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Spectrophotometric Estimation of Lanthanum with Alizarine Red S and Triton X-100 -Applications to Water Samples and Urine 茜素红S和Triton X-100分光光度法测定镧在水样和尿液中的应用
Pub Date : 2023-06-01 DOI: 10.33899/rjs.2023.178572
Ahmad G. Ismael, Salim J. Mohammed
This method involves the development of a highly sensitive spectrophotometric procedure to estimate lanthanum in an aqueous medium. The procedure involved the treatment of lanthanum with Alizarine Red S as chromophor reagent in presence of neutral surfactant (Triton X-100). At pH4.5, a soluble red complex was produced and exhibited absorption peak with maximum absorption at 523nm. The calibration graph was linear and compatible to Beer's law over the range of concentration 0.125 to 10.0 µg.ml -1 with determination coefficient (R 2 =0.9994). The apparent molar absorptivity of the complex La-ARS was found to be 0.7222x10 4 l.mol -1 .cm -1 which corresponds to the sensitivity of Sandell’s index of 1910.0 µg.cm -2 . The stoichiometric of the complex was studied and it is equal to 1:2 (La: ARS). The values of LOD, LOQ and the range of recovery percentage were estimated and found to be 0.04182, 0.04434 µg.ml -1 and 96.1% to 103.5%, respectively. The precision (RSD) was also calculated and found to be in the range 0.469 to 1.612. The proposed procedure has been applied successfully for the determination of lanthanum in natural waters and urine sample.
该方法涉及开发一种高灵敏度分光光度法程序来估计水介质中的镧。在中性表面活性剂(Triton X-100)存在下,用茜素红S作为显色剂处理镧。在pH4.5条件下,生成了可溶性红色配合物,并在523nm处出现了最大吸收峰。在0.125 ~ 10.0µg的浓度范围内,校准图呈线性,符合比尔定律。ml -1,测定系数(r2 =0.9994)。配合物La-ARS的表观摩尔吸光度为0.7222 × 10.4 l.mol -1 .cm -1,对应于桑德尔指数的灵敏度为1910.0µg。Cm -2。对配合物的化学计量学进行了研究,结果表明配合物的化学计量学比为1:2 (La: ARS)。定量限、定量限和回收率范围分别为0.04182、0.04434µg。Ml -1和96.1% ~ 103.5%。精密度(RSD)也进行了计算,发现在0.469至1.612的范围内。该方法已成功地应用于自然水体和尿液样品中镧的测定。
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引用次数: 0
Bioplastic Degradation, Production and Genetic Improvements of Bioplastic Producing Strains: A review 生物塑料降解、生产及产塑菌株的遗传改良研究进展
Pub Date : 2023-06-01 DOI: 10.33899/rjs.2023.178577
Rayan M. Faisal, R. Alsaffar
Plastics have been polluting the environment for a long time due to their persistence in all ecosystems and especially in the marine ecosystem. Until now, the best candidate found to substitute these products are the bioplastics. This is due to the presence of bacteria that can degrade them in nature and the similarities they show in their structure to petroleum-based plastics. These polymers are represented by polyhydroxy alcanoates (PHAs) and are produced naturally by bacterial cells as reservoir compounds for carbon and energy. Many PHA-producing microbial strains have been isolated worldwide including bacterial and fungal genera which could be used to produce bioplastics commercially. However, the major obstacle behind preventing the prevalence of bioplastics is their raw material cost. As a result, many studies have been conducted to produce PHAs, and their derivatives from waste raw materials. This will help to eliminate the cost of bioplastic production and simultaneously save the environment from an unfavorable accumulation of such wastes. Genetics has played an essential role in reducing the cost of bioplastics by manipulating microorganisms to produce more efficient bioplastic producers. Disrupting some genes and introducing others has been found to be helpful for the accumulation of PHAs in microbial producers.
