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α-LiIO3 single crystals grown from aqueous solutions containing L-Alanine and glycine 从含有l -丙氨酸和甘氨酸的水溶液中生长α-LiIO3单晶
IF 2.8 3区 物理与天体物理 Q3 CHEMISTRY, PHYSICAL Pub Date : 2026-01-31 DOI: 10.1016/j.radphyschem.2026.113685
Astghik Danghyan, Ruzan Sukiasyan, Ruben Apreyan, Liana Bezhanova, Nelli Gharibyan, Armen Atanesyan
The present study focuses on the growth and investigation of pure α-LiIO3 single crystals, as well as single crystals of α-LiIO3 grown from aqueous solutions containing amino acids L-alanine (L-Ala) and Glycine (Gly), using the slow evaporation solution growth technique. An attempt was made to grow α-LiIO3 crystals from an aqueous solution of lithium iodate containing amino acids to enhance the nonlinear optical and mechanical properties of α-LiIO3 crystals suitable for both academic and industrial applications. The grown bulk crystals were characterized by means of several complementary techniques, such as optical spectroscopy, IR spectroscopy, single-crystal X-ray diffraction, powder X-ray diffraction (PXRD), and measurements of the second harmonic generation efficiency. In the presence of an amino acid in the solution, an increase in the rate of crystal growth was experimentally observed. In the IR spectra of α-LiIO3:L-Ala and α-LiIO3:Gly crystals, absorption bands appear that are absent in pure lithium iodate, but are characteristic of amino acids. The lattice parameters of the grown crystals were confirmed through the X-ray technique. Single crystal X-ray and powder X-ray diffraction measurements revealed that pure, as well as α-LiIO3:L-Ala and α-LiIO3:Gly crystals maintained a hexagonal structure, remaining single-phase within the amino acid's concentration range (5 mol%), indicating that the presence of L-Ala and Gly in solution does not violate the parameters of the crystal lattice. It was obtained that the second harmonic generation activity of the α-LiIO3:L-Ala and α-LiIO3:Gly crystals is higher than that of the pure α-LiIO3 crystal. The enhancement of the optical properties of α-LiIO3:L-Ala and α-LiIO3:Gly crystals in comparison with pure LiIO3 has been precisely examined by UV–Visible spectral analysis within the wavelength range of 280–800 nm. UV–Visible spectral analysis is also used to evaluate the band gap.
本研究主要研究了纯α-LiIO3单晶的生长和研究,以及采用慢蒸发溶液生长技术在含有l -丙氨酸(L-Ala)和甘氨酸(Gly)的水溶液中生长α-LiIO3单晶。为了提高α-LiIO3晶体的非线性光学和力学性能,我们尝试在含氨基酸的碘酸锂水溶液中生长α-LiIO3晶体,以适应学术和工业应用。利用光谱学、红外光谱、单晶x射线衍射、粉末x射线衍射(PXRD)和二次谐波产生效率等互补技术对生长的块状晶体进行了表征。在溶液中存在氨基酸时,实验观察到晶体生长速率的增加。在α-LiIO3:L-Ala和α-LiIO3:Gly晶体的红外光谱中,出现了纯碘酸锂所没有的吸收带,这是氨基酸的特征。通过x射线技术确定了生长晶体的晶格参数。单晶x射线衍射和粉末x射线衍射测量表明,纯α-LiIO3:L-Ala和α-LiIO3:Gly晶体保持六方结构,在氨基酸浓度范围(5 mol%)内保持单相,表明溶液中L-Ala和Gly的存在不违反晶格参数。结果表明,α-LiIO3:L-Ala和α-LiIO3:Gly晶体的二次谐波生成活性高于纯α-LiIO3晶体。在280 ~ 800 nm波长范围内,通过紫外可见光谱分析,精确地考察了α-LiIO3:L-Ala和α-LiIO3:Gly晶体与纯LiIO3晶体相比,光学性能的增强。紫外可见光谱分析也用于评价带隙。
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引用次数: 0
Radionuclide adsorption and natural radioactivity in microplastics: An emerging toxicological hazard 微塑料中的放射性核素吸附和天然放射性:一种新出现的毒理学危害
IF 2.8 3区 物理与天体物理 Q3 CHEMISTRY, PHYSICAL Pub Date : 2026-01-31 DOI: 10.1016/j.radphyschem.2026.113677
Akbar Abbasi , Mayeen Uddin Khandaker , Fatemeh Mirekhtiary
