes were dehydrated at 60, 65, 70, 75 and 80 °C, respectively. Eight thin-layer drying mathematical models were used to explore the drying kinetic characteristics and comprehensively evaluate their quality. The results showed that the higher the drying temperature, the shorter the time required to dry the broccoli rhizomes to the endpoint, and the higher the drying rate. The drying temperature was 80 °C, the shortest drying time was 360 min, and the average drying rate was 4.72 g·g−1·min−1. The longest drying time at 60 °C was 660 min, and the minimum average drying rate was 1.99 g·g−1·min−1. The effective diffusion coefficients of moisture at different drying temperatures were 1.22 × 10−6, 1.25 × 10−6, 1.34 × 10−6, 1.46 × 10−6 and 1.55 × 10−6 m2/min, respectively. The activation energy was calculated to be 12.26 kJ/mol by the linear relationship between the effective moisture diffusion coefficient and time. From the thermodynamic parameters, the drying of broccoli rhizomes is a non-spontaneous process, and it is necessary to absorb heat from the medium to achieve dehydration. With an increase in the drying temperature, the drying effect is better. The fitting results of eight mathematical models showed that Modified Page, Page, and Wang and Singh were the best mathematical models for the far-infrared drying kinetics of the broccoli rhizomes. The membership function method comprehensively evaluated the quality of the broccoli rhizome dry products. The comprehensive order was 60 °C > 65 °C > 75 °C > 70 °C > 80 °C. When the temperature was 60 °C, the physicochemical properties and nutritional quality of broccoli rhizome were well preserved, and the quality was the best. Therefore, 60 °C is the best temperature for broccoli rhizome drying. The results provide a theoretical reference for further improving the far-infrared drying quality of broccoli rhizomes.
为明确远红外干燥技术对西兰花根茎干燥动力学和质量的影响，分别在 60、65、70、75 和 80 °C 下对西兰花根茎进行脱水。采用八个薄层干燥数学模型探讨了其干燥动力学特性，并对其品质进行了综合评价。结果表明，干燥温度越高，西兰花根茎干燥至终点所需的时间越短，干燥速率越高。干燥温度为 80 °C，最短干燥时间为 360 分钟，平均干燥速率为 4.72 g-g-1-min-1。在 60 °C 下，最长的干燥时间为 660 分钟，最小的平均干燥速率为 1.99 g-g-1-min-1。不同干燥温度下的水分有效扩散系数分别为 1.22 × 10-6、1.25 × 10-6、1.34 × 10-6、1.46 × 10-6 和 1.55 × 10-6 m2/min。根据有效水分扩散系数与时间的线性关系，计算出活化能为 12.26 kJ/mol。从热力学参数来看，西兰花根茎的干燥是一个非自发过程，必须从介质中吸收热量才能实现脱水。随着干燥温度的升高，干燥效果更好。8 个数学模型的拟合结果表明，Modified Page、Page、Wang 和 Singh 是西兰花根茎远红外干燥动力学的最佳数学模型。成员函数法综合评价了西兰花根茎干燥产品的质量。综合顺序为 60 °C > 65 °C > 75 °C > 70 °C > 80 °C。当温度为 60 ℃ 时，西兰花根茎的理化特性和营养质量都得到了很好的保存，品质最佳。因此，60 ℃ 是西兰花根茎干燥的最佳温度。该结果为进一步提高西兰花根茎的远红外干燥质量提供了理论参考。
{"title":"Effect of Far-Infrared Drying on Broccoli Rhizomes: Drying Kinetics and Quality Evaluation","authors":"Gen Zhang, Yun Yu, Chunyu Yao, Lang Zhou, Guangyao Zhu, Yushu Lai, Po Niu","doi":"10.3390/pr12081674","DOIUrl":"https://doi.org/10.3390/pr12081674","url":null,"abstract":"To clarify the effects of far-infrared drying technology on the drying kinetics and quality of broccoli rhizomes, broccoli rhizomes were dehydrated at 60, 65, 70, 75 and 80 °C, respectively. Eight thin-layer drying mathematical models were used to explore the drying kinetic characteristics and comprehensively evaluate their quality. The results showed that the higher the drying temperature, the shorter the time required to dry the broccoli rhizomes to the endpoint, and the higher the drying rate. The drying temperature was 80 °C, the shortest drying time was 360 min, and the average drying rate was 4.72 g·g−1·min−1. The