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On the assessment of strength and durability of weld lines in injection-moulded unreinforced and short glass fiber reinforced polypropylene 非增强和短玻纤增强聚丙烯注射成型焊缝强度和耐久性评价
IF 6 2区 材料科学 Q1 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-11-07 DOI: 10.1016/j.polymertesting.2025.109035
Aitor Arriaga , Sten J.J. van den Broek , Leon E. Govaert , Tom A.P. Engels
Identifying and predicting the performance of process-induced defects, such as weld lines in injection-moulded thermoplastic components, is critical for failure assessment. While previous studies have addressed various weld line phenomena, accurately predicting their instantaneous and long-term strength remains a challenge. This study investigates the thermo-mechanical performance of unreinforced, and 30 % glass fiber-reinforced isotactic polypropylene (iPP) processed by injection moulding into specimens containing a central weld line due to a stagnating flow. Short-term experiments on smooth tensile bars at various strain rates (from 10−6 to 10−2 s−1) and temperatures (−20 °C, 23 °C and 80 °C) identify plasticity driven failure kinetics with a transition towards brittle crack-growth driven failure at high temperatures and low strain rates. Long-term plasticity driven performance is assessed through creep-to-rupture and cyclic fatigue tests on tensile bars and identify the same transition from ductile-to-brittle failure, as well as a clear discrepancy in perceived plasticity-governed strength when comparing short- and long-term experiments. The key novelty of the work is found in the demonstration that stress rate-controlled tensile experiments rationalise this observed discrepancy in strength that is explained by strain localisation. We therefore propose the stress rate-controlled tensile test to be more suitable to assess the strength of a weld line compared to the traditional strain-rate controlled tensile test. All observations are accurately captured using Ree-Eyring flow theory. The crack-growth governed failure of the weld line is explored by including fatigue crack growth experiments on CT specimens on both unreinforced and reinforced materials and general findings are presented.
识别和预测工艺缺陷的性能,如注射成型热塑性部件的焊缝,是失效评估的关键。虽然以前的研究已经解决了各种焊缝现象,但准确预测其瞬时和长期强度仍然是一个挑战。本研究研究了未增强和30%玻璃纤维增强等规聚丙烯(iPP)的热机械性能,通过注射成型加工成含有中心焊缝的样品,因为流动停滞。在不同应变速率(从10−6到10−2 s−1)和温度(- 20°C, 23°C和80°C)下对光滑拉伸棒进行的短期实验确定了塑性驱动的破坏动力学,并在高温和低应变速率下向脆性裂纹扩展驱动的破坏过渡。通过拉伸杆的蠕变到断裂和循环疲劳试验来评估长期塑性驱动性能,并确定了从延性到脆性破坏的相同转变,以及在比较短期和长期实验时感知到的塑性控制强度的明显差异。这项工作的关键新颖之处在于,应力速率控制的拉伸实验使这种观察到的强度差异合理化,这种差异是由应变局部化解释的。因此,与传统的应变速率控制拉伸试验相比,我们提出应力速率控制拉伸试验更适合于评估焊缝的强度。所有的观测结果都是使用李-艾灵流理论准确捕获的。通过对未增强材料和增强材料的CT试样进行疲劳裂纹扩展试验,探讨了裂纹扩展对焊缝破坏的影响,并给出了一般结果。
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引用次数: 0
Accelerated sulfur vulcanization of silica-filled natural rubber analyzed by rubber-state NMR spectroscopy 用橡胶态核磁共振光谱分析了含硅天然橡胶的硫加速硫化
IF 6 2区 材料科学 Q1 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-11-07 DOI: 10.1016/j.polymertesting.2025.109037
Seiichi Kawahara , Kodai Fukushige , Thuong Nghiem Thi , Nghia Phan Trung , Yoshimasa Yamamoto
An optimal concentration (in phr) of vulcanization accelerator was determined for the preparation of silica-filled natural rubber (NR) vulcanizates without the use of a silane coupling agent, achieving outstanding mechanical properties. The silica-filled NR vulcanizates were prepared from 50 phr silica filled NR by accelerated sulfur vulcanization with N-tert-butyl-2-benzothiazyl sulfenamide (TBBS) at concentrations ranging from 0.7 to 12.0 phr, in combination with stearic acid, zinc oxide, and sulfur. The resulting vulcanizates were characterized by swelling method, uniaxial tensile test, and rubber-state nuclear magnetic resonance (NMR) spectroscopy. The optimal vulcanization time decreased with increasing TBBS concentration, reaching its minimum at 5.5 phr of TBBS. Crosslink density and the stresses at 100 % and 300 % strains increased with increasing TBBS concentration. The stress at break also depended on the TBBS concentration, reaching a maximum value of approximately 34.6 MPa at 5.5 phr. Rubber-state NMR spectroscopy revealed that accelerated sulfur vulcanization occurred at TBBS concentrations above 3.5 phr. Based on these results, the optimal TBBS concentration for the preparation of silica-filled NR vulcanizates was determined to be 5.5 phr.
