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Synthesis of zinc oxide nanoparticles using plant leaf extract against urinary tract infection pathogen 植物叶片提取物合成抗尿路感染病原体氧化锌纳米颗粒
Pub Date : 2017-12-01 DOI: 10.1016/j.reffit.2017.05.001
J. Santhoshkumar, S. Venkat Kumar, S. Rajeshkumar

In modern science, Nanotechnology is an ablaze field for the researchers. Zinc oxide nanoparticles (ZnO NPs) are known to be one of the most multifunctional inorganic nanoparticles with its application in treatment of urinary tract infection. Nanoparticles were synthesized using Passiflora caerulea fresh leaf extract and were characterized by UV-visible spectroscopy (UV–vis), X-ray diffractometer (XRD), Fourier transform infrared spectroscopy (FT-IR), Scanning electron microscopy (SEM), Energy dispersive analysis of x-ray (EDAX), Atomic force microscopy (AFM). Therefore, the study reveals an efficient, eco-friendly and simple method for the green synthesis of multifunctional ZnO NPs using P. caerulea. Urinary tract infection causing microbes were isolated from the disease affected patient urine sample. The synthesized nanoparticles have been tested against the pathogenic culture showed a very good zone of inhibition compared with plant extract. It indicates the biomedical capability of ZnO NPs.

在现代科学中,纳米技术是研究人员的一个热门领域。氧化锌纳米颗粒(ZnO NPs)是一种多功能无机纳米颗粒,在尿路感染的治疗中有着广泛的应用。以西番莲鲜叶提取物为原料合成纳米颗粒,采用紫外可见光谱(UV-vis)、x射线衍射仪(XRD)、傅里叶变换红外光谱(FT-IR)、扫描电镜(SEM)、x射线能谱分析(EDAX)、原子力显微镜(AFM)等对纳米颗粒进行了表征。因此,本研究揭示了一种高效、环保、简单的绿色合成多功能ZnO NPs的方法。从患病患者的尿液样本中分离出引起尿路感染的微生物。合成的纳米颗粒对病原菌的抑制作用较植物提取物明显。这表明ZnO NPs具有良好的生物医学性能。
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引用次数: 363
A review on green synthesis of zinc oxide nanoparticles – An eco-friendly approach 纳米氧化锌的绿色合成研究进展——一种环保方法
Pub Date : 2017-12-01 DOI: 10.1016/j.reffit.2017.03.002
Happy Agarwal, S. Venkat Kumar, S. Rajeshkumar

Nanotechnology deals with the production and usage of material with nanoscale dimension. Nanoscale dimension provides nanoparticles a large surface area to volume ratio and thus very specific properties. Zinc oxide nanoparticles (ZnO NPs) had been in recent studies due to its large bandwidth and high exciton binding energy and it has potential applications like antibacterial, antifungal, anti-diabetic, anti-inflammatory, wound healing, antioxidant and optic properties. Due to the large rate of toxic chemicals and extreme environment employed in the physical and chemical production of these NPs, green methods employing the use of plants, fungus, bacteria, and algae have been adopted. This review is a comprehensive study of the synthesis and characterization methods used for the green synthesis of ZnO NPs using different biological sources.

纳米技术研究的是纳米尺度材料的生产和使用。纳米尺度的尺寸使纳米颗粒具有较大的表面积和体积比,因此具有非常特殊的性质。氧化锌纳米粒子(ZnO NPs)由于其具有大带宽和高激子结合能的特性,在抗菌、抗真菌、抗糖尿病、抗炎、伤口愈合、抗氧化和光学等方面具有潜在的应用前景。由于这些NPs的物理和化学生产中使用了大量有毒化学物质和极端环境,因此采用了利用植物、真菌、细菌和藻类的绿色方法。本文综述了利用不同生物源绿色合成氧化锌纳米粒子的合成方法和表征方法。
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引用次数: 729
Design of a solar photovoltaic system to cover the electricity demand for the faculty of Engineering- Mu'tah University in Jordan 为约旦穆塔大学工程学院设计一个太阳能光伏系统,以满足其电力需求
Pub Date : 2017-12-01 DOI: 10.1016/j.reffit.2017.04.005
Mohammad I. Al-Najideen, Saad S. Alrwashdeh

In this study, the reduction ways of the electricity demand for Engineering Faculty at Mu'tah University were investigated. The using of the available resources efficiently and effectively to reduce energy bill is one way to reduce the energy consumption as well as the electricity generation. On grid photovoltaic system considers the most promising way to achieve the target of saving. For that, the availability of the solar photovoltaic system as an electricity generation source for Faculty of Engineering proposed to design a 56.7 kW grid-connected as a solar photovoltaic power plant to cover the electricity demand. The analysis revealed that the Engineering Faculty at Mu'tah University consumed 96 MWh annually and by installing an on-grid photovoltaic system with a capacity of 56.7 KW the electricity production to the grid will be 97.02 MWh per year, which cover the electricity demand for Engineering Faculty at Mu'tah University with a capital cost of $117,000 and payback period about 5.5 years.

