Young-Hee Kim, Kyoung-Hwa Choi, Jin-Young Hong, J. Lee, S. Kim, C. Jo, S. Jeong
Abstract Ola leaf manuscripts from Sri Lanka date back to several centuries. While they have been well preserved over the last century, their condition has worsened in recent years when black dots caused by microorganisms started occurring on their surface. In this study, the current state of preservation and the factors causing deterioration are examined using microscopy techniques. Microscopic images clearly show that the manuscripts are contaminated by microorganisms which penetrated deeply into the carrier material, destroying the internal structure. A Penicillium griseofulvum strain was recognized as the most active microorganism in xylan degradation. Sri Lanka’s climate provides favorable conditions for the growth of these fungi. Therefore, it is suggested that temperature and humidity of the archival space should be better controlled in order to ensure the Ola leaf manuscripts’ long-term preservation.
{"title":"Investigation of Microorganisms Deteriorating Ancient Ola Leaf Manuscripts","authors":"Young-Hee Kim, Kyoung-Hwa Choi, Jin-Young Hong, J. Lee, S. Kim, C. Jo, S. Jeong","doi":"10.1515/res-2020-0004","DOIUrl":"https://doi.org/10.1515/res-2020-0004","url":null,"abstract":"Abstract Ola leaf manuscripts from Sri Lanka date back to several centuries. While they have been well preserved over the last century, their condition has worsened in recent years when black dots caused by microorganisms started occurring on their surface. In this study, the current state of preservation and the factors causing deterioration are examined using microscopy techniques. Microscopic images clearly show that the manuscripts are contaminated by microorganisms which penetrated deeply into the carrier material, destroying the internal structure. A Penicillium griseofulvum strain was recognized as the most active microorganism in xylan degradation. Sri Lanka’s climate provides favorable conditions for the growth of these fungi. Therefore, it is suggested that temperature and humidity of the archival space should be better controlled in order to ensure the Ola leaf manuscripts’ long-term preservation.","PeriodicalId":21154,"journal":{"name":"Restaurator. International Journal for the Preservation of Library and Archival Material","volume":null,"pages":null},"PeriodicalIF":0.4,"publicationDate":"2020-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1515/res-2020-0004","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47024761","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Tali H. Horst, Richard D. Smith, A. Potthast, M. Hubbe
Abstract Three copies of a book that had been optionally deacidified using two different procedures in 1967, and then subjected to accelerated aging, were tested again after 52 years of natural aging. Matched copies of the book Cooking the Greek Way, which had been printed in Czechoslovakia on acidic paper, were evaluated. Nonaqueous treatment of two of the copies with magnesium methoxide dissolved in chlorofluorocarbon solvent had been found in 1967 to have decreased the susceptibility to embrittlement, as evidenced by the results of the accelerated aging, followed by folding endurance tests. Retesting of the same books in 2019, after 52 years of room temperature storage, showed that the deacidification treatments had achieved the following benefits in comparison to the untreated book: (a) higher brightness; (b) higher folding endurance; (c) tensile breaking length higher in the cross-direction of the paper; (d) substantial alkaline reserve content, (e) an alkaline surface pH in the range 7.1–7.4, and (f) higher molecular mass of the cellulose. Remarkably, some of the folding endurance results matched those of unaged samples evaluated in 1967. Scanning electron micrographs showed no differences between the treated and untreated books.
