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Determination of crystallinity of Chinese handmade papers by means of X-ray diffraction X射线衍射法测定中国手工纸的结晶度
IF 0.4 4区 管理学 Q3 INFORMATION SCIENCE & LIBRARY SCIENCE Pub Date : 2020-05-20 DOI: 10.1515/res-2019-0009
Peng Liu, Hongbin Zhang, Sinong Wang, Hui-na Yu, Bingjie Lu, Xinran Li, Chun Wang, Yueer Yan, Yi Tang
Abstract The crystallinity indices (CrI) of Chinese handmade papers were investigated using the X-ray diffraction (XRD) method. Four Chinese handmade papers, Yingchun, Zhuma, Yuanshu and Longxucao papers were used as model substrates of mulberry bark, ramie, bamboo and Eulaliopsis binata papers, respectively. Two forms of the paper samples, paper sheets and their comminuted powders, were used in this study. The results showed that their XRD patterns belong to the cellulose-I type and Iβ dominates the cellulose microstructure of these paper samples. Moreover, it was found that the microstructures and CrIs of cellulose of these papers were changed by the grinding treatment. This work suggested that the sheet form of the handmade papers is suitable to determine CrI by XRD, despite the contribution of non-cellulosic components in the papers. The order of CrIs for these paper sheet samples was Yingchun, Zhuma, Longxucao and Yuanshu papers. Besides CrIs, differences in cross-sectional areas of the crystalline zone of cellulose can be used for comparing different types of handmade papers. It was also found that the CrIs and crystallite size of paper cellulose varied between the sheet samples and the powder samples, illustrating that the pulverisation has a negative influence on the microstructure of the handmade papers.
摘要采用X射线衍射(XRD)方法研究了中国手工纸的结晶度指数(CrI)。以迎春纸、竹马纸、圆树纸和龙须草纸四种中国手工纸分别作为桑皮纸、苎麻纸、竹纸和龙须草纸的模型基质。在本研究中使用了两种形式的纸张样品,纸张和它们的粉碎粉末。结果表明,它们的XRD图谱属于纤维素-I型,Iβ主导了这些纸样品的纤维素微观结构。此外,还发现这些纸的纤维素的微观结构和CrIs在研磨处理后发生了变化。这项工作表明,尽管纸中存在非纤维素成分,但手工纸的片状形式适合通过XRD测定CrI。这些纸张样本的CrIs顺序为迎春、竹马、龙须草和袁书。除了CrIs之外,纤维素结晶区横截面积的差异也可用于比较不同类型的手工纸。还发现,纸纤维素的CrIs和微晶尺寸在片状样品和粉末样品之间变化,表明粉碎对手工纸的微观结构有负面影响。
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引用次数: 1
Editorial 编辑
IF 0.4 4区 管理学 Q3 INFORMATION SCIENCE & LIBRARY SCIENCE Pub Date : 2020-05-20 DOI: 10.1515/res-2020-2001
Sigrid Eyb-Green, U. Henniges
Dear colleagues, This issue of the RESTAURATOR is being published during special times. Our words may reach you at home, during quarantine, at your workplace which may have changed, or at your studio with fewer projects as planned in your order book. We do hope that you stay healthy and that your professional prospects have not worsened considerably. Securities which we have taken for granted have suddenly vanished and our perspectives have shifted. However, one realization seems to prove true more than ever before: the importance of scientific research. We clearly see that it is not only essential to conduct research, but to also share research results and to base decisions on the outcome of transparent studies. In this respect, we want to thank our authors, reviewers and our board for making this publication possible – even during times of constraints and instability. Those of you who have visited our journal homepage will have noticed that the design of the page has changed. We think that searching the homepage has become more convenient and while currently, it is still partly under construction with new changes and guideline upcoming, we hope that you enjoy our new homepage as well! It is always worth visiting because in each issue there is one open access contribution, carefully selected to highlight research results published in RESTAURATOR. The current issue features contributions that had to wait for being printed a bit longer than usual due to our last year’s thematic issue on the history in conservation and teaching. The topics of the current issue range from a technical note on improving paper stability after converting blackened lead white with hydrogen peroxide by Raab et al. to a novel labelling technique to proof ownership by Krejčí et al. and to an analytical study to research the crystallinity of various handmade Chinese papers as a fundament to evaluate the crystallinity’s role in durability of paper.
