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Biosynthesis of ZnO/SiO2 nanocatalyst with palash leaves’ powder for treatment of petroleum refinery effluent 用芭蕉叶粉生物合成氧化锌/二氧化硅纳米催化剂处理炼油废水
Pub Date : 2017-12-01 DOI: 10.1016/j.reffit.2017.08.004
Rajani Bharati, S. Suresh

This work aims the synthesis and characterization of ZnO/SiO2 nanocatalyst from plant waste material by green route and application of this ZnO/SiO2 nanocatalyst for the treatment of petroleum refinery effluent. Butea monosperma (Palash) leaves’ powder was used as reducing and stabilizing agent for synthesis of ZnO/SiO2 nanocatalyst. Palash leaves contain broad variability of biomolecules which work as reducing and capping agent. In this research work, COD and acenaphthylene which is Polycyclic Aromatic Hydrocarbons (PAH) were degraded by synthesizing ZnO/SiO2 nanocatalyst under UV-light in an annular photocatalytic reactor. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), FIELD emission gun-Scanning electron microscopy (FEG-SEM), Energy dispersive X-ray (EDX) and Transmission electron microscopy (TEM) analysis confirmed the formation of ZnO/SiO2 nanocatalyst. Characterization studies revealed that spherical and hexagonal nanoparticles with particle size ranging from 8 ± 5 nm to 40 ± 5 nm and mean particle with diameter of 20 ± 5 nm were synthesized using this method which is stable in the environment. Brunauer, Emmett and Teller (BET) surface area of ZnO/SiO2 nanocatalyst is found to be 150.25 m2/g. Fractional Factorial design was applied to find optimum condition of process parameters and found that optimum percent. Removal of COD (mg/l), and acenaphthylene were achieved at reaction condition of 1 g/L of ZnO/SiO2 nanocatalyst loading, 30°C temperature and 4 h reaction time and found that optimum percent removal of COD (mg/l), and acenaphthylene is 75%, and 73% respectively. Various metals, naturally present in palash leaves’ powder, decrease band gap of energy and improve photocatalytic activity of nanocatalyst.

本工作旨在通过绿色途径从植物废料中合成ZnO/SiO2纳米催化剂并对其进行表征,并将其应用于炼油废水的处理。以单精子丁茶(Butea monosperma, Palash)叶粉为还原剂和稳定剂合成ZnO/SiO2纳米催化剂。Palash叶含有广泛的可变性生物分子,作为还原和封盖剂。在环形光催化反应器中,采用紫外光下合成ZnO/SiO2纳米催化剂,降解了COD和多环芳烃(PAH)中的苊。x射线衍射(XRD)、傅里叶变换红外光谱(FT-IR)、场发射枪扫描电镜(fg - sem)、能量色散x射线(EDX)和透射电子显微镜(TEM)分析证实了ZnO/SiO2纳米催化剂的形成。表征研究表明,该方法合成的球形和六边形纳米颗粒粒径范围为8 ± 5 nm ~ 40 ± 5 nm,平均粒径为20 ± 5 nm,在环境中稳定。ZnO/SiO2纳米催化剂的Brunauer, Emmett and Teller (BET)表面积为150.25 m2/g。采用分数析因设计寻找工艺参数的最佳条件,并确定了最佳百分率。在ZnO/SiO2纳米催化剂负载量为1 g/l、反应温度为30℃、反应时间为4 h的条件下,对COD (mg/l)和苊的最佳去除率分别为75%和73%。天然存在于芭蕉叶粉末中的多种金属可以减小能量带隙,提高纳米催化剂的光催化活性。
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引用次数: 22
Development of advanced winding condition control technology of electric motors based on pulsed method 基于脉冲方法的先进电机绕组状态控制技术的开发
Pub Date : 2017-09-01 DOI: 10.1016/j.reffit.2017.08.001
Alexey V. Mytnikov, Valeriy A. Lavrinovich, Arina M. Evseeva, Ivan A. Stepanov

