Pub Date : 2020-02-27DOI: 10.18799/24056537/2019/4/266
S. Vasilevsky, A. A. Stepanov
In addition to the reported synthetic routes for the acetylene derivatives of quinones, a detailed analysis of the fundamental chemical, physicochemical, and biological properties of this class of compounds is presented herein. The advantages of Pd- and Cu-catalyzed cross-coupling of terminal alkynes with iodarenes via the Sonogashira reaction to produce new acetylenylquinones with predetermined properties are examined. Here, combining quinoid and acetylene residues into one molecule gives the resulting compounds chemical specificity, as demonstrated by several reported examples of non-trivial transformations. In particular, the presence of the quinoid cycle significantly increases the electrophilicity of the triple bond and determines the range of transformation possibilities. Moreover, acetylenylquinones have heightened sensitivity to both external (such as the reaction temperature and the nature of the solvent) and internal (e.g., the structure of substituents in the nucleus and the acetylene fragment) factors. For example, regioselective cleavage of a strong triple bond under the action of amines is possible in the absence of a metal catalyst. Peri-substituted acetylenyl-9,10-anthraquinones are most suited for the synthetic route because of the proximity of the acetylene and carbonyl groups. Mechanisms of reactions of selective alkynylquinones are described.
{"title":"FUNDAMENTAL AND APPLIED ASPECTS OF THE CHEMISTRY OF ACETYLENYLQUINONES","authors":"S. Vasilevsky, A. A. Stepanov","doi":"10.18799/24056537/2019/4/266","DOIUrl":"https://doi.org/10.18799/24056537/2019/4/266","url":null,"abstract":"In addition to the reported synthetic routes for the acetylene derivatives of quinones, a detailed analysis of the fundamental chemical, physicochemical, and biological properties of this class of compounds is presented herein. The advantages of Pd- and Cu-catalyzed cross-coupling of terminal alkynes with iodarenes via the Sonogashira reaction to produce new acetylenylquinones with predetermined properties are examined. Here, combining quinoid and acetylene residues into one molecule gives the resulting compounds chemical specificity, as demonstrated by several reported examples of non-trivial transformations. In particular, the presence of the quinoid cycle significantly increases the electrophilicity of the triple bond and determines the range of transformation possibilities. Moreover, acetylenylquinones have heightened sensitivity to both external (such as the reaction temperature and the nature of the solvent) and internal (e.g., the structure of substituents in the nucleus and the acetylene fragment) factors. For example, regioselective cleavage of a strong triple bond under the action of amines is possible in the absence of a metal catalyst. Peri-substituted acetylenyl-9,10-anthraquinones are most suited for the synthetic route because of the proximity of the acetylene and carbonyl groups. Mechanisms of reactions of selective alkynylquinones are described.","PeriodicalId":21019,"journal":{"name":"Resource-Efficient Technologies","volume":"5 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-02-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80787926","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-02-21DOI: 10.18799/24056537/2019/4/265
A. Voloshko, Ya. Bederak, Oleksandr A. Kozlovskyi
Relevance of research. In order to reduce energy losses, an accurate and timely forecast of the amount of consumed electricity is necessary. Accurate forecasting of electrical loads of industrial enterprises and their divisions (productions, workshops, departments etc.) allows planning of normal operating conditions, concluding contracts for the electricity supply with the electricity supply company under more favorable conditions, and improving the electricity quality, which ultimately affects the final cost of the products produced by an enterprise. So far, more than 150 forecasting methods of electrical loads have been developed. Usually, the most convenient one is selected based on the forecaster experience by creating and analyzing several forecasting models in order to identify the best. Therefore, in order to simplify the forecasting procedure, it is necessary to develop the methodology for forecasting analysis. This methodology should enable canceling forecasting algorithms that will create lower quality forecasts. The main objective is to develop the methodology for making a forecasting analysis of power consumption on the example of a pumping station of an enterprise with a continuous cycle of work to increase the efficiency of energy consumption and implementation of energy-saving measures. Objects of research: the process of forecasting electrical loads of a pumping station of the enterprise with a continuous cycle of work. Methods of research: fundamental principles of the theory of electrical engineering, statistical methods for power consumption forecasting, the method for detecting the trend of radio signals, and fractal analysis of time series. Research results. The methodology for forecasting analysis of power consumption, which makes it possible to apply the most appropriate methods to forecast the operational power consumption, is developed. For the first time, the radio signal trend detection method is applied to identify the trend of electrical loads. The variation ranges of the fractal parameters of time series of electrical loads are established depending on the variation coefficient of the time series for different periods of time. The Brown method of exponential smoothing that is used to forecast the electrical loads, in the case of identifying the smoothing constant α is in the beyond set ( ), is further improved. The regularity of changes in the fractal parameters of time series of power consumption of a pumping station with an increase in the time series duration and their field of application are explained.
