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Material composition trends in printed circuit boards of mobile phones 手机印刷电路板的材料组成趋势
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-11 DOI: 10.1016/j.resconrec.2025.108741
Aleksander Jandric , Lukas Ginzinger , Dzeneta Vrucak , Damien Latacz , Kathija Shaik , Tim Gießmann , Ricardo Gabbay de Souza , Cledwyn Mangunda , Alexander Birich , Stefan Salhofer
In this research, we have investigated 45 mobile phones manufactured between 1998 and 2021. After dismantling, the resulting Printed Circuit Boards (PCBs) have been mechanically processed and homogenised. From each PCB, three sample pellets were created and analysed with a portable X-Ray Fluorescence (pXRF). In addition, a post-hoc calibration was performed to correct element and sample-specific biases. This approach allowed us to analyse a large sample size and to identify element mass value trends over time. The results for precious metals show an average annual decrease -2.49 mg/PCB for Ag, -1.14 mg/PCB for Au, and -0.13 mg/PCB for Pd. By contrast, the concentrations of Cu and Ni were increasing, but due to the decreasing mass of PCBs, the overall trends remained constant. Ultimately, the applied methodological approach was effective for analysing large number of samples and provided unique insights into the material trends across different generations of mobile phones.
在这项研究中,我们调查了1998年至2021年间生产的45部手机。拆解后,得到的印刷电路板(pcb)经过机械加工和均质化。从每个PCB中创建三个样品颗粒,并用便携式x射线荧光(pXRF)进行分析。此外,进行了事后校准以纠正元素和样本特异性偏差。这种方法允许我们分析一个大的样本大小,并确定元素质量值随时间的变化趋势。贵金属的测定结果显示,银的年平均值为-2.49 mg/PCB,金的年平均值为-1.14 mg/PCB,钯的年平均值为-0.13 mg/PCB。相比之下,Cu和Ni的浓度呈上升趋势,但由于pcb质量的下降,总体趋势保持不变。最终,应用方法的方法是有效的分析大量的样本,并提供了独特的见解跨越不同代的手机材料趋势。
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引用次数: 0
Quality in the circular economy: What does it mean, and how is it measured? 循环经济中的质量:它意味着什么?如何衡量?
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-11 DOI: 10.1016/j.resconrec.2025.108739
Kobe Vulsteke , Sophie Huysveld , Gwenny Thomassen , Helmut Rechberger , Jo Dewulf
Quality is increasingly recognized as a critical factor for achieving functional value retention in the circular economy. However, the concept remains poorly defined and inconsistently measured, limiting its integration into circularity assessments. This article develops a typology that distinguishes six types of quality metrics based on two dimensions: the targeted resource state (material, component, or product) and the nature of the quality characteristics assessed (intrinsic or extrinsic). It also identifies three assessment levels (generic, application-specific, and indirect) reflecting how quality is evaluated in practice. To illustrate the typology, existing approaches that quantify changes in resource quality were collected and positioned within the typology. This analysis highlights the diversity of methodological strategies and provides guidance on when to use which type of metric. While no single metric can fully capture the multifaceted nature of resource quality, the typology provides a practical foundation for more consistent quality assessments in circular economy research.
质量越来越被认为是在循环经济中实现功能价值保留的关键因素。然而,这个概念仍然定义不清,测量不一致,限制了它与循环评估的结合。本文开发了一种类型学,基于两个维度来区分六种类型的质量度量:目标资源状态(材料、组件或产品)和被评估的质量特征的性质(内在或外在)。它还确定了三个评估级别(通用、特定应用程序和间接),反映了如何在实践中评估质量。为了说明这一类型学,我们收集了量化资源质量变化的现有方法,并将其定位在这一类型学中。该分析强调了方法策略的多样性,并提供了关于何时使用哪种类型的度量标准的指导。虽然没有单一的指标可以完全捕捉资源质量的多面性,但类型学为循环经济研究中更一致的质量评估提供了实践基础。
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引用次数: 0
The carbon footprint of the mussel food chain in Spain 西班牙贻贝食物链的碳足迹
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-11 DOI: 10.1016/j.resconrec.2025.108742
Pablo Saralegui-Díez , Sebastián Villasante , Andrés Ospina-Álvarez , Montserrat Ramón , Joan Moranta