longest drying time at 60 °C was 660 min, and the minimum average drying rate was 1.99 g·g−1·min−1. The effective diffusion coefficients of moisture at different drying temperatures were 1.22 × 10−6, 1.25 × 10−6, 1.34 × 10−6, 1.46 × 10−6 and 1.55 × 10−6 m2/min, respectively. The activation energy was calculated to be 12.26 kJ/mol by the linear relationship between the effective moisture diffusion coefficient and time. From the thermodynamic parameters, the drying of broccoli rhizomes is a non-spontaneous process, and it is necessary to absorb heat from the medium to achieve dehydration. With an increase in the drying temperature, the drying effect is better. The fitting results of eight mathematical models showed that Modified Page, Page, and Wang and Singh were the best mathematical models for the far-infrared drying kinetics of the broccoli rhizomes. The membership function method comprehensively evaluated the quality of the broccoli rhizome dry products. The comprehensive order was 60 °C > 65 °C > 75 °C > 70 °C > 80 °C. When the temperature was 60 °C, the physicochemical properties and nutritional quality of broccoli rhizome were well preserved, and the quality was the best. Therefore, 60 °C is the best temperature for broccoli rhizome drying. The results provide a theoretical reference for further improving the far-infrared drying quality of broccoli rhizomes.","PeriodicalId":20597,"journal":{"name":"Processes","volume":null,"pages":null},"PeriodicalIF":3.5,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141932502","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ya Tian, Li Yang, Yi Chen, Zhongkai Bai, Youxing Yang, Jianwei Wu, Suling Wang
This work employs the phase field method combined with a realistic microscopic heterogeneous pore structure model to conduct numerical simulations of CO2–oil two-phase flow. This study investigates the diffusion behavior of CO2 during the displacement process and analyzes the impact of various parameters such as the flow rate, the contact angle, and interfacial tension on the displacement effect. The results indicate that, over time, saturated oil is gradually replaced by CO2, which primarily flows along channels with larger throat widths and lower resistance. The preferential flow paths of CO2 correspond to high flow rates and high pore pressures occupied by CO2. As the injection rate increases, the CO2 filtration rate increases, CO2 movement becomes more pronounced, and CO2 saturation rises. Beyond the optimal flow rate, however, the displacement effect worsens. The wettability of the porous medium predominantly determines the CO2 migration path during the displacement process. As the contact angle increases, CO2 wettability towards the rock improves, significantly enhancing the displacement effect. Under different interfacial tension conditions, the recovery rate increases with the amount of CO2 entering the porous medium, but no clear correlation is observed between interfacial tension and the recovery rate. Therefore, it is challenging to further improve the recovery rate by altering interfacial tension. The viscosity ratio affects wettability and thereby influences the displacement effect. Lower viscosity ratios result in reduced wettability effects, making CO2 diffusion more difficult. This study provides theoretical guidance and technical support for CO2-EOR (Enhanced Oil Recovery) in highly heterogeneous reservoirs on a field scale.