{"title":"AN IMPROVED PRE-FORECASTING ANALYSIS OF ELECTRICAL LOADS OF PUMPING STATION","authors":"A. Voloshko, Ya. Bederak, Oleksandr A. Kozlovskyi","doi":"10.18799/24056537/2019/4/265","DOIUrl":"https://doi.org/10.18799/24056537/2019/4/265","url":null,"abstract":"Relevance of research. In order to reduce energy losses, an accurate and timely forecast of the amount of consumed electricity is necessary. Accurate forecasting of electrical loads of industrial enterprises and their divisions (productions, workshops, departments etc.) allows planning of normal operating conditions, concluding contracts for the electricity supply with the electricity supply company under more favorable conditions, and improving the electricity quality, which ultimately affects the final cost of the products produced by an enterprise. So far, more than 150 forecasting methods of electrical loads have been developed. Usually, the most convenient one is selected based on the forecaster experience by creating and analyzing several forecasting models in order to identify the best. Therefore, in order to simplify the forecasting procedure, it is necessary to develop the methodology for forecasting analysis. This methodology should enable canceling forecasting algorithms that will create lower quality forecasts. The main objective is to develop the methodology for making a forecasting analysis of power consumption on the example of a pumping station of an enterprise with a continuous cycle of work to increase the efficiency of energy consumption and implementation of energy-saving measures. Objects of research: the process of forecasting electrical loads of a pumping station of the enterprise with a continuous cycle of work. Methods of research: fundamental principles of the theory of electrical engineering, statistical methods for power consumption forecasting, the method for detecting the trend of radio signals, and fractal analysis of time series. Research results. The methodology for forecasting analysis of power consumption, which makes it possible to apply the most appropriate methods to forecast the operational power consumption, is developed. For the first time, the radio signal trend detection method is applied to identify the trend of electrical loads. The variation ranges of the fractal parameters of time series of electrical loads are established depending on the variation coefficient of the time series for different periods of time. The Brown method of exponential smoothing that is used to forecast the electrical loads, in the case of identifying the smoothing constant α is in the beyond set ( ), is further improved. The regularity of changes in the fractal parameters of time series of power consumption of a pumping station with an increase in the time series duration and their field of application are explained.","PeriodicalId":21019,"journal":{"name":"Resource-Efficient Technologies","volume":"13 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82457509","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-12-27DOI: 10.18799/24056537/2019/4/217
B. M. Das, D. Dutta
Nanotechnology encompasses the science and technology of objects with sizes ranging from 1 nm to 100 nm. Today, exploration and production from conventional oil and gas wells have reached a stage of depletion. Newer technologies have been developed to address this problem. Maximum oil production at a minimum cost is currently a huge challenge. This paper reviews nanotechnology applications in the oil and gas production sector, including in the fields of exploration, drilling, production, and waste management in oil fields, as well as their environmental concerns. The paper reviews experimental observations carried out by various researchers in these fields. The effect of various nanoparticles, such as titanium oxide, magnesium oxide, zinc oxide, copper oxide, and carbon nanotubes in drilling fluids and silica nanoparticles in enhanced oil recovery, has been observed and studied. This paper gives a detailed review of the benefits of nanotechnology in oil exploration and production. The fusion of nanotechnology and petroleum technology can result in great benefits. The physics and chemistry of nanoparticles and nanostructures are very new to petroleum technology. Due to the greater risk associated with adapting new technology, nanotechnology has been slow to gain widespread acceptance in the oil and gas industries. However, the current economic conditions have become a driving force for newer technologies.