The global food system is a major contributor to greenhouse gas emissions (GHG), and there is increasing interest in identifying sustainable protein alternatives. Mussels are often promoted as an environmentally friendly source of seafood. However, comprehensive assessments of its carbon footprint, which consider the entire food chain, remain limited. This study estimates the carbon footprint of the mussel food chain in Spain, focusing on its product forms—fresh, frozen, and canned— by reconstructing the mussel supply chain, integrating national production and trade data, and modelling its logistics across international, national, and intraprovincial transport. The relationship between fresh, frozen and processed mussel allows to articulate a consumption approach taking into consideration the interconnections between industrial processing, global supply chains and mussel production. Total GHG emissions reached 287.8 GgCO₂eq.yr-1, with the main contributions from aquaculture production (45 %), industrial processing (43 %), and transport (12 %). Emissions linked to domestic consumption are 190.1 GgCO₂eq.yr-1, representing 6.3 kgCO₂eq.kg-1 edible mussel meat, with pickled mussels representing the most impactful product (8.5 kgCO₂eq.kg-1 edible mussel meat), followed by mussels in brine (6.7 kgCO₂eq.kg-1 edible mussel meat), fresh mussels (4.1 kgCO₂eq.kg-1 edible mussel meat), and frozen mussels (3.6 kgCO₂eq.kg-1 edible mussel meat). Although Galicia accounts for 99 % of domestic mussel production, only 25 % of available fresh mussels are destined for direct domestic consumption. The remainder feeds industrial processing or is exported, revealing a structure highly dependent on international trade and interprovincial transport. Our findings show that processing and transport are key contributors, and that the most consumed forms present the highest carbon footprints. We highlight the need to promote more sustainable consumption patterns, enhance local consumption of lower-impact forms, and reconfigure industrial and trade strategies to reduce environmental impacts while maintaining the sector’s economic viability.
全球粮食系统是温室气体排放(GHG)的主要来源,人们对寻找可持续的蛋白质替代品越来越感兴趣。贻贝经常被宣传为一种环保的海鲜来源。然而,考虑到整个食物链,对其碳足迹的全面评估仍然有限。本研究通过重建贻贝供应链,整合国家生产和贸易数据,并模拟其在国际、国内和省内运输中的物流,估算了西班牙贻贝食物链的碳足迹,重点关注其产品形式(新鲜、冷冻和罐装)。新鲜、冷冻和加工贻贝之间的关系使我们能够清晰地表达一种消费方式,同时考虑到工业加工、全球供应链和贻贝生产之间的相互联系。温室气体排放总量达到287.8 GgCO₂当量。年-1年,主要来自水产养殖生产(45%)、工业加工(43%)和运输(12%)。与国内消费相关的排放量为190.1 GgCO₂当量。-1,代表6.3 kgCO₂eq。kg-1食用贻贝肉,腌制贻贝是最具影响力的产品(8.5 kgco2当量)。食用贻贝肉),其次是盐水贻贝(6.7 kgCO₂当量)。食用贻贝肉(kg-1),新鲜贻贝(4.1 kgco2当量)。食用贻贝肉(kg-1)和冷冻贻贝(3.6 kgco2当量)。Kg-1食用贻贝肉)。尽管加利西亚占国内贻贝产量的99%,但只有25%的新鲜贻贝直接用于国内消费。其余部分用于工业加工或出口,显示出高度依赖国际贸易和省际运输的结构。我们的研究结果表明,加工和运输是主要的贡献者,而消耗最多的形式产生了最高的碳足迹。我们强调有必要促进更可持续的消费模式,加强低影响形式的本地消费,重新配置工业和贸易战略,以减少对环境的影响,同时保持该行业的经济活力。
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引用次数: 0
Revealing the impact of electric vehicles trade restrictions on greenhouse gas emissions and welfare 揭示电动汽车贸易限制对温室气体排放和福利的影响
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-11 DOI: 10.1016/j.resconrec.2025.108744
Lanxin Zhang , Zongguo Wen , Xin Sun , Yihan Wang , Tingting Zhang
The global transition to electric vehicles (EV) is essential for decarbonization, yet it is increasingly challenged by a surge in trade restrictions. Existing studies lack a comprehensive impact assessment of EV trade restrictions. This study integrates multi-regional partial equilibrium model with emissions accounting method to quantify greenhouse gas (GHG) emissions and welfare effects under various trade policy scenarios. Our analysis reveals that trade restrictions reduce global EV output values by 0.5 %-2.4 %, especially in export-dependent regions such as South Korea. While bilateral trade restrictions cause moderate global welfare losses (up to US$4.6 billion) and emission increases (up to 2.3 MtCO2e), global extension substantially exacerbates these impacts, leading to welfare loss of US$18.2 billion and emissions increase of 10.5 MtCO2e. In contrast, trade liberalization generates significant co-benefits, boosting global welfare by US$26.1 billion and reducing emissions by 31.3 MtCO2e. The results demonstrate that trade restrictions on EV harm both welfare and climate objectives. This study provides critical quantitative evidence for policymakers to integrate trade and climate strategies for a sustainable EV transition.