这一期《餐馆者》在特殊时期出版。我们的话可能会在家里、在隔离期间、在你可能已经改变的工作场所,或者在你的工作室,你的订单簿中计划的项目减少了。我们真心希望你保持健康,你的职业前景没有严重恶化。我们认为理所当然的证券突然消失了,我们的观点也发生了变化。然而,有一种认识似乎比以往任何时候都更加正确:科学研究的重要性。我们清楚地看到,不仅必须进行研究,而且必须分享研究成果,并根据透明研究的结果作出决定。在这方面,我们要感谢我们的作者、审稿人和我们的董事会,即使在限制和不稳定的时期,他们也使我们的出版成为可能。那些访问过我们期刊主页的人会注意到页面的设计发生了变化。我们认为搜索主页已经变得更加方便,而目前,它仍在部分建设中,新的变化和指导方针即将到来,我们希望你喜欢我们的新主页!它总是值得访问的,因为每期都有一篇开放获取贡献,精心挑选以突出在RESTAURATOR上发表的研究成果。由于我们去年的主题是保护与教学的历史,本期的专题文章不得不比往常稍晚才付印。本期的主题包括Raab等人关于用过氧化氢将黑铅变白后提高纸张稳定性的技术说明,Krejčí等人关于证明所有权的新标签技术,以及研究各种手工中国纸的结晶度作为评估结晶度在纸张耐久性中的作用的基础的分析研究。
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引用次数: 0
Frontmatter Frontmatter
IF 0.4 4区 管理学 Q3 INFORMATION SCIENCE & LIBRARY SCIENCE Pub Date : 2020-03-06 DOI: 10.1515/res-2020-frontmatter1
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引用次数: 0
Tracing the Alteration of Verdigris Pigment through Combined Raman Spectroscopy and X-ray Diffraction, Part I 结合拉曼光谱和X射线衍射追踪Verdigris颜料的变化(上)
IF 0.4 4区 管理学 Q3 INFORMATION SCIENCE & LIBRARY SCIENCE Pub Date : 2020-03-01 DOI: 10.1515/res-2019-0007
L. Brostoff, Cynthia Connelly Ryan
Abstract This research investigates chemical alteration in the important historical pigment called verdigris, both in the form of neutral verdigris (Cu(II) (CH3COO)2 . H2O) and basic verdigris (Cu(II)x(CH3COO)y(OH)z . nH2O), using reference pigment powders and historically relevant “mock-up” samples exposed to artificial aging. Analytical study of model samples by combined Raman spectroscopy, X-ray diffraction and visible spectroscopy provides new evidence that clarifies and builds on the often conflicting body of literature, first in terms of analytical identification of different forms of verdigris pigment, and second by tracing the alteration of neutral verdigris in systems that link to its behavior in aqueous media on historical types of paper. Results further suggest that the historical importance of neutral verdigris as a pigment is underestimated, since commercially available verdigris throughout its heyday – from before the Renaissance through the eighteenth century – was likely to have been dominated by the more easily manufactured neutral salt. This misunderstanding may arise from pigment alteration, whereby the neutral verdigris converts to basic copper salts, or forms organo-copper complexes.