本研究以穆塔赫大学工程学院为研究对象,探讨降低用电需求的途径。有效地利用现有资源以减少能源消耗是减少能源消耗和发电的一种方法。并网光伏系统被认为是实现节能目标最有希望的途径。为此,考虑到太阳能光伏发电系统的可用性,工程学院建议设计一个56.7千瓦并网的太阳能光伏电站,以满足电力需求。分析显示,Mu'tah大学工程学院年用电量为96兆瓦时,通过安装一个容量为56.7千瓦的并网光伏系统,每年向电网输出的电力将达到97.02兆瓦时,这将满足Mu'tah大学工程学院的电力需求,资本成本为11.7万美元,投资回收期约为5.5年。
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引用次数: 61
Statistical optimization of acid catalyzed steam pretreatment of citrus peel waste for bioethanol production 酸催化蒸汽预处理柑桔皮废生产生物乙醇的统计优化
Pub Date : 2017-12-01 DOI: 10.1016/j.reffit.2017.04.001
Indulekha John, Prasanthi Yaragarla, Perumalsamy Muthaiah, Kalaichelvi Ponnusamy, Arunagiri Appusamy

Citrus waste is an attractive lignocellulosic biomass for the production of bioethanol due to the richness in carbohydrates and low lignin content. In this study, sweet lime peel was chosen as the lignocellulosic biomass. To increase the cellulose for enzymatic hydrolysis, the statistical optimization of process parameters namely, solid loading, time of exposure and sulphuric acid concentration for pretreatment of sweet lime peel were accomplished by Taguchi orthogonal array design. The sweet lime peel was exposed to acid catalyzed steam pretreatment for solid loading [10%, 12%, 15% and 17% (w/v)], time of exposure [15 min, 30 min, 45 min and 60 min] and sulphuric acid concentration [0.25%, 0.5%, 0.75% and 1% (v/v)]. The cellulose content was found to be an optimum at 35% for 17% (w/v) solid loading and 0.25% (v/v) acid concentration and steam exposure for 60 min. With these optimized process parameters, enzymatic hydrolysis of pretreated sweet lime peel was investigated at 50 °C for 48 h using in vitro isolated enzymes, viz., cellulase and pectinase from Aspergillus Niger with an activity of 1.7 FPU/ml and15 IU/ml respectively. 7.09 mg of reducing sugar/ml of hydrolysate was released in enzymatic hydrolysis which was estimated by DNS method. For the production of bioethanol, fermentation of hydrolysate was carried out at 30 °C for 72 h using baker's yeast. The yield of ethanol was 18%. From this study, it is proved that citrus waste is a promising source for the production of bioethanol.

柑橘废弃物因其丰富的碳水化合物和低木质素含量而成为生产生物乙醇的有吸引力的木质纤维素生物质。本研究选择甜酸橙皮作为木质纤维素生物质。为了增加酶解纤维素的用量,采用田口正交设计对酸橙皮预处理的固体负荷、暴露时间、硫酸浓度等工艺参数进行了统计优化。酸催化蒸汽预处理甜橙皮,固载[10%、12%、15%和17% (w/v)],处理时间[15、30、45和60 min],硫酸浓度[0.25%、0.5%、0.75%和1% (v/v)]。结果表明,在固体负荷为17% (w/v)、酸浓度为0.25% (v/v)、蒸汽处理60 min时,纤维素含量为35%时最优。在此条件下,利用体外分离的黑曲霉纤维素酶和果胶酶,分别以1.7 FPU/ml和15 IU/ml的活性对预处理后的酸橙皮进行酶解,温度为50℃,酶解48 h。酶解产物释放还原糖7.09 mg /ml,用DNS法测定。为了生产生物乙醇,将水解液在30°C下使用面包酵母发酵72 h。乙醇收率为18%。研究结果表明,柑橘废弃物是生产生物乙醇的理想原料。
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引用次数: 31
Heat transfer coefficients and productivity of a single slope single basin solar still in Indian climatic condition: Experimental and theoretical comparison 印度气候条件下单坡单盆太阳能蒸馏器的传热系数与生产力:实验与理论比较
Pub Date : 2017-12-01 DOI: 10.1016/j.reffit.2017.05.003
Abhay Agrawal , R.S. Rana , Pankaj K. Srivastava