To unveil the natural radioactivity levels in various types of petrochemical-derived microplastics (MPs), a study was conducted using a gamma spectrometry system to measure 226Ra, 232Th, and 40K in microplastics. The maximum value of all measured radionuclides was observed in polyethylene terephthalate (PET) microplastic samples. The measured activity concentrations ranged from values below the minimum detectable limit (MDA = 2 Bq·kg−1) up to 5.14 ± 0.11 Bq·kg−1 for 226Ra, from below the MDA (2.5 Bq·kg−1) up to 3.17 ± 0.04 Bq·kg−1 for 232Th, and from 15.18 ± 0.08 Bq·kg−1 to 47.14 ± 1.85 Bq·kg−1 for 40K. The interactions between Uranium-232 (232U) and Cesium-137 (137Cs) with commonly used microplastics in the food industry have been explored in aqueous environments that mimic seawater and freshwater. Various physicochemical conditions, including temperature (T) and pH, were analyzed to determine the adsorption coefficient (Kd). The experiments were performed at different pH levels (6, 8.5), and the adsorption efficiency was evaluated primarily as a function of temperature (20, 28, 35 °C). The highest Kd for both uranium (0.284 ± 0.014 Bq kg−1) and Cesium (0.107 ± 0.009 Bq kg−1) was observed in freshwater at T = 20 °C, pH = 6, and T = 20 °C, pH = 8.5, respectively. This research demonstrated that the 232U adsorption coefficient by PET was higher than that of 137Cs in freshwater and seawater environments.
为了揭示各种石化衍生微塑料(MPs)中的天然放射性水平,研究人员使用伽马能谱系统测量微塑料中的226Ra, 232Th和40K。在聚对苯二甲酸乙二醇酯(PET)微塑料样品中观察到所有测量的放射性核素的最大值。测得的活性浓度范围为:226Ra低于最低检测限(MDA = 2 Bq·kg - 1)至5.14±0.11 Bq·kg - 1, 232Th低于MDA (2.5 Bq·kg - 1)至3.17±0.04 Bq·kg - 1, 40K为15.18±0.08 Bq·kg - 1至47.14±1.85 Bq·kg - 1。在模拟海水和淡水的水环境中,研究了铀-232 (232U)和铯-137 (137Cs)与食品工业中常用的微塑料之间的相互作用。分析了不同的物理化学条件,包括温度(T)和pH,以确定吸附系数(Kd)。实验在不同的pH值(6、8.5)下进行,吸附效率主要作为温度(20、28、35°C)的函数进行评估。在T = 20°C, pH = 6和T = 20°C, pH = 8.5的淡水中,铀和铯的Kd值分别为0.284±0.014 Bq kg - 1和0.107±0.009 Bq kg - 1。研究表明,在淡水和海水环境中,PET对232U的吸附系数高于137Cs。
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引用次数: 0
Experimental and theoretical insights into Ce3+-doped optical fiber luminescence mechanisms under X-rays x射线下掺Ce3+光纤发光机理的实验与理论研究
IF 2.9 3区 物理与天体物理 Q3 CHEMISTRY, PHYSICAL Pub Date : 2026-01-31 DOI: 10.1016/j.radphyschem.2026.113675
Ismail Zghari, Hicham El Hamzaoui, Adriana Morana, Youcef Ouerdane, Bruno Capoen, Sylvain Girard, Aziz Boukenter, Mohamed Bouazaoui
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引用次数: 0
Effect of Europium oxide on structural, mechanical, optical, and radiation shielding properties of silver–doped oxyfluoro phospho–silicate glasses 氧化铕对掺银氟氧磷硅酸盐玻璃结构、机械、光学和辐射屏蔽性能的影响
IF 2.8 3区 物理与天体物理 Q3 CHEMISTRY, PHYSICAL Pub Date : 2026-01-30 DOI: 10.1016/j.radphyschem.2026.113678
S.A. Bassam , K.A. Naseer , C.S. Suchand Sangeeth , Mohammed S. Alqahtani , Muhammed Arshad Thottappali , Mayeen Uddin Khandaker , E. El Shiekh