确定了在不使用硅烷偶联剂的情况下,制备硅填充天然橡胶(NR)硫化胶的最佳硫化促进剂浓度(phr),获得了优异的力学性能。以50 phr的二氧化硅填充NR为原料,在0.7 ~ 12.0 phr的浓度范围内,与硬脂酸、氧化锌和硫混合,采用n -叔丁基-2-苯并噻唑磺酰胺(TBBS)进行硫加速硫化,制备了二氧化硅填充NR硫化胶。通过膨胀法、单轴拉伸试验和橡胶态核磁共振(NMR)光谱对所制得的硫化胶进行了表征。最佳硫化时间随TBBS浓度的增加而减小,在TBBS浓度为5.5 phr时达到最小。交联密度和100%和300%应变下的应力随TBBS浓度的增加而增加。断裂应力也与TBBS浓度有关,在5.5 phr时达到最大值约为34.6 MPa。橡胶态核磁共振光谱显示,TBBS浓度高于3.5 phr时,硫的加速硫化发生。在此基础上,确定了制备二氧化硅填充NR硫化胶的最佳TBBS浓度为5.5 phr。
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引用次数: 0
Optimization of 3D printing parameters for recycled polybutylene succinate (PBS) using a granule-based 3D printer 基于颗粒的3D打印机优化再生丁二酸聚丁二烯(PBS)的3D打印参数
IF 6 2区 材料科学 Q1 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-11-07 DOI: 10.1016/j.polymertesting.2025.109038
Laura Aliotta , Vito Gigante , Aimè Duniau , Serena Gabrielli , Fabrizio Sarasini , Jacopo Tirillò , Andrea Lazzeri
In recent years, the use of recycled materials in 3D printing has gained significant attention due to its potential for sustainability and cost-effectiveness. This study opens the possibility of exploring bio-based recycled materials for additive manufacturing, and for the first time, investigates the use of recycled polybutylene succinate (PBS) for 3D printing applications. Particular attention was devoted to optimizing the mechanical properties by varying the printing speed and raster angles. Recycled PBS has proven to be a valuable polymer, allowing for excellent mechanical properties through optimized processing parameters. Additionally, its rapid crystallization kinetics facilitate uniform final crystallinity across sequentially deposited layers. The synergistic application of mechanical, thermal and morphological characterization techniques provided comprehensive insights into the performance and applicability of recycled PBS, highlighting the critical influence of process parameter optimization on achieving optimal material properties. Finally, the use of a 3D printer that utilizes granules not only broadens the application of recycled materials in 3D printing, thereby enhancing the sustainability of the printed components, but also contributes to a reduction in the costs associated with filament production.