{"title":"A REVIEW OF NANOTECHNOLOGY APPLICATIONS IN THE OIL AND GAS INDUSTRIES","authors":"B. M. Das, D. Dutta","doi":"10.18799/24056537/2019/4/217","DOIUrl":"https://doi.org/10.18799/24056537/2019/4/217","url":null,"abstract":"Nanotechnology encompasses the science and technology of objects with sizes ranging from 1 nm to 100 nm. Today, exploration and production from conventional oil and gas wells have reached a stage of depletion. Newer technologies have been developed to address this problem. Maximum oil production at a minimum cost is currently a huge challenge. This paper reviews nanotechnology applications in the oil and gas production sector, including in the fields of exploration, drilling, production, and waste management in oil fields, as well as their environmental concerns. The paper reviews experimental observations carried out by various researchers in these fields. The effect of various nanoparticles, such as titanium oxide, magnesium oxide, zinc oxide, copper oxide, and carbon nanotubes in drilling fluids and silica nanoparticles in enhanced oil recovery, has been observed and studied. This paper gives a detailed review of the benefits of nanotechnology in oil exploration and production. The fusion of nanotechnology and petroleum technology can result in great benefits. The physics and chemistry of nanoparticles and nanostructures are very new to petroleum technology. Due to the greater risk associated with adapting new technology, nanotechnology has been slow to gain widespread acceptance in the oil and gas industries. However, the current economic conditions have become a driving force for newer technologies.","PeriodicalId":21019,"journal":{"name":"Resource-Efficient Technologies","volume":"20 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90418940","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-12-13DOI: 10.18799/24056537/2019/3/247
R. Avetisyan, R. Avagyan, A. Avetisyan, A. Gyurjinyan, A. G. Barseghyan, I. Kerobyan, A. Manukyan
The role of neutron beam investigation is significant not only for fundamental science but also for various fields of applied science. This work is dedicated to the formation of neutron beams using the external 18-MeV proton beam of IBA cyclotron C18/18 with a beam current of up to 100 µA. The facility is located at the A. Alikhanyan National Science Laboratory (Yerevan Physics Institute). The possibility to obtain thermal or epithermal neutron beams using the external proton beam of the cyclotron is studied using Geant4 simulations. In this case, a quasimonoenergetic neutron source 9Be (p, n)9B reaction is chosen. As a result of the simulations, the optimal thickness of the 9Be beryllium isotope target is determined. The induced neutron beam is accompanied by a gamma ray background. To decrease the number of accompanying gamma rays, the lead absorber is considered. As a method of separating neutrons from gamma rays, the pulse shape discrimination (PSD) technique is developed. This study shows the possibility of neutron-gamma PSD and its applicability using the EJ-299-33A plastic scintillator.