Five distinctive series of glasses were synthesized to investigate the effect of Eu3+ ions on the structural, elastic, optical, and gamma–ray shielding properties of the silver–doped alkaline oxyfluro phospho–silicate glasses, featuring a nominal composition of 50P2O5 + 15SiO2 + 10BaF2 + 10SrF2 + (15−X) AgNO3 + XEu2O3, where (X = 0.1, 0.5, 1, 1.5, and 3 wt%). The preparation was carried out with the traditional melt–quench technique, and the presence of an amorphous nature was confirmed through the XRD spectrum. The functional groups present in the glass network were identified utilizing the FTIR spectra. Some of the physical, structural, and elastic properties of the glasses were evaluated. The inclusion of Eu3+ ions densifies the glass matrix which significantly increases the density (2.061–2.308 g/cm3), refractive index (1.672–1.766), and elastic moduli (Young's modulus 54.1–104.1 GPa) while decreasing the molar volume (99.373–91.026 cm3/mol). These glasses are suitable for radiation shielding applications due to their enhanced effectiveness in attenuating high–energy radiation, as demonstrated by the increase in mass attenuation coefficient (MAC, up to 5.678 cm2/g at 0.0395 MeV) and the reduction in both direct (3.221–3.125 eV) and indirect (2.608–2.463 eV) optical band gaps, which indicate improved photon absorption. The results showed that the glass with the highest Eu2O3 content has the highest mass attenuation coefficient and thus has the best attenuation performance.
为了研究Eu3+离子对掺银碱性氧氟磷硅酸盐玻璃的结构、弹性、光学和伽马射线屏蔽性能的影响,合成了五种不同系列的玻璃,其公称组成为50P2O5 + 15SiO2 + 10BaF2 + 10SrF2 +(15−X) AgNO3 + XEu2O3,其中(X = 0.1, 0.5, 1,1.5和3wt %)。采用传统的熔融淬火工艺进行制备,并通过XRD谱分析证实了材料的无定形性质。利用FTIR光谱确定了玻璃网络中的官能团。对玻璃的一些物理、结构和弹性性能进行了评价。Eu3+离子的加入使玻璃基体致密化,使其密度(2.061 ~ 2.308 g/cm3)、折射率(1.672 ~ 1.766)和弹性模量(杨氏模量54.1 ~ 104.1 GPa)显著增加,而摩尔体积(99.373 ~ 91.026 cm3/mol)显著减小。这些玻璃适合于辐射屏蔽应用,因为它们在衰减高能辐射方面具有增强的有效性,如质量衰减系数(MAC,在0.0395 MeV时高达5.678 cm2/g)的增加和直接(3.221-3.125 eV)和间接(2.608-2.463 eV)光学带隙的减小,这表明光子吸收得到了改善。结果表明,Eu2O3含量最高的玻璃具有最高的质量衰减系数,因此具有最佳的衰减性能。
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引用次数: 0
Gamma irradiation-induced enhancement of agar-based bioplastics incorporating poly(lactic acid) and poly(butylene adipate-co-terephthalate) γ射线辐照增强聚乳酸和聚己二酸丁二醇-对苯二甲酸酯的琼脂基生物塑料
IF 2.8 3区 物理与天体物理 Q3 CHEMISTRY, PHYSICAL Pub Date : 2026-01-30 DOI: 10.1016/j.radphyschem.2026.113673
Angelica Isabella Christian , Farah Nurlidar , Dien Puji Rahayu , Ade Lestari Yunus , Tita Puspitasari , Yudi Nugraha Thaha , Lutviasari Nuraini , Rossy Choreun Nissa , Yeyen Nurhamiyah
This study explores the fabrication of biodegradable bioplastics based on agar, poly(lactic acid) (PLA), and poly(butylene adipate-co-terephthalate) (PBAT), enhanced through cobalt-60 gamma irradiation to improve their mechanical, thermal, and degradation behavior. A range of irradiation doses (0–50 kGy) was applied to evaluate the effects of crosslinking and chain scission on material performance. The tensile strength showed a marked improvement, increasing from 2.72 ± 1.94 MPa (0 kGy) to 6.01 ± 0.92 MPa at 30 kGy, indicating enhanced mechanical integrity due to effective crosslinking. In parallel, water absorption decreased dramatically from 83.03% to 15.22%, reflecting a significant reduction in hydrophilicity. At higher doses, degradation processes became more prominent, as evidenced by increased melt flow rate and biodegradability. These findings demonstrate that controlled gamma irradiation is an effective approach to fine-tune the performance and environmental responsiveness of agar-based bioplastics, making them more suitable for sustainable packaging and related applications.