{"title":"Accelerated Aging of Deacidified and Untreated Book Paper in 1967 Compared with 52 Years of Natural Aging","authors":"Tali H. Horst, Richard D. Smith, A. Potthast, M. Hubbe","doi":"10.1515/res-2020-0006","DOIUrl":"https://doi.org/10.1515/res-2020-0006","url":null,"abstract":"Abstract Three copies of a book that had been optionally deacidified using two different procedures in 1967, and then subjected to accelerated aging, were tested again after 52 years of natural aging. Matched copies of the book Cooking the Greek Way, which had been printed in Czechoslovakia on acidic paper, were evaluated. Nonaqueous treatment of two of the copies with magnesium methoxide dissolved in chlorofluorocarbon solvent had been found in 1967 to have decreased the susceptibility to embrittlement, as evidenced by the results of the accelerated aging, followed by folding endurance tests. Retesting of the same books in 2019, after 52 years of room temperature storage, showed that the deacidification treatments had achieved the following benefits in comparison to the untreated book: (a) higher brightness; (b) higher folding endurance; (c) tensile breaking length higher in the cross-direction of the paper; (d) substantial alkaline reserve content, (e) an alkaline surface pH in the range 7.1–7.4, and (f) higher molecular mass of the cellulose. Remarkably, some of the folding endurance results matched those of unaged samples evaluated in 1967. Scanning electron micrographs showed no differences between the treated and untreated books.","PeriodicalId":21154,"journal":{"name":"Restaurator. International Journal for the Preservation of Library and Archival Material","volume":null,"pages":null},"PeriodicalIF":0.4,"publicationDate":"2020-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1515/res-2020-0006","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43864929","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Acidification mechanisms of paper were examined, studying 120 pairs of identical copies of books published from 1971 to 2010 housed in two Japanese university libraries. The pH at the edges of the alkaline paper lowered from 7.5 to 6.4 after 5–10 years and to 5.8 after 10–15 years after publication. The pH bottomed at 5.4 at the edges and at 7.0 in the centre of the sheet. Acid paper showed higher pH at the edges than in the centre of the sheet. The edge pH of the alkaline paper of books stored on an above-ground floor was lower due to more exposure to incoming open air with pollutants compared to paper stored in the basement. Elemental analysis suggested nitrogen oxide deposition, but could not prove sulphur oxide deposition at the edges of the paper. The position-dependent acidification is presumed to relate to the deposition tendency of air pollutants contained in open air, and accordingly the edge pH dropped dramatically. In the 1980s, alkaline paper was increasingly used in the production of books, and it was assumed that no more book acidification was to occur; however, this study concludes that even in alkaline paper, acidification processes will take place over time.
{"title":"Mechanism of Acidification that Progresses in Library Collections of Books Made of Alkaline Paper","authors":"Y. Mochizuki, Hiroshi Itsumura, T. Enomae","doi":"10.1515/res-2020-0008","DOIUrl":"https://doi.org/10.1515/res-2020-0008","url":null,"abstract":"Abstract Acidification mechanisms of paper were examined, studying 120 pairs of identical copies of books published from 1971 to 2010 housed in two Japanese university libraries. The pH at the edges of the alkaline paper lowered from 7.5 to 6.4 after 5–10 years and to 5.8 after 10–15 years after publication. The pH bottomed at 5.4 at the edges and at 7.0 in the centre of the sheet. Acid paper showed higher pH at the edges than in the centre of the sheet. The edge pH of the alkaline paper of books stored on an above-ground floor was lower due to more exposure to incoming open air with pollutants compared to paper stored in the basement. Elemental analysis suggested nitrogen oxide deposition, but could not prove sulphur oxide deposition at the edges of the paper. The position-dependent acidification is presumed to relate to the deposition tendency of air pollutants contained in open air, and accordingly the edge pH dropped dramatically. In the 1980s, alkaline paper was increasingly used in the production of books, and it was assumed that no more book acidification was to occur; however, this study concludes that even in alkaline paper, acidification processes will take place over time.","PeriodicalId":21154,"journal":{"name":"Restaurator. International Journal for the Preservation of Library and Archival Material","volume":null,"pages":null},"PeriodicalIF":0.4,"publicationDate":"2020-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1515/res-2020-0008","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47240447","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-06-04DOI: 10.1515/res-2020-frontmatter2
{"title":"Frontmatter","authors":"","doi":"10.1515/res-2020-frontmatter2","DOIUrl":"https://doi.org/10.1515/res-2020-frontmatter2","url":null,"abstract":"","PeriodicalId":21154,"journal":{"name":"Restaurator. International Journal for the Preservation of Library and Archival Material","volume":null,"pages":null},"PeriodicalIF":0.4,"publicationDate":"2020-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1515/res-2020-frontmatter2","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44418334","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Hydrogen peroxide (HP) residues that remain after the conversion of blackened lead white may cause unwanted paper discolouration and degradation. Four VOCs sorption materials were tested for their ability to eliminate HP gas evolving from the treated substrate. This was tested by measuring the change in HP concentration in aqueous solution and in an enclosed air space in the presence of MicroChamber® Interleaving Paper, Corrosion Intercept® film, Zorflex® activated carbon cloth (ACC) and iron sulphate-impregnated paper. Detection with the colour indicator Quantofix® test strips and a Dräger X-am® 5100 single gas detection device showed that ACC is by far most efficient in decreasing the HP concentration. ACC was also effective in preventing paper discolouration in test objects that had been HP-treated for lead white conversion and then were stored sandwiched between ACC. Although ACC may not eliminate all HP from the substrate, it can diminish its negative effects on the treated object and protect other objects in the vicinity.