近年来,由于其可持续性和成本效益的潜力,在3D打印中使用回收材料获得了极大的关注。这项研究开启了探索生物基再生材料用于增材制造的可能性,并首次研究了再生聚丁二酸丁二烯(PBS)在3D打印应用中的使用。特别注意通过改变印刷速度和光栅角度来优化机械性能。再生PBS已被证明是一种有价值的聚合物,通过优化的加工参数可以获得优异的机械性能。此外,它的快速结晶动力学有助于在顺序沉积层之间均匀的最终结晶度。机械、热学和形态学表征技术的协同应用为再生PBS的性能和适用性提供了全面的见解,突出了工艺参数优化对实现最佳材料性能的关键影响。最后,利用颗粒的3D打印机不仅扩大了回收材料在3D打印中的应用,从而增强了打印部件的可持续性,而且还有助于降低与长丝生产相关的成本。
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引用次数: 0
Mechanical, thermal, and antimicrobial behavior of copper-enhanced polypropylene composites with improved UV stability 提高紫外线稳定性的铜增强聚丙烯复合材料的机械、热学和抗菌性能
IF 6 2区 材料科学 Q1 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-11-06 DOI: 10.1016/j.polymertesting.2025.109036
Mohammed Baafif , Hany S. Abdo , Abdulmohsen Albedah
This study investigates the incorporation of copper nanoparticles (Cu NPs) into polypropylene (PP) matrices to enhance mechanical, thermal, and antimicrobial properties, addressing the growing challenge of antimicrobial resistance (AMR). Cu NP–PP composites were fabricated using twin-screw extrusion and injection molding, with nanoparticle concentrations of 0 %, 1 %, 2 %, 5 %, and 10 %. Mechanical testing revealed that lower Cu NP loadings (1 %–5 %) improved yield strength (by 2 %–5 %) and elastic modulus (by 1.2 %–1.9 %), while higher concentrations (≥5 %) led to performance reductions due to stress concentration effects. Thermal analysis demonstrated increased stability, with TGA onset and peak degradation temperatures rising from 445 °C and 469 °C (pure PP) to 455- °C - 462 °C and 475 °C -481 °C, respectively, in Cu NP–reinforced composites. DSC results showed higher crystallinity retention in Cu NP–PP composites (40.8 %–50.2 %) compared to pure PP (41.7 %). Furthermore, Cu NPs imparted significant antimicrobial efficacy, particularly against Gram-negative bacteria such as Pseudomonas aeruginosa. In addition, a minor improvement in UV stability was observed, suggesting secondary protection of the polymer matrix against photodegradation. These findings highlight the multifunctional potential of Cu NP–PP composites for healthcare and outdoor applications, offering a promising approach to mitigating AMR-related risks while enhancing durability.
本研究探讨了将铜纳米颗粒(Cu NPs)掺入聚丙烯(PP)基质中,以增强其机械、热学和抗菌性能,解决日益严峻的抗菌素耐药性(AMR)挑战。采用双螺杆挤压和注射成型法制备了纳米颗粒浓度分别为0%、1%、2%、5%和10%的铜NP-PP复合材料。力学测试表明,较低的Cu NP负荷(1% - 5%)提高了屈服强度(2% - 5%)和弹性模量(1.2% - 1.9%),而较高的Cu NP负荷(≥5%)由于应力集中效应导致性能降低。热分析表明,Cu - np增强复合材料的稳定性有所提高,TGA起始温度和峰值降解温度分别从445°C和469°C(纯PP)上升到455°C - 462°C和475°C -481°C。DSC结果表明,与纯PP(41.7%)相比,Cu NP-PP复合材料的结晶度保留率(40.8% - 50.2%)更高。此外,铜NPs具有显著的抗菌功效,特别是对革兰氏阴性细菌,如铜绿假单胞菌。此外,观察到紫外线稳定性略有改善,表明聚合物基质对光降解具有二次保护作用。这些发现突出了Cu NP-PP复合材料在医疗保健和户外应用中的多功能潜力,提供了一种有希望的方法来减轻amr相关风险,同时提高耐用性。
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引用次数: 0
In-situ synthesized aramid nanoparticles for multiscale fiber reinforcement of polymer composites 原位合成芳纶纳米颗粒用于聚合物复合材料的多尺度纤维增强
IF 6 2区 材料科学 Q1 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-11-06 DOI: 10.1016/j.polymertesting.2025.109032
Wei Guo , Shifan Lu , Liangfan Gong , Zhiping Zhao , Changmei Sun , Cuiqing Teng , Ying Zhang , Rongjun Qu , Ying Wang
Aramid fiber has attracted much attention in the field of ballistic protection because of their exceptional energy absorption capabilities, but their application in fiber-reinforced polymer (FRP) composites for structural uses has been limited. The limitation is mainly due to their smooth and chemically inert surfaces, leading to poor dispersion and weak interfacial strength in FRP composites. Here, a novel approach to address the limitation by in-situ synthesized aramid nanoparticles (ANPs) within a styrene-butadiene rubber (SBR) matrix is reported. The ANPs are formed through polycondensation of p-phenylenediamine and p-phthaloyl dichloride directly in SBR-cyclohexanone/N-methyl pyrrolidone solution. Those ANPs not only serve as nanoscale reinforcements to significantly enhance the mechanical properties of the SBR matrix, but also act as “bridges” to dramatically improve the interfacial bonding strength between aramid fibers and SBR matrix. Pullout tests demonstrated a significant increase in interfacial load from 75.0 N to 140 N for aramid fiber-reinforced rubber sheets and from 70.9 N to 302 N for aramid fabric-reinforced rubber sheets. Hydrogen bonding and π-π stacking interactions between ANPs and aramid fibers enable effective stress dispersion and transfer, mitigating interfacial stress concentration. The study provides a rather practical process to enhance aramid fiber-polymer matrix interfacial strength in FRP composites.