{"title":"Pore-Scale Modeling of Gas–Oil Two-Phase Flow Based on the Phase-Field Method—A Case Study of Glutenite Reservoirs in China","authors":"Ya Tian, Li Yang, Yi Chen, Zhongkai Bai, Youxing Yang, Jianwei Wu, Suling Wang","doi":"10.3390/pr12081670","DOIUrl":"https://doi.org/10.3390/pr12081670","url":null,"abstract":"This work employs the phase field method combined with a realistic microscopic heterogeneous pore structure model to conduct numerical simulations of CO2–oil two-phase flow. This study investigates the diffusion behavior of CO2 during the displacement process and analyzes the impact of various parameters such as the flow rate, the contact angle, and interfacial tension on the displacement effect. The results indicate that, over time, saturated oil is gradually replaced by CO2, which primarily flows along channels with larger throat widths and lower resistance. The preferential flow paths of CO2 correspond to high flow rates and high pore pressures occupied by CO2. As the injection rate increases, the CO2 filtration rate increases, CO2 movement becomes more pronounced, and CO2 saturation rises. Beyond the optimal flow rate, however, the displacement effect worsens. The wettability of the porous medium predominantly determines the CO2 migration path during the displacement process. As the contact angle increases, CO2 wettability towards the rock improves, significantly enhancing the displacement effect. Under different interfacial tension conditions, the recovery rate increases with the amount of CO2 entering the porous medium, but no clear correlation is observed between interfacial tension and the recovery rate. Therefore, it is challenging to further improve the recovery rate by altering interfacial tension. The viscosity ratio affects wettability and thereby influences the displacement effect. Lower viscosity ratios result in reduced wettability effects, making CO2 diffusion more difficult. This study provides theoretical guidance and technical support for CO2-EOR (Enhanced Oil Recovery) in highly heterogeneous reservoirs on a field scale.","PeriodicalId":20597,"journal":{"name":"Processes","volume":null,"pages":null},"PeriodicalIF":3.5,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141932435","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Glyzel Ann C. Madlangbayan, Khyle Glainmer N. Quiton, Ming-Chun Lu
Lead and nitrate are pollutants that are commonly found in wastewater, and these pollutants pose significant risks to humans, animals, plants, and the environment. Therefore, it is essential to treat the wastewater to remove these toxic substances. This study utilized hydroxide precipitation for the removal of lead and nitrate from simulated lead- and nitrate-containing wastewater through jar testing. The effects of pH, lead nitrate (Pb(NO3)2) concentration, and precipitant-to-metal ([P]/[M]) ratio were examined. The hydroxide precipitation effectively removed lead and nitrate by forming basic lead nitrate precipitates, such as lead hydroxide nitrates and lead oxide hydroxide nitrates, and operated efficiently at a pH of around 8.0. Lead and nitrate removal was highly effective and primarily influenced by the [P]/[M] ratio, with [P]/[M] of 1.0 as the optimum condition. Varying the lead nitrate concentrations resulted in a higher sludge volume compared to other parameters; however, it was only significant in nitrate removal with an optimum concentration of 0.07 M.
{"title":"Removal of Lead and Nitrate from Simulated Lead- and Nitrate-Containing Wastewater via Hydroxide Precipitation","authors":"Glyzel Ann C. Madlangbayan, Khyle Glainmer N. Quiton, Ming-Chun Lu","doi":"10.3390/pr12081662","DOIUrl":"https://doi.org/10.3390/pr12081662","url":null,"abstract":"Lead and nitrate are pollutants that are commonly found in wastewater, and these pollutants pose significant risks to humans, animals, plants, and the environment. Therefore, it is essential to treat the wastewater to remove these toxic substances. This study utilized hydroxide precipitation for the removal of lead and nitrate from simulated lead- and nitrate-containing wastewater through jar testing. The effects of pH, lead nitrate (Pb(NO3)2) concentration, and precipitant-to-metal ([P]/[M]) ratio were examined. The hydroxide precipitation effectively removed lead and