本研究探索了基于琼脂、聚乳酸(PLA)和聚己二酸丁二醇酯(PBAT)的可生物降解生物塑料的制备,并通过钴-60 γ辐射增强以改善其机械、热和降解行为。采用0-50 kGy辐照剂量范围评价交联和断链对材料性能的影响。拉伸强度明显提高,从2.72±1.94 MPa (0 kGy)增加到6.01±0.92 MPa (30 kGy),表明有效交联提高了机械完整性。同时,吸水率从83.03%急剧下降到15.22%,反映亲水性显著降低。在较高的剂量下,降解过程变得更加突出,如增加的熔体流动速率和生物降解性所证明的那样。这些发现表明,受控伽马辐射是一种有效的方法,可以微调琼脂基生物塑料的性能和环境响应性,使其更适合可持续包装和相关应用。
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引用次数: 0
Enhanced sono-radio dynamic therapy of non-small cell lung cancer using a polydopamine coated manganese dioxide-gold nanosystem: reactive oxygen species amplification and tumor microenvironment modulation 使用聚多巴胺包被二氧化锰-金纳米系统增强非小细胞肺癌的声放动态治疗:活性氧扩增和肿瘤微环境调节
IF 2.8 3区 物理与天体物理 Q3 CHEMISTRY, PHYSICAL Pub Date : 2026-01-29 DOI: 10.1016/j.radphyschem.2026.113648
F. Mortazavi , H. Haghighi , P. Tamaddon , A. Ketabi , H. Heli , N. Sattarahmady
Radiotherapy (RT) and sonodynamic therapy (SDT) are reactive oxygen species (ROS)-dependent cancer treatments that suffer from limited efficacy in hypoxic and glutathione (GSH)-rich tumor microenvironments (TMEs). In this study, we developed and characterized a multifunctional polydopamine coated manganese dioxide-gold nanosystem (GMnD) as a dual sensitizer to enhance the therapeutic outcomes of RT and SDT in non-small cell lung carcinoma (NSCLC). Polydopamine coating enhanced the biocompatibility of the nanosystem and imparts stimuli-responsive properties. GMnD exhibited broad optical absorptions (visible to near-infrared), a narrow band gap (1.1 eV), and a high sonothermal conversion efficiency (80.7 %), enabling strong electromagnetic sensitization. On A549 NSCLC cells, the nanosystem in combination with ultrasound (US) and RT significantly increased ROS generation, and induced mitochondrial dysfunction, GSH depletion, catalase-like activity, and sonoporation. These effects led to synergistic cytotoxicity, correlating with mitochondrial membrane potential loss and decreased cell viability. In overall, GMnD presented a promising strategy for improving ROS-mediated combination therapy by modulating the hypoxic TME and disrupting mitochondrial redox balance.
放射治疗(RT)和声动力治疗(SDT)是依赖活性氧(ROS)的癌症治疗方法,在缺氧和谷胱甘肽(GSH)丰富的肿瘤微环境(TMEs)中疗效有限。在这项研究中,我们开发并表征了一种多功能多多巴胺包被二氧化锰-金纳米系统(GMnD)作为双重增敏剂,以提高RT和SDT治疗非小细胞肺癌(NSCLC)的疗效。聚多巴胺包被增强了纳米系统的生物相容性,并赋予其刺激响应特性。GMnD具有广泛的光学吸收(可见光到近红外),窄带隙(1.1 eV)和高声热转换效率(80.7%),具有强的电磁敏化能力。在A549 NSCLC细胞中,纳米系统联合超声(US)和RT显著增加ROS的产生,并诱导线粒体功能障碍、GSH消耗、过氧化氢酶样活性和超声穿孔。这些作用导致协同细胞毒性,与线粒体膜电位损失和细胞活力下降有关。总体而言,GMnD通过调节缺氧TME和破坏线粒体氧化还原平衡,为改善ros介导的联合治疗提供了一种有希望的策略。
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引用次数: 0
EPR of neutron-radiation-induced defects in Gd3Ga5O12 Gd3Ga5O12中子辐射缺陷的EPR
IF 2.8 3区 物理与天体物理 Q3 CHEMISTRY, PHYSICAL Pub Date : 2026-01-29 DOI: 10.1016/j.radphyschem.2026.113664
Jekabs Cirulis, Uldis Rogulis, Nina Mironova-Ulmane, Guntars Zvejnieks, Andris Antuzevics
Stable radiation-induced defects can have significant effects on materials usability in solid state lasers, scintillators, and other devices that may be exposed to ionising radiation. This study investigates several paramagnetic centres in gadolinium gallium garnet (Gd3Ga5O12). Analysis of single-crystal electron paramagnetic resonance (EPR) spectra was performed after irradiation with fast neutron radiation. It was determined that paramagnetic centres with highly anisotropic g-factor values are formed and remain stable well above room temperature. The irregular defect symmetry suggests that one of the defects is formed along the direction of cubic lattice diagonal. This defect was attributed to Ge centres resulting from Ga neutron capture coupled with multiple oxygen vacancies. The origin of other paramagnetic centres is discussed based on unusual temperature dependencies of EPR spectra and ab initio calculations.
