Introduced work addresses the research gap concerning the structural role and radiation-shielding influence of Nd2O3 within multi-component borophosphate glasses, which are promising candidates for lead-free, transparent radiation shielding. A series of glasses with composition (35-x)B2O3–30Na2O–30P2O5–5Bi2O3-xNd2O3 (where x = 0, 0.1, 0.25, 0.5, 0.75, 1 mol%) were synthesized via the melt-quenching technique at 1100 °C. Their amorphous nature was confirmed by XRD, while FTIR spectroscopy coupled with deconvolution analysis was employed to probe structural modifications. Physical properties, including density, molar volume, and oxygen packing density, were measured experimentally. Gamma-ray and neutron shielding parameters were comprehensively evaluated over 0.015–15 MeV using the Phy-X/PSD software. The results reveal a consistent densification of the glass network with Nd2O3 addition: density increased from 2.82 to 3.02 g cm-3, while molar volume decreased from 38.596 to 36.924 cm3 mol-1. The fraction of four-coordinated boron (N4) remained nearly constant (∼0.83–0.84), indicating Nd2O3 acts primarily as a modifier without disrupting the established boron coordination equilibrium. Significant improvements in radiation shielding were observed: the linear attenuation coefficient at 0.015 MeV rose from 72.8 to 82.3 cm-1, and the half-value layer at 15 MeV decreased from 9.154 to 8.368 cm. The fast neutron removal cross-section also increased from 0.0930 to 0.0978 cm-1 with Nd2O3 doping. Results reveal that Nd2O3 incorporation enhances glass compactness and radiation attenuation without inducing major structural reorganization. The sample with 1 mol% Nd2O3 (Nd1) exhibited the most promising shielding performance, combining high density, low photon penetration, and effective neutron attenuation. These findings provide a clear structure–property relationship essential for designing efficient, non-toxic, and transparent radiation shielding glasses for medical, industrial, and nuclear applications.
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