nitrate by forming basic lead nitrate precipitates, such as lead hydroxide nitrates and lead oxide hydroxide nitrates, and operated efficiently at a pH of around 8.0. Lead and nitrate removal was highly effective and primarily influenced by the [P]/[M] ratio, with [P]/[M] of 1.0 as the optimum condition. Varying the lead nitrate concentrations resulted in a higher sludge volume compared to other parameters; however, it was only significant in nitrate removal with an optimum concentration of 0.07 M.","PeriodicalId":20597,"journal":{"name":"Processes","volume":null,"pages":null},"PeriodicalIF":3.5,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141932388","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Asadullah Khan, Zuo Jihong, Haolin Luo, Ali Raza, Quaid Hussain, Zhangli Hu
Using Chlamydomonas as a model organism, we attempted to eliminate mitochondrial DNA (mtDNA) similar to rho0 or rho− cells (completely or partially mtDNA-eliminated cells) in yeast. We successfully generated partially mtDNA-eliminated cells named as crm- cells, causing the inactivation of mitochondrial activity. We used three different chemicals to eliminate mtDNA including acriflavine (AF), ethidium bromide (EB) and dideoxycytidine (ddC) which prevents replication, inhibits POLG (DNA polymerase gamma) and terminates the mtDNA chain, respectively. The qPCR method was used to detect the mtDNA copy number and the selected rrnL6 gene for the detection of mitochondria, as well as the selected Chlamydomonas CC-124 strain. A reduction in the mitochondrial copy number led to a higher expression of AOX1, UCP1, PGRL1 and ICL1, which indicates the disturbance of the mitochondria–chloroplast ATP and NADPH balance. We selected AOX genes to further study this family and carried out a genome-wide search to identify AOX genes in green algae (C. reinhardtii). Our results revealed that C. reinhardtii contains four AOX genes, i.e., CrAOX1, CrAOX2, CrAOX3 and CrAOX4, which are distributed on Chr 3, Chr7 and Chr9. All CrAOX genes were predicted to localize in mitochondria using bioinformatics tools. Phylogenetic analysis suggests that these CrAOXs are subdivided into four groups and genes existing in the same group could perform identical functions. Collinearity analysis describes the strong evolutionary relationships of AOXs between the unicellular green algae Chlamydomonas reinhardtii and the multicellular green algae Volvox carteri. GO (gene ontology) annotation analysis predicted that CrAOXs played an integral part in carrying out alternate oxidative and respirative activities. Three putative miRNAs, cre-miR1162-3p, cre-miR1171 and cre-miR914, targeting the CrAOX2 gene were identified. Our studies have laid a foundation for the further use of partially mtDNA-eliminated cells and elucidating the functional characteristics of the AOX gene family.
{"title":"Effect of Partial Elimination of Mitochondrial DNA on Genome-Wide Identified AOX Gene Family in Chlamydomonas reinhardtii","authors":"Asadullah Khan, Zuo Jihong, Haolin Luo, Ali Raza, Quaid Hussain, Zhangli Hu","doi":"10.3390/pr12081654","DOIUrl":"https://doi.org/10.3390/pr12081654","url":null,"abstract":"Using Chlamydomonas as a model organism, we attempted to eliminate mitochondrial DNA (mtDNA) similar to rho0 or rho− cells (completely or partially mtDNA-eliminated cells) in yeast. We successfully generated partially mtDNA-eliminated cells named as crm- cells, causing the inactivation of mitochondrial activity. We used three different chemicals to eliminate mtDNA including acriflavine (AF), ethidium bromide (EB) and dideoxycytidine (ddC) which prevents replication, inhibits POLG (DNA polymerase gamma) and terminates the mtDNA chain, respectively. The qPCR method was used to detect the mtDNA copy number and the selected rrnL6 gene for the detection of mitochondria, as well as the selected Chlamydomonas CC-124 strain. A reduction in the mitochondrial copy number led to a higher expression of AOX1, UCP1, PGRL1 and ICL1, which indicates the disturbance of the mitochondria–chloroplast ATP and NADPH balance. We selected AOX genes to further study this family and carried out a genome-wide search to identify AOX genes in green algae (C. reinhardtii). Our results revealed that C. reinhardtii contains four AOX genes, i.e., CrAOX1, CrAOX2, CrAOX3 