在固态激光器、闪烁体和其他可能暴露于电离辐射的器件中,稳定的辐射诱导缺陷会对材料的可用性产生重大影响。本文研究了钆镓石榴石(Gd3Ga5O12)中的几个顺磁中心。对快中子辐照后的单晶电子顺磁共振(EPR)谱进行分析。确定形成了具有高度各向异性g因子值的顺磁中心,并在室温以上保持稳定。缺陷的不规则对称性表明其中一个缺陷是沿立方晶格对角线方向形成的。这种缺陷是由于Ga中子捕获与多个氧空位耦合而产生的Ge中心。根据EPR谱的异常温度依赖性和从头计算,讨论了其他顺磁中心的起源。
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引用次数: 0
Relationship between exposure index and radiographic noise under varying exposure conditions for chest and abdominal radiography 胸腹造影不同照射条件下暴露指数与影像噪声的关系
IF 2.8 3区 物理与天体物理 Q3 CHEMISTRY, PHYSICAL Pub Date : 2026-01-28 DOI: 10.1016/j.radphyschem.2026.113676
Nobukazu Tanaka , Yongsu Yoon , Tadamitsu Ideguchi
Recently, flat-panel detector (FPD) systems have been developed to display exposure index (EI) values on the console immediately after exposure, thereby enhancing user comprehension. However, differences between examination rooms and bedside imaging can lead to discrepancies in EI values. This study aimed to investigate the relationship between EI and radiographic noise for an indirect-FPD system under varying exposure conditions in digital chest and abdominal radiography. For chest radiography, the following exposure conditions were used: 120 kV with an anti-scatter grid and 70 kV without a grid. For abdominal radiography, the exposure conditions were: 80 kV with a high-ratio (12:1) grid and 80 kV with a low-ratio (5:1) grid. Acrylic phantoms of different thicknesses were used for both chest and abdominal radiography. Radiographic noise was assessed using the Wiener spectrum (WS). For chest radiography, when the incident doses on the imaging detector were identical, the EI values displayed at 120 kV were significantly higher than those at 70 kV. At similar EI values, WS values were lower at 70 kV than at 120 kV. For abdominal radiography, when the incident doses on the imaging detector were identical, the displayed EI values with the high-ratio grid were considerably higher than those with the low-ratio grid. At similar EI values, WS values were lower with the low-ratio grid than with the high-ratio grid. Even when EI values are similar for the same anatomical regions, variations in exposure conditions, such as tube voltage and grid type, affect radiographic noise.