塑料长期以来一直污染环境,因为它们在所有生态系统中都存在,特别是在海洋生态系统中。到目前为止,这些产品的最佳替代品是生物塑料。这是由于存在可以在自然界中降解它们的细菌,以及它们在结构上与石油基塑料的相似性。这些聚合物以多羟基己酸盐(PHAs)为代表,由细菌细胞自然产生,作为碳和能量的储存化合物。许多生产pha的微生物菌株已经在世界范围内被分离出来,包括细菌和真菌属,它们可以用于商业生产生物塑料。然而,阻止生物塑料普及的主要障碍是其原材料成本。因此,人们进行了许多研究,以从废弃原料中生产pha及其衍生物。这将有助于消除生物塑料生产的成本,同时使环境免于这类废物的不利积累。遗传学通过操纵微生物生产更高效的生物塑料生产商,在降低生物塑料成本方面发挥了重要作用。破坏某些基因并引入其他基因有助于微生物生产者中pha的积累。
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引用次数: 1
Shielding Properties of Al- Cu- Pb Alloys by XCOM and Experimental Data 铝-铜-铅合金的XCOM屏蔽性能及实验数据
Pub Date : 2023-06-01 DOI: 10.33899/rjs.2023.178582
Karam Abd Al- Aziz, M. Hamood, Laith Najam, Ayman Al Sawalha, Howaida Ahmed
The current study, the efficiency of many binary and triple aluminum alloys was examined for the alloy’s samples consisting of (Al-Cu-Pb). These alloys were manufactured in the laboratories of the physics Department and the manufacture of melting furnaces as well as the design of casting molds
本研究以(Al-Cu-Pb)合金为样品,考察了多种二元和三元铝合金的效率。这些合金是在物理系的实验室、熔炼炉的制造以及铸造模具的设计中制造的
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引用次数: 0
Physiological Effects of Biological Control Aureobasidium pullulans on Barley Varieties Infected with Rhizoctonia solani 根腐心菌对大麦品种的生理防治效果
Pub Date : 2023-03-01 DOI: 10.33899/rjs.2023.177288
Thuraya Al-zubaidy, Hadeel A. Al-Ameri
In a greenhouse experiment, barley varieties infected with R. solani showed a significant decrease in plant height, number of leaves, spike number, and number of grains in spike while the treatment of these varieties with biological control Aureobasidium pullulans showed a significant increase in plant height, number of leaves, number of spikes, and number of grains in spike compared to untreated one. moreover, of biological control A . pullulans to R . solani induced a significant improvement in vegetative growth, In the treatment with biological control A . pullulans in addition to R. solani , the highest rate of plant height was found in Aswad two rows variety and reaching 38.81cm. in the second reading, up from 16.52 cm. in the first reading. Among Rehan white six rows that received the treatment with R. solani alone, the lowest plant height, reached 22.08 cm. in the second reading, and it increased from the first reading. Ebaa 265 White six rows variety produced the most number in the treatment with biological control A. pullulans added to R. solani , reaching 8.66 leaves per plant., In the Nour white two rows variety, the lowest leaf rate was 6.6 leaves in the treatment R. solani alone. Aswad two rows variety exhibited the highest spike of barley when treated with biological control A. pullulans alone, reaching 5 spikes in the first, second, and third readings. Among the three readings, there were no spikes in Samir White variety when treated with R. solani alone. the average grains number in spikes, the highest rate was in the treatment of sterilized soil with formalin (control) in Aswad two rows variety which amounted to 7.67 grains in the second reading, up from 7.2 grains in the four reading. Biological control A. pullulans were added to R. solani in the variety Ebaa 265 White six rows, as it, and increased from 4.6 grains in the first to 9.8 in the second reading.
在大棚试验中,大麦品种感染番茄红霉后,其株高、叶片数、穗数和穗粒数均显著降低,而生物防治药剂普鲁兰短毛霉处理后,其株高、叶片数、穗数和穗粒数均显著高于未处理的品种。此外,生物防治A。普鲁兰到R。在生物防治a的处理下,茄尼对植株的营养生长有显著的促进作用。普鲁兰株高率最高的品种为阿斯瓦德(Aswad)二行品种,达到38.81cm。在第二次读数中,从16.52厘米上升。在第一次阅读中。热白6行单独处理的株高最低,为22.08 cm。在第二次阅读中,它比第一次阅读增加了。ebaa265白6行品种在加防菌处理中产量最高,达到8.66片/株。在白二行品种中,单独处理的叶片率最低,为6.6片。两行品种Aswad单作生物防治时,大麦穗数最高,一、二、三次读数均达5穗。在这三个读数中,萨米尔白品种在单独使用枯枯菌处理时没有出现峰值。在穗平均粒数方面,阿斯瓦德二行品种以福尔马林消毒土壤(对照)处理最高,第二次达7.67粒,高于四次的7.2粒。在ebaa265白6行中,在茄蚜中添加生物防治普鲁兰,从第一期的4.6粒增加到第二期的9.8粒。
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引用次数: 0