全球向电动汽车(EV)的过渡对脱碳至关重要,但它正日益受到贸易限制激增的挑战。现有研究缺乏对电动汽车贸易限制的全面影响评估。本研究将多区域部分平衡模型与排放核算方法相结合,量化了不同贸易政策情景下的温室气体排放和福利效应。我们的分析显示,贸易限制使全球电动汽车产值下降0.5% - 2.4%,尤其是在韩国等依赖出口的地区。虽然双边贸易限制造成了适度的全球福利损失(高达46亿美元)和排放增加(高达230万吨二氧化碳当量),但全球扩张大大加剧了这些影响,导致182亿美元的福利损失和1050万吨二氧化碳当量的排放增加。相比之下,贸易自由化产生了显著的协同效益,增加了261亿美元的全球福利,减少了3130万吨二氧化碳当量的排放。结果表明,电动汽车的贸易限制损害了福利和气候目标。该研究为政策制定者整合贸易和气候战略以实现电动汽车的可持续转型提供了关键的定量证据。
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引用次数: 0
Long-term changes in city-level CH4 emissions from rice cultivation in China: Patterns, drivers, projections, and sustainable pathways 中国城市水稻种植CH4排放的长期变化:模式、驱动因素、预测和可持续途径
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-11 DOI: 10.1016/j.resconrec.2025.108738
Sen Liang , Ke Wang , Wensheng Duan , Yanhan Ma
China is the world’s largest methane (CH4) emitter, with rice cultivation a major source. This study develops a city-level, production-based CH4 inventory for rice cultivation from 2018 to 2022. Emissions are decomposed using the Logarithmic Mean Divisia Index (LMDI) into efficiency index (EI), industrial structure (IS), economic level (EL), and labor force (LF), and future trends are projected via the STIRPAT model under Shared Socioeconomic Pathways (SSPs). Annual CH₄ emissions ranged from 6.83 to 7.23 Mt, concentrated in northeastern and central-southern China. Over 80 % originated from first-season rice. EI improvements curbed emissions, but rising EL remains a key growth driver. No SSP scenario achieves a national CH4 peak by 2030; under SSP2, emissions peak at 7.02 Mt. Single-season rice regions have already peaked, while mixed cultivation zones will become the primary mitigation focus. This work offers spatially detailed insights to support CH4 reduction and advance China's "carbon peaking" goals.
中国是世界上最大的甲烷(CH4)排放国,其中水稻种植是主要来源。本研究为2018 - 2022年的水稻种植开发了一个城市层面的、基于生产的CH4库存。利用对数平均分割指数(LMDI)将排放分解为效率指数(EI)、产业结构(IS)、经济水平(EL)和劳动力(LF),并通过共享社会经济路径(ssp)下的STIRPAT模型预测了未来趋势。4氯化甲烷年排放量在6.83 ~ 7.23 Mt之间,主要集中在东北和中南部。80%以上的原料来自第一季大米。能源效率的提高抑制了排放,但能源效率的上升仍然是主要的增长动力。到2030年,任何SSP方案都无法达到全国CH4峰值;在SSP2下,排放峰值为702万吨。单季水稻区已经达到峰值,而混合种植区将成为主要的缓解重点。这项工作为支持减少CH4和推进中国的“碳峰值”目标提供了空间上的详细见解。
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引用次数: 0
Corrigendum to “Carbon sink potential and contributions to dual carbon goals of the grain for green program in the arid regions of Northwest China” [Resources, Conservation & Recycling 220 (2025) 108355/j.resconrec.2025.108355] 西北干旱区退耕还林工程碳汇潜力及其对双碳目标的贡献[j] .资源涵养与循环利用220 (2025)108355/j.r recrec.2025 .108355]
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-10 DOI: 10.1016/j.resconrec.2025.108714
Jingye Yang , Chuanglin Fang , Lifang Zhang , Yulu Yang
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引用次数: 0
Molten salt-mediated separation and recovery of valuable elements from spent LiFePO4 black mass 熔融盐介导的废LiFePO4黑团中有价元素的分离与回收
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-10 DOI: 10.1016/j.resconrec.2025.108740
Yao Yu , Xiao Yang
Spent LiFePO4 (LFP) battery black mass (SLFPB) recycling is important and faces significant challenges due to complex composition. This work presents a novel molten CaCl2-based leaching-electrolysis method for comprehensive valuable component recovery. This process yields recovery percentages exceeding 95 % for Fe, Cu, and P, 87 % for graphite, and 70 % for Al, while enriching Li in the melt. The molten salt shows potential for cyclic operation. Mechanistically, LiFePO4 and FePO4 in SLFPB react with molten CaCl2 to form metal chlorides, Ca5(PO4)3Cl, and Ca2PO4Cl intermediates, which subsequently dissociate into soluble ions. Most Fe escapes as FeCl2 vapor. Graphite, due to its lower density, floats to the melt surface. The distinct thermodynamic properties of Fe2+, Cu+, and PO43– allow their separation and recovery as metals and P4 through two-step electrolysis. Differences in leaching and volatilization rates leads to the accumulation of Li. This approach provides a simple pathway for comprehensive SLFPB recycling.