and CrAOX4, which are distributed on Chr 3, Chr7 and Chr9. All CrAOX genes were predicted to localize in mitochondria using bioinformatics tools. Phylogenetic analysis suggests that these CrAOXs are subdivided into four groups and genes existing in the same group could perform identical functions. Collinearity analysis describes the strong evolutionary relationships of AOXs between the unicellular green algae Chlamydomonas reinhardtii and the multicellular green algae Volvox carteri. GO (gene ontology) annotation analysis predicted that CrAOXs played an integral part in carrying out alternate oxidative and respirative activities. Three putative miRNAs, cre-miR1162-3p, cre-miR1171 and cre-miR914, targeting the CrAOX2 gene were identified. Our studies have laid a foundation for the further use of partially mtDNA-eliminated cells and elucidating the functional characteristics of the AOX gene family.","PeriodicalId":20597,"journal":{"name":"Processes","volume":null,"pages":null},"PeriodicalIF":3.5,"publicationDate":"2024-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141932443","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Deep and ultra-deep reservoirs are characterized by low porosity and permeability, pronounced heterogeneity, and complex pore structures, complicating permeability evaluations. Permeability, directly influencing the fluid production capacity of reservoirs, is a key parameter in comprehensive reservoir assessments. In the X Depression, low-porosity and low-permeability formations present highly discrete and variable core data points for porosity and permeability, rendering single-variable regression models ineffective. Consequently, accurately representing permeability in heterogeneous reservoirs proves challenging. In the following study, lithological and physical property data are integrated with mercury injection data to analyze pore structure types. The formation flow zone index (FZI) is utilized to differentiate reservoir types, and permeability is calculated based on core porosity–permeability relationships from logging data for each flow unit. Subsequently, the average permeability for each flow unit is computed according to reservoir classification, followed by a weighted average according to effective thickness. This approach transforms logging permeability into drill stem test permeability. Unlike traditional point-by-point averaging methods, this approach incorporates reservoir thickness and heterogeneity, making it more suitable for complex reservoir environments and resulting in more reasonable conversion outcomes.
深层和超深层储层的特点是孔隙度和渗透率低、异质性明显、孔隙结构复杂，这使得渗透率评估变得复杂。渗透率直接影响储层的产液能力，是储层综合评估的关键参数。在 X 凹陷，低孔隙度和低渗透率地层的孔隙度和渗透率的岩心数据点高度离散且多变，使得单一变量回归模型无法发挥作用。因此，在异质储层中准确表示渗透率具有挑战性。在以下研究中，将岩性和物性数据与注汞数据相结合，分析孔隙结构类型。利用地层流动带指数（FZI）来区分储层类型，并根据测井数据中每个流动单元的岩心孔隙度-渗透率关系来计算渗透率。随后，根据储层分类计算每个流动单元的平均渗透率，再根据有效厚度进行加权平均。这种方法将测井渗透率转化为钻杆测试渗透率。与传统的逐点平均法不同，这种方法包含了储层厚度和异质性，因此更适合复杂的储层环境，转换结果也更合理。
{"title":"Permeability Upscaling Conversion Based on Reservoir Classification","authors":"Jiali Li, Chuqiao Gao, Bin Zhao, Xincai Cheng","doi":"10.3390/pr12081653","DOIUrl":"https://doi.org/10.3390/pr12081653","url":null,"abstract":"Deep and ultra-deep reservoirs are characterized by low porosity and permeability, pronounced heterogeneity, and complex pore structures, complicating permeability evaluations. Permeability, directly influencing the fluid production capacity of reservoirs, is a key parameter in comprehensive reservoir assessments. In the X Depression, low-porosity and low-permeability formations present highly discrete and variable core data points for porosity and permeability, rendering single-variable regression models ineffective. Consequently, accurately representing permeability in heterogeneous reservoirs proves challenging. In the following study, lithological and physical property data are integrated with mercury injection data to analyze pore structure types. The formation flow zone index (FZI) is utilized to differentiate reservoir types, and permeability is calculated based on core porosity–permeability relationships from logging data for each flow unit. Subsequently, the average permeability for each flow unit is computed according to reservoir classification, followed by a weighted average according to effective thickness. This