{"title":"INVESTIGATION OF PULSE SHAPE NEUTRON-GAMMA DISCRIMINATION","authors":"R. Avetisyan, R. Avagyan, A. Avetisyan, A. Gyurjinyan, A. G. Barseghyan, I. Kerobyan, A. Manukyan","doi":"10.18799/24056537/2019/3/247","DOIUrl":"https://doi.org/10.18799/24056537/2019/3/247","url":null,"abstract":"The role of neutron beam investigation is significant not only for fundamental science but also for various fields of applied science. This work is dedicated to the formation of neutron beams using the external 18-MeV proton beam of IBA cyclotron C18/18 with a beam current of up to 100 µA. The facility is located at the A. Alikhanyan National Science Laboratory (Yerevan Physics Institute). The possibility to obtain thermal or epithermal neutron beams using the external proton beam of the cyclotron is studied using Geant4 simulations. In this case, a quasimonoenergetic neutron source 9Be (p, n)9B reaction is chosen. As a result of the simulations, the optimal thickness of the 9Be beryllium isotope target is determined. The induced neutron beam is accompanied by a gamma ray background. To decrease the number of accompanying gamma rays, the lead absorber is considered. As a method of separating neutrons from gamma rays, the pulse shape discrimination (PSD) technique is developed. This study shows the possibility of neutron-gamma PSD and its applicability using the EJ-299-33A plastic scintillator.","PeriodicalId":21019,"journal":{"name":"Resource-Efficient Technologies","volume":"111 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-12-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77872521","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-12-05DOI: 10.18799/24056537/2019/3/243
M. Popova, A. Kharitonov, Sergey N. Parfenyuk
Drilling wells is one of the primary methods used for mineral exploration. Scientific studies have aimed at improving the technical and economic aspects of drilling because of the current competitive economic conditions. Note that the primary topic of these studies has been developing new effective rock-cutting tools. To design a new rock-cutting tool, a thorough, reliable, and accurate study of the processes that occur during drilling is necessary. During drilling, mechanical, hydraulic, thermal, and chemical phenomena, which are interdependent and affect the performance of a drilling tool, simultaneously occur; therefore, a systematic, integrated approach is required for studying drilling processes. Field-based and laboratory experiments are quite tedious to perform and require high material costs, and it is often not possible to separately evaluate small elements of the drilling model. Therefore, computer simulation is an important research tool that enables accurate and reliable visualization of even small parts of the model. The aim. The aim of this study is to examine the potential for computer simulation of the processes that occur during drilling. Objective. In this study, we evaluated the simulation features of various software products, such as KOMPAS-3D, ANSYS, Delphi, and LabVIEW, for their utility in studying the processes that occur during drilling. The possibility of computer simulation for studying drilling processes, including its advantages and disadvantages, are demonstrated. The results are obtained from a model that simulates a rock cutting tool. The main uses of the rock cutting tool are outlined, and the drilling simulation development is planned. Choice of research method. The study of the capabilities of existing modern software products, for use in drilling process research, is carried out by an analytical review method.
{"title":"USING COMPUTER SIMULATION TO AID THE RESERCH OF DRILLING PROCESSES","authors":"M. Popova, A. Kharitonov, Sergey N. Parfenyuk","doi":"10.18799/24056537/2019/3/243","DOIUrl":"https://doi.org/10.18799/24056537/2019/3/243","url":null,"abstract":"Drilling wells is one of the primary methods used for mineral exploration. Scientific studies have aimed at improving the technical and economic aspects of drilling because of the current competitive economic conditions. Note that the primary topic of these studies has been developing new effective rock-cutting tools. To design a new rock-cutting tool, a thorough, reliable, and accurate study of the processes that occur during drilling is necessary. During drilling, mechanical, hydraulic, thermal, and chemical phenomena, which are interdependent and affect the performance of a drilling tool, simultaneously occur; therefore, a systematic, integrated approach is required for studying drilling processes. Field-based and laboratory experiments are quite tedious to perform and require high material costs, and it is often not possible to separately evaluate small elements of the drilling model. Therefore, computer simulation is an important research tool that enables accurate and reliable visualization of even small parts of the model. The aim. The aim of this study is to examine the potential for computer simulation of the processes that occur during drilling. Objective. In this study, we evaluated the simulation features of various software products, such as KOMPAS-3D, ANSYS, Delphi, and LabVIEW, for their utility in studying the processes that occur during drilling. The possibility of computer simulation for studying drilling processes, including its advantages and disadvantages, are demonstrated. The results are obtained from a model that simulates a rock cutting tool. The main uses of the rock cutting tool are outlined, and the drilling simulation development is planned. Choice of research method. The study of the capabilities of existing modern software products, for use in drilling process research, is carried out by an analytical review method.","PeriodicalId":21019,"journal":{"name":"Resource-Efficient Technologies","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87667848","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-12-05DOI: 10.18799/24056537/2019/3/196
H. Bouchekara, Y. Latreche, K. Naidu, H. Mokhlis, W. Dahalan, M. Javaid
A comprehensive review of existing radial distribution test systems available for power system distribution research is presented. The review can be used to establish a record of cases suitable for distribution operation and planning studies. The importance of the distribution system, the structure of the system in the grid, and various configurations of the distribution network are discussed. The primary requirement of a distribution network is highlighted to underline the important system parameters that should be considered in the design and planning stages. Various research related to the distribution network can be conducted, such as load flow algorithms, optimal incorporation of distributed generation, network reconfiguration, and optimal capacitor allocation, such as important details pertaining to each test system are given. Additional information, such as active and reactive loads and losses, minimum voltage values, and bus location with the weakest voltage values, is provided. Application of the reviewed works based on the test system is tabulated and presented. The information presented in this paper will be beneficial for future research in distribution system design and planning.