摘要本研究调查了一种名为铜绿的重要历史颜料的化学变化,这两种颜料都是中性铜绿(Cu(II)(CH3COO)2 . H2O)和碱性绿柱石(Cu(II)x(CH3COO)y(OH)z。nH2O),使用参考颜料粉末和暴露于人工老化的历史上相关的“模型”样品。通过结合拉曼光谱、X射线衍射和可见光谱对模型样品进行分析研究,提供了新的证据,澄清并建立在经常相互矛盾的文献基础上,首先是不同形式的铜绿颜料的分析鉴定,第二,通过追踪中性绿在系统中的变化,这些变化与历史类型纸张在水介质中的行为有关。结果进一步表明,中性铜绿作为一种颜料的历史重要性被低估了,因为从文艺复兴之前到18世纪,商业上可买到的铜绿在其全盛时期很可能是由更容易制造的中性盐主导的。这种误解可能源于色素的改变,即中性铜绿转化为碱性铜盐,或形成有机铜络合物。
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引用次数: 4
Investigation of Pigments on an Indian Palm Leaf Manuscript (18th – 19th century) by SEM-EDX and other Techniques 用SEM-EDX等技术研究18 - 19世纪印度棕榈叶手稿上的颜料
IF 0.4 4区 管理学 Q3 INFORMATION SCIENCE & LIBRARY SCIENCE Pub Date : 2020-03-01 DOI: 10.1515/res-2019-0006
M. Singh, D. Sharma
Abstract This paper discusses pigments used in Indian palm leaf manuscripts. Formerly it was believed that pigments for palm leaf illustrations were mostly sourced from plant extracts – a believe that is still widespread in India. This paper reports the identification of pigments of an illustrated palm leaf manuscript (eighteenth – nineteenth century) collected from the east coast of India. As Raman spectra of many pigments gave too high background noise, the identification was mostly accomplished through SEM-EDX and FTIR spectroscopy. The analytical findings indicated that both mineral colours and plant extracts were sourced for Indian palm-leaf manuscripts. Analysis indicated the use of lamp black for black, indigo for blue, vermillion for red, orpiment for yellow, china clay for white and a mixture of orpiment and indigo for green coloration in the illustrations. The data has improved our knowledge of historic pigments used in palm leaf illustrations. As some of the pigments are either photosensitive or darken due to atmospheric pollution, necessary preventive conservation measures need to be adopted.
摘要本文讨论了印度棕榈叶手稿中使用的颜料。以前,人们认为棕榈叶插图的颜料主要来自植物提取物——这种观点在印度仍然很普遍。本文报道了一份从印度东海岸收集的18 - 19世纪棕榈叶手稿的颜料鉴定。由于许多颜料的拉曼光谱具有较高的背景噪声,因此主要通过SEM-EDX和FTIR光谱进行鉴定。分析结果表明,矿物颜色和植物提取物都来自印度棕榈叶手稿。分析表明,在插图中使用了灯黑代替黑色,靛蓝代替蓝色,朱砂代替红色,黄粉代替黄色,瓷土代替白色,黄粉和靛蓝的混合物代替绿色。这些数据提高了我们对棕榈叶插图中使用的历史颜料的认识。由于部分色素因大气污染而光敏或变暗,需要采取必要的预防性保护措施。
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引用次数: 6
Editorial 编辑
IF 0.4 4区 管理学 Q3 INFORMATION SCIENCE & LIBRARY SCIENCE Pub Date : 2020-02-28 DOI: 10.1515/res-2020-0005
U. Henniges, Sigrid Eyb-Green
Multigene phylogeny and reclassification of yeasts and related filamentous taxa in Basidiomycota Basidiomycota are mainly known from mushroom-forming or plant pathogenic species, such as the agarics, smuts, bunts and rusts. However, all three subphyla of Basidiomycota, namely Agaricomycotina, Pucciniomycotina and Ustilaginomycotina, contain species that entirely or largely grow in a unicellular stage and that are known as basidiomycetous yeasts. The taxonomy of these basidiomycetous yeasts, however, has developed largely independent from that of the other taxa and was mainly based on physiological growth profiles, biochemical features of the cell wall, but also DNA features, such as molar percentage guanine and cytosine of the DNA, and molecular phylogenetic inferences. The taxonomy of the filamentous and mushroom-forming Basidiomycota was mainly based on morphology. However, in the era of molecular systematics and comparative genomics the taxonomies of these two “groups” of Basidiomycota can be unified. In this volume of Studies in Mycology we present phylogenies using multiple genes mainly of yeast taxa of Basidiomycota that we integrated with phylogenetic information from filamentous growing basidiomycetes, mainly sequence information of the D1D2 domains of the large subunit of the ribosomal DNA. As a