最近,平板探测器(FPD)系统已经开发出来,可以在暴露后立即在控制台上显示暴露指数(EI)值,从而增强用户的理解。然而,检查室和床边影像的差异会导致EI值的差异。本研究旨在探讨在数字胸腹x线摄影中不同暴露条件下,间接fpd系统的EI与放射噪声之间的关系。胸部x线摄影使用以下暴露条件:120kv带防散射栅格和70kv无栅格。对于腹部x线摄影,暴露条件为:80kv高比值栅格(12:1)和80kv低比值栅格(5:1)。胸部和腹部x线摄影均采用不同厚度的丙烯酸胶片。采用维纳谱(Wiener spectrum, WS)评估放射成像噪声。对于胸部x线摄影,当成像探测器上的入射剂量相同时,120 kV时显示的EI值明显高于70 kV。在EI值相近的情况下,70 kV的WS值低于120 kV。对于腹部x线摄影,当成像探测器上的入射剂量相同时,高比例网格显示的EI值明显高于低比例网格显示的EI值。在EI值相近的情况下,低比例网格的WS值比高比例网格的WS值要低。即使相同解剖区域的EI值相似,暴露条件的变化,如管电压和栅格类型,也会影响放射成像噪声。
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引用次数: 0
Size-controlled Gd2O3 nanospheres reinforced B4C/HDPE nanocomposites for neutron and gamma-ray complex radiation shielding 控制尺寸的Gd2O3纳米球增强B4C/HDPE纳米复合材料用于中子和伽马射线复合辐射屏蔽
IF 2.8 3区 物理与天体物理 Q3 CHEMISTRY, PHYSICAL Pub Date : 2026-01-28 DOI: 10.1016/j.radphyschem.2026.113679
Zhipeng Huo , Yidong Lu , Jie Zhang , Guoqiang Zhong
Gd2O3 nanospheres with three controlled sizes were synthesized via a homogeneous precipitation method. Both synthesized and commercial Gd2O3 fillers were employed as bifunctional neutron and gamma radiation absorbing agents to fabricate radiation shielding materials. FESEM confirmed the nanospherical morphology of synthesized Gd2O3 fillers. HRTEM and SEAD indicate that all Gd2O3 fillers are polycrystalline. HRTEM confirmed that the synthesized Gd2O3 fillers have (321), (400), and (521) exposed crystal planes, while the commercial Gd2O3 fillers have (222) exposed crystal planes, aligning with the corresponding XRD patterns. FESEM of fracture surfaces revealed a more uniform distribution of synthesized Gd2O3 nanosphere fillers within the HDPE matrix compared to the irregularly shaped commercial Gd2O3 fillers. The high specific surface area and superior dispersibility of synthesized Gd2O3 fillers enhanced the overall performance of the nanocomposite. Notably, nanocomposites containing synthesized Gd2O3-Ⅱ nanospheres with an average size of 82.6 ± 14.2 nm achieved a neutron and gamma shielding rates of 99.3 % and 73.7 %, the Σ, μ, μm, HVL are 0.239 cm−1, 0.092 cm−1, 0.076 cm2/g, 7.57 cm, correspondingly, at a thickness of 15 cm, demonstrating its potential for high-performance radiation shielding applications. This study provides a novel strategy for designing lightweight, high-performance radiation shielding materials for nuclear facilities, aerospace applications, radioactive waste conditioning and relative fields.
采用均匀沉淀法合成了三种粒径可控的Gd2O3纳米球。采用合成的和市售的Gd2O3填料作为双功能中子和γ辐射吸收剂制备辐射屏蔽材料。FESEM证实了合成的Gd2O3填料的纳米球形形貌。HRTEM和SEAD表明,所有的Gd2O3填料都是多晶的。HRTEM证实,合成的Gd2O3填料具有(321)、(400)和(521)暴露晶面,而工业Gd2O3填料具有(222)暴露晶面,与相应的XRD图谱一致。断裂表面的FESEM显示,与不规则形状的工业Gd2O3填料相比,合成的Gd2O3纳米球填料在HDPE基体中的分布更为均匀。合成的Gd2O3填料具有较高的比表面积和良好的分散性,提高了纳米复合材料的整体性能。值得注意的是,含有平均尺寸为82.6±14.2 nm的Gd2O3-Ⅱ纳米球的纳米复合材料的中子和伽马屏蔽率分别为99.3%和73.7%,Σ, μ, μm, HVL分别为0.239 cm−1,0.092 cm−1,0.076 cm2/g, 7.57 cm,厚度为15 cm,显示了其高性能辐射屏蔽应用的潜力。该研究为核设施、航空航天、放射性废物处理等相关领域设计轻量化、高性能辐射屏蔽材料提供了新思路。
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引用次数: 0
Monte Carlo evaluation of a novel functionally graded tri-layer composite system for MOX spent nuclear fuel casks 一种新型功能分级三层复合材料体系的蒙特卡罗评价
IF 2.8 3区 物理与天体物理 Q3 CHEMISTRY, PHYSICAL Pub Date : 2026-01-23 DOI: 10.1016/j.radphyschem.2026.113663
Ayman Abu Ghazal , Rawand Alakash , Feras Afaneh