芳纶纤维以其优异的吸能性能在防弹领域受到广泛关注,但其在结构用纤维增强聚合物(FRP)复合材料中的应用一直受到限制。其局限性主要是由于其表面光滑且化学惰性,导致FRP复合材料的分散性差,界面强度弱。本文报道了一种新的方法来解决原位合成芳纶纳米颗粒(ANPs)在苯乙烯-丁二烯橡胶(SBR)基体中的局限性。对苯二胺和对苯二酰二氯直接在sbr -环己酮/ n -甲基吡咯烷酮溶液中缩聚生成ANPs。这些ANPs不仅可以作为纳米级增强剂,显著提高SBR基体的力学性能,而且还可以作为“桥梁”,显著提高芳纶纤维与SBR基体之间的界面结合强度。拉伸试验表明,芳纶纤维增强橡胶板的界面载荷从75.0 N显著增加到140 N,芳纶纤维增强橡胶板的界面载荷从70.9 N显著增加到302 N。ANPs和芳纶纤维之间的氢键和π-π堆叠相互作用能够有效地分散和传递应力,减轻界面应力集中。该研究为提高玻璃钢复合材料中芳纶纤维-聚合物基体界面强度提供了一种较为实用的方法。
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引用次数: 0
Detection of damage in a rotating glass fibre-reinforced polymer disc using swept-source optical coherence tomography 扫描源光学相干层析成像检测旋转玻璃纤维增强聚合物光盘的损伤
IF 6 2区 材料科学 Q1 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-11-05 DOI: 10.1016/j.polymertesting.2025.109021
C. Habenicht , T. Wollmann , C. Ebert , J. Lich , R. Kuschmierz , J. Czarske , C. Schnabel , E. Koch , M. Gude
Glass fibre-reinforced polymer composites exhibit attractive properties, such as a high strength-to-weight ratio. They can also be customized through manufacturing conditions and composition. However, to ensure reliability, measurement testing under realistic conditions is essential. A swept-source optical coherence tomography (OCT) system was used to evaluate the development of the damage behaviour of a polar-orthotropically reinforced multi-layered composite rotor in situ under rotational loading conditions. The experiment was carried out at various rotational velocities up to 165 rotations per second, corresponding to a linear speed of 259.2 m s-1 at the outer edge of the rotor. The 3-dimensional data enable studying of the rotor’s textile architecture, in-plane and out-of-plane deformations as well as the crack growth over the entire accessible disc volume up to a depth of 2.5 mm even at the highest applied rotational speeds. In contrast to previous OCT investigations conducted on stationary composite structures, this study demonstrated that this method is also suitable for acquiring volumetric images of fast-moving objects. This is important because the increasing radial loads resulting from higher rotation frequency are incorporated into reliability studies. Unlike OCT, other in situ measurement methods, such as Doppler distance sensors, diffraction grating sensors, and strain gauges, do not provide direct information about the inner material structure of the rotor. Furthermore, the work demonstrates that OCT can detect thin cracks and polyester threads not resolvable by computer tomography, another 3-dimensional imaging technique. Consequently, swept-source optical coherence tomography may be used to enhance the understanding and modelling of the damage behaviour of composite materials under load.