More than 80 percent of all electrical energy customers are electric motors. Therefore one of the prospects of resource-effective technologies in power industry is control of rotating electric equipment condition. Winding defects are one of the main causes of electric motor failures. Reliable control of winding condition is an urgent task of modern electrical engineering technology. The present article is devoted to the research of pulsed method application of transformer winding control for electric motor winding condition control. The procedure of winding condition control technology is described. The proposed method is based on the known pulsed method. The essential difference between the two methods is that only one probing impulse is used which is a probing impulse and response signal at once. The results of diagnostic procedure research at different winding defects are given. It is established that the place of winding damage corresponds to characteristic impulse changes. The defect of definite types causes specific changes of the probing impulse form. Therefore, different winding defects could be found with high accuracy along winding.

80%以上的电能客户是电动机。因此,旋转电力设备状态控制是电力工业资源高效技术的前景之一。绕组缺陷是电动机故障的主要原因之一。绕组状态的可靠控制是现代电气工程技术的一项紧迫任务。本文主要研究了脉冲法变压器绕组控制在电机绕组状态控制中的应用。介绍了卷绕工况控制技术的流程。提出的方法是基于已知的脉冲方法。两种方法的本质区别在于只使用一个探测脉冲,即同时使用探测脉冲和响应信号。给出了不同绕组缺陷诊断程序研究的结果。确定了绕组损伤位置与特征脉冲变化相对应。确定类型的缺陷引起探测脉冲形式的特定变化。因此,沿绕线方向可以高精度地发现不同的绕线缺陷。
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引用次数: 2
Renewable energy resources in South Asian countries: Challenges, policy and recommendations 南亚国家的可再生能源:挑战、政策和建议
Pub Date : 2017-09-01 DOI: 10.1016/j.reffit.2016.12.003
Akash Kumar Shukla, K. Sudhakar, Prashant Baredar

In South Asia, a number of developing countries like India, Pakistan, Sri Lanka, Bhutan, Nepal, Afghanistan and Maldives are looking into inexhaustible and repeatable alternative energy sources such as solar, wind, hydro and biomass. Geographically, South Asian countries are located in a region of different climatic conditions such as tropical, humid etc. which provides easy access to a variety of renewable energy sources. The governments of South Asian countries have initiated renewable energy policies to encourage industries and individuals to employ renewable energy powered systems in power applications. This article provides an updated and comprehensive overview of the renewable energy status in the South Asian countries, and it includes an assessment of the region's renewable potential, current installed renewable energy capacity. This paper gives a brief description about energy scenario, renewable energy potential and challenges in South Asian countries. The study also provides the renewable energy policies and recommendation in South Asian countries.

在南亚,印度、巴基斯坦、斯里兰卡、不丹、尼泊尔、阿富汗和马尔代夫等一些发展中国家正在研究取之不尽、可重复使用的替代能源,如太阳能、风能、水能和生物质能。从地理上看,南亚国家位于热带、潮湿等不同气候条件的地区,这为获取各种可再生能源提供了便利。南亚各国政府已经启动了可再生能源政策,鼓励工业和个人在电力应用中采用可再生能源供电系统。本文对南亚国家的可再生能源现状进行了更新和全面的概述,并对该地区的可再生能源潜力和目前的可再生能源装机容量进行了评估。本文简要介绍了南亚国家的能源情景、可再生能源潜力和面临的挑战。本研究还对南亚国家的可再生能源政策提出了建议。
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引用次数: 117
Sustainable chemistry and chemical processes for a sustainable future 可持续的化学和化学过程为可持续的未来
Pub Date : 2017-09-01 DOI: 10.1016/j.reffit.2017.08.006
Veera Gnaneswar Gude
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引用次数: 5
Optimization of adsorptive removal of α-toluic acid by CaO2 nanoparticles using response surface methodology 响应面法优化氧化钙纳米颗粒吸附去除α-甲酸的工艺
Pub Date : 2017-09-01 DOI: 10.1016/j.reffit.2017.03.004
Sapana S. Madan, Kailas L. Wasewar, C. Ravi Kumar