Spent nuclear fuel (SNF) transport and dry-storage containers are crucial for guaranteeing the safe confinement and radiation shielding of highly radioactive materials at the conclusion of the nuclear fuel cycle. This work presents a comprehensive Monte Carlo investigation of a novel Tri-Layer Adaptive Composite System (TACS) developed for radiation shielding in SNF transport and dry-storage casks. The proposed architecture adopts a functionally graded design composed of three optimized layers: a Refractory High-Entropy Alloy (RHEA) inner layer providing structural integrity and initial gamma attenuation, a Hydrogenated Boron Nitride (HBN) composite layer serving as the primary neutron moderator and absorber, and an outer Tungsten–Metallic Glass Matrix Composite (W-MGMC) layer delivering further suppression of residual gamma and neutron radiation. Radiation transport simulations were performed using MCNP5, modeling a homogenized pressurized water reactor (PWR) mixed-oxide (MOX) spent fuel assembly with a heavy-metal loading of 0.492 tHM and a representative burnup of 50 GWd tHM−1. Conservative, bounding source terms were employed, assuming 137Cs as the dominant gamma-emitting radionuclide and 244Cm as the primary neutron source via spontaneous fission, for cooling times up to 50 years. The results show smooth and monotonic attenuation of both photon and neutron fields across the multilayer system, with no localized dose-rate hot spots. Energy-dependent total microscopic photon cross-section analyses confirm substantial interaction probabilities in the high-Z RHEA and W-MGMC layers across the relevant energy range, explaining the rapid suppression of gamma flux and dose observed within these regions. At the same time, HBN exhibits minimal photon interaction consistent with its low-Z composition. Half-value layer (HVL) analysis further quantifies the shielding efficiency, revealing that RHEA and W-MGMC exhibit the smallest gamma HVLs (≈0.8 cm). In contrast, HBN provides the lowest neutron HVL (≈1.5 cm), confirming its dominant role in fast-neutron removal. At the cask surface, the TACS configuration achieves a total dose rate of approximately 0.10 mSv h−1, corresponding to a safety margin of about 20 × below the IAEA SSR-6 transport limit. Comparative benchmarking against conventional Fe–PE–Pb and steel–air–concrete shielding configurations demonstrates the superior shielding efficiency and compactness of the proposed system, particularly for neutron-dominated, high-burnup MOX fuel inventories.
乏燃料运输和干贮存容器对于在核燃料循环结束时保证高放射性材料的安全限制和辐射屏蔽至关重要。本文对一种新型三层自适应复合材料系统(TACS)进行了全面的蒙特卡罗研究,该系统用于SNF运输和干储存桶的辐射屏蔽。所提出的结构采用功能梯度设计,由三层优化组成:具有结构完整性和初始伽马衰减的耐火高熵合金(RHEA)内层,作为主要中子慢慢剂和吸收剂的氢化氮化硼(HBN)复合材料层,以及具有进一步抑制残余伽马和中子辐射的钨金属玻璃基复合材料(W-MGMC)外层。采用MCNP5进行辐射输运模拟,模拟均质压水堆(PWR)混合氧化物(MOX)乏燃料组件,其重金属负荷为0.492 tHM,代表性燃耗为50 GWd tHM−1。采用保守的边界源项,假设137Cs为主要的伽马发射放射性核素,244Cm为自发裂变的主要中子源,冷却时间长达50年。结果表明,光子场和中子场在多层体系中都有平滑单调的衰减,没有局部的剂量率热点。能量依赖的总微观光子截面分析证实了高z RHEA和W-MGMC层在相关能量范围内的大量相互作用概率,解释了在这些区域内观察到的伽马通量和剂量的快速抑制。同时,HBN表现出最小的光子相互作用,这与其低z组成相一致。半值层(HVL)分析进一步量化了屏蔽效率,表明RHEA和W-MGMC的γ HVL最小(≈0.8 cm)。相比之下,HBN提供了最低的中子HVL(≈1.5 cm),证实了它在快中子去除中的主导作用。在桶表面,TACS结构的总剂量率约为0.10 mSv h−1,对应于比IAEA SSR-6传输限值低约20倍的安全边际。与传统的Fe-PE-Pb和钢-空气-混凝土屏蔽结构的比较基准表明,所提出的系统具有优越的屏蔽效率和紧凑性,特别是对于以中子为主的高燃耗MOX燃料库存。
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Radiation Physics and Chemistry
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