{"title":"COMPREHENSIVE REVIEW OF RADIAL DISTRIBUTION TEST SYSTEMS FOR POWER SYSTEM DISTRIBUTION EDUCATION AND RESEARCH","authors":"H. Bouchekara, Y. Latreche, K. Naidu, H. Mokhlis, W. Dahalan, M. Javaid","doi":"10.18799/24056537/2019/3/196","DOIUrl":"https://doi.org/10.18799/24056537/2019/3/196","url":null,"abstract":"A comprehensive review of existing radial distribution test systems available for power system distribution research is presented. The review can be used to establish a record of cases suitable for distribution operation and planning studies. The importance of the distribution system, the structure of the system in the grid, and various configurations of the distribution network are discussed. The primary requirement of a distribution network is highlighted to underline the important system parameters that should be considered in the design and planning stages. Various research related to the distribution network can be conducted, such as load flow algorithms, optimal incorporation of distributed generation, network reconfiguration, and optimal capacitor allocation, such as important details pertaining to each test system are given. Additional information, such as active and reactive loads and losses, minimum voltage values, and bus location with the weakest voltage values, is provided. Application of the reviewed works based on the test system is tabulated and presented. The information presented in this paper will be beneficial for future research in distribution system design and planning. ","PeriodicalId":21019,"journal":{"name":"Resource-Efficient Technologies","volume":"10 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75938526","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-08-02DOI: 10.18799/24056537/2019/2/239
S. Shyla, R. M. Kumar, M. Singanan
The objective of this study is to investigate the removal of divalent cadmium ions from an aqueous solution using Lantana camara leaves biocarbon (LCBC). Batch experiments are conducted to test the effects of various parameters such as pH, initial metal ion concentration, amount of biocarbon, and contact time on the cadmium removal process at room temperature, which allows establishing as the optimum conditions a pH value of 4.0 and 2.5g/100 mL of biocarbon dose at the equilibrium time of 180 min. The maximum percentage removal of cadmium is 93.30%. Langmuir and Freundlich adsorption isotherms are used to verify the adsorption parameters, and the experimental data is well fitted to the Langmuir model. Analysis of the biosorption kinetics shows that the pseudo-second-order model is well fitted for Cd (II) ions removal. The correlation coefficient (r2) for the second-order model is 0.9848. The results reveal LCBC as an efficient, low cost, and harmless to environment adsorbent for the removal of Cd (II) ions in the biosorption process.