{"title":"Eliminating Hydrogen Peroxide Volatiles after Lead White Conversion Treatment Via Sorption Agents","authors":"Luise Raab, U. Henniges, I. Brückle","doi":"10.1515/res-2019-0022","DOIUrl":"https://doi.org/10.1515/res-2019-0022","url":null,"abstract":"Abstract Hydrogen peroxide (HP) residues that remain after the conversion of blackened lead white may cause unwanted paper discolouration and degradation. Four VOCs sorption materials were tested for their ability to eliminate HP gas evolving from the treated substrate. This was tested by measuring the change in HP concentration in aqueous solution and in an enclosed air space in the presence of MicroChamber® Interleaving Paper, Corrosion Intercept® film, Zorflex® activated carbon cloth (ACC) and iron sulphate-impregnated paper. Detection with the colour indicator Quantofix® test strips and a Dräger X-am® 5100 single gas detection device showed that ACC is by far most efficient in decreasing the HP concentration. ACC was also effective in preventing paper discolouration in test objects that had been HP-treated for lead white conversion and then were stored sandwiched between ACC. Although ACC may not eliminate all HP from the substrate, it can diminish its negative effects on the treated object and protect other objects in the vicinity.","PeriodicalId":21154,"journal":{"name":"Restaurator. International Journal for the Preservation of Library and Archival Material","volume":null,"pages":null},"PeriodicalIF":0.4,"publicationDate":"2020-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1515/res-2019-0022","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47542456","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract Theft of archival documents constitutes a serious problem for archives. A possible solution to this problem lies in labelling these documents with codes that are invisible to the naked eye. A possible method could involve use, e.g. of the oxides of lanthanum, dysprosium, samarium, gadolinium and niobium, which have good responses in the XRF spectrum and are normally not present in archival materials. This study is concerned with the impact of these oxides on the properties of lignocellulosic materials. The identification tags were printed on three different kinds of paper supports (Whatman No. 1 filter paper, paper according to ISO 9706 and sulphite pulp). The colour change, average degree of polymerisation, the pH values of an aqueous extract and selected mechanical properties after application of the tag and artificial ageing were studied on all the samples. The measurements showed that the studied oxides do not have a negative effect on the monitored properties of the paper supports and do not affect their long-term ageing behaviour.
{"title":"Identification tags for archival documents based on oxides of transition and inner transition metals – influence on paper supports","authors":"J. Krejčí, B. Benetková, K. Drábková, M. Ďurovič","doi":"10.1515/res-2019-0017","DOIUrl":"https://doi.org/10.1515/res-2019-0017","url":null,"abstract":"Abstract Theft of archival documents constitutes a serious problem for archives. A possible solution to this problem lies in labelling these documents with codes that are invisible to the naked eye. A possible method could involve use, e.g. of the oxides of lanthanum, dysprosium, samarium, gadolinium and niobium, which have good responses in the XRF spectrum and are normally not present in archival materials. This study is concerned with the impact of these oxides on the properties of lignocellulosic materials. The identification tags were printed on three different kinds of paper supports (Whatman No. 1 filter paper, paper according to ISO 9706 and sulphite pulp). The colour change, average degree of polymerisation, the pH values of an aqueous extract and selected mechanical properties after application of the tag and artificial ageing were studied on all the samples. The measurements showed that the studied oxides do not have a negative effect on the monitored properties of the paper supports and do not affect their long-term ageing behaviour.","PeriodicalId":21154,"journal":{"name":"Restaurator. International Journal for the Preservation of Library and Archival Material","volume":null,"pages":null},"PeriodicalIF":0.4,"publicationDate":"2020-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1515/res-2019-0017","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45261482","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Peng Liu, Hongbin Zhang, Sinong Wang, Hui-na Yu, Bingjie Lu, Xinran Li, Chun Wang, Yueer Yan, Yi Tang
Abstract The crystallinity indices (CrI) of Chinese handmade papers were investigated using the X-ray diffraction (XRD) method. Four Chinese handmade papers, Yingchun, Zhuma, Yuanshu and Longxucao papers were used as model substrates of mulberry bark, ramie, bamboo and Eulaliopsis binata papers, respectively. Two forms of the paper samples, paper sheets and their comminuted powders, were used in this study. The results showed that their XRD patterns belong to the cellulose-I type and Iβ dominates the cellulose microstructure of these paper samples. Moreover, it was found that the microstructures and CrIs of cellulose of these papers were changed by the grinding treatment. This work suggested that the sheet form of the handmade papers is suitable to determine CrI by XRD, despite the contribution of non-cellulosic components in the papers. The order of CrIs for these paper sheet samples was Yingchun, Zhuma, Longxucao and Yuanshu papers. Besides CrIs, differences in cross-sectional areas of the crystalline zone of cellulose can be used for comparing different types of handmade papers. It was also found that the CrIs and crystallite size of paper cellulose varied between the sheet samples and the powder samples, illustrating that the pulverisation has a negative influence on the microstructure of the handmade papers.