A theoretical and experimental study was conducted at the central Indian location of Rewa, M.P., India (Latitude: 24°33′ 20.81′′ N, Longitude: 81°18′ 49.1′′ E). This paper presents a detailed comparison of the theoretical and the experimental results obtained for a single sloped basin type solar still. Results for different parameters such as basin water temperature, glass cover temperature, distillate output, evaporative, convective and radiative heat transfer coefficients and attenuation factor were obtained for basin water depths ranging from 2 cm to 10 cm. For solar still, daily distillate output decreased with increase in basin water depth. The theoretical value of daily efficiency for 2 cm and 10 cm basin water depth was around 52.83% and 41.75%, respectively, and for the same basin water depth, experimental daily efficiency was around 41.49% and 32.42% respectively. A sound agreement between the theoretical and the experimental results was observed.

在印度中部的Rewa, m.p.,印度(纬度:24°33′20.81”N,经度:81°18′49.1”E)进行了理论和实验研究。本文详细比较了单个倾斜盆地型太阳能蒸馏器的理论和实验结果。在2 ~ 10 cm的流域水深范围内,得到了不同参数(如盆水温、玻璃盖温度、馏出物产量、蒸发传热系数、对流传热系数和辐射传热系数以及衰减系数)的结果。对于太阳能蒸馏器,日馏出物产量随池水深的增加而降低。2 cm和10 cm流域水深下的日效率理论值分别为52.83%和41.75%左右,相同流域水深下的实验日效率分别为41.49%和32.42%左右。理论结果与实验结果完全吻合。
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引用次数: 78
Experimental and simulation studies of parabolic trough collector design for obtaining solar energy 抛物面槽式太阳能集热器设计的实验与仿真研究
Pub Date : 2017-12-01 DOI: 10.1016/j.reffit.2017.03.003
Syed Ameen Murtuza , H.V. Byregowda , Mohammed Mohsin Ali H , Mohammed Imran

Concentrated solar power has great potential for large scale renewable energy sources, and is currently an eye catching one for its utilization with wide area of improvement. Especially, parabolic trough solar collectors (PTSCs) are gaining popularity due to their increased efficiency as compared to photovoltaics. In this work, an effort has been made to evaluate the performance of a designed 5-m length PTSC model. Heat collecting element was made of stainless steel with water as working fluid. The authentication of the proposed model is justified based on the results obtained on a yearly scale with respect to average inlet and outlet temperatures, surface temperatures and thermal efficiency for the climatic conditions of Ramanagaram. It was observed that March to May yielded better outlet temperatures ranging from 93 °C to 103 °C. Experiments were carried out at different flow rates of 0.4 LPM, 0.8 LPM and 1.2 LPM and corresponding Reynolds number was calculated. It was seen that February to May gave good surface and outlet temperatures as compared with other months while the liquid flow is laminar. Simulation studies were carried out using ANSYS software on receiver tube to ensure the robustness and design effectiveness under static loading conditions.

聚光太阳能是一种极具规模化发展潜力的可再生能源,其利用前景广阔,是目前备受关注的可再生能源。特别是,抛物槽太阳能集热器(PTSCs)由于其与光伏相比效率的提高而越来越受欢迎。在这项工作中,已经努力评估设计的5米长度PTSC模型的性能。集热元件由不锈钢制成,工作流体为水。根据拉曼纳加拉姆气候条件下的年平均进出口温度、表面温度和热效率的结果,证明了所提出模型的正确性。3月至5月的出口温度较好,为93°C至103°C。在0.4 LPM、0.8 LPM和1.2 LPM的不同流量下进行了实验,并计算了相应的雷诺数。结果表明,2月至5月的表面温度和出口温度较其他月份好,而液体流动为层流。利用ANSYS软件对接收管进行了仿真研究,以保证接收管在静载荷条件下的鲁棒性和设计有效性。
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引用次数: 19
Ethanol steam reforming with Co0 (111) for hydrogen and carbon nanofilament generation 用Co0(111)重整乙醇蒸汽制备氢和碳纳米丝
Pub Date : 2017-12-01 DOI: 10.1016/j.reffit.2017.03.006
Ashutosh Kumar , Ram Prasad , Yogesh Chandra Sharma