废旧LiFePO4 (LFP)电池黑质量(SLFPB)的回收利用非常重要,但由于其成分复杂,面临着重大挑战。本文提出了一种基于熔融氯化钙的浸出-电解综合回收有价组分的新方法。该工艺对铁、铜和磷的回收率超过95%,石墨的回收率超过87%,铝的回收率超过70%,同时富集了熔体中的锂。熔盐显示出循环操作的潜力。SLFPB中的LiFePO4和FePO4与熔融的CaCl2反应生成金属氯化物、Ca5(PO4)3Cl和Ca2PO4Cl中间体,这些中间体随后解离成可溶性离子。大多数铁以FeCl2蒸气的形式逸出。石墨由于密度较低,浮在熔体表面。Fe2+、Cu+和PO43 -具有不同的热力学性质,可以通过两步电解分离并回收为金属和P4。浸出速率和挥发速率的差异导致了锂的积累。该方法为SLFPB的综合回收提供了一条简单的途径。
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引用次数: 0
Achieving painless energy conservation via equity-oriented efficiency nudge: evidence from electricity consumption in China 通过公平导向的效率推动实现无痛节能:来自中国电力消费的证据
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-10 DOI: 10.1016/j.resconrec.2025.108736
Wenhui Zhao , Rina Su , Pengyu Zou , Yiming Li , Bo Yang , Bin Zhang
Demand-side emission reduction is crucial yet often overlooked due to fragmented policies lacking balance between equity and efficiency. This study proposes a data-driven behavioral nudging framework based on the Equitable Electricity Efficiency (EEE) index, which quantifies household saving potential under social and environmental constraints while preserving welfare. EEE is estimated through a multi-method pipeline combining Meta-Frontier Analysis, ANN-DEA, SFA (Battese-Coelli, 1988), and Three-Stage DEA, identifying inefficiencies, distortions, and fairness-adjusted gaps. Analysis of large-scale Chinese household electricity data shows an average EEE of 70 %, implying a recoverable potential of 26.5 %–31.5 %, equal to 72.12 billion kWh and 5.66 million tons of CO₂ annually. Results reveal nonlinear patterns: middle-income, moderately aware households have the highest untapped efficiency; affluent users respond less; disadvantaged groups face structural barriers. Embedding fairness into nudges offers a scalable, interpretable, and inclusive path for equity-aware demand-side management and just energy transition.
需求侧减排至关重要,但由于缺乏公平与效率之间的平衡,零散的政策往往被忽视。本研究提出了一个基于公平电力效率(EEE)指数的数据驱动的行为推动框架,该框架量化了社会和环境约束下的家庭储蓄潜力,同时保持了福利。EEE是通过结合Meta-Frontier Analysis、ANN-DEA、SFA (Battese-Coelli, 1988)和三阶段DEA的多方法管道来估计的,以确定低效率、扭曲和公平调整的差距。对中国大规模家庭用电数据的分析显示,平均EEE为70%,可回收潜力为26.5% ~ 31.5%,相当于每年721.2亿千瓦时和566万吨二氧化碳。结果显示出非线性模式:中等收入、中等意识家庭的未开发效率最高;富裕用户的反应较少;弱势群体面临结构性障碍。将公平嵌入到推动中,为公平意识的需求侧管理和公正的能源转型提供了一条可扩展、可解释和包容的道路。
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引用次数: 0
Quantifying energy consumption variability in injection molding: A meta-regression analysis 量化能源消耗可变性注射成型:一个元回归分析
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-09 DOI: 10.1016/j.resconrec.2025.108730
Cole Van Emburg , Hao Chen , Srikanth Pilla , Gang Li , Michael Carbajales-Dale
Injection molding dominates global thermoplastic production, making its energy performance critical to sustainability assessments. Specific energy consumption (SEC, kWh/kg) is a key metric for comparing manufacturing efficiency and is widely used in decision-support tools such as life cycle assessment (LCA). However, for injection molding, SEC is often represented by a single generic value, with limited consideration of variability across material types, process parameters, and system configurations, potentially compromising the robustness of LCA results. Here, we conduct a meta-analysis of 160 energy-use data points from 15 peer-reviewed studies, spanning 20 material types and three machine types. We find a mean SEC of 3.13 kWh/kg, which is 2 to 2.5 times higher than default values in commonly used databases, and observe that acrylonitrile butadiene styrene (ABS) exhibits a distinct high-SEC cluster. A mixed-effects meta-regression further identifies material theoretical heat energy, machine type, and injection utilization as the primary drivers of variability, collectively explaining 74.2 % of the observed variance. Selecting polymers with low theoretical heat energy and maximizing injection utilization can reduce SEC by up to 50 % across machine types. This study provides a data-driven model to improve LCA accuracy and guide energy-efficiency strategies in sustainable materials manufacturing.