The present work addresses the optimization of process parameters for adsorptive removal of α-toluic acid by calcium peroxide (CaO2) nanoparticles using response surface methodology (RSM). CaO2 nanoparticles were synthesized by chemical precipitation method and confirmed by Transmission electron microscopy (TEM) and high-resolution TEM (HRTEM) analysis which shows the CaO2 nanoparticles size range of 5–15 nm. A series of batch adsorption experiments were performed using CaO2 nanoparticles to remove α-toluic acid from the aqueous solution. Further, an experimental based central composite design (CCD) was developed to study the interactive effect of CaO2 adsorbent dosage, initial concentration of α-toluic acid, and contact time on α-toluic acid removal efficiency (response) and optimization of the process. Analysis of variance (ANOVA) was performed to determine the significance of the individual and the interactive effects of variables on the response. The model predicted response showed a good agreement with the experimental response, and the coefficient of determination, (R2) was 0.92. Among the variables, the interactive effect of adsorbent dosage and the initial α-toluic acid concentration was found to have more influence on the response than the contact time. Numerical optimization of process by RSM showed the optimal adsorbent dosage, initial concentration of α-toluic acid, and contact time as 0.03 g, 7.06 g/L, and 34 min respectively. The predicted removal efficiency was 99.50%. The experiments performed under these conditions showed α-toluic acid removal efficiency up to 98.05%, which confirmed the adequacy of the model prediction.

采用响应面法(RSM)对过氧化钙(CaO2)纳米颗粒吸附去除α-甲酸的工艺参数进行了优化。采用化学沉淀法合成了CaO2纳米颗粒,并通过透射电子显微镜(TEM)和高分辨率透射电子显微镜(HRTEM)对其进行了分析,结果表明CaO2纳米颗粒的尺寸范围为5 ~ 15 nm。采用CaO2纳米颗粒对水溶液中α-甲苯进行了批量吸附实验。在此基础上,建立了基于实验的中心复合设计(CCD),研究了吸附剂用量、α-甲苯初始浓度和接触时间对α-甲苯脱除效率(响应)的交互作用,并对工艺进行了优化。进行方差分析(ANOVA)以确定个体的显著性和变量对反应的交互影响。模型预测响应与实验响应吻合较好,决定系数(R2)为0.92。其中,吸附剂用量和α-甲酸初始浓度的交互作用比对接触时间的影响更大。结果表明,吸附剂用量为0.03 g, α-甲苯初始浓度为7.06 g/L,接触时间为34 min。预测去除率为99.50%。在此条件下进行的实验表明,α-甲苯的去除率可达98.05%,证实了模型预测的充分性。
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引用次数: 13
Sorption characteristics of economically viable silicate sorbents for sequestration of lead ions from aqueous solutions 经济可行的硅酸盐吸附剂对水溶液中铅离子的吸附特性
Pub Date : 2017-09-01 DOI: 10.1016/j.reffit.2017.05.002
S.B. Yarusova , P.S. Gordienko , Ramya Krishna , Yu.A. Azarova , A.P. Suponina , A.V. Perfilev , Yogesh Chandra Sharma

The adsorption of Pb2+ from aqueous solutions by sorbents based on calcium silicates, obtained in multi-component systems CaCl2–Na2SiO3–H2O (sorbent I) and CaSO4·2H2O–SiO2·nH2O–KOH–H2O (sorbent II), was studied. Surface area of the two sorbents was found to be 100 and 40 m2/g respectively. The sorption capacities of the adsorbent materials were found to be 3.6 l/mmol and 8.4 l/mmol respectively. Characterization of the sorbent materials was carried out. The equilibrium data was fitted in Langmuir's isotherm and the adsorption capacity of the adsorbent materials was determined. The distribution coefficients at Pb2+ ions for the sorbents were determined at different ratios of solid and liquid phases.