result many so-called yeast or yeast-like species could be linked to filamentous growing species and an updated taxonomy is proposed accordingly. Several traditionally recognized genera of basidiomycetous yeasts were highly polyphyletic, e.g. Cryptococcus and Rhodotorula, just to name two. The multigene phylogenies made it possible to a large extent to redefine such polyphyletic genera. Monophyly was used as a leading principle with clustering optimization and the iterative application of a modified general mixed Yule coalescent (GMYC) as operational
担子菌主要是由木耳菌、黑穗病菌、黑穗病菌和锈病菌等形成蘑菇或植物的病原菌组成的。然而,担子菌的所有三个亚门,即Agaricomycotina、puccinomycotina和Ustilaginomycotina,都含有完全或大部分在单细胞阶段生长的物种,这些物种被称为担子菌酵母。然而,这些担子菌酵母的分类在很大程度上独立于其他分类群,主要基于生理生长特征、细胞壁的生化特征,以及DNA特征,如DNA的鸟嘌呤和胞嘧啶的摩尔百分比,以及分子系统发育推断。丝状和蕈状担子菌的分类主要基于形态学。然而,在分子系统学和比较基因组学时代,担子菌科这两个“类群”的分类可以统一起来。在这本真菌学研究中,我们介绍了主要来自担子菌酵母分类群的多个基因的系统发育,我们将这些基因与来自丝状生长担子菌的系统发育信息整合在一起,主要是核糖体DNA大亚基D1D2结构域的序列信息。因此,许多所谓的酵母或酵母样物种可以与丝状生长物种联系起来,并相应地提出了一种更新的分类方法。几个传统上公认的担子菌酵母属是高度多系的,例如隐球菌和红酵母,仅举两例。多基因系统发生使得在很大程度上重新定义这种多基因属成为可能。以一元性为主导原则,采用聚类优化和改进的通用混合Yule聚结(GMYC)迭代应用作为操作
{"title":"Editorial","authors":"U. Henniges, Sigrid Eyb-Green","doi":"10.1515/res-2020-0005","DOIUrl":"https://doi.org/10.1515/res-2020-0005","url":null,"abstract":"Multigene phylogeny and reclassification of yeasts and related filamentous taxa in Basidiomycota Basidiomycota are mainly known from mushroom-forming or plant pathogenic species, such as the agarics, smuts, bunts and rusts. However, all three subphyla of Basidiomycota, namely Agaricomycotina, Pucciniomycotina and Ustilaginomycotina, contain species that entirely or largely grow in a unicellular stage and that are known as basidiomycetous yeasts. The taxonomy of these basidiomycetous yeasts, however, has developed largely independent from that of the other taxa and was mainly based on physiological growth profiles, biochemical features of the cell wall, but also DNA features, such as molar percentage guanine and cytosine of the DNA, and molecular phylogenetic inferences. The taxonomy of the filamentous and mushroom-forming Basidiomycota was mainly based on morphology. However, in the era of molecular systematics and comparative genomics the taxonomies of these two “groups” of Basidiomycota can be unified. In this volume of Studies in Mycology we present phylogenies using multiple genes mainly of yeast taxa of Basidiomycota that we integrated with phylogenetic information from filamentous growing basidiomycetes, mainly sequence information of the D1D2 domains of the large subunit of the ribosomal DNA. As a result many so-called yeast or yeast-like species could be linked to filamentous growing species and an updated taxonomy is proposed accordingly. Several traditionally recognized genera of basidiomycetous yeasts were highly polyphyletic, e.g. Cryptococcus and Rhodotorula, just to name two. The multigene phylogenies made it possible to a large extent to redefine such polyphyletic genera. Monophyly was used as a leading principle with clustering optimization and the iterative application of a modified general mixed Yule coalescent (GMYC) as operational","PeriodicalId":21154,"journal":{"name":"Restaurator. International Journal for the Preservation of Library and Archival Material","volume":"41 1","pages":"1 - 2"},"PeriodicalIF":0.4,"publicationDate":"2020-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1515/res-2020-0005","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43311779","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Common Deathwatch Beetle Xestobium rufovillosum (DeGeer, 1774) as a Pest for Paper in Books 常见的守望者甲虫Xestobium rufovillosum (DeGeer, 1774)是书中纸张的害虫