注塑成型在全球热塑性塑料生产中占主导地位,使其能源性能对可持续发展评估至关重要。比能耗(SEC, kWh/kg)是比较制造效率的关键指标,广泛用于生命周期评估(LCA)等决策支持工具。然而,对于注塑成型,SEC通常由单一的通用值表示,对材料类型、工艺参数和系统配置的可变性考虑有限,这可能会损害LCA结果的稳健性。在这里,我们对来自15项同行评审研究的160个能源使用数据点进行了荟萃分析,涉及20种材料类型和3种机器类型。我们发现平均SEC为3.13 kWh/kg,比常用数据库的默认值高2至2.5倍,并且观察到丙烯腈-丁二烯-苯乙烯(ABS)表现出明显的高SEC簇。混合效应元回归进一步确定了材料理论热能、机器类型和注入利用率是可变性的主要驱动因素,共同解释了观察到的74.2%的方差。选择具有较低理论热能的聚合物并最大限度地提高注射利用率,可以在各种机器类型中减少高达50%的SEC。本研究提供了一个数据驱动的模型,以提高LCA的准确性和指导可持续材料制造的能源效率策略。
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引用次数: 0
Environmental and economic performance of sewage sludge-dominated organic solid waste management strategies from a life cycle perspective: co-treatment versus mono-treatment 从生命周期角度看污水污泥为主的有机固体废物管理策略的环境和经济绩效:共同处理与单一处理
IF 10.9 1区 环境科学与生态学 Q1 ENGINEERING, ENVIRONMENTAL Pub Date : 2025-12-09 DOI: 10.1016/j.resconrec.2025.108737
Binbin Liu , Peng Yang , Hao Zhou , Lanfeng Li , Jing Ai , Hang He , Junxia Yu , Weijun Zhang
Synergistic advantages between organic solid wastes may facilitate a strategy shift from mono-management to co-management, while the implementation of these transformations should be considered in terms of its environmental and economic performance. This study utilized life cycle assessment and life cycle cost analysis to quantitatively assess the co-management and mono-management strategies for the incineration of sewage sludge (SS) and municipal solid waste, composting of SS and pig manure, and anaerobic digestion (AD) of SS and food waste. The results showed that co-incineration resulted in a 7.67% decrease in feasibility, whereas co-composting and co-AD demonstrated increases of 76.50% and 21.36%, respectively. Sensitivity analysis indicated that global warming potential was positively correlated with SS addition in co-incineration and co-AD, but negatively in co-composting. This study recommends adopting co-management methods tailored to local conditions and optimizing waste composition to guide future policy towards more sustainable and safer waste management.
有机固体废物之间的协同优势可能促进从单一管理到共同管理的战略转变,而这些转变的执行应根据其环境和经济绩效加以考虑。本研究利用生命周期评估和生命周期成本分析,定量评估了污泥焚烧与城市生活垃圾、污泥与猪粪堆肥、污泥与食物垃圾厌氧消化的协同管理和单一管理策略。结果表明,共焚烧的可行性降低了7.67%,而共堆肥和共ad的可行性分别提高了76.50%和21.36%。敏感性分析表明,全球变暖潜势与共焚烧和共ad中SS添加量呈正相关,而与共堆肥中SS添加量呈负相关。本研究建议采用因地制宜的共同管理方法,优化废物组成,以指导未来的政策,实现更可持续和更安全的废物管理。
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引用次数: 0
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Resources Conservation and Recycling
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