Effect of Lubanum and Potash Alum on Co-aggregation and Biofilm Formation of Porphyromonas gingivalis, Treponema denticola and Tannerella forsythia 苜蓿和钾明矾对牙龈卟啉单胞菌、齿状密螺旋体和连翘单宁菌共聚集和生物膜形成的影响
Pub Date : 2023-03-01 DOI: 10.33899/rjs.2023.177287
Sumaya A. S. M. Al-Hamdoni, A. Al-Rawi, E. Oparaji
Porphyromonas gingivalis , Treponema denticola , and Tannerella forsythia can co-aggregate in a more stable and resistant multispecies biofilm. Therefore, the current study aimed to test the effectiveness of lubanum and potash alum solutions, as a natural rinse, to affect the attachment between the cells and the multispecies biofilm of these periodontitis pathogens, and also to enhance the action of the chemical rinse, BioFresh K (chlorhexidine (CHX)). The results revealed that the solutions of 12 mg/ ml of both natural substances can prevent bacterial co-aggregation, and the solutions of 40 mg/ ml of natural substances and 1.2 mg/ml of CHX can affect the cells in their polymicrobial population after 1hr exposure. The results also revealed that increasing the concentration of lubanum made it possible to affect the resistant preformed multispecies biofilm and the effect became more maxima when it was used in combination with other agents. This combination is benefit in controlling
牙龈卟啉单胞菌、齿状密螺旋体和连翘Tannerella可以共同聚集在一个更稳定和耐药的多物种生物膜中。因此,本研究旨在测试lubanum和钾盐明矾溶液作为一种天然漂洗剂,对这些牙周炎病原体的细胞与多物种生物膜之间的附着的影响,以及增强化学漂洗剂BioFresh K(氯己定(CHX))的作用。结果表明,12 mg/ml的天然物质和1.2 mg/ml的CHX溶液均能阻止细菌共聚集,40 mg/ml的天然物质和1.2 mg/ml的CHX溶液在暴露1hr后对其多微生物群体中的细胞有影响。结果还表明,增加lubanum的浓度可以影响耐药的预成型多种生物膜,且与其他药剂合用效果最大。这种组合有利于控制
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引用次数: 0
Synthesis, Characterization of some new Heterocyclic Compounds Derived from Chalcones Containing Schiff Bases 含席夫碱查尔酮类杂环化合物的合成与表征
Pub Date : 2023-03-01 DOI: 10.33899/rjs.2023.177295
tharee Ghanim, A. Omar
The present work involves the new chalcones containing Schiff bases, In this study, firstly, reaction of 3-acetylcoumarin with terephthaldehyde to prepared chalcones which contains a free aldehyde group which has been reacted with (4-Aminoantipyrine) to prepare Schiff bases, which was reacted (sodiumazide) as precursor to form (Tetrazole) followed by condensation of these chalcones with some compounds (hydroxylamine, aminophenol, phenylenediamine, hydrazine, semicar-bazide, thiosemicarbazide, urea, thiourea and quanidine) as precursor to form Isoxazole, oxazepane, diazepine, pyrazoles and pyrimidine derivatives in basic medium using classical and ultrasonic technique. The comparison of the classical methods with ultrasonic methods. Was achieved. The compositions of the prepared compounds were confirmed by FT-IR and 1 H NMR spectroscopy.
本研究首先将3-乙酰香豆素与对苯二醛反应制得含有游离醛基团的查尔酮,该查尔酮与(4-氨基安替比林)反应制得席夫碱,以(钠氮肼)为前体反应制得(四唑),然后与某些化合物(羟胺、氨基酚、苯二胺、肼、半脲、硫代氨基脲)缩合。以尿素、硫脲和喹啶为前体,利用经典和超声技术在碱性介质中合成异恶唑、恶西烷、二氮卓、吡唑和嘧啶衍生物。经典方法与超声方法的比较。是实现。通过FT-IR和1h NMR对所制化合物的组成进行了确证。
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引用次数: 0
Spectrophotometric Determination of Isoniazid in Pharmaceutical Preparations Using Oxidative Coupling Reaction with 2,4-dinitrophenylhydrazine 用2,4-二硝基苯肼氧化偶联反应分光光度法测定药物制剂中的异烟肼
Pub Date : 2023-03-01 DOI: 10.33899/rjs.2023.178227
Shaimaa Nayif, D. Mohammed
A spectrophotometric method is proposed to determine isoniazid using oxidative coupling reaction. The proposed method depends on adding the oxidizing agent potassium periodate to the reagent solution 2,4-dinitrophenylhydrazine. Different optimum conditions are studied and explained based on various experiments and tests. The wavelength is (406) nm. Beer's law within the concentration (0.2-40) µg/ml, and with a molar absorptivity value of 0.2482 × l.mol -1 .cm -1 , while the recovery was (98.46%), and the relative standard deviation did not exceed 1.34. The method was successfully applied for the determination of isoniazid in its pharmaceutical preparations (medicine tablets).