研究了在CaCl2-Na2SiO3-H2O(吸附剂I)和CaSO4·2H2O-SiO2·nH2O-KOH-H2O(吸附剂II)体系中制备的硅酸钙吸附剂对Pb2+的吸附性能。两种吸附剂的表面积分别为100和40 m2/g。吸附材料的吸附量分别为3.6 l/mmol和8.4 l/mmol。对吸附材料进行了表征。用Langmuir等温线拟合了平衡数据,测定了吸附材料的吸附量。测定了不同固液相比下吸附剂的Pb2+离子分布系数。
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引用次数: 3
Bio-augmentation of antioxidants and phenolic content of Lablab purpureus by solid state fermentation with GRAS filamentous fungi GRAS丝状真菌固态发酵对紫菜抗氧化剂和酚类含量的生物增强作用
Pub Date : 2017-09-01 DOI: 10.1016/j.reffit.2016.12.007
Pardeep Kumar Sadh, Pooja Saharan, Joginder Singh Duhan

The present study was conducted to find out the effect of solid state fermentation on release of phenolics and subsequently on improvement of antioxidant activity of fermented seed and flour of Lablab purpureus (seim), using GRAS filamentous fungi i.e. Aspergillus awamori and Aspergillus oryzae. Significant increase in TPC level was observed on 5th day of fermentation of seed and flour with A. awamori and A. oryzae as compared to non-fermented ones. In DPPH and ABTS antioxidant assay, maximum activity was noticed in fermented ethanolic extract of seim seed with A. awamori and A. oryzae on 3rd and 4th day of incubation, respectively. The findings showed higher antioxidant activity formation in fermented seim seed than flour. Significant increase in enzyme activity of α-amylase was also contributed by SSF. This study demonstrated that fermented seed and flour of seim are better source of phytochemicals compared to the non-fermented ones.

本研究利用GRAS丝状真菌awamaspergillus和Aspergillus oryzae,研究固态发酵对紫菜(Lablab purpureus, seim)发酵种子和面粉中酚类物质释放的影响,以及对其抗氧化活性的提高。在发酵第5天,与未发酵的种子和面粉相比,加了awamori和a.m oryzae的种子和面粉的TPC水平显著提高。在DPPH和ABTS抗氧化实验中,加青霉和米霉发酵的芝麻籽乙醇提取物的抗氧化活性分别在培养第3天和第4天达到最高。结果表明,发酵荞麦种子的抗氧化活性高于面粉。SSF对α-淀粉酶活性也有显著的促进作用。本研究表明,发酵过的豆豉种子和豆粉是较好的植物化学物质来源。
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引用次数: 20
Development of a green procedure of citrus fruits waste processing to recover carotenoids 柑橘类水果废弃物绿色处理回收类胡萝卜素工艺的研究
Pub Date : 2017-09-01 DOI: 10.1016/j.reffit.2017.08.007
Meryem Boukroufa , Chahrazed Boutekedjiret , Farid Chemat

In this study, an original and green procedure of processing waste of the citrus fruits was developed using the concept of bio-refinery, innovative techniques “ultrasound” and “micro-wave”, and a green solvent “limonene” to recover carotenoids. Essential oil extraction was performed by Solvent Free Microwave Extraction (SFME) and compared to steam distillation (SD). The essential oil yields were comparable for both processes: 4.02 ± 0.23% for SFME and 4.16 ± 0.05% for SD. After that, carotenoid extraction from citrus peels was performed by ultrasound-assisted extraction (UAE) and conventional extraction (CE) using d-limonene obtained starting from essential oil, as a solvent, and then compared to n-hexane extract. Response surface methodology (RSM) using central composite designs (CCD) approach was launched to investigate the influence of process variables on the ultrasound-assisted extraction (UAE). The statistical analysis revealed that the optimized conditions of ultrasound power, temperature and time were 208 W cm−2, 20 °C and 5 min giving carotenoid content of 11.25 mg L−1. Compared to the conventional extraction, (UAE) gave an increase of 40% in carotenoid content. The comparison to n-hexane extract gave no significant changes in carotenoid content. Combination of microwave, ultrasound and d-limonene obtained from a bio-refinery of a by-product of citrus fruits industry allow us to develop a very good environmental green approach giving high added values compounds, with a saving of time, and a complete valorisation of waste.

