The present study focuses on the growth and investigation of pure α-LiIO3 single crystals, as well as single crystals of α-LiIO3 grown from aqueous solutions containing amino acids L-alanine (L-Ala) and Glycine (Gly), using the slow evaporation solution growth technique. An attempt was made to grow α-LiIO3 crystals from an aqueous solution of lithium iodate containing amino acids to enhance the nonlinear optical and mechanical properties of α-LiIO3 crystals suitable for both academic and industrial applications. The grown bulk crystals were characterized by means of several complementary techniques, such as optical spectroscopy, IR spectroscopy, single-crystal X-ray diffraction, powder X-ray diffraction (PXRD), and measurements of the second harmonic generation efficiency. In the presence of an amino acid in the solution, an increase in the rate of crystal growth was experimentally observed. In the IR spectra of α-LiIO3:L-Ala and α-LiIO3:Gly crystals, absorption bands appear that are absent in pure lithium iodate, but are characteristic of amino acids. The lattice parameters of the grown crystals were confirmed through the X-ray technique. Single crystal X-ray and powder X-ray diffraction measurements revealed that pure, as well as α-LiIO3:L-Ala and α-LiIO3:Gly crystals maintained a hexagonal structure, remaining single-phase within the amino acid's concentration range (5 mol%), indicating that the presence of L-Ala and Gly in solution does not violate the parameters of the crystal lattice. It was obtained that the second harmonic generation activity of the α-LiIO3:L-Ala and α-LiIO3:Gly crystals is higher than that of the pure α-LiIO3 crystal. The enhancement of the optical properties of α-LiIO3:L-Ala and α-LiIO3:Gly crystals in comparison with pure LiIO3 has been precisely examined by UV–Visible spectral analysis within the wavelength range of 280–800 nm. UV–Visible spectral analysis is also used to evaluate the band gap.
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