提出了用氧化偶联反应分光光度法测定异烟肼的方法。所提出的方法依赖于在试剂溶液2,4-二硝基苯肼中加入氧化剂高碘酸钾。在各种实验和试验的基础上,对不同的最佳条件进行了研究和说明。波长为(406)nm。在浓度(0.2 ~ 40)µg/ml范围内,摩尔吸光度值为0.2482 × l.mol -1 .cm -1,回收率为98.46%,相对标准偏差不超过1.34。本法可用于异烟肼制剂(片剂)中异烟肼的含量测定。
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引用次数: 0
Biological Control of some Weeds with Aqueous Extract of Wheat (Triticum aestivum L.) 小麦水提液对几种杂草的生物防治
Pub Date : 2023-03-01 DOI: 10.33899/rjs.2023.177289
W. S. Hussain, Mahmmod Abbas, Raid Al-Safar
Allelopathic effects of wheat aqueous extract were studied on seeds germination and seedling growth of four weeds Canary grass ( Phalaris minor L.), Mallow ( Malva rotundifolia L.), Sweet clover ( Mililotus indica Mill)
研究了小麦水提液对金丝雀草(Phalaris minor L.)、锦葵(Malva rotundifolia L.)、甜三叶草(Mililotus indica Mill)种子萌发和幼苗生长的化感作用。
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引用次数: 0
The Identification and Synthesis of Barium-Substituted Lead Hydroxyapatite Structure (Pb10-x Bax (PO4)6(OH)2) by Ceramic Method 钡取代铅羟基磷灰石结构(Pb10-x Bax (PO4)6(OH)2)的陶瓷鉴定与合成
Pub Date : 2023-03-01 DOI: 10.33899/rjs.2023.177294
Mohammed A. B. Abdul Jabar
The substitution of barium ion (Ba 2+ ) with lead ion (Pb 2+ ) in the following composition: Pb 10-x Ba x (PO 4 ) 6 (OH) 2 has been investigated by an X-ray diffractometer. Samples with the range x=0 up to x=5 were calcined at 800 ºC for 25 hours, and the samples with the range from x=6 up to x=10 were calcined at 1100 ºC for 15 hours. The solid solutions hydroxyapatite samples are synthesized by the ceramic method. It was established that the sample with x=0 showed only reflections of composition Pb 10 (PO 4 ) 6 (OH) 2 , while the sample with x=10 showed only reflections of composition Ba 10 (PO 4 ) 6 (OH) 2 . The Samples with x = 1–9 showed more reflections called "unknown phase" besides those of pure hydroxyapatite.
用x射线衍射仪研究了铅离子(pb2 +)取代钡离子(ba2 +)在pb10 -x bax (po4) 6 (OH) 2中的作用。范围为x=0至x=5的样品在800℃下煅烧25小时,范围为x=6至x=10的样品在1100℃下煅烧15小时。采用陶瓷法制备了固溶体羟基磷灰石样品。结果表明,当x=0时,样品仅反射成分pb10 (po4) 6 (OH) 2,而当x=10时,样品仅反射成分ba10 (po4) 6 (OH) 2。x = 1 ~ 9时,除了纯羟基磷灰石外,样品还显示出更多的“未知相”反射。
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引用次数: 1
Survey and Prevalence of Lice Infestation the Pigeons (Columba livia domestica) in Kurdistan Region-Iraq 伊拉克库尔德斯坦地区鸽子(Columba livia domestica)虱病调查及流行情况
Pub Date : 2023-03-01 DOI: 10.33899/rjs.2023.177282
M. Al-badrani, S. Al-muffti
{"title":"Survey and Prevalence of Lice Infestation the Pigeons (Columba livia domestica) in Kurdistan Region-Iraq","authors":"M. Al-badrani, S. Al-muffti","doi":"10.33899/rjs.2023.177282","DOIUrl":"https://doi.org/10.33899/rjs.2023.177282","url":null,"abstract":"","PeriodicalId":20803,"journal":{"name":"Rafidain journal of science","volume":"30 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77664032","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Rafidain journal of science
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