{"title":"REMOVAL OF DIVALENT CADMIUM IONS FROM AQUEOUS SOLUTION USING LANTANA CAMARA LEAVES BIOCARBON","authors":"S. Shyla, R. M. Kumar, M. Singanan","doi":"10.18799/24056537/2019/2/239","DOIUrl":"https://doi.org/10.18799/24056537/2019/2/239","url":null,"abstract":"The objective of this study is to investigate the removal of divalent cadmium ions from an aqueous solution using Lantana camara leaves biocarbon (LCBC). Batch experiments are conducted to test the effects of various parameters such as pH, initial metal ion concentration, amount of biocarbon, and contact time on the cadmium removal process at room temperature, which allows establishing as the optimum conditions a pH value of 4.0 and 2.5g/100 mL of biocarbon dose at the equilibrium time of 180 min. The maximum percentage removal of cadmium is 93.30%. Langmuir and Freundlich adsorption isotherms are used to verify the adsorption parameters, and the experimental data is well fitted to the Langmuir model. Analysis of the biosorption kinetics shows that the pseudo-second-order model is well fitted for Cd (II) ions removal. The correlation coefficient (r2) for the second-order model is 0.9848. The results reveal LCBC as an efficient, low cost, and harmless to environment adsorbent for the removal of Cd (II) ions in the biosorption process.","PeriodicalId":21019,"journal":{"name":"Resource-Efficient Technologies","volume":"69 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78316311","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-07-24DOI: 10.18799/24056537/2019/2/237
A. Abrahamyan, A. Mkrtchyan, R. Chilingaryan
Glow discharge (GD) in a tube, arc discharge (AD) without cathode heating from an external source, and magnetron discharge (MD) in a planar magnetron are compared. In each of the discharges, characteristic areas are distinguished. In MD, electrons trapped in the near-cathode region are not directly involved in ionization processes, but “wake” acceleration of slow ions by electrons that move along Larmor orbits is possible, which gives additional energy to ions moving toward the cathode. In GD in the near-cathode region, the average energy of the ejected electrons is on the order of several electron volts, and the energy of the ions and neutrals is less than 0.1 eV. In MD in the near-cathode region, the average energy of knocked-out electrons, ions, and neutrals is on the order of tens of electron volts. The differential resistance of GD is negative, that of AD is usually negative, and that of MD is positive. The energy of ions in the magnetron plasma can be greater than that of electrons, which gives new possibilities for acoustoplasma control of MD and the creation of appropriate instruments and devices.
{"title":"COMPARISON OF GLOW, ARC, AND MAGNETRON DIRECT CURRENT DISCHARGES","authors":"A. Abrahamyan, A. Mkrtchyan, R. Chilingaryan","doi":"10.18799/24056537/2019/2/237","DOIUrl":"https://doi.org/10.18799/24056537/2019/2/237","url":null,"abstract":"Glow discharge (GD) in a tube, arc discharge (AD) without cathode heating from an external source, and magnetron discharge (MD) in a planar magnetron are compared. In each of the discharges, characteristic areas are distinguished. In MD, electrons trapped in the near-cathode region are not directly involved in ionization processes, but “wake” acceleration of slow ions by electrons that move along Larmor orbits is possible, which gives additional energy to ions moving toward the cathode. In GD in the near-cathode region, the average energy of the ejected electrons is on the order of several electron volts, and the energy of the ions and neutrals is less than 0.1 eV. In MD in the near-cathode region, the average energy of knocked-out electrons, ions, and neutrals is on the order of tens of electron volts. The differential resistance of GD is negative, that of AD is usually negative, and that of MD is positive. The energy of ions in the magnetron plasma can be greater than that of electrons, which gives new possibilities for acoustoplasma control of MD and the creation of appropriate instruments and devices.","PeriodicalId":21019,"journal":{"name":"Resource-Efficient Technologies","volume":"8 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85723659","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-07-11DOI: 10.18799/24056537/2019/2/233
V. Evdokimov, A. Artamonov, E. Plotnikov, N. Konstantinova
The power plant resource efficiency is largely dependent on heat-resistant alloys and is limited by the standard turbine operating temperature, which is slightly greater than 1000°C. These temperature limits are dependent on the characteristics of the heat-resistant alloys used in power plants. The current research aimed to discover new heat-resistant alloys using computer-based models to simulate the various properties of such materials. The first-principle methods were initially used in this study. These methods can determine the most important properties of alloys with a high degree of accuracy. This study presented an overview of the software used for first-principle simulation. Using RuAl as the demonstration alloy in this study, we provided step-by-step instructions on how to effectively study the properties of the heat-resistant alloys. Using the first-principle methods, the phonon spectrum and density of the phonon states of B2 RuAl were assessed. We use the parameters of the phonon spectrum to calculate the Grüneisen constant, volume coefficient of thermal expansion, Debye temperature, and temperature dependence of the heat capacity to estimate the melting temperature. Based on the RuAl alloy, the bulk moduli of the elasticity and equilibrium values of lattice parameters were calculated. The simulated results showed good agreement with the experimental data. The calculated parameters of RuAl were compared with those of the NiAl heat-resistant alloy. Using these results, we presented a method for selecting an alloy based on the replacement of ruthenium with nickel in the RuAl alloy. Selection was performed by analyzing the bulk modulus of elasticity and the electron structure of the Ru(Ni)Al alloy.