玻璃纤维增强聚合物复合材料表现出吸引人的性能,如高强度重量比。它们也可以通过制造条件和组成来定制。然而,为了确保可靠性,在实际条件下进行测量测试是必不可少的。利用扫描源光学相干层析成像(OCT)系统评估了旋转载荷条件下原位极化正交热带增强多层复合材料转子损伤行为的发展。实验在不同转速下进行,最高转速为165转/秒,对应转子外缘线速度为259.2 m s-1。三维数据可以研究转子的纺织结构,面内和面外变形,以及在整个可访问的圆盘体积上的裂纹增长,即使在最高的应用转速下,深度也可达2.5毫米。与之前对静止复合结构进行的OCT研究相比,本研究表明该方法也适用于获取快速运动物体的体积图像。这一点很重要,因为更高的旋转频率导致的径向载荷增加被纳入可靠性研究。与OCT不同,其他原位测量方法,如多普勒距离传感器、衍射光栅传感器和应变片,不能提供转子内部材料结构的直接信息。此外,研究表明,OCT可以检测到计算机断层扫描(另一种三维成像技术)无法分辨的薄裂纹和聚酯线。因此,扫描源光学相干层析成像可用于增强对复合材料在载荷作用下损伤行为的理解和建模。
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引用次数: 0
Thermal and mechanical properties of sustainable rigid polyurethane foam composites reinforced with coffee husk fillers 咖啡壳填料增强可持续硬质聚氨酯泡沫复合材料的热力学性能
IF 6 2区 材料科学 Q1 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-11-05 DOI: 10.1016/j.polymertesting.2025.109028
Kicoun Jean-Yves N’Zi Toure , Alassane Compaore , Desmond Klenam , Tabiri Kwayie Asumadu , John David Obayemi , Merenga Abdallah Sarroney , Edja Florentin Assanvo , Nima Rahbar , Winston Oluwole Soboyejo
Coffee husk waste fibers (CHWFs) offer a sustainable solution for reinforcing bio-based polyurethane foams. This study investigates the use of CHWFs in rigid polyurethane foams (RPUFs) synthesized from cashew nutshell-based polyol and evaluates mechanical, thermal, and combustion properties. Uniquely, three CHWF treatments based on untreated, mercerized, and grafted processes were comparatively analyzed to assess overall impact on foam performance. Mercerization increased cellulose content and crystallinity, whereas grafting enhanced moisture resistance and ash content. The CHWF addition reduced pore size and improved thermal stability, with onset temperature increasing from 279.9°C to 334.4°C for neat foam, whereas the peak decomposition temperatures from 318.7°C, 403.9°C, 449.2°C–321.5°C, 408.1°C, 459.9°C respectively for reinforced foams. Cone calorimeter tests at 30 kW/m2 showed significant reduction in release rate of heat, CO/CO2 emissions, and smoke with increasing fiber content. This work presents a novel dual-waste composite approach with enhanced fire safety and environmental value by combining two underutilized agro-wastes (coffee husks and cashew nutshells). Thus, these results highlight the potential of CHWFs as green reinforcements in high-performance, fire-safe RPUF composites.