The cobalt metal catalysts are highly active at low temperature ESR. In this study, ESR was studied over barren Co metal (Co0) from oxalate precursor without any pre-reduction to find out its role in hydrogen and carbon nano-filament generation. The ethanol conversion was found to be 100% with 96.5% hydrogen selectivity at 723K. The time on stream (TOS) study has shown stability up to 19h for Co catalyst. The diameter of Co-carbon nanofilament was calculated and found to be typically in the range of 70–80 nm by the TEM image analysis of spent catalyst. The SEM with EDS analysis revealed that Co0 state was found in between the carbon nanofilament as well as at the tip of carbon nanofilament. The obtained Co-C nanofilament displayed an adsorption capacity of 552 mg/g at optimum parameter of pH = 2, contact time = 60 minute, concentration = 30 ppm, dose = 0.05g for Orange G dye removal without any chemical or physical treatment. This approach has shown significant results in terms of hydrogen generation and method of Co carbon nanofilament for further utilization in different prospects.

钴金属催化剂在低温ESR下具有很高的活性。本研究对草酸盐前驱体中未预还原的Co金属(Co0)进行了ESR研究,以了解其在氢和碳纳米丝生成中的作用。在723K时,乙醇转化率为100%,氢气选择性为96.5%。催化时间(TOS)研究表明,Co催化剂的稳定性可达19小时。通过对废催化剂的TEM图像分析,计算了co -碳纳米丝的直径,发现其典型直径在70-80 nm之间。扫描电镜和能谱分析表明,碳纳米丝之间和尖端存在Co0态。在pH = 2、接触时间= 60 min、浓度= 30 ppm、剂量= 0.05g的最佳条件下,获得的Co-C纳米丝的吸附量为552 mg/g,无需任何化学或物理处理。该方法在制氢和Co -碳纳米丝制备方法方面取得了显著的成果,具有广泛的应用前景。
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引用次数: 7
Modeling and performance simulation of 100 MW LFR based solar thermal power plant in Udaipur India 印度乌代普尔100mw LFR太阳能热电厂的建模与性能仿真
Pub Date : 2017-12-01 DOI: 10.1016/j.reffit.2017.02.002
Deepak Bishoyi , K. Sudhakar

Solar energy is the most abundant source of energy on the earth and considered as an important alternative to fossil fuels. Solar energy can be converted into electric energy by using two different processes: photovoltaic conversion and the thermodynamic cycles. Lifetime and efficiency of PV power plant is lesser as compared to the CSP technology. CSP technology is viewed as one of the most promising alternative technology in the field of solar energy utilization. A 100 MW Linear Fresnel Reflector solar thermal power plant design with 6 hours of thermal energy storage has been evaluated for thermal performance using NREL SAM. A location receiving an annual DNI of 2248.17 kWh/m2/year in Rajasthan is chosen for the technical feasibility of hypothetical CSP plant. The plant design consists of 16 numbers of solar collector modules in a loop. HITEC solar salt is chosen as an HTF due to its excellent thermodynamic properties. The designed plant can generate annual electricity of 263,973,360 kWh with the plant efficiency of 18.3 %. The capacity utilization of the proposed LFR plant is found to be 30.2%. The LFR solar thermal power plant performance results encourage further innovation and development of CSP plants in India.

太阳能是地球上最丰富的能源,被认为是化石燃料的重要替代品。太阳能可以通过两种不同的过程转化为电能:光伏转换和热力学循环。与光热技术相比,光伏电站的寿命和效率较低。CSP技术被认为是太阳能利用领域最有前途的替代技术之一。利用NREL SAM对100 MW线性菲涅耳反射式太阳能热电厂设计进行了热性能评估,该电厂具有6小时的热能储存。为了假设CSP电厂的技术可行性,选择了拉贾斯坦邦一个年DNI为2248.17 kWh/m2/年的地点。该电站设计由16个太阳能收集模块组成一个回路。由于其优异的热力学性能,HITEC太阳能盐被选为HTF。设计的电厂年发电量263,973,360千瓦时,电厂效率为18.3%。建议的轻堆电厂的产能利用率为30.2%。LFR太阳能热电厂的性能结果鼓励了印度CSP电厂的进一步创新和发展。
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引用次数: 115
Reverse micellar partitioning of Bovine Serum Albumin with novel system 新型系统牛血清白蛋白的反胶束分配
Pub Date : 2017-12-01 DOI: 10.1016/j.reffit.2017.06.004
Swapnali S. Pawar, I. Regupathi, B.D. Prasanna