{"title":"RESOURCE-EFFICIENT METHODS FOR PREDICTING AND SELECTING HEAT-RESISTANT ALLOYS","authors":"V. Evdokimov, A. Artamonov, E. Plotnikov, N. Konstantinova","doi":"10.18799/24056537/2019/2/233","DOIUrl":"https://doi.org/10.18799/24056537/2019/2/233","url":null,"abstract":"The power plant resource efficiency is largely dependent on heat-resistant alloys and is limited by the standard turbine operating temperature, which is slightly greater than 1000°C. These temperature limits are dependent on the characteristics of the heat-resistant alloys used in power plants. The current research aimed to discover new heat-resistant alloys using computer-based models to simulate the various properties of such materials. The first-principle methods were initially used in this study. These methods can determine the most important properties of alloys with a high degree of accuracy. This study presented an overview of the software used for first-principle simulation. Using RuAl as the demonstration alloy in this study, we provided step-by-step instructions on how to effectively study the properties of the heat-resistant alloys. Using the first-principle methods, the phonon spectrum and density of the phonon states of B2 RuAl were assessed. We use the parameters of the phonon spectrum to calculate the Grüneisen constant, volume coefficient of thermal expansion, Debye temperature, and temperature dependence of the heat capacity to estimate the melting temperature. Based on the RuAl alloy, the bulk moduli of the elasticity and equilibrium values of lattice parameters were calculated. The simulated results showed good agreement with the experimental data. The calculated parameters of RuAl were compared with those of the NiAl heat-resistant alloy. Using these results, we presented a method for selecting an alloy based on the replacement of ruthenium with nickel in the RuAl alloy. Selection was performed by analyzing the bulk modulus of elasticity and the electron structure of the Ru(Ni)Al alloy.","PeriodicalId":21019,"journal":{"name":"Resource-Efficient Technologies","volume":"55 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2019-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73687872","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2019-07-10DOI: 10.18799/24056537/2019/2/184
B. Heidary, T. Tavakoli, B. Ghobadian, R. Roshandel
Introduction: Water, energy, and the environment are three important elements of sustainable development. Production of potable water using desalination technologies powered by renewable energy systems could help solve water scarcity in remote areas with shortages of water or conventional energy sources, or in large cities with air pollution. Hybridization of solar and wind could increase the sustainability and availability of renewable energy sources and reduce energy costs. Additionally, hybridization of reverse osmosis (RO) and MSF could increase efficiency and desalinated water quality and decrease desalinated water cost. Materials and Methods: The research method in this paper is based on modeling, computer simulation, and optimization with MATLAB software, and manufacturing and evaluating the plant at the Tarbiat Modares University Renewable Energy Laboratory. Results: The process of manufacturing the MSF system, solar panel structure, and wind turbine was explained and modeling and optimization results were presented. Testing results of the plant were mentioned, as were the produced power of wind turbine simulated and plant performance evaluated under the environmental conditions of the Tehran region. The rate of fresh water production under changing feed water salinity was evaluated and the real costs of fresh water produced ($/m3) were estimated. At the end of this section, model results and test results were compared. Conclusion: Hybridization of RO and MSF systems with wind and solar energy resources led to increased system reliability and flexibility and higher produced drinking water quality. The desalinated water cost was 1.35 $/m3 in theory and 1.5 $/m3 for actual conditions. Hybridization of wind, solar, RO, and MSF showed proved the best choices to minimize water cost compared to fossil fuel RO or MSF, wind RO, wind MSF, solar RO, solar MSF, or fossil fuel RO-MSF. Hybridization of RO and MSF would result in better economics and operation characteristics than those corresponding to MSF. Water cost can be reduced by 23 to 26% of that of a sole MSF process and the amount of desalinated water produced by the hybrid RO-MSF system is much greater than that of MSF. A comparison of theory outputs and experimental test results showed very good agreement between measured and model data. The test results of the manufactured hybrid solar-wind RO-MSF justified theory results.
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