咖啡壳废料纤维(CHWFs)为增强生物基聚氨酯泡沫提供了可持续的解决方案。本研究探讨了CHWFs在腰果壳多元醇合成的硬质聚氨酯泡沫(RPUFs)中的应用,并评估了其机械、热学和燃烧性能。独特的是,三种基于未经处理、丝光和接枝工艺的CHWF处理进行了比较分析,以评估对泡沫性能的总体影响。丝光处理提高了纤维素含量和结晶度,而接枝提高了抗湿性和灰分含量。CHWF的加入减小了孔隙尺寸,提高了热稳定性,纯泡沫的起始温度从279.9℃升高到334.4℃,而增强泡沫的峰值分解温度分别为318.7℃、403.9℃、449.2℃- 321.5℃、408.1℃、459.9℃。30 kW/m2的锥形量热计测试表明,随着纤维含量的增加,热量释放率、CO/CO2排放量和烟雾显著降低。这项工作提出了一种新的双废物复合方法,通过结合两种未充分利用的农业废物(咖啡壳和腰果壳),提高了消防安全和环境价值。因此,这些结果突出了CHWFs作为高性能,防火RPUF复合材料的绿色增强材料的潜力。
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引用次数: 0
Scaffold-engineered PVDF–graphene oxide membranes for gel and quasi-solid electrolytes in lithium metal batteries 支架工程pvdf -氧化石墨烯膜用于锂金属电池中的凝胶和准固体电解质
IF 6 2区 材料科学 Q1 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-11-05 DOI: 10.1016/j.polymertesting.2025.109034
Wei-Fan Kuan , Meng-Wen Chiu , Ting-Syuan Huang , Nguyen Thuy Dung
In this study, asymmetric polyvinylidene fluoride (PVDF) membranes incorporating graphene oxide (GO) are developed as multifunctional electrolyte scaffolds for both gel and quasi-solid-state lithium metal batteries. Introduction of GO is found to enhance β-phase crystalline of PVDF, thereby improving the ion transport properties. At an optimal loading, the GO-modified PVDF (PVDF-GO100) membrane achieves a favorable performance, including low interfacial resistance, high Li+ transference number, and reduced nucleation overpotential, which collectively promote uniform Li deposition and suppress dendrite growth. In Li||LiFePO4 full cells, gel electrolytes based on PVDF-GO100 enable excellent rate capability of 100 mAh g−1 at 10C and 80 % capacity retention after 300 cycles at 0.5C. When employed as a porous scaffold for in-situ polymerization of 1,3-dioxolane (DOL), the resulting PVDF-GO100-polyDOL quasi-solid electrolyte further demonstrates superior cycling performance, maintaining 77 mAh g−1 at 10C and 77 % capacity retention after 300 cycles under 0.5C at room temperature. These findings highlight GO-modified PVDF membranes as a versatile and durable platform for high-performance gel and quasi-solid-state lithium metal batteries with enhanced stability and prolonged cycle life.
在这项研究中,不对称聚偏氟乙烯(PVDF)膜结合氧化石墨烯(GO)被开发为凝胶和准固态锂金属电池的多功能电解质支架。发现氧化石墨烯的引入增强了PVDF的β相结晶,从而改善了离子输运性能。在最佳负载下,氧化石墨烯修饰的PVDF (PVDF- go100)膜具有较低的界面电阻、较高的Li+转移数和较低的成核过电位,共同促进了均匀的Li沉积,抑制了枝晶的生长。在Li b| |LiFePO4充满电池中,基于PVDF-GO100的凝胶电解质在10C下具有100 mAh g - 1的优异倍率能力,在0.5C下循环300次后容量保持率为80%。作为原位聚合1,3-二氧唑烷(DOL)的多孔支架,所制备的PVDF-GO100-polyDOL准固体电解质进一步表现出优异的循环性能,在10C下保持77 mAh g−1,在室温0.5C下循环300次后保持77%的容量。这些发现强调了氧化石墨烯修饰的PVDF膜作为高性能凝胶和准固态锂金属电池的通用和耐用平台,具有更高的稳定性和更长的循环寿命。
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引用次数: 0
Triboresponsive behavior of mechanochromic luminescent molecule containing polymers 含聚合物的机械致变色发光分子的摩擦响应行为
IF 6 2区 材料科学 Q1 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-11-05 DOI: 10.1016/j.polymertesting.2025.109033
Chenglong Lu , Jiayi Li , Weijun Zhao , Zhe Zhang
Mechanochromic luminescent (MCL) materials have recently garnered significant attention in intelligent sensing, information encryption, and flexible displays. Although plenty of MCL polymer blends have been reported, but the investigations of the effects of the loading conditions on MCL behavior are still inadequate, which highly restricts the further engineering applications. In this study, a MCL molecule doped polyurethane film was fabricated. The effects of luminogen content, applied force, and sliding linear velocity on triboluminescence (TL) performance were investigated using a tribological testing platform. The results indicate that both luminogen content and morphology have significant influence on TL intensity. The uniformly distributed fine luminogen particles can provide high effectively MCL response. The overloaded applied force squeezes the MCL luminogens from the center to the edge of the friction track and cause the damage of the film surface, restricting the TL intensity. Furthermore, an increased sliding linear velocity leads to a reduced TL intensity.