approach transforms logging permeability into drill stem test permeability. Unlike traditional point-by-point averaging methods, this approach incorporates reservoir thickness and heterogeneity, making it more suitable for complex reservoir environments and resulting in more reasonable conversion outcomes.","PeriodicalId":20597,"journal":{"name":"Processes","volume":null,"pages":null},"PeriodicalIF":3.5,"publicationDate":"2024-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141932436","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Uniform air distribution is the basic condition for the stable operation of circulating fluidized beds and closely related to the hole layout of nozzles and the air outlet conditions. In this paper, CAD modeling software is used to establish different opening types for nozzles and the corresponding gasifier models, and Fluent simulation software for numerical simulations (k-ε model) is introduced to the hydrodynamic behavior of the upper opening, the side opening and the combined opening types of nozzles, as well as the corresponding single-nozzle fluidized bed gasifiers. The flow field distribution under the above opening modes is obtained, including the velocity distribution, static pressure distribution, and total pressure distribution, and the influence of the boundary conditions, including the inlet gas velocity and outlet pressure, on the flow field distribution inside the nozzle and in the single-nozzle fluidized bed gasifier is also investigated. The simulation results show that the suitable optimal operating conditions for the coal gasifier can be achieved with an inlet velocity of 30 m/s and an outlet pressure of 25 kPaG. Under the above conditions, the local fluidization dead zone at the elbow and top of the nozzle is narrower, the uniformity of the wind velocity can be improved, the pressure drop of the inner core tube of the nozzle is gentle, and the pressure distribution tends to be stable. Theoretically, the anti-slag performance of the nozzle is improved, which will enhance the stability and reliability of the operation of the gasification unit.
{"title":"Simulation and Analysis of Hydrodynamic Behavior in Different Nozzles and Its Corresponding Fluidized Beds","authors":"Minghang Tian, Junqiang Li, Wenlong Mo, Kunpeng Jiao, Wei Peng, Xiaoqin Yang, Shupei Zhang","doi":"10.3390/pr12081656","DOIUrl":"https://doi.org/10.3390/pr12081656","url":null,"abstract":"Uniform air distribution is the basic condition for the stable operation of circulating fluidized beds and closely related to the hole layout of nozzles and the air outlet conditions. In this paper, CAD modeling software is used to establish different opening types for nozzles and the corresponding gasifier models, and Fluent simulation software for numerical simulations (k-ε model) is introduced to the hydrodynamic behavior of the upper opening, the side opening and the combined opening types of nozzles, as well as the corresponding single-nozzle fluidized bed gasifiers. The flow field distribution under the above opening modes is obtained, including the velocity distribution, static pressure distribution, and total pressure distribution, and the influence of the boundary conditions, including the inlet gas velocity and outlet pressure, on the flow field distribution inside the nozzle and in the single-nozzle fluidized bed gasifier is also investigated. The simulation results show that the suitable optimal operating conditions for the coal gasifier can be achieved with an inlet velocity of 30 m/s and an outlet pressure of 25 kPaG. Under the above conditions, the local fluidization dead zone at the elbow and top of the nozzle is narrower, the uniformity of the wind velocity can be improved, the pressure drop of the inner core tube of the nozzle is gentle, and the pressure distribution tends to be stable. Theoretically, the anti-slag performance of the nozzle is improved, which will enhance the stability and reliability of the operation of the gasification unit.","PeriodicalId":20597,"journal":{"name":"Processes","volume":null,"pages":null},"PeriodicalIF":3.5,"publicationDate":"2024-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141932437","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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