本研究采用生物精馏的概念,采用“超声波”和“微波”的创新技术,采用绿色溶剂“柠檬烯”回收类胡萝卜素,开发了一种新颖、绿色的柑橘类水果废弃物处理工艺。采用无溶剂微波萃取法(SFME)提取精油,并与蒸汽蒸馏法(SD)进行比较。两种工艺的精油得率相当:SFME为4.02±0.23%,SD为4.16±0.05%。然后,以精油中提取的d-柠檬烯为溶剂,采用超声辅助提取法(UAE)和常规提取法(CE)提取柑橘皮中的类胡萝卜素,并与正己烷提取物进行比较。采用中心复合设计(CCD)方法,建立了响应面法(RSM),研究了工艺变量对超声辅助提取(UAE)的影响。经统计分析,超声功率、温度、时间分别为208 W cm−2、20℃、5 min,类胡萝卜素含量为11.25 mg L−1。与常规提取相比,(UAE)的类胡萝卜素含量增加了40%。与正己烷提取物相比,类胡萝卜素含量没有显著变化。结合微波,超声波和从柑橘类水果工业副产品的生物精炼厂获得的d-柠檬烯,使我们能够开发出一种非常环保的绿色方法,提供高附加值的化合物,节省时间,并完全实现废物的增值。
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引用次数: 42
Comparison of BIPV and BIPVT: A review BIPV与BIPVT的比较综述
Pub Date : 2017-09-01 DOI: 10.1016/j.reffit.2016.11.013
Mary Debbarma, K. Sudhakar, Prashant Baredar

Building-Integrated Photovoltaic (BIPV) is a smart energy production system that incorporates solar PV panels as part of the roof, windows, facades and shading devices. When active heat recovery is combined with BIPV systems either in closed loop (like PV-T with liquid loop) or in an open loop with forced air they are known as building-integrated photovoltaic-thermal (BIPVT systems). This paper reviews the BIPV and BIPVT technology. The paper shows various technologies involved in BIPV and BIPVT as well as their function, cost and aesthetics. In addition a review of the application of BIPV and BIPVT installations is described. In comparison to BIPV systems, BIPVT system has significant benefits and potential for wide use in buildings. The building integrated photovoltaic-thermal system design (BIPVT) is also becoming popular among architects and design engineers.

建筑集成光伏(BIPV)是一种智能能源生产系统,它将太阳能光伏板作为屋顶、窗户、立面和遮阳设备的一部分。当主动热回收与BIPV系统相结合时,无论是在闭环(如PV-T与液体回路)还是在带强制空气的开环中,它们都被称为建筑集成光伏热(BIPVT系统)。本文综述了BIPV和BIPVT技术。本文介绍了BIPV和BIPVT所涉及的各种技术,以及它们的功能、成本和美观性。此外,还介绍了BIPV和BIPVT装置的应用情况。与BIPV系统相比,BIPVT系统具有显著的优势和广泛应用的潜力。建筑集成光伏热系统设计(BIPVT)也越来越受到建筑师和设计工程师的欢迎。
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引用次数: 110
The impact of a shock-compressed layer on the mass transfer of target material during processing compression plasma flows 压缩等离子体流动过程中冲击压缩层对目标材料传质的影响
Pub Date : 2017-09-01 DOI: 10.1016/j.reffit.2017.06.003
A.Ya. Leyvi , N.N. Cherenda , V.V. Uglov , A.P. Yalovets

The paper describes the results of experimental and numerical research of the thickness of the molten bath and the surface erosion of a substance under the influence of compression plasma flows. It has been demonstrated that the formation of the shock-compressed layer affects the melted depth and the mass erosion from the surface of the treated target.

本文介绍了在压缩等离子体流影响下熔池厚度和物质表面侵蚀的实验和数值研究结果。结果表明,冲击压缩层的形成影响了熔化深度和被处理目标表面的质量侵蚀。
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引用次数: 2
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Resource-Efficient Technologies
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