机械致变色发光(MCL)材料近年来在智能传感、信息加密和柔性显示等领域引起了广泛的关注。虽然已经报道了大量的MCL共混物,但对加载条件对MCL性能影响的研究仍然不足,这极大地限制了其进一步的工程应用。本研究制备了一种掺杂MCL分子的聚氨酯薄膜。在摩擦学测试平台上研究了发光材料含量、施加的作用力和滑动线速度对摩擦发光性能的影响。结果表明,发光物质的含量和形态对发光强度有显著影响。均匀分布的发光微粒可以提供高效的MCL响应。过载的施加力将MCL发光源从摩擦轨迹的中心挤压到边缘,造成薄膜表面的损伤,限制了TL强度。此外,滑动线速度的增加导致TL强度的降低。
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引用次数: 0
Design of 3D-Printed strain-responsive TPU/WS2/CB nanocomposites as dual-function flexible supercapacitor electrodes 3d打印应变响应TPU/WS2/CB纳米复合材料双功能柔性超级电容器电极设计
IF 6 2区 材料科学 Q1 MATERIALS SCIENCE, CHARACTERIZATION & TESTING Pub Date : 2025-11-04 DOI: 10.1016/j.polymertesting.2025.109031
Subramanian Praveenkumar , Jong Seob Choi , Jin-Heong Yim
In this study, a multifunctional strain-responsive supercapacitor (SC) was developed by integrating tungsten disulfide (WS2) and carbon black (CB) into a 3D-printed thermoplastic polyurethane (TPU) matrix. This device simultaneously serves as an energy storage unit and a strain sensor. The incorporation of 1.5 wt% WS2 into TPU and treating with 0.5 wt% CB in ethanol within the TPU framework significantly enhanced the electrochemical and mechanical properties, achieving an areal capacitance of 206.5 mF cm−2, outstanding cyclic stability of 98 % over 10,000 charge-discharge cycles, and superior strain sensitivity. The electrochemical impedance spectroscopy, cyclic voltammetry, and galvanostatic charge-discharge analysis confirmed the high charge storage capability and low internal resistance of the composite electrodes. Additionally, strain-sensing experiments demonstrated a strong linear correlation between mechanical deformation and electrical resistance, with a gauge factor in the range of 1000–1500 and an R2 value of 0.939, validating the exceptional strain sensitivity and reliability of the sensor. By combining mechanical flexibility, superior electrochemical performance, and real-time strain sensing capabilities, the 3D-printed TPU/WS2/CB composite offers a highly adaptable and efficient solution for health monitoring devices, smart textiles, and next-generation electronic interfaces. This 3D-printed work advances dual-function energy storage and sensing systems, eliminating the need for separate sensing components while enhancing space utilization and reducing system complexity.
在这项研究中,通过将二硫化钨(WS2)和炭黑(CB)集成到3d打印热塑性聚氨酯(TPU)基体中,开发了多功能应变响应超级电容器(SC)。该装置同时作为能量存储单元和应变传感器。将1.5 wt% WS2掺入TPU中,并在TPU框架内用0.5 wt% CB在乙醇中处理,显著提高了TPU的电化学和机械性能,实现了206.5 mF cm - 2的面电容,在10,000次充放电循环中具有98%的优异循环稳定性,以及优异的应变灵敏度。电化学阻抗谱、循环伏安法和恒流充放电分析证实了复合电极具有较高的电荷存储能力和较低的内阻。此外,应变传感实验表明,机械变形与电阻之间存在较强的线性相关性,测量因子在1000-1500之间,R2值为0.939,验证了该传感器卓越的应变灵敏度和可靠性。通过结合机械灵活性、卓越的电化学性能和实时应变传感能力,3d打印TPU/WS2/CB复合材料为健康监测设备、智能纺织品和下一代电子接口提供了高度适应性和高效的解决方案。这项3d打印工作推进了双功能储能和传感系统,消除了对单独传感组件的需求,同时提高了空间利用率并降低了系统复杂性。
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Polymer Testing
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