To overcome the difficulties associated with the conventional extraction process like poor selective extraction of biomolecule and scale up of the process, the reverse micellar system consist of AOT/n-heptanol was considered to extract Bovine Serum Albumin (BSA) as a model biomolecule. The maximum forward extraction of BSA from aqueous phase to micelle phase was observed at AOT concentration 160 mM, aqueous phase pH value of 4, NaCl concentration 0.8 M and 95% back extraction of BSA from micelle phase to stripping phase was obtained at 1 M NaCl concentration with the pH of 7.5. HPLC analysis confirmed the stability of BSA during extraction. The size and water content of the reverse micelle was also reported. The obtained results emphasize the application of the AOT/n-heptanol reverse micellar system for the extraction of BSA and may be utilized for the selective extraction of similar hydrophilic proteins from the complex sources.

为了克服传统提取工艺对生物分子选择性差的困难和工艺的规模化,采用AOT/正庚醇组成的反胶束体系提取牛血清白蛋白(Bovine Serum Albumin, BSA)作为模型生物分子。当AOT浓度为160 mM、水相pH值为4、NaCl浓度为0.8 M时,牛血清白蛋白从水相向胶束相正向萃取率最高;当NaCl浓度为1 M、pH值为7.5时,牛血清白蛋白从胶束相向提提相反向萃取率为95%。高效液相色谱分析证实了牛血清白蛋白在提取过程中的稳定性。还报道了反胶束的大小和含水量。研究结果强调了AOT/正庚醇反胶束体系在提取牛血清白蛋白中的应用,并可用于从络合物来源中选择性提取类似的亲水性蛋白。
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引用次数: 10
Review on enzymatic synthesis of value added products of glycerol, a by-product derived from biodiesel production 酶法合成生物柴油副产品甘油高附加值产品研究进展
Pub Date : 2017-12-01 DOI: 10.1016/j.reffit.2017.02.009
J. Pradima, M. Rajeswari Kulkarni, Archna

Crude glycerol is produced as a by-product from biodiesel production via trans-esterification with methanol and this process accounts for 10% (w/w) of the total biodiesel produced worldwide. The glycerol glut created can be utilized to increase biodiesel profitability since disposal can pose a threat to the environment. The need is to transform this surplus crude glycerol into added-value products. Biological based conversions are efficient in providing products that are drop-in replacements for petro-chemicals and offer functionality advantage, commanding higher price with the potential to increase bio-refinery revenue. Glycerol is a stable and multifunctional compound used as a building block in fine chemical synthesis like bio-polymers, polyunsaturated fatty acids, ethanol, hydrogen, n-butanol, glycerol carbonate, glycerol acetyl esters etc. Bio-catalysts add higher value to bio based products by catalyzing not only their selective modification, but also their synthesis under controlled and mild conditions. This article focuses on different bioconversion technologies of crude-glycerol to value added industrial products – obtained as waste from current bio-diesel production. We abridge the recent relevant approach for the production of various platform chemicals from bio-glycerol over enzyme and chemical catalysts.

粗甘油是生物柴油生产的副产品,通过与甲醇的反式酯化反应生产,这一过程占全球生物柴油总产量的10%。产生的甘油过剩可以用来提高生物柴油的盈利能力,因为处理会对环境造成威胁。需要的是将这些过剩的粗甘油转化为附加值产品。生物基转化在提供石化产品的替代产品方面效率很高,具有功能优势,价格更高,有可能增加生物炼油厂的收入。甘油是一种稳定的多功能化合物,用于生物聚合物、多不饱和脂肪酸、乙醇、氢、正丁醇、碳酸甘油、甘油乙酰酯等精细化学合成。生物催化剂不仅可以催化生物基产品的选择性修饰,还可以在可控和温和的条件下催化生物基产品的合成,从而提高生物基产品的价值。本文重点介绍了当前生物柴油生产中作为废弃物的粗甘油转化为高附加值工业产品的不同生物转化技术。我们简化了最近的相关方法,从酶和化学催化剂上的生物甘油生产各种平台化学品。
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引用次数: 61
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Resource-Efficient Technologies
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