{"title":"Determination of crystallinity of Chinese handmade papers by means of X-ray diffraction","authors":"Peng Liu, Hongbin Zhang, Sinong Wang, Hui-na Yu, Bingjie Lu, Xinran Li, Chun Wang, Yueer Yan, Yi Tang","doi":"10.1515/res-2019-0009","DOIUrl":"https://doi.org/10.1515/res-2019-0009","url":null,"abstract":"Abstract The crystallinity indices (CrI) of Chinese handmade papers were investigated using the X-ray diffraction (XRD) method. Four Chinese handmade papers, Yingchun, Zhuma, Yuanshu and Longxucao papers were used as model substrates of mulberry bark, ramie, bamboo and Eulaliopsis binata papers, respectively. Two forms of the paper samples, paper sheets and their comminuted powders, were used in this study. The results showed that their XRD patterns belong to the cellulose-I type and Iβ dominates the cellulose microstructure of these paper samples. Moreover, it was found that the microstructures and CrIs of cellulose of these papers were changed by the grinding treatment. This work suggested that the sheet form of the handmade papers is suitable to determine CrI by XRD, despite the contribution of non-cellulosic components in the papers. The order of CrIs for these paper sheet samples was Yingchun, Zhuma, Longxucao and Yuanshu papers. Besides CrIs, differences in cross-sectional areas of the crystalline zone of cellulose can be used for comparing different types of handmade papers. It was also found that the CrIs and crystallite size of paper cellulose varied between the sheet samples and the powder samples, illustrating that the pulverisation has a negative influence on the microstructure of the handmade papers.","PeriodicalId":21154,"journal":{"name":"Restaurator. International Journal for the Preservation of Library and Archival Material","volume":null,"pages":null},"PeriodicalIF":0.4,"publicationDate":"2020-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1515/res-2019-0009","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41875037","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Dear colleagues, This issue of the RESTAURATOR is being published during special times. Our words may reach you at home, during quarantine, at your workplace which may have changed, or at your studio with fewer projects as planned in your order book. We do hope that you stay healthy and that your professional prospects have not worsened considerably. Securities which we have taken for granted have suddenly vanished and our perspectives have shifted. However, one realization seems to prove true more than ever before: the importance of scientific research. We clearly see that it is not only essential to conduct research, but to also share research results and to base decisions on the outcome of transparent studies. In this respect, we want to thank our authors, reviewers and our board for making this publication possible – even during times of constraints and instability. Those of you who have visited our journal homepage will have noticed that the design of the page has changed. We think that searching the homepage has become more convenient and while currently, it is still partly under construction with new changes and guideline upcoming, we hope that you enjoy our new homepage as well! It is always worth visiting because in each issue there is one open access contribution, carefully selected to highlight research results published in RESTAURATOR. The current issue features contributions that had to wait for being printed a bit longer than usual due to our last year’s thematic issue on the history in conservation and teaching. The topics of the current issue range from a technical note on improving paper stability after converting blackened lead white with hydrogen peroxide by Raab et al. to a novel labelling technique to proof ownership by Krejčí et al. and to an analytical study to research the crystallinity of various handmade Chinese papers as a fundament to evaluate the crystallinity’s role in durability of paper.