IF 0.4 4区 管理学 Q3 INFORMATION SCIENCE & LIBRARY SCIENCE Pub Date : 2020-02-28 DOI: 10.1515/res-2019-0010
J. Karbowska-Berent, Izabela Żołowicz, E. Jabłońska
Abstract A small repository in a cathedral in Poland, storing severely damaged books, was investigated with regard to insects and fungi. Entomological and microbiological surveys were performed to estimate the extent of the infestation and the microbial deterioration of the books. Most of the books were attacked by insects although to varying degrees. They were damaged by tunnels bored by the larvae and filled with larval faeces. Some living larvae and many dead adult beetles were found in the books or in the frass. The larvae and most of the beetles were identified as the common deathwatch beetle Xestobium rufovillosum (DeGeer, 1774). The development of Xestobium rufovillosum in books is an unusual case and has rarely been mentioned in the literature. Several books in the repository were also covered by microfungi, especially by Chaetomium murorum, Ch. elatum, Myxotrichum chartarum, Stachybotrys atra and Epicoccum nigrum. The temperature in the repository varied, depending on the season of the year (2.6 °C – 26.2 °C), while the relative humidity was high (constantly above 65 %). The concentration of the fungal bioaerosol was very high (4,120 cfu/m3). The article includes a list of recommendations pertaining to the elimination of the microorganisms and insects.
摘要波兰一座大教堂的一个小仓库,存放着严重受损的书籍,对昆虫和真菌进行了调查。进行了昆虫学和微生物学调查,以估计书籍的虫害程度和微生物退化情况。大多数书都受到了昆虫的攻击,尽管程度各不相同。它们被幼虫钻的隧道破坏,隧道里充满了幼虫的粪便。一些活的幼虫和许多死的成年甲虫在书中或在废墟中被发现。幼虫和大多数甲虫被鉴定为常见的死亡观察甲虫Xestobium rufovillosum(DeGeer,1774)。在书中发现的若弗氏Xestobium是一个不寻常的案例,在文献中很少提及。储存库中的几本书也被微真菌覆盖,尤其是毛壳藻、透明藻、黄曲霉、黑曲霉和黑表球菌。储存库中的温度因季节而异(2.6°C–26.2°C),而相对湿度较高(始终高于65 %). 真菌生物气溶胶的浓度非常高(4120 cfu/m3)。这篇文章包括一份关于消灭微生物和昆虫的建议清单。
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引用次数: 1
Index 指数
IF 0.4 4区 管理学 Q3 INFORMATION SCIENCE & LIBRARY SCIENCE Pub Date : 2019-12-31 DOI: 10.3138/9781487534264-012
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引用次数: 0
8. Analytic Concept of History 8. 历史分析概念
IF 0.4 4区 管理学 Q3 INFORMATION SCIENCE & LIBRARY SCIENCE Pub Date : 2019-12-31 DOI: 10.3138/9781487534264-009
{"title":"8. Analytic Concept of History","authors":"","doi":"10.3138/9781487534264-009","DOIUrl":"https://doi.org/10.3138/9781487534264-009","url":null,"abstract":"","PeriodicalId":21154,"journal":{"name":"Restaurator. International Journal for the Preservation of Library and Archival Material","volume":"52 1","pages":""},"PeriodicalIF":0.4,"publicationDate":"2019-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90863752","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
2. Pantōn Anakephalaiōsis: A Theory of Human Solidarity 2. Pantōn Anakephalaiōsis:人类团结理论
IF 0.4 4区 管理学 Q3 INFORMATION SCIENCE & LIBRARY SCIENCE Pub Date : 2019-12-31 DOI: 10.3138/9781487534264-003
{"title":"2. Pantōn Anakephalaiōsis: A Theory of Human Solidarity","authors":"","doi":"10.3138/9781487534264-003","DOIUrl":"https://doi.org/10.3138/9781487534264-003","url":null,"abstract":"","PeriodicalId":21154,"journal":{"name":"Restaurator. International Journal for the Preservation of Library and Archival Material","volume":"31 1","pages":""},"PeriodicalIF":0.4,"publicationDate":"2019-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87619697","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"管理学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Restaurator. International Journal for the Preservation of Library and Archival Material
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