{"title":"Editorial","authors":"Sigrid Eyb-Green, U. Henniges","doi":"10.1515/res-2020-2001","DOIUrl":"https://doi.org/10.1515/res-2020-2001","url":null,"abstract":"Dear colleagues, This issue of the RESTAURATOR is being published during special times. Our words may reach you at home, during quarantine, at your workplace which may have changed, or at your studio with fewer projects as planned in your order book. We do hope that you stay healthy and that your professional prospects have not worsened considerably. Securities which we have taken for granted have suddenly vanished and our perspectives have shifted. However, one realization seems to prove true more than ever before: the importance of scientific research. We clearly see that it is not only essential to conduct research, but to also share research results and to base decisions on the outcome of transparent studies. In this respect, we want to thank our authors, reviewers and our board for making this publication possible – even during times of constraints and instability. Those of you who have visited our journal homepage will have noticed that the design of the page has changed. We think that searching the homepage has become more convenient and while currently, it is still partly under construction with new changes and guideline upcoming, we hope that you enjoy our new homepage as well! It is always worth visiting because in each issue there is one open access contribution, carefully selected to highlight research results published in RESTAURATOR. The current issue features contributions that had to wait for being printed a bit longer than usual due to our last year’s thematic issue on the history in conservation and teaching. The topics of the current issue range from a technical note on improving paper stability after converting blackened lead white with hydrogen peroxide by Raab et al. to a novel labelling technique to proof ownership by Krejčí et al. and to an analytical study to research the crystallinity of various handmade Chinese papers as a fundament to evaluate the crystallinity’s role in durability of paper.","PeriodicalId":21154,"journal":{"name":"Restaurator. International Journal for the Preservation of Library and Archival Material","volume":null,"pages":null},"PeriodicalIF":0.4,"publicationDate":"2020-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1515/res-2020-2001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43028305","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-03-06DOI: 10.1515/res-2020-frontmatter1
{"title":"Frontmatter","authors":"","doi":"10.1515/res-2020-frontmatter1","DOIUrl":"https://doi.org/10.1515/res-2020-frontmatter1","url":null,"abstract":"","PeriodicalId":21154,"journal":{"name":"Restaurator. International Journal for the Preservation of Library and Archival Material","volume":null,"pages":null},"PeriodicalIF":0.4,"publicationDate":"2020-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1515/res-2020-frontmatter1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47524071","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abstract This research investigates chemical alteration in the important historical pigment called verdigris, both in the form of neutral verdigris (Cu(II) (CH3COO)2 . H2O) and basic verdigris (Cu(II)x(CH3COO)y(OH)z . nH2O), using reference pigment powders and historically relevant “mock-up” samples exposed to artificial aging. Analytical study of model samples by combined Raman spectroscopy, X-ray diffraction and visible spectroscopy provides new evidence that clarifies and builds on the often conflicting body of literature, first in terms of analytical identification of different forms of verdigris pigment, and second by tracing the alteration of neutral verdigris in systems that link to its behavior in aqueous media on historical types of paper. Results further suggest that the historical importance of neutral verdigris as a pigment is underestimated, since commercially available verdigris throughout its heyday – from before the Renaissance through the eighteenth century – was likely to have been dominated by the more easily manufactured neutral salt. This misunderstanding may arise from pigment alteration, whereby the neutral verdigris converts to basic copper salts, or forms organo-copper complexes.
{"title":"Tracing the Alteration of Verdigris Pigment through Combined Raman Spectroscopy and X-ray Diffraction, Part I","authors":"L. Brostoff, Cynthia Connelly Ryan","doi":"10.1515/res-2019-0007","DOIUrl":"https://doi.org/10.1515/res-2019-0007","url":null,"abstract":"Abstract This research investigates chemical alteration in the important historical pigment called verdigris, both in the form of neutral verdigris (Cu(II) (CH3COO)2 . H2O) and basic verdigris (Cu(II)x(CH3COO)y(OH)z . nH2O), using reference pigment powders and historically relevant “mock-up” samples exposed to artificial aging. Analytical study of model samples by combined Raman spectroscopy, X-ray diffraction and visible spectroscopy provides new evidence that clarifies and builds on the often conflicting body of literature, first in terms of analytical identification of different forms of verdigris pigment, and second by tracing the alteration of neutral verdigris in systems that link to its behavior in aqueous media on historical types of paper. Results further suggest that the historical importance of neutral verdigris as a pigment is underestimated, since commercially available verdigris throughout its heyday – from before the Renaissance through the eighteenth century – was likely to have been dominated by the more easily manufactured neutral salt. This misunderstanding may arise from pigment alteration, whereby the neutral verdigris converts to basic copper salts, or forms organo-copper complexes.","PeriodicalId":21154,"journal":{"name":"Restaurator. International Journal for the Preservation of Library and Archival Material","volume":null,"pages":null},"PeriodicalIF":0.4,"publicationDate":"2020-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1515/res-2019-0007","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42759375","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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